US20050188890A1

US20050188890A1 - Composition and method for making frangible bullet

Info

Publication number: US20050188890A1
Application number: US10/787,604
Authority: US
Inventors: Derek Tarrant
Original assignee: Alltrista Zinc Products Co LP
Current assignee: Jarden Zinc Products Inc
Priority date: 2004-02-26
Filing date: 2004-02-26
Publication date: 2005-09-01

Abstract

A composition and method for making a frangible bullet. In one embodiment, the bullet comprises a primarily zinc composition with the addition of bismuth, tin, and/or indium in the amount of about 0.5% to about 20%, by weight. In another embodiment, the bullet comprises additional elements, including but not limited to lead, iron, cadmium, aluminum, copper, and/or titanium. In one embodiment of the method of making a bullet, the composition containing from about 0.5% to about 20% of bismuth, tin, and/or indium is admixed and hand cast into the shape of a bullet core. In another embodiment of the method, the bullet is formed by die casting the admixed composition having from about 0.5% to about 20% of bismuth, tin, and/or indium into the shape of a bullet core.

Description

BACKGROUND OF THE INVENTION

This invention relates to bullets and making bullets and, more particularly, to a composition for a frangible bullet and method of making the same.
Nearly all bullets used by civilians, as well as by the United States military, have a lead core. Lead is used for bullet cores because it has a high density. Lead cores produce increased accuracy and effectiveness when compared to many other types of bullets. Further, lead has a relatively low melting point. Therefore, it is inexpensive to form lead into the core of a bullet when compared with metals having a high melting point. In addition, lead is less expensive than other metals that may have a high density and a low melting point.
A shortcoming associated with bullets having lead cores is that, because lead usually comprises 90-95% of the total weight of bullets, bullets have the potential to introduce large quantities of lead into the environment. Bullets are often left in large quantities on the grounds of practice ranges and on battlefields. The lead leaches into the environment from whole or fragmented bullets that fall onto or are buried in the ground, eventually contaminating the soil, rain water run off and ground water. As a result, wildlife, and possibly even humans, may suffer lead poisoning from the contaminated ground water. Also, the predators of such wildlife suffer from secondary lead poisoning after ingesting the wildlife. In addition, when shooting ranges are converted into residential areas, human exposure to lead may lead to numerous health problems, especially for children exposed to lead. Such health problems include, for example, damage to the nervous system, increased blood pressure, and decreased fertility. Further, the lead may leach into water supplies, potentially harming all living things taking water from such a contaminated supply.
The cost of hazardous waste clean-up, such as lead clean-up, is often significant. Therefore, the operators of outdoor shooting ranges do not voluntarily engage in clean-up operations. Thus, lead contamination of the environment by bullets having lead cores left on such ranges continues to grow.
In view of the environmental hazards resulting from bullets having a lead core, it is desired to develop a bullet that eliminates or reduces these hazards. One solution to the environmental problems associated with lead is to design bullets that do not contain a lead core. However, when used for the purpose of desired injury to the target, non-lead core bullets are often less dense than bullets having a lead core. This lesser density results in inferior ballistic performance and may also result in less stopping power.
During the past several decades, bullet manufacturers have been experimenting with a variety of different types of bullet core and bullet jacket materials. One of the reasons for such experimentation is the desire to avoid the contamination issues associated with lead core bullets. Lead vapors and lead dust caused by the use of standard lead bullets in indoor shooting ranges are a significant hazard to employees and users of such ranges. As previously mentioned, the lead from standard bullets leaches into the soil, eventually contaminating the soil, rainwater run-off and ground water. One of the materials sometimes used, with or without lead, in the manufacture of bullet cores is zinc, for the presence of zinc can act like a battery anode and prevent the lead from reacting with the environment, thereby preventing environmental contamination of soil and water.
Cast or wrought zinc bullets using conventional zinc alloys have been made into bullets in solid core format. Zinc bullets of this type are harder than lead, and do not deform much on impact. As a result, such zinc bullets ricochet considerably more than lead bullets. The use of conventional zinc bullets at shooting ranges poses considerable capture problems, and represents a safety hazard due to the possibility that a ricocheted bullet could hit unintended targets (such as humans) near the intended target. These capture and safety issues have caused all major manufacturers of bullets to discontinue the manufacture of conventional solid core zinc bullets.
Alternatives to solid core zinc bullets have been developed. Typically, these alternative bullets involve fabrication of a core from discrete pieces of zinc. These pieces of zinc are, generally, in the form of stranded zinc wire pressure formed into a compact core within a copper jacket. Such fabrication is difficult to perform and involves the use of expensive stranded zinc wire.
Alternate materials, such as tungsten, have been used for bullet cores. However, tungsten is a very expensive material. Sintered iron cores have also been used, but the sintering operation is costly and difficult to control to a specific degree of core consolidation. Hence, variations in core tensile strengths results from such a process. These differing tensile strengths give rise to differing fragmentation performance of the bullet upon impact. Injection molded cores made from metal powder mixed with thermoplastic resin, such as nylon, have also been manufactured. These injection-molded cores require the use of sophisticated, expensive molding machinery.
In addition to problems of ricochet, when used at shooting ranges, bullets of the prior art do not always address other hazards to individuals, including over-penetration, and back-splatter. While penetration is desirable in a combat or hunting situation when it is desired to inflict harm on the intended target, when in target practice, penetration of the target leads to costly damage to target systems and training structures.
Thus, it is desired to provide a frangible bullet that does not have the ricochet, penetration, and back-splatter problems associated with conventional projectiles, that does not contribute to contamination of the environment or poisoning of persons or animals, and that is reasonable in the costs and other resources required for the composition and manufacture of the bullet.

SUMMARY

As discussed above, most bullets have a lead core because the use of lead ensures that the bullet is accurate and powerful. Further, lead is relatively inexpensive, as is the cost of manufacturing bullets having a lead core due to the low melting point of lead. However, these lead bullets have the potential to introduce large quantities of toxic lead into the environment. Further, when used for situations where no harm is desired or required to the intended target, it is desired to product a projectile that does not penetrate, ricochet, or result in back-splatter.
The present invention comprises a composition and method for making a frangible bullet. The composition of the bullet according to the present invention is comprised primarily of zinc. In one embodiment, the bullet also comprises from about 0.5% to about 20%, by weight, of bismuth, tin, and/or indium. In yet another embodiment, the bullet also comprises one or more additives such as lead, iron, cadmium, aluminum, copper, and/or titanium.
A bullet made with the composition of the present invention is produced by: (a) admixing the zinc together with the bismuth, tin, and/or indium, and (b) forming the composition into the desired shape of the projectile. If the bullet is also to contain one or more of the aforementioned additives, those additives are included in the admixture before the bullet is formed. In one embodiment of the method according to the present invention, the forming process comprises hand casting, while in another embodiment, the forming process is die casting.

DETAILED DESCRIPTION

The present invention comprises a composition and method of making a frangible projectile, such as a bullet. In one embodiment, the composition comprises primarily zinc. The composition also comprises from about 0.5% to about 20%, by weight, of one or more of the combination of bismuth, tin, and/or indium.

In an exemplary embodiment of invention formed by hand casting, the composition comprises from about 1% to about 2% bismuth or tin added to zinc or to conventional zinc alloys. As an example, one composition comprises:



	Metal	Percentage (By Weight)

	Bismuth or Tin	About 1% to about 2%
	Lead	To about 0.005% maximum
	Iron	To about 0.010% maximum
	Cadmium	To about 0.005% maximum
	Aluminum	To about 0.002% maximum
	Copper	To about 0.7% maximum
	Titanium	To about 0.18% maximum
	Zinc	Balance of 100%

The “second additives” of lead, iron, cadmium, aluminum, copper, titanium, and zinc in this example comprise a conventional zinc alloy.

Bullets created according to the above exemplary composition were shot at rifle velocity at a conventional target. Upon impact with the target, these bullets disintegrated entirely. When these bullets were shot at velocities as low as typically achieved with a handgun (circa 1000 feet per second) into a 45-degree inclined hardened steel plate in an enclosed box, all bullets made according to this composition disintegrated into particles less than 5 gains (0.319 grams) in weight, satisfying the requirements of a frangible bullet.
During experimentation, compositions according to the present invention have been molded (formed) successfully into bullets using the process of hand casting and according to the die casting process. Generally, the method of making frangible projectiles according to the present invention comprises the step of admixing the composition, and forming a desired shape and size of the projectile. It is this forming step that involves hand casting or die casting.
When a bullet of the present invention is formed by the process of die casting, experiments have shown that a greater percentage of bismuth, tin, and/or indium may be desired to produce a frangible bullet of desired quality, including the lack of penetration, ricochet, and back-splatter. In one embodiment, the composition for bullets formed by the die casting process comprises from about 5% to about 20%, by weight, of bismuth, tin, and/or indium.
Various experiments were conducted with a wide range of tin, bismuth, and/or indium additives according to the present invention. Such experiments have demonstrated that as little as 0.5% by weight of tin, bismuth, tin and bismuth, or indium result in bullets of suitable frangibility. As much as 5% by weight of indium and as much as 20% by weight of tin, bismuth, or tin and bismuth have also resulted in frangible bullets.
It will be appreciated by those of skill in the art that the term “bullet” as used herein is not intended to be limited to any particular size or shape. Instead, the term “bullet” is intended to extend to all types of projectiles used in weaponry, including various types of ammunition used by small weapons, such as handguns, rifles, and semi-automatic and automatic guns, as well as mortars used by larger weapons.
It will also be appreciated that a projectile comprising the composition of the present invention may be made by processes well known in the art of metal working. It will be further appreciated that indium is generally an expensive material, particularly when compared to bismuth or tin. For this reason, a manufacturer may opt to include only bismuth and/or tin to create a frangible projectile according to the present invention.
It will be yet further appreciated that the projectile composition of the present invention contains primarily zinc, which is not poisonous to humans or wildlife. The composition is not required to contain any poisonous lead, and, if it does contain any lead (as in the example set forth herein), the level of lead is insignificant. If the composition contains no more than about 0.005% lead as in the above example, more than 200 such bullets are required to produce lead equal a single lead core bullet of the weight.
It will be still further appreciated that the materials and the processes used for production of projectiles of the composition according to the present invention are readily available and inexpensive, particularly when compared to many of the complex alternative bullets of the prior art. It will also be appreciated that the frangible bullet of the present invention significantly reduces the hazards of over-penetration, ricochet, and back-splatter.
The present invention can be further modified within the scope and spirit of this disclosure. This application is therefore intended to cover any variations, uses, or adaptations of the invention using its general principles. Further, this application is intended to cover such departures from the present disclosure as come within known or customary practice in the art to which this invention pertains and which fall within the limits of the appended claims.

Claims

1. A denture care kit for decreasing food entrapment comprising:

a. a denture adhesive composition comprising a safe and effective adhesive amount of a denture adhesive component, wherein said denture adhesive composition has a viscosity of from about 5 to about 80 Brookfield;

b. a container for holding and dispensing said denture adhesive composition, said container comprising a nozzle; and

c, information for use for decreasing food entrapment which instructs the denture wearer to apply said denture adhesive composition as a continuous peripheral bead along at least one of a back quarter portion, a back half portion, a back three-quarters portion, a front quarter portion, a front half portion, a front three-quarters portion, or an entire periphery of an upper or lower denture.

2. The denture care kit of claim 1, wherein said nozzle has a tip diameter of from about 80 mils to about 120 mils or has a nozzle tip open surface area of from about 5,024 square mils to about 11,304 square mils, and wherein said nozzle has a length of from about 10 mm to about 25 mm.

3. The denture care kit of claim 1, wherein said nozzle has a tip diameter from about 90 mils to about 110 mils or has a nozzle tip open surface area of from about 6,359 square mils to about 9,499 square mils, and wherein said nozzle has a length of from about 10 mm to about 25 mm.

4. The denture care kit of claim 3, wherein said denture adhesive composition has a viscosity of from about 10 to about 50 Brookfield.

5. The denture care kit of claim 4, wherein said denture adhesive component is selected from the group consisting of AVE/MA, mixed salts of AVE/MA, AVE/MA/IB, mixed salts of AVE/MA/IB, cellulose derivatives, and mixtures thereof.

6. The denture care kit of claim 5, wherein said denture adhesive component is selected from the group consisting of AVE/MA, mixed salts of AVE/MA, cellulose derivatives, and mixtures thereof.

7. The denture care kit of claim 1, wherein said information for use further instructs the denture wearer to apply said denture adhesive composition within a non-peripheral area of said denture.

8. The denture care kit of claim 7, wherein said information for use further instructs the denture wearer to apply said denture adhesive composition to a central portion of said upper or lower denture.

9. The denture care kit of claim 1, wherein the denture care kit further comprises a box for holding said container, said box having said information fixed or printed at least within an interior portion of said box, wherein said information may be viewed upon opening said box.

10. A method of decreasing food entrapment comprising:

a opening a box having information fixed or printed within an interior portion of said box, said information for instructing a denture wearer how to apply a denture adhesive composition along a periphery of a denture in a manner that will decrease food entrapment between said denture and the denture wearer's gums or oral mucous tissues;

b. removing a tube from said box, said tube containing said denture adhesive composition, said denture adhesive composition having a viscosity of from about 5 to about 80 Brookfield; and

c. applying a continuous peripheral bead of said denture adhesive composition to an upper or a lower denture in substantial conformity with said information.

11. The method of claim 10, wherein said information for use instructs the denture wearer to apply said denture adhesive composition as a continuous peripheral bead along at least one of a back quarter portion, a back half portion, a back three-quarters portion, a front quarter portion, a front half portion, a front three-quarters portion, or an entire periphery of an upper or lower denture.

12. The method of claim 10, wherein said information instructs the denture wearer to apply said denture adhesive composition around the entire upper or lower denture.

13. The method of claim 11, wherein said denture wearer applies a continuous bead from about 1 mm to about 15 mm from the edge of said upper denture.

14. The method of claim 11, wherein said denture wearer applies a continuous bead from about 1 mm to about 5 mm from the edge of said lower denture.

15. The method of claim 14, wherein said nozzle has a tip diameter of from about 80 mils to about 120 mils or has a nozzle tip open surface area of from about 5,024 square mils to about 11,304 square mils, and wherein said nozzle has a length of from about 10 mm to about 25 mm.

16. The method of claim 15, wherein said denture adhesive composition has a viscosity of from about 15 to about 30 Brookfield.

17. The method of claim 10, wherein said denture adhesive composition comprises mixed salts of AVE/MA, cellulose derivatives, petrolatum mineral oil, and silica.

18. The method of claim 17, wherein said denture adhesive composition further comprises AVE/MA acid.

19. The method of claim 11, wherein said information is fixed or printed on both said interior and exterior portions of said box, wherein said information on said interior portion of said box is a larger font than said information on said exterior portion of said box.

20. A denture care kit for improving hold comprising;

c. information for use which instructs a denture wearer to apply said denture adhesive composition as a peripheral bead along at least one of a back quarter portion, a back half portion, a back three-quarters portion, a front quarter portion, a front half portion, a front three-quarters portion, or an entire periphery of an upper or lower denture, wherein said information also instructs the denture wearer to apply said denture adhesive composition within a non-peripheral area of an upper or lower denture.

21. The denture care kit of claim 20, wherein said peripheral bead is continuous.

22. The denture care kit of claim 21, wherein said information for use instructs the denture wearer to apply said denture adhesive composition around said entire periphery of said upper denture.

23. The denture care kit of claim 21, wherein said nozzle has a tip diameter of from about 80 mils to about 120 mils or has a nozzle tip open surface area of from about 5,024 square mils to about 11,304 square mils, and wherein said nozzle has a length of from about 10 mm to about 25 mm.

24. The denture care kit of claim 22, wherein said information for use further instructs the denture wearer to apply said denture adhesive composition for decreasing food entrapment.

25. The denture care kit of claim 22, wherein said information for use instructs the denture wearer to apply said denture adhesive composition around said entire periphery of said upper denture.

26. The denture care kit of claim 25, wherein said information for use instructs the denture wearer to apply the denture adhesive composition as two generally parallel non-peripheral beads in said non-peripheral area of said upper denture, wherein said non-peripheral beads are oriented generally transverse to a longitudinal axis of said upper denture.

27. The denture care kit of claim 25, wherein said information for use instructs the denture wearer to apply said denture adhesive composition as a continuous non-peripheral bead in said non-peripheral area of said lower denture, wherein said non-peripheral bead is oriented generally evenly between said peripheral bead.

28. The denture care kit of claim 21, wherein said information for use instructs the denture wearer to apply said denture adhesive composition around said back quarter portion of said upper denture.

29. A method of decreasing food entrapment or sealing out food from under an upper or lower denture, the method comprising:

a. applying a safe and effective amount of a denture adhesive composition on at least a back quarter portion of said upper or lower denture as a continuous peripheral bead for decreasing food entrapment or sealing out food from under said upper or lower denture; and

b. inserting said upper or lower denture into the oral cavity of a denture wearer in need thereof.

30. The method of claim 29, wherein method further comprises applying said denture adhesive composition to at least one of a back half portion, a back three-quarters portion, a front quarter portion, a front half portion, a front three-quarters portion, or an entire periphery of an upper or lower denture.

31. The method of claim 29, wherein said method further comprises applying said denture adhesive composition to a non-peripheral area of said upper or lower denture.

32. The method of claim 31, wherein said method further comprises applying said denture adhesive composition as two generally parallel non-peripheral beads to said non-peripheral area of said upper denture for improved hold, wherein said non-peripheral beads are oriented generally transverse to a longitudinal axis of said upper denture.

33. The method of claim 31, wherein said method further comprises applying said denture adhesive composition as a continuous non-peripheral bead to said non-peripheral area of said lower denture for improved hold.

34. The method of claim 29, wherein said denture adhesive composition is applied from about 1 mm to about 15 mm from the edge of said upper or lower denture.

35. The method of claim 30, wherein said denture adhesive composition is applied from about 1 mm to about 5 mm from the edge of said upper or lower denture.

36. The method of claim 30, wherein said method further comprises applying a continuous bead of said denture adhesive composition around said entire periphery of said lower denture, and applying a non-peripheral bead of said denture adhesive composition in a non-peripheral area of said lower denture, wherein said non-peripheral bead is oriented generally evenly between said peripheral bead.