US20050171246A1 - Method and apparatus for forming composite material and composite material therefrom - Google Patents
Method and apparatus for forming composite material and composite material therefrom Download PDFInfo
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- US20050171246A1 US20050171246A1 US11/065,787 US6578705A US2005171246A1 US 20050171246 A1 US20050171246 A1 US 20050171246A1 US 6578705 A US6578705 A US 6578705A US 2005171246 A1 US2005171246 A1 US 2005171246A1
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- composite material
- filler
- column
- polymer
- oriented polymer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/30—Drawing through a die
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27N—MANUFACTURE BY DRY PROCESSES OF ARTICLES, WITH OR WITHOUT ORGANIC BINDING AGENTS, MADE FROM PARTICLES OR FIBRES CONSISTING OF WOOD OR OTHER LIGNOCELLULOSIC OR LIKE ORGANIC MATERIAL
- B27N3/00—Manufacture of substantially flat articles, e.g. boards, from particles or fibres
- B27N3/08—Moulding or pressing
- B27N3/28—Moulding or pressing characterised by using extrusion presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/86—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling at the nozzle zone
- B29C48/865—Heating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/90—Thermal treatment of the stream of extruded material, e.g. cooling with calibration or sizing, i.e. combined with fixing or setting of the final dimensions of the extruded article
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
- E04F15/10—Flooring or floor layers composed of a number of similar elements of other materials, e.g. fibrous or chipped materials, organic plastics, magnesite tiles, hardboard, or with a top layer of other materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/475—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using pistons, accumulators or press rams
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/90—Thermal treatment of the stream of extruded material, e.g. cooling with calibration or sizing, i.e. combined with fixing or setting of the final dimensions of the extruded article
- B29C48/904—Thermal treatment of the stream of extruded material, e.g. cooling with calibration or sizing, i.e. combined with fixing or setting of the final dimensions of the extruded article using dry calibration, i.e. no quenching tank, e.g. with water spray for cooling or lubrication
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
- B29C48/9135—Cooling of flat articles, e.g. using specially adapted supporting means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
- B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
- B29K2105/16—Fillers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2711/00—Use of natural products or their composites, not provided for in groups B29K2601/00 - B29K2709/00, for preformed parts, e.g. for inserts
- B29K2711/14—Wood, e.g. woodboard or fibreboard
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F2201/00—Joining sheets or plates or panels
- E04F2201/01—Joining sheets, plates or panels with edges in abutting relationship
- E04F2201/0153—Joining sheets, plates or panels with edges in abutting relationship by rotating the sheets, plates or panels around an axis which is parallel to the abutting edges, possibly combined with a sliding movement
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/19—Sheets or webs edge spliced or joined
- Y10T428/192—Sheets or webs coplanar
- Y10T428/195—Beveled, stepped, or skived in thickness
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24777—Edge feature
Definitions
- the present invention relates to extrusion processes.
- the present invention relates to an extrusion method and apparatus for composite material.
- Extrusion processes that are used include ram extrusion and hydrostatic extrusion.
- Ram extrusion utilises a chamber in which polymer billets are placed, one end of which contains a die and the other an axially mobile ram. The billet is placed within the chamber such that the sides of the billet are touching the sides of the chamber. The mobile ram pushes the billets and forces them through the die.
- the billet In hydrostatic extrusion processes, the billet is of a smaller size than the chamber and does not come into contact with the sides of the chamber.
- the chamber contains a pressure generating device at one end and a die at the other.
- the space between the billet and the chamber is filled with a hydraulic fluid, pumped into the chamber at the end containing the pressure generating device.
- pressure is increased on the hydraulic fluid and this in turn transmits pressure to the surface of the billet.
- some of the hydraulic fluid adheres to the surface of the billet, providing additional lubrication to the process.
- Both processes produce a polymer that is oriented in a longitudinal direction, having increased mechanical properties, such as tensile strength and stiffness.
- the orientation in a longitudinal direction can also make the polymer weak and subject to transverse cracking or fibrillation under abrasion.
- the process of pushing the polymer through a die can also create surface imperfections caused by frictional forces.
- U.S. Pat. No. 5,204,045 to Courval et al. discloses a process for extruding polymer shapes with smooth, unbroken surfaces.
- the process includes heating the polymer shape to below the melting point of the polymer and then extruding the polymer through a die that is heated to a temperature at least as high as the temperature of the polymer.
- the process also involves melting a thin surface layer of the polymer to form a thin, smooth surface layer. The process produces a material of a uniform appearance and subsequent commercial applications are limited as a result.
- a composite material comprising an oriented polymer and a particulate filler dispersed throughout the oriented polymer.
- the composite material has a reduced density which is less than the combined masses of the oriented polymer and a particulate filler divided by their combined respective volumes.
- the oriented polymer maybe of plastic and the particulate filler may be selected from the group consisting of wood, slate, talc, vermiculite and mica.
- the plastic may be polypropylene, polyethylene and polyvinyl chloride and present in an amount of from 95% to 60% by weight as compared to the particulate filler.
- the oriented polymer is polypropylene and the particulate filler is wood sawdust having a particle size of about 60 mesh and present in amount of from 20% to 30% by weight as compared to the weight of the oriented polymer.
- a process for producing an oriented composite material comprising the steps
- the extrudable polymer may be of plastic, such as polypropylene, polyethylene or polyvinyl chloride.
- the particulate filler may be wood, slate, talc, vermiculite or mica.
- the extruable polymer may be present in an amount of from 95% to 60% by weight in the starting material.
- the extruable polymer is polypropylene
- the particulate filler is wood sawdust having a particle size of about 60 mesh, the wood sawdust being present in an amount from about 20% to 30% by weight in the starting material.
- the rate of drawing through the drawing die may be sufficient to cause the composite material to have a density of from 0.5 to 0.9 of the density of the starting material.
- a composite material which includes a filler for enhancing the physical properties of the composite material and a binding agent mixed with the filler for permitting extrusion of the composite material in a plastic extrusion process to provide a predetermined dispersion pattern of the filler in the composite material.
- the filler may be natural or synthetic fiber and the binding agent may be a polymer.
- a composite material which comprises a particulate material dispersed in an oriented polymer.
- the particulate material may be wood sawdust having a particle size of about 60 mesh.
- the oriented polymer may be polyethylene with the oriented polymer forming from 60% to 95% by weight of the composite material.
- a strip of composite material is provided, suitable for strip flooring and having parallel upper and lower faces with first and second parallel edges extending between the upper and lower faces.
- the first edge has a tongue extending therefrom with parallel upper and lower curved surfaces.
- the second edge has a groove extending thereinto with curved parallel opposite sides.
- the tongue and the groove are of complimentary curvature for the tongue of a first strip to be rotatable into registration with the groove of an adjacent strip to resist lateral separation between the first strip, and the adjacent strips by interference between the upper and lower curved surfaces and the curved parallel opposite sides.
- FIG. 1 illustrates a method of extruding a composite material according to the present invention
- FIG. 2 illustrates an extruder for extruding same
- FIG. 3 illustrates an extruded billet of the composite material
- FIG. 4 is an end elevation of a tongue and groove joint which may be formed in the extrusion method of the present invention
- FIG. 5 is a cross-sectional illustration of an alternate forming method according to the present invention.
- FIG. 6 is a schematic illustration of an automated process of the method of FIG. 5 .
- a method of extruding a composite material is shown generally at 10 .
- a filler 12 and a binding agent 14 are placed in a feeder 16 .
- Feeder 16 feeds a predetermined volume of filler 12 and binding agent 14 into melt extruder 18 .
- feeder 16 is a gravimetric feeder controlled by an external CPU 17 .
- Melt extruder 18 mixes filler 12 and binding agent 14 to form feedstock 20 , as is well known to those of skill in the art.
- Feedstock 20 then passes to an extruder 22 , and is extruded to produce a composite material 24 .
- Filler 12 can be a natural fibre, such as wood and agricultural fibres such as hemp, flax, straw or wheat; a synthetic fibre such as nylon, polyethylene terephthalate, glass or polypropylene fibre with a polyethylene matrix. Filler 12 can also be a mineral based filler such as slate, talc, vermiculite or mica. In a presently preferred embodiment, filler 12 is a wood fibre concentrate. Filler 12 has a mesh in the range of 10-300, more preferably in the range 10 - 150 . In the presently preferred embodiment filler 12 has a 60 mesh.
- Binding agent 14 is a polymer or other suitable extrudable plastic, such as polypropylene (PP), polyethylene (PE) or polyvinyl chloride (PVC). Binding agent 14 forms approximately 55-95% by weight of feedstock 20 . Other ranges for the % weight of binding agent 14 in feedstock 20 may be appropriate depending on the filler chosen. More limited ranges of 60-95% or 70-90% may be required depending on the chosen filler 12 .
- PP polypropylene
- PE polyethylene
- PVC polyvinyl chloride
- filler 12 and binding agent 14 have been fed to feeder 16 , they pass to melt extruder 18 .
- a predetermined volume of filler 12 , in accordance with the % weight of binding agent 14 that is used, and binding agent 14 are mixed in melt extruder 18 and extruded in a conventional manner to produce feedstock 20 .
- the resultant feedstock 20 is fed by melt extruder 18 to extruder 22 .
- FIG. 2 illustrates a preferred embodiment of extruder 22 .
- Extruder 22 has a ram 34 , a pressure chamber 30 and a die 38 .
- the method and apparatus of the extrusion process are detailed in U.S. Pat. No. 5,169,589 to Francoeur et al., U.S. Pat. No. 5,204,045 to Courval et al. and U.S. Pat. No. 5,169,587 to Courval, the contents of which are incorporated herein by reference.
- the method of the extrusion process produces a highly oriented polymer profile.
- the resultant composite material 24 produced by this process, generally has a higher tensile strength and modulus than feedstock 20 .
- an oriented product 48 of composite material 24 formed with a wood-fibre concentrate filler is produced in standard widths of 2 inches, 3 inches or 6 inches (5.08 cm, 7.62 cm or 15.24 cm).
- FIG. 3 illustrates an oriented product 48 of composite material 24 .
- composite material 24 has striations 50 of filler 12 , formed in a dispersion pattern with a wood-grain appearance.
- the resultant oriented product 48 resembles hard wood flooring and can be adapted to be used in commercial applications as such.
- Appropriate attaching means such as a tongue and groove, or snap lock, can be subsequently tooled in to the oriented material to create a product that can be attached in series in a commercial application, such as flooring or furniture manufacturing.
- Surface treatment can also be applied to the billet for increasing the surface properties of the billet, such as adding a protective coating, such as polyurethane, to protect the surface layer from scratching.
- properties of composite material 24 can be changed.
- the properties of composite material 24 can also be changed by varying amounts of filler 12 , and by changing the composition of filler 12 . This will affect the physical properties of composite material 24 , such as colour, texture, electrical conductivity, glow in the dark and fire retardancy.
- the oriented product 48 of composite material 24 can be manipulated in order to meet a manufacturer's specifications with regards to the final commercial application. Oriented product 48 can be cut and shaped during the ram extruding process. In the presently preferred embodiment, composite material 24 is extruded as oriented product 48 of varying specifications, however it can also be extruded as a sheet for use in commercial applications such as indoor and outdoor furniture manufacturing.
- the present invention provides a new composite material, and a method and apparatus for extruding the composite material.
- the invention includes the initial mixing of a binding agent and a filler to produce a feedstock which is subsequently extruded as a billet of a composite material.
- the composite material is stronger and more durable then the starting materials.
- the composite material also contains striations of the filler which allows the manufacturer to produce a composite material that can reflect the image of a natural product and can be used in commercial applications such as floor coverings.
- the properties of the composite material can also be changed, in order to met the requirements for the commercial application of the product, by the incorporation of different types of filler and by varying the amount of filler used.
- FIG. 4 is an end elevation showing a particularly advantageous tongue and groove configuration which can be formed along opposite edges of the oriented product 48 of the composite material 24 .
- a first edge 50 has a tongue 52 formed thereon having an upper concave face 54 and a lower convex face 56 .
- the opposite edge 60 has a groove 62 with an upper convex edge 64 and a lower concave edge 66 .
- the tongue 52 and the groove 62 register to allow the tongue to be initially inserted into the groove 62 of an adjacent strip of oriented product 48 at a relative angle on the order of 45° between the adjacent strips of oriented product 48 and then rotated into place in the direction of arrow 70 so that the tongue 52 nests in the groove 62 with the adjacent strips of oriented product in a parallel side by side configuration.
- Extrusion rates for the composite material 24 will vary depending on various factors such as the particular composite material 24 selected, the degree of reduction, and the cross-sectional area of the extruded strip or column. Extrusion rates are however rather slow and rates on the order of six inches per minute (6 in./min.) are not atypical.
- FIG. 5 illustrates such a drawing process.
- One manner of drawing the composite material through the die 38 is to initially commence by extrusion, as discussed above. Once an end 100 of the oriented product 48 begins to emerge from the die 38 , the end may be grasped, such as by a clamp 102 and pulled. The pulling would typically be done with no further pressing force being applied and yields an oriented end product 104 .
- a starting billet 110 was first formed by combining a wood fiber plastic concentrate containing 60% wood particles of about 60 mesh size and 50% polypropylene with virgin polypropylene in a 1:1 ratio. This yielded a composition having about 30% wood fiber and 70% polypropylene. The resulting combination was heated and extruded to form the billet 110 .
- the billet 110 was of rectangular cross-section measuring about two inches by two inches (2′′ ⁇ 2′′).
- the billet 110 was heated in an oven to about 150° C. (ie. close to but below the melting point of polypropylene which is about 160° C.) and transferred to the pressure chamber 30 and initially forced through the die 38 .
- the extruded material was then grasped using the clamp 102 and drawn at a rate of about 4 ft./min. (Four feet per minute) and once it had been entirely drawn through the die 38 , allowed to cool into the oriented end product 104 .
- the draw ratio i.e. the initial cross-sectional area divided by the final cross-sectional area) was 10:4.
- the oriented end product 104 bore a remarkable similarity both in look and in feel to wood.
- the oriented end product 104 diminished in density by about half compared to the starting billet 110 .
- the density of the oriented end product 104 was about 0.59 g/cc (grams per cubic centimeter) compared to a density of about 1 g/cc for the starting billet 110 .
- the oriented end product 104 could be shaped as if it were wood and in planing and sawing behaved very much like wood producing shavings remarkably like wood shavings and sawdust remarkably like wood sawdust.
- the oriented end product 104 received both nails and screws without splitting much like wood.
- the oriented end product was found to have a density and flexural strength not unlike wood and a modulus of elasticity of about half that of wood. Typical properties were a density of 0.059 g/cc, flexural strength of 6,353 lb/in 2 and a modulus of elasticity of 799,298 lb/in 2 . Unlike wood however the oriented product 104 was virtually non adsorptive to water.
- FIG. 6 shows an extruder 120 in which feed materials 121 may be blended and extruded through a die 122 into a first column 124 .
- the first column 124 is fed through a first haul off 125 into a continuous furnace 126 where its temperature is adjusted to a drawing temperature.
- the first haul off 125 acts against the extrusion direction to maintain extrusion pressure and to support the column 124 .
- the temperature adjusted first column 124 is fed into a drawing die 128 at the exit of which it is reduced in size to a second column 130 .
- the second column 130 is grasped by a suitable haul off 132 such as sold under the trademark CATERPILLAR as it exits the drawing die 128 .
- the haul off 132 then pulls the second column 130 at a desired rate to form an oriented product 138 .
Abstract
A system and method for extruding composite material and the composite material therefrom. The composite material consists of a filler mixed with a binding agent. The composite material is extruded as billets with enhanced physical properties, such as colour, texture, electrical conductivity and fire retardancy, and contains a dispersion pattern of the filler material. A system and method are also provided for drawing the composite material through a die and a composite material produced thereby. The drawn composite material exhibits a density reduction over the density of the starting material and enhanced physical properties. A particularly useful tongue and groove arrangement are also provided for joining adjacent strips of a composite material made according to the extrusion process.
Description
- The present invention relates to extrusion processes. In particular, the present invention relates to an extrusion method and apparatus for composite material.
- The process of solid-state extrusion is known. Extrusion processes that are used include ram extrusion and hydrostatic extrusion. Ram extrusion utilises a chamber in which polymer billets are placed, one end of which contains a die and the other an axially mobile ram. The billet is placed within the chamber such that the sides of the billet are touching the sides of the chamber. The mobile ram pushes the billets and forces them through the die.
- In hydrostatic extrusion processes, the billet is of a smaller size than the chamber and does not come into contact with the sides of the chamber. The chamber contains a pressure generating device at one end and a die at the other. The space between the billet and the chamber is filled with a hydraulic fluid, pumped into the chamber at the end containing the pressure generating device. During operation pressure is increased on the hydraulic fluid and this in turn transmits pressure to the surface of the billet. As the billet passes through the die some of the hydraulic fluid adheres to the surface of the billet, providing additional lubrication to the process.
- Both processes produce a polymer that is oriented in a longitudinal direction, having increased mechanical properties, such as tensile strength and stiffness. However, the orientation in a longitudinal direction can also make the polymer weak and subject to transverse cracking or fibrillation under abrasion. The process of pushing the polymer through a die can also create surface imperfections caused by frictional forces.
- U.S. Pat. No. 5,204,045 to Courval et al. discloses a process for extruding polymer shapes with smooth, unbroken surfaces. The process includes heating the polymer shape to below the melting point of the polymer and then extruding the polymer through a die that is heated to a temperature at least as high as the temperature of the polymer. The process also involves melting a thin surface layer of the polymer to form a thin, smooth surface layer. The process produces a material of a uniform appearance and subsequent commercial applications are limited as a result.
- A composite material comprising an oriented polymer and a particulate filler dispersed throughout the oriented polymer. The composite material has a reduced density which is less than the combined masses of the oriented polymer and a particulate filler divided by their combined respective volumes.
- The oriented polymer maybe of plastic and the particulate filler may be selected from the group consisting of wood, slate, talc, vermiculite and mica.
- The plastic may be polypropylene, polyethylene and polyvinyl chloride and present in an amount of from 95% to 60% by weight as compared to the particulate filler.
- According to one embodiment, the oriented polymer is polypropylene and the particulate filler is wood sawdust having a particle size of about 60 mesh and present in amount of from 20% to 30% by weight as compared to the weight of the oriented polymer.
- A process for producing an oriented composite material, said process comprising the steps
- of combining:
-
-
- (i) an extrudable polymer with a particulate filler to form a starting material;
- (ii) heating and extruding said starting material into a first column;
- (iii) adjusting the temperature of said first column to a drawing temperature;
- (iv) presenting said first column to a drawing die and causing said first column to exit said drawing die in a second column having a cross-sectional area less than that of said first column;
- (v) applying a pulling force to said second column to draw said first column through said drawing die at a rate sufficient to cause orientation of said polymer and to cause said second column diminish in density to form said composite material.
- The extrudable polymer may be of plastic, such as polypropylene, polyethylene or polyvinyl chloride.
- The particulate filler may be wood, slate, talc, vermiculite or mica.
- The extruable polymer may be present in an amount of from 95% to 60% by weight in the starting material.
- According to one embodiment, the extruable polymer is polypropylene, the particulate filler is wood sawdust having a particle size of about 60 mesh, the wood sawdust being present in an amount from about 20% to 30% by weight in the starting material.
- The rate of drawing through the drawing die may be sufficient to cause the composite material to have a density of from 0.5 to 0.9 of the density of the starting material.
- A composite material is provided which includes a filler for enhancing the physical properties of the composite material and a binding agent mixed with the filler for permitting extrusion of the composite material in a plastic extrusion process to provide a predetermined dispersion pattern of the filler in the composite material.
- The filler may be natural or synthetic fiber and the binding agent may be a polymer.
- A composite material is provided which comprises a particulate material dispersed in an oriented polymer.
- The particulate material may be wood sawdust having a particle size of about 60 mesh. The oriented polymer may be polyethylene with the oriented polymer forming from 60% to 95% by weight of the composite material.
- A strip of composite material is provided, suitable for strip flooring and having parallel upper and lower faces with first and second parallel edges extending between the upper and lower faces. The first edge has a tongue extending therefrom with parallel upper and lower curved surfaces. The second edge has a groove extending thereinto with curved parallel opposite sides. The tongue and the groove are of complimentary curvature for the tongue of a first strip to be rotatable into registration with the groove of an adjacent strip to resist lateral separation between the first strip, and the adjacent strips by interference between the upper and lower curved surfaces and the curved parallel opposite sides.
- Preferred embodiments of the present invention will now be described, by way of example only, with reference to the attached Figures, wherein:
-
FIG. 1 illustrates a method of extruding a composite material according to the present invention; -
FIG. 2 illustrates an extruder for extruding same; -
FIG. 3 illustrates an extruded billet of the composite material; -
FIG. 4 is an end elevation of a tongue and groove joint which may be formed in the extrusion method of the present invention; -
FIG. 5 is a cross-sectional illustration of an alternate forming method according to the present invention; and -
FIG. 6 is a schematic illustration of an automated process of the method ofFIG. 5 . - Referring now to
FIG. 1 a method of extruding a composite material is shown generally at 10. Afiller 12 and abinding agent 14 are placed in afeeder 16. Feeder 16 feeds a predetermined volume offiller 12 and bindingagent 14 intomelt extruder 18. In an embodiment,feeder 16 is a gravimetric feeder controlled by anexternal CPU 17. Melt extruder 18mixes filler 12 and bindingagent 14 to formfeedstock 20, as is well known to those of skill in the art. Feedstock 20 then passes to anextruder 22, and is extruded to produce acomposite material 24. -
Filler 12 can be a natural fibre, such as wood and agricultural fibres such as hemp, flax, straw or wheat; a synthetic fibre such as nylon, polyethylene terephthalate, glass or polypropylene fibre with a polyethylene matrix.Filler 12 can also be a mineral based filler such as slate, talc, vermiculite or mica. In a presently preferred embodiment,filler 12 is a wood fibre concentrate.Filler 12 has a mesh in the range of 10-300, more preferably in the range 10-150. In the presently preferredembodiment filler 12 has a 60 mesh. - Binding
agent 14 is a polymer or other suitable extrudable plastic, such as polypropylene (PP), polyethylene (PE) or polyvinyl chloride (PVC). Bindingagent 14 forms approximately 55-95% by weight offeedstock 20. Other ranges for the % weight of bindingagent 14 infeedstock 20 may be appropriate depending on the filler chosen. More limited ranges of 60-95% or 70-90% may be required depending on the chosenfiller 12. - Once
filler 12 and bindingagent 14 have been fed tofeeder 16, they pass to meltextruder 18. A predetermined volume offiller 12, in accordance with the % weight of bindingagent 14 that is used, and bindingagent 14 are mixed inmelt extruder 18 and extruded in a conventional manner to producefeedstock 20. Theresultant feedstock 20 is fed bymelt extruder 18 toextruder 22. -
FIG. 2 illustrates a preferred embodiment ofextruder 22.Extruder 22 has aram 34, apressure chamber 30 and adie 38. The method and apparatus of the extrusion process are detailed in U.S. Pat. No. 5,169,589 to Francoeur et al., U.S. Pat. No. 5,204,045 to Courval et al. and U.S. Pat. No. 5,169,587 to Courval, the contents of which are incorporated herein by reference. The method of the extrusion process produces a highly oriented polymer profile. The resultantcomposite material 24, produced by this process, generally has a higher tensile strength and modulus thanfeedstock 20. In the presently preferred embodiment an orientedproduct 48 ofcomposite material 24, formed with a wood-fibre concentrate filler is produced in standard widths of 2 inches, 3 inches or 6 inches (5.08 cm, 7.62 cm or 15.24 cm). -
FIG. 3 illustrates an orientedproduct 48 ofcomposite material 24. Produced in the manner outlined above,composite material 24 has striations 50 offiller 12, formed in a dispersion pattern with a wood-grain appearance. The resultant orientedproduct 48 resembles hard wood flooring and can be adapted to be used in commercial applications as such. Appropriate attaching means, such as a tongue and groove, or snap lock, can be subsequently tooled in to the oriented material to create a product that can be attached in series in a commercial application, such as flooring or furniture manufacturing. Surface treatment can also be applied to the billet for increasing the surface properties of the billet, such as adding a protective coating, such as polyurethane, to protect the surface layer from scratching. - By varying parameters of the ram extrusion process, such as temperature, pressure and die contours, properties of
composite material 24 can be changed. The properties ofcomposite material 24 can also be changed by varying amounts offiller 12, and by changing the composition offiller 12. This will affect the physical properties ofcomposite material 24, such as colour, texture, electrical conductivity, glow in the dark and fire retardancy. - The oriented
product 48 ofcomposite material 24 can be manipulated in order to meet a manufacturer's specifications with regards to the final commercial application. Orientedproduct 48 can be cut and shaped during the ram extruding process. In the presently preferred embodiment,composite material 24 is extruded as orientedproduct 48 of varying specifications, however it can also be extruded as a sheet for use in commercial applications such as indoor and outdoor furniture manufacturing. - The present invention provides a new composite material, and a method and apparatus for extruding the composite material. The invention includes the initial mixing of a binding agent and a filler to produce a feedstock which is subsequently extruded as a billet of a composite material. The composite material is stronger and more durable then the starting materials. The composite material also contains striations of the filler which allows the manufacturer to produce a composite material that can reflect the image of a natural product and can be used in commercial applications such as floor coverings. The properties of the composite material can also be changed, in order to met the requirements for the commercial application of the product, by the incorporation of different types of filler and by varying the amount of filler used.
-
FIG. 4 is an end elevation showing a particularly advantageous tongue and groove configuration which can be formed along opposite edges of the orientedproduct 48 of thecomposite material 24. Afirst edge 50 has atongue 52 formed thereon having an upperconcave face 54 and a lowerconvex face 56. Theopposite edge 60 has agroove 62 with an upperconvex edge 64 and a lowerconcave edge 66. Thetongue 52 and thegroove 62 register to allow the tongue to be initially inserted into thegroove 62 of an adjacent strip of orientedproduct 48 at a relative angle on the order of 45° between the adjacent strips of orientedproduct 48 and then rotated into place in the direction ofarrow 70 so that thetongue 52 nests in thegroove 62 with the adjacent strips of oriented product in a parallel side by side configuration. - Once the
tongue 52 and thegroove 62 are nested, removal in a lateral direction indicated byarrows 80 is prevented first by interference between anupper edge 58 of the tongue and a depending edge 68 of the groove. Lateral separation is further inhibited by an upwardly extendingedge 69 of thegroove 62 interfering with alowermost portion 59 of thetongue 52. - Extrusion rates for the
composite material 24 will vary depending on various factors such as the particularcomposite material 24 selected, the degree of reduction, and the cross-sectional area of the extruded strip or column. Extrusion rates are however rather slow and rates on the order of six inches per minute (6 in./min.) are not atypical. - It has been found that rather than extruding the
composite material 24, by pressing it through thedie 38, the composite material may be drawn through thedie 38.FIG. 5 illustrates such a drawing process. - One manner of drawing the composite material through the
die 38 is to initially commence by extrusion, as discussed above. Once anend 100 of the orientedproduct 48 begins to emerge from thedie 38, the end may be grasped, such as by aclamp 102 and pulled. The pulling would typically be done with no further pressing force being applied and yields an orientedend product 104. - In tests, pulling rates of up to 14 ft./min. (fourteen feet per minute) have been achieved which was limited by machine capacity. It is expected that pulling rates of 20 ft./min. (twenty feet per minute) are entirely feasible.
- The properties of the oriented
end product 104 produced by drawing are significantly different than those produced by extrusion. By way of example, a startingbillet 110 was first formed by combining a wood fiber plastic concentrate containing 60% wood particles of about 60 mesh size and 50% polypropylene with virgin polypropylene in a 1:1 ratio. This yielded a composition having about 30% wood fiber and 70% polypropylene. The resulting combination was heated and extruded to form thebillet 110. - The
billet 110 was of rectangular cross-section measuring about two inches by two inches (2″×2″). Thebillet 110 was heated in an oven to about 150° C. (ie. close to but below the melting point of polypropylene which is about 160° C.) and transferred to thepressure chamber 30 and initially forced through thedie 38. The extruded material was then grasped using theclamp 102 and drawn at a rate of about 4 ft./min. (Four feet per minute) and once it had been entirely drawn through thedie 38, allowed to cool into the orientedend product 104. The draw ratio (i.e. the initial cross-sectional area divided by the final cross-sectional area) was 10:4. - The oriented
end product 104 bore a remarkable similarity both in look and in feel to wood. The orientedend product 104 diminished in density by about half compared to the startingbillet 110. The density of the orientedend product 104 was about 0.59 g/cc (grams per cubic centimeter) compared to a density of about 1 g/cc for the startingbillet 110. - The oriented
end product 104 could be shaped as if it were wood and in planing and sawing behaved very much like wood producing shavings remarkably like wood shavings and sawdust remarkably like wood sawdust. The orientedend product 104 received both nails and screws without splitting much like wood. - In testing, the oriented end product was found to have a density and flexural strength not unlike wood and a modulus of elasticity of about half that of wood. Typical properties were a density of 0.059 g/cc, flexural strength of 6,353 lb/in2 and a modulus of elasticity of 799,298 lb/in2. Unlike wood however the oriented
product 104 was virtually non adsorptive to water. - Although testing was carried out using a starting
billet 110, the process can no doubt be automated as schematically illustrated inFIG. 6 .FIG. 6 shows anextruder 120 in which feedmaterials 121 may be blended and extruded through adie 122 into afirst column 124. Thefirst column 124 is fed through a first haul off 125 into acontinuous furnace 126 where its temperature is adjusted to a drawing temperature. The first haul off 125 acts against the extrusion direction to maintain extrusion pressure and to support thecolumn 124. The temperature adjustedfirst column 124 is fed into a drawing die 128 at the exit of which it is reduced in size to asecond column 130. Thesecond column 130 is grasped by a suitable haul off 132 such as sold under the trademark CATERPILLAR as it exits the drawing die 128. The haul off 132 then pulls thesecond column 130 at a desired rate to form an oriented product 138. - The above-described embodiments of the invention are intended to be examples of the present invention and alterations and modifications may be effected thereto, by those of skill in the art, without departing from the scope of the invention which is defined solely by the claims appended hereto.
Claims (16)
1. A composite material comprising:
an oriented polymer; and
a particulate filler dispersed throughout said oriented polymer,
wherein said composite material has a reduced density which is less than the combined masses of the oriented polymer and particulate filler divided by their combined respective volumes.
2. The composite material of claim 1 wherein:
said oriented polymer is a plastic; and
said particulate filler is selected from the group consisting of wood, slate, talc, vermiculite and mica.
3. The composite material of claim 2 wherein:
said oriented polymer is selected from the group consisting of polypropylene, polyethylene and polyvinyl chloride.
4. The composite material of claim 1 where:
said oriented polymer is present in an amount of from 95 to 60 percent by weight as compared to said particulate filler.
5. The composite material of claim 4 wherein:
said oriented polymer is selected from the group consisting of polypropylene, polyethylene, and polyvinyl chloride.
6. The composite material of claim 4 wherein:
said particulate filler is selected from the group consisting of wood, slate, talc, vermiculite and mica.
7. The composite material of claim 4 wherein:
said oriented polymer is polypropylene; and
said particulate filler is wood sawdust.
8. The composite material of claim 7 wherein:
said sawdust has a particle size of about 60 mesh.
9. The composite material of claim 8 wherein:
said particulate filler is present in an amount of from 20% to 30% by weight as compared to said oriented polymer.
20. An oriented composite material as produced by a process comprising the steps of:
i) combining an extrudable polymer with a cellulose based particulate filler to form a starting material;
ii) heating and extruding said starting material into a first column;
iii) adjusting the temperature of said first column to a drawing temperature;
iv) presenting said first column to a drawing die and causing said first column to exit said drawing die in a second column having a cross-sectional area less than that of said first column;
v) applying a pulling force to said second column to draw said first column through said drawing die at a rate sufficient to cause orientation of said polymer and to cause said second column to diminish in density to form said composite material.
21. A composite material comprising:
a filler for enhancing the physical properties of said composite material; and a binding agent, mixed with said filler, for permitting extrusion of billet of said composite material in a plastic extrusion process to provide a predetermined dispersion pattern of said filler in said composite material.
22. The composite material of claim 21 wherein said filler is a natural fiber.
23. The composite material of claim 21 wherein said filler is a synthetic fiber.
24. The composite material of claim 21 wherein said binding agent is a polymer.
25. A composite material comprising a particulate material dispersed in an oriented polymer.
26. The composite material of claim 25 wherein said particulate material is wood sawdust having a particle size of about 60 mesh;
said oriented polymer is polyethylene; and
said oriented polymer forms from 60% to 95% by weight of said composite material.
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US10/168,716 US6939496B2 (en) | 1999-12-20 | 2000-12-19 | Method and apparatus for forming composite material and composite material therefrom |
US11/065,787 US20050171246A1 (en) | 1999-12-20 | 2005-02-25 | Method and apparatus for forming composite material and composite material therefrom |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
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US8101100B1 (en) | 2007-07-19 | 2012-01-24 | Advanced Environmental Recycling Technologies, Inc. | Method for processing and analyzing contaminated mixed waste plastics to produce reformulated, blended feed materials having a target density |
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Citations (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2365374A (en) * | 1941-04-23 | 1944-12-19 | Plax Corp | Method of shaping plastics by extrusion |
US3493527A (en) * | 1962-06-07 | 1970-02-03 | George Berthold Edward Schuele | Moldable composition formed of waste wood or the like |
US3888810A (en) * | 1972-07-11 | 1975-06-10 | Nippon Oil Co Ltd | Thermoplastic resin composition including wood and fibrous materials |
US4104207A (en) * | 1975-04-04 | 1978-08-01 | Hans Dieter Pelikan | Process for production of cellular cavities in thermoplastic material in which the medium which forms the gas bubbles is bound to a carrier |
US4228116A (en) * | 1973-03-23 | 1980-10-14 | G.O.R. Applicazioni Speciali S.P.A. | Process for producing remoldable panels |
US4426820A (en) * | 1979-04-24 | 1984-01-24 | Heinz Terbrack | Panel for a composite surface and a method of assembling same |
US4624976A (en) * | 1984-07-20 | 1986-11-25 | Nippon Petrochemicals Co., Ltd. | Modeling material composition |
US5070111A (en) * | 1991-03-13 | 1991-12-03 | Advanced Elastomer Systems, L.P. | Foaming thermoplastic elastomers |
US5088910A (en) * | 1990-03-14 | 1992-02-18 | Advanced Environmental Recycling Technologies, Inc. | System for making synthetic wood products from recycled materials |
US5130342A (en) * | 1988-10-14 | 1992-07-14 | Mcallister Jerome W | Particle-filled microporous materials |
US5169589A (en) * | 1990-06-27 | 1992-12-08 | Symplastics Limited | Process and apparatus for deformation of solid thermoplastic polymers and related products |
US5169587A (en) * | 1990-06-15 | 1992-12-08 | Symplastics Limited | Process for extruding large oriented polymer shapes |
US5204045A (en) * | 1990-06-15 | 1993-04-20 | Symplastics Limited | Process for extruding polymer shapes with smooth, unbroken surface |
US5406768A (en) * | 1992-09-01 | 1995-04-18 | Andersen Corporation | Advanced polymer and wood fiber composite structural component |
US5474722A (en) * | 1992-11-13 | 1995-12-12 | The Governing Council Of The University Of Toronto | Oriented thermoplastic and particulate matter composite material |
US5516472A (en) * | 1993-11-12 | 1996-05-14 | Strandex Corporation | Extruded synthetic wood composition and method for making same |
US5518677A (en) * | 1993-02-12 | 1996-05-21 | Andersen Corporation | Advanced polymer/wood composite pellet process |
US5797723A (en) * | 1996-11-13 | 1998-08-25 | General Electric Company | Turbine flowpath seal |
US5847016A (en) * | 1996-05-16 | 1998-12-08 | Marley Mouldings Inc. | Polymer and wood flour composite extrusion |
US6006486A (en) * | 1996-06-11 | 1999-12-28 | Unilin Beheer Bv, Besloten Vennootschap | Floor panel with edge connectors |
US6054207A (en) * | 1998-01-21 | 2000-04-25 | Andersen Corporation | Foamed thermoplastic polymer and wood fiber profile and member |
US6345481B1 (en) * | 1997-11-25 | 2002-02-12 | Premark Rwp Holdings, Inc. | Article with interlocking edges and covering product prepared therefrom |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4153751A (en) * | 1975-03-31 | 1979-05-08 | Biax-Fiberfilm Corporation | Process for stretching an impregnated film of material and the microporous product produced thereby |
US4350655A (en) * | 1977-05-05 | 1982-09-21 | Biax Fiberfilm | Process for producing highly porous thermoplastic films |
WO1980002671A1 (en) | 1979-06-06 | 1980-12-11 | Nat Res Dev | Polymer processing |
EP0066672B1 (en) * | 1981-06-09 | 1987-09-02 | Mitsubishi Kasei Corporation | Process for producing porous film or sheet |
US4957787A (en) * | 1987-10-19 | 1990-09-18 | Ppg Industries, Inc. | Artificial flower |
US4877679A (en) * | 1988-12-19 | 1989-10-31 | Ppg Industries, Inc. | Multilayer article of microporous and porous materials |
JP2538755B2 (en) | 1993-10-04 | 1996-10-02 | ツウスエンスウチヤウコンイエクウフン ヨオシエンコンスウ | Synthetic wood having wood grain pattern and method for producing the same |
FR2743378B1 (en) * | 1996-01-04 | 1998-02-06 | Socrep Sa | COMPOSITE PROFILE ELEMENT AND PARTITION USING THIS ELEMENT |
JP3602272B2 (en) * | 1996-08-30 | 2004-12-15 | アイン・エンジニアリング株式会社 | Synthetic wood |
DE19854475B4 (en) * | 1997-11-25 | 2006-06-14 | Premark RWP Holdings, Inc., Wilmington | Locking area coverage product |
ZA985962B (en) | 1998-09-24 | 2000-04-05 | Mayer Gert | Component produced by the plastics extrusion process. |
-
2000
- 2000-12-19 AT AT00988529T patent/ATE266510T1/en not_active IP Right Cessation
- 2000-12-19 EP EP00988529A patent/EP1242220B1/en not_active Expired - Lifetime
- 2000-12-19 US US10/168,716 patent/US6939496B2/en not_active Expired - Lifetime
- 2000-12-19 ES ES00988529T patent/ES2221627T3/en not_active Expired - Lifetime
- 2000-12-19 DK DK00988529T patent/DK1242220T3/en active
- 2000-12-19 WO PCT/CA2000/001555 patent/WO2001045915A1/en active IP Right Grant
- 2000-12-19 DE DE60010752T patent/DE60010752T2/en not_active Expired - Lifetime
- 2000-12-19 CA CA002397676A patent/CA2397676C/en not_active Expired - Fee Related
-
2003
- 2003-03-25 HK HK03102179A patent/HK1050342A1/en not_active IP Right Cessation
-
2005
- 2005-02-25 US US11/065,787 patent/US20050171246A1/en not_active Abandoned
Patent Citations (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2365374A (en) * | 1941-04-23 | 1944-12-19 | Plax Corp | Method of shaping plastics by extrusion |
US3493527A (en) * | 1962-06-07 | 1970-02-03 | George Berthold Edward Schuele | Moldable composition formed of waste wood or the like |
US3888810A (en) * | 1972-07-11 | 1975-06-10 | Nippon Oil Co Ltd | Thermoplastic resin composition including wood and fibrous materials |
US4228116A (en) * | 1973-03-23 | 1980-10-14 | G.O.R. Applicazioni Speciali S.P.A. | Process for producing remoldable panels |
US4104207A (en) * | 1975-04-04 | 1978-08-01 | Hans Dieter Pelikan | Process for production of cellular cavities in thermoplastic material in which the medium which forms the gas bubbles is bound to a carrier |
US4426820A (en) * | 1979-04-24 | 1984-01-24 | Heinz Terbrack | Panel for a composite surface and a method of assembling same |
US4624976A (en) * | 1984-07-20 | 1986-11-25 | Nippon Petrochemicals Co., Ltd. | Modeling material composition |
US5130342A (en) * | 1988-10-14 | 1992-07-14 | Mcallister Jerome W | Particle-filled microporous materials |
US5088910A (en) * | 1990-03-14 | 1992-02-18 | Advanced Environmental Recycling Technologies, Inc. | System for making synthetic wood products from recycled materials |
US5169587A (en) * | 1990-06-15 | 1992-12-08 | Symplastics Limited | Process for extruding large oriented polymer shapes |
US5204045A (en) * | 1990-06-15 | 1993-04-20 | Symplastics Limited | Process for extruding polymer shapes with smooth, unbroken surface |
US5169589A (en) * | 1990-06-27 | 1992-12-08 | Symplastics Limited | Process and apparatus for deformation of solid thermoplastic polymers and related products |
US5070111A (en) * | 1991-03-13 | 1991-12-03 | Advanced Elastomer Systems, L.P. | Foaming thermoplastic elastomers |
US5406768A (en) * | 1992-09-01 | 1995-04-18 | Andersen Corporation | Advanced polymer and wood fiber composite structural component |
US5474722A (en) * | 1992-11-13 | 1995-12-12 | The Governing Council Of The University Of Toronto | Oriented thermoplastic and particulate matter composite material |
US5518677A (en) * | 1993-02-12 | 1996-05-21 | Andersen Corporation | Advanced polymer/wood composite pellet process |
US5516472A (en) * | 1993-11-12 | 1996-05-14 | Strandex Corporation | Extruded synthetic wood composition and method for making same |
US5847016A (en) * | 1996-05-16 | 1998-12-08 | Marley Mouldings Inc. | Polymer and wood flour composite extrusion |
US5951927A (en) * | 1996-05-16 | 1999-09-14 | Marley Mouldings Inc. | Method of making a polymer and wood flour composite extrusion |
US6006486A (en) * | 1996-06-11 | 1999-12-28 | Unilin Beheer Bv, Besloten Vennootschap | Floor panel with edge connectors |
US5797723A (en) * | 1996-11-13 | 1998-08-25 | General Electric Company | Turbine flowpath seal |
US6345481B1 (en) * | 1997-11-25 | 2002-02-12 | Premark Rwp Holdings, Inc. | Article with interlocking edges and covering product prepared therefrom |
US6054207A (en) * | 1998-01-21 | 2000-04-25 | Andersen Corporation | Foamed thermoplastic polymer and wood fiber profile and member |
Cited By (46)
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US20050192382A1 (en) * | 1999-12-20 | 2005-09-01 | Maine Francis W. | Method and apparatus for extruding composite material and composite material therefrom |
US8074339B1 (en) | 2004-11-22 | 2011-12-13 | The Crane Group Companies Limited | Methods of manufacturing a lattice having a distressed appearance |
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US9822547B2 (en) | 2005-11-30 | 2017-11-21 | Cpg International Llc | Rail system and method for assembly |
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USD797307S1 (en) | 2005-11-30 | 2017-09-12 | Cpg International Llc | Rail assembly |
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US10358841B2 (en) | 2005-11-30 | 2019-07-23 | Cpg International Llc | Rail system and method for assembly |
USD782697S1 (en) | 2005-11-30 | 2017-03-28 | Cpg International Llc | Rail |
US8167275B1 (en) | 2005-11-30 | 2012-05-01 | The Crane Group Companies Limited | Rail system and method for assembly |
USD782698S1 (en) | 2005-11-30 | 2017-03-28 | Cpg International Llc | Rail |
US8871130B2 (en) | 2006-11-10 | 2014-10-28 | Eovations, Llc | Solid state drawing a filled polymer composition to a stable extent of cavitation and density |
US20080111278A1 (en) * | 2006-11-10 | 2008-05-15 | Nichols Kevin L | Solid state drawing a filled polymer composition to a stable extent of cavitation and density |
US8460797B1 (en) | 2006-12-29 | 2013-06-11 | Timbertech Limited | Capped component and method for forming |
US20100072660A1 (en) * | 2007-03-27 | 2010-03-25 | Felix Achille | Low relative crystallinity die drawing process for a cavitated filled oriented polymer composition |
US8142697B2 (en) * | 2007-05-14 | 2012-03-27 | Nichols Kevin L | Low density oriented polymer composition with inert inorganic filler |
US20100301511A1 (en) * | 2007-05-14 | 2010-12-02 | Nichols Kevin L | Low density oriented polymer composition with inert inorganic filler |
US20080287576A1 (en) * | 2007-05-14 | 2008-11-20 | Nichols Kevin L | Low density oriented polymer composition with inert inorganic filler |
US20080286551A1 (en) * | 2007-05-16 | 2008-11-20 | Nova Chemicals Inc. | Plastic-cellulosic composite articles |
US20090001625A1 (en) * | 2007-06-29 | 2009-01-01 | Weyerhaeuser Co. | Oriented polymer composite template |
US20110223582A1 (en) * | 2008-11-13 | 2011-09-15 | Castillo Jose | Cell culture device and method of culturing cells |
US9833937B2 (en) * | 2009-01-15 | 2017-12-05 | Eovations, Llc | Solid state drawing laminated polymer billets |
US9393735B2 (en) * | 2009-01-15 | 2016-07-19 | Eovations, Llc | Solid state drawing laminated polymer billets |
US20160229106A1 (en) * | 2009-01-15 | 2016-08-11 | Eovations, Llc | Solid state drawing laminated polymer billets |
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Also Published As
Publication number | Publication date |
---|---|
CA2397676C (en) | 2004-07-06 |
CA2397676A1 (en) | 2001-06-28 |
DE60010752D1 (en) | 2004-06-17 |
ES2221627T3 (en) | 2005-01-01 |
EP1242220A1 (en) | 2002-09-25 |
EP1242220B1 (en) | 2004-05-12 |
US20030224147A1 (en) | 2003-12-04 |
WO2001045915A1 (en) | 2001-06-28 |
DE60010752T2 (en) | 2005-09-08 |
HK1050342A1 (en) | 2003-06-20 |
DK1242220T3 (en) | 2004-09-13 |
US6939496B2 (en) | 2005-09-06 |
ATE266510T1 (en) | 2004-05-15 |
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