US20050133156A1 - Apparatus and method for wafer planarization - Google Patents

Apparatus and method for wafer planarization Download PDF

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Publication number
US20050133156A1
US20050133156A1 US11/022,166 US2216604A US2005133156A1 US 20050133156 A1 US20050133156 A1 US 20050133156A1 US 2216604 A US2216604 A US 2216604A US 2005133156 A1 US2005133156 A1 US 2005133156A1
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wafer
etchant
nitrogen gas
transfer tube
linked
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US11/022,166
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Sang Kim
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DB HiTek Co Ltd
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DongbuAnam Semiconductor Inc
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Assigned to DONGBUANAM SEMICONDUCTOR INC. reassignment DONGBUANAM SEMICONDUCTOR INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: KIM, SANG KWON
Publication of US20050133156A1 publication Critical patent/US20050133156A1/en
Assigned to DONGBU ELECTRONICS CO., LTD. reassignment DONGBU ELECTRONICS CO., LTD. CHANGE OF NAME (SEE DOCUMENT FOR DETAILS). Assignors: DONGBUANAM SEMICONDUCTOR INC.
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02002Preparing wafers
    • H01L21/02005Preparing bulk and homogeneous wafers
    • H01L21/02008Multistep processes
    • H01L21/0201Specific process step
    • H01L21/02019Chemical etching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having at least one potential-jump barrier or surface barrier, e.g. PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic System or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/30Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26
    • H01L21/302Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to change their surface-physical characteristics or shape, e.g. etching, polishing, cutting
    • H01L21/306Chemical or electrical treatment, e.g. electrolytic etching
    • H01L21/30604Chemical etching
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/67Apparatus specially adapted for handling semiconductor or electric solid state devices during manufacture or treatment thereof; Apparatus specially adapted for handling wafers during manufacture or treatment of semiconductor or electric solid state devices or components ; Apparatus not specifically provided for elsewhere
    • H01L21/67005Apparatus not specifically provided for elsewhere
    • H01L21/67011Apparatus for manufacture or treatment
    • H01L21/67017Apparatus for fluid treatment
    • H01L21/67063Apparatus for fluid treatment for etching
    • H01L21/67075Apparatus for fluid treatment for etching for wet etching
    • H01L21/6708Apparatus for fluid treatment for etching for wet etching using mainly spraying means, e.g. nozzles

Definitions

  • the present invention relates to an apparatus and a method for wafer planarization and, more particularly, to an apparatus and a method used to planarize the entire surface of a wafer by spraying high-pressure etchant vapor into the wafer surface, which can substitute an existing CMP (Chemical Mechanical Polish) process.
  • CMP Chemical Mechanical Polish
  • FIG. 1 a through FIG. 1 c illustrate a conventional spin type wafer processing equipment.
  • a spin type of wafer processing equipment to substitute the existing CMP equipments comprises a wafer chuck 10 on which a wafer is loaded and a chemical supply line 14 to supply etching chemical solution to an upper part of the wafer chuck.
  • a wafer 12 is loaded on the wafer chuck, this wafer chuck rotates and the chemical solution is dropped and supplied to this rotating wafer through the chemical supply line.
  • the chemical supply line moves back and forth across the wafer.
  • 14 a and 14 b represent chemical supply lines placed between the wafer center and wafer edge.
  • the virtual line 18 shows moving path of the chemical supply line 14 .
  • a centrifugal force by wafer rotation affects the chemical supplied to wafer, so the chemical moves from first supplied points to wafer edges. Therefore, the result of a wafer processing such as etching, strip and cleaning is different by the regions on a wafer.
  • wafer processing chemical on the center of wafer has high relative velocities to the wafer and experiences a centrifugal force directed outward this wafer. Accordingly, the chemical moves fast to the first region (R 1 ) at a distance of radius r from the first supplied point. Outside this R 1 region, the relative velocity between the chemical and the wafer 12 is near 0 and the movement toward wafer edge becomes very slow even though the chemicals still get affected by the centrifugal force. That is, the chemical arriving at the second region (R 2 ) between the first region (R 1 ) and the edge moves together with the wafer without fast movement directed to the wafer edge.
  • the reaction time is longer on the first region (R 1 ) than on the second region (R 2 ).
  • processing time is short for the first region (R 1 ) and long for the second region (R 2 ). Therefore, the first region (R 1 ) is processed thickly and the second region (R 2 ) thinly.
  • This spin type wafer processing equipment has advantage that wafer surface can be planarized without using existing CMP equipment. By avoiding mechanical polishing by the friction with the polishing pad of the CMP equipment, the defects like scratch can be prevented. Furthermore, slurry needs not be used, so production cost and the expense for processing byproducts can be saved.
  • etching chemical have a enough reaction time only for limited wafer region, so it is difficult to evenly planarize the entire surface of the wafer.
  • the present invention is directed to an apparatus and a method for wafer planarization that substantially obviates one or more problems due to limitations and disadvantages of the related art.
  • An object of the present invention is to provide an apparatus and a method used to planarize the entire surface of a wafer by spraying high pressure etchant vapor into the wafer surface which can substitute an existing CMP (Chemical Mechanical Polish) process to substantially obviate one or more problems due to limitations and disadvantages of the related art.
  • CMP Chemical Mechanical Polish
  • an apparatus for wafer planarization comprises: a liquid nitrogen supply tank; a nitrogen gas transfer tube linked with the liquid nitrogen supply tank by a valve; an etchant supply tube linked with the nitrogen gas transfer tube; an etchant supply tank for containing etchant linked with the etchant supply tube; and a chamber with a spray nozzle part linked with the nitrogen gas transfer tube attached to the upper part thereof and a wafer rotating equipment placed in the lower part thereof.
  • a method for wafer planarization comprises: emitting nitrogen gas into a transfer tube; mixing the emitted nitrogen gas with etchant; planarizing a wafer by spraying the mixed etchant on the entire surface of wafer through a spraying nozzle part of chamber; and cleaning the wafer.
  • FIG. 1 a through FIG. 1 c illustrate a conventional spin type wafer processing equipment.
  • FIG. 2 a and FIG. 2 b illustrate a wafer planarization equipment using high pressure etchant vapor in accordance with the teachings of the present invention.
  • FIG. 2 a and FIG. 2 b illustrate a wafer planarization equipment using high pressure etchant vapor.
  • FIG. 2 a is a sketch illustrating a wafer planarization apparatus of the present invention.
  • This wafer planarization apparatus comprises a supply part to provide high pressure etchant and a chamber part 50 for wafer planarization.
  • the supply part comprises a liquid nitrogen (LN 2 ) supply tank 20 , an etchant supply tank 30 and a spraying nozzle part 40 and the chamber part comprises a wafer rotating equipment 45 and a cleaning unit not shown.
  • LN 2 liquid nitrogen
  • liquid nitrogen at ultra low temperature is stored in the storing tank 20 at high pressure.
  • a tank valve opens, the pressure decreases so fast that the triple point at which all three phases of solid, liquid and gas can coexist is formed and high pressure is generated.
  • This high pressure makes nitrogen gas vaporized from the liquid nitrogen emit into a nitrogen gas transfer tube 21 .
  • This transfer tube 21 is linked to an etchant supply tube 33 , which is in turn linked to the etchant supply tank 30 containing etchant.
  • the nitrogen gas transfer tube 21 and the etchant supply tube 33 At the confluence of the nitrogen gas transfer tube 21 and the etchant supply tube 33 , low pressure is generated due to the nitrogen gas moving through the transfer tube at high speed.
  • the fine particles of the etchant are carried by this nitrogen gas, pass through the transfer tube 21 linked to the chamber part 50 , and then arrive at the spray nozzle part 40 attached to the upper part of the interior of chamber part 50 .
  • the etchant is sprayed onto the rotating wafer at a high speed as fume of fire particles at a high pressure, due to the fine holes of the nozzles and the high pressure of the nitrogen gas.
  • silicon oxide SiO 2
  • HF hydrofluoric acid
  • the wafer is rotated at high speed.
  • the wafer is rotated at high speed and spraying uniformly the etchant of fire particles in vapor, the wafer is etched anisotropically in the same direction as that of the wafer rotation and planarized.
  • FIG. 2 b represents the wafer rotating equipment 45 .
  • a wafer 51 is put between the top of a clamp 52 and a wafer stage 53 for a fixation by a lift 54 for a loading and an unloading.
  • the clamp 52 is positioned at the upper edge of the stage 53 to fix the wafer.
  • the stage 53 is positioned at the upper part of the lift on which the wafer is positioned.
  • the lift 54 is positioned at the upper part of the rotation actuation.
  • the wafer 51 then rotates by a high speed rotation actuator 55 with a motor. After the wafer 51 is planarized by the etchant in vapor, it is cleaned with de-ionized water sprayed from a cleaning nozzle (not shown).

Abstract

An apparatus and a method for wafer planarization is disclosed. A disclosed apparatus comprises a liquid nitrogen supply tube; a nitrogen gas transfer tube linked to the nitrogen gas supply tank by valve; an etchant supply tube linked with the nitrogen gas transfer tube; a spray nozzle part linked with the nitrogen gas supply tube; and a chamber with a spray nozzle attached to the upper part of the chamber and a wafer rotating equipment placed in the lower part. A disclosed apparatus and a method has advantage to planarize an entire surface of wafer by spraying high pressure of etchant vapor into a wafer surface rotating at high speed.

Description

    BACKGROUND OF THE INVENTION
  • 1. Field of the Invention
  • The present invention relates to an apparatus and a method for wafer planarization and, more particularly, to an apparatus and a method used to planarize the entire surface of a wafer by spraying high-pressure etchant vapor into the wafer surface, which can substitute an existing CMP (Chemical Mechanical Polish) process.
  • 2. Background of the Related Art
  • FIG. 1 a through FIG. 1 c illustrate a conventional spin type wafer processing equipment.
  • Referring to FIG. 1 a, a spin type of wafer processing equipment to substitute the existing CMP equipments comprises a wafer chuck 10 on which a wafer is loaded and a chemical supply line 14 to supply etching chemical solution to an upper part of the wafer chuck. Once a wafer 12 is loaded on the wafer chuck, this wafer chuck rotates and the chemical solution is dropped and supplied to this rotating wafer through the chemical supply line. The chemical supply line moves back and forth across the wafer. 14 a and 14 b represent chemical supply lines placed between the wafer center and wafer edge.
  • Referring to FIG. 1 b, the virtual line 18 shows moving path of the chemical supply line 14. A centrifugal force by wafer rotation affects the chemical supplied to wafer, so the chemical moves from first supplied points to wafer edges. Therefore, the result of a wafer processing such as etching, strip and cleaning is different by the regions on a wafer.
  • Referring to FIG. 1 c, during the wafer rotation, wafer processing chemical on the center of wafer has high relative velocities to the wafer and experiences a centrifugal force directed outward this wafer. Accordingly, the chemical moves fast to the first region (R1) at a distance of radius r from the first supplied point. Outside this R1 region, the relative velocity between the chemical and the wafer 12 is near 0 and the movement toward wafer edge becomes very slow even though the chemicals still get affected by the centrifugal force. That is, the chemical arriving at the second region (R2) between the first region (R1) and the edge moves together with the wafer without fast movement directed to the wafer edge. This difference in moving speed of chemicals by the regions on a wafer, results in different reaction time by the regions. The reaction time is longer on the first region (R1) than on the second region (R2). Owing to the reaction time difference, on a wafer, processing time is short for the first region (R1) and long for the second region (R2). Therefore, the first region (R1) is processed thickly and the second region (R2) thinly.
  • This spin type wafer processing equipment has advantage that wafer surface can be planarized without using existing CMP equipment. By avoiding mechanical polishing by the friction with the polishing pad of the CMP equipment, the defects like scratch can be prevented. Furthermore, slurry needs not be used, so production cost and the expense for processing byproducts can be saved.
  • However, for the above-described spin type wafer processing equipment, etching chemical have a enough reaction time only for limited wafer region, so it is difficult to evenly planarize the entire surface of the wafer. To solve this problem, it is necessary to repeat the wafer processing with changing processing conditions. For example, during an at the above oxide etching process, after the first process is performed the second etching process should be performed under the condition that the first region (R1) with thicker oxide is given a longer reaction time and the second region (R2) with thinner oxide is given a shorter reaction time. This two-step process becomes a main reason for increasing the wafer processing time and lowering semiconductor equipment productivity.
  • SUMMARY OF THE INVENTION
  • Accordingly, the present invention is directed to an apparatus and a method for wafer planarization that substantially obviates one or more problems due to limitations and disadvantages of the related art.
  • An object of the present invention is to provide an apparatus and a method used to planarize the entire surface of a wafer by spraying high pressure etchant vapor into the wafer surface which can substitute an existing CMP (Chemical Mechanical Polish) process to substantially obviate one or more problems due to limitations and disadvantages of the related art.
  • To achieve this object, in accordance with the purpose of the invention, as embodied and broadly described herein, an apparatus for wafer planarization comprises: a liquid nitrogen supply tank; a nitrogen gas transfer tube linked with the liquid nitrogen supply tank by a valve; an etchant supply tube linked with the nitrogen gas transfer tube; an etchant supply tank for containing etchant linked with the etchant supply tube; and a chamber with a spray nozzle part linked with the nitrogen gas transfer tube attached to the upper part thereof and a wafer rotating equipment placed in the lower part thereof.
  • Additionally, to achieve the object of the present invention, a method for wafer planarization comprises: emitting nitrogen gas into a transfer tube; mixing the emitted nitrogen gas with etchant; planarizing a wafer by spraying the mixed etchant on the entire surface of wafer through a spraying nozzle part of chamber; and cleaning the wafer.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • The accompanying drawings, which are included to provide a further understanding of the invention and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the invention and together with the description serve to explain the principle of the invention. In the drawings;
  • FIG. 1 a through FIG. 1 c illustrate a conventional spin type wafer processing equipment.
  • FIG. 2 a and FIG. 2 b illustrate a wafer planarization equipment using high pressure etchant vapor in accordance with the teachings of the present invention.
  • DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
  • Reference will now be made in detail to the preferred embodiments of the present invention, examples of which are illustrated in the accompanying drawings.
  • FIG. 2 a and FIG. 2 b illustrate a wafer planarization equipment using high pressure etchant vapor.
  • FIG. 2 a is a sketch illustrating a wafer planarization apparatus of the present invention. This wafer planarization apparatus comprises a supply part to provide high pressure etchant and a chamber part 50 for wafer planarization. The supply part comprises a liquid nitrogen (LN2) supply tank 20, an etchant supply tank 30 and a spraying nozzle part 40 and the chamber part comprises a wafer rotating equipment 45 and a cleaning unit not shown.
  • Referring to FIG. 2 a, liquid nitrogen at ultra low temperature is stored in the storing tank 20 at high pressure. When a tank valve opens, the pressure decreases so fast that the triple point at which all three phases of solid, liquid and gas can coexist is formed and high pressure is generated. This high pressure makes nitrogen gas vaporized from the liquid nitrogen emit into a nitrogen gas transfer tube 21. This transfer tube 21 is linked to an etchant supply tube 33, which is in turn linked to the etchant supply tank 30 containing etchant. At the confluence of the nitrogen gas transfer tube 21 and the etchant supply tube 33, low pressure is generated due to the nitrogen gas moving through the transfer tube at high speed. Thus, there is significant pressure difference between the confluence at low atmospheric pressure and the etchant supply tube 33 at atmospheric pressure. This significant pressure difference makes the etchant 31 in the etchant supply tank 30 rise through the etchant supply tube 33 and mix with the nitrogen gas. The etchant 31 is stored, dilated with de-ionized water and a sensor 32 attached to the etchant supply tank 30 can detect the remaining volume of the etchant in the store tank. In addition, the exit of the etchant supply tube 33 at the confluence is made of a nozzle so that the etchant rising through this supply tube 33 transforms into fine particles and these particles are mixed with the nitrogen gas. This nitrogen gas plays a role as carrier. The fine particles of the etchant are carried by this nitrogen gas, pass through the transfer tube 21 linked to the chamber part 50, and then arrive at the spray nozzle part 40 attached to the upper part of the interior of chamber part 50. There may be plural nozzles in the spray nozzle part 40 so that the etchant can be sprayed uniformly on the entire surface of a wafer through these nozzles. The etchant is sprayed onto the rotating wafer at a high speed as fume of fire particles at a high pressure, due to the fine holes of the nozzles and the high pressure of the nitrogen gas.
  • Further processes for etching are as follows. For example, silicon oxide (SiO2) is positioned on a wafer surface and an etchant is hydrofluoric acid (HF). The silicon oxide reacts with the hydrofluoric acid (HF) as vapor as below.
    SiO2+HF→SiO4↑+H2O↑
  • The above reaction causes only an isotropic etching which is inappropriate to planarization. Therefore, to induce an anisotropic etching, the wafer is rotated at high speed. By rotating the wafer at high speed and spraying uniformly the etchant of fire particles in vapor, the wafer is etched anisotropically in the same direction as that of the wafer rotation and planarized.
  • FIG. 2 b represents the wafer rotating equipment 45. A wafer 51 is put between the top of a clamp 52 and a wafer stage 53 for a fixation by a lift 54 for a loading and an unloading. The clamp 52 is positioned at the upper edge of the stage 53 to fix the wafer. The stage 53 is positioned at the upper part of the lift on which the wafer is positioned. The lift 54 is positioned at the upper part of the rotation actuation. The wafer 51 then rotates by a high speed rotation actuator 55 with a motor. After the wafer 51 is planarized by the etchant in vapor, it is cleaned with de-ionized water sprayed from a cleaning nozzle (not shown).
  • The foregoing embodiments are merely exemplary and are not to be construed as limiting the present invention. The present teachings can be readily applied to other types of apparatuses. The description of the present invention is intended to be illustrative, and not to limit the scope of the claims. Many alternatives, modifications, and variations will be apparent to those skilled in the art.

Claims (9)

1. An apparatus for wafer planarization comprising:
a liquid nitrogen supply tank;
a nitrogen gas transfer tube linked with the liquid nitrogen supply tank by a valve;
an etchant supply tube linked with the nitrogen gas transfer tube;
an etchant supply tank for containing etchant linked with the etchant supply tube; and
a chamber with a spray nozzle part linked with the nitrogen gas transfer tube attached to the upper part thereof and a wafer rotating equipment placed in the lower part thereof.
2. The apparatus as defined by claim 1, wherein a sensor to detect the remaining volume of the etchant is attached to the etchant supply tank.
3. The apparatus as defined by claim 1, wherein the exit of the etchant supply tube comprises a nozzle.
4. The apparatus as defined by claim 1, wherein the spray nozzle part comprises plural nozzles.
5. The apparatus as defined by claim 1, wherein the wafer rotating equipment comprises:
a rotation actuator with a motor;
a lift for loading and unloading a wafer at the upper part of the rotation actuator;
a wafer stage at the upper part of the lift on which the wafer is positioned;
a clamp at the upper edge of the stage to fix the wafer; and
a cleaning nozzle to supply de-ionized water to the wafer.
6. A method for wafer planarization comprising:
emitting nitrogen gas to a nitrogen gas transfer tube;
mixing the emitted nitrogen gas and etchant;
planarizing a wafer by spraying the mixed etchant from a spray nozzle part linked with the nitrogen gas transfer tube onto the entire surface of the wafer; and
cleaning the wafer.
7. The method as defined by claim 6, wherein the nitrogen gas is emitted at high pressure from a liquid nitrogen supply tank into the nitrogen gas transfer tube.
8. The method as defined by claim 6, wherein mixing the emitted nitrogen gas and the etchant comprises:
rising of the etchant, which is stored and, diluted with de-ionized water in an etchant supply tank, by pressure difference between the nitrogen gas transfer tube at low pressure and an etchant supply tube at high pressure linked with the nitrogen gas transfer tube and the etchant supply tank; and
mixing fine particles of the etchant sprayed through a nozzle at the end of the etchant supply tube with the emitted nitrogen gas.
9. The method as defined by claim 6, wherein planarizing the wafer comprises:
transforming the etchant sprayed from the spray nozzle part into vapor by means of the nitrogen at high pressure;
spraying uniformly the etchant in vapor onto the entire surface of the wafer rotating at high speed; and
etching anisotropically the wafer in the same direction as that of the wafer rotation.
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US20100151597A1 (en) * 2006-01-20 2010-06-17 Sumco Corporation Method for smoothing wafer surface and apparatus used therefor
US7955982B2 (en) 2006-01-20 2011-06-07 Sumco Corporation Method for smoothing wafer surface and apparatus used therefor
US10593603B2 (en) 2018-03-16 2020-03-17 Sandisk Technologies Llc Chemical mechanical polishing apparatus containing hydraulic multi-chamber bladder and method of using thereof
US20220364241A1 (en) * 2021-05-14 2022-11-17 Darwin Precisions Corporation Mask manufacturing method and mask manufacturing device

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JP4011579B2 (en) 2007-11-21
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DE102004063066A1 (en) 2005-11-03
DE102004063066B4 (en) 2008-01-17

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