US20050055982A1 - Phase-change structural insulated panels and walls - Google Patents

Phase-change structural insulated panels and walls Download PDF

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Publication number
US20050055982A1
US20050055982A1 US10/639,910 US63991003A US2005055982A1 US 20050055982 A1 US20050055982 A1 US 20050055982A1 US 63991003 A US63991003 A US 63991003A US 2005055982 A1 US2005055982 A1 US 2005055982A1
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Prior art keywords
wall
phase change
macroencapsulated
sheathing
housing
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US10/639,910
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Mario Medina
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University of Kansas
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University of Kansas
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Publication of US20050055982A1 publication Critical patent/US20050055982A1/en
Abandoned legal-status Critical Current

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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04BGENERAL BUILDING CONSTRUCTIONS; WALLS, e.g. PARTITIONS; ROOFS; FLOORS; CEILINGS; INSULATION OR OTHER PROTECTION OF BUILDINGS
    • E04B1/00Constructions in general; Structures which are not restricted either to walls, e.g. partitions, or floors or ceilings or roofs
    • E04B1/62Insulation or other protection; Elements or use of specified material therefor
    • E04B1/74Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls
    • E04B1/76Heat, sound or noise insulation, absorption, or reflection; Other building methods affording favourable thermal or acoustical conditions, e.g. accumulating of heat within walls specifically with respect to heat only
    • E04B1/78Heat insulating elements
    • E04B1/80Heat insulating elements slab-shaped
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • E04C2/292Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and sheet metal
    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04CSTRUCTURAL ELEMENTS; BUILDING MATERIALS
    • E04C2/00Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
    • E04C2/02Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
    • E04C2/26Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
    • E04C2/284Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
    • E04C2/296Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and non-metallic or unspecified sheet-material
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • F28D20/023Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat the latent heat storage material being enclosed in granular particles or dispersed in a porous, fibrous or cellular structure
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28FDETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION
    • F28F2270/00Thermal insulation; Thermal decoupling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

Definitions

  • the present invention relates to structural walls and ceilings, and more specifically to a structural insulated panel and wall having macroencapsulated phase-change materials incorporated therein.
  • the walls, roofs, ceilings and floors are typically designed to thermally insulate the space enclosed thereby.
  • a variety of different construction techniques have been devised.
  • a wood frame for the structure is constructed with load-bearing walls comprising studs, top and bottom plates, and headers over the openings.
  • Floor and ceiling joists span between the walls.
  • sheathing is typically applied to the exteriors of the walls.
  • the walls are then insulated with, for example, fiberglass insulation for controlling thermal conduction therethrough. Insulation is also typically placed between the ceiling joists or roof rafters and between the floor joists over unheated areas.
  • the wall interiors generally comprise a layer of drywall, gypsum board, paneling or the like.
  • SIPs structural insulated panels
  • Foam-core panels stress-skin panels
  • sandwich panels structural foam panels
  • the typical SIP includes an inner insulating core and two outer sheathings comprised of a rigid material such as gypsum or cementous composite, waferboard, metal, plywood, drywall, oriented strand board (“OSB”), or an agricultural board product such as strawboard.
  • OSB oriented strand board
  • SIPs have several advantages over conventional frame construction.
  • the use of panels permits the closing of a building in a week's time (or less) depending on the size of the building. This promotes faster, easier, and lower cost methods of erecting structures. For example, a 2,000-ft 2 (186 m 2 ) house can usually be erected in less than 3 days. This avoids delay costs and waste and/or losses that result from weather and pilfering of materials lying around.
  • SIPs also provide design flexibility because panels can be manufactured in sizes, typically ranging from about 4 to 24 feet (about 1.2 to 7.3 m). This in turn can save time on engineering and design costs. The use of SIPs also makes the walls stronger, and the buildings more airtight, thereby making them more comfortable, energy efficient, and quieter.
  • phase-change materials have been imbibed into plywood boards and gypsum boards themselves. See Rudd, Phase Change Material Wallboard for Distributed Thermal Storage in Buildings (1993); Sayler et al., A Review of Phase Change Materials Research for Thermal Energy Storage in Heating and Cooling Applications at the University of Dayton from 1982 to 1996 (1997).
  • PCMs phase-change materials
  • the imbibed method results in increased flammability of the boards.
  • the PCMs are often wax-like materials, which decrease the permeability of the board to water vapor, thereby increasing humidity problems indoor.
  • the application of paints and other coatings or finishes to the imbibed PCM boards is often problematic.
  • the present invention is directed to a phase-change structural insulated panel or wall in which the PCM is macroencapsulated between the two sheathings.
  • the present invention provides a lightweight, high strength, insulated panel which is easily fabricated, modified and installed.
  • the panel also has decreased flammability and coatability as compared to imbibed phase change boards. In fact, the panels of the present invention do not compromise the mandated 15-minute fire rating for SIPs.
  • Yet another object of the present invention is to provide a PCM structural panel that can accept common coatings and finishes, such as paints.
  • Still a further object of the present invention is to provide a PCM panel that does not significantly affect the water vapor transfer across the panel.
  • FIG. 1 illustrates an exploded view of a phase-change structural insulated panel in accordance with the present invention.
  • FIG. 2 is a cross-section of the panel illustrated in FIG. 1 .
  • FIG. 3 is a cut-away perspective view illustrating how the macroencapsulated PCMs are incorporated into a SIP by heating a housing containing the PCMs or by removing a volume of the core of about equal volume to the pipe.
  • FIG. 4 illustrates a wall having macroencapsulated phase-change materials in accordance with the present invention with the exterior sheathing removed.
  • FIG. 5 shows how the phase-change structural insulated panels of the present invention incorporated the capsules into a test house.
  • FIG. 6 summarizes the wall heat fluxes depicting the potential demand reduction of PCM-enhanced wall panels.
  • the data plotted are from a west-facing panel with 4 inch (10.2 cm) of insulation and 10% PCM by OSB weight.
  • Structural panel 10 includes first and second sheathings 20 and 22 disposed on and affixed to opposed outer surfaces of a generally planar, insulating core 30 .
  • One or more PCMs 40 are macroencapsulated between the sheathings 20 , 22 .
  • sheathings 20 , 22 are known to those skilled in the art.
  • the sheathing is preferably comprised of a rigid material such as gypsum or cementous composite, waferboard, metal, plywood, drywall, OSB, or an agricultural board product such as strawboard or wheatboard.
  • the sheathing comprises OSB.
  • the sheathings 20 , 22 of the present invention are of any suitable thickness.
  • the sheathing preferably has a thickness between about 0.125 to 3 inches (7.18 mm to 7.62 cm), more preferably between about 0.25 to 2 inches (6.35 mm to 5.08 cm), and most preferably about 0.5 to 0.75 inches (1.27 to 1.91 cm).
  • Common commercially available sheathing material has a thickness of about ⁇ fraction (7/16) ⁇ , 1 ⁇ 2, 3 ⁇ 4, and 1 inch (1.11, 1.27, 1.90, and 2.54 cm).
  • the insulation 30 of the present invention can be any suitable material known to those skilled in the art.
  • the insulation 30 is preferably an expanded polystyrene (“EPS”).
  • EPS expanded polystyrene
  • suitable materials include, but are not limited to, molded expanded polystyrene (“MEPS”), extruded polystyrene (“XEPS”), expanded polystyrene (“EPS”), urethane, polyurethane and isocyanurate, fiberglass, cementitious or fibrous core insulating materials, and compressed straw insulation.
  • the insulation can be of any suitable thickness.
  • the insulation preferably has a thickness between about 1-12 inches (2.54-38.1 cm), more preferably between about 2-8 inches (5.08-20.32 cm), and most preferably between about 3-7 inches (7.62-17.78 cm).
  • Commercially available insulation usually has a thickness ranging between about 35 ⁇ 8 to 113 ⁇ 8 inch (9.21-28.89 cm).
  • the first and second sheathings 20 , 22 are preferably attached to the respective opposed facings of the panel's insulating core 30 by any of the more conventional adhesive materials such as urethane or epoxy cement, glue or a mastic coating (not shown).
  • the panel 10 may be constructed with sheathing only on one face of the panel with the insulating core 30 exposed. Such panels are well suited for unfinished warehouses and unfinished basements.
  • the other sheathing is preferably added as or after the panel 10 is installed in the building.
  • Suitable PCMs 40 within the scope of the present invention include but are not limited to solid-to-liquid PCMs.
  • the PCM materials preferably change from solid to liquid and back to solid as a function of the wall temperature.
  • the PCMs preferably have their solid-to-liquid transition between about 72° F. and 86° F. (about 22° C. to 30° C.).
  • Suitable inorganic PCMs 40 include water, sodium sulphate, decahydrate, calcium chloride hexahydrate, sodium acetate trihydrate, quaternary ammonium/water clathrates or mixtures thereof.
  • Organic solid-to-liquid PCMs include linear crystalline alkyl hydrocarbons, polyethylene glycols, pentaethritol, pentaglycerine, neo pentylglycol, acetamide, tetrahydrofuran, butyl stearate, butyl palmitate, lauric acid, capric acid, and other fatty acids and esters, primary long chain alcohols, or mixtures thereof.
  • Silica gels can also be used to help reduce problems with leakage and volume change.
  • the PCMs 40 are selected from the group consisting of paraffin hydrocarbons, salt hydrates, fatty acids and eutectic mixtures, fatty alcohols, and neopentyl glycol.
  • Preferred PCMs are commercially available from Rubitherm GmbH (Hamberger, Germany) and sold in the United States by Energy Storage Technologies (Dayton, Ohio).
  • a most preferred PCM is RUBITHERM® R-26.
  • the PCMs 40 of the present invention are macroencapsulated between the sheathings 20 , 22 in a housing 45 .
  • the PCM is macroencapsulated in a housing 45 comprising a tube.
  • the tube may be of any suitable size but preferably has a diameter of between about 0.5 inch and 3 inch, and most preferably about 1 inch.
  • the tube 45 is preferably capped at one or both ends 42 to prevent leakage.
  • the housing is comprised of any suitable material, such as PVC, copper, aluminum, and the like.
  • the housing 45 containing the PCM is oriented in any suitable manner, e.g. horizontally, vertically, diagonally, or any variation thereof. As illustrated in FIGS. 1-3 , the housing is most preferably oriented horizontally within the panel 10 . Further, the housing 45 may be oriented between the sheathings 20 , 22 in any suitable manner, e.g. centered, proximal to the outer sheathing, directly adjacent the outer sheathing, proximal to the inner sheathing, directly adjacent to the inner sheathing. Most preferably, as illustrated in FIGS. 1-3 , the housing 45 is in close proximity to the internal sheathing 22 . The housing containing the PCM may span all or part of the length, L, of the panel 10 .
  • the housing 45 containing the PCM 40 is preferably positioned between the sheathings 20 , 22 by heating the housing 45 or by cutting a volume of insulation 30 similar to the volume of the housing so that the insulation 30 is removed (by melting or cutting) upon contact with the heated housing 45 .
  • the insulation 30 itself can support the housing 45 without the aid of additional materials.
  • brackets, screws, and conventional adhesive materials such as urethane or epoxy cement, glue or a mastic coating can be used to position the macroencapsulated PCM 40 .
  • a suitable amount of PCM is encapsulated in the structural panel.
  • the PCM preferably comprises about 5 to 30%, and most preferably about 10 to 20% of the weight of the sheathing of the panel 10 . It will be appreciated that this percentage is useful to compare the amount of macroencapsulated PCM in the panels and walls of present invention to conventional boards in which the PCM is imbibed in the board and therefore % PCM was expressed as a percentage of the overall board weight.
  • the panels 10 of the present invention are used in buildings in a manner well known to those skilled in the art for SIPs. See generally Morley, Michael, 2000, Structural Insulated Panels ( SIPs ), The Taunton Press, Newborn, Conn., which is incorporated by reference.
  • a 12-foot (3.66 m) wall can have two 6-foot (1.83 m) panels of the present invention located between 2 ⁇ 4 (5.08 ⁇ 10.2 cm), 2 ⁇ 6-inch (5.08 ⁇ 15.2 cm) or other studs about 12 feet apart.
  • Structural panel 10 is shown as generally rectangular in shape, but may assume virtually any of the more common shapes assumed by structural panels in building construction.
  • the phase-change structural panels 10 of the present invention are preferably custom manufactured to meet building specifications. Common sizes on structural panels that are commercially available range from about 4 ft ⁇ 8 ft (1.22 m to 2.44 m) to about 8 ft ⁇ 24 ft (2.44 m to 7.32 m).
  • the macroencapsulated PCMs 40 of the present invention are incorporated into conventional walls 100 , as opposed to the structural insulated wall panels 10 of the first embodiment.
  • a plurality of substantially vertical splines 50 are preferably spaced about every 10 to 20 inches (25.4 to 50.8 cm), even more preferably about every 14 inches (35.6 cm).
  • the splines 50 are typically 2 ⁇ 4 inch (5.08 ⁇ 10.2 cm) wood studs, but can be any suitable size and material, such as metal I-or H-beams.
  • Insulation 30 resides between the spines. Sheathings 20 , 22 are attached to the spines in a conventional manner.
  • the macroencapsulated PCMs 40 of the present invention are positioned between one or more of the splines 50 using any suitable means.
  • the PCMs are preferably housed in a housing comprised of a copper pipe that is suspended from the splines 50 using a bracket 49 .
  • the housing 45 containing the PCMs 40 could be positioned in holes drilled through the splines 50 ; however, this approach is not preferable because it may decrease the structural stability of the splines.
  • the PCMs are preferably positioned near the inner sheathing 22 and are horizontal; however, any suitable orientation and position may be utilized.
  • FIG. 5 illustrates an unfolded-box type test house using the macroencapsulated PCMs of the present invention in the walls 100 .
  • Preliminary findings from research conducted at the University of Kansas show that the integration of PCMs in insulated frame walls offer the potential to reduce wall peak heat flux by as much as about 40 percent based on wall orientation, quantity of PCM used, and wall insulation level.
  • a test house with dimensions illustrated in FIG. 5 was constructed.
  • the splines were comprised of 2 ⁇ 4-inch (5.08 ⁇ 10.2 cm) pine.
  • PCMs comprising linear crystalline alkyl hydrocarbons, or paraffin wax, commercially available under the trade name of RT-26, which is manufactured by Rubitherm GmbH (Hamberger, Germany) and sold in the United States by Energy Storage Technologies (Dayton, Ohio), were placed into copper pipes capped at both ends with closed-ends copper caps.
  • the macroencapsulated PCM pipes were then placed horizontally and secured to the studs with steel brackets and into the fiberglass insulation having a thickness of 4 in. (10.2 cm). Both sides of the wall were covered with OSB, manufactured by Georgia Pacific Corporation, and having a thickness of 0.5 in. (1.27 cm).

Abstract

A wall, ceiling, or structural insulated panel having macroencapsulated phase-change materials incorporated therein.

Description

    CROSS-REFERENCE TO RELATED APPLICATIONS
  • None.
  • STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT
  • None.
  • FIELD OF THE INVENTION
  • The present invention relates to structural walls and ceilings, and more specifically to a structural insulated panel and wall having macroencapsulated phase-change materials incorporated therein.
  • DESCRIPTION OF RELATED ART
  • In the construction of various types of buildings, the walls, roofs, ceilings and floors are typically designed to thermally insulate the space enclosed thereby. In this regard, a variety of different construction techniques have been devised.
  • Conventional frame construction is widely employed in residential and other types of construction. Typically, a wood frame for the structure is constructed with load-bearing walls comprising studs, top and bottom plates, and headers over the openings. Floor and ceiling joists span between the walls. During or after the framing stage, sheathing is typically applied to the exteriors of the walls. The walls are then insulated with, for example, fiberglass insulation for controlling thermal conduction therethrough. Insulation is also typically placed between the ceiling joists or roof rafters and between the floor joists over unheated areas. The wall interiors generally comprise a layer of drywall, gypsum board, paneling or the like.
  • In recent years, structural insulated panels (“SIPs”), “foam-core panels,” stress-skin panels, sandwich panels, or structural foam panels have gained increasing acceptance in building construction in replacing the conventional combination of drywall sheets and rolls of fiberglass insulation. The typical SIP includes an inner insulating core and two outer sheathings comprised of a rigid material such as gypsum or cementous composite, waferboard, metal, plywood, drywall, oriented strand board (“OSB”), or an agricultural board product such as strawboard. See generally Babcock et al., U.S. Pat. No. 6,256,960; Porter, U.S. Pat. No. 5,842,314; Parker, U.S. Pat. No. 4,628,650. SIPs have several advantages over conventional frame construction. First, the use of panels permits the closing of a building in a week's time (or less) depending on the size of the building. This promotes faster, easier, and lower cost methods of erecting structures. For example, a 2,000-ft2 (186 m2) house can usually be erected in less than 3 days. This avoids delay costs and waste and/or losses that result from weather and pilfering of materials lying around. SIPs also provide design flexibility because panels can be manufactured in sizes, typically ranging from about 4 to 24 feet (about 1.2 to 7.3 m). This in turn can save time on engineering and design costs. The use of SIPs also makes the walls stronger, and the buildings more airtight, thereby making them more comfortable, energy efficient, and quieter.
  • Even more recently, to improve energy efficiency, phase-change materials (“PCMs”) have been imbibed into plywood boards and gypsum boards themselves. See Rudd, Phase Change Material Wallboard for Distributed Thermal Storage in Buildings (1993); Sayler et al., A Review of Phase Change Materials Research for Thermal Energy Storage in Heating and Cooling Applications at the University of Dayton from 1982 to 1996 (1997). However, the imbibed method results in increased flammability of the boards. In addition, the PCMs are often wax-like materials, which decrease the permeability of the board to water vapor, thereby increasing humidity problems indoor. Lastly, the application of paints and other coatings or finishes to the imbibed PCM boards is often problematic.
  • The present invention is directed to a phase-change structural insulated panel or wall in which the PCM is macroencapsulated between the two sheathings. The present invention provides a lightweight, high strength, insulated panel which is easily fabricated, modified and installed. The panel also has decreased flammability and coatability as compared to imbibed phase change boards. In fact, the panels of the present invention do not compromise the mandated 15-minute fire rating for SIPs.
  • BRIEF SUMMARY OF THE INVENTION
  • It is an object of the present invention to provide a lightweight, high strength, PCM structural insulated panel.
  • It is a further object of the present invention to provide a PCM structural panel that has decreased flammability.
  • Yet another object of the present invention is to provide a PCM structural panel that can accept common coatings and finishes, such as paints.
  • Still a further object of the present invention is to provide a PCM panel that does not significantly affect the water vapor transfer across the panel.
  • It is still another object of the present invention to provide a wall having macroencapsulated PCMs therein.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 illustrates an exploded view of a phase-change structural insulated panel in accordance with the present invention.
  • FIG. 2 is a cross-section of the panel illustrated in FIG. 1.
  • FIG. 3 is a cut-away perspective view illustrating how the macroencapsulated PCMs are incorporated into a SIP by heating a housing containing the PCMs or by removing a volume of the core of about equal volume to the pipe.
  • FIG. 4 illustrates a wall having macroencapsulated phase-change materials in accordance with the present invention with the exterior sheathing removed.
  • FIG. 5 shows how the phase-change structural insulated panels of the present invention incorporated the capsules into a test house.
  • FIG. 6 summarizes the wall heat fluxes depicting the potential demand reduction of PCM-enhanced wall panels. The data plotted are from a west-facing panel with 4 inch (10.2 cm) of insulation and 10% PCM by OSB weight.
  • DETAILED DESCRIPTION OF PREFERRED EMBODIMENT
  • Referring to FIGS. 1-2, a structural panel in accordance with the present invention is shown. Structural panel 10 includes first and second sheathings 20 and 22 disposed on and affixed to opposed outer surfaces of a generally planar, insulating core 30. One or more PCMs 40 are macroencapsulated between the sheathings 20, 22.
  • Various types of sheathings 20, 22 are known to those skilled in the art. The sheathing is preferably comprised of a rigid material such as gypsum or cementous composite, waferboard, metal, plywood, drywall, OSB, or an agricultural board product such as strawboard or wheatboard. Most preferably, the sheathing comprises OSB.
  • The sheathings 20, 22 of the present invention are of any suitable thickness. The sheathing preferably has a thickness between about 0.125 to 3 inches (7.18 mm to 7.62 cm), more preferably between about 0.25 to 2 inches (6.35 mm to 5.08 cm), and most preferably about 0.5 to 0.75 inches (1.27 to 1.91 cm). Common commercially available sheathing material has a thickness of about {fraction (7/16)}, ½, ¾, and 1 inch (1.11, 1.27, 1.90, and 2.54 cm).
  • The insulation 30 of the present invention can be any suitable material known to those skilled in the art. The insulation 30 is preferably an expanded polystyrene (“EPS”). Other suitable materials include, but are not limited to, molded expanded polystyrene (“MEPS”), extruded polystyrene (“XEPS”), expanded polystyrene (“EPS”), urethane, polyurethane and isocyanurate, fiberglass, cementitious or fibrous core insulating materials, and compressed straw insulation.
  • The insulation can be of any suitable thickness. The insulation preferably has a thickness between about 1-12 inches (2.54-38.1 cm), more preferably between about 2-8 inches (5.08-20.32 cm), and most preferably between about 3-7 inches (7.62-17.78 cm). Commercially available insulation usually has a thickness ranging between about 3⅝ to 11⅜ inch (9.21-28.89 cm).
  • The first and second sheathings 20, 22 are preferably attached to the respective opposed facings of the panel's insulating core 30 by any of the more conventional adhesive materials such as urethane or epoxy cement, glue or a mastic coating (not shown). It will be appreciated that the panel 10 may be constructed with sheathing only on one face of the panel with the insulating core 30 exposed. Such panels are well suited for unfinished warehouses and unfinished basements. In such an embodiment, the other sheathing is preferably added as or after the panel 10 is installed in the building.
  • Suitable PCMs 40 within the scope of the present invention include but are not limited to solid-to-liquid PCMs. The PCM materials preferably change from solid to liquid and back to solid as a function of the wall temperature. The PCMs preferably have their solid-to-liquid transition between about 72° F. and 86° F. (about 22° C. to 30° C.).
  • Suitable inorganic PCMs 40 include water, sodium sulphate, decahydrate, calcium chloride hexahydrate, sodium acetate trihydrate, quaternary ammonium/water clathrates or mixtures thereof. Organic solid-to-liquid PCMs include linear crystalline alkyl hydrocarbons, polyethylene glycols, pentaethritol, pentaglycerine, neo pentylglycol, acetamide, tetrahydrofuran, butyl stearate, butyl palmitate, lauric acid, capric acid, and other fatty acids and esters, primary long chain alcohols, or mixtures thereof. Silica gels can also be used to help reduce problems with leakage and volume change.
  • Most preferably, the PCMs 40 are selected from the group consisting of paraffin hydrocarbons, salt hydrates, fatty acids and eutectic mixtures, fatty alcohols, and neopentyl glycol. Preferred PCMs are commercially available from Rubitherm GmbH (Hamberger, Germany) and sold in the United States by Energy Storage Technologies (Dayton, Ohio). A most preferred PCM is RUBITHERM® R-26.
  • The PCMs 40 of the present invention are macroencapsulated between the sheathings 20, 22 in a housing 45. In the preferred embodiment, as illustrated in FIGS. 1-3, the PCM is macroencapsulated in a housing 45 comprising a tube. The tube may be of any suitable size but preferably has a diameter of between about 0.5 inch and 3 inch, and most preferably about 1 inch. The tube 45 is preferably capped at one or both ends 42 to prevent leakage. The housing is comprised of any suitable material, such as PVC, copper, aluminum, and the like.
  • The housing 45 containing the PCM is oriented in any suitable manner, e.g. horizontally, vertically, diagonally, or any variation thereof. As illustrated in FIGS. 1-3, the housing is most preferably oriented horizontally within the panel 10. Further, the housing 45 may be oriented between the sheathings 20, 22 in any suitable manner, e.g. centered, proximal to the outer sheathing, directly adjacent the outer sheathing, proximal to the inner sheathing, directly adjacent to the inner sheathing. Most preferably, as illustrated in FIGS. 1-3, the housing 45 is in close proximity to the internal sheathing 22. The housing containing the PCM may span all or part of the length, L, of the panel 10.
  • As shown in FIG. 3, the housing 45 containing the PCM 40 is preferably positioned between the sheathings 20, 22 by heating the housing 45 or by cutting a volume of insulation 30 similar to the volume of the housing so that the insulation 30 is removed (by melting or cutting) upon contact with the heated housing 45. As such, the insulation 30 itself can support the housing 45 without the aid of additional materials. Alternatively, brackets, screws, and conventional adhesive materials such as urethane or epoxy cement, glue or a mastic coating can be used to position the macroencapsulated PCM 40.
  • A suitable amount of PCM is encapsulated in the structural panel. The PCM preferably comprises about 5 to 30%, and most preferably about 10 to 20% of the weight of the sheathing of the panel 10. It will be appreciated that this percentage is useful to compare the amount of macroencapsulated PCM in the panels and walls of present invention to conventional boards in which the PCM is imbibed in the board and therefore % PCM was expressed as a percentage of the overall board weight.
  • The panels 10 of the present invention are used in buildings in a manner well known to those skilled in the art for SIPs. See generally Morley, Michael, 2000, Structural Insulated Panels (SIPs), The Taunton Press, Newborn, Conn., which is incorporated by reference. For example, a 12-foot (3.66 m) wall can have two 6-foot (1.83 m) panels of the present invention located between 2×4 (5.08×10.2 cm), 2×6-inch (5.08×15.2 cm) or other studs about 12 feet apart.
  • Structural panel 10 is shown as generally rectangular in shape, but may assume virtually any of the more common shapes assumed by structural panels in building construction. The phase-change structural panels 10 of the present invention are preferably custom manufactured to meet building specifications. Common sizes on structural panels that are commercially available range from about 4 ft×8 ft (1.22 m to 2.44 m) to about 8 ft×24 ft (2.44 m to 7.32 m).
  • In a second embodiment of the present invention, the macroencapsulated PCMs 40 of the present invention are incorporated into conventional walls 100, as opposed to the structural insulated wall panels 10 of the first embodiment. As illustrated in FIG. 4, as is typical in wall construction, a plurality of substantially vertical splines 50 are preferably spaced about every 10 to 20 inches (25.4 to 50.8 cm), even more preferably about every 14 inches (35.6 cm). The splines 50 are typically 2×4 inch (5.08×10.2 cm) wood studs, but can be any suitable size and material, such as metal I-or H-beams. Insulation 30 resides between the spines. Sheathings 20, 22 are attached to the spines in a conventional manner.
  • The macroencapsulated PCMs 40 of the present invention are positioned between one or more of the splines 50 using any suitable means. As shown in FIG. 4, the PCMs are preferably housed in a housing comprised of a copper pipe that is suspended from the splines 50 using a bracket 49. Those skilled in the art will appreciate that the housing 45 containing the PCMs 40 could be positioned in holes drilled through the splines 50; however, this approach is not preferable because it may decrease the structural stability of the splines. As discussed above, the PCMs are preferably positioned near the inner sheathing 22 and are horizontal; however, any suitable orientation and position may be utilized.
  • FIG. 5 illustrates an unfolded-box type test house using the macroencapsulated PCMs of the present invention in the walls 100. Preliminary findings from research conducted at the University of Kansas show that the integration of PCMs in insulated frame walls offer the potential to reduce wall peak heat flux by as much as about 40 percent based on wall orientation, quantity of PCM used, and wall insulation level.
  • More specifically, a test house with dimensions illustrated in FIG. 5 was constructed. The splines were comprised of 2×4-inch (5.08×10.2 cm) pine. PCMs comprising linear crystalline alkyl hydrocarbons, or paraffin wax, commercially available under the trade name of RT-26, which is manufactured by Rubitherm GmbH (Hamberger, Germany) and sold in the United States by Energy Storage Technologies (Dayton, Ohio), were placed into copper pipes capped at both ends with closed-ends copper caps. The macroencapsulated PCM pipes were then placed horizontally and secured to the studs with steel brackets and into the fiberglass insulation having a thickness of 4 in. (10.2 cm). Both sides of the wall were covered with OSB, manufactured by Georgia Pacific Corporation, and having a thickness of 0.5 in. (1.27 cm).
  • As a control, a wall of similar dimensions and construction without any macroencapsulated PCMs was constructed. Heat flux meters, Model A, manufactured and calibrated by International Thermal Instrument Company (Del Mar, Calif.) were used to measure the energy transferred. As shown in FIG. 6, the maximum wall heat flux reduction recorded was about 40 percent, which occurred in the west-facing wall. The average wall heat flux reduction was 20 percent when all orientations were taken into account when 10 percent of PCM (by OSB weight) was used. The peak heat flux reductions were lowest in north-facing walls. Total heat transferred across the envelope over a seven-day period was reduced by approximately 14 percent. The reductions were highest in west-facing walls (19 percent) and least in north facing walls (8 percent).
  • While specific embodiments have been shown and discussed, various modifications may of course be made, and the invention is not limited to the specific forms or arrangement of parts and steps described herein, except insofar as such limitations are included in the following claims. Further, it will be understood that certain features and sub-combinations are of utility and may be employed without reference to other features and sub-combinations. This is contemplated by and is within the scope of the claims.

Claims (45)

1. A structural panel comprising:
a first sheathing disposed on a first outer surface of an insulating core; and
a macroencapsulated phase change material positioned within said insulating core.
2. The structural panel of claim 1 further comprising a second sheathing disposed on a second outer surface of said insulating core, said second outer surface opposing said first outer surface, and
wherein said insulating core is positioned between said first sheathing and said second sheathing.
3. The structural panel of claim 1 wherein said first sheathing is comprised of a material selected from the group consisting of oriented strand board gypsum, waferboard, metal, plywood, drywall, oriented strand board, strawboard and wheatboard.
4. The structural panel of claim 1 wherein said insulating core is comprised of a material selected from the group consisting of polystyrene, urethane, polyurethane, isocyanurate, fiberglass, and straw insulation.
5. The structural panel of claim 1 wherein said first sheathing is affixed on said first outer surface of said insulating core using a material selected from the group consisting of a urethane cement, epoxy cement, glue and mastic.
6. The structural panel of claim 1 wherein said macroencapsulated phase change material is one or more solid-to-liquid phase change materials.
7. The structural panel of claim 1 wherein the macroencapsulated phase change material has a solid-to-liquid transition between about 72° F. and 86° F. (22° C. to 30° C.).
8. The structural panel of claim 1 wherein the phase change material is macroencapsulated in a housing.
9. The structural panel of claim 8 wherein said housing comprises a tube.
10. The structural panel of claim 9 wherein said tube is capped at both ends.
11. The structural panel of claim 8 wherein the housing is comprised of a material selected from the group consisting of PVC, copper, and aluminum.
12. The structural panel of claim 8 wherein said housing is orientated substantially horizontally within the panel.
13. The structural panel of claim 8 wherein said housing is proximal to the first sheathing.
14. The structural panel of claim 8 wherein said housing is substantially centered between said first and second sheathings.
15. The structural panel of claim 1 wherein said panel is substantially rectangular in shape.
16. A wall comprising:
a plurality of spines; and
a macroencapsulated phase-change material positioned between at least two of said splines.
17. The wall of claim 16 further comprising insulation between at least two of said splines.
18. The wall of claim 17 wherein said insulation is comprised of a material selected from the group consisting of polystyrene, urethane, polyurethane, isocyanurate, fiberglass, and straw insulation.
19. The wall of claim 16 wherein at least two of said splines are substantially vertical.
20. The wall of claim 16 further comprising a sheathing positioned over at least two adjacent splines.
21. The wall of claim 20 wherein said sheathing is comprised of a material selected from the group consisting of oriented strand board gypsum, waferboard, metal, plywood, drywall, oriented strand board, strawboard and wheatboard.
22. The wall of claim 16 wherein said macroencapsulated phase change material is one or more solid-to-liquid phase change materials.
23. The wall of claim 16 wherein the phase change material has a solid-to-liquid transition between about 72° F. and 86° F. (22° C. to 30° C.).
24. The wall of claim 16 wherein the phase change material is macroencapsulated in a housing.
25. The wall of claim 24 wherein said housing comprises a tube.
26. The wall of claim 25 wherein said tube is capped at one or both ends.
27. The wall of claim 24 wherein the housing is comprised of a material selected from the group consisting of PVC, copper, and aluminum.
28. The wall of claim 24 wherein said housing is orientated substantially horizontally.
29. The wall of claim 24 wherein a first and second sheathing are positioned on opposing sides of at least two adjacent splines, and said macroencapsulated PCM is proximal to the said first sheathing.
30. The wall of claim 16 wherein said wall is substantially rectangular in shape.
31. A method for constructing a wall or wall panel comprising:
providing an insulating core for said wall; and
inserting a macroencapsulated phase change material within said insulating core.
32. The method of claim 31 wherein said insulating core is comprised of a material selected from the group consisting of polystyrene, urethane, polyurethane, isocyanurate, fiberglass, and straw insulation.
33. The method of claim 31 further comprising the step of providing a sheathing over at least one surface of said insulating core.
34. The method of claim 33 wherein said sheathing is comprised of a material selected from the group consisting of oriented strand board gypsum, waferboard, metal, plywood, drywall, oriented strand board, strawboard and wheatboard.
35. The method of claim 31 wherein said macroencapsulated phase change material is one or more solid-to-liquid phase change materials.
36. The method of claim 31 wherein the phase change material has a solid-to-liquid transition between about 72° F. and 86° F. (22° C. to 30° C.).
37. The method of claim 31 wherein the phase change material is macroencapsulated in a housing comprising a tube.
38. The method of claim 37 wherein the housing is being comprised a material selected from the group consisting of PVC, copper, and aluminum.
39. The method of claim 37 wherein said housing is orientated substantially horizontally.
40. The method of claim 37 further comprising the step of positioning a first and second sheathing over said insulating core such that said macroencapsulated phase change material is proximal to said first sheathing.
41. The method of claim 31 wherein said macroencapsulated phase change materials are inserted by heating a housing containing the phase change materials and then melting the insulation of said insulating core.
42. The method of claim 31 wherein said macroencapsulated phase change materials are inserted by cutting away a portion of said insulating core.
43. The method of claim 31 further comprising the step of providing a plurality of splines whereby said insulating core containing said macroencapsulated phase change materials is positioned between at least two of said splines.
44. The method of claim 43 further comprising the step of securing said macroencapsulated phase change materials to said two splines.
45. The method of claim 44 wherein said securing step comprises attaching a bracket to said splines for holding said macroencapsulated phase change materials.
US10/639,910 2003-08-13 2003-08-13 Phase-change structural insulated panels and walls Abandoned US20050055982A1 (en)

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Cited By (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1703033A2 (en) * 2005-02-23 2006-09-20 Corus Bausysteme GmbH Interior building panel with PCM
US20070094967A1 (en) * 2005-09-23 2007-05-03 Ut-Battelle, Llc Panelized wall system with foam core insulation
US20070125041A1 (en) * 2005-09-13 2007-06-07 Harvey Misbin Wallboard system and methods of installation and repair
US20080099187A1 (en) * 2004-01-26 2008-05-01 Rini Daniel P Method and apparatus for absorbing thermal energy
CN100404764C (en) * 2005-04-15 2008-07-23 黄振利 Thermal insulation flooring
US20080174147A1 (en) * 2007-01-24 2008-07-24 Martin Marietta Materials, Inc. Insulated Composite Body Panel Structure for a Refrigerated Truck Body
US20090205277A1 (en) * 2008-02-19 2009-08-20 Gibson A David Construction Panel System And Method Of Manufacture Thereof
EP2098655A1 (en) * 2008-03-04 2009-09-09 Corus Technology BV Ceiling with corrugated steel sheet
US20090313931A1 (en) * 2008-06-24 2009-12-24 Porter William H Multilayered structural insulated panel
ES2333092A1 (en) * 2009-07-29 2010-02-16 Universidad Politecnica De Madrid Thermal conditioner pavement for interiors (Machine-translation by Google Translate, not legally binding)
WO2010076118A1 (en) * 2008-12-17 2010-07-08 Basf Se Laminar component made from composite material
US20100223875A1 (en) * 2009-03-05 2010-09-09 Cornel Preda Insulating board system
US20100249283A1 (en) * 2009-03-31 2010-09-30 Weyerhaeuser Nr Company Wood composite with water-repelling agent
EP2239388A1 (en) * 2009-03-30 2010-10-13 Kalzip GmbH Building component based on a phase change material
ES2351290A1 (en) * 2010-07-28 2011-02-02 Universidad Politecnica De Madrid Thermal conditioning system and energetic storage for technical floors. (Machine-translation by Google Translate, not legally binding)
US20110047908A1 (en) * 2009-08-28 2011-03-03 Brusman Bryan Daniel High-strength insulated building panel with internal stud members
US20110108241A1 (en) * 2009-01-20 2011-05-12 Driscoll Joseph A Method for making phase change products from an encapsulated phase change material
CZ302477B6 (en) * 2009-12-11 2011-06-08 Vysoké ucení technické v Brne Heat accumulating module based on materials with phase change and assembly of such modules
US20120096716A1 (en) * 2011-12-28 2012-04-26 Tran Bao Q Smart building systems and methods
CN102470067A (en) * 2009-08-26 2012-05-23 拜尔材料科学股份公司 Polyurethane foam with latent heat storage unit
CZ303841B6 (en) * 2012-02-14 2013-05-22 Vysoké ucení technické v Brne Heat-storage module with a system of capillary mats and assembly of such modules
WO2013087953A1 (en) * 2011-12-16 2013-06-20 Detea, S. A. Honeycomb floor panel and slab
US8601761B2 (en) 2011-09-30 2013-12-10 John Daines Chadwick Techniques for building construction using fabricated timbers
US20140069040A1 (en) * 2012-09-11 2014-03-13 David Gibson Contruction panel system and methods of assembly thereof
US20140190105A1 (en) * 2013-01-07 2014-07-10 Clifford Eugene Babson Method of framing and constructing a building structure and walls and panels for use in such construction
US20140335292A1 (en) * 2013-05-07 2014-11-13 King Fahd University Of Petroleum And Minerals Thermal insulation panel for buildings
CN104196140A (en) * 2014-09-26 2014-12-10 常熟建工建设集团有限公司苏州分公司 Reinforced gypsum polyphenyl composite insulation board
US8950130B2 (en) 2011-09-30 2015-02-10 John Daines Chadwick Techniques for building construction using fabricated timbers
CN105157097A (en) * 2015-10-13 2015-12-16 哈尔滨工业大学建筑设计研究院 Detachable phase-change heat storage device applied to fire wall
US9279075B2 (en) 2009-01-20 2016-03-08 Smart Pcm Patent Holdco, Llc Phase change material-containing composition and related products and methods
CN105696724A (en) * 2016-01-25 2016-06-22 深圳大学 Large-volume replaceable phase-change energy storage plate body system and phase-change energy storage wall body
US20160208489A1 (en) * 2012-09-11 2016-07-21 A. David Gibson Construction panel system and methods of assembly thereof
US9399866B2 (en) 2014-02-18 2016-07-26 Kuwait University Thermal barrier panel with selectable phase change materials
CN106088368A (en) * 2016-08-10 2016-11-09 温州大学 Phase-transition heat-preserving flooring
US9702152B2 (en) 2011-06-17 2017-07-11 Basf Se Prefabricated wall assembly having an outer foam layer
US20170370656A1 (en) * 2014-12-26 2017-12-28 Eidai Co., Ltd. Heat reservoir impregnated with latent heat storage material with excellent thermostability
CN107628785A (en) * 2017-08-29 2018-01-26 北京禾木之家科技发展有限公司 The preparation method of Light Wall
CN108999312A (en) * 2018-09-14 2018-12-14 西安建筑科技大学 A kind of heat-preserving heat-insulating wall structure
CN109025006A (en) * 2018-09-13 2018-12-18 沈阳建筑大学 A kind of energy-saving phase transformation desulfurated plaster wall and preparation method thereof
CN109868930A (en) * 2019-01-30 2019-06-11 深装总建设集团股份有限公司 Metal phase change composite curtain wall plate and its preparation method and application
US10385562B2 (en) * 2014-01-18 2019-08-20 4Wall Ip Ltd Building panel assembly and method of manufacturing
CN111535474A (en) * 2020-05-13 2020-08-14 山东海冠新能源科技有限公司 Phase change energy storage sealing wallboard with multiple temperature control adjusting structures
US10801197B2 (en) 2015-01-19 2020-10-13 Basf Se Wall assembly having a spacer
CN112127495A (en) * 2020-09-30 2020-12-25 邓允云 Heat insulation board for building
US20210062510A1 (en) * 2019-08-27 2021-03-04 Robert Joe Alderman Retrofit Roof With A Phase Change Material Modulated Climate Space
US11118347B2 (en) 2011-06-17 2021-09-14 Basf Se High performance wall assembly
US20210293017A1 (en) * 2020-03-23 2021-09-23 Owens Corning Intellectual Capital, Llc Insulation including phase change materials
US11352783B2 (en) * 2020-01-28 2022-06-07 University Of North Texas Fabrication of a phase change material (PCM) integrated insulation
CN115233859A (en) * 2022-06-24 2022-10-25 哈尔滨工业大学 Low-energy-consumption phase-change energy storage connecting piece
US20220341605A1 (en) * 2021-04-23 2022-10-27 Korea Institute Of Science And Technology Building system for reducing energy consumption
US11530880B2 (en) * 2017-06-13 2022-12-20 South China University Of Technology Phase-change energy-storage structure for building insulation
US11541625B2 (en) 2015-01-19 2023-01-03 Basf Se Wall assembly
US20230049445A1 (en) * 2021-08-12 2023-02-16 Plank Structural Systems LLC Foam filled structural plank building foundation with laminated reinforcement
EP4227628A1 (en) * 2015-08-31 2023-08-16 Phase Change Energy Solutions, Inc. Modular and portable fixtures containing a phase change material
US11959272B1 (en) 2020-11-25 2024-04-16 Herbert L. deNourie Building construction

Citations (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676967A (en) * 1970-07-01 1972-07-18 Augustus Frati Forms for concrete wall construction
US3697633A (en) * 1970-07-21 1972-10-10 Howard M Edgar Structural core
US4178727A (en) * 1978-02-01 1979-12-18 Architectural Research Corporation Heat absorbing panel
US4259401A (en) * 1976-08-10 1981-03-31 The Southwall Corporation Methods, apparatus, and compositions for storing heat for the heating and cooling of buildings
US4267822A (en) * 1978-11-08 1981-05-19 Grumman Energy Systems, Inc. Integrated solar energy system
US4290416A (en) * 1978-09-13 1981-09-22 One Design, Inc. Phase change energy storage panel for environmentally driven heating and cooling system
US4498459A (en) * 1982-11-27 1985-02-12 Ben-Gurion University Of The Negev Phase-change heat storage building panels
US4572864A (en) * 1985-01-04 1986-02-25 The United States Of America As Represented By The United States Department Of Energy Composite materials for thermal energy storage
US4628650A (en) * 1985-09-09 1986-12-16 Parker Bert A Structural insulated panel system
US4747240A (en) * 1981-08-06 1988-05-31 National Gypsum Company Encapsulated PCM aggregate
US4825939A (en) * 1984-08-31 1989-05-02 The University Of Dayton Polymeric compositions incorporating polyethylene glycol as a phase change material
US5007478A (en) * 1989-05-26 1991-04-16 University Of Miami Microencapsulated phase change material slurry heat sinks
US5290904A (en) * 1991-07-31 1994-03-01 Triangle Research And Development Corporation Heat shield
US5532039A (en) * 1994-04-25 1996-07-02 Gateway Technologies, Inc. Thermal barriers for buildings, appliances and textiles
US5626936A (en) * 1993-09-09 1997-05-06 Energy Pillow, Inc. Phase change insulation system
US5770295A (en) * 1993-09-09 1998-06-23 Energy Pillow, Inc. Phase change thermal insulation structure
US5795621A (en) * 1992-09-04 1998-08-18 Cca Inc. Methods for production of patterned shaped articles
US5842314A (en) * 1997-05-08 1998-12-01 Porter; William H. Metal reinforcement of gypsum, concrete or cement structural insulated panels
US6230444B1 (en) * 1997-03-26 2001-05-15 Outlast Technologies, Inc. Building conditioning technique using phase change materials
US6256960B1 (en) * 1999-04-12 2001-07-10 Frank J. Babcock Modular building construction and components thereof
US20020069600A1 (en) * 1998-10-09 2002-06-13 American Structural Composites, Inc. Composite structural building panels and systems and method for erecting a structure using such panels
US6481172B1 (en) * 2000-01-12 2002-11-19 William H. Porter Structural wall panels
US6564521B1 (en) * 2000-05-12 2003-05-20 Brown Paul A Structural sandwich panels and method of manufacture of structural sandwich panels
US20030124318A1 (en) * 2002-01-02 2003-07-03 Magill Monte C. Thermal barriers with reversible enhanced thermal properties
US20030131623A1 (en) * 2001-09-05 2003-07-17 Suppes Galen J. Heat pump using phase change materials
US6699266B2 (en) * 2001-12-08 2004-03-02 Charles A. Lachenbruch Support surface with phase change material or heat tubes
US6835334B2 (en) * 2000-09-27 2004-12-28 Microtek Laboratories, Inc. Macrocapsules containing microencapsulated phase change materials
US6855422B2 (en) * 2000-09-21 2005-02-15 Monte C. Magill Multi-component fibers having enhanced reversible thermal properties and methods of manufacturing thereof
US6855410B2 (en) * 1992-07-14 2005-02-15 Theresa M. Buckley Phase change material thermal capacitor clothing

Patent Citations (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3676967A (en) * 1970-07-01 1972-07-18 Augustus Frati Forms for concrete wall construction
US3697633A (en) * 1970-07-21 1972-10-10 Howard M Edgar Structural core
US4259401A (en) * 1976-08-10 1981-03-31 The Southwall Corporation Methods, apparatus, and compositions for storing heat for the heating and cooling of buildings
US4178727A (en) * 1978-02-01 1979-12-18 Architectural Research Corporation Heat absorbing panel
US4290416A (en) * 1978-09-13 1981-09-22 One Design, Inc. Phase change energy storage panel for environmentally driven heating and cooling system
US4267822A (en) * 1978-11-08 1981-05-19 Grumman Energy Systems, Inc. Integrated solar energy system
US4747240A (en) * 1981-08-06 1988-05-31 National Gypsum Company Encapsulated PCM aggregate
US4498459A (en) * 1982-11-27 1985-02-12 Ben-Gurion University Of The Negev Phase-change heat storage building panels
US4825939A (en) * 1984-08-31 1989-05-02 The University Of Dayton Polymeric compositions incorporating polyethylene glycol as a phase change material
US4572864A (en) * 1985-01-04 1986-02-25 The United States Of America As Represented By The United States Department Of Energy Composite materials for thermal energy storage
US4628650A (en) * 1985-09-09 1986-12-16 Parker Bert A Structural insulated panel system
US5007478A (en) * 1989-05-26 1991-04-16 University Of Miami Microencapsulated phase change material slurry heat sinks
US5290904A (en) * 1991-07-31 1994-03-01 Triangle Research And Development Corporation Heat shield
US6855410B2 (en) * 1992-07-14 2005-02-15 Theresa M. Buckley Phase change material thermal capacitor clothing
US5795621A (en) * 1992-09-04 1998-08-18 Cca Inc. Methods for production of patterned shaped articles
US5626936A (en) * 1993-09-09 1997-05-06 Energy Pillow, Inc. Phase change insulation system
US5770295A (en) * 1993-09-09 1998-06-23 Energy Pillow, Inc. Phase change thermal insulation structure
US5532039A (en) * 1994-04-25 1996-07-02 Gateway Technologies, Inc. Thermal barriers for buildings, appliances and textiles
US6230444B1 (en) * 1997-03-26 2001-05-15 Outlast Technologies, Inc. Building conditioning technique using phase change materials
US5842314A (en) * 1997-05-08 1998-12-01 Porter; William H. Metal reinforcement of gypsum, concrete or cement structural insulated panels
US20020069600A1 (en) * 1998-10-09 2002-06-13 American Structural Composites, Inc. Composite structural building panels and systems and method for erecting a structure using such panels
US6256960B1 (en) * 1999-04-12 2001-07-10 Frank J. Babcock Modular building construction and components thereof
US6481172B1 (en) * 2000-01-12 2002-11-19 William H. Porter Structural wall panels
US6564521B1 (en) * 2000-05-12 2003-05-20 Brown Paul A Structural sandwich panels and method of manufacture of structural sandwich panels
US6855422B2 (en) * 2000-09-21 2005-02-15 Monte C. Magill Multi-component fibers having enhanced reversible thermal properties and methods of manufacturing thereof
US6835334B2 (en) * 2000-09-27 2004-12-28 Microtek Laboratories, Inc. Macrocapsules containing microencapsulated phase change materials
US20030131623A1 (en) * 2001-09-05 2003-07-17 Suppes Galen J. Heat pump using phase change materials
US6699266B2 (en) * 2001-12-08 2004-03-02 Charles A. Lachenbruch Support surface with phase change material or heat tubes
US20030124318A1 (en) * 2002-01-02 2003-07-03 Magill Monte C. Thermal barriers with reversible enhanced thermal properties

Cited By (73)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9612061B2 (en) * 2004-01-26 2017-04-04 Rini Technologies, Inc. Method and apparatus for absorbing thermal energy
US20080099187A1 (en) * 2004-01-26 2008-05-01 Rini Daniel P Method and apparatus for absorbing thermal energy
EP1703033A2 (en) * 2005-02-23 2006-09-20 Corus Bausysteme GmbH Interior building panel with PCM
EP1703033A3 (en) * 2005-02-23 2007-02-14 Corus Bausysteme GmbH Interior building panel with PCM
CN100404764C (en) * 2005-04-15 2008-07-23 黄振利 Thermal insulation flooring
US20070125041A1 (en) * 2005-09-13 2007-06-07 Harvey Misbin Wallboard system and methods of installation and repair
US7603822B2 (en) * 2005-09-23 2009-10-20 Ut-Battelle, Llc Panelized wall system with foam core insulation
US20070094967A1 (en) * 2005-09-23 2007-05-03 Ut-Battelle, Llc Panelized wall system with foam core insulation
US8342588B2 (en) * 2007-01-24 2013-01-01 Martin Marietta Materials, Inc. Insulated composite body panel structure for a refrigerated truck body
US20080174147A1 (en) * 2007-01-24 2008-07-24 Martin Marietta Materials, Inc. Insulated Composite Body Panel Structure for a Refrigerated Truck Body
US20090205277A1 (en) * 2008-02-19 2009-08-20 Gibson A David Construction Panel System And Method Of Manufacture Thereof
EP2098655A1 (en) * 2008-03-04 2009-09-09 Corus Technology BV Ceiling with corrugated steel sheet
US20090313931A1 (en) * 2008-06-24 2009-12-24 Porter William H Multilayered structural insulated panel
CN102317073A (en) * 2008-12-17 2012-01-11 巴斯夫欧洲公司 Laminar component made from composite material
WO2010076118A1 (en) * 2008-12-17 2010-07-08 Basf Se Laminar component made from composite material
US8491992B2 (en) 2008-12-17 2013-07-23 Basf Se Laminar component made from composite material
US20110108241A1 (en) * 2009-01-20 2011-05-12 Driscoll Joseph A Method for making phase change products from an encapsulated phase change material
US20110108758A1 (en) * 2009-01-20 2011-05-12 Driscoll Joseph A Method for Making Phase Change Aggregates From a Microencapsulated Phase Change Material Liquid Emulsion
US9279075B2 (en) 2009-01-20 2016-03-08 Smart Pcm Patent Holdco, Llc Phase change material-containing composition and related products and methods
US20100223875A1 (en) * 2009-03-05 2010-09-09 Cornel Preda Insulating board system
EP2239388A1 (en) * 2009-03-30 2010-10-13 Kalzip GmbH Building component based on a phase change material
US8748516B2 (en) 2009-03-31 2014-06-10 Weyerhaeuser Nr Company Wood composite with water-repelling agent
US20100249283A1 (en) * 2009-03-31 2010-09-30 Weyerhaeuser Nr Company Wood composite with water-repelling agent
ES2333092A1 (en) * 2009-07-29 2010-02-16 Universidad Politecnica De Madrid Thermal conditioner pavement for interiors (Machine-translation by Google Translate, not legally binding)
CN102470067A (en) * 2009-08-26 2012-05-23 拜尔材料科学股份公司 Polyurethane foam with latent heat storage unit
US20110047908A1 (en) * 2009-08-28 2011-03-03 Brusman Bryan Daniel High-strength insulated building panel with internal stud members
CZ302477B6 (en) * 2009-12-11 2011-06-08 Vysoké ucení technické v Brne Heat accumulating module based on materials with phase change and assembly of such modules
ES2351290A1 (en) * 2010-07-28 2011-02-02 Universidad Politecnica De Madrid Thermal conditioning system and energetic storage for technical floors. (Machine-translation by Google Translate, not legally binding)
US11131089B2 (en) 2011-06-17 2021-09-28 Basf Se High performace wall assembly
US9702152B2 (en) 2011-06-17 2017-07-11 Basf Se Prefabricated wall assembly having an outer foam layer
US11118347B2 (en) 2011-06-17 2021-09-14 Basf Se High performance wall assembly
US8950130B2 (en) 2011-09-30 2015-02-10 John Daines Chadwick Techniques for building construction using fabricated timbers
US8601761B2 (en) 2011-09-30 2013-12-10 John Daines Chadwick Techniques for building construction using fabricated timbers
WO2013087953A1 (en) * 2011-12-16 2013-06-20 Detea, S. A. Honeycomb floor panel and slab
US8359750B2 (en) * 2011-12-28 2013-01-29 Tran Bao Q Smart building systems and methods
US20120096716A1 (en) * 2011-12-28 2012-04-26 Tran Bao Q Smart building systems and methods
CZ303841B6 (en) * 2012-02-14 2013-05-22 Vysoké ucení technické v Brne Heat-storage module with a system of capillary mats and assembly of such modules
US20140069040A1 (en) * 2012-09-11 2014-03-13 David Gibson Contruction panel system and methods of assembly thereof
US10024057B2 (en) * 2012-09-11 2018-07-17 A. David Gibson Construction panel system and methods of assembly thereof
US9328506B2 (en) * 2012-09-11 2016-05-03 David Gibson Construction panel system and methods of assembly
US20160208489A1 (en) * 2012-09-11 2016-07-21 A. David Gibson Construction panel system and methods of assembly thereof
US20140190105A1 (en) * 2013-01-07 2014-07-10 Clifford Eugene Babson Method of framing and constructing a building structure and walls and panels for use in such construction
US9702147B2 (en) * 2013-01-07 2017-07-11 Clifford Eugene Babson Panels for framing and constructing a building structure
US20140335292A1 (en) * 2013-05-07 2014-11-13 King Fahd University Of Petroleum And Minerals Thermal insulation panel for buildings
US10385562B2 (en) * 2014-01-18 2019-08-20 4Wall Ip Ltd Building panel assembly and method of manufacturing
US9399866B2 (en) 2014-02-18 2016-07-26 Kuwait University Thermal barrier panel with selectable phase change materials
CN104196140A (en) * 2014-09-26 2014-12-10 常熟建工建设集团有限公司苏州分公司 Reinforced gypsum polyphenyl composite insulation board
US20170370656A1 (en) * 2014-12-26 2017-12-28 Eidai Co., Ltd. Heat reservoir impregnated with latent heat storage material with excellent thermostability
US10801197B2 (en) 2015-01-19 2020-10-13 Basf Se Wall assembly having a spacer
US11541625B2 (en) 2015-01-19 2023-01-03 Basf Se Wall assembly
EP4227628A1 (en) * 2015-08-31 2023-08-16 Phase Change Energy Solutions, Inc. Modular and portable fixtures containing a phase change material
CN105157097A (en) * 2015-10-13 2015-12-16 哈尔滨工业大学建筑设计研究院 Detachable phase-change heat storage device applied to fire wall
CN105696724A (en) * 2016-01-25 2016-06-22 深圳大学 Large-volume replaceable phase-change energy storage plate body system and phase-change energy storage wall body
CN106088368A (en) * 2016-08-10 2016-11-09 温州大学 Phase-transition heat-preserving flooring
US11530880B2 (en) * 2017-06-13 2022-12-20 South China University Of Technology Phase-change energy-storage structure for building insulation
CN107628785A (en) * 2017-08-29 2018-01-26 北京禾木之家科技发展有限公司 The preparation method of Light Wall
CN109025006A (en) * 2018-09-13 2018-12-18 沈阳建筑大学 A kind of energy-saving phase transformation desulfurated plaster wall and preparation method thereof
CN108999312B (en) * 2018-09-14 2020-11-24 西安建筑科技大学 Heat preservation and insulation wall structure
CN108999312A (en) * 2018-09-14 2018-12-14 西安建筑科技大学 A kind of heat-preserving heat-insulating wall structure
CN109868930A (en) * 2019-01-30 2019-06-11 深装总建设集团股份有限公司 Metal phase change composite curtain wall plate and its preparation method and application
US20210062510A1 (en) * 2019-08-27 2021-03-04 Robert Joe Alderman Retrofit Roof With A Phase Change Material Modulated Climate Space
US11761211B2 (en) * 2019-08-27 2023-09-19 Robert Joe Alderman Retrofit roof with a phase change material modulated climate space
US11352783B2 (en) * 2020-01-28 2022-06-07 University Of North Texas Fabrication of a phase change material (PCM) integrated insulation
US11828060B2 (en) 2020-01-28 2023-11-28 University Of North Texas Fabrication of a phase change material (PCM) integrated insulation
US20210293017A1 (en) * 2020-03-23 2021-09-23 Owens Corning Intellectual Capital, Llc Insulation including phase change materials
CN111535474A (en) * 2020-05-13 2020-08-14 山东海冠新能源科技有限公司 Phase change energy storage sealing wallboard with multiple temperature control adjusting structures
CN112127495A (en) * 2020-09-30 2020-12-25 邓允云 Heat insulation board for building
US11959272B1 (en) 2020-11-25 2024-04-16 Herbert L. deNourie Building construction
US20220341605A1 (en) * 2021-04-23 2022-10-27 Korea Institute Of Science And Technology Building system for reducing energy consumption
US20230049445A1 (en) * 2021-08-12 2023-02-16 Plank Structural Systems LLC Foam filled structural plank building foundation with laminated reinforcement
US11814841B2 (en) * 2021-08-12 2023-11-14 Plank Structural Systems LLC Foam filled structural plank building foundation with laminated reinforcement
US11851875B2 (en) * 2021-08-12 2023-12-26 Plank Structural Systems LLC Foam filled structural plank building foundation with laminated reinforcement
CN115233859A (en) * 2022-06-24 2022-10-25 哈尔滨工业大学 Low-energy-consumption phase-change energy storage connecting piece

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