US20040259449A1 - Backing fabrics for papermaking machine convering materials - Google Patents

Backing fabrics for papermaking machine convering materials Download PDF

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Publication number
US20040259449A1
US20040259449A1 US10/489,057 US48905704A US2004259449A1 US 20040259449 A1 US20040259449 A1 US 20040259449A1 US 48905704 A US48905704 A US 48905704A US 2004259449 A1 US2004259449 A1 US 2004259449A1
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United States
Prior art keywords
polyamide
monofilaments
twisted yarn
twisted
fabrics
Prior art date
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Abandoned
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US10/489,057
Inventor
Thierry Onder de Linden
Jurgen Budenbender
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Asahi Kasei Spandex Europe GmbH
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Bayer Faser GmbH
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Filing date
Publication date
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Assigned to BAYER FRASER GMBH reassignment BAYER FRASER GMBH ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: ONDER DE LINDEN, THIERRY, BUDENBENDER, JURGEN
Publication of US20040259449A1 publication Critical patent/US20040259449A1/en
Abandoned legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D15/00Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
    • DTEXTILES; PAPER
    • D03WEAVING
    • D03DWOVEN FABRICS; METHODS OF WEAVING; LOOMS
    • D03D7/00Woven fabrics designed to be resilient, i.e. to recover from compressive stress
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21FPAPER-MAKING MACHINES; METHODS OF PRODUCING PAPER THEREON
    • D21F7/00Other details of machines for making continuous webs of paper
    • D21F7/08Felts
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B17/00Recovery of plastics or other constituents of waste material containing plastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2277/00Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as reinforcement
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2031/00Other particular articles
    • B29L2031/709Articles shaped in a closed loop, e.g. conveyor belts
    • B29L2031/7092Conveyor belts
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2211/00Protein-based fibres, e.g. animal fibres
    • D10B2211/01Natural animal fibres, e.g. keratin fibres
    • D10B2211/02Wool
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/02Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
    • DTEXTILES; PAPER
    • D10INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10BINDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
    • D10B2331/00Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
    • D10B2331/04Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyesters, e.g. polyethylene terephthalate [PET]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T442/00Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
    • Y10T442/30Woven fabric [i.e., woven strand or strip material]

Definitions

  • the present invention relates to backing fabrics for papermaking machine felt with improved properties, preferably improved wear resistance and in particular improved dimensional stability during paper manufacture.
  • Fabrics employed in the forming part consist predominantly of polyester monofilaments.
  • monofilaments of polyamides together with polyester monofilaments in an alternating pick-and-shot arrangement on the machine side are also used.
  • the basic fabrics for the pressing felt or wet pressing felt are produced almost exclusively from polyamide fibres and polyamide monofilaments, preferably from pure polyamide-6 but also from polyamide-66.
  • a nonwoven layer of polyamide fibres is needled onto the base fabrics consisting of polyamide monofilaments in a second processing stage and this layer is thereby mechanically anchored in the said base fabric.
  • Dry screens on the other hand normally consist of polyester monofilaments that are largely stabilised by means of suitable products, for example Stabaxol (a commercial product available from Rheinchemie, Mannheim), against hydrolytic decomposition.
  • Stabaxol a commercial product available from Rheinchemie, Mannheim
  • press felts made from polyamide-6 monofilaments have on account of their high abrasion resistance, compressibility and very good recovery of the felts after passing through the press nip major advantages compared to press felts of other materials, e.g. polypropylene, polyester, wool or other types of polyamide (e.g. PA 6.10, PA 6.12).
  • other materials e.g. polypropylene, polyester, wool or other types of polyamide (e.g. PA 6.10, PA 6.12).
  • a significant disadvantage of these press felts is however the lack of dimensional stability in the event of machine downtimes.
  • the materials polyamide-6 and polyamide-66 absorb up to 10 wt. % of water in a wet environment.
  • the length and thickness of the monofilaments changes with the absorption of water.
  • the change in length means that in the event of malfunctions or downtimes of the papermaking machine due to other causes the felts have a different weight and fabric density in the wet zones than in the dry zones.
  • a disadvantage of these fabrics and of the felt produced therefrom is however the significantly reduced wear resistance when used in papermaking machines compared to fabrics of polyamide-6 monofilaments and felts produced therefrom.
  • the object of the invention is achieved if in the production of the backing fabric there are used combination twisted yarns with 1 to 20 monofilaments of polyamide-6 and 20 to 1 monofilaments of polyamide 6.10, polyamide 6.12, polyamide 11 or polyamide 12 in the warp instead of twisted yarns of polyamide-6 monofilaments.
  • the fabrics produced in this way also have a significantly improved economic utility since the raw materials polyamide-6 and polyamide-66 are industrially more readily available and can be re-used in many recycling systems after economic utilisation.
  • a particular advantage of the process according to the invention is that twisted yarns of an even number of the materials used as well as also an odd number of these materials can be twisted with one another. In this way specific, calculable dimensional changes of the twisted yarns or fabrics produced therefrom can be established and the economic utility can optionally also be improved.
  • Pre-twisted yarns of construction 0.20 mm ⁇ 2 were produced on an Allma Saurer AZB-T type yarn twisting machine at 304 revolutions/metre
  • Pre-twisted yarns of polyamide 6, experimental part V 1, were processed on an Allma Saurer AZB-T type yarn twisting machine to form a balanced annular twisted yarn of construction 0.2 mm ⁇ 2 ⁇ 2 with S 304/Z 260 revolutions.
  • the twisted yarn was then fixed tension-free in a heating cabinet for 5 minutes at 160° C. and cut into pieces of length 1.00 m. The exact length and the weight of the sample pieces was determined. Following this the samples were then stored tension-free for 24 hours in a water bath at 20° C., removed from the water, dried, and the change in length as well as the weight were determined.
  • the abrasion resistance of the twisted yarns was determined by an abrasion test developed in-house. For this, the monofilaments and twisted yarns are drawn cyclically under a defined load over a grinding roller until they break. The number of grinding cycles is a measure of the abrasion resistance.
  • Pre-twisted yarn V 1 and pre-twisted yarn V 2 were processed into an annular twisted yarn as described in comparison example 1.
  • the annular twisted yarn had a proportion of PA 6.10 of 25%.
  • the change in length after wet/dry alternating cycles as well as the abrasion resistance was also determined as described in comparison example 1. The results are summarised in Table 1.
  • Pre-twisted yarn V 1 and pre-twisted yarn V 3 were processed into an annular twisted yarn as described in comparison example 1.
  • the annular twisted yarn had a proportion of PA 6.10 of 50%.
  • the change in length after wet/dry alternating cycles as well as the abrasion resistance was also determined as described in comparison example 1. The results are summarised in Table 1.
  • Pre-twisted yarn V 2 and pre-twisted yarn V 2 were processed into an annular twisted yarn as described in comparison example 1.
  • the annular twisted yarn had a proportion of PA 6.10 of 50%.
  • the change in length after wet/dry alternating cycles as well as the abrasion resistance was also determined as described in comparison example 1. The results are summarised in Table 1.
  • Pre-twisted yarn V 3 and pre-twisted yarn V 2 were processed into an annular twisted yarn as described in comparison example 1.
  • the annular twisted yarn had a proportion of PA 6.10 of 75%.
  • the change in length after wet/dry alternating cycles as well as the abrasion resistance was also determined as described in comparison example 1. The results are summarised in Table 1.
  • Pre-twisted yarn V 4 and pre-twisted yarn V 1 were processed into an annular twisted yarn as described in comparison example 1.
  • the annular twisted yarn had a proportion of PA 6.12 of 50%.
  • the change in length after wet/dry alternating cycles as well as the abrasion resistance was also determined as described in comparison example 1.
  • the results are summarised in Table 1.
  • Example 1 75 25 6.0 2.7 260-320
  • Example 2 50 50 5.2 2.0 250-295
  • Example 3 50 50 4.9 1.9 255-305
  • Example 4 25 75 3.8 1.6 225-290 Propn.
  • PA 6.12 Example 5 50 50 5.1 2.1 245-300

Abstract

Backing fabric for paper machine felts, based on yarn made of polyamide 6 and polyamide 6.10, polyamide 6.11, polyamide 11 and/or polyamide 12.

Description

  • The present invention relates to backing fabrics for papermaking machine felt with improved properties, preferably improved wear resistance and in particular improved dimensional stability during paper manufacture. [0001]
  • Processes for the production of monofilaments from thermoplastic polymers are in principle known (c.f. Handbuch der Kunststofftechnik II, C. Hanser Verlag, Munich 1986, pp. 295-319). [0002]
  • Paper production on modern papermaking machines involving sheet forming (forming part), mechanical dewatering (pressing part) and thermal dewatering (drying part), smoothing and rolling is known from Lehrbuch der Papier- und Kartonerzeugung (VEB Fachbuchverlag 1987, p. 190 ff). [0003]
  • Fabrics employed in the forming part consist predominantly of polyester monofilaments. In order to improve the abrasion resistance monofilaments of polyamides together with polyester monofilaments in an alternating pick-and-shot arrangement on the machine side are also used. [0004]
  • In the pressing part the basic fabrics for the pressing felt or wet pressing felt are produced almost exclusively from polyamide fibres and polyamide monofilaments, preferably from pure polyamide-6 but also from polyamide-66. A nonwoven layer of polyamide fibres is needled onto the base fabrics consisting of polyamide monofilaments in a second processing stage and this layer is thereby mechanically anchored in the said base fabric. [0005]
  • Dry screens on the other hand normally consist of polyester monofilaments that are largely stabilised by means of suitable products, for example Stabaxol (a commercial product available from Rheinchemie, Mannheim), against hydrolytic decomposition. [0006]
  • The commercially available press felts made from polyamide-6 monofilaments have on account of their high abrasion resistance, compressibility and very good recovery of the felts after passing through the press nip major advantages compared to press felts of other materials, e.g. polypropylene, polyester, wool or other types of polyamide (e.g. PA 6.10, PA 6.12). [0007]
  • A significant disadvantage of these press felts is however the lack of dimensional stability in the event of machine downtimes. The materials polyamide-6 and polyamide-66 absorb up to 10 wt. % of water in a wet environment. The length and thickness of the monofilaments changes with the absorption of water. In particular the change in length means that in the event of malfunctions or downtimes of the papermaking machine due to other causes the felts have a different weight and fabric density in the wet zones than in the dry zones. After dealing with the malfunctions and starting up the papermaking machine again no high-quality paper can be produced with these felts until the felts have re-established the same water content and the same density and width over the whole area. [0008]
  • Furthermore the change in width often means that the full working width of the papermaking machine cannot be utilised since the felts extend beyond the maximum width of the machine and are damaged at their edges. [0009]
  • There has therefore been no lack of attempts to improve the dimensional stability of press felts in wet/dry cycles. [0010]
  • One possibility is to use other fabric constructions. [0011]
  • The use of other materials in the warp of the fabrics is widespread, for example the replacement of polyamide-6 or polyamide-66 monofilaments by filaments which absorb substantially less moisture under high ambient moisture conditions and in which the dimensions of the fabrics consequently change only slightly. Monofilaments of polyamide 6.10 and polyamide 6.12 have proved suitable. [0012]
  • A disadvantage of these fabrics and of the felt produced therefrom is however the significantly reduced wear resistance when used in papermaking machines compared to fabrics of polyamide-6 monofilaments and felts produced therefrom. [0013]
  • It has now surprisingly been found that the disadvantages of the lack of wear resistance can be avoided and can be replaced by the advantages of a good dimensional stability if the warp of the basic fabric consists of combination twisted yarns that contain monofilaments of polyamide-6 as well as also monofilaments of polyamide 6.10 or polyamide 6.12. [0014]
  • The object of the invention is achieved if in the production of the backing fabric there are used combination twisted yarns with 1 to 20 monofilaments of polyamide-6 and 20 to 1 monofilaments of polyamide 6.10, polyamide 6.12, polyamide 11 or polyamide 12 in the warp instead of twisted yarns of polyamide-6 monofilaments. [0015]
  • Moreover, the fabrics produced in this way also have a significantly improved economic utility since the raw materials polyamide-6 and polyamide-66 are industrially more readily available and can be re-used in many recycling systems after economic utilisation. [0016]
  • A particular advantage of the process according to the invention is that twisted yarns of an even number of the materials used as well as also an odd number of these materials can be twisted with one another. In this way specific, calculable dimensional changes of the twisted yarns or fabrics produced therefrom can be established and the economic utility can optionally also be improved. [0017]
  • The following examples demonstrate the advantages according to the invention of the combination twisted yarns, without restricting the possibilities of these combinations. [0018]
  • EXAMPLES
  • [0019]
    Monofilament
    Commercial Product Diameter
    Polyamide 6 X 201 0.20 mm
    Polyamide 6.10 ATF 2311 0.20 mm
    Polyamide 6.12 ATF 23 0.20 mm
  • Manufacturer: Bayer Faser GmbH [0020]
  • Pre-Twisted Yarns [0021]
  • Pre-twisted yarns of construction 0.20 mm×2 were produced on an Allma Saurer AZB-T type yarn twisting machine at 304 revolutions/metre [0022]
  • Experimental part V 1: X 201/X 201, 0.20 mm×2, S 304 revolutions/metre [0023]
  • Experimental part V 2: X 201/ATF 2311, 0.20 mm×2, S 304 revolutions/metre [0024]
  • Experimental part V 3: ATF 2311, 0.20 mm×2, S 304 revolutions/metre [0025]
  • Experimental part V 4: ATF 2300 0.20 mm×2, S 304 revolutions/metre [0026]
  • Comparison Example 1
  • Pre-twisted yarns of polyamide 6, experimental part V 1, were processed on an Allma Saurer AZB-T type yarn twisting machine to form a balanced annular twisted yarn of construction 0.2 mm×2×2 with S 304/Z 260 revolutions. [0027]
  • The twisted yarn was then fixed tension-free in a heating cabinet for 5 minutes at 160° C. and cut into pieces of length 1.00 m. The exact length and the weight of the sample pieces was determined. Following this the samples were then stored tension-free for 24 hours in a water bath at 20° C., removed from the water, dried, and the change in length as well as the weight were determined. [0028]
  • The twisted yarn was then dried for 24 hours at 80° C. in a circulating air drying cabinet and the change in length and weight loss were again determined. This cycle was repeated three times. The changes in length between the wet/dry cycles are summarised in Table 1. [0029]
  • The abrasion resistance of the twisted yarns was determined by an abrasion test developed in-house. For this, the monofilaments and twisted yarns are drawn cyclically under a defined load over a grinding roller until they break. The number of grinding cycles is a measure of the abrasion resistance. [0030]
  • Comparison Example 2
  • Pre-twisted yarns of polyamide 6.10 (ATF 2311), experimental part V 3, 0.20 mm were processed into an annular twisted yarn as described in comparison example 1. The change in length after wet/dry alternating cycles as well as the abrasion resistance were also determined as described in comparison example 1. The results are summarised in Table 1. [0031]
  • Example 1
  • Pre-twisted yarn V 1 and pre-twisted yarn V 2 were processed into an annular twisted yarn as described in comparison example 1. The annular twisted yarn had a proportion of PA 6.10 of 25%. The change in length after wet/dry alternating cycles as well as the abrasion resistance was also determined as described in comparison example 1. The results are summarised in Table 1. [0032]
  • Example 2
  • Pre-twisted yarn V 1 and pre-twisted yarn V 3 were processed into an annular twisted yarn as described in comparison example 1. The annular twisted yarn had a proportion of PA 6.10 of 50%. The change in length after wet/dry alternating cycles as well as the abrasion resistance was also determined as described in comparison example 1. The results are summarised in Table 1. [0033]
  • Example 3
  • Pre-twisted yarn V 2 and pre-twisted yarn V 2 were processed into an annular twisted yarn as described in comparison example 1. The annular twisted yarn had a proportion of PA 6.10 of 50%. The change in length after wet/dry alternating cycles as well as the abrasion resistance was also determined as described in comparison example 1. The results are summarised in Table 1. [0034]
  • Example 4
  • Pre-twisted yarn V 3 and pre-twisted yarn V 2 were processed into an annular twisted yarn as described in comparison example 1. The annular twisted yarn had a proportion of PA 6.10 of 75%. The change in length after wet/dry alternating cycles as well as the abrasion resistance was also determined as described in comparison example 1. The results are summarised in Table 1. [0035]
  • Example 5
  • Pre-twisted yarn V 4 and pre-twisted yarn V 1 were processed into an annular twisted yarn as described in comparison example 1. The annular twisted yarn had a proportion of PA 6.12 of 50%. The change in length after wet/dry alternating cycles as well as the abrasion resistance was also determined as described in comparison example 1. The results are summarised in Table 1. [0036]
    TABLE 1
    Abrasion
    Propn. Propn. Water Water Behaviour
    PA 6 PA 6.10 Absorption 1) Elongation 1) min-max
    % % % % Cycles
    Comp. Ex. 1 100 0 6.8 3.0 260-350
    Comp. Ex. 2 0 100 2.8 1.2 220-290
    Example 1 75 25 6.0 2.7 260-320
    Example 2 50 50 5.2 2.0 250-295
    Example 3 50 50 4.9 1.9 255-305
    Example 4 25 75 3.8 1.6 225-290
    Propn.
    PA 6.12
    Example 5 50 50 5.1 2.1 245-300

Claims (8)

1. Backing fabric for papermaking machine covering materials, having a base fabric which comprises combination twisted yarns of monofilaments of polyamide 6 and monofilaments of polyamide 6.10, in the warp direction.
2. Backing fabric for papermaking machine covering materials, having a base fabric which comprises combination twisted fabrics of monofilaments of polyamide 6 and monofilaments of polyamide 6.12, polyamide 11 or polyamide 12 in the warp direction.
3. Backing fabric according to claim 1, wherein the twisted yarns contain 1 to 20 monofilaments of polyamide 6 and 20 to 1 monofilaments of polyamide 6.10.
4. Backing fabric according to claim 2, wherein the twisted yarns contain 1 to 20, monofilaments of polyamide 6 and 20 to 1 monofilaments of polyamide 6.12, polyamide 11 or polyamide 12.
5. Backing fabric according to any one of claims 1 to 4, wherein said monofilaments of said base fabrics have a diameter of 0.08 to 0.3 mm.
6. Process for the production of base fabrics of papermaking machine covering materials, which comprises forming a combination twisted yarn of polyamide 6 monofilaments with monofilaments of polyamide 6.10, polyamide 6.12, polyamide 11 or polyamide 12 and forming the warp of a base fabric with said combination twisted yarn.
7. Backing fabric according to claim 3, wherein said twisted yarns contain 1 to 6 monofilaments of polyamide 6 and 6 to 1 monofilaments of polyamide 6.10.
8. Backing fabric according to claim 4, wherein said twisted yarns contain 1 to 6 monofilaments of polyamide 6 and 6 to 1 monofilaments of polyamide 6.12, polyamide 11 or polyamide 12.
US10/489,057 2001-09-10 2002-08-29 Backing fabrics for papermaking machine convering materials Abandoned US20040259449A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE10144307A DE10144307A1 (en) 2001-09-10 2001-09-10 Stable carrier web support for paper machine, has weft of twisted yarns combining specified types of nylon monofilaments
DE10144307.2 2001-09-10
PCT/EP2002/009624 WO2003023136A1 (en) 2001-09-10 2002-08-29 Backing fabric for paper machine clothings

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EP (1) EP1432869B1 (en)
JP (1) JP2005502797A (en)
KR (1) KR20040039340A (en)
CN (1) CN1304686C (en)
AT (1) ATE338160T1 (en)
BR (1) BR0212379A (en)
CA (1) CA2459901A1 (en)
DE (2) DE10144307A1 (en)
PL (1) PL367354A1 (en)
WO (1) WO2003023136A1 (en)

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DE50208019D1 (en) 2006-10-12
WO2003023136A1 (en) 2003-03-20
DE10144307A1 (en) 2003-03-27
PL367354A1 (en) 2005-02-21
CA2459901A1 (en) 2003-03-20
BR0212379A (en) 2004-07-27
KR20040039340A (en) 2004-05-10
EP1432869B1 (en) 2006-08-30
EP1432869A1 (en) 2004-06-30
JP2005502797A (en) 2005-01-27
ATE338160T1 (en) 2006-09-15
CN1304686C (en) 2007-03-14

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