US20040149997A1 - Methods of forming electronic devices including semiconductor mesa structures and conductivity junctions and related devices - Google Patents

Methods of forming electronic devices including semiconductor mesa structures and conductivity junctions and related devices Download PDF

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US20040149997A1
US20040149997A1 US10/742,426 US74242603A US2004149997A1 US 20040149997 A1 US20040149997 A1 US 20040149997A1 US 74242603 A US74242603 A US 74242603A US 2004149997 A1 US2004149997 A1 US 2004149997A1
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mesa
semiconductor
substrate
junction
base layer
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Michael Bergman
David Emerson
Amber Abare
Kevin Haberern
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Wolfspeed Inc
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Assigned to CREE, INC. reassignment CREE, INC. ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: HABERERN, KEVIN WARD, ABARE, AMBER CHRISTINE, BERGMAN, MICHAEL JOHN, EMERSON, DAVID TODD
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/14Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a carrier transport control structure, e.g. highly-doped semiconductor layer or current-blocking structure
    • H01L33/145Semiconductor devices with at least one potential-jump barrier or surface barrier specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a carrier transport control structure, e.g. highly-doped semiconductor layer or current-blocking structure with a current-blocking structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/30Structure or shape of the active region; Materials used for the active region
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/04Processes or apparatus for excitation, e.g. pumping, e.g. by electron beams
    • H01S5/042Electrical excitation ; Circuits therefor
    • H01S5/0421Electrical excitation ; Circuits therefor characterised by the semiconducting contacting layers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/20Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/22Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/20Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/22Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
    • H01S5/223Buried stripe structure
    • H01S5/2231Buried stripe structure with inner confining structure only between the active layer and the upper electrode
    • HELECTRICITY
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    • H01S5/00Semiconductor lasers
    • H01S5/30Structure or shape of the active region; Materials used for the active region
    • H01S5/32Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures
    • H01S5/323Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser
    • H01S5/32308Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength less than 900 nm
    • H01S5/32341Structure or shape of the active region; Materials used for the active region comprising PN junctions, e.g. hetero- or double- heterostructures in AIIIBV compounds, e.g. AlGaAs-laser, InP-based laser emitting light at a wavelength less than 900 nm blue laser based on GaN or GaP
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    • H01S2301/00Functional characteristics
    • H01S2301/17Semiconductor lasers comprising special layers
    • H01S2301/176Specific passivation layers on surfaces other than the emission facet
    • HELECTRICITY
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    • H01S5/00Semiconductor lasers
    • H01S5/02Structural details or components not essential to laser action
    • H01S5/0206Substrates, e.g. growth, shape, material, removal or bonding
    • H01S5/021Silicon based substrates
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    • H01S5/00Semiconductor lasers
    • H01S5/04Processes or apparatus for excitation, e.g. pumping, e.g. by electron beams
    • H01S5/042Electrical excitation ; Circuits therefor
    • H01S5/0425Electrodes, e.g. characterised by the structure
    • H01S5/04254Electrodes, e.g. characterised by the structure characterised by the shape
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    • H01S5/00Semiconductor lasers
    • H01S5/20Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/22Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
    • H01S5/2205Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure comprising special burying or current confinement layers
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    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/20Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/22Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
    • H01S5/2205Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure comprising special burying or current confinement layers
    • H01S5/2206Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure comprising special burying or current confinement layers based on III-V materials
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    • H01S5/00Semiconductor lasers
    • H01S5/20Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/22Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
    • H01S5/2205Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure comprising special burying or current confinement layers
    • H01S5/2214Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure comprising special burying or current confinement layers based on oxides or nitrides
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S5/00Semiconductor lasers
    • H01S5/20Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers
    • H01S5/22Structure or shape of the semiconductor body to guide the optical wave ; Confining structures perpendicular to the optical axis, e.g. index or gain guiding, stripe geometry, broad area lasers, gain tailoring, transverse or lateral reflectors, special cladding structures, MQW barrier reflection layers having a ridge or stripe structure
    • H01S5/227Buried mesa structure ; Striped active layer
    • H01S5/2275Buried mesa structure ; Striped active layer mesa created by etching

Definitions

  • the present invention relates to the field of electronics, and more particularly, to methods of forming electronic. semiconductor devices and related structures.
  • a laser is a device that produces a beam of coherent monochromatic light as a result of stimulated emission of photons. Stimulated emission of photons may also produce optical gain, which may cause light beams produced by lasers to have a high optical energy.
  • a number of materials are capable of producing the lasing effect and include certain high-purity crystals (ruby is a common example), semiconductors, certain types of glass, certain gases including carbon dioxide, helium, argon and neon, and certain plasmas.
  • photonic devices include light-emitting diodes (LEDs), photodetectors, photovoltaic devices, and semiconductor lasers.
  • Semiconductor lasers are similar to other lasers in that the emitted radiation has spatial and temporal coherence. As noted above, laser radiation is highly monochromatic (i.e., of narrow band width) and it produces highly directional beams of light. Semiconductor lasers may differ, however, from other lasers in several respects. For example, in semiconductor lasers, the quantum transitions are associated with the band properties of materials; semiconductor lasers may be very compact in size, may have very narrow active regions, and larger divergence of the laser beam; the characteristics of a semiconductor laser may be strongly influenced by the properties of the junction medium; and for P-N junction lasers, the lasing action is produced by passing a forward current through the diode itself.
  • semiconductor lasers can provide very efficient systems that may be controlled by modulating the current directed across the devices. Additionally, because semiconductor lasers can have very short photon lifetimes, they may be used to produce high-frequency modulation. In turn, the compact size and capability for such high-frequency modulation may make semiconductor lasers an important light source for optical fiber communications.
  • the structure of a semiconductor laser should provide optical confinement to create a resonant cavity in which light amplification may occur, and electrical confinement to produce high current densities to cause stimulated emission to occur.
  • the semiconductor may be a direct bandgap material rather than an indirect bandgap material.
  • a direct bandgap material is one in which an electron's transition from the valence band to the conduction band does not require a change in crystal momentum for the electron.
  • Gallium arsenide and gallium nitride are examples of direct bandgap semiconductors.
  • In indirect bandgap semiconductors the alternative situation exists; i.e., a change of crystal momentum is required for an electron's transition between the valence and conduction bands.
  • Silicon and silicon carbide are examples of such indirect semiconductors.
  • the frequency of electromagnetic radiation i.e., the photons
  • the photons may be a function of the material's bandgap. Smaller bandgaps produce lower energy, longer wavelength photons, while wider bandgap materials produce higher energy, shorter wavelength photons.
  • one semiconductor commonly used for lasers is aluminum indium gallium phosphide (AlInGaP).
  • the light that AlInGaP can produce may be limited to the red portion of the visible spectrum, i.e., about 600 to 700 nanometers (nm).
  • semiconductor materials having relatively large bandgaps may be used.
  • Group III-nitride materials such as gallium nitride (GaN), the ternary alloys indium gallium nitride (InGaN), aluminum gallium nitride (AlGaN) and aluminum indium nitride (AlInN) as well as the quaternary alloy aluminum gallium indium nitride (AlInGaN) are attractive candidate materials for blue and UV lasers because of their relatively high bandgap (3.36 eV at room temperature for GaN). Accordingly, Group III-nitride based laser diodes have been demonstrated that emit light in the 370-420 nm range.
  • a light emitting device may include a silicon carbide substrate, and a semiconductor structure on the substrate. More particularly, the semiconductor structure may include a mesa having a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base. In addition, the semiconductor structure may have a first conductivity type adjacent the silicon carbide substrate, the semiconductor structure may have a second conductivity type adjacent the mesa surface, and the semiconductor structure may have a junction between the first and second conductivity types. Moreover, the mesa may be configured to provide at least one of current confinement or optical confinement for a light emitting device in the semiconductor structure.
  • the junction may be between the mesa base and the mesa surface.
  • the semiconductor structure may include a semiconductor base layer between the mesa base and the silicon carbide substrate and the junction may be between a surface of the base layer opposite the silicon carbide substrate and the silicon carbide substrate.
  • the semiconductor structure may include a Group III-V semiconductor material.
  • an electronic device may include a substrate and a semiconductor mesa on the substrate. More particularly, the semiconductor mesa may have a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base. Moreover, the semiconductor mesa may have a first conductivity type between the mesa base and a junction, the junction may be between the mesa base and the mesa surface, and the semiconductor mesa may have a second conductivity type between the junction and the mesa surface.
  • the junction may comprise a physical location where doping of the second conductivity type begins, the first conductivity type may be N-type, and the second conductivity type may be P-type.
  • the semiconductor mesa may comprise a Group III-V semiconductor material such as a Group III-nitride semiconductor material.
  • the junction may be no more that approximately 5 microns from the mesa base, and more particularly, the junction may be no more than approximately 0.75 microns from the mesa base. Moreover, the junction may be at least approximately 0.05 microns from the mesa base, and more particularly, the junction may be at least approximately 0.1 microns from the mesa base.
  • the semiconductor mesa may have a thickness in the range of approximately 0.1 microns to 5 microns.
  • a semiconductor base layer may be included between the substrate and the semiconductor mesa, and the semiconductor base layer may have the first conductivity type throughout. More particularly, the semiconductor base layer may have a thickness no greater than approximately 5 microns, and each of the semiconductor base layer and the semiconductor mesa may comprise a Group III-V semiconductor material.
  • the substrate may comprise silicon carbide.
  • an electronic device may include a substrate, a semiconductor base layer on the substrate, and a semiconductor mesa on a surface of the base layer opposite the substrate.
  • the semiconductor base layer may have a first conductivity type between the substrate and a junction, the junction may be between the substrate and a surface of the base layer opposite the substrate, and the semiconductor base layer may have a second. conductivity type between the junction and the surface of the base layer opposite the substrate.
  • the semiconductor mesa may have a mesa surface opposite the semiconductor base layer and mesa sidewalls between the mesa surface and the base layer, and the semiconductor mesa may have the second conductivity type throughout.
  • the junction may be a physical location where doping of the second conductivity type begins, the first conductivity type may be N-type, and the second conductivity type may be P-type.
  • Each of the semiconductor mesa and the semiconductor base layer may comprise a Group III-V semiconductor material such as a Group III-nitride semiconductor material.
  • the junction may be no more that approximately 0.4 microns from the surface of the base layer opposite the substrate, and more particularly, the junction may be no more than approximately 0.2 microns from the surface of the base layer opposite the substrate. In addition, the junction may be at least approximately 0.05 microns from the surface of the base layer opposite the substrate, and more particularly, the junction may be at least approximately 0.1 microns from the surface of the base layer opposite the substrate. Moreover, the semiconductor mesa may have a thickness in the range of approximately 0.1 microns to 5 microns, the semiconductor base layer may have a thickness no greater than approximately 5 microns. In addition, the substrate may comprise silicon carbide.
  • methods of forming an electronic device may include forming a semiconductor mesa on a substrate.
  • the semiconductor mesa may have a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base.
  • the semiconductor mesa may have a first conductivity type between the mesa base and a junction, the junction may be between the mesa base and the mesa surface, and the semiconductor mesa may have a second conductivity type between the junction and the mesa surface.
  • the junction may comprise a physical location where doping of the second conductivity type begins, the first conductivity type may be N-type, and the second conductivity type may be P-type.
  • the semiconductor mesa may comprise a Group III-V semiconductor material such as a Group III-nitride semiconductor material.
  • the junction may be no more that approximately 5 microns from the mesa base, and more particularly, the junction may be no more than approximately 0.75 microns from the mesa base. In addition, the junction may be at least approximately 0.05 microns from the mesa base, and more particularly, the junction may be at least approximately 0.1 microns from the mesa base.
  • the semiconductor mesa may have a thickness in the range of approximately 0.1 microns to 5 microns.
  • a semiconductor base layer may be formed between the substrate and the semiconductor mesa, and the semiconductor base layer may have the first conductivity type throughout. More particularly, forming the semiconductor mesa and forming the semiconductor base layer may include forming a layer of a semiconductor material on the substrate, forming a mask on the layer of the semiconductor material, and etching portions of layer of the semiconductor material exposed by the mask wherein a depth of etching defines a thickness of the mesa. The layer of the semiconductor material may also include a junction at a junction depth and wherein the depth of etching of the layer of the semiconductor material is greater than the junction depth.
  • the semiconductor base layer may have a thickness no greater than approximately 5 microns, and each of the semiconductor base layer and the semiconductor mesa may comprise a Group III-V semiconductor material.
  • the substrate may comprise silicon carbide.
  • methods of forming an electronic devices may include forming a semiconductor base layer on a substrate, and forming a semiconductor mesa of a surface of the base layer opposite the substrate.
  • the semiconductor base layer may have a first conductivity type between the substrate and a junction, the junction may be between the substrate and a surface of the base layer opposite the substrate, and the semiconductor base layer may have a second conductivity type between the junction and the surface of the base layer opposite the substrate.
  • the semiconductor mesa may have a mesa surface opposite the semiconductor base layer and mesa sidewalls between the mesa surface and the base layer, wherein the semiconductor mesa has the second conductivity type throughout.
  • the junction may include a physical location where doping of the second conductivity type begins, the first conductivity type may be N-type, and the second conductivity type may be P-type.
  • Each of the semiconductor mesa and the semiconductor base layer may comprises a Group III-V semiconductor material such as a Group III-nitride semiconductor material.
  • the junction is no more that approximately 0.4 microns from the surface of the base layer opposite the substrate, and more particularly, the junction may be no more than approximately 0.2 microns from the surface of the base layer opposite the substrate.
  • the junction may be at least approximately 0.05 microns from the surface of the base layer opposite the substrate, and more particularly, the junction may be at least approximately 0.1 microns from the surface of the base layer opposite the substrate.
  • the semiconductor mesa may have a thickness in the range of approximately 0.1 microns to 5 microns.
  • the semiconductor base layer may have a thickness no greater than approximately 5 microns, and the substrate may comprise silicon carbide.
  • forming the semiconductor mesa and forming the semiconductor base layer may include forming a layer of a semiconductor material on the substrate, forming a mask on the layer of the semiconductor material, and etching portions of layer of the semiconductor material exposed by the mask wherein a depth of etching defines a thickness of the mesa.
  • the semiconductor material may include a junction at a junction depth and wherein the depth of etching of the layer of the semiconductor material may be less than the junction depth.
  • FIG. 1 is a cross-sectional view illustrating semiconductor devices according to embodiments of the present invention.
  • FIG. 2 is a cross-sectional view illustrating semiconductor devices according to additional embodiments of the present invention.
  • FIG. 3 is a cross-sectional view illustrating semiconductor devices according to still additional embodiments of the present invention.
  • a semiconductor device may include a substrate 12 and an epitaxial semiconductor structure 14 including a semiconductor base layer 19 and a semiconductor mesa 20 on a portion of the base layer 19 .
  • the semiconductor mesa 20 may include a mesa surface 20 A opposite the base layer 19 , mesa sidewalls 20 B between the mesa surface 20 A and the base layer 19 , and a mesa base 20 C adjacent the base layer.
  • the device may also include a passivation layer 24 on the semiconductor base layer 19 and on portions of the semiconductor mesa 20 with portions of the mesa surface 20 A being free of the passivation layer 24 .
  • a first ohmic contact layer 26 may be provided on portions of the mesa surface 20 A free of the passivation layer, and a metal overlayer 28 may be provided on the passivation layer 24 and the ohmic contact layer 26 .
  • a second ohmic contact layer 27 may be provided on the substrate 12 opposite the semiconductor structure 14 to define an electrical current path through the mesa 20 , the semiconductor base layer 19 , and the substrate 12 .
  • a second ohmic contact layer may be provided on a same side of the substrate as the epitaxial semiconductor structure 14 so that current through the substrate 12 is not required.
  • the substrate 12 may included substrate material such as N-type silicon carbide having a polytype such as 2H, 4H, 6H, 8H, 15R, and/or 3C; sapphire; gallium nitride; and/or aluminum nitride.
  • the substrate 12 may be conductive to provide a “vertical” device having a “vertical” current flow through the epitaxial semiconductor structure 14 and the substrate 12 .
  • the substrate 12 may be insulating or semi-insulating where both ohmic contacts are provided on a same side of the substrate to provide a “horizontal” device.
  • a conductive substrate could also be used in a “horizontal” device.
  • the term substrate may be defined to include a non-patterned portion of the semiconductor material making up the semiconductor structure 14 , and/or there may not be a material transition between the substrate 12 and the semiconductor structure 14 .
  • Portions of the epitaxial semiconductor structure 14 may be patterned into a mesa stripe, for example, to provide optical and/or current confinement for a semiconductor laser device. As shown, only a portion of the epitaxial semiconductor structure 14 is included in the mesa 20 .
  • the epitaxial semiconductor structure 14 may include N-type and P-type layers and portions of one or both of the N-type and P-type layers may be included in the mesa 20 .
  • the epitaxial semiconductor structure 14 may include an N-type layer adjacent the substrate 12 and a P-type layer on the N-type layer opposite the substrate 12 .
  • the mesa may include portions of the P-type layer and none of the N-type layer.
  • the mesa may include all of the P-type layer and portions (but not all) of the N-type layer; or all of the P-type layer and all of the N-type layer (such that sidewalls of the mesa 20 extend to the substrate 12 ).
  • the semiconductor structure 14 may also include a junction between the N-type and P-type layers.
  • the junction for example, may be a structural junction defined as a physical location in the semiconductor structure 14 where P-type doping begins.
  • a structural junction and an actual electronic P-N junction may thus have different locations in the semiconductor structure 14 due to reactor effects, dopant incorporation rates, dopant activation rates, dopant diffusion, and/or other mechanisms.
  • the epitaxial semiconductor structure 14 may also include an active layer at the junction between the N-type layer and the P-type layer.
  • the active layer may include a number of different structures and/or layers and/or combinations thereof.
  • the active layer for example, may include single or multiple quantum wells, double heterostructures, and/or superlattices.
  • the active layer may also include light and/or current confinement layers that may encourage laser action in the device.
  • portions of the active layer may be included in the N-type layer and/or the P-type layer adjacent the junction therebetween. According to particular embodiments, the active layer may be included in the N-type layer adjacent the junction with the P-type layer.
  • a uniformly thick layer of epitaxial semiconductor material may be formed on the substrate 12 , and a layer of an ohmic contact material may be formed on the layer of the epitaxial semiconductor material.
  • the semiconductor mesa 20 and the ohmic contact layer 26 may be formed, for example, by selectively etching the layer of the contact material and the layer of the epitaxial semiconductor material using a same etch mask, using different etch masks, and/or using a lift-off technique. Methods of forming mesas, contact layers, and passivation layers are discussed, for example, in U.S. application Ser. No. ______ (Attorney Docket No. 5308-280), in U.S. application Ser. No. ______ (Attorney Docket No. 5308-281), and in U.S. application Ser. No. ______ (Attorney Docket No. 5308-282), the disclosures of which are hereby incorporated herein by reference.
  • Exposed portions of the epitaxial semiconductor material can be removed using a dry etch such as a Reactive Ion Etch (RIE), an Electron Cyclotron Resonance (ECR) plasma etch, and/or an Inductively Coupled Plasma (ICP) etch. More particularly, the epitaxial semiconductor layer can be etched using a dry etch in an Argon (Ar) environment with a chlorine (Cl 2 ) etchant.
  • RIE Reactive Ion Etch
  • ECR Electron Cyclotron Resonance
  • ICP Inductively Coupled Plasma
  • argon can flow at a rate in the range of approximately 2 to 40 sccm and chlorine can flow at a rate in the range of approximately 5 to 50 sccm in an RIE reactor at a pressure in the range of approximately 5 to 50 mTorr and at an RF power in the range of approximately 200 to 1000 W.
  • etch parameters are provided by way of example, and other etch parameters may be used.
  • thicknesses of the semiconductor base layer 19 and the semiconductor mesa 20 and a distance of a conductivity junction from the mesa base may be determined by an original thickness of the semiconductor layer from which the base layer and mesa are patterned, an original depth of the junction in the semiconductor layer, and a depth of an etch used to form the semiconductor mesa 20 .
  • the mesa etch depth (and resulting mesa thickness) may be in the range of approximately 0.1 to 5 microns, and according to additional embodiments may be no greater than approximately 2.5 microns.
  • a width of the mesa surface 20 A between mesa sidewalls 20 B may be in the range of approximately 1 to 3 microns, and a distance D substrate from the mesa base 20 C to the substrate can be in the range of approximately 0 to 4.9 microns.
  • the distance D substrate is also a measure of the thickness of the semiconductor base layer 19 .
  • the mesa surface 20 A may be a P-type semiconductor material.
  • the location of the junction in the semiconductor base layer 19 or the semiconductor mesa 20 can be determined by an original depth of the conductivity junction in the semiconductor layer from which the base layer and mesa are patterned. If the etch depth of the etch used to form the semiconductor mesa 20 is greater than a depth of the junction in the semiconductor layer, the junction can be in included in the resulting semiconductor mesa 20 . In an alternative, if the etch depth of the etch used to form the semiconductor mesa 20 is less than a depth of the junction in the semiconductor layer, the junction can be included in the semiconductor base layer 19 .
  • the semiconductor mesa 20 may be formed such that the structural junction between N-type and P-type layers is included in the semiconductor base layer 19 spaced from the mesa base 20 C by a distance of no more than approximately 0.4 microns, and more particularly, by a distance of no more than approximately 0.2 microns.
  • the structural junction in the semiconductor base layer 19 outside the semiconductor mesa 20 beam quality, stability, and/or voltage characteristics for a resulting semiconductor laser may be improved.
  • the semiconductor mesa 20 may be formed such that the structural junction between N-type and P-type layers is included in the semiconductor mesa 20 spaced from the mesa base 20 C by a distance of no more than approximately 5 microns, and more particularly, by a distance of no more than approximately 0.75 microns.
  • a resulting semiconductor laser may provide stronger guiding and/or improved operating current characteristics.
  • a semiconductor device may include a substrate 112 and an epitaxial semiconductor structure 114 including a semiconductor base layer 119 and a semiconductor mesa 120 on a portion of the base layer 119 .
  • the semiconductor mesa 120 may include a mesa surface 120 A opposite the base layer 119 , mesa sidewalls 120 B between the mesa surface 120 A and the base layer 119 , and a mesa base 120 C adjacent the base layer.
  • the device may also include a passivation layer 124 on the semiconductor base layer 119 and on portions of the semiconductor mesa 120 with portions of the mesa surface 120 A being free of the passivation layer 124 .
  • a first ohmic contact layer 126 may be provided on portions of the mesa surface 120 A free of the passivation layer, and a metal overlayer 128 may be provided on the passivation layer 124 and the ohmic contact layer 126 .
  • a second ohmic contact layer 127 may be provided on the substrate 112 opposite the semiconductor structure 114 to define an electrical current path through the mesa 120 , the semiconductor base layer 119 , and the substrate 112 .
  • a second ohmic contact layer may be provided on a same side of the substrate as the epitaxial semiconductor structure 114 so that current through the substrate 112 is not required.
  • the substrate 112 may include a substrate material such as N-type silicon carbide having a polytype such as 2H, 4H, 6H, 8H, 15R, and/or 3C; sapphire; gallium nitride; and/or aluminum nitride.
  • the substrate 112 may be conductive to provide a “vertical” device having a “vertical” current flow through the epitaxial semiconductor structure 114 and the substrate 112 .
  • the substrate 112 may be insulating or semi-insulating where both ohmic contacts are provided on a same side of the substrate to provide a “horizontal” device.
  • a conductive substrate could also be used in a “horizontal” device.
  • the term substrate may be defined to include a non-patterned portion of the semiconductor material making up the semiconductor structure 114 , and/or there may not be a material transition between the substrate 112 and the semiconductor structure 114 .
  • Portions of the epitaxial semiconductor structure 114 may be patterned into a mesa stripe, for example, to provide optical and/or current confinement for a semiconductor laser device. As shown, only a portion of the epitaxial semiconductor structure 114 is included in the mesa 120 , and the remainder of the epitaxial semiconductor structure 114 is included in the semiconductor base layer 119 . More particularly, the epitaxial semiconductor structure 114 may include an N-type layer 115 , all of which is included in the semiconductor base layer 119 adjacent the substrate 112 . The epitaxial semiconductor structure 114 may also include a P-type layer (including portions 117 ′ and 117 ′′) with a junction 122 between the N-type and P-type layers.
  • junction 122 may be a structural junction defined as a location where P-type doping begins.
  • a structural junction and an actual electronic P-N junction may thus have different locations in the semiconductor structure 114 due to reactor effects, dopant incorporation rates, dopant activation rates, dopant diffusion, and/or other mechanisms.
  • a first portion 117 ′ of the P-type layer is included in the semiconductor base layer 119
  • a second portion 117 ′′ of the P-type layer is included in the semiconductor mesa 120
  • a thickness of the first portion 117 ′ of the P-type layer is the same as the distance (labeled D′ junction ) from the mesa base 120 C to the junction 122 in the semiconductor base layer 119
  • the thickness of the second portion 117 ′′ of the P-type layer (labeled T′) is the same as the thickness of the semiconductor mesa 120
  • a distance D′ substrate between the mesa base 120 C and the substrate 112 is the same as a thickness of the semiconductor base layer 119
  • a thickness of the N-type layer 115 may be equal to a difference of D′ substrate minus D′ junction .
  • the semiconductor mesa 120 may be formed such that the junction 122 between N-type and P-type layers is included in the semiconductor base layer 119 spaced from the mesa base 120 C by a distance D′ junction of no more than approximately 0.4 microns, and more particularly, by a distance of no more than approximately 0.2 microns.
  • the junction 122 may be included in the semiconductor base layer 119 spaced from the mesa base 120 C by a distance D′ junction of at least approximately 0.05 microns, and more particularly, the junction 122 may be included in the semiconductor base layer 119 spaced from the mesa base 120 C by a distance D′ junction of at least approximately 0.1 microns.
  • the epitaxial semiconductor structure 114 may also include an active layer at the junction 122 between the N-type layer and the P-type layer.
  • the active layer may include a number of different structures and/or layers and/or combinations thereof.
  • the active layer for example, may include single or multiple quantum wells, double heterostructures, and/or superlattices.
  • the active layer may also include light and/or current confinement layers that may encourage laser action in the device.
  • portions of the active layer may he included in the N-type layer and/or the P-type layer adjacent the junction therebetween. According to particular embodiments, the active layer may be included in the N-type layer 115 adjacent the junction 122 with the P-type layer.
  • a uniformly thick layer of epitaxial semiconductor material may be formed on the substrate 112 , and a layer of an ohmic contact material may be formed on the layer of the epitaxial semiconductor material.
  • the semiconductor mesa 120 and the ohmic contact layer 126 may be formed, for example, by selectively etching the layer of the contact material and the layer of the epitaxial semiconductor material using a same etch mask, using different etch masks, and/or using a lift-off technique. Methods of forming mesas, contact layers, and passivation layers are discussed, for example, in U.S. application Ser. No. ______ (Attorney Docket No. 5308-280), in U.S. application Ser. No. ______ (Attorney Docket No. 5308-281), and in U.S. application Ser. No. ______ (Attorney Docket No. 5308-282), the disclosures of which are hereby incorporated herein by reference.
  • Exposed portions of the epitaxial semiconductor material can be removed using a dry etch such as a Reactive Ion Etch (RIE), an Electron Cyclotron Resonance (ECR) plasma etch, and/or an Inductively Coupled Plasma (ICP) etch. More particularly, the epitaxial semiconductor layer can be etched using a dry etch in an Argon (Ar) environment with a chlorine (Cl 2 ) etchant.
  • RIE Reactive Ion Etch
  • ECR Electron Cyclotron Resonance
  • ICP Inductively Coupled Plasma
  • argon can flow at a rate in the range of approximately 2 to 40 sccm and chlorine can flow at a rate in the range of approximately 5 to 50 sccm in an RIE reactor at a pressure in the range of approximately 5 to 50 mTorr and at an RF power in the range of approximately 200 to 1000 W.
  • etch parameters are provided by way of example, and other etch parameters may be used.
  • thicknesses of the semiconductor base layer 119 and the semiconductor mesa 120 and the distance D′ junction of the junction 112 from the mesa base 120 C may be determined by an original thickness of the semiconductor layer from which the base layer 119 and mesa 120 are patterned, an original depth of the conductivity junction 122 in the semiconductor layer, and a depth of an etch used to form the semiconductor mesa 120 .
  • the mesa etch depth (and resulting mesa thickness T′) may be in the range of approximately 0.1 to 5 microns, and according to additional embodiments may be no greater than approximately 2.5 microns.
  • a width of the mesa surface 120 A between mesa sidewalls 120 B may be in the range of approximately 1 to 3 microns, and a distance D substrate from the mesa base 120 C to the substrate can be in the range of approximately 0 to 4.9 microns.
  • the distance D substrate is also a measure of the thickness of the semiconductor base layer 119 .
  • the mesa surface 120 A may be a P-type semiconductor material.
  • the location of the junction 122 in the semiconductor base layer 119 can be determined by an original depth (T′+D′ junction ) of the junction in the semiconductor layer from which the base layer and mesa are patterned and an etch depth T′ used to form the mesa 120 .
  • the etch depth T′ of the etch used to form the semiconductor mesa 120 can be less than the depth of the junction in the semiconductor layer so that the junction 122 is included in the semiconductor base layer 119 .
  • a semiconductor device may include a substrate 212 and an epitaxial semiconductor structure 214 including a semiconductor base layer 219 and a semiconductor mesa 220 on a portion of the base layer 219 .
  • the semiconductor mesa 220 may include a mesa surface 220 A opposite the base layer 219 , mesa sidewalls 220 B between the mesa surface 220 A and the base layer 219 , and a mesa base 220 C adjacent the base layer.
  • the device may also include a passivation layer 224 on the semiconductor base layer 219 and on portions of the semiconductor mesa 220 with portions of the mesa surface 220 A being free of the passivation layer 224 .
  • a first ohmic contact layer 226 may be provided on portions of the mesa surface 220 A free of the passivation layer, and a metal overlayer 228 may be provided on the passivation layer 224 and the ohmic contact layer 226 .
  • a second ohmic contact layer 227 may be provided on the substrate 212 opposite the semiconductor structure 214 to define an electrical current path through the mesa 220 , the semiconductor base layer 219 , and the substrate 212 .
  • a second ohmic contact layer may be provide on a same side of the substrate as the epitaxial semiconductor structure 214 so that current through the substrate 212 is not required.
  • the substrate 212 may include a substrate material such as N-type silicon carbide having a polytype such as 2H, 4H, 6H, 8H, 15R, and/or 3C; sapphire; gallium nitride; and/or aluminum nitride.
  • the substrate 212 may be conductive to provide a “vertical” device having a “vertical” current flow through the epitaxial semiconductor structure 214 and the substrate 212 .
  • the substrate 212 may be insulating or semi-insulating where both ohmic contacts are provided on a same side of the substrate to provide a “horizontal” device.
  • a conductive substrate could also be used in a “horizontal” device.
  • the term substrate may be defined to include a non-patterned portion of the semiconductor material making up the semiconductor structure 214 , and/or there may not be a material transition between the substrate 212 and the semiconductor structure 214 .
  • Portions of the epitaxial semiconductor structure 214 may be patterned into a mesa stripe, for example, to provide optical and/or current confinement for a semiconductor laser device. As shown, only a portion of the epitaxial semiconductor structure 214 is included in the mesa 220 , and the remainder of the epitaxial semiconductor structure 214 is included in the semiconductor base layer 219 . More particularly, the epitaxial semiconductor structure 214 may include a P-type layer 217 , all of which is included in the semiconductor mesa 220 adjacent the mesa surface 220 A. The epitaxial semiconductor structure 214 may also include an N-type layer (including portions 215 ′ and 215 ′′) with a junction 222 between the P-type layer and the N-type layer.
  • the junction 222 may be a structural junction defined as a location where P-type doping begins.
  • a structural junction and an actual electronic P-N junction may thus have different locations in the semiconductor structure 114 due to reactor effects, dopant incorporation rates, dopant activation rates, dopant diffusion, and/or other mechanisms.
  • a first portion 215 ′ of the N-type layer is included in the semiconductor base layer 219
  • a second portion 215 ′′ of the N-type layer is included in the semiconductor mesa 220
  • a thickness of the first portion 215 ′ of the N-type layer is the same as the distance (labeled D′′ substrate ) from the mesa base 220 C to the substrate 212
  • the thickness of the second portion 215 ′′ of the N-type layer (labeled D′′ junction ) is the same as the distance from the mesa base 220 C to the junction between the N-type and P-type layers.
  • the thickness of the semiconductor mesa is labeled T′′.
  • a thickness of the P-type layer 217 may be equal to a difference of the mesa thickness T′′ minus D′′ junction .
  • the semiconductor mesa 220 may be formed such that the junction 222 between N-type and P-type layers is included in the mesa 220 spaced apart from the mesa base 220 C by a distance D′′junction of no more than approximately 5 microns, and more particularly, by a distance of no more than approximately 0.75 microns.
  • the junction 222 may be included in the semiconductor mesa 220 spaced from the mesa base 220 C by a distance D′′ junction of at least approximately 0.05 microns, and more particularly, the junction 222 may be included in the semiconductor mesa 220 spaced from the mesa base 220 C by a distance D′′ junction of at least approximately 0.1 microns.
  • the epitaxial semiconductor structure 214 may also include an active layer at the junction between the N-type layer and the P-type layer.
  • the active layer may include a number of different structures and/or layers and/or combinations thereof.
  • the active layer for example, may include single or multiple quantum wells, double heterostructures, and/or superlattices.
  • the active layer may also include light and/or current confinement layers that may encourage laser action in the device.
  • portions of the active layer may be included in the N-type layer and/or the P-type layer adjacent the junction therebetween. According to particular embodiments, the active layer may be included in the second portion 215 ′′ of the N-type layer adjacent the junction 222 with the P-type layer 217 .
  • a uniformly thick layer of epitaxial semiconductor material may be formed on the substrate 212 , and a layer of an ohmic contact material may be formed on the layer of the epitaxial semiconductor material.
  • the semiconductor mesa 220 and the ohmic contact layer 226 may be formed, for example, by selectively etching the layer of the contact material and the layer of the epitaxial semiconductor material using a same etch mask, using different etch masks, and/or using a lift-off technique. Methods of forming mesas, contact layers, and passivation layers are discussed, for example, in U.S. application Ser. No. ______ (Attorney Docket No. 5308-280), in U.S. application Ser. No. ______ (Attorney Docket No. 5308-281), and in U.S. application Ser. No. ______ (Attorney Docket No. 5308-282), the disclosures of which are hereby incorporated herein by reference.
  • Exposed portions of the epitaxial semiconductor material can be removed using a dry etch such as a Reactive Ion Etch (RIE), an Electron Cyclotron Resonance (ECR) plasma etch, and/or an Inductively Coupled Plasma (ICP) etch. More particularly, the epitaxial semiconductor layer can be etched using a dry etch in an Argon (Ar) environment with a chlorine (Cl 2 ) etchant.
  • RIE Reactive Ion Etch
  • ECR Electron Cyclotron Resonance
  • ICP Inductively Coupled Plasma
  • argon can flow at a rate in the range of approximately 2 to 40 sccm and chlorine can flow at a rate in the range of approximately 5 to 50 sccm in an RIE reactor at a pressure in the range of approximately 5 to 50 mTorr and at an RF power in the range of approximately 200 to 1000 W.
  • etch parameters are provided by way of example, and other etch parameters may be used.
  • thicknesses of the semiconductor base layer 219 and the semiconductor mesa 220 and a distance D′′ junction of a junction from the mesa base 220 C may be determined by an original thickness of the semiconductor layer from which the base layer 219 and mesa 220 are patterned, an original depth of the junction in the semiconductor layer, and a depth of an etch used to form the semiconductor mesa 220 .
  • the mesa etch depth (and resulting mesa thickness T′′) may be in the range of approximately 0.1 to 5 microns, and according to additional embodiments may be no greater than approximately 2.5 microns.
  • a width of the mesa surface 220 A between mesa sidewalls 220 B may be in the range of approximately 1 to 3 microns, and a distance D substrate from the mesa base 220 C to the substrate can be in the range of approximately 0 to 4.9 microns.
  • the distance D substrate is also a measure of the thickness of the semiconductor base layer 219 .
  • the mesa surface 220 A may be a P-type semiconductor material.
  • the location of the junction 222 in the semiconductor mesa 220 can be determined by an original depth (T′′ ⁇ D′′ junction ) of the junction in the semiconductor layer from which the base layer 219 and mesa 220 are patterned and an etch depth used to form the mesa 220 .
  • the etch depth T′′ of the etch used to form the semiconductor mesa 220 can be greater than a depth of the junction in the semiconductor layer so that the junction can be included in the semiconductor base layer 219 .
  • the resulting semiconductor devices may provide edge emitting semiconductor lasers with light being emitted parallel to the substrate along a lengthwise direction of a semiconductor mesa stripe. Stated in other words, the light may be emitted along a direction perpendicular to the cross section of the Figures discussed above. While methods and devices have been discussed with reference to methods of forming light emitting devices such as laser diodes, methods according to embodiments of the present invention may be used to form other semiconductor devices such as conventional diodes, conventional light emitting diodes, or any other semiconductor device including a semiconductor mesa.

Abstract

An electronic device may include a substrate and a semiconductor mesa on the substrate. More particularly, the semiconductor mesa may have a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base. In addition, the semiconductor mesa may have a first conductivity type between the mesa base and a junction, the junction may be between the mesa base and the mesa surface, and the semiconductor mesa may have a second conductivity type between the junction and the mesa surface. Related methods are also discussed.

Description

    RELATED APPLICATIONS
  • The present application claims the benefit of, U.S. Provisional Application No. 60/435,213 filed Dec. 20, 2002, and entitled “Laser Diode With Self-Aligned Index Guide And Via”; U.S. Provisional Application No. 60/434,914 filed Dec. 20, 2002, and entitled “Laser Diode With Surface Depressed Ridge Waveguide”; U.S. Provisional Application No. 60/434,999 filed Dec. 20, 2002 and entitled “Laser Diode with Etched Mesa Structure”; and U.S. Provisional Application No. 60/435,211 filed Dec. 20, 2002, and entitled “Laser Diode With Metal Current Spreading Layer.” The disclosures of each of these provisional applications are hereby incorporated herein in their entirety by reference. [0001]
  • The present application is also related to: U.S. Application No. ______ (Attorney Docket No. 5308-281) entitled “Methods Of Forming Semiconductor Devices Having Self Aligned Semiconductor Mesas and Contact Layers And Related Devices” filed concurrently herewith; U.S. Application No. ______ (Attorney Docket No. 5308-282) entitled “Methods Of Forming Semiconductor Devices Including Mesa Structures And Multiple Passivation Layers And Related Devices” filed concurrently herewith; and U.S. Application No. ______ (Attorney Docket No. 5308-280) entitled “Methods Of Forming Semiconductor Mesa Structures Including Self-Aligned Contact Layers And Related Devices” filed concurrently herewith. The disclosures of each of these U.S. Applications are hereby incorporated herein in their entirety by reference.[0002]
  • FIELD OF THE INVENTION
  • The present invention relates to the field of electronics, and more particularly, to methods of forming electronic. semiconductor devices and related structures. [0003]
  • BACKGROUND OF THE INVENTION
  • A laser is a device that produces a beam of coherent monochromatic light as a result of stimulated emission of photons. Stimulated emission of photons may also produce optical gain, which may cause light beams produced by lasers to have a high optical energy. A number of materials are capable of producing the lasing effect and include certain high-purity crystals (ruby is a common example), semiconductors, certain types of glass, certain gases including carbon dioxide, helium, argon and neon, and certain plasmas. [0004]
  • More recently, lasers have been developed in semiconducting materials, thus taking advantage of the smaller size, lower cost and other related advantages typically associated with semiconductor devices. In the semiconductor arts, devices in which photons play a major role are referred to as “photonic” or “optoelectronic” devices. In turn, photonic devices include light-emitting diodes (LEDs), photodetectors, photovoltaic devices, and semiconductor lasers. [0005]
  • Semiconductor lasers are similar to other lasers in that the emitted radiation has spatial and temporal coherence. As noted above, laser radiation is highly monochromatic (i.e., of narrow band width) and it produces highly directional beams of light. Semiconductor lasers may differ, however, from other lasers in several respects. For example, in semiconductor lasers, the quantum transitions are associated with the band properties of materials; semiconductor lasers may be very compact in size, may have very narrow active regions, and larger divergence of the laser beam; the characteristics of a semiconductor laser may be strongly influenced by the properties of the junction medium; and for P-N junction lasers, the lasing action is produced by passing a forward current through the diode itself. Overall, semiconductor lasers can provide very efficient systems that may be controlled by modulating the current directed across the devices. Additionally, because semiconductor lasers can have very short photon lifetimes, they may be used to produce high-frequency modulation. In turn, the compact size and capability for such high-frequency modulation may make semiconductor lasers an important light source for optical fiber communications. [0006]
  • In broad terms, the structure of a semiconductor laser should provide optical confinement to create a resonant cavity in which light amplification may occur, and electrical confinement to produce high current densities to cause stimulated emission to occur. Additionally, to produce the laser effect (stimulated emission of radiation), the semiconductor may be a direct bandgap material rather than an indirect bandgap material. As known to those familiar with semiconductor characteristics, a direct bandgap material is one in which an electron's transition from the valence band to the conduction band does not require a change in crystal momentum for the electron. Gallium arsenide and gallium nitride are examples of direct bandgap semiconductors. In indirect bandgap semiconductors, the alternative situation exists; i.e., a change of crystal momentum is required for an electron's transition between the valence and conduction bands. Silicon and silicon carbide are examples of such indirect semiconductors. [0007]
  • A useful explanation of the theory, structure and operation of semiconductor lasers, including optical and electronic confinement and mirroring, is given by Sze, Physics of Semiconductor Devices, 2nd Edition (1981) at pages 704-742, and these pages are incorporated entirely herein by reference. [0008]
  • As known to those familiar with photonic devices such as LEDs and lasers, the frequency of electromagnetic radiation (i.e., the photons) that can be produced by a given semiconductor material may be a function of the material's bandgap. Smaller bandgaps produce lower energy, longer wavelength photons, while wider bandgap materials produce higher energy, shorter wavelength photons. For example, one semiconductor commonly used for lasers is aluminum indium gallium phosphide (AlInGaP). Because of this material's bandgap (actually a range of bandgaps depending upon the mole or atomic fraction of each element present), the light that AlInGaP can produce may be limited to the red portion of the visible spectrum, i.e., about 600 to 700 nanometers (nm). In order to produce photons that have wavelengths in the blue or ultraviolet portions of the spectrum, semiconductor materials having relatively large bandgaps may be used. Group III-nitride materials such as gallium nitride (GaN), the ternary alloys indium gallium nitride (InGaN), aluminum gallium nitride (AlGaN) and aluminum indium nitride (AlInN) as well as the quaternary alloy aluminum gallium indium nitride (AlInGaN) are attractive candidate materials for blue and UV lasers because of their relatively high bandgap (3.36 eV at room temperature for GaN). Accordingly, Group III-nitride based laser diodes have been demonstrated that emit light in the 370-420 nm range. [0009]
  • A number of commonly assigned patents and co-pending patent applications likewise discuss the design and manufacture of optoelectronic devices. For example, U.S. Pat. Nos. 6,459,100; 6,373,077; 6,201,262; 6,187,606; 5,912,477; and 5,416,342 describe various methods and structures for gallium-nitride based optoelectronic devices. U.S. Pat. No. 5,838,706 describes low-strain nitride laser diode structures. Published U.S. application Ser. Nos. 20020093020 and 20020022290 describe epitaxial structures for nitride-based optoelectronic devices. Various metal contact structures and bonding methods, including flip-chip bonding methods, are described in Published U.S. application Ser. No. 20020123164 as well as Published U.S. application Ser. No. 030045015 entitled “Flip Chip Bonding of Light Emitting Devices and Light Emitting Devices Suitable for Flip-Chip Bonding”; Published U.S. application Ser. No. 20030042507 entitled “Bonding of Light Emitting Diodes Having Shaped Substrates and Collets for Bonding of Light Emitting Diodes Having Shaped Substrates”, and Published U.S. application Ser. No. 20030015721 entitled “Light Emitting Diodes Including Modifications for Submount Bonding and Manufacturing Methods Therefor.” Dry etching methods are described in U.S. Pat. No. 6,475,889. Passivation methods for nitride optoelectronic devices are described in U.S. application Ser. No. 08/920,409 entitled “Robust Group III Light Emitting Diode for High Reliability in Standard Packaging Applications” and Published U.S. application Ser. No. 20030025121 entitled “Robust Group III Light Emitting Diode for High Reliability in Standard Packaging Applications.” Active layer structures suitable for use in nitride laser diodes are described in Published U.S. application Ser. No. 20030006418 entitled “Group III Nitride Based Light Emitting Diode Structures with a Quantum Well and Superlattice, Group III Nitride Based Quantum Well Structures and Group III Nitride Based Superlattice Structures” and Published U.S. application Ser. No. 20030020061 entitled “Ultraviolet Light Emitting Diode.” The contents of all of the foregoing patents, patent applications and published patent applications are incorporated entirely herein by reference as if fully set forth herein. [0010]
  • Not withstanding the structures and methods discussed above, further structures and/or methods providing improved beam quality, stability, voltage characteristics, guiding, and/or operating current characteristics may be desired. [0011]
  • SUMMARY
  • According to embodiments of the present invention, a light emitting device may include a silicon carbide substrate, and a semiconductor structure on the substrate. More particularly, the semiconductor structure may include a mesa having a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base. In addition, the semiconductor structure may have a first conductivity type adjacent the silicon carbide substrate, the semiconductor structure may have a second conductivity type adjacent the mesa surface, and the semiconductor structure may have a junction between the first and second conductivity types. Moreover, the mesa may be configured to provide at least one of current confinement or optical confinement for a light emitting device in the semiconductor structure. [0012]
  • In one alternative, the junction may be between the mesa base and the mesa surface. In another alternative, the semiconductor structure may include a semiconductor base layer between the mesa base and the silicon carbide substrate and the junction may be between a surface of the base layer opposite the silicon carbide substrate and the silicon carbide substrate. Moreover, the semiconductor structure may include a Group III-V semiconductor material. [0013]
  • According to more embodiments of the present invention, an electronic device may include a substrate and a semiconductor mesa on the substrate. More particularly, the semiconductor mesa may have a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base. Moreover, the semiconductor mesa may have a first conductivity type between the mesa base and a junction, the junction may be between the mesa base and the mesa surface, and the semiconductor mesa may have a second conductivity type between the junction and the mesa surface. [0014]
  • The junction may comprise a physical location where doping of the second conductivity type begins, the first conductivity type may be N-type, and the second conductivity type may be P-type. The semiconductor mesa may comprise a Group III-V semiconductor material such as a Group III-nitride semiconductor material. [0015]
  • In addition, the junction may be no more that approximately 5 microns from the mesa base, and more particularly, the junction may be no more than approximately 0.75 microns from the mesa base. Moreover, the junction may be at least approximately 0.05 microns from the mesa base, and more particularly, the junction may be at least approximately 0.1 microns from the mesa base. The semiconductor mesa may have a thickness in the range of approximately 0.1 microns to 5 microns. [0016]
  • A semiconductor base layer may be included between the substrate and the semiconductor mesa, and the semiconductor base layer may have the first conductivity type throughout. More particularly, the semiconductor base layer may have a thickness no greater than approximately 5 microns, and each of the semiconductor base layer and the semiconductor mesa may comprise a Group III-V semiconductor material. In addition, the substrate may comprise silicon carbide. [0017]
  • According to additional embodiments of the present invention, an electronic device may include a substrate, a semiconductor base layer on the substrate, and a semiconductor mesa on a surface of the base layer opposite the substrate. The semiconductor base layer may have a first conductivity type between the substrate and a junction, the junction may be between the substrate and a surface of the base layer opposite the substrate, and the semiconductor base layer may have a second. conductivity type between the junction and the surface of the base layer opposite the substrate. The semiconductor mesa may have a mesa surface opposite the semiconductor base layer and mesa sidewalls between the mesa surface and the base layer, and the semiconductor mesa may have the second conductivity type throughout. [0018]
  • The junction may be a physical location where doping of the second conductivity type begins, the first conductivity type may be N-type, and the second conductivity type may be P-type. Each of the semiconductor mesa and the semiconductor base layer may comprise a Group III-V semiconductor material such as a Group III-nitride semiconductor material. [0019]
  • The junction may be no more that approximately 0.4 microns from the surface of the base layer opposite the substrate, and more particularly, the junction may be no more than approximately 0.2 microns from the surface of the base layer opposite the substrate. In addition, the junction may be at least approximately 0.05 microns from the surface of the base layer opposite the substrate, and more particularly, the junction may be at least approximately 0.1 microns from the surface of the base layer opposite the substrate. Moreover, the semiconductor mesa may have a thickness in the range of approximately 0.1 microns to 5 microns, the semiconductor base layer may have a thickness no greater than approximately 5 microns. In addition, the substrate may comprise silicon carbide. [0020]
  • According to still additional embodiments of the present invention, methods of forming an electronic device may include forming a semiconductor mesa on a substrate. The semiconductor mesa may have a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base. Moreover, the semiconductor mesa may have a first conductivity type between the mesa base and a junction, the junction may be between the mesa base and the mesa surface, and the semiconductor mesa may have a second conductivity type between the junction and the mesa surface. [0021]
  • The junction may comprise a physical location where doping of the second conductivity type begins, the first conductivity type may be N-type, and the second conductivity type may be P-type. The semiconductor mesa may comprise a Group III-V semiconductor material such as a Group III-nitride semiconductor material. [0022]
  • The junction may be no more that approximately 5 microns from the mesa base, and more particularly, the junction may be no more than approximately 0.75 microns from the mesa base. In addition, the junction may be at least approximately 0.05 microns from the mesa base, and more particularly, the junction may be at least approximately 0.1 microns from the mesa base. The semiconductor mesa may have a thickness in the range of approximately 0.1 microns to 5 microns. [0023]
  • In addition, a semiconductor base layer may be formed between the substrate and the semiconductor mesa, and the semiconductor base layer may have the first conductivity type throughout. More particularly, forming the semiconductor mesa and forming the semiconductor base layer may include forming a layer of a semiconductor material on the substrate, forming a mask on the layer of the semiconductor material, and etching portions of layer of the semiconductor material exposed by the mask wherein a depth of etching defines a thickness of the mesa. The layer of the semiconductor material may also include a junction at a junction depth and wherein the depth of etching of the layer of the semiconductor material is greater than the junction depth. [0024]
  • The semiconductor base layer may have a thickness no greater than approximately 5 microns, and each of the semiconductor base layer and the semiconductor mesa may comprise a Group III-V semiconductor material. The substrate may comprise silicon carbide. [0025]
  • According to yet additional embodiments of the present invention, methods of forming an electronic devices may include forming a semiconductor base layer on a substrate, and forming a semiconductor mesa of a surface of the base layer opposite the substrate. The semiconductor base layer may have a first conductivity type between the substrate and a junction, the junction may be between the substrate and a surface of the base layer opposite the substrate, and the semiconductor base layer may have a second conductivity type between the junction and the surface of the base layer opposite the substrate. The semiconductor mesa may have a mesa surface opposite the semiconductor base layer and mesa sidewalls between the mesa surface and the base layer, wherein the semiconductor mesa has the second conductivity type throughout. [0026]
  • The junction may include a physical location where doping of the second conductivity type begins, the first conductivity type may be N-type, and the second conductivity type may be P-type. Each of the semiconductor mesa and the semiconductor base layer may comprises a Group III-V semiconductor material such as a Group III-nitride semiconductor material. In addition, the junction is no more that approximately 0.4 microns from the surface of the base layer opposite the substrate, and more particularly, the junction may be no more than approximately 0.2 microns from the surface of the base layer opposite the substrate. [0027]
  • The junction may be at least approximately 0.05 microns from the surface of the base layer opposite the substrate, and more particularly, the junction may be at least approximately 0.1 microns from the surface of the base layer opposite the substrate. The semiconductor mesa may have a thickness in the range of approximately 0.1 microns to 5 microns. The semiconductor base layer may have a thickness no greater than approximately 5 microns, and the substrate may comprise silicon carbide. [0028]
  • In addition, forming the semiconductor mesa and forming the semiconductor base layer may include forming a layer of a semiconductor material on the substrate, forming a mask on the layer of the semiconductor material, and etching portions of layer of the semiconductor material exposed by the mask wherein a depth of etching defines a thickness of the mesa. More particularly, the semiconductor material may include a junction at a junction depth and wherein the depth of etching of the layer of the semiconductor material may be less than the junction depth.[0029]
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a cross-sectional view illustrating semiconductor devices according to embodiments of the present invention. [0030]
  • FIG. 2 is a cross-sectional view illustrating semiconductor devices according to additional embodiments of the present invention. [0031]
  • FIG. 3 is a cross-sectional view illustrating semiconductor devices according to still additional embodiments of the present invention. [0032]
  • DETAILED DESCRIPTION
  • The present invention will now be described more fully hereinafter with reference to the accompanying drawings, in which preferred embodiments of the invention are shown. The invention may, however, be embodied in different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. In the drawings, the thickness of layers and regions are exaggerated for clarity. It will also be understood that when a layer is referred to as being “on” another layer or substrate, it can be directly on the other layer or substrate, or intervening layers may also be present. It will also be understood that when an element is referred to as being “coupled” or “connected” to another element, it can be directly coupled or connected to the other element, or intervening elements may also be present. Like numbers refer to like elements throughout. Furthermore, relative terms such as “vertical” and “horizontal” may be used herein to describe a relationship with respect to a substrate or base layer as illustrated in the figures. It will be understood that these terms are intended to encompass different orientations of the device in addition to the orientation depicted in the figures. [0033]
  • As shown in the cross-section of FIG. 1, a semiconductor device according to embodiments of the present invention may include a [0034] substrate 12 and an epitaxial semiconductor structure 14 including a semiconductor base layer 19 and a semiconductor mesa 20 on a portion of the base layer 19. More particularly, the semiconductor mesa 20 may include a mesa surface 20A opposite the base layer 19, mesa sidewalls 20B between the mesa surface 20A and the base layer 19, and a mesa base 20C adjacent the base layer. While a dashed line is shown between the semiconductor mesa 20 and the semiconductor base layer 19 for purposes of illustration, it will be understood that adjacent portions of the semiconductor base layer 19 and the semiconductor mesa 20 may comprise a same semiconductor material with no physical barrier, junction, or discontinuity between the two.
  • The device may also include a [0035] passivation layer 24 on the semiconductor base layer 19 and on portions of the semiconductor mesa 20 with portions of the mesa surface 20A being free of the passivation layer 24. Moreover, a first ohmic contact layer 26 may be provided on portions of the mesa surface 20A free of the passivation layer, and a metal overlayer 28 may be provided on the passivation layer 24 and the ohmic contact layer 26. In addition, a second ohmic contact layer 27 may be provided on the substrate 12 opposite the semiconductor structure 14 to define an electrical current path through the mesa 20, the semiconductor base layer 19, and the substrate 12. In an alternative, a second ohmic contact layer may be provided on a same side of the substrate as the epitaxial semiconductor structure 14 so that current through the substrate 12 is not required.
  • In some embodiments, the [0036] substrate 12 may included substrate material such as N-type silicon carbide having a polytype such as 2H, 4H, 6H, 8H, 15R, and/or 3C; sapphire; gallium nitride; and/or aluminum nitride. Moreover, the substrate 12 may be conductive to provide a “vertical” device having a “vertical” current flow through the epitaxial semiconductor structure 14 and the substrate 12. In an alternative, the substrate 12 may be insulating or semi-insulating where both ohmic contacts are provided on a same side of the substrate to provide a “horizontal” device. A conductive substrate could also be used in a “horizontal” device. Moreover, the term substrate may be defined to include a non-patterned portion of the semiconductor material making up the semiconductor structure 14, and/or there may not be a material transition between the substrate 12 and the semiconductor structure 14.
  • Portions of the [0037] epitaxial semiconductor structure 14 may be patterned into a mesa stripe, for example, to provide optical and/or current confinement for a semiconductor laser device. As shown, only a portion of the epitaxial semiconductor structure 14 is included in the mesa 20. For example, the epitaxial semiconductor structure 14 may include N-type and P-type layers and portions of one or both of the N-type and P-type layers may be included in the mesa 20. According to particular embodiments, the epitaxial semiconductor structure 14 may include an N-type layer adjacent the substrate 12 and a P-type layer on the N-type layer opposite the substrate 12. The mesa may include portions of the P-type layer and none of the N-type layer. In alternatives, the mesa may include all of the P-type layer and portions (but not all) of the N-type layer; or all of the P-type layer and all of the N-type layer (such that sidewalls of the mesa 20 extend to the substrate 12).
  • The [0038] semiconductor structure 14 may also include a junction between the N-type and P-type layers. The junction, for example, may be a structural junction defined as a physical location in the semiconductor structure 14 where P-type doping begins. A structural junction and an actual electronic P-N junction may thus have different locations in the semiconductor structure 14 due to reactor effects, dopant incorporation rates, dopant activation rates, dopant diffusion, and/or other mechanisms.
  • The [0039] epitaxial semiconductor structure 14 may also include an active layer at the junction between the N-type layer and the P-type layer. The active layer may include a number of different structures and/or layers and/or combinations thereof. The active layer, for example, may include single or multiple quantum wells, double heterostructures, and/or superlattices. The active layer may also include light and/or current confinement layers that may encourage laser action in the device. Moreover, portions of the active layer may be included in the N-type layer and/or the P-type layer adjacent the junction therebetween. According to particular embodiments, the active layer may be included in the N-type layer adjacent the junction with the P-type layer.
  • By way of example, a uniformly thick layer of epitaxial semiconductor material may be formed on the [0040] substrate 12, and a layer of an ohmic contact material may be formed on the layer of the epitaxial semiconductor material. The semiconductor mesa 20 and the ohmic contact layer 26 may be formed, for example, by selectively etching the layer of the contact material and the layer of the epitaxial semiconductor material using a same etch mask, using different etch masks, and/or using a lift-off technique. Methods of forming mesas, contact layers, and passivation layers are discussed, for example, in U.S. application Ser. No. ______ (Attorney Docket No. 5308-280), in U.S. application Ser. No. ______ (Attorney Docket No. 5308-281), and in U.S. application Ser. No. ______ (Attorney Docket No. 5308-282), the disclosures of which are hereby incorporated herein by reference.
  • Exposed portions of the epitaxial semiconductor material can be removed using a dry etch such as a Reactive Ion Etch (RIE), an Electron Cyclotron Resonance (ECR) plasma etch, and/or an Inductively Coupled Plasma (ICP) etch. More particularly, the epitaxial semiconductor layer can be etched using a dry etch in an Argon (Ar) environment with a chlorine (Cl[0041] 2) etchant. For example, argon can flow at a rate in the range of approximately 2 to 40 sccm and chlorine can flow at a rate in the range of approximately 5 to 50 sccm in an RIE reactor at a pressure in the range of approximately 5 to 50 mTorr and at an RF power in the range of approximately 200 to 1000 W. These etch parameters are provided by way of example, and other etch parameters may be used.
  • Moreover, thicknesses of the [0042] semiconductor base layer 19 and the semiconductor mesa 20 and a distance of a conductivity junction from the mesa base may be determined by an original thickness of the semiconductor layer from which the base layer and mesa are patterned, an original depth of the junction in the semiconductor layer, and a depth of an etch used to form the semiconductor mesa 20. According to embodiments of the present invention, the mesa etch depth (and resulting mesa thickness) may be in the range of approximately 0.1 to 5 microns, and according to additional embodiments may be no greater than approximately 2.5 microns. In addition, a width of the mesa surface 20A between mesa sidewalls 20B may be in the range of approximately 1 to 3 microns, and a distance Dsubstrate from the mesa base 20C to the substrate can be in the range of approximately 0 to 4.9 microns. The distance Dsubstrate is also a measure of the thickness of the semiconductor base layer 19. In addition, the mesa surface 20A may be a P-type semiconductor material.
  • The location of the junction in the [0043] semiconductor base layer 19 or the semiconductor mesa 20 can be determined by an original depth of the conductivity junction in the semiconductor layer from which the base layer and mesa are patterned. If the etch depth of the etch used to form the semiconductor mesa 20 is greater than a depth of the junction in the semiconductor layer, the junction can be in included in the resulting semiconductor mesa 20. In an alternative, if the etch depth of the etch used to form the semiconductor mesa 20 is less than a depth of the junction in the semiconductor layer, the junction can be included in the semiconductor base layer 19.
  • According to particular embodiments, the [0044] semiconductor mesa 20 may be formed such that the structural junction between N-type and P-type layers is included in the semiconductor base layer 19 spaced from the mesa base 20C by a distance of no more than approximately 0.4 microns, and more particularly, by a distance of no more than approximately 0.2 microns. By providing the structural junction in the semiconductor base layer 19 outside the semiconductor mesa 20, beam quality, stability, and/or voltage characteristics for a resulting semiconductor laser may be improved.
  • In an alternative, the [0045] semiconductor mesa 20 may be formed such that the structural junction between N-type and P-type layers is included in the semiconductor mesa 20 spaced from the mesa base 20C by a distance of no more than approximately 5 microns, and more particularly, by a distance of no more than approximately 0.75 microns. By providing the structural junction in the semiconductor mesa 20, a resulting semiconductor laser may provide stronger guiding and/or improved operating current characteristics.
  • A semiconductor device according to particular embodiments of the present invention is illustrated in FIG. 2. As shown in FIG. 2, a semiconductor device may include a [0046] substrate 112 and an epitaxial semiconductor structure 114 including a semiconductor base layer 119 and a semiconductor mesa 120 on a portion of the base layer 119. More particularly, the semiconductor mesa 120 may include a mesa surface 120A opposite the base layer 119, mesa sidewalls 120B between the mesa surface 120A and the base layer 119, and a mesa base 120C adjacent the base layer. While a dashed line is shown between the semiconductor mesa 120 and the semiconductor base layer 119 for purposes of illustration, it will be understood that adjacent portions of the semiconductor base layer 119 and the semiconductor mesa 120 may comprise a same semiconductor material with no physical barrier, junction, or discontinuity between the two.
  • The device may also include a [0047] passivation layer 124 on the semiconductor base layer 119 and on portions of the semiconductor mesa 120 with portions of the mesa surface 120A being free of the passivation layer 124. Moreover, a first ohmic contact layer 126 may be provided on portions of the mesa surface 120A free of the passivation layer, and a metal overlayer 128 may be provided on the passivation layer 124 and the ohmic contact layer 126. In addition, a second ohmic contact layer 127 may be provided on the substrate 112 opposite the semiconductor structure 114 to define an electrical current path through the mesa 120, the semiconductor base layer 119, and the substrate 112. In an alternative, a second ohmic contact layer may be provided on a same side of the substrate as the epitaxial semiconductor structure 114 so that current through the substrate 112 is not required.
  • In some embodiments, the [0048] substrate 112 may include a substrate material such as N-type silicon carbide having a polytype such as 2H, 4H, 6H, 8H, 15R, and/or 3C; sapphire; gallium nitride; and/or aluminum nitride. Moreover, the substrate 112 may be conductive to provide a “vertical” device having a “vertical” current flow through the epitaxial semiconductor structure 114 and the substrate 112. In an alternative, the substrate 112 may be insulating or semi-insulating where both ohmic contacts are provided on a same side of the substrate to provide a “horizontal” device. A conductive substrate could also be used in a “horizontal” device. Moreover, the term substrate may be defined to include a non-patterned portion of the semiconductor material making up the semiconductor structure 114, and/or there may not be a material transition between the substrate 112 and the semiconductor structure 114.
  • Portions of the [0049] epitaxial semiconductor structure 114 may be patterned into a mesa stripe, for example, to provide optical and/or current confinement for a semiconductor laser device. As shown, only a portion of the epitaxial semiconductor structure 114 is included in the mesa 120, and the remainder of the epitaxial semiconductor structure 114 is included in the semiconductor base layer 119. More particularly, the epitaxial semiconductor structure 114 may include an N-type layer 115, all of which is included in the semiconductor base layer 119 adjacent the substrate 112. The epitaxial semiconductor structure 114 may also include a P-type layer (including portions 117′ and 117″) with a junction 122 between the N-type and P-type layers. As discussed above, the junction 122 may be a structural junction defined as a location where P-type doping begins. A structural junction and an actual electronic P-N junction may thus have different locations in the semiconductor structure 114 due to reactor effects, dopant incorporation rates, dopant activation rates, dopant diffusion, and/or other mechanisms.
  • As shown in FIG. 2, a [0050] first portion 117′ of the P-type layer is included in the semiconductor base layer 119, and a second portion 117″ of the P-type layer is included in the semiconductor mesa 120. A thickness of the first portion 117′ of the P-type layer is the same as the distance (labeled D′junction) from the mesa base 120C to the junction 122 in the semiconductor base layer 119, and the thickness of the second portion 117″ of the P-type layer (labeled T′) is the same as the thickness of the semiconductor mesa 120. In addition, a distance D′substrate between the mesa base 120C and the substrate 112 is the same as a thickness of the semiconductor base layer 119. Accordingly, a thickness of the N-type layer 115 may be equal to a difference of D′substrate minus D′junction.
  • According to particular embodiments, the [0051] semiconductor mesa 120 may be formed such that the junction 122 between N-type and P-type layers is included in the semiconductor base layer 119 spaced from the mesa base 120C by a distance D′junction of no more than approximately 0.4 microns, and more particularly, by a distance of no more than approximately 0.2 microns. In addition, the junction 122 may be included in the semiconductor base layer 119 spaced from the mesa base 120C by a distance D′junction of at least approximately 0.05 microns, and more particularly, the junction 122 may be included in the semiconductor base layer 119 spaced from the mesa base 120C by a distance D′junction of at least approximately 0.1 microns. By providing the structural junction in the semiconductor base layer 119 outside the semiconductor mesa 120, beam quality, stability, and/or voltage characteristics for a resulting semiconductor laser may be improved.
  • The [0052] epitaxial semiconductor structure 114 may also include an active layer at the junction 122 between the N-type layer and the P-type layer. The active layer may include a number of different structures and/or layers and/or combinations thereof. The active layer, for example, may include single or multiple quantum wells, double heterostructures, and/or superlattices. The active layer may also include light and/or current confinement layers that may encourage laser action in the device. Moreover, portions of the active layer may he included in the N-type layer and/or the P-type layer adjacent the junction therebetween. According to particular embodiments, the active layer may be included in the N-type layer 115 adjacent the junction 122 with the P-type layer.
  • By way of example, a uniformly thick layer of epitaxial semiconductor material may be formed on the [0053] substrate 112, and a layer of an ohmic contact material may be formed on the layer of the epitaxial semiconductor material. The semiconductor mesa 120 and the ohmic contact layer 126 may be formed, for example, by selectively etching the layer of the contact material and the layer of the epitaxial semiconductor material using a same etch mask, using different etch masks, and/or using a lift-off technique. Methods of forming mesas, contact layers, and passivation layers are discussed, for example, in U.S. application Ser. No. ______ (Attorney Docket No. 5308-280), in U.S. application Ser. No. ______ (Attorney Docket No. 5308-281), and in U.S. application Ser. No. ______ (Attorney Docket No. 5308-282), the disclosures of which are hereby incorporated herein by reference.
  • Exposed portions of the epitaxial semiconductor material can be removed using a dry etch such as a Reactive Ion Etch (RIE), an Electron Cyclotron Resonance (ECR) plasma etch, and/or an Inductively Coupled Plasma (ICP) etch. More particularly, the epitaxial semiconductor layer can be etched using a dry etch in an Argon (Ar) environment with a chlorine (Cl[0054] 2) etchant. For example, argon can flow at a rate in the range of approximately 2 to 40 sccm and chlorine can flow at a rate in the range of approximately 5 to 50 sccm in an RIE reactor at a pressure in the range of approximately 5 to 50 mTorr and at an RF power in the range of approximately 200 to 1000 W. These etch parameters are provided by way of example, and other etch parameters may be used.
  • Moreover, thicknesses of the [0055] semiconductor base layer 119 and the semiconductor mesa 120 and the distance D′junction of the junction 112 from the mesa base 120C may be determined by an original thickness of the semiconductor layer from which the base layer 119 and mesa 120 are patterned, an original depth of the conductivity junction 122 in the semiconductor layer, and a depth of an etch used to form the semiconductor mesa 120. According to embodiments of the present invention, the mesa etch depth (and resulting mesa thickness T′) may be in the range of approximately 0.1 to 5 microns, and according to additional embodiments may be no greater than approximately 2.5 microns. In addition, a width of the mesa surface 120A between mesa sidewalls 120B may be in the range of approximately 1 to 3 microns, and a distance Dsubstrate from the mesa base 120C to the substrate can be in the range of approximately 0 to 4.9 microns. The distance Dsubstrate is also a measure of the thickness of the semiconductor base layer 119. In addition, the mesa surface 120A may be a P-type semiconductor material.
  • The location of the [0056] junction 122 in the semiconductor base layer 119 can be determined by an original depth (T′+D′junction) of the junction in the semiconductor layer from which the base layer and mesa are patterned and an etch depth T′ used to form the mesa 120. In particular, the etch depth T′ of the etch used to form the semiconductor mesa 120 can be less than the depth of the junction in the semiconductor layer so that the junction 122 is included in the semiconductor base layer 119.
  • A semiconductor device according to additional embodiments of the present invention is illustrated in FIG. 3. As shown in FIG. 3, a semiconductor device may include a [0057] substrate 212 and an epitaxial semiconductor structure 214 including a semiconductor base layer 219 and a semiconductor mesa 220 on a portion of the base layer 219. More particularly, the semiconductor mesa 220 may include a mesa surface 220A opposite the base layer 219, mesa sidewalls 220B between the mesa surface 220A and the base layer 219, and a mesa base 220C adjacent the base layer. While a dashed line is shown between the semiconductor mesa 220 and the semiconductor base layer 219 for purposes of illustration, it will be understood that adjacent portions of the semiconductor base layer 219 and the semiconductor mesa 220 may comprise a same semiconductor material with no physical barrier, junction, or discontinuity between the two.
  • The device may also include a [0058] passivation layer 224 on the semiconductor base layer 219 and on portions of the semiconductor mesa 220 with portions of the mesa surface 220A being free of the passivation layer 224. Moreover, a first ohmic contact layer 226 may be provided on portions of the mesa surface 220A free of the passivation layer, and a metal overlayer 228 may be provided on the passivation layer 224 and the ohmic contact layer 226. In addition, a second ohmic contact layer 227 may be provided on the substrate 212 opposite the semiconductor structure 214 to define an electrical current path through the mesa 220, the semiconductor base layer 219, and the substrate 212. In an alternative, a second ohmic contact layer may be provide on a same side of the substrate as the epitaxial semiconductor structure 214 so that current through the substrate 212 is not required.
  • In some embodiments, the [0059] substrate 212 may include a substrate material such as N-type silicon carbide having a polytype such as 2H, 4H, 6H, 8H, 15R, and/or 3C; sapphire; gallium nitride; and/or aluminum nitride. Moreover, the substrate 212 may be conductive to provide a “vertical” device having a “vertical” current flow through the epitaxial semiconductor structure 214 and the substrate 212. In an alternative, the substrate 212 may be insulating or semi-insulating where both ohmic contacts are provided on a same side of the substrate to provide a “horizontal” device. A conductive substrate could also be used in a “horizontal” device. Moreover, the term substrate may be defined to include a non-patterned portion of the semiconductor material making up the semiconductor structure 214, and/or there may not be a material transition between the substrate 212 and the semiconductor structure 214.
  • Portions of the [0060] epitaxial semiconductor structure 214 may be patterned into a mesa stripe, for example, to provide optical and/or current confinement for a semiconductor laser device. As shown, only a portion of the epitaxial semiconductor structure 214 is included in the mesa 220, and the remainder of the epitaxial semiconductor structure 214 is included in the semiconductor base layer 219. More particularly, the epitaxial semiconductor structure 214 may include a P-type layer 217, all of which is included in the semiconductor mesa 220 adjacent the mesa surface 220A. The epitaxial semiconductor structure 214 may also include an N-type layer (including portions 215′ and 215″) with a junction 222 between the P-type layer and the N-type layer. As discussed above, the junction 222 may be a structural junction defined as a location where P-type doping begins. A structural junction and an actual electronic P-N junction may thus have different locations in the semiconductor structure 114 due to reactor effects, dopant incorporation rates, dopant activation rates, dopant diffusion, and/or other mechanisms.
  • As shown in FIG. 3, a [0061] first portion 215′ of the N-type layer is included in the semiconductor base layer 219, and a second portion 215″ of the N-type layer is included in the semiconductor mesa 220. A thickness of the first portion 215′ of the N-type layer is the same as the distance (labeled D″substrate) from the mesa base 220C to the substrate 212, and the thickness of the second portion 215″ of the N-type layer (labeled D″junction) is the same as the distance from the mesa base 220C to the junction between the N-type and P-type layers. In addition, the thickness of the semiconductor mesa is labeled T″. Accordingly, a thickness of the P-type layer 217 may be equal to a difference of the mesa thickness T″ minus D″junction.
  • According to particular embodiments, the semiconductor mesa [0062] 220 may be formed such that the junction 222 between N-type and P-type layers is included in the mesa 220 spaced apart from the mesa base 220C by a distance D″junction of no more than approximately 5 microns, and more particularly, by a distance of no more than approximately 0.75 microns. In addition, the junction 222 may be included in the semiconductor mesa 220 spaced from the mesa base 220C by a distance D″junction of at least approximately 0.05 microns, and more particularly, the junction 222 may be included in the semiconductor mesa 220 spaced from the mesa base 220C by a distance D″junction of at least approximately 0.1 microns. By providing the structural junction in the semiconductor mesa 220 outside the semiconductor mesa 220, a resulting semiconductor laser may provide stronger guiding and/or improved operating current characteristics.
  • The [0063] epitaxial semiconductor structure 214 may also include an active layer at the junction between the N-type layer and the P-type layer. The active layer may include a number of different structures and/or layers and/or combinations thereof. The active layer, for example, may include single or multiple quantum wells, double heterostructures, and/or superlattices. The active layer may also include light and/or current confinement layers that may encourage laser action in the device. Moreover, portions of the active layer may be included in the N-type layer and/or the P-type layer adjacent the junction therebetween. According to particular embodiments, the active layer may be included in the second portion 215″ of the N-type layer adjacent the junction 222 with the P-type layer 217.
  • By way of example, a uniformly thick layer of epitaxial semiconductor material may be formed on the [0064] substrate 212, and a layer of an ohmic contact material may be formed on the layer of the epitaxial semiconductor material. The semiconductor mesa 220 and the ohmic contact layer 226 may be formed, for example, by selectively etching the layer of the contact material and the layer of the epitaxial semiconductor material using a same etch mask, using different etch masks, and/or using a lift-off technique. Methods of forming mesas, contact layers, and passivation layers are discussed, for example, in U.S. application Ser. No. ______ (Attorney Docket No. 5308-280), in U.S. application Ser. No. ______ (Attorney Docket No. 5308-281), and in U.S. application Ser. No. ______ (Attorney Docket No. 5308-282), the disclosures of which are hereby incorporated herein by reference.
  • Exposed portions of the epitaxial semiconductor material can be removed using a dry etch such as a Reactive Ion Etch (RIE), an Electron Cyclotron Resonance (ECR) plasma etch, and/or an Inductively Coupled Plasma (ICP) etch. More particularly, the epitaxial semiconductor layer can be etched using a dry etch in an Argon (Ar) environment with a chlorine (Cl[0065] 2) etchant. For example, argon can flow at a rate in the range of approximately 2 to 40 sccm and chlorine can flow at a rate in the range of approximately 5 to 50 sccm in an RIE reactor at a pressure in the range of approximately 5 to 50 mTorr and at an RF power in the range of approximately 200 to 1000 W. These etch parameters are provided by way of example, and other etch parameters may be used.
  • Moreover, thicknesses of the [0066] semiconductor base layer 219 and the semiconductor mesa 220 and a distance D″junction of a junction from the mesa base 220C may be determined by an original thickness of the semiconductor layer from which the base layer 219 and mesa 220 are patterned, an original depth of the junction in the semiconductor layer, and a depth of an etch used to form the semiconductor mesa 220. According to embodiments of the present invention, the mesa etch depth (and resulting mesa thickness T″) may be in the range of approximately 0.1 to 5 microns, and according to additional embodiments may be no greater than approximately 2.5 microns. In addition, a width of the mesa surface 220A between mesa sidewalls 220B may be in the range of approximately 1 to 3 microns, and a distance Dsubstrate from the mesa base 220C to the substrate can be in the range of approximately 0 to 4.9 microns. The distance Dsubstrate is also a measure of the thickness of the semiconductor base layer 219. In addition, the mesa surface 220A may be a P-type semiconductor material.
  • The location of the [0067] junction 222 in the semiconductor mesa 220 can be determined by an original depth (T″−D″junction) of the junction in the semiconductor layer from which the base layer 219 and mesa 220 are patterned and an etch depth used to form the mesa 220. In particular, the etch depth T″ of the etch used to form the semiconductor mesa 220 can be greater than a depth of the junction in the semiconductor layer so that the junction can be included in the semiconductor base layer 219.
  • The resulting semiconductor devices may provide edge emitting semiconductor lasers with light being emitted parallel to the substrate along a lengthwise direction of a semiconductor mesa stripe. Stated in other words, the light may be emitted along a direction perpendicular to the cross section of the Figures discussed above. While methods and devices have been discussed with reference to methods of forming light emitting devices such as laser diodes, methods according to embodiments of the present invention may be used to form other semiconductor devices such as conventional diodes, conventional light emitting diodes, or any other semiconductor device including a semiconductor mesa. [0068]
  • While this invention has been particularly shown and described with reference to preferred embodiments thereof, it will be understood by those skilled in the art that various changes in form and details may be made therein without departing from the spirit and scope of the invention as defined by the appended claims and their equivalents. [0069]

Claims (93)

That which is claimed is:
1. A light emitting device comprising:
a silicon carbide substrate; and
a semiconductor structure on the substrate, the semiconductor structure including a mesa having a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base, wherein the semiconductor structure has a first conductivity type adjacent the silicon carbide substrate, wherein the semiconductor structure has a second conductivity type adjacent the mesa surface, wherein the semiconductor structure has a junction between the first and second conductivity types, and wherein the mesa is configured to provide at least one of current confinement or optical confinement for a light emitting device in the semiconductor structure.
2. A light emitting device according to claim 1 wherein the junction is between the mesa base and the mesa surface.
3. A light emitting device according to claim 2 wherein the junction is no more than approximately 5 microns from the mesa base.
4. A light emitting device according to claim 2 wherein the junction is no more than approximately 0.75 microns from the mesa base.
5. A light emitting device according to claim 2 wherein the junction is at least approximately 0.05 microns from the mesa base.
6. A light emitting device according to claim 5 wherein the junction is at least approximately 0.1 microns from the mesa base.
7. A light emitting device according to claim 1 wherein the semiconductor structure includes a semiconductor base layer between the mesa base and the silicon carbide substrate wherein the junction is between a surface of the base layer opposite the silicon carbide substrate and the silicon carbide substrate.
8. A light emitting device according to claim 7 wherein the junction is no more than approximately 0.4 microns from the surface of the base layer opposite the silicon carbide substrate.
9. A light emitting device according to claim 8 wherein the junction is no more than approximately 0.2 microns from the surface of the base layer opposite the substrate.
10. A light emitting device according to claim 7 wherein the junction is at least approximately 0.05 microns from the surface of the base layer opposite the substrate.
11. A light emitting device according to claim 10 wherein the junction is at least approximately 0.1 microns from the surface of the base layer opposite the substrate.
12. A light emitting device according to claim 1 wherein the semiconductor structure comprises a Group III-V semiconductor material.
13. A method of forming a light emitting device, the method comprising:
forming a silicon carbide substrate; and
forming a semiconductor structure on the substrate, the semiconductor structure including a mesa having a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base, wherein the semiconductor structure has a first conductivity type adjacent the silicon carbide substrate, wherein the semiconductor structure has a second conductivity type adjacent the mesa surface, wherein the semiconductor structure has a junction between the first and second conductivity types, and wherein the mesa is configured to provide at least one of current confinement or optical confinement for a light emitting device in the semiconductor structure.
14. A method according to claim 13 wherein the junction is between the mesa base and the mesa surface.
15. A method according to claim 14 wherein the junction is no more than approximately 5 microns from the mesa base.
16. A method according to claim 14 wherein the junction is no more than approximately 0.75 microns from the mesa base.
17. A method according to claim 14 wherein the junction is at least approximately 0.05 microns from the mesa base.
18. A method according to claim 17 wherein the junction is at least approximately 0.1 microns from the mesa base.
19. A method according to claim 13 wherein the semiconductor structure includes a semiconductor base layer between the mesa base and the silicon carbide substrate wherein the junction is between a surface of the base layer opposite the silicon carbide substrate and the silicon carbide substrate.
20. A method according to claim 19 wherein the junction is no more than approximately 0.4 microns from the surface of the base layer opposite the silicon carbide substrate.
21. A method according to claim 20 wherein the junction is no more than approximately 0.2 microns from the surface of the base layer opposite the substrate.
22. A method according to claim 19 wherein the junction is at least approximately 0.05 microns from the surface of the base layer opposite the substrate.
23. A method according to claim 22 wherein the junction is at least approximately 0.1 microns from the surface of the base layer opposite the substrate.
24. A method according to claim 13 wherein the semiconductor structure comprises a Group III-V semiconductor material.
25. An electronic device comprising:
a substrate; and
a semiconductor mesa on the substrate, the semiconductor mesa having a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base, wherein the semiconductor mesa has a first conductivity type between the mesa base and a junction, wherein the junction is between the mesa base and the mesa surface, and wherein the semiconductor mesa has a second conductivity type between the junction and the mesa surface.
26. An electronic device according to claim 25 wherein the semiconductor mesa is configured to provide at least one of optical confinement or current confinement for a light emitting device in the semiconductor mesa.
27. An electronic device according to claim 25 wherein the substrate comprises a silicon carbide substrate.
28. An electronic device according to claim 25 wherein the junction comprises a physical location where doping of the second conductivity type begins.
29. An electronic device according to claim 25 wherein the first conductivity type comprises N-type and wherein the second conductivity type comprises P-type.
30. An electronic device according to claim 25 wherein the semiconductor mesa comprises a Group III-V semiconductor material.
31. An electronic device according to claim 30 wherein the semiconductor mesa comprises a Group III-nitride semiconductor material.
32. An electronic device according to claim 25 wherein the junction is no more that approximately 5 microns from the mesa base.
33. An electronic device according to claim 32 wherein the junction is no more than approximately 0.75 microns from the mesa base.
34. An electronic device according to claim 25 wherein the junction is at least 0.05 microns from the mesa base.
35. An electronic device according to claim 34 wherein the junction is at least 0.1 microns from the mesa base.
36. An electronic device according to claim 25 wherein the semiconductor mesa has a thickness in the range of approximately 0.1 microns to 5 microns.
37. An electronic device according to claim 25 further comprising:
a semiconductor base layer between the substrate and the semiconductor mesa, wherein the semiconductor base layer has the first conductivity type throughout.
38. An electronic device according to claim 37 wherein the semiconductor base layer has a thickness no greater than approximately 5 microns.
39. An electronic device according to claim 37 wherein each of the semiconductor base layer and the semiconductor mesa comprise a Group III-V semiconductor material.
40. An electronic device according to claim 25 wherein the substrate comprises a conductive material.
41. An electronic device according to claim 40 wherein the substrate comprises a conductive semiconductor material.
42. An electronic device according to claim 41 wherein the conductive semiconductor material comprises at least one of gallium nitride and/or silicon carbide.
43. An electronic device comprising:
a substrate;
a semiconductor base layer on the substrate, wherein the semiconductor base layer has a first conductivity type between the substrate and a junction, wherein the junction is between the substrate and a surface of the base layer opposite the substrate, and wherein the semiconductor base layer has a second conductivity type between the junction and the surface of the base layer opposite the substrate; and
a semiconductor mesa on the surface of the base layer opposite the substrate, the semiconductor mesa having a mesa surface opposite the semiconductor base layer and mesa sidewalls between the mesa surface and the base layer, wherein the semiconductor mesa has the second conductivity type throughout.
44. An electronic device according to claim 43 wherein the semiconductor mesa is configured to provide at least one of optical confinement or current confinement for a light emitting device in the semiconductor base layer and semiconductor mesa.
45. An electronic device according to claim 43 wherein the substrate comprises a silicon carbide substrate.
46. An electronic device according to claim 43 wherein the junction comprises a physical location where doping of the second conductivity type begins.
47. An electronic device according to claim 43 wherein the first conductivity type comprises N-type and wherein the second conductivity type comprises P-type.
48. An electronic device according to claim 43 wherein each of the semiconductor mesa and the semiconductor base layer comprises a Group III-V semiconductor material.
49. An electronic device according to claim 43 wherein each of the semiconductor mesa and the semiconductor base layer comprises a Group III-nitride semiconductor material.
50. An electronic device according to claim 43 wherein the junction is no more that approximately 0.4 microns from the surface of the base layer opposite the substrate.
51. An electronic device according to claim 43 wherein the junction is no more than approximately 0.2 microns from the surface of the base layer opposite the substrate.
52. An electronic device according to claim 43 wherein the junction is at least approximately 0.05 microns from the surface of the base layer opposite the substrate.
53. An electronic device according to claim 52 wherein the junction is at least approximately 0.1 microns from the surface of the base layer opposite the substrate.
54. An electronic device according to claim 43 wherein the semiconductor mesa has a thickness in the range of approximately 0.1 microns to 5 microns.
55. An electronic device according to claim 43 wherein the semiconductor base layer has a thickness no greater than approximately 5 microns.
56. An electronic device according to claim 43 wherein the substrate comprises a conductive material.
57. An electronic device according to claim 56 wherein the substrate comprises a conductive semiconductor material.
58. An electronic device according to claim 57 wherein the conductive semiconductor material comprises at least one of gallium nitride and/or silicon carbide.
59. A method of forming an electronic device, the method comprising:
forming a semiconductor mesa on a substrate, the semiconductor mesa having a mesa base adjacent the substrate, a mesa surface opposite the substrate, and mesa sidewalls between the mesa surface and the mesa base, wherein the semiconductor mesa has a first conductivity type between the mesa base and a junction, wherein the junction is between the mesa base and the mesa surface, and wherein the semiconductor mesa has a second conductivity type between the junction and the mesa surface.
60. A method according to claim 59 wherein the semiconductor mesa is configured to provide at least one of optical confinement or current confinement for a light emitting device in the semiconductor mesa.
61. A method according to claim 59 wherein the substrate comprises a silicon carbide substrate.
62. A method according to claim 59 wherein the junction comprises a physical location where doping of the second conductivity type begins.
63. A method according to claim 59 wherein the first conductivity type comprises N-type and wherein the second conductivity type comprises P-type.
64. A method according to claim 59 wherein the semiconductor mesa comprises a Group III-V semiconductor material.
65. A method according to claim 64 wherein the semiconductor mesa comprises a Group III-nitride semiconductor material.
66. A method according to claim 59 wherein the junction is no more that approximately 5 microns from the mesa base.
67. A method according to claim 59 wherein the junction is no more than approximately 0.75 microns from the mesa base.
68. A method according to claim 59 wherein the junction is at least 0.05 microns from the mesa base.
69. A method according to claim 63 wherein the junction is at least 0.1 microns from the mesa base.
70. A method according to claim 59 wherein the semiconductor mesa has a thickness in the range of approximately 0.1 microns to 5 microns.
71. A method according to claim 59 wherein forming the semiconductor mesa comprises forming a layer of a semiconductor material on the substrate, forming a mask on the layer of the semiconductor material, and etching portions of layer of the semiconductor material exposed by the mask wherein a depth of etching defines a thickness of the mesa.
72. A method according to claim 59 further comprising:
forming a semiconductor base layer between the substrate and the semiconductor mesa, wherein the semiconductor base layer has the first conductivity type throughout.
73. A method according to claim 72 wherein forming the semiconductor mesa and forming the semiconductor base layer comprise forming a layer of a semiconductor material on the substrate, forming a mask on the layer of the semiconductor material, and etching portions of layer of the semiconductor material exposed by the mask wherein a depth of etching defines a thickness of the mesa.
74. A method according to claim 73 wherein the layer of the semiconductor material includes a junction at a junction depth and wherein the depth of etching of the layer of the semiconductor material is greater than the junction depth.
75. A method according to claim 72 wherein the semiconductor. base layer has a thickness no greater than approximately 5 microns.
76. A method according to claim 72 wherein each of the semiconductor base layer and the semiconductor mesa comprise a Group III-V semiconductor material.
77. A method according to claim 59 wherein the substrate comprises silicon carbide.
78. A method of forming an electronic device, the method comprising:
forming a semiconductor base layer on a substrate, wherein the semiconductor base layer has a first conductivity type between the substrate and a junction, wherein the junction is between the substrate and a surface of the base layer opposite the substrate, and wherein the semiconductor base layer has a second conductivity type between the junction and the surface of the base layer opposite the substrate; and
forming a semiconductor mesa on the surface of the base layer opposite the substrate, the semiconductor mesa having a mesa surface opposite the semiconductor base layer and mesa sidewalls between the mesa surface and the base layer, wherein the semiconductor mesa has the second conductivity type throughout.
79. A method according to claim 78 wherein the semiconductor mesa is configured to provide at least one of optical confinement or current confinement for a light emitting device in the semiconductor base layer and semiconductor mesa.
80. A method according to claim 78 wherein the. substrate comprises a silicon carbide substrate.
81. A method according to claim 78 wherein the junction comprises a physical location where doping of the second conductivity type begins.
82. A method according to claim 78 wherein the first conductivity type comprises N-type and wherein the second conductivity type comprises P-type.
83. A method according to claim 78 wherein each of the semiconductor mesa and the semiconductor base layer comprises a Group III-V semiconductor material.
84. A method according to claim 83 wherein each of the semiconductor mesa and the semiconductor base layer comprises a Group III-nitride semiconductor material.
85. A method according to claim 78 wherein the junction is no more that approximately 0.4 microns from the surface of the base layer opposite the substrate.
86. A method according to claim 78 wherein the junction is no more than approximately 0.2 microns from the surface of the base layer opposite the substrate.
87. A method according to claim 78 wherein the junction is at least approximately 0.05 microns from the surface of the base layer opposite the substrate.
88. A method according to claim 87 wherein the junction is at least approximately 0.1 microns from the surface of the base layer opposite the substrate.
89. A method according to claim 78 wherein the semiconductor mesa has a thickness in the range of approximately 0.1 microns to 5 microns.
90. A method according to claim 78 wherein the semiconductor base layer has a thickness no greater than approximately 5 microns.
91. A method according to claim 78 wherein the substrate comprises silicon carbide.
92. A method according to claim 78 wherein forming the semiconductor mesa and forming the semiconductor base layer comprise forming a layer of a semiconductor material on the substrate, forming a mask on the layer of the semiconductor material, and etching portions of layer of the semiconductor material exposed by the mask wherein a depth of etching defines a thickness of the mesa.
93. A method according to claim 92 wherein the layer of the semiconductor material includes a junction at a junction depth and wherein the depth of etching of the layer of the semiconductor material is less than the junction depth.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080229142A1 (en) * 2007-03-14 2008-09-18 Microsoft Corporation Self-service recovery of application data

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004021461A2 (en) 2002-08-30 2004-03-11 Gelcore Llc Phosphor-coated led with improved efficiency
US10340424B2 (en) 2002-08-30 2019-07-02 GE Lighting Solutions, LLC Light emitting diode component
US7800121B2 (en) 2002-08-30 2010-09-21 Lumination Llc Light emitting diode component
KR101045160B1 (en) * 2002-12-20 2011-06-30 크리 인코포레이티드 Methods of forming semiconductor devices having self aligned semiconductor mesas and contact layers and related devices
GB0302580D0 (en) * 2003-02-05 2003-03-12 Univ Strathclyde MICRO LEDs
KR100818522B1 (en) * 2004-08-31 2008-03-31 삼성전기주식회사 The fabrication method of laser diode
US7345309B2 (en) * 2004-08-31 2008-03-18 Lockheed Martin Corporation SiC metal semiconductor field-effect transistor
US20060262243A1 (en) * 2005-05-19 2006-11-23 Lester Steven D Display system and method using a solid state laser
JP2007027164A (en) * 2005-07-12 2007-02-01 Rohm Co Ltd Manufacturing method of semiconductor light emitting device and semiconductor light emitting device
JP2007184426A (en) * 2006-01-06 2007-07-19 Shinko Electric Ind Co Ltd Manufacturing method of semiconductor device
US8193591B2 (en) 2006-04-13 2012-06-05 Freescale Semiconductor, Inc. Transistor and method with dual layer passivation
KR100794380B1 (en) * 2006-05-08 2008-01-15 한국광기술원 Manufacturing Method Of The Buried Heterostructure Type Laser Diode Having Activation Layer Protected By Mesa Sidewall Passivation
US7842960B2 (en) 2006-09-06 2010-11-30 Lumination Llc Light emitting packages and methods of making same
US7598104B2 (en) 2006-11-24 2009-10-06 Agency For Science, Technology And Research Method of forming a metal contact and passivation of a semiconductor feature
US7833695B2 (en) * 2007-05-31 2010-11-16 Corning Incorporated Methods of fabricating metal contact structures for laser diodes using backside UV exposure
US8237183B2 (en) * 2007-08-16 2012-08-07 Kabushiki Kaisha Toshiba Semiconductor light emitting device and method for manufacturing same
KR100892983B1 (en) * 2007-09-05 2009-04-10 한국광기술원 Formation method of buried heterostructure Laser Diode
JP2009129943A (en) * 2007-11-20 2009-06-11 Mitsubishi Electric Corp Nitride semiconductor device and method of manufacturing the same
US7935620B2 (en) * 2007-12-05 2011-05-03 Freescale Semiconductor, Inc. Method for forming semiconductor devices with low leakage Schottky contacts
JP2009158745A (en) * 2007-12-27 2009-07-16 Mitsubishi Electric Corp Method of manufacturing semiconductor device
US9318874B2 (en) 2009-06-03 2016-04-19 Nichia Corporation Semiconductor device and method of manufacturing semiconductor device
US8593040B2 (en) 2009-10-02 2013-11-26 Ge Lighting Solutions Llc LED lamp with surface area enhancing fins
JP5742325B2 (en) * 2010-03-25 2015-07-01 日亜化学工業株式会社 Semiconductor laser device and manufacturing method thereof
KR101731056B1 (en) * 2010-08-13 2017-04-27 서울바이오시스 주식회사 Semiconductor light emitting device having ohmic electrode structure and method of fabricating the same
US20120149176A1 (en) * 2010-12-10 2012-06-14 Taiwan Semiconductor Manufacturing Company, Ltd. Method and apparatus for forming a iii-v family layer
US20130009045A1 (en) * 2011-07-07 2013-01-10 Raytheon Company Self-Aligned Contacts for Photosensitive Detection Devices
US10115764B2 (en) 2011-08-15 2018-10-30 Raytheon Company Multi-band position sensitive imaging arrays
GB2494008A (en) * 2011-08-23 2013-02-27 Oclaro Technology Ltd semiconductor laser device and a method for manufacturing a semiconductor laser device
CN103021840B (en) * 2011-09-23 2015-11-04 中国科学院微电子研究所 Prevent the method for passivation layer over etching
US8710859B2 (en) * 2011-09-23 2014-04-29 Powertech Technology Inc. Method for testing multi-chip stacked packages
US9500355B2 (en) 2012-05-04 2016-11-22 GE Lighting Solutions, LLC Lamp with light emitting elements surrounding active cooling device
CN107579428B (en) * 2012-05-08 2020-03-03 镁可微波技术有限公司 Laser with beam shape modification
JP6205826B2 (en) * 2013-05-01 2017-10-04 住友電気工業株式会社 Semiconductor optical device manufacturing method
RU2617179C2 (en) * 2014-11-14 2017-04-21 Федеральное государственное бюджетное учреждение науки Физический институт им. П.Н. Лебедева Российской академии наук (ФИАН) POWER AMPLIFICATION METHOD OF RADIO FREQUENCY MODULATED TERAHERTZ RADIATION OF 30-PERIOD WEAKLY BOUND SEMICONDUCTOR SUPERLATTICE GaAs / AlGaAs
CN109154697B (en) * 2016-05-20 2020-11-10 镁可微波技术有限公司 Semiconductor laser and method for planarizing semiconductor laser
EP4019154B1 (en) * 2016-10-06 2024-01-31 Stefan Widhalm Device and method for binding dust
US11211525B2 (en) 2017-05-01 2021-12-28 Ohio State Innovation Foundation Tunnel junction ultraviolet light emitting diodes with enhanced light extraction efficiency
CN108666216B (en) * 2018-05-15 2021-05-07 西安电子科技大学 HEMT device based on laminated passivation structure and preparation method thereof
KR102544296B1 (en) * 2018-09-13 2023-06-16 쑤저우 레킨 세미컨덕터 컴퍼니 리미티드 A VERTICAL-CAVITY SURFACE-EMITTING LASER DEVICE and APPARATUS HAVING THE SAME
CN109659810B (en) * 2018-12-24 2021-10-08 香港中文大学(深圳) Method for reducing threshold of microcavity semiconductor laser
WO2020136012A1 (en) 2018-12-26 2020-07-02 Asml Netherlands B.V. Method of manufacturing an aperture device
WO2020258282A1 (en) * 2019-06-28 2020-12-30 Boe Technology Group Co., Ltd. Radiation detection and method of fabricating radiation detector
US20230197896A1 (en) * 2019-10-30 2023-06-22 The Regents Of The University Of California Method to improve the performance of gallium-containing light-emitting devices
US11626532B2 (en) 2021-01-06 2023-04-11 Applied Materials, Inc. Methods and apparatus for forming light emitting diodes
TWI748856B (en) * 2021-01-29 2021-12-01 錼創顯示科技股份有限公司 Micro light-emitting diode and display panel

Citations (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4032944A (en) * 1975-03-11 1977-06-28 U.S. Philips Corporation Semiconductor device for generating incoherent radiation and method of manufacturing same
US4053914A (en) * 1974-10-03 1977-10-11 Itt Industries, Inc. Light emissive diode
US4142160A (en) * 1972-03-13 1979-02-27 Hitachi, Ltd. Hetero-structure injection laser
US4531142A (en) * 1982-03-10 1985-07-23 Siemens Aktiengesellschaft Light emitting diode having silicon carbide layers
US4966862A (en) * 1989-08-28 1990-10-30 Cree Research, Inc. Method of production of light emitting diodes
US5187108A (en) * 1990-01-16 1993-02-16 Oki Electric Industry Co., Ltd. Method of manufacturing a bipolar transistor
US5208183A (en) * 1990-12-20 1993-05-04 At&T Bell Laboratories Method of making a semiconductor laser
US5243204A (en) * 1990-05-18 1993-09-07 Sharp Kabushiki Kaisha Silicon carbide light emitting diode and a method for the same
US5387804A (en) * 1988-12-28 1995-02-07 Sharp Kabushiki Kaisha Light emitting diode
US5416342A (en) * 1993-06-23 1995-05-16 Cree Research, Inc. Blue light-emitting diode with high external quantum efficiency
US5418190A (en) * 1993-12-30 1995-05-23 At&T Corp. Method of fabrication for electro-optical devices
US5429954A (en) * 1993-02-20 1995-07-04 Temic Telefunken Microelectronic Gmbh Radiation-emitting diode with improved radiation output
US5574743A (en) * 1994-03-22 1996-11-12 U.S. Philips Corporation Semiconductor diode laser having improved performance and method of manufacturing same
US5631190A (en) * 1994-10-07 1997-05-20 Cree Research, Inc. Method for producing high efficiency light-emitting diodes and resulting diode structures
US5650339A (en) * 1994-12-08 1997-07-22 Kabushiki Kaisha Toshiba Method of manufacturing thin film transistor
US5661074A (en) * 1995-02-03 1997-08-26 Advanced Technology Materials, Inc. High brightness electroluminescent device emitting in the green to ultraviolet spectrum and method of making the same
US5838706A (en) * 1994-09-20 1998-11-17 Cree Research, Inc. Low-strain laser structures with group III nitride active layers
US5874747A (en) * 1996-02-05 1999-02-23 Advanced Technology Materials, Inc. High brightness electroluminescent device emitting in the green to ultraviolet spectrum and method of making the same
US5916460A (en) * 1995-07-07 1999-06-29 Hitachi Cable, Ltd. Method and apparatus for dicing a substrate
US5923690A (en) * 1996-01-25 1999-07-13 Matsushita Electric Industrial Co., Ltd. Semiconductor laser device
US5923946A (en) * 1997-04-17 1999-07-13 Cree Research, Inc. Recovery of surface-ready silicon carbide substrates
US5923053A (en) * 1995-09-29 1999-07-13 Siemens Aktiengesellschaft Light-emitting diode having a curved side surface for coupling out light
US5972781A (en) * 1997-09-30 1999-10-26 Siemens Aktiengesellschaft Method for producing semiconductor chips
US6048748A (en) * 1999-01-14 2000-04-11 Hewlett-Packard Company Advanced semiconductor devices fabricated with passivated high aluminum content III-V materials
US6120600A (en) * 1995-05-08 2000-09-19 Cree, Inc. Double heterojunction light emitting diode with gallium nitride active layer
US6134368A (en) * 1996-08-30 2000-10-17 Nec Corporation Optical semiconductor device with a current blocking structure and method for making the same
US6187606B1 (en) * 1997-10-07 2001-02-13 Cree, Inc. Group III nitride photonic devices on silicon carbide substrates with conductive buffer interlayer structure
US6204161B1 (en) * 1998-10-17 2001-03-20 Samsung Electronics, Co., Ltd. Self aligned contact pad in a semiconductor device and method for forming the same
US6255198B1 (en) * 1998-11-24 2001-07-03 North Carolina State University Methods of fabricating gallium nitride microelectronic layers on silicon layers and gallium nitride microelectronic structures formed thereby
US6349104B1 (en) * 1997-05-30 2002-02-19 Denso Corporation Stripe-geometry heterojunction laser diode device
US20020022290A1 (en) * 1999-10-14 2002-02-21 Hua-Shuang Kong Single step pendeo-and lateral epitaxial overgrowth of group III-nitride epitaxial layers with group III-nitride buffer layer and resulting structures
US20020034204A1 (en) * 2000-09-14 2002-03-21 Koji Iwamoto Semiconductor laser device and method of manufacturing the same
US6376866B1 (en) * 1994-08-22 2002-04-23 Rohm Co., Ltd. GaN semiconductor light emitting device having a group II-VI substrate
US20020048835A1 (en) * 2000-08-12 2002-04-25 Kwak Joon-Seop Method for manufacturing semiconducter laser diode
US20020072250A1 (en) * 2000-12-07 2002-06-13 Hong-Sik Jeong Methods of manufacturing integrated circuit devices having an encapsulated insulation layer
US6413839B1 (en) * 1998-10-23 2002-07-02 Emcore Corporation Semiconductor device separation using a patterned laser projection
US6420252B1 (en) * 2000-05-10 2002-07-16 Emcore Corporation Methods of forming robust metal contacts on compound semiconductors
US20020093020A1 (en) * 2001-01-16 2002-07-18 Edmond John Adam Group III nitride LED with undoped cladding layer (5000.137)
US6432788B1 (en) * 1999-07-22 2002-08-13 Implant Sciences Corporation Method for fabricating an emitter-base junction for a gallium nitride bipolar transistor
US20020110945A1 (en) * 1998-05-18 2002-08-15 Fujitsu Limited Of Kawasaki, Japan Optical semiconductor device having an epitaxial layer of iii-v compound semiconductor material containing n as a group v element
US20020123164A1 (en) * 2001-02-01 2002-09-05 Slater David B. Light emitting diodes including modifications for light extraction and manufacturing methods therefor
US6459100B1 (en) * 1998-09-16 2002-10-01 Cree, Inc. Vertical geometry ingan LED
US20020159494A1 (en) * 2001-04-12 2002-10-31 Tsuyoshi Tojo Semiconductor laser device
US6475889B1 (en) * 2000-04-11 2002-11-05 Cree, Inc. Method of forming vias in silicon carbide and resulting devices and circuits
US20030006418A1 (en) * 2001-05-30 2003-01-09 Emerson David Todd Group III nitride based light emitting diode structures with a quantum well and superlattice, group III nitride based quantum well structures and group III nitride based superlattice structures
US20030006425A1 (en) * 2000-02-22 2003-01-09 International Rectifier Corporation Manufacturing process and termination structure for fast recovery diode
US20030015721A1 (en) * 2001-07-23 2003-01-23 Slater, David B. Light emitting diodes including modifications for submount bonding and manufacturing methods therefor
US20030020061A1 (en) * 2001-06-15 2003-01-30 Emerson David Todd Ultraviolet light emitting diode
US20030025121A1 (en) * 1997-08-29 2003-02-06 Edmond John Adam Robust Group III light emitting diode for high reliability in standard packaging applications
US20030045015A1 (en) * 2001-07-23 2003-03-06 Slater David B. Flip-chip bonding of light emitting devices and light emitting devices suitable for flip-chip bonding
US20030042507A1 (en) * 2001-07-23 2003-03-06 Slater David B. Bonding of light emitting diodes having shaped substrates and collets for bonding of light emitting diodes having shaped substrates
US6580054B1 (en) * 2002-06-10 2003-06-17 New Wave Research Scribing sapphire substrates with a solid state UV laser
US6677173B2 (en) * 2000-03-28 2004-01-13 Pioneer Corporation Method of manufacturing a nitride semiconductor laser with a plated auxiliary metal substrate
US20040051118A1 (en) * 2002-07-19 2004-03-18 Bruhns Michael T. Trench cut light emitting diodes and methods of fabricating same
US6946682B2 (en) * 1997-08-29 2005-09-20 Cree, Inc. Robust group III light emitting diode for high reliability in standard packaging applications

Family Cites Families (95)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US25121A (en) * 1859-08-16 Improvement in mole-plows
US592053A (en) * 1897-10-19 Antifriction-bearing
US93020A (en) * 1869-07-27 Improvement in eye-xlasses
US15721A (en) * 1856-09-09 Improvement in harvesters
US542995A (en) * 1895-07-23 Mechanism for giving reciprocating motion to canvas
US22290A (en) * 1858-12-14 Harness-snap
US123164A (en) * 1872-01-30 Improvement in fishing-apparatus
US45015A (en) * 1864-11-15 Improvement in flaring metal hoops
US6418A (en) * 1849-05-01 Improvement in the preparation of flour for bread-making
US920409A (en) * 1908-11-21 1909-05-04 Rudolf Wild Manicure implement.
GB406665A (en) * 1932-08-30 1934-02-28 Roger Harry Cubitt Improvements relating to the manufacture of photo-electric cells
US3495140A (en) * 1967-10-12 1970-02-10 Rca Corp Light-emitting diodes and method of making same
US3865646A (en) * 1972-09-25 1975-02-11 Bell Telephone Labor Inc Dielectric optical waveguides and technique for fabricating same
US3833435A (en) * 1972-09-25 1974-09-03 Bell Telephone Labor Inc Dielectric optical waveguides and technique for fabricating same
GB1432697A (en) * 1973-05-04 1976-04-22 Standard Telephones Cables Ltd Optically coupled semiconductive switching devices
US4084130A (en) * 1974-01-18 1978-04-11 Texas Instruments Incorporated Laser for integrated optical circuits
US4099305A (en) * 1977-03-14 1978-07-11 Bell Telephone Laboratories, Incorporated Fabrication of mesa devices by MBE growth over channeled substrates
US4236122A (en) * 1978-04-26 1980-11-25 Bell Telephone Laboratories, Incorporated Mesa devices fabricated on channeled substrates
US4276098A (en) * 1980-03-31 1981-06-30 Bell Telephone Laboratories, Incorporated Batch processing of semiconductor devices
JPS61236189A (en) * 1985-04-11 1986-10-21 Sharp Corp Semiconductor laser element
FR2613547B1 (en) * 1987-04-01 1989-06-23 Cit Alcatel SEMICONDUCTOR LASER WITH UNDERGROUND HETEROSTRUCTURE
US5003548A (en) * 1988-09-21 1991-03-26 Cornell Research Foundation, Inc. High power (1,4 W)AlGaInP graded-index separate confinement heterostructure visible (λ-658 nm) laser
JPH02188983A (en) * 1989-01-17 1990-07-25 Nec Corp Embedded structure semiconductor laser device
KR900013612A (en) * 1989-02-17 1990-09-05 프레데릭 얀 스미트 Method and device for connecting two objects
JPH0396289A (en) * 1989-09-08 1991-04-22 Nec Corp Semiconductor laser
EP0450255B1 (en) * 1990-04-06 1994-07-06 International Business Machines Corporation Process for forming the ridge structure of a self-aligned semiconductor laser
US5088099A (en) * 1990-12-20 1992-02-11 At&T Bell Laboratories Apparatus comprising a laser adapted for emission of single mode radiation having low transverse divergence
US5260230A (en) * 1991-07-12 1993-11-09 Nippon Telegraph And Telephone Corporation Method of manufacturing buried heterostructure semiconductor laser
JPH05235481A (en) * 1992-02-21 1993-09-10 Nippon Telegr & Teleph Corp <Ntt> Semiconductor light emitting device
DE69308977T2 (en) * 1992-09-25 1997-10-09 Furukawa Electric Co Ltd Semiconductor laser device
US5276699A (en) * 1992-11-05 1994-01-04 Eastman Kodak Company Depressed-index ridge waveguide laser diode containing a stabilizing region
JP3312146B2 (en) * 1993-06-25 2002-08-05 株式会社日立製作所 Magnetic head and method of manufacturing the same
JPH0750448A (en) * 1993-08-04 1995-02-21 Matsushita Electric Ind Co Ltd Semiconductor laser and manufacture thereof
US5422901A (en) * 1993-11-15 1995-06-06 Motorola, Inc. Semiconductor device with high heat conductivity
JP2822868B2 (en) * 1993-12-10 1998-11-11 日本電気株式会社 Manufacturing method of semiconductor laser
US5559053A (en) * 1994-04-14 1996-09-24 Lucent Technologies Inc. Vertical cavity semiconductor laser
US5787104A (en) * 1995-01-19 1998-07-28 Matsushita Electric Industrial Co., Ltd. Semiconductor light emitting element and method for fabricating the same
JPH0936484A (en) * 1995-07-14 1997-02-07 Oki Electric Ind Co Ltd Semiconductor laser and fabrication thereof
KR0172797B1 (en) * 1995-10-16 1999-03-30 김주용 Laser diode and method for fabricating the same
KR19980702366A (en) * 1995-12-21 1998-07-15 롤페스 제이 지 에이 Method for manufacturing semiconductor device having p-junction provided through epitaxy
KR970054972A (en) * 1995-12-29 1997-07-31 김주용 Laser diode manufacturing method
KR970054992A (en) * 1995-12-29 1997-07-31 김주용 Laser diode manufacturing method
JPH09270569A (en) * 1996-01-25 1997-10-14 Matsushita Electric Ind Co Ltd Semiconductor laser device
JPH09270528A (en) 1996-03-29 1997-10-14 Sanyo Electric Co Ltd Light emitting diode element and manufacturing method thereof
JP3708213B2 (en) * 1996-04-18 2005-10-19 松下電器産業株式会社 Semiconductor light emitting device and manufacturing method thereof
JPH1027940A (en) * 1996-07-12 1998-01-27 Matsushita Electric Ind Co Ltd Semiconductor laser device
US5668049A (en) * 1996-07-31 1997-09-16 Lucent Technologies Inc. Method of making a GaAs-based laser comprising a facet coating with gas phase sulphur
JPH1075011A (en) * 1996-08-30 1998-03-17 Sony Corp Semiconductor laser
KR100251348B1 (en) * 1996-12-30 2000-05-01 김영환 Rwg laser diode and its manufacturing method
JP3954686B2 (en) 1997-03-24 2007-08-08 平田機工株式会社 Substrate transport apparatus and substrate transport method
JP3897186B2 (en) * 1997-03-27 2007-03-22 シャープ株式会社 Compound semiconductor laser
WO1998047170A1 (en) * 1997-04-11 1998-10-22 Nichia Chemical Industries, Ltd. Method of growing nitride semiconductors, nitride semiconductor substrate and nitride semiconductor device
JPH10290025A (en) * 1997-04-15 1998-10-27 Oki Electric Ind Co Ltd Led array
JP3270374B2 (en) * 1997-11-07 2002-04-02 日本電気株式会社 Manufacturing method of semiconductor laser
JPH11150334A (en) * 1997-11-14 1999-06-02 Sony Corp Semiconductor light-emitting element
JP3653169B2 (en) * 1998-01-26 2005-05-25 シャープ株式会社 Gallium nitride semiconductor laser device
JP3604278B2 (en) * 1998-02-17 2004-12-22 日亜化学工業株式会社 Nitride semiconductor laser device
JP4352473B2 (en) * 1998-06-26 2009-10-28 ソニー株式会社 Manufacturing method of semiconductor device
JP4245691B2 (en) * 1998-08-04 2009-03-25 シャープ株式会社 Gallium nitride semiconductor laser device and optical pickup device
US6365968B1 (en) * 1998-08-07 2002-04-02 Corning Lasertron, Inc. Polyimide/silicon oxide bi-layer for bond pad parasitic capacitance control in semiconductor electro-optical device
JP3348024B2 (en) * 1998-08-17 2002-11-20 松下電器産業株式会社 Semiconductor laser device
JP3907854B2 (en) * 1998-12-07 2007-04-18 富士通株式会社 Semiconductor laser and manufacturing method thereof
US6744800B1 (en) * 1998-12-30 2004-06-01 Xerox Corporation Method and structure for nitride based laser diode arrays on an insulating substrate
JP2000223742A (en) 1999-01-29 2000-08-11 Toshiba Corp Nitrogen compound semiconductor element
KR100683877B1 (en) * 1999-03-04 2007-02-15 니치아 카가쿠 고교 가부시키가이샤 Nitride Semiconductor Laser Element
JP3459607B2 (en) * 1999-03-24 2003-10-20 三洋電機株式会社 Semiconductor laser device and method of manufacturing the same
JP2000299528A (en) * 1999-04-12 2000-10-24 Nec Corp Semiconductor laser and manufacture thereof
JP3735638B2 (en) * 1999-04-23 2006-01-18 ソニー株式会社 Semiconductor laser and manufacturing method thereof
JP2001156398A (en) * 1999-05-19 2001-06-08 Canon Inc Method for fabricating semiconductor element, semiconductor element, and gyro
JP2001094197A (en) * 1999-09-21 2001-04-06 Nec Corp Self-oscillating type semiconductor laser
JP2001148532A (en) * 1999-11-19 2001-05-29 Pioneer Electronic Corp Nitride semiconductor laser and manufacturing method therefor
US6835963B2 (en) * 1999-12-22 2004-12-28 Kabushiki Kaisha Toshiba Light-emitting element and method of fabrication thereof
JP4007737B2 (en) * 1999-12-24 2007-11-14 三洋電機株式会社 Semiconductor element
JP3636976B2 (en) * 2000-03-17 2005-04-06 日本電気株式会社 Nitride semiconductor device and manufacturing method thereof
JP3484394B2 (en) * 2000-04-12 2004-01-06 Necエレクトロニクス株式会社 Optical semiconductor device and method of manufacturing the same
WO2001082136A2 (en) * 2000-04-20 2001-11-01 General Electric Company Method and system for graphically identifying replacement parts for generally complex equipment
US6642270B2 (en) * 2000-05-15 2003-11-04 Paratek Pharmaceuticals, Inc. 7-substituted fused ring tetracycline compounds
KR100763827B1 (en) * 2000-06-08 2007-10-05 니치아 카가쿠 고교 가부시키가이샤 Semiconductor laser device, and method of manufacturing the same
US6432735B1 (en) * 2000-06-23 2002-08-13 Agere Systems Guardian Corp. High power single mode laser and method of fabrication
JP2002094189A (en) * 2000-09-14 2002-03-29 Sharp Corp Nitride semiconductor laser device and optical instrument using it
US6387804B1 (en) 2000-09-19 2002-05-14 Advanced Micro Devices, Inc. Passivation of sidewall spacers using ozonated water
US6475100B1 (en) * 2000-10-11 2002-11-05 Callaway Golf Company Golf club head with adjustable face angle
US7053413B2 (en) * 2000-10-23 2006-05-30 General Electric Company Homoepitaxial gallium-nitride-based light emitting device and method for producing
DE10054966A1 (en) 2000-11-06 2002-05-16 Osram Opto Semiconductors Gmbh Component for optoelectronics
JP2002222859A (en) * 2001-01-26 2002-08-09 Sanken Electric Co Ltd Method for forming contact electrode of semiconductor element
JP2002335048A (en) * 2001-03-06 2002-11-22 Sony Corp Nitride semiconductor laser element and its manufacturing method
JP4304883B2 (en) * 2001-05-30 2009-07-29 日亜化学工業株式会社 Nitride semiconductor laser diode and manufacturing method thereof
MY132031A (en) * 2001-05-31 2007-09-28 Nichia Corp Semiconductor laser element
JP3876649B2 (en) * 2001-06-05 2007-02-07 ソニー株式会社 Nitride semiconductor laser and manufacturing method thereof
US6977953B2 (en) * 2001-07-27 2005-12-20 Sanyo Electric Co., Ltd. Nitride-based semiconductor light-emitting device and method of fabricating the same
US6746948B2 (en) * 2001-09-17 2004-06-08 Matsushita Electric Industrial Co., Ltd. Method for fabricating semiconductor light-emitting device
DE10148227B4 (en) 2001-09-28 2015-03-05 Osram Opto Semiconductors Gmbh Radiation-emitting semiconductor chip, method for its production and radiation-emitting component
US20040075160A1 (en) * 2002-10-18 2004-04-22 Jack Eng Transient voltage suppressor having an epitaxial layer for higher avalanche voltage operation
DE10254190B4 (en) * 2002-11-20 2005-12-22 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Infrared semiconductor laser
KR101045160B1 (en) * 2002-12-20 2011-06-30 크리 인코포레이티드 Methods of forming semiconductor devices having self aligned semiconductor mesas and contact layers and related devices

Patent Citations (59)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4142160A (en) * 1972-03-13 1979-02-27 Hitachi, Ltd. Hetero-structure injection laser
US4053914A (en) * 1974-10-03 1977-10-11 Itt Industries, Inc. Light emissive diode
US4032944A (en) * 1975-03-11 1977-06-28 U.S. Philips Corporation Semiconductor device for generating incoherent radiation and method of manufacturing same
US4531142A (en) * 1982-03-10 1985-07-23 Siemens Aktiengesellschaft Light emitting diode having silicon carbide layers
US5387804A (en) * 1988-12-28 1995-02-07 Sharp Kabushiki Kaisha Light emitting diode
US4966862A (en) * 1989-08-28 1990-10-30 Cree Research, Inc. Method of production of light emitting diodes
US5187108A (en) * 1990-01-16 1993-02-16 Oki Electric Industry Co., Ltd. Method of manufacturing a bipolar transistor
US5243204A (en) * 1990-05-18 1993-09-07 Sharp Kabushiki Kaisha Silicon carbide light emitting diode and a method for the same
US5208183A (en) * 1990-12-20 1993-05-04 At&T Bell Laboratories Method of making a semiconductor laser
US5429954A (en) * 1993-02-20 1995-07-04 Temic Telefunken Microelectronic Gmbh Radiation-emitting diode with improved radiation output
US5416342A (en) * 1993-06-23 1995-05-16 Cree Research, Inc. Blue light-emitting diode with high external quantum efficiency
US5418190A (en) * 1993-12-30 1995-05-23 At&T Corp. Method of fabrication for electro-optical devices
US5574743A (en) * 1994-03-22 1996-11-12 U.S. Philips Corporation Semiconductor diode laser having improved performance and method of manufacturing same
US6376866B1 (en) * 1994-08-22 2002-04-23 Rohm Co., Ltd. GaN semiconductor light emitting device having a group II-VI substrate
US5838706A (en) * 1994-09-20 1998-11-17 Cree Research, Inc. Low-strain laser structures with group III nitride active layers
US5631190A (en) * 1994-10-07 1997-05-20 Cree Research, Inc. Method for producing high efficiency light-emitting diodes and resulting diode structures
US5912477A (en) * 1994-10-07 1999-06-15 Cree Research, Inc. High efficiency light emitting diodes
US5650339A (en) * 1994-12-08 1997-07-22 Kabushiki Kaisha Toshiba Method of manufacturing thin film transistor
US5661074A (en) * 1995-02-03 1997-08-26 Advanced Technology Materials, Inc. High brightness electroluminescent device emitting in the green to ultraviolet spectrum and method of making the same
US6120600A (en) * 1995-05-08 2000-09-19 Cree, Inc. Double heterojunction light emitting diode with gallium nitride active layer
US5916460A (en) * 1995-07-07 1999-06-29 Hitachi Cable, Ltd. Method and apparatus for dicing a substrate
US5923053A (en) * 1995-09-29 1999-07-13 Siemens Aktiengesellschaft Light-emitting diode having a curved side surface for coupling out light
US5923690A (en) * 1996-01-25 1999-07-13 Matsushita Electric Industrial Co., Ltd. Semiconductor laser device
US5874747A (en) * 1996-02-05 1999-02-23 Advanced Technology Materials, Inc. High brightness electroluminescent device emitting in the green to ultraviolet spectrum and method of making the same
US6134368A (en) * 1996-08-30 2000-10-17 Nec Corporation Optical semiconductor device with a current blocking structure and method for making the same
US5923946A (en) * 1997-04-17 1999-07-13 Cree Research, Inc. Recovery of surface-ready silicon carbide substrates
US6349104B1 (en) * 1997-05-30 2002-02-19 Denso Corporation Stripe-geometry heterojunction laser diode device
US6946682B2 (en) * 1997-08-29 2005-09-20 Cree, Inc. Robust group III light emitting diode for high reliability in standard packaging applications
US6825501B2 (en) * 1997-08-29 2004-11-30 Cree, Inc. Robust Group III light emitting diode for high reliability in standard packaging applications
US20030025121A1 (en) * 1997-08-29 2003-02-06 Edmond John Adam Robust Group III light emitting diode for high reliability in standard packaging applications
US5972781A (en) * 1997-09-30 1999-10-26 Siemens Aktiengesellschaft Method for producing semiconductor chips
US6201262B1 (en) * 1997-10-07 2001-03-13 Cree, Inc. Group III nitride photonic devices on silicon carbide substrates with conductive buffer interlay structure
US6187606B1 (en) * 1997-10-07 2001-02-13 Cree, Inc. Group III nitride photonic devices on silicon carbide substrates with conductive buffer interlayer structure
US6373077B1 (en) * 1997-10-07 2002-04-16 Cree, Inc. Group III nitride photonic devices on silicon carbide substrates with conductive buffer interlayer structure
US20020110945A1 (en) * 1998-05-18 2002-08-15 Fujitsu Limited Of Kawasaki, Japan Optical semiconductor device having an epitaxial layer of iii-v compound semiconductor material containing n as a group v element
US6459100B1 (en) * 1998-09-16 2002-10-01 Cree, Inc. Vertical geometry ingan LED
US6204161B1 (en) * 1998-10-17 2001-03-20 Samsung Electronics, Co., Ltd. Self aligned contact pad in a semiconductor device and method for forming the same
US6413839B1 (en) * 1998-10-23 2002-07-02 Emcore Corporation Semiconductor device separation using a patterned laser projection
US6255198B1 (en) * 1998-11-24 2001-07-03 North Carolina State University Methods of fabricating gallium nitride microelectronic layers on silicon layers and gallium nitride microelectronic structures formed thereby
US6048748A (en) * 1999-01-14 2000-04-11 Hewlett-Packard Company Advanced semiconductor devices fabricated with passivated high aluminum content III-V materials
US6432788B1 (en) * 1999-07-22 2002-08-13 Implant Sciences Corporation Method for fabricating an emitter-base junction for a gallium nitride bipolar transistor
US20020022290A1 (en) * 1999-10-14 2002-02-21 Hua-Shuang Kong Single step pendeo-and lateral epitaxial overgrowth of group III-nitride epitaxial layers with group III-nitride buffer layer and resulting structures
US20030006425A1 (en) * 2000-02-22 2003-01-09 International Rectifier Corporation Manufacturing process and termination structure for fast recovery diode
US6677173B2 (en) * 2000-03-28 2004-01-13 Pioneer Corporation Method of manufacturing a nitride semiconductor laser with a plated auxiliary metal substrate
US6475889B1 (en) * 2000-04-11 2002-11-05 Cree, Inc. Method of forming vias in silicon carbide and resulting devices and circuits
US6420252B1 (en) * 2000-05-10 2002-07-16 Emcore Corporation Methods of forming robust metal contacts on compound semiconductors
US20020048835A1 (en) * 2000-08-12 2002-04-25 Kwak Joon-Seop Method for manufacturing semiconducter laser diode
US20020034204A1 (en) * 2000-09-14 2002-03-21 Koji Iwamoto Semiconductor laser device and method of manufacturing the same
US20020072250A1 (en) * 2000-12-07 2002-06-13 Hong-Sik Jeong Methods of manufacturing integrated circuit devices having an encapsulated insulation layer
US20020093020A1 (en) * 2001-01-16 2002-07-18 Edmond John Adam Group III nitride LED with undoped cladding layer (5000.137)
US20020123164A1 (en) * 2001-02-01 2002-09-05 Slater David B. Light emitting diodes including modifications for light extraction and manufacturing methods therefor
US20020159494A1 (en) * 2001-04-12 2002-10-31 Tsuyoshi Tojo Semiconductor laser device
US20030006418A1 (en) * 2001-05-30 2003-01-09 Emerson David Todd Group III nitride based light emitting diode structures with a quantum well and superlattice, group III nitride based quantum well structures and group III nitride based superlattice structures
US20030020061A1 (en) * 2001-06-15 2003-01-30 Emerson David Todd Ultraviolet light emitting diode
US20030045015A1 (en) * 2001-07-23 2003-03-06 Slater David B. Flip-chip bonding of light emitting devices and light emitting devices suitable for flip-chip bonding
US20030042507A1 (en) * 2001-07-23 2003-03-06 Slater David B. Bonding of light emitting diodes having shaped substrates and collets for bonding of light emitting diodes having shaped substrates
US20030015721A1 (en) * 2001-07-23 2003-01-23 Slater, David B. Light emitting diodes including modifications for submount bonding and manufacturing methods therefor
US6580054B1 (en) * 2002-06-10 2003-06-17 New Wave Research Scribing sapphire substrates with a solid state UV laser
US20040051118A1 (en) * 2002-07-19 2004-03-18 Bruhns Michael T. Trench cut light emitting diodes and methods of fabricating same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080229142A1 (en) * 2007-03-14 2008-09-18 Microsoft Corporation Self-service recovery of application data

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US7613219B2 (en) 2009-11-03
US20040147054A1 (en) 2004-07-29
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US20080135982A1 (en) 2008-06-12
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US7642626B2 (en) 2010-01-05
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