US1986920A - Electroosmotic process and apparatus - Google Patents
Electroosmotic process and apparatus Download PDFInfo
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- US1986920A US1986920A US619811A US61981132A US1986920A US 1986920 A US1986920 A US 1986920A US 619811 A US619811 A US 619811A US 61981132 A US61981132 A US 61981132A US 1986920 A US1986920 A US 1986920A
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- 238000000034 method Methods 0.000 title description 7
- 239000007788 liquid Substances 0.000 description 17
- 239000012528 membrane Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 11
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 10
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 10
- 235000013922 glutamic acid Nutrition 0.000 description 10
- 239000004220 glutamic acid Substances 0.000 description 10
- 150000002500 ions Chemical class 0.000 description 10
- 235000001014 amino acid Nutrition 0.000 description 8
- 150000001413 amino acids Chemical class 0.000 description 8
- 230000005012 migration Effects 0.000 description 7
- 238000013508 migration Methods 0.000 description 7
- 238000000926 separation method Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 4
- 238000004891 communication Methods 0.000 description 4
- 238000011109 contamination Methods 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- 229930195712 glutamate Natural products 0.000 description 4
- -1 glutamate ions Chemical class 0.000 description 4
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000004475 Arginine Substances 0.000 description 2
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 description 2
- 239000004472 Lysine Substances 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 1
- KDXKERNSBIXSRK-YFKPBYRVSA-N L-lysine Chemical compound NCCCC[C@H](N)C(O)=O KDXKERNSBIXSRK-YFKPBYRVSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/422—Electrodialysis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/42—Electrodialysis; Electro-osmosis ; Electro-ultrafiltration; Membrane capacitive deionization
- B01D61/44—Ion-selective electrodialysis
- B01D61/46—Apparatus therefor
Definitions
- This invention relates to electro-osmotic method and apparatus,'its object being to provide an electro-osmotic cell and a method of operating the same by which more efllcient and exact control of the operation may be secured,
- a further object of the invention is to provide improved electro osmotic apparatus in which separation or recovery is secured not only by migrating eflects, either electrical or by diffusion,
- a further object of the invention is to improve the operation of such apparatus by the counterflow principle, in which flow or travel of the liquid body is produced in a direction contrary to the direction of difiusion of migrating travel of the ions, for any desirable purpose, such as to produce a concentrating effect, or to avoid contamination.
- Fig. 1 is a plan view representing one embodiment of the invention, the containing vessel being shown in section for clearness of illustration;
- Fig. 2 is a sectional elevation on approximately the line 22, Fig. 1;
- Fig. 3 is a view corresponding to Fig. 2 and showing another arrangement;
- Fig. 4 is a similar view showing still another arrangement:
- Fig. 5 is a similar view showing another form.
- the apparatus shown in the drawings comprises a multiple compartment electro-osmotic cell, which, as to its general form and dimensions, as well as tothe form, arrangement and attachment of the semipermeable membranes, may be constructed in any desirable manner, and is shown for convenience in more or less conventional form.
- the apparatus shown in the drawings comprises a multiple compartment electro-osmotic cell, which, as to its general form and dimensions, as well as tothe form, arrangement and attachment of the semipermeable membranes, may be constructed in any desirable manner, and is shown for convenience in more or less conventional form.
- the apparatus shown in the drawings comprises
- cell comprises a hollow vessel 1 divided into a series of compartments by semi-permeable membranes 2 through which diffusion and migration of ions can occur.
- end compartments are located respectively a positive electrode or anode 3 and a negative electrode or cathode 4 connected to any suitable source of current.
- electro-osmotic action occurs with the migration of anions toward the anode and cations toward the cathode through the several semi-permeable membranes.
- I utilize a plurality of semi-permeable 5 membranes, so as to divide the cell to form not only the two end compartments referred to as containing the anode and cathode respectively,- and an intermediate or center compartment, but also one, two or more additional guard compart 10 ments lying between the center compartment and one or the other or both of the end compartments.
- Such guard compartments may be located and utilized in a manner to assist in the control of the action for various purposes, such as for providing more exact separation or collection, or for the avoidance of contamination of one material by the other.
- I have located two of the guard compartments between the middle compartment and each of the two end compartments. That is to say, between the anode compartment 5 and the center compartment 6 I locatetwo anode guard compartments 7, 7a, and between the cathode compartment 8 and the center compartment 6 I locate two cathode guard compartments 9, 9a, the several compartments being formed, as stated, by the provision of the proper semi-permeable membranes 2. Furthermore, I establish communication between each pair of the guard compartments in any suitable manner, such as by a con- .nection of the compartments '7, 7a by a siphon 10 and of compartments 9, 9a by a siphon 11.
- Guard compartment 7 is provided with a supply pipe '12 and compartment 711 with an overflow discharge pipe 13, while guard compartment 9 is provided with a supply pipe 14 and compartment 9a with an'over-flow discharge pipe 15, this arrange- 40 ment enabling a continuous stream of liquid to be supplied to each of the compartments '7, 9, from which the liquid flows or travels by the siphons to the compartments 7a, 9a and thence outwardly therefrom through the discharge pipes 13, 15.
- the material to be treated is supplied to the center compartment 6. If all compartments except the center compartment contain distilled water, simple diffusion will occur through the semi-permeable membranes, so that ultimately crystalline materials dissolved in the liquid supplied to the center compartment will reach all other compartments.
- an electric current is caused to flow through the liquids in the cells, the migration of ions is promoted and accelerated, and, more important, such acceleration varies with different materials. For example, with a mixture of glutamic acid, which is comparatively acid in its properties, with other amino acids which are more basic in character or more nearly neutral, migration of the ions of the glutamic acid is accelerated to a greater degree than the migration of ions of the other acids.
- the counter-flow principle involved in the guard compartment arrangement and operation is here intended and utilized to wash back toward the center cell those substances which are undesired. For example, in the instance given, it is made use of to wash back the other amino acids and to permit the glutamic acid to proceed by reason of the greater acceleration of its ions, for the ultimate purpose of separating glutamic acid from the other amino acids.
- the liquid to be treated containing, for example, glutamic acid and other more basic or more nearly neutral amino acids
- the cell is energized by the passage of electric current water is introduced at 12 and the over-flow at 13 is caught and saved if desired.
- the more slowly migrating ions of the basic and more nearly neutral amino acids are washed back from 7 into 7a by the counter-flow of liquid through the siphon l0 and while this action is proceeding, the migration of the ions of glutamic acid proceeds and is accelerated at a greater rate so that the ions of glutamic acid travel beyond the compartment 7 and into the end compartment 5.
- the ultimate result is the possibility of collecting one substance, such as glutamic acid, in the end compartment, free of contamination with undesirable materials, such as other amino acids, which are washed back toward the center compartment.
- the compartments 7, 7a and 9, 9a are therefore guard compartments which shield the end compartments 5, 8 from receiving undesirable materials which otherwise might reach them.
- the eflect is to utilize the counter-flow principle to wash back or return toward the center compartment and away from the anode (or from the cathode, as the case may be) undesirable substances at a rate fast enough to counteract travel by natural difiusion, but still slow enough so as not to materially interfere with the desired migration of the desirable substances to the anode compartment (or cathode compartment) and its accumulation there.
- the operation may be made more or less continuous and with the further possibility of quite exact regulation of certain conditions in each of the several compartments, such, for example, as the regulation of the hydrogen ion concentration, which is of considerable importance in the separation of various materials from each other, such, for example, as the separation of certain amines as a group from other amines, or the separation of one amine from others of the same group.
- the hydrogen ion concentration arginine, lysine and histidine, all of which have a high isoelectric point, may be separated from other amines, and
- histidine may be separated from arginine and lysine.
- histidine may be separated from arginine and lysine.
- the operation may be carried out as before, with a counter-flow effect or operation in the pairs of guard compartments and with the collection or separation of desirable substances there, but the pH may be readily regulated in .the reservoirs containing the large masses of liquid with a corresponding regulation in the compartments with which they communicate. Furthermore, such an arrangement enables the semipermeable membranes to be placed very close together so as to materially reduce the actual capacities of the compartments themselves, with the possibility of bringing the anode and cathode very close together to reduce the total electric power consumption.
- the large reservoirs offer a means of readily dissipating any heat produced, because they may be readily provided with cooling pipes or other heat dissipating means, as at 17a. Further, the large reservoirs with their larger liquid capacity make it possible to maintain unchanged practically any desired hydrogen ion concentration or any other variable condition, wtihout the rapid or wide fluctuations which occur when the liquid mass is small.
- guard compartment next to an end compartment may be worked in tandem with it.
- the products to be recovered are those which migrate toward the anode, so that guard compartments '7, 7a are located between the center compartment 6 and the anode compartment 5.
- Guard compartment 7 is in circulatory communication, not with the guard compartment 711, as in Fig, 1, but with the end compartment 5, by the siphon 22.
- a constant stream of liquid is introduced into the guard compartment 7, from which it flows toward and into the anode compartment 5 and thence through the discharge pipe 23 to either the sewer or to a reservoir, with the result of continuously and completely washing all anode products out of the cell so as to keep them entirely separate from the material which is to be collected, which is drained off directly from the guard compartment 7a.
- This compartment as shown, is not in circulatory communication with any other compartment.
- Fig. 4 shows another arrangement in which it is desirable to collect only those materials migrating toward the cathode, the guard compartments 9, 90. being in circulatory communication by a siphon 24 in the same manner illustrated in Fig. 1.
- Fig. 5 shows still another arrangement in which a plurality of cells are connected successively to each other for successive action on the same material.
- the cell as a whole may be of the same arrangement shown in Fig. 1 and may be assumed to include all features utilized in connection with the cell of Fig. 1 such as the reservoirs, etc., but in the form shown the center compartment 6 is provided with an in-flow pipe and soon through a series of any number -of' cells.
- the several end compartments of successive cells may communicate, as a result of which some recovery or collection ma occur in any of the compartments of the first cell, such as in the guard compartments or the end compartments, followed by further recovery from the corresponding compartments of each of the following cells.
- . l. Electra-osmotic apparatus, comprising a cell provided with semi-permeable membranes forming two electrode compartments, a center compartment between them, a plurality of guard compartments between the center compartment and each of the electrode compartments, and means for causing flow or travel of liquid from guard compartment to guard compartment independently ln each set of such compartments.
- Electro-osmotic apparatus comprising a cell provided with semi-permeable membranes forming two electrode compartments, a center compartment between them, a plurality of guard compartments between the center compartment and each of the electrode compartments, and means for causing flow or travel of liquid from one of the guard compartments of each set of such compartments toward the corresponding electrode compartment.
Description
Jan. 8, 1935. R, J CROSS ELECTROOSMOTIC PROCESS AND APPARATUS 2 Sheeis-Sheet 1 Filed June '28, 1932 a M I INVEN OR I 056??? cf 55056 ATTORNEYS Jan. 8, 1935. R. J. CROSS ELECTROOSMOTIC PROCESS AND APPARATUS 2 Sheets-Sheet 2 Filed June 28, 1932 INVENTOR Patented Jan. 8, 1935 amc'raoosmonc mocass mm mmrus Ro r I. cr ss M mm h. assignor a s. m. A. ggirporation, Cleveland, Ohio, a corporation of Application June as, 193:, Serial N... 619,811 a claims (c1. 204-1) This invention relates to electro-osmotic method and apparatus,'its object being to provide an electro-osmotic cell and a method of operating the same by which more efllcient and exact control of the operation may be secured,
making it possible to use the method and apparatus for more exact separation or recovery of certain materials, to avoid contamination of one material by another, and to carry out the operation more or less continuously.
A further object of the invention is to provide improved electro osmotic apparatus in which separation or recovery is secured not only by migrating eflects, either electrical or by diffusion,
' but also by flow conduction of the liquid from place to place, either from compartment to compartment, as will appear, or from a compartment or other part of the electro-osmotic cell to a reservoir, to another cell or the like.
A further object of the invention is to improve the operation of such apparatus by the counterflow principle, in which flow or travel of the liquid body is produced in a direction contrary to the direction of difiusion of migrating travel of the ions, for any desirable purpose, such as to produce a concentrating effect, or to avoid contamination.
Further objects ofthe invention are in part obvious and in part will appear more in detail hereinafter.
In the drawings, Fig. 1 isa plan view representing one embodiment of the invention, the containing vessel being shown in section for clearness of illustration; Fig. 2 is a sectional elevation on approximately the line 22, Fig. 1; Fig. 3 is a view corresponding to Fig. 2 and showing another arrangement; Fig. 4 is a similar view showing still another arrangement: Fig. 5 is a similar view showing another form. The apparatus shown in the drawings comprises a multiple compartment electro-osmotic cell, which, as to its general form and dimensions, as well as tothe form, arrangement and attachment of the semipermeable membranes, may be constructed in any desirable manner, and is shown for convenience in more or less conventional form. The
cell comprises a hollow vessel 1 divided into a series of compartments by semi-permeable membranes 2 through which diffusion and migration of ions can occur. In the end compartments are located respectively a positive electrode or anode 3 and a negative electrode or cathode 4 connected to any suitable source of current. Upon energize.- tion of the circuit, with a liquid to be treated 55 in the cell compartments, electro-osmotic action occurs with the migration of anions toward the anode and cations toward the cathode through the several semi-permeable membranes. For various purposes, as will appear more fully hereinafter, I utilize a plurality of semi-permeable 5 membranes, so as to divide the cell to form not only the two end compartments referred to as containing the anode and cathode respectively,- and an intermediate or center compartment, but also one, two or more additional guard compart 10 ments lying between the center compartment and one or the other or both of the end compartments. Such guard compartments may be located and utilized in a manner to assist in the control of the action for various purposes, such as for providing more exact separation or collection, or for the avoidance of contamination of one material by the other.
In the arrangement shown in Figs. 1 and 2, for purposes of illustration and not in any sense of 20 limitation, I have located two of the guard compartments between the middle compartment and each of the two end compartments. That is to say, between the anode compartment 5 and the center compartment 6 I locatetwo anode guard compartments 7, 7a, and between the cathode compartment 8 and the center compartment 6 I locate two cathode guard compartments 9, 9a, the several compartments being formed, as stated, by the provision of the proper semi-permeable membranes 2. Furthermore, I establish communication between each pair of the guard compartments in any suitable manner, such as by a con- .nection of the compartments '7, 7a by a siphon 10 and of compartments 9, 9a by a siphon 11. Guard compartment 7 is provided with a supply pipe '12 and compartment 711 with an overflow discharge pipe 13, while guard compartment 9 is provided with a supply pipe 14 and compartment 9a with an'over-flow discharge pipe 15, this arrange- 40 ment enabling a continuous stream of liquid to be supplied to each of the compartments '7, 9, from which the liquid flows or travels by the siphons to the compartments 7a, 9a and thence outwardly therefrom through the discharge pipes 13, 15.
With such an apparatus the operation is as fol- 1ows:
Assuming liquid in the several compartments at the level indicated in Fig. 2, the material to be treated is supplied to the center compartment 6. If all compartments except the center compartment contain distilled water, simple diffusion will occur through the semi-permeable membranes, so that ultimately crystalline materials dissolved in the liquid supplied to the center compartment will reach all other compartments. However, when an electric current is caused to flow through the liquids in the cells, the migration of ions is promoted and accelerated, and, more important, such acceleration varies with different materials. For example, with a mixture of glutamic acid, which is comparatively acid in its properties, with other amino acids which are more basic in character or more nearly neutral, migration of the ions of the glutamic acid is accelerated to a greater degree than the migration of ions of the other acids. The counter-flow principle involved in the guard compartment arrangement and operation is here intended and utilized to wash back toward the center cell those substances which are undesired. For example, in the instance given, it is made use of to wash back the other amino acids and to permit the glutamic acid to proceed by reason of the greater acceleration of its ions, for the ultimate purpose of separating glutamic acid from the other amino acids.
As a result, the liquid to be treated, containing, for example, glutamic acid and other more basic or more nearly neutral amino acids, is introduced into the center compartment and while the cell is energized by the passage of electric current water is introduced at 12 and the over-flow at 13 is caught and saved if desired. The more slowly migrating ions of the basic and more nearly neutral amino acids are washed back from 7 into 7a by the counter-flow of liquid through the siphon l0 and while this action is proceeding, the migration of the ions of glutamic acid proceeds and is accelerated at a greater rate so that the ions of glutamic acid travel beyond the compartment 7 and into the end compartment 5. The ultimate result is the possibility of collecting one substance, such as glutamic acid, in the end compartment, free of contamination with undesirable materials, such as other amino acids, which are washed back toward the center compartment. The compartments 7, 7a and 9, 9a are therefore guard compartments which shield the end compartments 5, 8 from receiving undesirable materials which otherwise might reach them. Stated in another way, the eflect is to utilize the counter-flow principle to wash back or return toward the center compartment and away from the anode (or from the cathode, as the case may be) undesirable substances at a rate fast enough to counteract travel by natural difiusion, but still slow enough so as not to materially interfere with the desired migration of the desirable substances to the anode compartment (or cathode compartment) and its accumulation there.
If desired, the operation may be made more or less continuous and with the further possibility of quite exact regulation of certain conditions in each of the several compartments, such, for example, as the regulation of the hydrogen ion concentration, which is of considerable importance in the separation of various materials from each other, such, for example, as the separation of certain amines as a group from other amines, or the separation of one amine from others of the same group. Thus, by careful regulation of the hydrogen ion concentration, arginine, lysine and histidine, all of which have a high isoelectric point, may be separated from other amines, and
by more accurate regulation histidine may be separated from arginine and lysine. Such result I accomplish by connecting certain of the compartments of my cell to outside reservoirs, as it compartments themselves, but capable of con- 'taining a larger mass of liquid with the possibility of more exact regulation of-the hydrogen ion concentration in the respective compartments. In Fig. 1, for example, the end compartments 5, 8 communicate respectively with reservoirs 16, 1'7, by way of pumps 18, supply pipes 19 and over-flow pipes 20, while the center compartment fi communicates with a reservoir 21 by a corresponding pump and supply and discharge pipes. The operation may be carried out as before, with a counter-flow effect or operation in the pairs of guard compartments and with the collection or separation of desirable substances there, but the pH may be readily regulated in .the reservoirs containing the large masses of liquid with a corresponding regulation in the compartments with which they communicate. Furthermore, such an arrangement enables the semipermeable membranes to be placed very close together so as to materially reduce the actual capacities of the compartments themselves, with the possibility of bringing the anode and cathode very close together to reduce the total electric power consumption. Again, the large reservoirs offer a means of readily dissipating any heat produced, because they may be readily provided with cooling pipes or other heat dissipating means, as at 17a. Further, the large reservoirs with their larger liquid capacity make it possible to maintain unchanged practically any desired hydrogen ion concentration or any other variable condition, wtihout the rapid or wide fluctuations which occur when the liquid mass is small.
In certain cases, where re-combination with products given oil at either anode or cathode might be injurious to the products desirably recovered, the guard compartment next to an end compartment may be worked in tandem with it. Thus, in Fig. 3 it is assumed that the products to be recovered are those which migrate toward the anode, so that guard compartments '7, 7a are located between the center compartment 6 and the anode compartment 5. Guard compartment 7 is in circulatory communication, not with the guard compartment 711, as in Fig, 1, but with the end compartment 5, by the siphon 22. Here, a constant stream of liquid is introduced into the guard compartment 7, from which it flows toward and into the anode compartment 5 and thence through the discharge pipe 23 to either the sewer or to a reservoir, with the result of continuously and completely washing all anode products out of the cell so as to keep them entirely separate from the material which is to be collected, which is drained off directly from the guard compartment 7a. This compartment, as shown, is not in circulatory communication with any other compartment.
Fig. 4 shows another arrangement in which it is desirable to collect only those materials migrating toward the cathode, the guard compartments 9, 90. being in circulatory communication by a siphon 24 in the same manner illustrated in Fig. 1.
Fig. 5 shows still another arrangement in which a plurality of cells are connected successively to each other for successive action on the same material. The cell as a whole may be of the same arrangement shown in Fig. 1 and may be assumed to include all features utilized in connection with the cell of Fig. 1 such as the reservoirs, etc., but in the form shown the center compartment 6 is provided with an in-flow pipe and soon through a series of any number -of' cells. Likewise, the several end compartments of successive cells may communicate, as a result of which some recovery or collection ma occur in any of the compartments of the first cell, such as in the guard compartments or the end compartments, followed by further recovery from the corresponding compartments of each of the following cells.
v Other arrangements will readily occur to those skilled in the art.
What I claim is:
. l. Electra-osmotic apparatus, comprising a cell provided with semi-permeable membranes forming two electrode compartments, a center compartment between them, a plurality of guard compartments between the center compartment and each of the electrode compartments, and means for causing flow or travel of liquid from guard compartment to guard compartment independently ln each set of such compartments.
2. Electro-osmotic apparatus, comprising a cell provided with semi-permeable membranes forming two electrode compartments, a center compartment between them, a plurality of guard compartments between the center compartment and each of the electrode compartments, and means for causing flow or travel of liquid from one of the guard compartments of each set of such compartments toward the corresponding electrode compartment.
3. The method of separating glutamic acid from a mixture containing less acidic amino acids ing such mixture to an electrical potential to accelerate the passage of glutamate ions through a a semi-permeable membrane at a higher rate of speed than the ions of the less acidic amino acids, simultaneously causing a flow of solution around said membrane in the opposite direction to the movement of the glutamate ions at a rate of sp dcounteracting the diffusion of the less acidic constituents but slow enough not to interfere materially with the progress of the glutamate ions, passing the glutamate ions through another semi-permeable membrane and collecting glutamic acid.
ROBERT J. CROSS.
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US619811A US1986920A (en) | 1932-06-28 | 1932-06-28 | Electroosmotic process and apparatus |
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US619811A US1986920A (en) | 1932-06-28 | 1932-06-28 | Electroosmotic process and apparatus |
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Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2542112A (en) * | 1945-04-16 | 1951-02-20 | Boeing Co | Method of regenerating aluminum anodizing solution |
US2566308A (en) * | 1947-02-07 | 1951-09-04 | Aubrey K Brewer | Process and apparatus for the electrochemical separation of chemicals by ion migration |
US2645610A (en) * | 1942-02-25 | 1953-07-14 | Atomic Energy Commission | Process for the separation of isotopic ions |
US2689826A (en) * | 1950-07-21 | 1954-09-21 | Kollsman Paul | Electrodialytic apparatus |
US2777811A (en) * | 1952-07-22 | 1957-01-15 | Ionics | Treatment of electrolytic solutions |
US2794776A (en) * | 1954-03-16 | 1957-06-04 | Robert E Briggs | Water purification process |
US2848402A (en) * | 1949-04-12 | 1958-08-19 | Tno | Process for electrodialyzing liquids |
US2897130A (en) * | 1956-01-18 | 1959-07-28 | Tno | Apparatus for electrodialyzing liquids |
US3079318A (en) * | 1959-01-15 | 1963-02-26 | Bier Milan | Electrical filtering process and device |
US3136710A (en) * | 1960-09-07 | 1964-06-09 | Sulphite Products Corp | Electrodialysis |
US3144397A (en) * | 1960-04-13 | 1964-08-11 | Stamberg Jiri | Chemical manufacture of germanium and its compounds |
US3179583A (en) * | 1960-07-26 | 1965-04-20 | American Mach & Foundry | Fluid treatment |
US3862893A (en) * | 1974-07-24 | 1975-01-28 | Scm Corp | Electrolytic cell method for transfer of dispersed solids from one liquid electrolyte to another with suppression of transfer of dispersing liquid |
US4605477A (en) * | 1984-03-01 | 1986-08-12 | Mitsubishi Gas Chemical Company, Inc. | Electrodialytic recovery of α-amino acid from its amide |
US4964366A (en) * | 1987-10-30 | 1990-10-23 | Sharp Kabushiki Kaisha | Apparatus for the production of photoconductive components for use in electrophotography |
-
1932
- 1932-06-28 US US619811A patent/US1986920A/en not_active Expired - Lifetime
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2645610A (en) * | 1942-02-25 | 1953-07-14 | Atomic Energy Commission | Process for the separation of isotopic ions |
US2542112A (en) * | 1945-04-16 | 1951-02-20 | Boeing Co | Method of regenerating aluminum anodizing solution |
US2566308A (en) * | 1947-02-07 | 1951-09-04 | Aubrey K Brewer | Process and apparatus for the electrochemical separation of chemicals by ion migration |
US2848402A (en) * | 1949-04-12 | 1958-08-19 | Tno | Process for electrodialyzing liquids |
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US3136710A (en) * | 1960-09-07 | 1964-06-09 | Sulphite Products Corp | Electrodialysis |
US3862893A (en) * | 1974-07-24 | 1975-01-28 | Scm Corp | Electrolytic cell method for transfer of dispersed solids from one liquid electrolyte to another with suppression of transfer of dispersing liquid |
US4605477A (en) * | 1984-03-01 | 1986-08-12 | Mitsubishi Gas Chemical Company, Inc. | Electrodialytic recovery of α-amino acid from its amide |
US4964366A (en) * | 1987-10-30 | 1990-10-23 | Sharp Kabushiki Kaisha | Apparatus for the production of photoconductive components for use in electrophotography |
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