US1679919A - of whiting - Google Patents
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- Publication number
- US1679919A US1679919A US1679919DA US1679919A US 1679919 A US1679919 A US 1679919A US 1679919D A US1679919D A US 1679919DA US 1679919 A US1679919 A US 1679919A
- Authority
- US
- United States
- Prior art keywords
- copper
- mineral oil
- oil
- seeds
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 241000276489 Merlangius merlangus Species 0.000 title 2
- 239000002480 mineral oil Substances 0.000 description 36
- 235000010446 mineral oil Nutrition 0.000 description 34
- 230000000749 insecticidal Effects 0.000 description 20
- 239000000203 mixture Substances 0.000 description 20
- 230000000855 fungicidal Effects 0.000 description 18
- 239000002917 insecticide Substances 0.000 description 18
- 241000196324 Embryophyta Species 0.000 description 16
- 239000000839 emulsion Substances 0.000 description 16
- 239000000417 fungicide Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 229910052802 copper Inorganic materials 0.000 description 14
- 239000010949 copper Substances 0.000 description 14
- 239000003921 oil Substances 0.000 description 14
- 229940108928 Copper Drugs 0.000 description 12
- LSNNMFCWUKXFEE-UHFFFAOYSA-N sulfonic acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 12
- 150000001875 compounds Chemical class 0.000 description 10
- 150000001879 copper Chemical class 0.000 description 10
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 10
- 239000011780 sodium chloride Substances 0.000 description 10
- 239000005749 Copper compound Substances 0.000 description 8
- 241000158728 Meliaceae Species 0.000 description 8
- 150000001880 copper compounds Chemical class 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 8
- 239000000344 soap Substances 0.000 description 8
- 230000002378 acidificating Effects 0.000 description 6
- -1 alkali-metal salts Chemical class 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N Oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-L Sulphite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 4
- 239000003995 emulsifying agent Substances 0.000 description 4
- 125000005608 naphthenic acid group Chemical class 0.000 description 4
- 150000003460 sulfonic acids Chemical class 0.000 description 4
- 241000935926 Diplodia Species 0.000 description 2
- 241000223218 Fusarium Species 0.000 description 2
- 229940059904 Light Mineral Oil Drugs 0.000 description 2
- 241000054817 Lycaena dione Species 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- 239000005662 Paraffin oil Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- 235000014987 copper Nutrition 0.000 description 2
- 229940120693 copper naphthenate Drugs 0.000 description 2
- SVOAENZIOKPANY-CVBJKYQLSA-L copper;(Z)-octadec-9-enoate Chemical compound [Cu+2].CCCCCCCC\C=C/CCCCCCCC([O-])=O.CCCCCCCC\C=C/CCCCCCCC([O-])=O SVOAENZIOKPANY-CVBJKYQLSA-L 0.000 description 2
- 230000000875 corresponding Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 230000001804 emulsifying Effects 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 235000010755 mineral Nutrition 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006011 modification reaction Methods 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 235000005985 organic acids Nutrition 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000010902 straw Substances 0.000 description 2
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
- A01N55/02—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur containing metal atoms
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/28—Compounds containing heavy metals
- A61K31/30—Copper compounds
Definitions
- This invention relates to improvements in insecticides and fungicides, and more particularly to insecticides and fungicides suitable for the treatment of seeds and plants.
- the improved composition comprises a mineral oil, a salt of sulfonic acid derived from mineral oil and anoil-dispersible copper derivative, and is capable of forming a stable lo emulsion With Water which is suitable for application to plants and seeds for insecticidal and fungicidal purposes.
- the emulsifying compound it is preferred to employ as the emulsifying compound the so-called mahogany l soaps or alkali-metal salts of preferentially oil soluble sulfonic acids derived from mineral oil in the manner described in the Humphreys U. S. Patent No. 1,286,17 9 granted November 26, 1918, or in any other suitable manner.
- the copper compound it is preferred to employ the corresponding copper sulfonate or copper sulfonates of the preferentially Water-soluble sulfonic acids, derived from mineral oils in the manner described in Patent No. 1,474,933, granted November 20, 1923, to Humphreys and others, or in any other suitable manner; or we may employ the copper salt of naphthenic acids,
- the naphthenic acids derived, as soaps, from coastal or other crudes Which contain them by treating a lubricant dis-' tillate thereof With alkali and extracting With alcohol.
- the improved product preferably contains about 8 to 25% of the emulsifying agent about 10 to 30% of the copper compound and about to 70% of mineral oil.
- mineral oil employed is preferably a light mineral oil heavier than gasoline, as keroto 'sene, straw oil or the like.
- copper compounds as are herein named, and which are particularly adapted for .the production of freely emulsiliable compositions efficient in use
- other oil dispersible copper derivatives as the copper salts of organic acids, particularly of the fatty acid type (e. g. copper oleate) or the copper salt of mahogany acids may be employed.
- compositions thus constituted are mixed with from 10 to 1000 times their volume of water. Complete emulsion is readily effected and the emulsions are stable and suitable for spraying or otherwise applying to infected plants or seeds.
- the improved insecticide has given greatly increased yields from diseased seeds, particularly Diplodia and Gibberella infected seeds, and is highly effective as a plant spray.
- a composition capable of readily form ing a stable emulsion with Water and efl'ective as an insecticide and fungicide for plants and seeds, comprising a mineral oil, an oil dispersible copper compound and a sallt of sulfonic acid derived from mineral o1 2.
- a composition capable of readily forming a stable emulsion With Water and effective as an insecticide and fungicide for seeds and plants comprising a mineral oil, a compound of copper with an acidic radical. derived from mineral oil, and an emulsifying agent,
- a composition capable of forming a stable emulsion With Water and effective as an insecticide and fungicide for plants and seeds comprising a salt of sulfonic acid dcrived from mineral oil, a compound of cop-- per With an acidic radical derived from mineral oil and a mineral oil.
- composition capable of forming a stable emulsion with Water and cliective as an insecticide and fungicide for plants and seeds comprising a salt of a preferentially oil-soluble sulfonic acid derived from mineral oil, a compound of -copper with an 7 acidic radical derived from mineral oil and a mineral oil.
- a composition capable of forming a stable emulsion with water and effective as an insecticide and fungicide forplants and seeds comprising a salt of a preferentially oil soluble sulfonic acid derived from mineral oil, a compound of copper with a sulfonic acid derived from mineral oil, and mineral oil.
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Veterinary Medicine (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Epidemiology (AREA)
- Pharmacology & Pharmacy (AREA)
- Pest Control & Pesticides (AREA)
- Environmental Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Zoology (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
Patented Aug. 7, 1928.
UNITED STATES I 1,679,919 PATENT OFFICE.
FRANCIS M. ROGERS AND CLAUDE P. MCNEIL, OF WHITING, INDIANA, ASSIGNORS TO STANDARD OIL COMPANY, OF WHI'IING, INDIANA, A CORPORATION OF INDIANA.
INSECTICIDE AND FUNGICIDE.
No Drawing.
This invention relates to improvements in insecticides and fungicides, and more particularly to insecticides and fungicides suitable for the treatment of seeds and plants.
a In accordance with the present invention the improved composition comprises a mineral oil, a salt of sulfonic acid derived from mineral oil and anoil-dispersible copper derivative, and is capable of forming a stable lo emulsion With Water which is suitable for application to plants and seeds for insecticidal and fungicidal purposes.
It is preferred to employ as the emulsifying compound the so-called mahogany l soaps or alkali-metal salts of preferentially oil soluble sulfonic acids derived from mineral oil in the manner described in the Humphreys U. S. Patent No. 1,286,17 9 granted November 26, 1918, or in any other suitable manner. As the copper compound it is preferred to employ the corresponding copper sulfonate or copper sulfonates of the preferentially Water-soluble sulfonic acids, derived from mineral oils in the manner described in Patent No. 1,474,933, granted November 20, 1923, to Humphreys and others, or in any other suitable manner; or we may employ the copper salt of naphthenic acids,
for example, the naphthenic acids derived, as soaps, from coastal or other crudes Which contain them, by treating a lubricant dis-' tillate thereof With alkali and extracting With alcohol.
The improved product preferably contains about 8 to 25% of the emulsifying agent about 10 to 30% of the copper compound and about to 70% of mineral oil. The
mineral oil employed is preferably a light mineral oil heavier than gasoline, as keroto 'sene, straw oil or the like.
Although it is preferred to employ such copper compounds as are herein named, and which are particularly adapted for .the production of freely emulsiliable compositions efficient in use, other oil dispersible copper derivatives, as the copper salts of organic acids, particularly of the fatty acid type (e. g. copper oleate) or the copper salt of mahogany acids may be employed.
The invention will be more fully appreciated from the following examples of pre ferred compositions, but must he understood that these examples are illustrative only and that the invention is not limited thereto, since the invention. comprises innum.
Application filed May 3, 1926. Serial No. 106,549.
erable modifications thereof, within the scope of the appended claims.
Example I.
Per cent. Mahogany soap 18 A; Paraflin oil 61 Copper naphthenate i 13 Water 3 Alcohol 3 35 Example 11.
Per cent. Mahogany soap .4. 11 Paraffin oil 52% Copper sulfonate 28 Oleic acid 1% 50% sodium hydroxide solution Alcohol 3 1 Watci 3X;
In use the compositions thus constituted are mixed with from 10 to 1000 times their volume of water. Complete emulsion is readily effected and the emulsions are stable and suitable for spraying or otherwise applying to infected plants or seeds.
The improved insecticide has given greatly increased yields from diseased seeds, particularly Diplodia and Gibberella infected seeds, and is highly effective as a plant spray.
We claim:
v 1. A composition capable of readily form= ing a stable emulsion with Water and efl'ective as an insecticide and fungicide for plants and seeds, comprising a mineral oil, an oil dispersible copper compound and a sallt of sulfonic acid derived from mineral o1 2. A composition capable of readily forming a stable emulsion With Water and effective as an insecticide and fungicide for seeds and plants comprising a mineral oil, a compound of copper with an acidic radical. derived from mineral oil, and an emulsifying agent,
3. A composition capable of forming a stable emulsion With Water and effective as an insecticide and fungicide for plants and seeds, comprising a salt of sulfonic acid dcrived from mineral oil, a compound of cop-- per With an acidic radical derived from mineral oil and a mineral oil.
t A composition capable of forming a stable emulsion with Water and cliective as an insecticide and fungicide for plants and seeds, comprising a salt of a preferentially oil-soluble sulfonic acid derived from mineral oil, a compound of -copper with an 7 acidic radical derived from mineral oil and a mineral oil.
5. A composition capable of forming a stable emulsion with water and effective as an insecticide and fungicide forplants and seeds, comprising a salt of a preferentially oil soluble sulfonic acid derived from mineral oil, a compound of copper with a sulfonic acid derived from mineral oil, and mineral oil.
6.'A composition capable of forming a
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US1679919A true US1679919A (en) | 1928-08-07 |
Family
ID=3415725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US1679919D Expired - Lifetime US1679919A (en) | of whiting |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US1679919A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2534277A (en) * | 1946-02-19 | 1950-12-19 | Sonneborn Sons Inc L | Crystallization point depressants for ddt hydrocarbon solutions and fungicidal insecticides obtained thereby |
| US2534278A (en) * | 1950-12-19 | Crystallization point depressants | ||
| US2577969A (en) * | 1944-08-17 | 1951-12-11 | American Chem Paint Co | Compositions for killing weeds |
| US2944936A (en) * | 1954-06-25 | 1960-07-12 | Richfield Oil Corp | Powdered composition consisting essentially of pentachlorophenol and a member of the group of metal naphthenates and mahogany sulfonates |
| US2951789A (en) * | 1955-12-27 | 1960-09-06 | Pan American Petroleum Corp | Preservative composition for cellulosic materials comprising heavy metal soaps |
| US4003994A (en) * | 1973-05-15 | 1977-01-18 | Texaco Trinidad, Inc. | Copper-alkaline earth metal fungicidal compositions |
| US20110129545A1 (en) * | 2001-12-20 | 2011-06-02 | Frank Miele | Method of protecting vascular plants against pathogens |
-
0
- US US1679919D patent/US1679919A/en not_active Expired - Lifetime
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2534278A (en) * | 1950-12-19 | Crystallization point depressants | ||
| US2577969A (en) * | 1944-08-17 | 1951-12-11 | American Chem Paint Co | Compositions for killing weeds |
| US2534277A (en) * | 1946-02-19 | 1950-12-19 | Sonneborn Sons Inc L | Crystallization point depressants for ddt hydrocarbon solutions and fungicidal insecticides obtained thereby |
| US2944936A (en) * | 1954-06-25 | 1960-07-12 | Richfield Oil Corp | Powdered composition consisting essentially of pentachlorophenol and a member of the group of metal naphthenates and mahogany sulfonates |
| US2951789A (en) * | 1955-12-27 | 1960-09-06 | Pan American Petroleum Corp | Preservative composition for cellulosic materials comprising heavy metal soaps |
| US4003994A (en) * | 1973-05-15 | 1977-01-18 | Texaco Trinidad, Inc. | Copper-alkaline earth metal fungicidal compositions |
| US20110129545A1 (en) * | 2001-12-20 | 2011-06-02 | Frank Miele | Method of protecting vascular plants against pathogens |
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