US1549615A - Hard-metal alloy and the process of making same - Google Patents

Hard-metal alloy and the process of making same Download PDF

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Publication number
US1549615A
US1549615A US672014A US67201423A US1549615A US 1549615 A US1549615 A US 1549615A US 672014 A US672014 A US 672014A US 67201423 A US67201423 A US 67201423A US 1549615 A US1549615 A US 1549615A
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United States
Prior art keywords
metal
hard
alloy
metal alloy
making same
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Expired - Lifetime
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US672014A
Inventor
Schroter Karl
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General Electric Co
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General Electric Co
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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C29/00Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
    • C22C29/02Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides
    • C22C29/06Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds
    • C22C29/08Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on carbides or carbonitrides based on carbides, but not containing other metal compounds based on tungsten carbide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S76/00Metal tools and implements, making
    • Y10S76/05Electric welding
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S76/00Metal tools and implements, making
    • Y10S76/11Tungsten and tungsten carbide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S76/00Metal tools and implements, making
    • Y10S76/12Diamond tools
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T407/00Cutters, for shaping
    • Y10T407/27Cutters, for shaping comprising tool of specific chemical composition

Definitions

  • -My invention relates tohard metal alloys. More particularly, it relates to alloyed tun stic' carbide which alloy is suitable for making working implements-of various sorts and hones.
  • auxil'ia metalof a considerably lower melting p'omt as, for instance, iron, cobalt or nickel, in quantitles' up to a maximum of p 10- per cent.
  • a tungstic' metal thus consti- To make the new allo s,--'it carbide. containing from 3 to 10 per cent carif. occurs .at t'emperaturesjwhichd-ie in the neighborhood of 1000 degrees belowjthe. 9:
  • the new alloy is not interior fin res eat to hardness to the known tiihgstic carbi e alloys and is quiteconsiderably sir-- to press into a body' oi pulvcrized-rtungstic "together with' a'nflauxiliary' metal? in 'a divided state and in a quantity-within sinteringjtemperature.
  • the alloy of invention difiers from" 's advantageous.
  • iron, cobaltor nickel. base metals may be m a'finely divided form.
  • the tem'- perature at which the sinterin occurs, is. affected by the quantity oi the. a 'xed'aux'-' iliary metal, which can be'pm ade as high as 10 cent of the alloy.
  • admixture of 5 per cent cobalt has proved- 7o two or several of the auxiliary metalsma 76 be addedv toe-the tungstic powder-in whic case'the auxil ary, metals can be taken-in- -any suitable ratio to each.
  • b t 5 3 must not, all told, make up more than 10, 1 per cent of the total qggntity 'of thefalloy 'Iihe sintering of the dies, wh chibodies areiormedv for instance by hydraulicipressure, can be efiected' by heating'them--in- ⁇ a h protective atmosphere such as'a-n atmosphere" of hydrogen, nitrogen, argon, illuminating 88 gas, carbonic oxide, or an admixture ofsuch gases, or the sintering can be-e'fi'ecte'd by embedding 1: e'bodies in carboni-graphiteand; the like.
  • Siiitable- 1 temperature ay be found between 1 500. andf gqq v grees'C-.fa
  • a hard-metal allo comprising a ca'r alloy having, inaddition, a metalgofa con:
  • H ranges from 3 to 10% of the tungsten, said: alloy having iron, the latter forming not more than 10% of the content.
  • the proportions of the tungsten carbon and of the metal being respectively not more than 80% of tungsten, 10% of carbon and 10% of the metal.

Description

' Aug-1 11",: l
. NITEDf ESTATE-S.
sc'n n'ogmn'br 15mm, 01mm, 'nssrenon roommat- M1329 0011mm, A-conrom'nouon NEW 2031:. p I
m i na I i ibima ma mmam Be it known that PI, KARI: '8"
citizen: qt thefGerman Realm, residingat Lichtenberg, near Berlin, Germany, have-1nin Hardf Metal Alloys and the Processes of vented certain new and useful Improvements Making T'Same, of which the following is a which is {particularly suitablefor making known alloys primarily'by'consisting of a" tungstic carbide with a carbon content of from 4: to 10 percent, in combination with specification. 1-
-My invention relates tohard metal alloys. More particularly, it relates to alloyed tun stic' carbide which alloy is suitable for making working implements-of various sorts and hones.
an auxil'ia metalof a considerably lower melting; p'omt as, for instance, iron, cobalt or nickel, in quantitles' up to a maximum of p 10- per cent. A tungstic' metal thus consti- To make the new allo s,--'it carbide. containing from 3 to 10 per cent carif. occurs .at t'emperaturesjwhichd-ie in the neighborhood of 1000 degrees belowjthe. 9:
-- perioi" to: these for strength.
Q -fin'ely J thelimits specified, and to heat this Body to .j 35. auxih 'e.
tutes the .pr'edominating element amounting I te at least '80 per cent of the total content -'of'the alloy.- The new alloy is not interior fin res eat to hardness to the known tiihgstic carbi e alloys and is quiteconsiderably sir-- to press into a body' oi pulvcrized-rtungstic "together with' a'nflauxiliary' metal? in 'a divided state and in a quantity-within sinteringjtemperature. -The effect of the 7 ;metal is to" reducethe' sintering point o body to such' an extent that it '-;.:1;, going method is considerably cheaper easier and simpler than the methods used hereto: :iore inthe prior methodsiand: a temperature of them 2500degrees must ,be. obtained." Another ob'ect of 'myjinvention-"is' that inasmuch-as tehody maybe pr, sintered in a manner well known,"itii;-os j" sible'to make the-'bodyintoany desired'form, such" as. is obtained. onlyjwith. greatflifliv v h a e p d d .ei Powder from h m hw; q y
when other processes are used.
- and ear-bide can be i sed as the main-materia carbl fri'zingtung Applicationflled emb r-en; was. Serial no. 072.014.
The alloy of invention difiers from" 's advantageous.
ing-point'ofthe purecarbide. The-forc v p v bide of-tungstemthe'car oncontent of which. ranges from 3 to;10%T;'f' the tu'n gsten, said 91;
ofo-the tungsten content.
'2.- A hard metal all y comprising I akm'g the new. na pnlverizedjtungi t 1,549,615 PATENT. OFFICE-. 3,
J nan-gnu, nil-pox Ann me mom or MAKING sum Ra'ssuw 1 ing the tnngstic powder with carbon; --The 56 carbon may .be 'of' soot, sugar 'of carbon," graphite and the like, A carbon content. of
'7' 'per cent has proved especially favorable, 1
but it can be varied home to 10' "er c'enti A.met'al which can be reduce by. h dromelting point than 'the tungstie @enbide is suitable for use'as the auxilia' metal, for
example, iron, cobaltor nickel. base metals may be m a'finely divided form. The tem'- perature at which the sinterin occurs, is. affected by the quantity oi the. a 'xed'aux'-' iliary metal, which can be'pm ade as high as 10 cent of the alloy. For instance, admixture of 5 per cent cobalt has proved- 7o two or several of the auxiliary metalsma 76 be addedv toe-the tungstic powder-in whic case'the auxil ary, metals can be taken-in- -any suitable ratio to each. other, b t 5 3 must not, all told, make up more than 10, 1 per cent of the total qggntity 'of thefalloy 'Iihe sintering of the dies, wh chibodies areiormedv for instance by hydraulicipressure, can be efiected' by heating'them--in-}a h protective atmosphere such as'a-n atmosphere" of hydrogen, nitrogen, argon, illuminating 88 gas, carbonic oxide, or an admixture ofsuch gases, or the sintering can be-e'fi'ecte'd by embedding 1: e'bodies in carboni-graphiteand; the like. Siiitable- 1 temperature ay be found between 1 500. andf gqq v grees'C-.fa
, Wh t I claim as new and desire to secure by-Letters Patent'of the'UnjitedfStates, :isf'z' 1. A hard-metal allo comprising a ca'r alloy having, inaddition, a metalgofa con:
bide, said metal forming'not more the bide of tungsten,- the carbon content ciwhich es fiamat 10% of the tungsten',l.said.- alloy having ametal 'of the iron group, the.
latter 'formingnot f'more. than 10% of the tungsten content.
i wj u me a v a w if a gen and which has a considerably ower .3.;9A. hard metal alloy" comprising .a car? H ranges from 3 to 10% of the tungsten, said: alloy having iron, the latter forming not more than 10% of the content.
4;. The method of making an alloy of a carbide of tungsten and a metal which consists in bringing, together a pulverized tun'ge sten carbide and a quantity of finely divided metal, mixing said materiaIsand pressing them into forms and heating the forms to sintering temperature;
5.. The method of. making an alloy of a. carbide of'tungsten and a metal which conslsts in bringing together a pulverized tungsten carbide, said carbide having a carbon content within the ranges of from 3 to 10%,
- of thecarbide, the proportions of the tungsten carbon and of the metal being respectively not more than 80% of tungsten, 10% of carbon and 10% of the metal.
In Witness whereof, I have hereunto set my hand this 8th day of October, 1923.
KARL scHRoTER.
US672014A 1923-10-31 1923-10-31 Hard-metal alloy and the process of making same Expired - Lifetime US1549615A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2735421A (en) * 1951-10-22 1956-02-21 Shaping of bodies of crystalline carbon
US2798474A (en) * 1951-09-18 1957-07-09 Deutsche Edelstahlwerke Ag Hard-metal containing mixtures and processes of applying them to supporting bodies and supporting bodies so treated
US4452325A (en) * 1982-09-27 1984-06-05 Conoco Inc. Composite structure for cutting tools
US20050025657A1 (en) * 2003-07-25 2005-02-03 Sandvik Ab Method of making a fine grained cemented carbide
US8778259B2 (en) 2011-05-25 2014-07-15 Gerhard B. Beckmann Self-renewing cutting surface, tool and method for making same using powder metallurgy and densification techniques
US9640746B2 (en) 2013-01-22 2017-05-02 California Institute Of Technology High performance high temperature thermoelectric composites with metallic inclusions

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2798474A (en) * 1951-09-18 1957-07-09 Deutsche Edelstahlwerke Ag Hard-metal containing mixtures and processes of applying them to supporting bodies and supporting bodies so treated
US2735421A (en) * 1951-10-22 1956-02-21 Shaping of bodies of crystalline carbon
US4452325A (en) * 1982-09-27 1984-06-05 Conoco Inc. Composite structure for cutting tools
US20050025657A1 (en) * 2003-07-25 2005-02-03 Sandvik Ab Method of making a fine grained cemented carbide
US20060029511A1 (en) * 2003-07-25 2006-02-09 Sandvik Ab Method of making a fine grained cemented carbide
US8778259B2 (en) 2011-05-25 2014-07-15 Gerhard B. Beckmann Self-renewing cutting surface, tool and method for making same using powder metallurgy and densification techniques
US9640746B2 (en) 2013-01-22 2017-05-02 California Institute Of Technology High performance high temperature thermoelectric composites with metallic inclusions

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