EP2645022A2 - Passive thermally regulated shipping container employing phase change material panels containing dual immiscible phase change materials - Google Patents
Passive thermally regulated shipping container employing phase change material panels containing dual immiscible phase change materials Download PDFInfo
- Publication number
- EP2645022A2 EP2645022A2 EP13159788.2A EP13159788A EP2645022A2 EP 2645022 A2 EP2645022 A2 EP 2645022A2 EP 13159788 A EP13159788 A EP 13159788A EP 2645022 A2 EP2645022 A2 EP 2645022A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- phase change
- shipping container
- thermally regulated
- change materials
- passive thermally
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D3/00—Devices using other cold materials; Devices using cold-storage bodies
- F25D3/02—Devices using other cold materials; Devices using cold-storage bodies using ice, e.g. ice-boxes
- F25D3/06—Movable containers
- F25D3/08—Movable containers portable, i.e. adapted to be carried personally
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D81/00—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents
- B65D81/38—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents with thermal insulation
- B65D81/3813—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents with thermal insulation rigid container being in the form of a box, tray or like container
- B65D81/3823—Containers, packaging elements, or packages, for contents presenting particular transport or storage problems, or adapted to be used for non-packaging purposes after removal of contents with thermal insulation rigid container being in the form of a box, tray or like container formed of different materials, e.g. laminated or foam filling between walls
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2303/00—Details of devices using other cold materials; Details of devices using cold-storage bodies
- F25D2303/08—Devices using cold storage material, i.e. ice or other freezable liquid
- F25D2303/082—Devices using cold storage material, i.e. ice or other freezable liquid disposed in a cold storage element not forming part of a container for products to be cooled, e.g. ice pack or gel accumulator
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2303/00—Details of devices using other cold materials; Details of devices using cold-storage bodies
- F25D2303/08—Devices using cold storage material, i.e. ice or other freezable liquid
- F25D2303/084—Position of the cold storage material in relationship to a product to be cooled
- F25D2303/0843—Position of the cold storage material in relationship to a product to be cooled on the side of the product
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25D—REFRIGERATORS; COLD ROOMS; ICE-BOXES; COOLING OR FREEZING APPARATUS NOT OTHERWISE PROVIDED FOR
- F25D2303/00—Details of devices using other cold materials; Details of devices using cold-storage bodies
- F25D2303/08—Devices using cold storage material, i.e. ice or other freezable liquid
- F25D2303/085—Compositions of cold storage materials
Definitions
- Thermally labile goods are frequently transported or shipped in passive thermally regulated shipping containers to prevent spoilage, decomposition, deactivation, transformation, conversion, breakdown, denaturing, etc.
- PCM phase change material
- Insulated shipping containers employing a PCM can be deployed for a wide range of thermally labile goods over a wide range of target temperatures by using different PCMs.
- D 2 O melts at +4 °C
- H 2 O melts at 0 °C
- a 20% ethylene glycol solution melts at -8 °C
- castor oil melts at -10 °C
- mineral oil melts at -30 °C
- a 50% ethylene glycol solution melts at -37 °C This permits use of insulted shipping containers for a broad range of thermally labile goods.
- the shipper needs to purchase and inventory a sufficient number of PCM panels containing each of the different PCMs to meet the highest possible demand for that type of PCM panel.
- a shipper typically has between about 800 and 1,200 passive thermally regulated shipping containers in transport on any given day, each of which employ six PCM panels and all of which could require one of two different PCM panels containing different PCM.
- This shipper would need to purchase, inventory, track and maintain 14,400 PCM panels ((1,200 containers)(6 PCM panels/container)(2 PCM panel types)).
- the need to purchase, track and maintain such a large number of PCM panels can become cost prohibitive.
- the invention is a passive thermally regulated shipping container.
- the container has an outer shell, a layer of thermal insulation, and a phase change material panel (PCM panel).
- the outer shell defines a retention chamber.
- the layer of thermal insulation lines the retention chamber so as to define an insulated retention chamber.
- the PCM panel is removably positioned within the insulated retention chamber, and contains dual immiscible phase change materials having different freezing points.
- Figure 1 is an exploded isometric view of one embodiment of the invention.
- Figure 2A is a cross-sectional view of the fully assembled container depicted in FIG. 1 employing phase change panels that have been thermally conditioned in a horizontal position below the freezing point of both phase change materials.
- Figure 2B is a cross-sectional view of the fully assembled container depicted in FIG. 1 employing phase change panels that have been thermally conditioned in a vertical position below the freezing point of both phase change materials.
- removable means capable of being inserted and removed without application of violent force and without damage or destruction.
- the term "immiscible" means insoluble such that the liquids form separate layers, each of which have a separate and independent melting point such that one layer can be frozen into a solid while the other layer remains a liquid.
- the invention is a passive thermally regulated shipping container 10 .
- the container 10 has an outer shell 20 , a layer of thermal insulation 30 , and at least one phase change material panel (PCM panel) 40 .
- PCM panel phase change material panel
- the outer shell 20 defines a retention chamber.
- the outer shell 20 may be made from any material possessing sufficient structural integrity, including specifically but not exclusively, cellulosic materials such as paperboard and cardboard, engineered wood products such as laminated and unlaminated fiberboard and plywood, wood, plastics such as polyethylene, polypropylene, polyethylene terephthalate, nylon polycarbonates and phenolic resins, wood-plastic composites, metals such as aluminum, copper, brass and steel, glass, ceramics, combinations thereof, and the like.
- the layer of thermal insulation 30 lines the retention chamber 19 so as to define an insulated retention chamber (not separately numbered).
- the layer of thermal insulation 30 may be formed as a single unitary piece with a removable cover (not shown) or as separate panels such as shown in FIGs 1 , 2A and 2B .
- the thermal insulation may be constructed from any material having good thermal insulating qualities, ( i.e. , having a high thermal resistance "R"), such as Styrofoam, vacuum insulated panels, or the like.
- the PCM panel 40 is removably positioned within the insulated retention chamber, and contains dual immiscible phase change materials ( 51 and 52 ) having different freezing points.
- the container 10 includes at least one phase change material panel (PCM panel) 40 and preferably includes a plurality of planar PCM panels 40 configured and arranged for lining the insulated retention chamber.
- PCM panel phase change material panel
- each PCM panel 40 By filling each PCM panel 40 with dual immiscible phase change materials ( 51 and 52) having different freezing points, a single PCM panel 40 can be used for shipping thermally labile goods at two different target temperatures by thermally conditioning the PCM panels 40 at the desired target temperature.
- Such PCM panels 40 thermally conditioned at a temperature below the melting point of the water but above the melting point of the castor oil allows the thermally conditioned PCM panels to regulate the temperature of a insulated retention chamber 19 at a temperature of 0°C, while such PCM panels 40 thermally conditioned at a temperature below the melting point of the castor oil allows the thermally conditioned PCM panels to regulate the temperature of a insulated retention chamber 19 at a temperature of -10°C. This avoids the need to purchase, inventory and track separate PCM panels.
- phase change materials need to be immiscible as soluble or miscible PCMs do not retain their individual melting points.
- PCMs phase change materials
- water and ethylene glycol are miscible and produce a mixture which has a single melting point (e.g., a 20% ethylene glycol solution melts at -8 °C).
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Packages (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
Abstract
Description
- Thermally labile goods are frequently transported or shipped in passive thermally regulated shipping containers to prevent spoilage, decomposition, deactivation, transformation, conversion, breakdown, denaturing, etc.
- Transportation of thermally labile goods is particularly challenging when the thermally labile goods must be maintained within a narrow temperature range. Numerous insulated shipping containers have been developed over the years, with those deploying a phase change material (PCM) generally providing superior temperature control over extended periods. A nonexhaustive list of United States Patents and Published Patent Applications disclosing insulated shipping containers employing a PCM include United States Patents
4,145,895 ;4,579,170 ;4,923,077 ;4,931,333 ;5,626,936 ;5,899,088 ;6,209,343 and6,718,776 , and United States Patent Application Publications2005/0188714 ;2004/0079794 ;2004/0079793 and2002/0050147 . - Insulated shipping containers employing a PCM can be deployed for a wide range of thermally labile goods over a wide range of target temperatures by using different PCMs. For example, D2O melts at +4 °C, H2O melts at 0 °C, a 20% ethylene glycol solution melts at -8 °C, castor oil melts at -10 °C, neat ethylene glycol melts at -12.9 °C, mineral oil melts at -30 °C, and a 50% ethylene glycol solution melts at -37 °C. This permits use of insulted shipping containers for a broad range of thermally labile goods. However, in order to accommodate the packaging of a wide variety of thermally labile goods, the shipper needs to purchase and inventory a sufficient number of PCM panels containing each of the different PCMs to meet the highest possible demand for that type of PCM panel. For example, assume that a shipper typically has between about 800 and 1,200 passive thermally regulated shipping containers in transport on any given day, each of which employ six PCM panels and all of which could require one of two different PCM panels containing different PCM. This shipper would need to purchase, inventory, track and maintain 14,400 PCM panels ((1,200 containers)(6 PCM panels/container)(2 PCM panel types)). The need to purchase, track and maintain such a large number of PCM panels can become cost prohibitive.
- Accordingly, a substantial need exists for a system of packaging thermally labile goods that reduces the total number of PCM panels that need to be purchased, tracked and maintained by a shipper.
- The invention is a passive thermally regulated shipping container. The container has an outer shell, a layer of thermal insulation, and a phase change material panel (PCM panel). The outer shell defines a retention chamber. The layer of thermal insulation lines the retention chamber so as to define an insulated retention chamber. The PCM panel is removably positioned within the insulated retention chamber, and contains dual immiscible phase change materials having different freezing points.
-
Figure 1 is an exploded isometric view of one embodiment of the invention. -
Figure 2A is a cross-sectional view of the fully assembled container depicted inFIG. 1 employing phase change panels that have been thermally conditioned in a horizontal position below the freezing point of both phase change materials. -
Figure 2B is a cross-sectional view of the fully assembled container depicted inFIG. 1 employing phase change panels that have been thermally conditioned in a vertical position below the freezing point of both phase change materials. - As utilized herein, including the claims, the term " removable " means capable of being inserted and removed without application of violent force and without damage or destruction.
- As utilized herein, including the claims, the term "immiscible" means insoluble such that the liquids form separate layers, each of which have a separate and independent melting point such that one layer can be frozen into a solid while the other layer remains a liquid.
-
- 10
- Passive Thermally Regulated Shipping Container
- 19
- Payload Retention Chamber
- 20
- Outer Structural Shell
- 30
- Thermal Insulation
- 40
- Phase Change Material Panels (PCM Panel)
- 51
- Higher Density First Phase Change Material
- 52
- Lower Density Second Phase Change Material
- Referring generally to
FIGs 1 ,2A and2B , the invention is a passive thermally regulatedshipping container 10. Thecontainer 10 has anouter shell 20, a layer ofthermal insulation 30, and at least one phase change material panel (PCM panel) 40. - The
outer shell 20 defines a retention chamber. Theouter shell 20 may be made from any material possessing sufficient structural integrity, including specifically but not exclusively, cellulosic materials such as paperboard and cardboard, engineered wood products such as laminated and unlaminated fiberboard and plywood, wood, plastics such as polyethylene, polypropylene, polyethylene terephthalate, nylon polycarbonates and phenolic resins, wood-plastic composites, metals such as aluminum, copper, brass and steel, glass, ceramics, combinations thereof, and the like. - The layer of
thermal insulation 30 lines theretention chamber 19 so as to define an insulated retention chamber (not separately numbered). The layer ofthermal insulation 30 may be formed as a single unitary piece with a removable cover (not shown) or as separate panels such as shown inFIGs 1 ,2A and2B . The thermal insulation may be constructed from any material having good thermal insulating qualities, (i.e., having a high thermal resistance "R"), such as Styrofoam, vacuum insulated panels, or the like. - The
PCM panel 40 is removably positioned within the insulated retention chamber, and contains dual immiscible phase change materials (51 and 52) having different freezing points. - The
container 10 includes at least one phase change material panel (PCM panel) 40 and preferably includes a plurality ofplanar PCM panels 40 configured and arranged for lining the insulated retention chamber. - By filling each
PCM panel 40 with dual immiscible phase change materials (51 and 52) having different freezing points, asingle PCM panel 40 can be used for shipping thermally labile goods at two different target temperatures by thermally conditioning thePCM panels 40 at the desired target temperature. For example, PCM panels containing 50% v/v water (0°C melting point) and 50% v/v castor oil (-10 °C melting point).Such PCM panels 40 thermally conditioned at a temperature below the melting point of the water but above the melting point of the castor oil allows the thermally conditioned PCM panels to regulate the temperature of a insulatedretention chamber 19 at a temperature of 0°C, whilesuch PCM panels 40 thermally conditioned at a temperature below the melting point of the castor oil allows the thermally conditioned PCM panels to regulate the temperature of a insulatedretention chamber 19 at a temperature of -10°C. This avoids the need to purchase, inventory and track separate PCM panels. - The phase change materials (PCMs) need to be immiscible as soluble or miscible PCMs do not retain their individual melting points. For example water and ethylene glycol are miscible and produce a mixture which has a single melting point (e.g., a 20% ethylene glycol solution melts at -8 °C).
- Exemplary combinations of immiscible PCMs are provided in TABLE ONE.
-
EXAMPLE HYDROPHILIC PCM HYDROPHOBIC PCM A Water n-Octadecane B Salt Water n-Octadecane C Water n-Tetradecane D Salt Water n-Tetradecane E Water n-Heptadecane F Ethylene Glycol and Water n-Octadecane G Ethylene Glycol and Water n-Tetradecane
Claims (8)
- A passive thermally regulated shipping container, comprising:a. an outer shell defining a retention chamber,b. a layer of thermal insulation lining the retention chamber so as to define an insulated retention chamber, andc. a removable phase change material panel positioned within the insulated retention chamber, wherein the phase change material panel contains dual immiscible phase change materials having different freezing points.
- The passive thermally regulated shipping container of claim 1, wherein the thermal insulation is vacuum insulated panels.
- The passive thermally regulated shipping container of claim 1 or 2, comprising a plurality of the removable phase change material panels lining the insulated retention chamber.
- The passive thermally regulated shipping container of any of claims 1 to 3, wherein one of the immiscible phase change materials is water.
- The passive thermally regulated shipping container of any of claims 1 to 4, wherein one of the immiscible phase change materials is ethylene glycol.
- A passive thermally regulated shipping container of any of claims 1 to 5, wherein one of the immiscible phase change materials is a paraffin which is liquid at room temperature.
- A passive thermally regulated shipping container of any of claims 1 to 5, wherein one of the immiscible phase change materials is a paraffin which is solid at room temperature.
- The passive thermally regulated shipping container of any of claims 1 to 7, wherein one of the immiscible phase change materials is salt water.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US13/430,794 US20130255306A1 (en) | 2012-03-27 | 2012-03-27 | Passive thermally regulated shipping container employing phase change material panels containing dual immiscible phase change materials |
Publications (2)
Publication Number | Publication Date |
---|---|
EP2645022A2 true EP2645022A2 (en) | 2013-10-02 |
EP2645022A3 EP2645022A3 (en) | 2015-11-11 |
Family
ID=48045260
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP13159788.2A Withdrawn EP2645022A3 (en) | 2012-03-27 | 2013-03-18 | Passive thermally regulated shipping container employing phase change material panels containing dual immiscible phase change materials |
Country Status (2)
Country | Link |
---|---|
US (1) | US20130255306A1 (en) |
EP (1) | EP2645022A3 (en) |
Cited By (1)
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GB2551115A (en) * | 2016-05-31 | 2017-12-13 | Laminar Medica Ltd | A thermally insulated container |
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EP2200904B1 (en) | 2007-09-11 | 2013-06-26 | Cold Chain Technologies, Inc. | Insulated pallet shipper |
KR101697113B1 (en) * | 2010-09-06 | 2017-01-18 | 삼성전자주식회사 | Refrigerator |
WO2016011207A1 (en) | 2014-07-15 | 2016-01-21 | Ron Nagar | Devices, systems and methods for controlling conditions and delivery of substances |
GB2534910C (en) * | 2015-02-05 | 2021-10-27 | Laminar Medica Ltd | A Thermally Insulated Container and Method for Making Same |
US10661969B2 (en) | 2015-10-06 | 2020-05-26 | Cold Chain Technologies, Llc | Thermally insulated shipping system for pallet-sized payload, methods of making and using the same, and kit for use therein |
US11964795B2 (en) | 2015-10-06 | 2024-04-23 | Cold Chain Technologies, Llc | Device comprising one or more temperature-control members and kit for use in making the device |
US11591133B2 (en) | 2015-10-06 | 2023-02-28 | Cold Chain Technologies, Llc | Pallet cover comprising one or more temperature-control members and kit for use in making the pallet cover |
US10583978B2 (en) | 2015-10-06 | 2020-03-10 | Cold Chain Technologies, Llc | Pallet cover compromising one or more temperature-control members and kit for use in making the pallet cover |
WO2017062675A2 (en) | 2015-10-06 | 2017-04-13 | Cold Chain Technologies, Inc. | Pallet cover comprising one or more temperature-control members and kit for use in making the pallet cover |
US9890988B2 (en) * | 2016-04-27 | 2018-02-13 | Bae Systems Plc | High temperature resistant shipping container |
US20170350635A1 (en) * | 2016-06-06 | 2017-12-07 | Google Inc. | Container with passive temperature controls |
GB201611031D0 (en) * | 2016-06-24 | 2016-08-10 | Softbox Systems Ltd | A passive temperature control system for transport and storage containers |
GB201611050D0 (en) * | 2016-06-24 | 2016-08-10 | Softbox Systems Ltd | A passive temperature control system for transport and storage containers |
US11511928B2 (en) | 2017-05-09 | 2022-11-29 | Cold Chain Technologies, Llc | Shipping system for storing and/or transporting temperature-sensitive materials |
EP3634879B1 (en) | 2017-05-09 | 2023-11-01 | Cold Chain Technologies, LLC | Shipping system for storing and/or transporting temperature-sensitive materials |
AU201717676S (en) | 2017-12-14 | 2018-01-16 | Dometic Sweden Ab | Zip Puller |
USD904830S1 (en) | 2017-12-14 | 2020-12-15 | Dometic Sweden Ab | Soft bag cooler |
CN112136012A (en) | 2018-04-19 | 2020-12-25 | 恩伯技术公司 | Portable cooler with active temperature control |
AT520919B1 (en) * | 2018-05-29 | 2019-09-15 | Rep Ip Ag | Transport container for transporting temperature-sensitive cargo |
SG11202012328VA (en) | 2018-06-15 | 2021-01-28 | Cold Chain Technologies Llc | Shipping system for storing and/or transporting temperature-sensitive materials |
MX2021004595A (en) * | 2018-10-24 | 2021-06-15 | Ron Nagar | Devices, systems and methods for controlling environmental conditions of substances. |
KR20210113233A (en) | 2019-01-11 | 2021-09-15 | 엠버 테크놀로지스 인코포레이티드 | Portable cooler with active temperature control |
EP3911582A4 (en) | 2019-01-17 | 2022-10-19 | Cold Chain Technologies, LLC | Thermally insulated shipping system for parcel-sized payload |
WO2020206306A1 (en) | 2019-04-05 | 2020-10-08 | American Aerogel Corporation | Multiple immiscible phase change materials contained in common vessel |
CA3143365A1 (en) | 2019-06-25 | 2020-12-30 | Ember Technologies, Inc. | Portable cooler |
US11668508B2 (en) | 2019-06-25 | 2023-06-06 | Ember Technologies, Inc. | Portable cooler |
US11162716B2 (en) | 2019-06-25 | 2021-11-02 | Ember Technologies, Inc. | Portable cooler |
GB2619685A (en) * | 2021-03-11 | 2023-12-13 | Cryoport Inc | Box-in-a-box shipper |
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-
2012
- 2012-03-27 US US13/430,794 patent/US20130255306A1/en not_active Abandoned
-
2013
- 2013-03-18 EP EP13159788.2A patent/EP2645022A3/en not_active Withdrawn
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US6718776B2 (en) | 2001-07-10 | 2004-04-13 | University Of Alabama In Huntsville | Passive thermal control enclosure for payloads |
US20040079794A1 (en) | 2002-10-23 | 2004-04-29 | Mayer William N. | Container having passive controlled temperature interior |
US20040079793A1 (en) | 2002-10-23 | 2004-04-29 | Mayer William N. | Container having passive controlled temperature interior, and method of construction |
US20050188714A1 (en) | 2004-01-12 | 2005-09-01 | Wallace Mark W. | Passive, portable blood storage system |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2551115A (en) * | 2016-05-31 | 2017-12-13 | Laminar Medica Ltd | A thermally insulated container |
GB2551115B (en) * | 2016-05-31 | 2021-02-10 | Laminar Medica Ltd | A thermally insulated container |
Also Published As
Publication number | Publication date |
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EP2645022A3 (en) | 2015-11-11 |
US20130255306A1 (en) | 2013-10-03 |
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