EP1213612A3 - Radiation curable resin composition, manufacturing process and article made using such a composition - Google Patents

Radiation curable resin composition, manufacturing process and article made using such a composition Download PDF

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Publication number
EP1213612A3
EP1213612A3 EP01000758A EP01000758A EP1213612A3 EP 1213612 A3 EP1213612 A3 EP 1213612A3 EP 01000758 A EP01000758 A EP 01000758A EP 01000758 A EP01000758 A EP 01000758A EP 1213612 A3 EP1213612 A3 EP 1213612A3
Authority
EP
European Patent Office
Prior art keywords
resin composition
composition
radiation curable
curable resin
manufacturing process
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP01000758A
Other languages
German (de)
French (fr)
Other versions
EP1213612A2 (en
Inventor
Yuichi Haruta
Hideaki Takase
Takashi Ukachi
Tsuyoshi Watanabe
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JSR Corp
Japan Fine Coatings Co Ltd
DSM IP Assets BV
Original Assignee
Japan Fine Coatings Co Ltd
Japan Synthetic Rubber Co Ltd
DSM NV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=17210084&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1213612(A3) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Japan Fine Coatings Co Ltd, Japan Synthetic Rubber Co Ltd, DSM NV filed Critical Japan Fine Coatings Co Ltd
Publication of EP1213612A2 publication Critical patent/EP1213612A2/en
Publication of EP1213612A3 publication Critical patent/EP1213612A3/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00—Moulds or cores; Details thereof or accessories therefor
    • B29C33/38—Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
    • B29C33/3842—Manufacturing moulds, e.g. shaping the mould surface by machining
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
    • B29C64/129—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
    • B29C64/135—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F22/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides or nitriles thereof
    • C08F22/10—Esters
    • C08F22/1006—Esters of polyhydric alcohols or polyhydric phenols, e.g. ethylene glycol dimethacrylate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2105/00—Condition, form or state of moulded material or of the material to be shaped
    • B29K2105/06—Condition, form or state of moulded material or of the material to be shaped containing reinforcements, fillers or inserts
    • B29K2105/16—Fillers

Abstract

The resin composition of this invention is a radiation curable resin composition used for manufacturing a fibrous material forming mold by laminate fabricating using selective irradiation with light. This resin composition contains a filler dispersed in a liquid constituent comprising at least an ethylenically unsaturated monomer and a photoinitiator. The liquid constituent preferably additionnally comprises a cationic polymerizable organic compound. Preferably the filler is an inorganic filler, and it can be surface-treated with a silane. Preferably the ethylenically unsaturated monomer comprises at least a polyfunctional monomer having three or more acrylate functions. Preferably the cationic polymerizable organic compound is composed of 50% or more of an epoxy containing compound.
EP01000758A 1996-09-20 1997-09-19 Radiation curable resin composition, manufacturing process and article made using such a composition Withdrawn EP1213612A3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP8250585A JPH1087963A (en) 1996-09-20 1996-09-20 Resin composition and mold for forming fibrous material
JP25058596 1996-09-20
EP97202879A EP0830928B1 (en) 1996-09-20 1997-09-19 Resin composition and mold made from such resin, for forming fibrous material

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
EP97202879A Division EP0830928B1 (en) 1996-09-20 1997-09-19 Resin composition and mold made from such resin, for forming fibrous material

Publications (2)

Publication Number Publication Date
EP1213612A2 EP1213612A2 (en) 2002-06-12
EP1213612A3 true EP1213612A3 (en) 2002-06-26

Family

ID=17210084

Family Applications (2)

Application Number Title Priority Date Filing Date
EP97202879A Expired - Lifetime EP0830928B1 (en) 1996-09-20 1997-09-19 Resin composition and mold made from such resin, for forming fibrous material
EP01000758A Withdrawn EP1213612A3 (en) 1996-09-20 1997-09-19 Radiation curable resin composition, manufacturing process and article made using such a composition

Family Applications Before (1)

Application Number Title Priority Date Filing Date
EP97202879A Expired - Lifetime EP0830928B1 (en) 1996-09-20 1997-09-19 Resin composition and mold made from such resin, for forming fibrous material

Country Status (4)

Country Link
US (1) US6013714A (en)
EP (2) EP0830928B1 (en)
JP (1) JPH1087963A (en)
DE (1) DE69713558T2 (en)

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JP4473364B2 (en) * 1999-06-03 2010-06-02 Ｊｓｒ株式会社 Photocurable resin composition and optical member
US6485512B1 (en) * 2000-09-27 2002-11-26 Advanced Cardiovascular Systems, Inc. Two-stage light curable stent and delivery system
US6528571B1 (en) 2000-11-22 2003-03-04 The United States Of America As Represented By The Secretary Of Agriculture Extrusion freeform fabrication of soybean oil-based composites by direct deposition
US20050040562A1 (en) * 2003-08-19 2005-02-24 3D Systems Inc. Nanoparticle-filled stereolithographic resins
US7232850B2 (en) 2003-10-03 2007-06-19 Huntsman Advanced Materials Americas Inc. Photocurable compositions for articles having stable tensile properties
US20050101684A1 (en) * 2003-11-06 2005-05-12 Xiaorong You Curable compositions and rapid prototyping process using the same
DK2198088T3 (en) * 2007-09-14 2019-10-21 Natural Resources 2000 Ltd PROCEDURE AND MACHINE FOR SHAPING A MOLDED ARTICLE
US20090298617A1 (en) * 2008-05-28 2009-12-03 Bridgestone Sports Co., Ltd. Golf ball material and golf ball
JP5280771B2 (en) * 2008-08-29 2013-09-04 三洋化成工業株式会社 Permeable mold-forming composition for pulp mold
EP2396299B1 (en) 2009-12-17 2013-07-24 DSM IP Assets B.V. Liquid radiation curable resin compositions for additive fabrication comprising a triaryl sulfonium borate cationic photoinitiator
US20130059987A1 (en) * 2011-09-06 2013-03-07 Advanced Composite Materials, Llc Functionalized Silicon Carbide And Functionalized Inorganic Whiskers For Improving Abrasion Resistance Of Polymers
EP2842980B1 (en) 2013-08-09 2021-05-05 DSM IP Assets B.V. Low-viscosity liquid radiation curable dental aligner mold resin compositions for additive manufacturing
CN104610511B (en) 2013-11-05 2018-11-16 帝斯曼知识产权资产管理有限公司 The liquid radiation-curable resin composition of stable matrix filling for addition manufacture
JP6437446B2 (en) * 2013-11-22 2018-12-12 綜研化学株式会社 Photo-setting resin composition for imprint, antireflection film
DE102014113993A1 (en) * 2014-09-26 2016-03-31 Endress + Hauser Gmbh + Co. Kg Method for producing a container for a medium
US10683381B2 (en) 2014-12-23 2020-06-16 Bridgestone Americas Tire Operations, Llc Actinic radiation curable polymeric mixtures, cured polymeric mixtures and related processes
TW201940615A (en) * 2014-12-26 2019-10-16 日商太陽油墨製造股份有限公司 Curable resin composition, dry film, cured product and printed circuit board
EP3274155B1 (en) * 2015-03-23 2021-06-02 Dow Global Technologies LLC Photocurable compositions for three-dimensional printing
US20180243948A1 (en) * 2015-09-02 2018-08-30 Stratasys Ltd. 3-d printed mold for injection molding
CN105176070A (en) * 2015-09-16 2015-12-23 东莞深圳清华大学研究院创新中心 Modified 3D printing material and preparation method thereof
EP3390006B1 (en) 2015-12-17 2021-01-27 Bridgestone Americas Tire Operations, LLC Additive manufacturing cartridges and processes for producing cured polymeric products by additive manufacturing
US11198238B2 (en) 2016-10-18 2021-12-14 Stratasys Ltd. 3D printing of a structure for injection molding
WO2018081053A1 (en) 2016-10-27 2018-05-03 Bridgestone Americas Tire Operations, Llc Processes for producing cured polymeric products by additive manufacturing
US11299430B2 (en) * 2016-11-30 2022-04-12 Hrl Laboratories, Llc Formulations with active functional additives for 3D printing of preceramic polymers, and methods of 3D-printing the formulations
WO2018119041A1 (en) 2016-12-20 2018-06-28 Basf Se Method for determining an amount of sediment in a ceramic dispersion
WO2018119049A1 (en) 2016-12-20 2018-06-28 Basf Se Photopolymer ceramic dispersion for additive fabrication
WO2018119067A1 (en) 2016-12-20 2018-06-28 Basf Se Photopolymer ceramic dispersion
JP2020502300A (en) 2016-12-22 2020-01-23 ディーエスエム アイピー アセッツ ビー．ブイ．Ｄｓｍ Ｉｐ Ａｓｓｅｔｓ Ｂ．Ｖ． Improved heat and electrical resistance thermoplastic resin composition
CN107053668B (en) * 2017-04-28 2019-01-29 清华大学 A kind of preparation method and its special equipment of fibrous composite
US11180594B2 (en) 2017-12-29 2021-11-23 Covestro (Netherlands) B.V. Compositions and articles for additive fabrication and methods of using the same
US11851379B2 (en) 2018-07-03 2023-12-26 Corning Incorporated Selective masking and plugging of honeycomb bodies
CN112805316B (en) 2018-10-26 2023-09-15 科思创(荷兰)有限公司 Polyester powder and its use in three-dimensional printing process
CN110885253A (en) * 2019-11-26 2020-03-17 嘉兴饶稷科技有限公司 Laser scanning ceramic printing process
US20230146407A1 (en) * 2020-04-09 2023-05-11 Kaneka Americas Holding, Inc. Curable composition, cured product, and methods thereof
EP4352137A1 (en) 2021-06-11 2024-04-17 Stratasys, Inc. Biodegradable and/or compostable biobased powders for additive manufacturing, and methods for the use thereof
WO2022258689A1 (en) 2021-06-11 2022-12-15 Covestro (Netherlands) B.V. Methods of making biodegradable and/or compostable biobased powders for additive manufacturing

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0144148A2 (en) * 1983-10-28 1985-06-12 LOCTITE (IRELAND) Ltd. Photocurable compositions containing prepolymers of two curing types
JPH0275617A (en) * 1988-09-13 1990-03-15 Asahi Denka Kogyo Kk Resin composition for optical molding
EP0360869A1 (en) * 1988-02-19 1990-04-04 Asahi Denka Kogyo Kabushiki Kaisha Resin composition for optical modeling
EP0393673A2 (en) * 1989-04-21 1990-10-24 E.I. Du Pont De Nemours And Company Solid imaging method using multiphasic photohardenable compositions
US5434196A (en) * 1988-02-19 1995-07-18 Asahi Denka Kogyo K.K. Resin composition for optical molding
US5679722A (en) * 1993-07-15 1997-10-21 Teijin Seiki Co., Ltd. Resin composition for production of a three-dimensional object by curing
EP0807853A2 (en) * 1996-05-16 1997-11-19 Teijin Seiki Co., Ltd. Photocurable resin composition, method of producing photo-cured shaped object, vacuum casting mold, vacuum casting method and urethane acrylate
US5929130A (en) * 1995-06-29 1999-07-27 Takemoto Yushi Kabushiki Kaisha & Teijin Seiki Co., Ltd. Photocurable resin compositions for plastic molds

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AU497960B2 (en) * 1974-04-11 1979-01-25 Minnesota Mining And Manufacturing Company Photopolymerizable compositions
GB1516351A (en) * 1974-05-02 1978-07-05 Gen Electric Curable epoxide compositions
GB1516512A (en) * 1974-05-02 1978-07-05 Gen Electric Chalcogenium salts
GB1512982A (en) * 1974-05-02 1978-06-01 Gen Electric Salts
US4256828A (en) * 1975-09-02 1981-03-17 Minnesota Mining And Manufacturing Company Photocopolymerizable compositions based on epoxy and hydroxyl-containing organic materials
US4156035A (en) * 1978-05-09 1979-05-22 W. R. Grace & Co. Photocurable epoxy-acrylate compositions
US4139655A (en) * 1978-05-09 1979-02-13 W. R. Grace & Co. Photocurable epoxy compositions containing thiopyrylium salts
US4197174A (en) * 1979-03-14 1980-04-08 American Can Company Method for producing bis-[4-(diphenylsulfonio) phenyl] sulfide bis-MX6
JPS568428A (en) * 1979-06-19 1981-01-28 Ciba Geigy Ag Photopolymerizing and thermopolymerizing composition
JPH0245641B2 (en) * 1980-03-07 1990-10-11 Ciba Geigy HIKARIJUGOSEISOSEIBUTSUOYOBISONOJUGOHO
US4387216A (en) * 1981-05-06 1983-06-07 Ciba-Geigy Corporation Heat-polymerizable compositions comprising epoxide resins, aromatic sulfoxonium salts, and organic oxidants
JPH0586149A (en) * 1991-09-30 1993-04-06 I C I Japan Kk Resin composition for optical three-dimensional molding and formation of three-dimensional molded product
US5296335A (en) * 1993-02-22 1994-03-22 E-Systems, Inc. Method for manufacturing fiber-reinforced parts utilizing stereolithography tooling
JP2870445B2 (en) * 1995-02-20 1999-03-17 ソニー株式会社 Mold formed by additive manufacturing and method of forming the same

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0144148A2 (en) * 1983-10-28 1985-06-12 LOCTITE (IRELAND) Ltd. Photocurable compositions containing prepolymers of two curing types
EP0360869A1 (en) * 1988-02-19 1990-04-04 Asahi Denka Kogyo Kabushiki Kaisha Resin composition for optical modeling
US5434196A (en) * 1988-02-19 1995-07-18 Asahi Denka Kogyo K.K. Resin composition for optical molding
US5525645A (en) * 1988-02-19 1996-06-11 Asahi Denka Kogyo K.K. Resin composition for optical molding
JPH0275617A (en) * 1988-09-13 1990-03-15 Asahi Denka Kogyo Kk Resin composition for optical molding
EP0393673A2 (en) * 1989-04-21 1990-10-24 E.I. Du Pont De Nemours And Company Solid imaging method using multiphasic photohardenable compositions
US5679722A (en) * 1993-07-15 1997-10-21 Teijin Seiki Co., Ltd. Resin composition for production of a three-dimensional object by curing
US5929130A (en) * 1995-06-29 1999-07-27 Takemoto Yushi Kabushiki Kaisha & Teijin Seiki Co., Ltd. Photocurable resin compositions for plastic molds
EP0807853A2 (en) * 1996-05-16 1997-11-19 Teijin Seiki Co., Ltd. Photocurable resin composition, method of producing photo-cured shaped object, vacuum casting mold, vacuum casting method and urethane acrylate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
PATENT ABSTRACTS OF JAPAN vol. 014, no. 261 (C - 0725) 6 June 1990 (1990-06-06) *

Also Published As

Publication number Publication date
EP0830928A3 (en) 1999-02-03
JPH1087963A (en) 1998-04-07
EP0830928B1 (en) 2002-06-26
EP0830928A2 (en) 1998-03-25
DE69713558D1 (en) 2002-08-01
EP1213612A2 (en) 2002-06-12
US6013714A (en) 2000-01-11
DE69713558T2 (en) 2003-02-20

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Inventor name: WATANABE, TSUYOSHI

Inventor name: UKACHI, TAKASHI

Inventor name: TAKASE, HIDEAKI

Inventor name: HARUTA, YUICHI

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Owner name: JAPAN FINE COATINGS CO., LTD.

Owner name: JAPAN SYNTHETIC RUBBER CO., LTD.

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