EP0901810A2 - Method and apparatus for the continuous mixing of a droplet dispersion in a liquid - Google Patents
Method and apparatus for the continuous mixing of a droplet dispersion in a liquid Download PDFInfo
- Publication number
- EP0901810A2 EP0901810A2 EP98115928A EP98115928A EP0901810A2 EP 0901810 A2 EP0901810 A2 EP 0901810A2 EP 98115928 A EP98115928 A EP 98115928A EP 98115928 A EP98115928 A EP 98115928A EP 0901810 A2 EP0901810 A2 EP 0901810A2
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- European Patent Office
- Prior art keywords
- container
- flow
- liquid
- droplet dispersion
- droplet
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F23/00—Mixing according to the phases to be mixed, e.g. dispersing or emulsifying
- B01F23/40—Mixing liquids with liquids; Emulsifying
- B01F23/45—Mixing liquids with liquids; Emulsifying using flow mixing
- B01F23/451—Mixing liquids with liquids; Emulsifying using flow mixing by injecting one liquid into another
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/30—Injector mixers
- B01F25/31—Injector mixers in conduits or tubes through which the main component flows
- B01F25/314—Injector mixers in conduits or tubes through which the main component flows wherein additional components are introduced at the circumference of the conduit
Definitions
- a variety of technical processes for the production of fine-particle spherical Polymers or microcapsules are based on the fact that initially a droplet dispersion or cores of finely divided, liquid or with a liquid shell solid material are generated, then by adding another Liquid, e.g. a hardener or an acid or base to change the pH the dispersion the droplets or the liquid surrounding the particles Shell is hardened or stabilized.
- a hardener or an acid or base to change the pH the dispersion the droplets or the liquid surrounding the particles Shell is hardened or stabilized.
- the problem is that the liquid is so gentle in the droplet dispersion to interfere that an agglomeration and coalescence of the droplets and thus a Disruption of the droplet size distribution is avoided.
- the widely used microencapsulation process by coacervation or complex coacervation a droplet dispersion in one aqueous gelatin solution or an aqueous solution of gelatin and gum arabic generated at substantially neutral pH, the droplets with a Gelatin layer can be covered.
- the encapsulation is carried out by adding a copolymer with the addition of an aqueous solution of an inorganic acid, if appropriate with subsequent lowering of the temperature of the dispersion.
- Capsules are already so stable that they can be washed and, if necessary, added of formalin can be hardened with an increase in pH.
- the suspension very sensitive to droplets coated with gelatin before acidification against mechanical stress. The mixture with the acid solution must therefore done very gently.
- the object of the present invention is to provide a method and an apparatus for continuous mixing of a droplet dispersion with a liquid Introducing the liquid into a container through which the droplet dispersion flows to provide, in which the mixing of the liquid is gentle, i.e. if possible low mechanical stress is carried out.
- the object is achieved in that the liquid in the form of a large number of fine liquid jets are injected into the droplet dispersion, taking the energy of the liquid jets a short distance behind the injection site is broken down, and the further mixing by one generated in the container Circulation flow occurs with shear rates below 20 / s.
- the droplet dispersion is preferably introduced axially into a cylindrical container to excite the circulation flow, the introduction speed of the droplet dispersion being 15 to 100 times greater than the average speed determined on the basis of the throughput through the cylindrical container ( As a result, an axial forward flow and a peripheral backward flow with a corresponding flow deflection at a distance from the point of introduction for the droplet dispersion, which is repeated several times by the droplets, is generated in the cylindrical container.
- the flow velocity through the cylindrical container can be in the range from 0. 1 to 0.5 cm / s, and the droplet dispersion is introduced into the cylindrical container at a rate of 3 to 15 cm / s.
- the introduction point for the droplet dispersion preferably projects axially into the cylindrical one Containers so that the cylindrical container on the back to the discharge point has an annular space in which the return flow is deflected into a forward flow becomes.
- the liquid to be mixed into the droplet dispersion is preferably by the jacket of the cylindrical container is injected into the backflow.
- the cylindrical container jacket has a plane perpendicular to the container axis Large number of nozzles through which the liquid is introduced.
- the introduction speed for the liquid it can typically be 1 to 5 m / s.
- the liquid jets are preferably injected with a directional component against the peripheral backflow of the droplet dispersion, so that the Liquid jets in the area surrounding the introduction point for the droplet dispersion Annulus create a peripheral forward flow.
- the Ring space surrounding the inlet point causes a particularly intensive mass transfer.
- the impulse component introduced by the liquid jets parallel to the container axis can be of the order of magnitude of momentum input through the droplet dispersion lie, in particular about 1 to 10 times the momentum input by the Droplet dispersion.
- the introduction takes place the droplet dispersion in the cylindrical container from the bottom up when the Droplets have a lower specific gravity than the continuous one Phase.
- the droplets experience a buoyancy, which leads to the fact that in the droplet concentration in the annular space surrounding the point of introduction for the droplet dispersion impoverished. Accordingly, the existing in the annulus peripheral upward flow shows a reduced droplet concentration. This is particularly important if, for reasons of economy, droplet dispersions used with very high droplet concentrations of 40 to 60 vol% become.
- the liquid is then injected into a droplet dispersion with significantly reduced droplet concentration, so the risk the agglomeration of droplets in the area of the injection is further reduced.
- the flow direction through the cylindrical is preferred Container selected from top to bottom if the droplets have a greater density, than the continuous phase.
- Fig. 1 shows in principle a container 1 in the form of a cylindrical column with a axially arranged inlet pipe 2 for the droplet dispersion.
- the generation of the Droplet dispersion can be carried out by methods known per se. For example can the droplet dispersion by spraying the liquid forming the droplet be produced in an aqueous gelatin solution.
- On a circumferential line perpendicular to Axis 3 of the cylindrical container 1 are a plurality of nozzles 4, for example provided with a diameter of 0.4 mm.
- the number of nozzles can be, for example 12 to 120.
- the nozzles are fed from an annular channel 5, in the the liquid is introduced through one or more supply lines 6.
- the nozzles 4 obliquely upwards, so that the liquid injected is a Directional component in the flow direction of the container 1.
- the cross-sectional area the inlet pipe 2 for the droplet dispersion can 1/12 to 1/45 of Cross-sectional area of the cylindrical container 1 amount.
- the container 1 has a rotationally symmetrical flow distribution above the Drawing (not shown) an axial outlet with a conical transition to
- the outlet cross-section according to the invention is intended to be that caused by the circulating flow Droplet dispersion shear rate below 20 / s, preferably below 10 / s.
- the estimate of the shear rate is double Inflow velocity of the droplet dispersion through half the container radius divided.
- the inlet pipe 2 for the droplet dispersion projects at least over one Length, which corresponds to the radius of the container 1, into this, so that the rear an annular space 7 is formed by the inlet point, in which the return flow 11 is deflected becomes.
- the nozzles 4 are inclined upwards directed so that a peripheral forward flow 13 is excited in the annular space 7 becomes.
- the backflow 11 in the annular space 7 into a axial and a peripheral forward flow divided, so that an intensive exchange takes place, and on the other hand an additional circulation flow in the annular space 7 generated due to the longer dwell time and the density differences of Droplets and continuous phase as well as dilution by the liquid supplied has a significantly reduced droplet concentration.
- Fig. 2 shows an enlarged view of the flow conditions in the area of Annulus 7, the dashed lines 21 and 22 the boundaries between the Flow areas with a forward component on the one hand and a backflow component otherwise specify.
Abstract
Description
Eine Vielzahl von technischen Prozessen zur Herstellung von feinteiligen kugelförmigen Polymeren oder Mikrokapseln beruht darauf, daß zunächst eine Tröpfchendispersion oder mit einer flüssigen Hülle umgebene Kerne aus feinteiligem, flüssigem oder festem Material erzeugt werden, wobei anschließend durch Zugabe einer weiteren Flüssigkeit, z.B. eines Härters oder einer Säure oder Base zur Anderung des pH-Wertes der Dispersion die Tröpfchen bzw. die die Teilchen umschließende flüssige Hülle gehärtet bzw. stabilisiert wird.A variety of technical processes for the production of fine-particle spherical Polymers or microcapsules are based on the fact that initially a droplet dispersion or cores of finely divided, liquid or with a liquid shell solid material are generated, then by adding another Liquid, e.g. a hardener or an acid or base to change the pH the dispersion the droplets or the liquid surrounding the particles Shell is hardened or stabilized.
Dabei besteht das Problem, die Flüssigkeit so schonend in die Tröpfchendispersion einzumischen, daß eine Agglomeration und Koaleszenz der Tröpfchen und damit eine Störung der Tröpfchengrößenverteilung vermieden wird.The problem is that the liquid is so gentle in the droplet dispersion to interfere that an agglomeration and coalescence of the droplets and thus a Disruption of the droplet size distribution is avoided.
Beispielsweise wird bei dem weit verbreiteten Verfahren zur Mikroverkapselung durch Koazervation bzw. Komplexkoazervation eine Tröpfchendispersion in einer wäßrigen Gelatinelösung bzw. einer wäßrigen Lösung von Gelatine und Gummiarabicum bei im wesentlichen neutralen pH-Wert erzeugt, wobei die Tröpfchen mit einer Gelatineschicht belegt werden. Die Verkapselung erfolgt durch Zugabe eines Copolymeren unter Zusatz einer wäßrigen Lösung einer anorganischen Säure, gegebenenfalls mit anschließender Absenkung der Temperatur der Dispersion. Die so erhaltenen Kapseln sind bereits so stabil, daß sie gewaschen und gegebenenfalls durch Zugabe von Formalin unter pH-Werterhöhung gehärtet werden können. Dagegen ist die Suspension von mit Gelatine belegten Tröpfchen vor der Ansäuerung sehr empfindlich gegen mechanische Beanspruchung. Die Vermischung mit der Säurelösung muß also sehr schonend erfolgen.For example, the widely used microencapsulation process by coacervation or complex coacervation a droplet dispersion in one aqueous gelatin solution or an aqueous solution of gelatin and gum arabic generated at substantially neutral pH, the droplets with a Gelatin layer can be covered. The encapsulation is carried out by adding a copolymer with the addition of an aqueous solution of an inorganic acid, if appropriate with subsequent lowering of the temperature of the dispersion. The so obtained Capsules are already so stable that they can be washed and, if necessary, added of formalin can be hardened with an increase in pH. In contrast is the suspension very sensitive to droplets coated with gelatin before acidification against mechanical stress. The mixture with the acid solution must therefore done very gently.
Aufgabe der vorliegenden Erfindung ist es, ein Verfahren und eine Vorrichtung zur kontinuierlichen Vermischung einer Tröpfchendispersion mit einer Flüssigkeit durch Einleiten der Flüssigkeit in einen von der Tröpfchendispersion durchströmten Behälter bereitzustellen, bei dem die Einmischung der Flüssigkeit schonend, d.h. bei möglichst geringer mechanischer Beanspruchung durchgeführt wird. The object of the present invention is to provide a method and an apparatus for continuous mixing of a droplet dispersion with a liquid Introducing the liquid into a container through which the droplet dispersion flows to provide, in which the mixing of the liquid is gentle, i.e. if possible low mechanical stress is carried out.
Erfindungsgemäß wird die Aufgabe dadurch gelöst, daß die Flüssigkeit in Form von einer Vielzahl von feinen Flüssigkeitsstrahlen in die Tröpfchendispersion injiziert wird, wobei die Energie der Flüssigkeitsstrahlen in kurzer Entfernung hinter der Injektionsstelle abgebaut wird, und die weitere Vermischung durch eine in dem Behälter erzeugte Umwälzströmung mit Schergeschwindigkeiten unterhalb 20/s erfolgt.According to the invention the object is achieved in that the liquid in the form of a large number of fine liquid jets are injected into the droplet dispersion, taking the energy of the liquid jets a short distance behind the injection site is broken down, and the further mixing by one generated in the container Circulation flow occurs with shear rates below 20 / s.
Vorzugsweise wird die Tröpfchendispersion zur Anregung der Umwälzströmung axial in einen zylindrischen Behälter eingeleitet, wobei die Einleitgeschwindigkeit der Tröpfchendispersion 15- bis 100-mal größer ist als die aufgrund des Durchsatzes durch den zylindrischen Behälter ermittelte mittlere Geschwindigkeit (Durchströmgeschwindigkeit"). Hierdurch wird in dem zylindrischen Behälter eine axiale Vorwärtsströmung und eine periphere Rückwärtsströmung mit entsprechender Strömungsumlenkung im Abstand zur Einleitstelle für die Tröpfchendispersion erzeugt, die von den Tröpfchen mehrfach durchlaufen wird. Dabei kann die Durchströmgeschwindigkeit durch den zylindrischen Behälter im Bereich von 0,1 bis 0,5 cm/s betragen. Entsprechend wird die Tröpfchendispersion mit einer Geschwindigkeit von 3 bis 15 cm/s in den zylindrischen Behälter eingeleitet.The droplet dispersion is preferably introduced axially into a cylindrical container to excite the circulation flow, the introduction speed of the droplet dispersion being 15 to 100 times greater than the average speed determined on the basis of the throughput through the cylindrical container ( As a result, an axial forward flow and a peripheral backward flow with a corresponding flow deflection at a distance from the point of introduction for the droplet dispersion, which is repeated several times by the droplets, is generated in the cylindrical container. The flow velocity through the cylindrical container can be in the range from 0. 1 to 0.5 cm / s, and the droplet dispersion is introduced into the cylindrical container at a rate of 3 to 15 cm / s.
Vorzugsweise ragt die Einleitstelle für die Tröpfchendispersion axial in den zylindrischen Behälter hinein, so daß der zylindrische Behälter rückseitig zur Einleitstelle einen Ringraum aufweist, in dem die Rückströmung in eine Vorwärtsströmung umgelenkt wird.The introduction point for the droplet dispersion preferably projects axially into the cylindrical one Containers so that the cylindrical container on the back to the discharge point has an annular space in which the return flow is deflected into a forward flow becomes.
Die in die Tröpfchendispersion einzumischende Flüssigkeit wird vorzugsweise durch den Mantel des zylindrischen Behälters in die Rückströmung eingedüst. Vorzugsweise weist der zylindrische Behältermantel in einer Ebene senkrecht zur Behälterachse eine Vielzahl von Düsen auf, durch die die Flüssigkeit eingeleitet wird. Die Einleitgeschwindigkeit für die Flüssigkeit kann typischerweise 1 bis 5 m/s betragen.The liquid to be mixed into the droplet dispersion is preferably by the jacket of the cylindrical container is injected into the backflow. Preferably the cylindrical container jacket has a plane perpendicular to the container axis Large number of nozzles through which the liquid is introduced. The introduction speed for the liquid it can typically be 1 to 5 m / s.
Vorzugsweise erfolgt die Eindüsung der Flüssigkeitsstrahlen mit einer Richtungskomponente entgegen der peripheren Rückströmung der Tröpfchendispersion, so daß die Flüssigkeitsstrahlen in dem die Einleitstelle für die Tröpfchendispersion umgebenden Ringraum eine periphere Vorwärtsströmung erzeugen. Hierdurch wird in dem die Einleitstelle umgebenden Ringraum ein besonders intensiver Stoffaustausch bewirkt. Die durch die Flüssigkeitsstrahlen eingebrachte Impulskomponente parallel zur Behälterachse, kann etwa in der Größenordnung des Impulseintrages durch die Tröpfchendispersion liegen, insbesondere etwa das 1- bis 10-fache des Impulseintrags durch die Tröpfchendispersion betragen.The liquid jets are preferably injected with a directional component against the peripheral backflow of the droplet dispersion, so that the Liquid jets in the area surrounding the introduction point for the droplet dispersion Annulus create a peripheral forward flow. As a result, the Ring space surrounding the inlet point causes a particularly intensive mass transfer. The impulse component introduced by the liquid jets parallel to the container axis, can be of the order of magnitude of momentum input through the droplet dispersion lie, in particular about 1 to 10 times the momentum input by the Droplet dispersion.
In einer weitere bevorzugten Ausführungsform der Erfindung erfolgt die Einleitung der Tröpfchendispersion in den zylindrischen Behälter von unten nach oben, wenn die Tröpfchen ein geringeres spezifisches Gewicht aufweisen als die kontinuierliche Phase. In diesem Falle erfahren die Tröpfchen einen Auftrieb, der dazu führt, daß in dem die Einleitstelle für die Tröpfchendispersion umgebenden Ringraum die Tröpfchenkonzentration verarmt. Entsprechend weist die in dem Ringraum vorhandene periphere Aufwärtsströmung eine reduzierte Tröpfchenkonzentration auf. Dies ist insbesondere dann von Bedeutung, wenn aus Gründen der Wirtschaftlichkeit Tröpfchendispersionen mit sehr hohen Tröpfchenkonzentrationen von 40 bis 60 Vol-% eingesetzt werden. Die Eindüsung der Flüssigkeit erfolgt dann nämlich in eine Tröpfchendispersion mit erheblich reduzierter Tröpfchenkonzentration, so daß das Risiko der Agglomeration von Tröpfchen im Bereich der Eindüsung weiter reduziert wird.In a further preferred embodiment of the invention, the introduction takes place the droplet dispersion in the cylindrical container from the bottom up when the Droplets have a lower specific gravity than the continuous one Phase. In this case, the droplets experience a buoyancy, which leads to the fact that in the droplet concentration in the annular space surrounding the point of introduction for the droplet dispersion impoverished. Accordingly, the existing in the annulus peripheral upward flow shows a reduced droplet concentration. This is This is particularly important if, for reasons of economy, droplet dispersions used with very high droplet concentrations of 40 to 60 vol% become. The liquid is then injected into a droplet dispersion with significantly reduced droplet concentration, so the risk the agglomeration of droplets in the area of the injection is further reduced.
Entsprechend wird vorzugsweise die Durchströmrichtung durch den zylindrischen Behälter von oben nach unten gewählt, wenn die Tröpfchen eine größere Dichte aufweisen, als die kontinuierliche Phase.Accordingly, the flow direction through the cylindrical is preferred Container selected from top to bottom if the droplets have a greater density, than the continuous phase.
Die Erfindung wird nachfolgend anhand der beigefügten Figuren näher erläutert.
- Fig. 1
- zeigt eine erfindungsgemäße Vorrichtung zur kontinuierlichen Vermischung einer Tröpfchendispersion mit einer Flüssigkeit.
- Fig. 2
- zeigt in vergrößerter Darstellung den Bereich der Einleitung von Tröpfchendispersion und Flüssigkeit mit den dort herrschenden Strömungsverhältnissen.
- Fig. 1
- shows an inventive device for the continuous mixing of a droplet dispersion with a liquid.
- Fig. 2
- shows in an enlarged view the area of the introduction of droplet dispersion and liquid with the prevailing flow conditions.
Fig. 1 zeigt prinzipiell einen Behälter 1 in Form einer zylindrischen Säule mit einem
axial angeordneten Einleitrohr 2 für die Tröpfchendispersion. Die Erzeugung der
Tröpfchendispersion kann nach an sich bekannten Verfahren erfolgen. Beispielsweise
kann die Tröpfchendispersion durch Eindüsen der die Tröpfchen bildenden Flüssigkeit
in eine wäßrige Gelatinelösung erzeugt sein. Auf einer Umfangslinie senkrecht zur
Achse 3 des zylindrischen Behälters 1 sind eine Vielzahl von Düsen 4, beispielsweise
mit einem Durchmesser von 0,4 mm vorgesehen. Die Zahl der Düsen kann beispielsweise
12 bis 120 betragen. Die Düsen werden aus einem Ringkanal 5 gespeist, in den
die Flüssigkeit durch eine oder mehrere Zuleitungen 6 eingeleitet wird. Wie dargestellt,
weisen die Düsen 4 schräg nach oben, so daß die eingedüste Flüssigkeit eine
Richtungskomponente in Durchströmrichtung des Behälters 1 aufweist. Die Querschnittsfläche
des Einleitrohres 2 für die Tröpfchendispersion kann 1/12 bis 1/45 der
Querschnittsfläche des zylindrischen Behälters 1 betragen. Durch die einströmende
Tröpfchendispersion wird der Behälterinhalt zu einer Umwälzströmung mit axialer
Vorwärtsströmung 10 und peripherer Rückwärtsströmung 11 angeregt. Je nach Ausdehnung
des zylindrischen Behälters 1 in axialer Richtung wird die Umwälzströmung
in einer oder mehreren Ebenen 12 umgelenkt. Zur Gewährleistung einer möglichst
rotationssymmetrischen Strömungsverteilung weist der Behälter 1 oberhalb der
Zeichnung (nicht dargestellt) einen axialen Auslaß mit konischem Übergang zum
Auslaßquerschnitt auf Erfindungsgemäß soll die durch die Umlaufströmung bewirkte
Schergeschwindigkeit der Tröpfchendispersion unterhalb von 20/s, bevorzugt unterhalb
10/s, liegen. Dabei wird zur Abschätzung der Schergeschwindigkeit die doppelte
Einströmgeschwindigkeit der Tröpfchendispersion durch den halben Behälterradius
dividiert. Das Einleitrohr 2 für die Tröpfchendispersion ragt mindestens über eine
Länge, die dem Radius des Behälters 1 entspricht, in diesen hinein, so daß rückwärtig
von der Einleitstelle ein Ringraum 7 gebildet wird, in dem die Rückströmung 11 umgelenkt
wird. Wie aus der Zeichnung ersichtlich, sind die Düsen 4 schräg nach oben
gerichtet, so daß in dem Ringraum 7 eine periphere Vorwärtsströmung 13 angeregt
wird. Hierdurch wird einerseits die Rückströmung 11 in dem Ringraum 7 in eine
axiale und eine periphere Vorwärtsströmung geteilt, so daß ein intensiver Austausch
stattfindet, und andererseits eine zusätzliche Zirkulationsströmung im Ringraum 7
erzeugt, die aufgrund der längeren Verweilzeit und der Dichteunterschiede von
Tröpfchen und kontinuierlicher Phase sowie Verdünnung durch die zugeführte Flüssigkeit
eine erheblich reduzierte Tröpfchenkonzentration aufweist.Fig. 1 shows in principle a
Fig. 2 zeigt eine vergrößerte Darstellung der Strömungsverhältnisse im Bereich des
Ringraumes 7, wobei die strichlierten Linien 21 und 22 die Grenzen zwischen den
Strömungsbereichen mit Vorwärtskomponente einerseits und Rückströmungskomponente
andererseits angeben.Fig. 2 shows an enlarged view of the flow conditions in the area of
Annulus 7, the
Claims (10)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19738870A DE19738870A1 (en) | 1997-09-05 | 1997-09-05 | Method and device for continuously mixing a droplet dispersion with a liquid |
DE19738870 | 1997-09-05 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0901810A2 true EP0901810A2 (en) | 1999-03-17 |
EP0901810A3 EP0901810A3 (en) | 2001-02-07 |
EP0901810B1 EP0901810B1 (en) | 2003-02-12 |
Family
ID=7841320
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP98115928A Expired - Lifetime EP0901810B1 (en) | 1997-09-05 | 1998-08-24 | Method and apparatus for the continuous mixing of a droplet dispersion in a liquid |
Country Status (5)
Country | Link |
---|---|
US (2) | US6102309A (en) |
EP (1) | EP0901810B1 (en) |
JP (1) | JPH11137985A (en) |
DE (2) | DE19738870A1 (en) |
HU (1) | HUP9802004A3 (en) |
Cited By (1)
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---|---|---|---|---|
WO2020222651A1 (en) * | 2019-05-02 | 2020-11-05 | Water Iq International B.V. | Mixing device for mixing hydrogen peroxide and water |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE10206103A1 (en) * | 2002-02-13 | 2003-08-21 | Basf Ag | Device and method for producing molded articles from thermoplastic polymers |
SE525983C2 (en) * | 2003-10-13 | 2005-06-07 | Metso Paper Inc | Mixing device for mixing one liquid medium into another liquid medium |
DE102005056723B4 (en) * | 2005-11-29 | 2012-08-30 | Roland Damann | Device for mixing and reacting a gas and / or a liquid with a liquid medium |
GB201604412D0 (en) * | 2016-03-15 | 2016-04-27 | King S College London | Method and system pressure drop estimation |
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1997
- 1997-09-05 DE DE19738870A patent/DE19738870A1/en not_active Withdrawn
-
1998
- 1998-08-24 EP EP98115928A patent/EP0901810B1/en not_active Expired - Lifetime
- 1998-08-24 DE DE59807165T patent/DE59807165D1/en not_active Expired - Lifetime
- 1998-08-31 JP JP10259107A patent/JPH11137985A/en active Pending
- 1998-09-03 HU HU9802004A patent/HUP9802004A3/en unknown
- 1998-09-03 US US09/148,021 patent/US6102309A/en not_active Expired - Lifetime
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1999
- 1999-07-27 US US09/361,850 patent/US6170761B1/en not_active Expired - Lifetime
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US3242051A (en) * | 1958-12-22 | 1966-03-22 | Ncr Co | Coating by phase separation |
BE658300A (en) * | 1964-01-24 | |||
GB1240756A (en) * | 1968-04-11 | 1971-07-28 | Inventa Ag | Mixing apparatus |
US4637905A (en) * | 1982-03-04 | 1987-01-20 | Batelle Development Corporation | Process of preparing microcapsules of lactides or lactide copolymers with glycolides and/or ε-caprolactones |
US5173007A (en) * | 1989-10-23 | 1992-12-22 | Serv-Tech, Inc. | Method and apparatus for in-line blending of aqueous emulsion |
WO1993019735A1 (en) * | 1992-04-03 | 1993-10-14 | Centre National De La Recherche Scientifique (Cnrs) | Process for the preparation of microcapsules or liposomes with controlled sizes |
US5637350A (en) * | 1994-05-13 | 1997-06-10 | A.P.I. Asphalt Prilling Inc. | Encapsulation of asphalt prills |
DE4421352A1 (en) * | 1994-06-17 | 1995-12-21 | Specker Helmut | Process and assembly dilute liq. polymer within laminar flow water pipe |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2020222651A1 (en) * | 2019-05-02 | 2020-11-05 | Water Iq International B.V. | Mixing device for mixing hydrogen peroxide and water |
NL2023054B1 (en) * | 2019-05-02 | 2020-11-23 | Water Iq Int B V | Mixing device for mixing hydrogen peroxide and water |
Also Published As
Publication number | Publication date |
---|---|
EP0901810B1 (en) | 2003-02-12 |
DE19738870A1 (en) | 1999-03-18 |
HUP9802004A3 (en) | 2000-06-28 |
US6102309A (en) | 2000-08-15 |
US6170761B1 (en) | 2001-01-09 |
EP0901810A3 (en) | 2001-02-07 |
DE59807165D1 (en) | 2003-03-20 |
JPH11137985A (en) | 1999-05-25 |
HUP9802004A2 (en) | 1999-04-28 |
HU9802004D0 (en) | 1998-12-28 |
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