EP0781625A1 - Spray formed rapid tools - Google Patents

Spray formed rapid tools Download PDF

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Publication number
EP0781625A1
EP0781625A1 EP96308516A EP96308516A EP0781625A1 EP 0781625 A1 EP0781625 A1 EP 0781625A1 EP 96308516 A EP96308516 A EP 96308516A EP 96308516 A EP96308516 A EP 96308516A EP 0781625 A1 EP0781625 A1 EP 0781625A1
Authority
EP
European Patent Office
Prior art keywords
tool
pattern
mould
base
casting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP96308516A
Other languages
German (de)
French (fr)
Inventor
Dawn White
Joseph Szuba
Daniel Wikosz
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ford Werke GmbH
Ford Motor Co Ltd
Ford Motor Co
Original Assignee
Ford Werke GmbH
Ford Motor Co Ltd
Ford Motor Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ford Werke GmbH, Ford Motor Co Ltd, Ford Motor Co filed Critical Ford Werke GmbH
Publication of EP0781625A1 publication Critical patent/EP0781625A1/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/18After-treatment
    • C23C4/185Separation of the coating from the substrate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21DWORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21D37/00Tools as parts of machines covered by this subclass
    • B21D37/20Making tools by operations not covered by a single other subclass
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C7/00Patterns; Manufacture thereof so far as not provided for in other classes
    • B22C7/02Lost patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C9/00Moulds or cores; Moulding processes
    • B22C9/02Sand moulds or like moulds for shaped castings
    • B22C9/04Use of lost patterns
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/115Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces by spraying molten metal, i.e. spray sintering, spray casting
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F3/00Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
    • B22F3/12Both compacting and sintering
    • B22F3/1208Containers or coating used therefor
    • B22F3/1258Container manufacturing
    • B22F3/1275Container manufacturing by coating a model and eliminating the model before consolidation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F5/00Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product
    • B22F5/007Manufacture of workpieces or articles from metallic powder characterised by the special shape of the product of moulds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23PMETAL-WORKING NOT OTHERWISE PROVIDED FOR; COMBINED OPERATIONS; UNIVERSAL MACHINE TOOLS
    • B23P15/00Making specific metal objects by operations not covered by a single other subclass or a group in this subclass
    • B23P15/24Making specific metal objects by operations not covered by a single other subclass or a group in this subclass dies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10Processes of additive manufacturing
    • B29C64/106Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/124Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
    • B29C64/129Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
    • B29C64/135Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F2998/00Supplementary information concerning processes or compositions relating to powder metallurgy
    • B22F2998/10Processes characterised by the sequence of their steps
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C33/00Moulds or cores; Details thereof or accessories therefor
    • B29C33/38Moulds or cores; Details thereof or accessories therefor characterised by the material or the manufacturing process
    • B29C33/3842Manufacturing moulds, e.g. shaping the mould surface by machining
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B33ADDITIVE MANUFACTURING TECHNOLOGY
    • B33YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
    • B33Y80/00Products made by additive manufacturing
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/25Process efficiency

Definitions

  • This invention relates to the rapid making of prototype tools and more particularly to more rapid modes of making stamping dies for shaping sheet metal.
  • An initial advance uses stereolithography to fabricate a three dimensional wax or plastic pattern in free-form following a computer design; the pattern is invested in a ceramic mould, built up by a series of slurry coatings therearound, and then melted or burned out by heating the mould in a furnace or autoclave.
  • the mould is used in a conventional metal pouring or injection moulding operation to create a casting; the mould is destroyed to retrieve the casting (See U.S. Patent 4,844,144).
  • the casting must be milled, ground or further machined to substantially bring the casting to near net shape.
  • section thickness is limited to about 1.5 inches.
  • a further advance in the art is the use of metal spraying to form first and second thin mould shells around a pattern. Spraying is carried out robotically in accordance with the same computer design.
  • the shells are backed-up by supporting material to complete the mould and a release agent is usually applied to the pattern to facilitate separation of the pattern from the mould shells.
  • the mould shells are used conventionally to create a cast metal article (see U.S. patent 5,189,781). Unfortunately again, the cast article must be machined, milled or ground to near net shape to be used.
  • the present invention provides a method of making a rapid tool, comprising: (a) making a plastic pattern of the tool by free form fabrication techniques following a computer aided design, the design having a base and no undercuts taken in a direction perpendicular to base; (b) constructing a ceramic mould as the inverse of the pattern; ⁇ separating the pattern from the mould by a separating movement in a direction perpendicular to the base to leave a surface defining a casting cavity within the mould; and (d) spraying atomised tool steel particles against the casting cavity surface in a thickness exceeding 1 inch while rapidly cooling the sprayed particles to effect a net shape tool without the need for further working or heat treatment.
  • the tool steel particles achieve desired physical properties as a result of thermal spraying without further heat treatment or working is because the spraying process is conducted under carefully controlled conditions so that the deposited metal undergoes accelerated or rapid solidification upon hitting the target and automatically obtains a fine-grained micro structure that is uniform and quite hard.
  • the present invention involves the development of a unified CAD/CAM tool manufacturing system.
  • both prototyping and tooling fabrication are based upon compatible solid free form fabrication following a computer aided design and thus the underlying geometric and process models share a common representational scheme.
  • the representational scheme is created within a computer system by solid modelling methods. Certain conditions must be accommodated within the CAD/CAM die model such as a completely surfaced representation which can be converted to a STL file for use in some free-form fabrication system such as stereolithography.
  • solid free-form fabrication is utilised to build a three dimensional shape by incremental thin material layers.
  • the fabrication technique can make geometrically complex parts with little difficulty.
  • Free-form fabrication includes selective laser sintering stereolithography (described herein as the best mode), laminated object manufacturing, ballistic powder metallurgy, three dimensional printing, stratified extrusions and other methods.
  • Stereolithography is a relatively new process which creates plastic prototype models directly from a vat of liquid photo curable polymer through selective solidification using a scanning laser beam.
  • the system is comprised of a vat 11 of photosensitive liquid polymer 12, an x-y scanning ultraviolet laser beam 13, and a z-axis elevator 14 in the vat.
  • the laser beam is focused on the liquid surface 15 to cure the polymer 12, making a solid form 16 wherever the beam scans or intersects the surface.
  • the depth of cure is dosage-dependent.
  • the physical object to be created as described by the computer designed boundary representation model 17, is first sliced into thin cross-sectional layers along the z-axis. For each slice, the laser trajectory is dictated by the cross-section's boundary and by the bounded region.
  • the platform 18 of the elevator 14 is initially positioned at the surface of the liquid. As the laser draws a cross-section in the x-y plane, a solid layer is formed on the elevator platform. The platform is lowered and then the next layer is drawn in the same way and adheres to the previous layer. The layers are typically between .004" and .006" thick.
  • a three dimensional plastic object pattern 19 thus grows in the vat, starting at the object's bottom and building to the top. The accuracy of such stereolithographic object is of the order of 0.25mm (0.010 inches), while surface texture is dependent on the building orientation.
  • the pattern desirably is configured with a supporting platform 20.
  • Support structures may also be added to the plastic pattern to hold it together while it is being built.
  • the object is oriented in the vat and the stereolithography process parameters are planned for the best surface quality and fastest build time.
  • the bottom of the 3D stereolithography CAD pattern 19 is adhered to a base metal plate 21 of an open box 22 (preferably of aluminium); the box is open at its top 23.
  • a desired ceramic slurry 24 is poured around the SLA pattern 19 to form a mould 27 and completely covers its geometry to a thickness of greater than one inch at the thinnest wall section. Entrapped air is minimised by vibrating the box and slurry contained therein on a table 25, preferably in a vacuum chamber 26.
  • the mould 27 is either (i) air dried, removed and then fired to finally cure it, or (ii) the ceramic slurry is freeze cast to temperatures around -30°F and the pattern removed prior to the ceramic mould thawing out, or (iii) the ceramic slurry is dried and, then the pattern burned out while the ceramic is undergoing curing:
  • the latter is conventional investment casting and is not desirable because of the possibility of shell cracking, lower shell strength and poor geometric compatibility with the spray process. Freeze casting is preferred.
  • the pattern 19 is removed from the cured ceramic mould 27 by installing screws 28 in the back of the pattern 19 and pulling the pattern out physically.
  • a stationary plate may be used which the extraction screws extend through; by turning the screws inward they pull against the stationary plate and also pull the pattern 19 away from the ceramic mould 27.
  • the ceramic mould material is selected to provide a good surface finish (such as 1-4 microns), good thermal shock resistance value at temperatures of 1800-2400°F, able to withstand up to 2,400°F temperatures, have compressive strengths of about 9,000 psi and possess a low shrinkage (less than .3 percent) and possess low thermal expansion (1.0-4.0 E-6/degree F) and have no reaction to molten metal.
  • the ceramic is selected to be capable of withstanding a molten metal environment and have a very smooth surface with good dimensional accuracy. Materials useable for this invention include dental ceramics, investment casting slurries, fused silica and freeze cast alumina.
  • the open ceramic mould 27 is then used as a receptor for a metal spray forming step, such as melt atomisation or arc or plasma spraying.
  • a metal spray forming step such as melt atomisation or arc or plasma spraying.
  • Such step is desirably carried out by the osprey process wherein a semi-solid slurry 30 of hardenable steel is sprayed from an induction heated nozzle supply 31 and is impelled against the mould surface 29 with a high velocity due to the high pressure gases that atomise the molten fluid.
  • Metal droplets are formed from a melt that is atomised by gas (not from wire or powder). Continuous spraying is carried out to build up a layer that exceeds at least 1 inch in thickness, at its thinnest section.
  • Metals usable for the purpose of this invention include metals that have a high hardness as-deposited. These include certain tool steels such as A2 and plain carbon steel with (.8% carbon by weight) as well as maraging steels.
  • An A2 tool steel typically contains 1.0% by weight carbon, 1.0% Mo, and 5.0% chromium.
  • Such a tool steel usually must be hot worked to develop physical properties necessary for a die form. However, this hot working is eliminated by the osprey process because a fine grained microstructure is obtained in the as sprayed condition.
  • Other alloy steels that are air hardeable, will have a carbon content of between .5-1.35 percent.
  • Maraging steels are age-hardenable because of the presence of a martensitic microstructure. Such steels contain about 18% nickel, 7-9.5% cobalt, 3-5% molybdenum and .1-.8% titanium. Very little carbon is present. Such maraging steels are typically annealed at about 1,500°F and upon cooling transform to martensite (FeNi microstructure) and thereafter the steel is aged at about 900°F for about three hours to produce physical properties such as a tensile strength of about 250,000 psi, an elongation in 2 inches of about 7%, and a charpy impact value of about 12 foot pounds at 320°F. Maraging steels are difficult to machine and are seldom used for tooling, but can be readily spray formed to produce a desirable microstructure.
  • the density of the sprayed metal in accordance with this invention will vary depending on the spray process used, but is generally between 95-99.5%. If the tool is made by the osprey process, the density will be 99.5% and if it is made by an arc spraying process such as twin arc, the density will be about 95%.
  • the osprey process provides virtually no porosity in the as deposited metal because of the use of a semi-solid slurry that constantly feeds the solidifying tool material.
  • the spraying process will result in little or no shrinkage because of such continuous feeding of deposited material.
  • the spraying process results in a finer microstructure which produces improved strength, toughness and ductility over metals that are produced by typical casting techniques. The improvement in strength is usually about 25% above that of a casting and the ductility improvement is generally 50-100%.
  • the thermal spraying process of this invention avoids high residual stresses or at least produces lower residual stresses in the deposited metal because a controlled cooling process leads to control of transformation induced stresses, producing a neutral residual stress state in the finished part.
  • the lower residual stresses result because of the semi-solid nature of the material deposited; this allows for slow cooling after rapid solidification producing much lower residual stresses.
  • the spray cools at rates of up to 10 6 ° K/second during droplet flight, but the solidified tool will cool from 1800°F to room temperature over a period of two or more hours depending on the tool size after consolidation is complete.
  • twin arc spraying is utilised to deposit the sprayed metal, residual stresses are controlled by regulating the cooling rate through control of the metal deposit and gas flow rates, thereby regulating the martensitic transformation.
  • geometric accuracy and low residual stresses in the as deposited tool are achieved.
  • the completed tool 33 may then be mounted in a die set 34 and used to stamp parts just like any other stamping tool. Some machining may be required to square up the base 32 of the tool and obtain correct orientation when placed in part 35 of the die-set. Orientation of the base is critical in getting the tools oriented properly because the tool surfaces have complex shapes which must fit exactly.
  • the rapid tooling process of this invention creates very accurate geometrically curved surfaces, but some slight linear machining may be necessary to the die base to produce a tool which can be mounted correctly. The best and faster way to obtain linear straight cuts and surfaces, that are useful to orientation, is by a subsequent machining rather than to rely upon the rapid tooling technique.
  • the rapid tool may be used at least up to about 3000 stamping operations.

Abstract

Method of making a rapid tool, comprising: making a plastic pattern (19) of the tool by free form fabrication techniques following a computer aided design, the design having a base and no undercuts taken in a direction perpendicular to base; constructing a ceramic mould (27) as the inverse of the pattern; separating the pattern (19) from the mould (27) by a separating movement in a direction perpendicular to the base to leave a surface (29) defining a casting cavity within the mould; and thermally spraying tool steel particles (30) against the casting cavity surface (29) is a thickness exceeding 2.54 centimetres (1 inch) while rapidly cooling the sprayed particles to effect a net shape tool without the need for further working or heat treatment.

Description

  • This invention relates to the rapid making of prototype tools and more particularly to more rapid modes of making stamping dies for shaping sheet metal.
  • Heretofore, fabrication of tooling dies has been a time consuming and expensive process. There has not been a smooth transition from product concept to die concept, the tool product has required considerable machining to reach finished or near net shape.
  • An initial advance uses stereolithography to fabricate a three dimensional wax or plastic pattern in free-form following a computer design; the pattern is invested in a ceramic mould, built up by a series of slurry coatings therearound, and then melted or burned out by heating the mould in a furnace or autoclave. The mould is used in a conventional metal pouring or injection moulding operation to create a casting; the mould is destroyed to retrieve the casting (See U.S. Patent 4,844,144). Unfortunately, the casting must be milled, ground or further machined to substantially bring the casting to near net shape. There are also limitations on the sizes of components which can be cast to shape using this method as section thickness is limited to about 1.5 inches.
  • A further advance in the art is the use of metal spraying to form first and second thin mould shells around a pattern. Spraying is carried out robotically in accordance with the same computer design. The shells are backed-up by supporting material to complete the mould and a release agent is usually applied to the pattern to facilitate separation of the pattern from the mould shells. The mould shells are used conventionally to create a cast metal article (see U.S. patent 5,189,781). Unfortunately again, the cast article must be machined, milled or ground to near net shape to be used.
  • Each of the above advances do not create a tool that is near net shape as a result of metal deposition. Thus, more time and more cost must be expended to obtain the desired net shape. Furthermore, the cast metal must be worked to develop more desirable metallurgical properties needed for use as a die element, but even with such working, cast dies will have problems of porosity, microstructure, strength, ductility or residual stresses in some cases. Accordingly, it is an object of this invention to obtain an improved process for more rapidly making prototype stamping tools that create net shape dies that possess desirable physical properties including that for porosity, microstructure, strength, ductility and low residual stresses.
  • The present invention provides a method of making a rapid tool, comprising: (a) making a plastic pattern of the tool by free form fabrication techniques following a computer aided design, the design having a base and no undercuts taken in a direction perpendicular to base; (b) constructing a ceramic mould as the inverse of the pattern; © separating the pattern from the mould by a separating movement in a direction perpendicular to the base to leave a surface defining a casting cavity within the mould; and (d) spraying atomised tool steel particles against the casting cavity surface in a thickness exceeding 1 inch while rapidly cooling the sprayed particles to effect a net shape tool without the need for further working or heat treatment.
  • The tool steel particles achieve desired physical properties as a result of thermal spraying without further heat treatment or working is because the spraying process is conducted under carefully controlled conditions so that the deposited metal undergoes accelerated or rapid solidification upon hitting the target and automatically obtains a fine-grained micro structure that is uniform and quite hard.
  • The invention will now be described, by way of example, with reference to the accompanying drawings, in which:
    • Figure 1, is a schematic flow diagram of the processing steps of this invention;
    • Figure 2, is a plan view of a stereolithographic die pattern created from a computer aided design, the pattern being surrounded by ceramic mould material away from the pattern base; and
    • Figure 3, is a sectional elevational view of the pattern and mould of figure 2 taken along line 3-3 thereof.
  • The present invention involves the development of a unified CAD/CAM tool manufacturing system. In this system, both prototyping and tooling fabrication are based upon compatible solid free form fabrication following a computer aided design and thus the underlying geometric and process models share a common representational scheme. Turning to figure 1, the representational scheme is created within a computer system by solid modelling methods. Certain conditions must be accommodated within the CAD/CAM die model such as a completely surfaced representation which can be converted to a STL file for use in some free-form fabrication system such as stereolithography. Once the computer design or model has been created, solid free-form fabrication is utilised to build a three dimensional shape by incremental thin material layers. The fabrication technique can make geometrically complex parts with little difficulty. Free-form fabrication includes selective laser sintering stereolithography (described herein as the best mode), laminated object manufacturing, ballistic powder metallurgy, three dimensional printing, stratified extrusions and other methods.
  • Stereolithography is a relatively new process which creates plastic prototype models directly from a vat of liquid photo curable polymer through selective solidification using a scanning laser beam. The system is comprised of a vat 11 of photosensitive liquid polymer 12, an x-y scanning ultraviolet laser beam 13, and a z-axis elevator 14 in the vat. The laser beam is focused on the liquid surface 15 to cure the polymer 12, making a solid form 16 wherever the beam scans or intersects the surface. The depth of cure is dosage-dependent. The physical object to be created, as described by the computer designed boundary representation model 17, is first sliced into thin cross-sectional layers along the z-axis. For each slice, the laser trajectory is dictated by the cross-section's boundary and by the bounded region. The platform 18 of the elevator 14 is initially positioned at the surface of the liquid. As the laser draws a cross-section in the x-y plane, a solid layer is formed on the elevator platform. The platform is lowered and then the next layer is drawn in the same way and adheres to the previous layer. The layers are typically between .004" and .006" thick. A three dimensional plastic object pattern 19 thus grows in the vat, starting at the object's bottom and building to the top. The accuracy of such stereolithographic object is of the order of 0.25mm (0.010 inches), while surface texture is dependent on the building orientation. The pattern desirably is configured with a supporting platform 20.
  • Support structures may also be added to the plastic pattern to hold it together while it is being built. The object is oriented in the vat and the stereolithography process parameters are planned for the best surface quality and fastest build time.
  • To create the ceramic inverse pattern the bottom of the 3D stereolithography CAD pattern 19 is adhered to a base metal plate 21 of an open box 22 (preferably of aluminium); the box is open at its top 23. A desired ceramic slurry 24 is poured around the SLA pattern 19 to form a mould 27 and completely covers its geometry to a thickness of greater than one inch at the thinnest wall section. Entrapped air is minimised by vibrating the box and slurry contained therein on a table 25, preferably in a vacuum chamber 26. Depending on the character of the ceramic slurry 24 that is employed, the mould 27 is either (i) air dried, removed and then fired to finally cure it, or (ii) the ceramic slurry is freeze cast to temperatures around -30°F and the pattern removed prior to the ceramic mould thawing out, or (iii) the ceramic slurry is dried and, then the pattern burned out while the ceramic is undergoing curing: The latter is conventional investment casting and is not desirable because of the possibility of shell cracking, lower shell strength and poor geometric compatibility with the spray process. Freeze casting is preferred.
  • The pattern 19 is removed from the cured ceramic mould 27 by installing screws 28 in the back of the pattern 19 and pulling the pattern out physically. Or a stationary plate may be used which the extraction screws extend through; by turning the screws inward they pull against the stationary plate and also pull the pattern 19 away from the ceramic mould 27.
  • The ceramic mould material is selected to provide a good surface finish (such as 1-4 microns), good thermal shock resistance value at temperatures of 1800-2400°F, able to withstand up to 2,400°F temperatures, have compressive strengths of about 9,000 psi and possess a low shrinkage (less than .3 percent) and possess low thermal expansion (1.0-4.0 E-6/degree F) and have no reaction to molten metal. The ceramic is selected to be capable of withstanding a molten metal environment and have a very smooth surface with good dimensional accuracy. Materials useable for this invention include dental ceramics, investment casting slurries, fused silica and freeze cast alumina.
  • The open ceramic mould 27 is then used as a receptor for a metal spray forming step, such as melt atomisation or arc or plasma spraying. Such step is desirably carried out by the osprey process wherein a semi-solid slurry 30 of hardenable steel is sprayed from an induction heated nozzle supply 31 and is impelled against the mould surface 29 with a high velocity due to the high pressure gases that atomise the molten fluid. Metal droplets are formed from a melt that is atomised by gas (not from wire or powder). Continuous spraying is carried out to build up a layer that exceeds at least 1 inch in thickness, at its thinnest section.
  • Metals usable for the purpose of this invention include metals that have a high hardness as-deposited. These include certain tool steels such as A2 and plain carbon steel with (.8% carbon by weight) as well as maraging steels. An A2 tool steel typically contains 1.0% by weight carbon, 1.0% Mo, and 5.0% chromium. Such a tool steel usually must be hot worked to develop physical properties necessary for a die form. However, this hot working is eliminated by the osprey process because a fine grained microstructure is obtained in the as sprayed condition. Other alloy steels that are air hardeable, will have a carbon content of between .5-1.35 percent.
  • Maraging steels are age-hardenable because of the presence of a martensitic microstructure. Such steels contain about 18% nickel, 7-9.5% cobalt, 3-5% molybdenum and .1-.8% titanium. Very little carbon is present. Such maraging steels are typically annealed at about 1,500°F and upon cooling transform to martensite (FeNi microstructure) and thereafter the steel is aged at about 900°F for about three hours to produce physical properties such as a tensile strength of about 250,000 psi, an elongation in 2 inches of about 7%, and a charpy impact value of about 12 foot pounds at 320°F. Maraging steels are difficult to machine and are seldom used for tooling, but can be readily spray formed to produce a desirable microstructure.
  • The density of the sprayed metal in accordance with this invention, will vary depending on the spray process used, but is generally between 95-99.5%. If the tool is made by the osprey process, the density will be 99.5% and if it is made by an arc spraying process such as twin arc, the density will be about 95%. The osprey process provides virtually no porosity in the as deposited metal because of the use of a semi-solid slurry that constantly feeds the solidifying tool material. The spraying process will result in little or no shrinkage because of such continuous feeding of deposited material. The spraying process results in a finer microstructure which produces improved strength, toughness and ductility over metals that are produced by typical casting techniques. The improvement in strength is usually about 25% above that of a casting and the ductility improvement is generally 50-100%.
  • The thermal spraying process of this invention avoids high residual stresses or at least produces lower residual stresses in the deposited metal because a controlled cooling process leads to control of transformation induced stresses, producing a neutral residual stress state in the finished part. In the osprey process, the lower residual stresses result because of the semi-solid nature of the material deposited; this allows for slow cooling after rapid solidification producing much lower residual stresses. The spray cools at rates of up to 106° K/second during droplet flight, but the solidified tool will cool from 1800°F to room temperature over a period of two or more hours depending on the tool size after consolidation is complete.
  • If twin arc spraying is utilised to deposit the sprayed metal, residual stresses are controlled by regulating the cooling rate through control of the metal deposit and gas flow rates, thereby regulating the martensitic transformation. Thus, geometric accuracy and low residual stresses in the as deposited tool are achieved.
  • The completed tool 33 may then be mounted in a die set 34 and used to stamp parts just like any other stamping tool. Some machining may be required to square up the base 32 of the tool and obtain correct orientation when placed in part 35 of the die-set. Orientation of the base is critical in getting the tools oriented properly because the tool surfaces have complex shapes which must fit exactly. The rapid tooling process of this invention creates very accurate geometrically curved surfaces, but some slight linear machining may be necessary to the die base to produce a tool which can be mounted correctly. The best and faster way to obtain linear straight cuts and surfaces, that are useful to orientation, is by a subsequent machining rather than to rely upon the rapid tooling technique. The rapid tool may be used at least up to about 3000 stamping operations.

Claims (9)

  1. A method of making a rapid tool, comprising:
    (a) making a plastic pattern (19) of the tool by free-form fabrication techniques following a computer aided design, said design having an exposed base with no undercuts taken in a direction perpendicular to the base;
    (b) constructing a ceramic mould (27) as the inverse of the pattern;
    (c) separating the pattern (19) from the mould (27) by a separating movement in a direction perpendicular to the base to leave a surface (29) defining a casting cavity within the mould; and
    (d) thermally spraying tool steel particles (30) against said casting cavity surface (29) in a thickness exceeding 2.54 centimetres (1 inch) while rapidly cooling the sprayed particles to effect a near net shape tool possessing a hardness of at least HRc 40, without need for further working or heat treatment.
  2. A method as claimed in claim 1, in which the step (c) is carried out by use of a ceramic that is cured at room temperature or is cured by freezing or firing.
  3. A method as claimed in claim 1 or 2, in which the metal particles used in step (d) consist of semi-solid liquid particles with a liquid-solid fraction ranging from 20%-75%.
  4. A method as claimed in any one of claims 1 to 3, in which the step (d) is carried out at a deposition rate of about 0.454 kg(1 pound) per second.
  5. A method as claimed in any one of the preceding claims, in which the physical tool part properties resulting from the completion of the step (d) include a tensile strength of at least 25% more than a comparable casting, a ductility of 50%-100% or more comparable casting, and a microstructure characterised by five, uniform grains.
  6. A| method as claimed in claim 5, in which said physical properties further include a resistance to cracking, a porosity of 5 percent or less accompanied by little or no shrinkage, and low residual stresses.
  7. A method as claimed in any one of the preceding claims, in which said tool steel particles are selected from the group comprising plain carbon tool steels and maraging tool steels.
  8. A method as claimed in any one of the preceding claims, in which the step (d) is carried out by either the osprey process or twin arc spraying.
  9. A method as claimed in any one of the preceding claims, in which the ceramic used for the step (c) is selected from the group consisting of dental ceramics, investment casting slurries, fused silica, freeze cast alumina, and advanced cement based materials.
EP96308516A 1995-12-27 1996-11-26 Spray formed rapid tools Withdrawn EP0781625A1 (en)

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US08/579,110 US5658506A (en) 1995-12-27 1995-12-27 Methods of making spray formed rapid tools

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0962270A1 (en) * 1998-06-01 1999-12-08 Ford Global Technologies, Inc. A method for forming turbine hubs
EP0980916A2 (en) * 1998-07-30 2000-02-23 Ford Motor Company Sprayforming bulk deposits of allotropic metal
EP1038987A1 (en) * 1999-03-25 2000-09-27 Ford Motor Company Method of reducing distortion in a spray formed rapid tool
GB2351687A (en) * 1999-07-06 2001-01-10 Ford Global Tech Inc Optimizing cycle time and/or casting quality in the making of cast metal products
EP1159085A1 (en) * 1999-02-23 2001-12-05 Sprayform Holdings Limited Spray deposition process
EP1245304A1 (en) * 2000-12-13 2002-10-02 Ford Global Technologies, Inc. A method of making a spray formed rapid tool
DE10317797A1 (en) * 2003-04-16 2004-11-11 AHC-Oberflächentechnik GmbH & Co. OHG Production of mold tools for rapid prototyping comprises roughening of the surface without chemical pretreatment, application of an intermediate copper or nickel layer and application of a metallic or ceramic covering by thermal spraying
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Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB9419328D0 (en) * 1994-09-24 1994-11-09 Sprayform Tools & Dies Ltd Method for controlling the internal stresses in spray deposited articles
US7244622B2 (en) * 1996-04-03 2007-07-17 Applera Corporation Device and method for multiple analyte detection
US5983495A (en) * 1997-12-29 1999-11-16 Ford Global Technologies, Inc. Method of making spray-formed inserts
US5901593A (en) * 1998-01-26 1999-05-11 Northrop Grumman Corporation Making hydropress formblocks and dies utilizing stereolithography and liquid molding compounds
AU2496699A (en) * 1998-02-06 1999-08-23 Express Tool, Inc. Thermally efficient mold apparatus and method
US5967218A (en) * 1998-07-06 1999-10-19 Ford Motor Company Method of integrating detailed features into a spray formed rapid tool
US6298900B1 (en) 1998-07-06 2001-10-09 Ford Global Technologies, Inc. Method of integrating wear plates into a spray formed rapid tool
US6174481B1 (en) * 1998-09-10 2001-01-16 Lear Automotive Dearborn, Inc. Method for forming cast tooling for polymer molding
US6308765B1 (en) 1998-11-04 2001-10-30 Grigoriy Grinberg Method of making tools having a core die and a cavity die
US6155330A (en) * 1998-11-04 2000-12-05 Visteon Global Technologies, Inc. Method of spray forming metal deposits using a metallic spray forming pattern
US6257309B1 (en) 1998-11-04 2001-07-10 Ford Global Technologies, Inc. Method of spray forming readily weldable and machinable metal deposits
CN1093452C (en) * 1999-04-27 2002-10-30 张海鸥 Smelting-ejecting technology for manufacturing metallic mould
US6305459B1 (en) * 1999-08-09 2001-10-23 Ford Global Technologies, Inc. Method of making spray-formed articles using a polymeric mandrel
WO2001026498A1 (en) * 1999-10-08 2001-04-19 Rapid Design Technologies (Pty) Limited Die manufacturing
US6276431B1 (en) 2000-02-29 2001-08-21 Visteon Global Technologies, Inc. Method of making a spray formed rapid tool
US6447704B1 (en) 2000-05-23 2002-09-10 Gmic, Corp. Thermal-sprayed tooling
US6602545B1 (en) * 2000-07-25 2003-08-05 Ford Global Technologies, L.L.C. Method of directly making rapid prototype tooling having free-form shape
US6648053B2 (en) 2001-04-18 2003-11-18 Ford Motor Company Method and apparatus for controlling a spray form process based on sensed surface temperatures
US6640878B2 (en) 2001-04-18 2003-11-04 Ford Motor Company Automated spray form cell
US6805188B2 (en) * 2001-04-18 2004-10-19 Ford Global Technologies, Llc Method and arrangement for heat treatment before the execution of sprayform techniques
US6904950B2 (en) * 2001-11-05 2005-06-14 Ford Motor Company Method and arrangement for affecting time, temperature and transformation dependent stress relief in sprayform techniques
US6955209B2 (en) 2001-11-05 2005-10-18 Ford Motor Company Method and arrangement implementing heat treatment after the execution of sprayform techniques
US6883581B2 (en) * 2001-11-27 2005-04-26 Ford Motor Company Method and arrangement for implementing heat treatment during the execution of spray-form techniques
US6923241B2 (en) 2001-11-27 2005-08-02 Ford Motor Company Method and arrangement for controlling stresses based on one-dimensional modeling in sprayform techniques
US20030222366A1 (en) * 2001-12-21 2003-12-04 Ivan Stangel Production of dental restorations and other custom objects by free-form fabrication methods and systems therefor
US6837299B2 (en) * 2002-04-26 2005-01-04 Sky+Ltd. Heating to control solidification of cast structure
US6820677B2 (en) 2002-08-20 2004-11-23 Ford Motor Company Method of making a spray formed article
US6749002B2 (en) * 2002-10-21 2004-06-15 Ford Motor Company Method of spray joining articles
US6796366B2 (en) * 2002-10-30 2004-09-28 Ford Motor Company Method for producing a freeze-cast substrate
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US6810939B2 (en) * 2003-02-04 2004-11-02 Ford Motor Company Spray formed articles made of boron steel and method for making the same
US7357886B2 (en) * 2003-10-31 2008-04-15 Groth Lauren A Singular molded and co-molded electronic's packaging pre-forms
DE112006000461T5 (en) * 2005-02-22 2008-03-13 Milwaukee School Of Engineering, Milwaukee casting process
US20070029446A1 (en) * 2005-05-02 2007-02-08 Mosher Todd J Modular platform architecture for satellites
US20070040702A1 (en) * 2005-05-02 2007-02-22 Mosher Todd J Method for creating highly integrated satellite systems
US20090047439A1 (en) * 2007-08-16 2009-02-19 Withers James C Method and apparatus for manufacturing porous articles
US20100193480A1 (en) * 2009-01-30 2010-08-05 Honeywell International Inc. Deposition of materials with low ductility using solid free-form fabrication
US20110132562A1 (en) * 2009-12-08 2011-06-09 Merrill Gary B Waxless precision casting process
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CN115106731B (en) * 2022-06-08 2023-07-25 绍兴昌杰机械有限公司 Production process of die

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3512571A (en) 1968-04-12 1970-05-19 American Cast Iron Pipe Co Cryogenic formation of refractory molds and other foundry articles
JPS57187127A (en) * 1981-05-12 1982-11-17 Nissan Motor Co Ltd Production for pressure die
JPS58110138A (en) * 1981-12-23 1983-06-30 Nissan Motor Co Ltd Production of press die
US4844144A (en) 1988-08-08 1989-07-04 Desoto, Inc. Investment casting utilizing patterns produced by stereolithography
US5079974A (en) * 1991-05-24 1992-01-14 Carnegie-Mellon University Sprayed metal dies
US5189781A (en) 1990-08-03 1993-03-02 Carnegie Mellon University Rapid tool manufacturing

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE790453A (en) * 1971-10-26 1973-02-15 Brooks Reginald G MANUFACTURE OF METAL ARTICLES
US4066117A (en) * 1975-10-28 1978-01-03 The International Nickel Company, Inc. Spray casting of gas atomized molten metal to produce high density ingots
US4447466A (en) * 1981-08-14 1984-05-08 General Electric Company Process for making plasma spray-cast components using segmented mandrels
GB8507647D0 (en) * 1985-03-25 1985-05-01 Osprey Metals Ltd Manufacturing metal products
US5126529A (en) * 1990-12-03 1992-06-30 Weiss Lee E Method and apparatus for fabrication of three-dimensional articles by thermal spray deposition
EP0500225B1 (en) * 1991-01-31 1995-12-06 Texas Instruments Incorporated Method and system for computer-controlled manufacture of three dimensional objects from computer data
US5203944A (en) * 1991-10-10 1993-04-20 Prinz Fritz B Method for fabrication of three-dimensional articles by thermal spray deposition using masks as support structures
US5370692A (en) * 1992-08-14 1994-12-06 Guild Associates, Inc. Rapid, customized bone prosthesis

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3512571A (en) 1968-04-12 1970-05-19 American Cast Iron Pipe Co Cryogenic formation of refractory molds and other foundry articles
JPS57187127A (en) * 1981-05-12 1982-11-17 Nissan Motor Co Ltd Production for pressure die
JPS58110138A (en) * 1981-12-23 1983-06-30 Nissan Motor Co Ltd Production of press die
US4844144A (en) 1988-08-08 1989-07-04 Desoto, Inc. Investment casting utilizing patterns produced by stereolithography
US5189781A (en) 1990-08-03 1993-03-02 Carnegie Mellon University Rapid tool manufacturing
US5079974A (en) * 1991-05-24 1992-01-14 Carnegie-Mellon University Sprayed metal dies

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
A.R.E.SINGER: "The New Developments in Sprayfroming Technology", CONFERENCE PROCEEDINGS OF THE POWER METALLURGY WORLD CONGRESS, June 1994 (1994-06-01), PARIS, FRANCE, pages 1941 - 1944, XP000667240
PATENT ABSTRACTS OF JAPAN vol. 7, no. 215 (M - 244) 22 September 1983 (1983-09-22) *
PATENT ABSTRACTS OF JAPAN vol. 7, no. 31 (M - 192) 8 February 1983 (1983-02-08) *

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US6513567B2 (en) 1998-11-04 2003-02-04 Ford Global Technologies, Inc. Method of making a spray formed rapid tool
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