EP0591361A4 - Method for dyeing nylon filaments - Google Patents
Method for dyeing nylon filamentsInfo
- Publication number
- EP0591361A4 EP0591361A4 EP19920913760 EP92913760A EP0591361A4 EP 0591361 A4 EP0591361 A4 EP 0591361A4 EP 19920913760 EP19920913760 EP 19920913760 EP 92913760 A EP92913760 A EP 92913760A EP 0591361 A4 EP0591361 A4 EP 0591361A4
- Authority
- EP
- European Patent Office
- Prior art keywords
- solution
- nylon filament
- nylon
- batch
- filament
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B15/00—Other brushes; Brushes with additional arrangements
- A46B15/0002—Arrangements for enhancing monitoring or controlling the brushing process
- A46B15/0004—Arrangements for enhancing monitoring or controlling the brushing process with a controlling means
- A46B15/001—Arrangements for enhancing monitoring or controlling the brushing process with a controlling means with means indicating the remaining useful life of brush
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/04—Preparing bristles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/0004—General aspects of dyeing
- D06P1/002—Processing by repeated dyeing, e.g. in different baths
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
- D06P3/241—Polyamides; Polyurethanes using acid dyes
Definitions
- the invention relates to filaments for toothbrushes.
- Breuer et al. U.S. Pat. No. 4,802,255 describes nylon monofilaments that include at least two colored regions, one of which is provided by a dye.
- the monofilaments are included in the bristles of toothbrushes and, as the toothbrush is used by the owner, the color intensity of the dyed region changes in response to wear, providing an indication of when the toothbrush should be replaced.
- Breuer et al. lists six food dyes or colorants that can be used to dye the monofilaments including Indigotine (FD&C Blue No. 2) , and in col. 4 broadly describes the conditions that can be used for dyeing.
- Breuer et al. also provides a number of specific examples of dyeing procedures, including three (examples 4-6) in which Indigotine is used as the dye.
- the invention is a method for dyeing batches of nylon filaments for toothbrushes.
- a batch is at least two pounds of nylon filament.
- the method includes immersing a batch of a first nylon filament for between 10 minutes and 80 minutes in an aqueous solution containing between .01% and 0.1% weight to volume of Indigotine dye.
- the solution should have a pH between 1 and 7, and should have a temperature between 50 ⁇ C. and 90 *C.
- the nylon filament is immersed, the dye penetrates into an outer cross-sectional region but not into an inner cross-sectional region.
- the batch of the first nylon filament is removed from the solution, and can be used for bristles in a wear-indicating toothbrush.
- the same procedure is repeated for a batch of a second nylon filament, reusing the same solution.
- the same solution is then used for dyeing additional batches.
- the aqueous solution contains between 0.01% and 0.05% weight to volume of Indigotine dye; the solution has a pH of between 2.5 and 4.5; and the temperature of the solution is between 70'C. and 85"C.
- the dyeing step is performed at atmospheric pressure and takes less than 60 minutes, and the nylon filaments have a diameter of between 0.005 inches and 0.014 inches.
- the method can be used to produce commercial quantities of nylon filaments for use in wear- indicating toothbrushes in a cost-effective manner. For example, the procedure can be used on 10-40 lb.
- the dyeing solution used in the method of the invention contains between 0.01% and 0.1% weight to volume Indigotine. If too much Indigotine is used, too much dye penetrates too far into the filament. If too little dye is used, too little dye may penetrate, and the solution may not be reusable because the initial batch of filament may absorb the limited quantity of dye present.
- the temperature of the solution should be between 50 ⁇ C. and 90 ⁇ C. Too high a temperature results in water quickly evaporating off, resulting in the dye becoming more concentrated, and the dye being taken up too fast, making the degree of penetration more difficult to control. Too low a temperature results in too slow a dye uptake.
- the dyeing process preferably is done at atmospheric pressure, to avoid the necessity of using large pressurized equipment in a plant.
- Indigotine is an acid stable dye, and the solution should be acidic.
- the volume of dyeing solution should be large enough so that the first batch of filament does not absorb such a high percentage of the dye in the solution that the solution cannot be reused to dye a second batch.
- the nylon filaments should be of the diameter commonly used in toothbrushes, most preferably 0.008 or 0.009 inch.
- the nylon filament should be immersed in solution long enough to get adequate dye penetration of the outer cross-sectional diameter of the filament to provide good wear-indicating characteristics.
- the immersion time should be as limited as possible, and should be less than 1 hour.
- the dyeing step is performed in a 633 gallon Whiting stainless steel tank having side dimensions of 30" x 40" x 130".
- the dyeing solution used in the tan ' includes 633 gallons of distilled water; 7.7 liters of glacial acidic acid; and 555 g of 100% pure Indigotine. The temperature of the solution is maintained at 75*C. + 1.5*C.
- the first tank is filled with tap water.
- the second tank is filled with tap water mixed with 1.5 liters of Dow Corning #24 silicone emulsion.
- the monofilament used is an eight foot long, 0.008 inch diameter Wytex 6.12 S nylon hank (bundle) weighing approximately 10 pounds.
- the hank should be siliconed, annealed, wet, and combed prior to dyeing, according to standard procedures. The hank should not be dried prior to use.
- the above procedure can be modified by immersing set of hanks for 30 minutes in a dyeing solution heated to 80 ⁇ C. + 1.5 ⁇ C.
- the procedure can be used to dye 10 hanks at a time, as opposed to four hanks.
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US71619691A | 1991-06-17 | 1991-06-17 | |
US716196 | 1991-06-17 | ||
PCT/US1992/004589 WO1992022699A1 (en) | 1991-06-17 | 1992-06-02 | Method for dyeing nylon filaments |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0591361A1 EP0591361A1 (en) | 1994-04-13 |
EP0591361A4 true EP0591361A4 (en) | 1994-05-18 |
EP0591361B1 EP0591361B1 (en) | 1996-12-27 |
Family
ID=24877134
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92913760A Expired - Lifetime EP0591361B1 (en) | 1991-06-17 | 1992-06-02 | Method for dyeing nylon filaments |
Country Status (12)
Country | Link |
---|---|
EP (1) | EP0591361B1 (en) |
JP (1) | JP2831465B2 (en) |
KR (1) | KR100205843B1 (en) |
CN (1) | CN1051118C (en) |
AU (1) | AU663099B2 (en) |
BR (1) | BR9206016A (en) |
CA (1) | CA2109935C (en) |
DE (1) | DE69216234T2 (en) |
MX (1) | MX9202915A (en) |
SG (1) | SG48428A1 (en) |
WO (1) | WO1992022699A1 (en) |
ZA (1) | ZA923986B (en) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100425767C (en) * | 2007-02-03 | 2008-10-15 | 王小芳 | Staining method of tip brush silk |
CN103806307A (en) * | 2013-12-18 | 2014-05-21 | 慈溪市洁达纳米复合材料有限公司 | Preparation method for plating colorful dye on brush filaments |
CN105033836B (en) * | 2015-07-06 | 2017-12-08 | 上海悦瑞电子科技有限公司 | A kind of technique processing method based on the colouring of 3D printing product surface |
JP6232511B1 (en) * | 2017-03-03 | 2017-11-15 | 株式会社ショーワ | Denim product yarn manufacturing method, and denim product yarn, denim product fabric, and denim product manufactured by the method |
CN107724117A (en) * | 2017-09-21 | 2018-02-23 | 晋江市明仨纺织品科技有限公司 | A kind of preparation method of automatic decolouring fiber |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4802255A (en) * | 1987-08-10 | 1989-02-07 | Gillette Canada Inc. | Novel brush filaments |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2558992A (en) * | 1951-07-03 | Colored nylon article and method | ||
JP2770437B2 (en) * | 1989-07-10 | 1998-07-02 | 三井化学株式会社 | Rope dyeing method and rope dyeing |
-
1992
- 1992-06-01 ZA ZA923986A patent/ZA923986B/en unknown
- 1992-06-02 JP JP5500726A patent/JP2831465B2/en not_active Expired - Fee Related
- 1992-06-02 DE DE69216234T patent/DE69216234T2/en not_active Expired - Lifetime
- 1992-06-02 AU AU21862/92A patent/AU663099B2/en not_active Expired
- 1992-06-02 KR KR1019930703630A patent/KR100205843B1/en not_active IP Right Cessation
- 1992-06-02 EP EP92913760A patent/EP0591361B1/en not_active Expired - Lifetime
- 1992-06-02 CA CA002109935A patent/CA2109935C/en not_active Expired - Fee Related
- 1992-06-02 SG SG1996009602A patent/SG48428A1/en unknown
- 1992-06-02 BR BR9206016-1A patent/BR9206016A/en not_active IP Right Cessation
- 1992-06-02 WO PCT/US1992/004589 patent/WO1992022699A1/en active IP Right Grant
- 1992-06-16 CN CN92104692A patent/CN1051118C/en not_active Expired - Lifetime
- 1992-06-16 MX MX9202915A patent/MX9202915A/en not_active IP Right Cessation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4802255A (en) * | 1987-08-10 | 1989-02-07 | Gillette Canada Inc. | Novel brush filaments |
Non-Patent Citations (3)
Title |
---|
CHEMICAL ABSTRACTS, vol. 104, no. 18, 5 May 1986, Columbus, Ohio, US; abstract no. 150660v, BARYBINA, L. A. ET AL: "Multiple use of residual dye solutions" * |
See also references of WO9222699A1 * |
TEKST. PROM-ST. (MOSCOW), (12), 55, 1985 * |
Also Published As
Publication number | Publication date |
---|---|
ZA923986B (en) | 1993-02-24 |
MX9202915A (en) | 1993-01-01 |
JP2831465B2 (en) | 1998-12-02 |
JPH06503860A (en) | 1994-04-28 |
EP0591361A1 (en) | 1994-04-13 |
WO1992022699A1 (en) | 1992-12-23 |
DE69216234T2 (en) | 1997-06-05 |
SG48428A1 (en) | 1998-04-17 |
BR9206016A (en) | 1994-08-02 |
DE69216234D1 (en) | 1997-02-06 |
KR100205843B1 (en) | 1999-07-01 |
CN1067936A (en) | 1993-01-13 |
AU2186292A (en) | 1993-01-12 |
CA2109935C (en) | 2000-01-25 |
CN1051118C (en) | 2000-04-05 |
EP0591361B1 (en) | 1996-12-27 |
AU663099B2 (en) | 1995-09-28 |
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