EP0475620A3 - Microemulsion diesel fuel compositions and method of use - Google Patents

Microemulsion diesel fuel compositions and method of use Download PDF

Info

Publication number
EP0475620A3
EP0475620A3 EP19910307780 EP91307780A EP0475620A3 EP 0475620 A3 EP0475620 A3 EP 0475620A3 EP 19910307780 EP19910307780 EP 19910307780 EP 91307780 A EP91307780 A EP 91307780A EP 0475620 A3 EP0475620 A3 EP 0475620A3
Authority
EP
European Patent Office
Prior art keywords
diesel fuel
fuel compositions
microemulsion diesel
microemulsion
compositions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP19910307780
Other versions
EP0475620B1 (en
EP0475620A2 (en
Inventor
Michael David Sexton
Anthony Kitson Smith
Jan Bock
Max Leo Robbins
Salvatore James Pace
Patrick Gerard Grimes
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Publication of EP0475620A2 publication Critical patent/EP0475620A2/en
Publication of EP0475620A3 publication Critical patent/EP0475620A3/en
Application granted granted Critical
Publication of EP0475620B1 publication Critical patent/EP0475620B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/02Use of additives to fuels or fires for particular purposes for reducing smoke development
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/32Liquid carbonaceous fuels consisting of coal-oil suspensions or aqueous emulsions or oil emulsions
    • C10L1/328Oil emulsions containing water or any other hydrophilic phase
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00Use of additives to fuels or fires for particular purposes
    • C10L10/12Use of additives to fuels or fires for particular purposes for improving the cetane number
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02BINTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B3/00Engines characterised by air compression and subsequent fuel addition
    • F02B3/06Engines characterised by air compression and subsequent fuel addition with compression ignition
EP91307780A 1990-09-07 1991-08-23 Microemulsion diesel fuel compositions and method of use Expired - Lifetime EP0475620B1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US57848290A 1990-09-07 1990-09-07
US57848390A 1990-09-07 1990-09-07
US578483 1990-09-07
US578482 1990-09-07

Publications (3)

Publication Number Publication Date
EP0475620A2 EP0475620A2 (en) 1992-03-18
EP0475620A3 true EP0475620A3 (en) 1992-07-22
EP0475620B1 EP0475620B1 (en) 1995-11-08

Family

ID=27077508

Family Applications (1)

Application Number Title Priority Date Filing Date
EP91307780A Expired - Lifetime EP0475620B1 (en) 1990-09-07 1991-08-23 Microemulsion diesel fuel compositions and method of use

Country Status (4)

Country Link
EP (1) EP0475620B1 (en)
JP (1) JP2974466B2 (en)
CA (1) CA2048906C (en)
DE (1) DE69114422T2 (en)

Families Citing this family (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5584894A (en) * 1992-07-22 1996-12-17 Platinum Plus, Inc. Reduction of nitrogen oxides emissions from vehicular diesel engines
USRE35237E (en) * 1989-11-22 1996-05-14 Gunnerman Rudolf W Aqueous fuel for internal combustion engine and method of combustion
US5743922A (en) * 1992-07-22 1998-04-28 Nalco Fuel Tech Enhanced lubricity diesel fuel emulsions for reduction of nitrogen oxides
EP0682101A1 (en) * 1994-03-17 1995-11-15 Gerhard Auer Water-fuel emulsion for combustion engines
US6302929B1 (en) 1994-04-04 2001-10-16 Rudolf W. Gunnerman Aqueous fuel for internal combustion engine and method of preparing
US5669938A (en) * 1995-12-21 1997-09-23 Ethyl Corporation Emulsion diesel fuel composition with reduced emissions
HU216371B (en) * 1996-09-23 1999-06-28 Levente Fülöp Stable macromolecular disperse fuel composition containing water for the operation of internal combustion engines ashybrid engines and process to produce said composition
US5800576A (en) * 1996-11-13 1998-09-01 Quantum Energy Technologies Corporation Water clusters and uses therefor
US5997590A (en) * 1996-11-13 1999-12-07 Quantum Energy Technologies Corp. Stabilized water nanocluster-fuel emulsions designed through quantum chemistry
CA2313686C (en) * 1997-12-12 2011-02-22 Caterpillar Inc. Constant heating value aqueous fuel mixture and method for formulating the same
US6656236B1 (en) 1997-12-12 2003-12-02 Clean Fuel Technology, Inc. Constant heating value aqueous fuel mixture and method for formulating the same
US6648929B1 (en) 1998-09-14 2003-11-18 The Lubrizol Corporation Emulsified water-blended fuel compositions
AU1420600A (en) * 1999-09-06 2001-04-10 Agrofuel Ab Motor fuel for diesel engines
EP1721956B1 (en) 2000-01-12 2013-03-06 Pirelli & C. Eco Technology S.p.A. Polymeric surfactant for a fuel comprising an emulsion between water and a liquid hydrocarbon
US6606856B1 (en) 2000-03-03 2003-08-19 The Lubrizol Corporation Process for reducing pollutants from the exhaust of a diesel engine
US7276093B1 (en) * 2000-05-05 2007-10-02 Inievep, S.A. Water in hydrocarbon emulsion useful as low emission fuel and method for forming same
US20030084658A1 (en) 2000-06-20 2003-05-08 Brown Kevin F Process for reducing pollutants from the exhaust of a diesel engine using a water diesel fuel in combination with exhaust after-treatments
SE523228C2 (en) 2000-12-15 2004-04-06 Akzo Nobel Nv Fuel composition containing a hydrocarbon fraction, ethanol and an additive with water solubilizing capacity
EP1419225B1 (en) 2001-07-09 2006-09-13 Pirelli & C. Ambiente Eco Technology S.p.A. Fuel comprising an emulsion between water and a liquid hydrocarbon
EP1490458B1 (en) 2002-03-28 2015-06-10 Pirelli & C. Ambiente S.r.l. Method for reducing emission of pollutants from an internal combustion engine, and fuel emulsion comprising water and a liquid hydrocarbon
US7413583B2 (en) 2003-08-22 2008-08-19 The Lubrizol Corporation Emulsified fuels and engine oil synergy
EP2064153B1 (en) 2006-09-05 2016-06-29 Cerion LLC Method of preparing cerium dioxide nanoparticles
US10435639B2 (en) 2006-09-05 2019-10-08 Cerion, Llc Fuel additive containing lattice engineered cerium dioxide nanoparticles
US8883865B2 (en) 2006-09-05 2014-11-11 Cerion Technology, Inc. Cerium-containing nanoparticles
US7915470B2 (en) 2006-09-08 2011-03-29 Board Of Regents, The University Of Texas System Coupled electrochemical method for reduction of polyols to hydrocarbons
US20140041286A1 (en) * 2007-09-24 2014-02-13 Sylvatex, Inc. Method of formulating a fuel composition for use in internal-combustion engines
EP2253692A1 (en) 2009-05-19 2010-11-24 Universität zu Köln Bio-hydrofuel compounds
DE102009048223A1 (en) 2009-10-05 2011-06-16 Fachhochschule Trier Process for the in-situ production of fuel-water mixtures in internal combustion engines
CN101940981A (en) * 2010-08-07 2011-01-12 武贵丙 Highly watered micro-emulsified diesel oil additive, preparation method and application thereof
DE202011107729U1 (en) 2011-11-11 2012-01-12 Elmar Vitt Production and stabilization of water-oil emulsions by electro-osmosis
ITRM20110694A1 (en) 2011-12-29 2013-06-30 Fuel S A E STABILIZED EMULSIONS WITH WATER-EFFECTIVE DIESEL OIL.
WO2015058037A1 (en) 2013-10-17 2015-04-23 Cerion, Llc Malic acid stabilized nanoceria particles
DE102014225815A1 (en) 2014-12-15 2016-06-16 Fachhochschule Trier In-situ production of fuel-water mixtures in internal combustion engines
DE202015003014U1 (en) 2015-04-26 2015-05-28 Elmar Vitt Device for the indirect use of water-oil emulsions in vehicles and other external users

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1088759B (en) * 1957-11-29 1960-09-08 Exxon Research Engineering Co Fuel for engines with compression ignition
EP0022110A1 (en) * 1979-06-29 1981-01-07 Berol Kemi Ab Emulsifier and its use for the manufacture of an emulsion in mineral oil
US4477258A (en) * 1980-10-30 1984-10-16 Labofina, S.A. Diesel fuel compositions and process for their production
EP0209758A2 (en) * 1985-07-13 1987-01-28 Hüls Aktiengesellschaft Motor fuels and heating oils and use of an emulgator system in the preparation of these motor fuels and heating oils

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1088759B (en) * 1957-11-29 1960-09-08 Exxon Research Engineering Co Fuel for engines with compression ignition
EP0022110A1 (en) * 1979-06-29 1981-01-07 Berol Kemi Ab Emulsifier and its use for the manufacture of an emulsion in mineral oil
US4477258A (en) * 1980-10-30 1984-10-16 Labofina, S.A. Diesel fuel compositions and process for their production
EP0209758A2 (en) * 1985-07-13 1987-01-28 Hüls Aktiengesellschaft Motor fuels and heating oils and use of an emulgator system in the preparation of these motor fuels and heating oils

Also Published As

Publication number Publication date
CA2048906A1 (en) 1992-03-08
EP0475620B1 (en) 1995-11-08
DE69114422D1 (en) 1995-12-14
EP0475620A2 (en) 1992-03-18
DE69114422T2 (en) 1996-03-21
JPH04234492A (en) 1992-08-24
CA2048906C (en) 2002-12-10
JP2974466B2 (en) 1999-11-10

Similar Documents

Publication Publication Date Title
EP0475620A3 (en) Microemulsion diesel fuel compositions and method of use
EP0455185A3 (en) Hair-treating microemulsion composition and method of preparing and using the same
GB8929119D0 (en) Diesel fuel compositions
KR100230939B1 (en) Low nox combustion method and its burner
EP0554095A3 (en) Determination of fuel characteristics
GB2198289B (en) Electromagnetic fuel injector and method of producing the same
AU7367391A (en) Fuel injector method and apparatus
AU656593B2 (en) Methods of preparing and using stable oil external-aqueous internal emulsions
GB2283336B (en) Device and method of correcting the fuel amount supplied to Otto engines
GB9208479D0 (en) Method of making refuse-derived fuel and fuel made by the method
GB9213854D0 (en) Additives and fuel compositions
PL298704A1 (en) Environmentally friendly fuel and method of obtaining same
GB9116527D0 (en) Reduction of diesel emissions
GB9019440D0 (en) Fuels and fuel additives
AU7890291A (en) Fuel resistant glove and method of manufacture
GB2265988B (en) Testing of fuel suction lines
PL273985A1 (en) Fuel composition and method of obtaining the same
AU5019290A (en) This invention relates to improvements in and relating to combustion engines
GB8922067D0 (en) Improvements in combustion engines
GR910100007A (en) Method and additive for the improvement of the combustion of combustible materials
HU912642D0 (en) Producing diesel fuel of fat
GB9213873D0 (en) Additives and fuel compositions
GB9525893D0 (en) Testing of fuel suction lines
GB9005301D0 (en) Improvements in and relating to aircraft engines
HUT66034A (en) Method and water injector for increasing output of four-cycled petrol engine

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

AK Designated contracting states

Kind code of ref document: A2

Designated state(s): BE DE FR GB IT NL

PUAL Search report despatched

Free format text: ORIGINAL CODE: 0009013

AK Designated contracting states

Kind code of ref document: A3

Designated state(s): BE DE FR GB IT NL

17P Request for examination filed

Effective date: 19930107

17Q First examination report despatched

Effective date: 19930723

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): BE DE FR GB IT NL

REF Corresponds to:

Ref document number: 69114422

Country of ref document: DE

Date of ref document: 19951214

ET Fr: translation filed
ITF It: translation for a ep patent filed

Owner name: MODIANO & ASSOCIATI S.R.L.

PLBE No opposition filed within time limit

Free format text: ORIGINAL CODE: 0009261

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT

26N No opposition filed
PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: NL

Payment date: 19990625

Year of fee payment: 9

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20010301

NLV4 Nl: lapsed or anulled due to non-payment of the annual fee

Effective date: 20010301

REG Reference to a national code

Ref country code: GB

Ref legal event code: IF02

NLXE Nl: other communications concerning ep-patents (part 3 heading xe)

Free format text: A REQUEST FOR RESTORATION TO THE PRIOR STATE (ART. 23 OF THE PATENTS ACT 1995) HAS BEEN FILED ON 23.11.01.

NLXE Nl: other communications concerning ep-patents (part 3 heading xe)

Free format text: THE REQUEST FOR RESTORATION TO THE PRIOR STATE AS PROVIDED FOR IN ARTICLE 23 OF THE PATENTS ACT 1995 (SEE PUBLICATION IN HEADING XE OF THE PATENT BULLETIN OF 01.02.2002/02) HAS BEEN REJECTED.

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20040707

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20040804

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20040831

Year of fee payment: 14

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: BE

Payment date: 20040901

Year of fee payment: 14

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050823

Ref country code: GB

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050823

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20050831

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060301

GBPC Gb: european patent ceased through non-payment of renewal fee

Effective date: 20050823

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: FR

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20060428

REG Reference to a national code

Ref country code: FR

Ref legal event code: ST

Effective date: 20060428

BERE Be: lapsed

Owner name: *EXXON RESEARCH AND ENGINEERING CY

Effective date: 20050831