EP0261718A2 - Creamy scouring compositions - Google Patents
Creamy scouring compositions Download PDFInfo
- Publication number
- EP0261718A2 EP0261718A2 EP87201698A EP87201698A EP0261718A2 EP 0261718 A2 EP0261718 A2 EP 0261718A2 EP 87201698 A EP87201698 A EP 87201698A EP 87201698 A EP87201698 A EP 87201698A EP 0261718 A2 EP0261718 A2 EP 0261718A2
- Authority
- EP
- European Patent Office
- Prior art keywords
- composition
- weight
- compositions
- accordance
- organic solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
Definitions
- the present invention relates to stable, viscous abrasive-containing scouring compositions, which show excellent cleaning, ease-of-rinsing, and shine performance, and are not aggressive to surfaces to be cleansed therewith and packaging materials.
- compositions are substantially free of terpene solvents, and contain a narrowly-defined solvent derived from propylene glycol.
- creamy scouring compositions containing an abrasive and binary solvent system constituted of terpenes and polar solvents have been disclosed in European Patent Application 0,126,545, published on November 28, 1984.
- the terpenes show both cleaning and desirable emulsification properties, which enhance product viscosity.
- viscous terpene solvent free creamy scouring cleanser compositions showing remarkable cleaning efficiency, ease-of-rinsing and surface-compatibility, can be formulated which contain a narrowly-defined solvent derived from propylene glycol.
- the present invention relates to a viscous creamy scouring cleanser being substantially free of terpene solvents, containing a surface-active agent, an abrasive, and an organic solvent and if desired conventional additives, characterized in that said cleanser is substantially free of terpene solvents and that the organic solvent is represented by the formula: wherein R is a C1 to C8 alkyl, alkenyl or alkyl aryl group, preferably a C1 to C4 alkyl group, and n is an integer from 1 to 4, preferably 1 or 2.
- Water-soluble detersive surfactants useful herein include well-known synthetic anionic, nonionic, amphoteric and zwitterionic surfactants and mixtures thereof. Typical of these are the alkyl benzene sulfates and sulfonates, paraffin sulfonates, olefin sulfonates, alkoxylated (especially ethoxylated) alcohols and alkyl phenols, amine oxides, sulfonates of fatty acids and of fatty acid esters, and the like, which are well-known in the detergency art.
- such detersive surfactants contain an alkyl group in the C10-C18 range; the anionic detersive surfactants are most commonly used in the form of their sodium, potassium or triethanolammonium salts.
- the nonionics generally contain from 3 to 17 ethylene oxide groups per mole of hydrophobic moeity.
- Particular preferred in the compositions of the present invention are: C12-C16 alkyl benzene sulfonates, C12-C18 paraffin-sulfonates and the ethoxylated alcohols of the formula RO(CH2CH2O) n , with R being a C12-C15 alkyl chain and n being a number from 6 to 10.
- Anionic sufactants are frequently present at levels from 0.3 to 8%, preferably 2 to 4%, of the composition.
- Nonionic surfactants are used at levels between 0.1% to 6% by weight of the composition. Mixtures of the like surfactants can also be used.
- the total level of surface-active agent is preferably from 3% to 5%.
- Abrasive - The abrasive types employed herein are selected from water-insoluble, non-gritty materials well-known in the literature for their relatively mild abrasive properties. It is highly preferred that the abrasives used herein not be undesirably "scratchy". Abrasive materials having a Mohs hardness in the range of about 7, or below, are typically used; abrasives having a Mohs hardness of 3, or below, can be used to avoid scratches on aluminum or stainless steel finishes.
- Suitable abrasives herein include inorganic materials, especially such materials as calcium carbonate and diatomaceous earth, as well as materials such as Fuller's earth, magnesium carbonate, China clay, attapulgite, calcium hydroxyapatite, calcium orthophosphate, dolomite and the like.
- the aforesaid inorganic materials can be qualified as "strong abrasives”.
- Synthetic organic abrasives such as urea-formaldehyde, methyl methacrylate melamine-formaldehyde resins, polyethylene spheres and polyvinylchloride can be advantageously used in order to avoid scratching on certain surfaces, especially plastic surfaces. When such "soft abrasives” are used, strong builders can be incorporated in the composition.
- abrasives typically have a particle size range of 10-1000 microns and are used at concentrations of 5% to 30% in the compositions. Thickeners are frequently added to suspend the abrasives.
- the organic solvent - The organic solvent to be used in the present composition has the general formula wherein R is an alkyl, alkenyl, or alkyl-aryl group having from 1 to 8 carbon atoms, and n is an integer from 1 to 4.
- R is a alkyl group containing 1 to 4 carbon atoms, and n is 1 or 2.
- Especially preferred R groups are n-butyl or isobutyl.
- 1-n-butoxypropane-2-ol is especially preferred.
- the organic solvent herein is used at levels of from 2 to 10% by weight of the composition, preferably 4 to 6%.
- the solvent system can optionally contain, in combination with the solvent described hereinabove, water-soluble CARBITOL® solvents or water-soluble CELLOSOLVE® solvents.
- Water-soluble CARBITOL® solvents are compounds of the 2-(2-alkoxyethyoxy)ethanol class wherein the alkoxy group is derived from ethyl, propyl or butyl; a preferred water-soluble carbitol is 2-(2-butoxyethoxy)ethanol also known as butyl carbitol.
- Water-soluble CELLOSOLVE® solvents are compound of the 2-alkoxy ethanol class, with 2-butyl ethanol being preferred.
- Suitable solvents to be used with the solvents of the invention are also benzyl alcohol, and diols such as 2-ethyl-2,3-hexanediol and 2,2,4-trimethyl-1,3-pentanediol.
- co-solvents can be used in levels ranging from 0.1 to 5% of the composition.
- compositions herein are substantially free of terpene-solvents.
- solvents are generally used at levels exceeding about 2%, terpenes cannot be incorporated in the claimed compositions in such proportions.
- relatively minor sub-additive levels of terpenes e.g., below about 0.6% (calculated on the total cleanser composition), can be present originating from conventional ingredients such as perfumes.
- the present composition can contain additional components, which can be highly desirable.
- compositions contain a detergent builder and/or metal ion sequestrant.
- detergent builders include the nitrilotriacetates, (NTA), ethylene diamine tetracetate (EDTA), amino-polyphosphonates (DEQUEST), water-soluble phosphates such as tri-polyphosphate and sodium ortho- and pryo-phosphates, silicates, and mixtures thereof. These builders are preferably not used in combination with strong abrasives like calcium carbonate, but are recommended in combination with soft organic abrasives like polyvinylchloride.
- Metal ion sequestrants of lower metal sequestration constant can advantageously be used in combination with strong or soft abrasives.
- Those metal ion sequestrants include polycarboxylates, citrates.
- Preferred builders/sequestrants for use in the present invention are NTA, EDTA, citrates and mixtures thereof.
- the builders/sequestrant will be present at levels of from 1% to 15%, preferably from 2% to 7%.
- soaps in the compositions of the invention. Soaps prepared from coconut oil fatty acids are preferred.
- Soaps are used in amounts ranging from 0.2% to 3% by weight of the composition, preferably in an amount in excess of 1%, typically from 1% to 2% by weight.
- Thickeners should preferably be included in the compositions of the invention, in order to suspend the abrasive. However, the level will be kept under 2%, preferably from 0.2% to 1.5%. Common thickeners such as the polyacrylates, xanthan gums, carboxymethyl celluloses, swellable smectite clays, and the like, can be used herein.
- Optional components also represented by ingredients typically used in commercial products to provide aesthetic or additional product performance benefits.
- Typical ingredients include pH regulants, perfumes, dyes, optical brighteners, soil suspending agents, detersive enzymes, gel-control agents, freeze thaw stabilizers, bactericides, preservatives, and the like.
- Another optional ingredient for use herein is represented by conventional detergent hydrotropes.
- suitable hydrotropes are urea, monoethanolamine, diethanolamine, triethanolamine and the sodium potassium, ammonium and alkanol ammonium salts of xylene-, toluene-, ethylbenzene- and isopropyl-benzene sulfonates. It is a particular feature of the present invention, however, that stable formulations can be prepared without the need for hydrotropic materials of this kind.
- compositions herein typically contain up to about 90% water as a carrier.
- water-level can vary in the range from e.g. 50% to 80%.
- Water-alchol e.g., ethanol, isopropanol, butanol, etc.
- Alkylated polysaccharides can be used to increase the stability and performance characteristics of the compositions.
- compositions herein are preferbly formulated in the alkaline pH range, generally in the range of pH 8-11, preferably about 10-10.8.
- Caustics such as sodium hydroxide and sodium carbonate can be used to adjust and buffer the pH as desired.
- Creamy cleansers were prepared by mixing the listed ingredients in the stated proportions (% by weight).
- test-soils were prepared as follows.
- the plates are placed in the oven at 115°C ("soft soil”) or 170°C (“hard soil”) for 2 hours and then allowed to age at least 1 day.
- the testing conditions were as follows:
- compositions are prepared:
Abstract
Description
- The present invention relates to stable, viscous abrasive-containing scouring compositions, which show excellent cleaning, ease-of-rinsing, and shine performance, and are not aggressive to surfaces to be cleansed therewith and packaging materials.
- These compositions are substantially free of terpene solvents, and contain a narrowly-defined solvent derived from propylene glycol.
- It is well-known to formulate scouring compositions, in liquid or creamy form, containing solvents.
- In particular, creamy scouring compositions containing an abrasive and binary solvent system constituted of terpenes and polar solvents have been disclosed in European Patent Application 0,126,545, published on November 28, 1984. In these compositions, the terpenes show both cleaning and desirable emulsification properties, which enhance product viscosity.
- It has become desirable, however, to replace terpenes by solvents which are fully compatible with all types of surfaces to be cleansed therewith, and packaging materials, and at the same time exhibit good cleaning and emulsification properties.
- It now been found that viscous terpene solvent free creamy scouring cleanser compositions showing remarkable cleaning efficiency, ease-of-rinsing and surface-compatibility, can be formulated which contain a narrowly-defined solvent derived from propylene glycol.
- US-3,591,510 discloses the use of solvents of this type in liquid hard surface cleaning compositions free of abrasive. EP-A-O 040 882 mentions the use of propylene glycol-derived solvents, in combination with terpenes and benzyl alcohols, in liquid hard surface cleanser free of abrasive.
- It is an object of the present invention to provide viscous creamy cleanser compositions which are fully compatible with surfaces to be cleansed therewith and packaging materials. It is a further object of the present invention to provide a cleanser composition with excellent cleaning, ease-off-reasing and shine performance.
- The present invention relates to a viscous creamy scouring cleanser being substantially free of terpene solvents, containing a surface-active agent, an abrasive, and an organic solvent and if desired conventional additives, characterized in that said cleanser is substantially free of terpene solvents and that the organic solvent is represented by the formula:
- The surface-active agents, the abrasives, the solvent and the optional ingredients are described in more detail hereinafter.
- Unless indicated to the contrary, the %-indications stand for "% by weight".
- Water-soluble detersive surfactants useful herein include well-known synthetic anionic, nonionic, amphoteric and zwitterionic surfactants and mixtures thereof. Typical of these are the alkyl benzene sulfates and sulfonates, paraffin sulfonates, olefin sulfonates, alkoxylated (especially ethoxylated) alcohols and alkyl phenols, amine oxides, sulfonates of fatty acids and of fatty acid esters, and the like, which are well-known in the detergency art. In general, such detersive surfactants contain an alkyl group in the C₁₀-C₁₈ range; the anionic detersive surfactants are most commonly used in the form of their sodium, potassium or triethanolammonium salts. The nonionics generally contain from 3 to 17 ethylene oxide groups per mole of hydrophobic moeity. Especially preferred in the compositions of the present invention are: C₁₂-C₁₆ alkyl benzene sulfonates, C₁₂-C₁₈ paraffin-sulfonates and the ethoxylated alcohols of the formula RO(CH₂CH₂O)n, with R being a C₁₂-C₁₅ alkyl chain and n being a number from 6 to 10.
- Anionic sufactants are frequently present at levels from 0.3 to 8%, preferably 2 to 4%, of the composition. Nonionic surfactants, are used at levels between 0.1% to 6% by weight of the composition. Mixtures of the like surfactants can also be used. The total level of surface-active agent is preferably from 3% to 5%.
- Abrasive - The abrasive types employed herein are selected from water-insoluble, non-gritty materials well-known in the literature for their relatively mild abrasive properties. It is highly preferred that the abrasives used herein not be undesirably "scratchy". Abrasive materials having a Mohs hardness in the range of about 7, or below, are typically used; abrasives having a Mohs hardness of 3, or below, can be used to avoid scratches on aluminum or stainless steel finishes. Suitable abrasives herein include inorganic materials, especially such materials as calcium carbonate and diatomaceous earth, as well as materials such as Fuller's earth, magnesium carbonate, China clay, attapulgite, calcium hydroxyapatite, calcium orthophosphate, dolomite and the like. The aforesaid inorganic materials can be qualified as "strong abrasives". Synthetic organic abrasives such as urea-formaldehyde, methyl methacrylate melamine-formaldehyde resins, polyethylene spheres and polyvinylchloride can be advantageously used in order to avoid scratching on certain surfaces, especially plastic surfaces. When such "soft abrasives" are used, strong builders can be incorporated in the composition.
- Typically, abrasives have a particle size range of 10-1000 microns and are used at concentrations of 5% to 30% in the compositions. Thickeners are frequently added to suspend the abrasives.
- The organic solvent - The organic solvent to be used in the present composition has the general formula
- The organic solvent herein is used at levels of from 2 to 10% by weight of the composition, preferably 4 to 6%.
- The solvent system can optionally contain, in combination with the solvent described hereinabove, water-soluble CARBITOL® solvents or water-soluble CELLOSOLVE® solvents. Water-soluble CARBITOL® solvents are compounds of the 2-(2-alkoxyethyoxy)ethanol class wherein the alkoxy group is derived from ethyl, propyl or butyl; a preferred water-soluble carbitol is 2-(2-butoxyethoxy)ethanol also known as butyl carbitol. Water-soluble CELLOSOLVE® solvents are compound of the 2-alkoxy ethanol class, with 2-butyl ethanol being preferred.
- Suitable solvents to be used with the solvents of the invention are also benzyl alcohol, and diols such as 2-ethyl-2,3-hexanediol and 2,2,4-trimethyl-1,3-pentanediol.
- The above-described co-solvents can be used in levels ranging from 0.1 to 5% of the composition.
- The compositions herein are substantially free of terpene-solvents. Inasmuch as solvents are generally used at levels exceeding about 2%, terpenes cannot be incorporated in the claimed compositions in such proportions. It is understood, however, that relatively minor sub-additive levels of terpenes, e.g., below about 0.6% (calculated on the total cleanser composition), can be present originating from conventional ingredients such as perfumes.
- Optional Ingredients - In addition to the essential ingredients listed hereinbefore, the present composition can contain additional components, which can be highly desirable.
- For example, it is highly preferred that the compositions contain a detergent builder and/or metal ion sequestrant. Compounds classifiable and well-known in the art as detergent builders include the nitrilotriacetates, (NTA), ethylene diamine tetracetate (EDTA), amino-polyphosphonates (DEQUEST), water-soluble phosphates such as tri-polyphosphate and sodium ortho- and pryo-phosphates, silicates, and mixtures thereof. These builders are preferably not used in combination with strong abrasives like calcium carbonate, but are recommended in combination with soft organic abrasives like polyvinylchloride.
- Metal ion sequestrants of lower metal sequestration constant can advantageously be used in combination with strong or soft abrasives. Those metal ion sequestrants include polycarboxylates, citrates. Preferred builders/sequestrants for use in the present invention are NTA, EDTA, citrates and mixtures thereof. The builders/sequestrant will be present at levels of from 1% to 15%, preferably from 2% to 7%.
- It is highly preferred, as well, to include soaps in the compositions of the invention. Soaps prepared from coconut oil fatty acids are preferred.
- Soaps are used in amounts ranging from 0.2% to 3% by weight of the composition, preferably in an amount in excess of 1%, typically from 1% to 2% by weight.
- This level is clearly above levels currently used in similar compositions, since it has surprisingly been discovered that the presence of soaps at these higher levels not only provides suds control, but also has a thickening effect on the compositions containing the specific organic solvent of the invention. This finding allows to keep the amount of thickener at a very low level, thus substantially reducing certain drawbacks of thickeners, such as rinsing difficulties resulting from their use at substantial levels.
- Thickeners should preferably be included in the compositions of the invention, in order to suspend the abrasive. However, the level will be kept under 2%, preferably from 0.2% to 1.5%. Common thickeners such as the polyacrylates, xanthan gums, carboxymethyl celluloses, swellable smectite clays, and the like, can be used herein.
- Optional components also represented by ingredients typically used in commercial products to provide aesthetic or additional product performance benefits. Typical ingredients include pH regulants, perfumes, dyes, optical brighteners, soil suspending agents, detersive enzymes, gel-control agents, freeze thaw stabilizers, bactericides, preservatives, and the like.
- Another optional ingredient for use herein is represented by conventional detergent hydrotropes. Examples of suitable hydrotropes are urea, monoethanolamine, diethanolamine, triethanolamine and the sodium potassium, ammonium and alkanol ammonium salts of xylene-, toluene-, ethylbenzene- and isopropyl-benzene sulfonates. It is a particular feature of the present invention, however, that stable formulations can be prepared without the need for hydrotropic materials of this kind.
- The compositions herein typically contain up to about 90% water as a carrier. By way of example the water-level can vary in the range from e.g. 50% to 80%. Water-alchol (e.g., ethanol, isopropanol, butanol, etc.) mixtures can also be used. Alkylated polysaccharides can be used to increase the stability and performance characteristics of the compositions.
- The compositions herein are preferbly formulated in the alkaline pH range, generally in the range of pH 8-11, preferably about 10-10.8. Caustics such as sodium hydroxide and sodium carbonate can be used to adjust and buffer the pH as desired.
-
-
- The above compositions were comparatively tested on synthetic soils representative of typical hard surface household soils. The test-soils were prepared as follows.
- a) HBTS soil: is composed of 250 ml isopropyl alcohol, 75g calcium stearate powder and 0.5g carbon black. It is applied on an enamel-coated metal plate (cleaned with a detergent and then with alcohol) with a paint roller, and the plates are baked at 180°C for 20 minutes.
- b) KD soil: is composed of 25% HSW® soil with carbon black (2), 37.5% Crisco® (1) oil, 37.5% Puritan® (1) oil. This soil is rolled onto stainless steel plates (beforehand cleaned with a detergent and then with alcohol) using a paint roller. A very thin uniform layer is needed since the soil is difficult to cure.
- The plates are placed in the oven at 115°C ("soft soil") or 170°C ("hard soil") for 2 hours and then allowed to age at least 1 day.
- (1) commercial cooking oil sold by The Procter & Gamble Company
- (2) commercial soil sold by Chem Pack Inc., U.S.A.
- The testing conditions were as follows:
- The test was run with the aid of an Erichsen washability machine. A sponge of approximately 0.5 x 5 x 4 cm was used after being carefully washed under hot running water and squeezed through drying rolls. 5g of the undiluted cleanser to be tested was spread over one side of the sponge. The number of strokes of the cleaning machine varied with the type of soil. Performance readings were done as soon as visible cleaning diffrences became noticeable. The gradings were done visually by three judges working independently. The performance benefits were established via paired comparison with duplicates as follows. A 0-4 scale was used whereby: 0 means no difference; 1 = probable difference; 2 = consistent difference; 3 = clear difference; 4 = big difference.
-
- The above test clearly confirms the significant performance benefits derivable from the inventive compositions vs. related art composition.
-
Claims (8)
- from 3% to 5% by weight of organic surface-active agent;
- from 1% to 2% by weight of fatty acid soap;
- 4% to 6% by weight of an organic solvent selected from 1-n-butoxypropane-2-ol, 1(2-n-butoxy-1-methyl ethoxy)propane-2-ol, and mixtures thereof;
- from 2% to 7% by weight of a detergent builder and/or metal ion sequestrant material selected from nitrilotriacetate, ethylene diamine tetraacetate, citrate, and mixtures thereof.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT87201698T ATE61401T1 (en) | 1986-09-22 | 1987-09-08 | PASTE DETERGENTS. |
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US91056186A | 1986-09-22 | 1986-09-22 | |
US910561 | 1986-09-22 | ||
GB8624156 | 1986-10-08 | ||
GB868624156A GB8624156D0 (en) | 1986-10-08 | 1986-10-08 | Creamy scouring compositions |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0261718A2 true EP0261718A2 (en) | 1988-03-30 |
EP0261718A3 EP0261718A3 (en) | 1989-01-25 |
EP0261718B1 EP0261718B1 (en) | 1991-03-06 |
Family
ID=26291398
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP19870201698 Expired EP0261718B1 (en) | 1986-09-22 | 1987-09-08 | Creamy scouring compositions |
Country Status (3)
Country | Link |
---|---|
EP (1) | EP0261718B1 (en) |
DE (1) | DE3768398D1 (en) |
IE (1) | IE60580B1 (en) |
Cited By (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0329209A2 (en) * | 1988-01-30 | 1989-08-23 | The Procter & Gamble Company | Creamy scouring compositions |
EP0426943A2 (en) * | 1989-11-08 | 1991-05-15 | Arakawa Chemical Industries, Ltd. | Agent and method for removing rosinbase solder flux |
US5330582A (en) * | 1989-11-08 | 1994-07-19 | Arakawa Chemical Industries, Ltd. | Method for cleaning rosin-base solder flux |
US5547476A (en) * | 1995-03-30 | 1996-08-20 | The Procter & Gamble Company | Dry cleaning process |
US5591236A (en) * | 1995-03-30 | 1997-01-07 | The Procter & Gamble Company | Polyacrylate emulsified water/solvent fabric cleaning compositions and methods of using same |
US5630848A (en) * | 1995-05-25 | 1997-05-20 | The Procter & Gamble Company | Dry cleaning process with hydroentangled carrier substrate |
US5630847A (en) * | 1995-03-30 | 1997-05-20 | The Procter & Gamble Company | Perfumable dry cleaning and spot removal process |
US5632780A (en) * | 1995-03-30 | 1997-05-27 | The Procter & Gamble Company | Dry cleaning and spot removal proces |
US5681355A (en) * | 1995-08-11 | 1997-10-28 | The Procter & Gamble Company | Heat resistant dry cleaning bag |
US5687591A (en) * | 1995-06-20 | 1997-11-18 | The Procter & Gamble Company | Spherical or polyhedral dry cleaning articles |
US5762648A (en) * | 1997-01-17 | 1998-06-09 | The Procter & Gamble Company | Fabric treatment in venting bag |
US5789368A (en) * | 1996-01-26 | 1998-08-04 | The Procter & Gamble Company | Fabric care bag |
US5804548A (en) * | 1995-03-30 | 1998-09-08 | The Procter & Gamble Company | Dry cleaning process and kit |
US5840675A (en) * | 1996-02-28 | 1998-11-24 | The Procter And Gamble Company | Controlled released fabric care article |
US5849039A (en) * | 1997-01-17 | 1998-12-15 | The Procter & Gamble Company | Spot removal process |
US5872090A (en) * | 1996-10-25 | 1999-02-16 | The Procter & Gamble Company | Stain removal with bleach |
US5891197A (en) * | 1996-08-02 | 1999-04-06 | The Proctor & Gamble Company | Stain receiver for dry cleaning process |
US5912408A (en) * | 1995-06-20 | 1999-06-15 | The Procter & Gamble Company | Dry cleaning with enzymes |
US5942484A (en) * | 1995-03-30 | 1999-08-24 | The Procter & Gamble Company | Phase-stable liquid fabric refreshment composition |
US6233771B1 (en) | 1996-01-26 | 2001-05-22 | The Procter & Gamble Company | Stain removal device |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3591509A (en) * | 1968-09-30 | 1971-07-06 | Procter & Gamble | Liquid hard surface cleaning compositions |
GB1533390A (en) * | 1976-04-08 | 1978-11-22 | Shell Int Research | Detergent compositions |
EP0040882A1 (en) * | 1980-05-27 | 1981-12-02 | THE PROCTER & GAMBLE COMPANY | Liquid detergent compositions |
EP0126545A1 (en) * | 1983-04-19 | 1984-11-28 | The Procter & Gamble Company | Liquid scouring cleansers containing solvent system |
-
1987
- 1987-09-08 DE DE8787201698T patent/DE3768398D1/en not_active Expired - Fee Related
- 1987-09-08 EP EP19870201698 patent/EP0261718B1/en not_active Expired
- 1987-09-21 IE IE253887A patent/IE60580B1/en not_active IP Right Cessation
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3591509A (en) * | 1968-09-30 | 1971-07-06 | Procter & Gamble | Liquid hard surface cleaning compositions |
GB1533390A (en) * | 1976-04-08 | 1978-11-22 | Shell Int Research | Detergent compositions |
EP0040882A1 (en) * | 1980-05-27 | 1981-12-02 | THE PROCTER & GAMBLE COMPANY | Liquid detergent compositions |
EP0126545A1 (en) * | 1983-04-19 | 1984-11-28 | The Procter & Gamble Company | Liquid scouring cleansers containing solvent system |
Cited By (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0329209A2 (en) * | 1988-01-30 | 1989-08-23 | The Procter & Gamble Company | Creamy scouring compositions |
EP0329209A3 (en) * | 1988-01-30 | 1990-05-23 | The Procter & Gamble Company | Creamy scouring compositions |
EP0426943A2 (en) * | 1989-11-08 | 1991-05-15 | Arakawa Chemical Industries, Ltd. | Agent and method for removing rosinbase solder flux |
EP0426943A3 (en) * | 1989-11-08 | 1991-09-04 | Arakawa Chemical Industries, Ltd. | Agent and method for removing rosinbase solder flux |
US5330582A (en) * | 1989-11-08 | 1994-07-19 | Arakawa Chemical Industries, Ltd. | Method for cleaning rosin-base solder flux |
US5591236A (en) * | 1995-03-30 | 1997-01-07 | The Procter & Gamble Company | Polyacrylate emulsified water/solvent fabric cleaning compositions and methods of using same |
US5804548A (en) * | 1995-03-30 | 1998-09-08 | The Procter & Gamble Company | Dry cleaning process and kit |
US5630847A (en) * | 1995-03-30 | 1997-05-20 | The Procter & Gamble Company | Perfumable dry cleaning and spot removal process |
US5632780A (en) * | 1995-03-30 | 1997-05-27 | The Procter & Gamble Company | Dry cleaning and spot removal proces |
US5547476A (en) * | 1995-03-30 | 1996-08-20 | The Procter & Gamble Company | Dry cleaning process |
US5942484A (en) * | 1995-03-30 | 1999-08-24 | The Procter & Gamble Company | Phase-stable liquid fabric refreshment composition |
US5630848A (en) * | 1995-05-25 | 1997-05-20 | The Procter & Gamble Company | Dry cleaning process with hydroentangled carrier substrate |
US5687591A (en) * | 1995-06-20 | 1997-11-18 | The Procter & Gamble Company | Spherical or polyhedral dry cleaning articles |
US5912408A (en) * | 1995-06-20 | 1999-06-15 | The Procter & Gamble Company | Dry cleaning with enzymes |
US5681355A (en) * | 1995-08-11 | 1997-10-28 | The Procter & Gamble Company | Heat resistant dry cleaning bag |
US5789368A (en) * | 1996-01-26 | 1998-08-04 | The Procter & Gamble Company | Fabric care bag |
US6233771B1 (en) | 1996-01-26 | 2001-05-22 | The Procter & Gamble Company | Stain removal device |
US5840675A (en) * | 1996-02-28 | 1998-11-24 | The Procter And Gamble Company | Controlled released fabric care article |
US5891197A (en) * | 1996-08-02 | 1999-04-06 | The Proctor & Gamble Company | Stain receiver for dry cleaning process |
US5872090A (en) * | 1996-10-25 | 1999-02-16 | The Procter & Gamble Company | Stain removal with bleach |
US5849039A (en) * | 1997-01-17 | 1998-12-15 | The Procter & Gamble Company | Spot removal process |
US5762648A (en) * | 1997-01-17 | 1998-06-09 | The Procter & Gamble Company | Fabric treatment in venting bag |
Also Published As
Publication number | Publication date |
---|---|
IE60580B1 (en) | 1994-07-27 |
DE3768398D1 (en) | 1991-04-11 |
IE872538L (en) | 1988-03-22 |
EP0261718B1 (en) | 1991-03-06 |
EP0261718A3 (en) | 1989-01-25 |
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