EP0205300A3 - Aromatization reactions with zeolites - Google Patents

Aromatization reactions with zeolites Download PDF

Info

Publication number
EP0205300A3
EP0205300A3 EP86304197A EP86304197A EP0205300A3 EP 0205300 A3 EP0205300 A3 EP 0205300A3 EP 86304197 A EP86304197 A EP 86304197A EP 86304197 A EP86304197 A EP 86304197A EP 0205300 A3 EP0205300 A3 EP 0205300A3
Authority
EP
European Patent Office
Prior art keywords
zeolites
aromatization reactions
aromatization
reactions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP86304197A
Other versions
EP0205300B1 (en
EP0205300A2 (en
Inventor
Chin-Chiun Chu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US06/744,072 external-priority patent/US4590321A/en
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of EP0205300A2 publication Critical patent/EP0205300A2/en
Publication of EP0205300A3 publication Critical patent/EP0205300A3/en
Application granted granted Critical
Publication of EP0205300B1 publication Critical patent/EP0205300B1/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
EP86304197A 1985-06-12 1986-06-03 Aromatization reactions with zeolites Expired - Lifetime EP0205300B1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US06/744,072 US4590321A (en) 1985-06-12 1985-06-12 Aromatization reactions with zeolites containing phosphorus oxide
US744072 1985-06-12
US810156 1985-12-18
US06/810,156 US4665251A (en) 1985-06-12 1985-12-18 Aromatization reactions with zeolites containing phosphorus oxide

Publications (3)

Publication Number Publication Date
EP0205300A2 EP0205300A2 (en) 1986-12-17
EP0205300A3 true EP0205300A3 (en) 1987-08-19
EP0205300B1 EP0205300B1 (en) 1991-07-03

Family

ID=27114255

Family Applications (1)

Application Number Title Priority Date Filing Date
EP86304197A Expired - Lifetime EP0205300B1 (en) 1985-06-12 1986-06-03 Aromatization reactions with zeolites

Country Status (5)

Country Link
US (1) US4665251A (en)
EP (1) EP0205300B1 (en)
AU (1) AU595508B2 (en)
CA (1) CA1262363A (en)
DE (1) DE3680034D1 (en)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA1270005A (en) * 1985-10-07 1990-06-05 Mobil Oil Corporation Catalytic conversion of propane to ethylene over zsm- 23
US4929791A (en) * 1985-10-07 1990-05-29 Mobil Oil Corporation Catalytic conversion of propane to ethylene over ZSM-50
US4854939A (en) * 1987-12-08 1989-08-08 Mobil Oil Corporation Aromatization and etherification process integration
US4918256A (en) * 1988-01-04 1990-04-17 Mobil Oil Corporation Co-production of aromatics and olefins from paraffinic feedstocks
US5026937A (en) * 1989-12-29 1991-06-25 Uop Aromatization of methane using zeolite incorporated in a phosphorus-containing alumina
EP0464249B1 (en) * 1990-07-05 1994-01-05 VAW Aluminium AG Process for the manufacture of crystalline molecular sieves with large pores
US6040257A (en) * 1997-11-07 2000-03-21 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
US6417421B1 (en) * 1998-03-03 2002-07-09 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and process therefor and therewith
US6395949B1 (en) 1998-08-03 2002-05-28 Phillips Petroleum Company Acid treated zeolite containing phosphorus used as a catalyst in processes for converting hydrocarbons, and use of binary hydrocarbon mixtures as diluents in processes for converting hydrocarbons
US6124227A (en) * 1998-08-28 2000-09-26 Phillips Petroleum Company Hydrocarbon conversion catalyst composition and processes therefor and therewith
DE10046734A1 (en) * 2000-09-21 2002-05-16 Siemens Ag Pressure relief valve
US7084318B2 (en) * 2003-08-01 2006-08-01 Saudi Basic Industries Corporation Toluene methylation process
US7064152B2 (en) * 2003-09-26 2006-06-20 3M Innovative Properties Company Arylsulfinate salts in photoinitiator systems for polymerization reactions
US7060864B2 (en) * 2003-09-30 2006-06-13 Saudi Basic Industries Corporation Toluene methylation process
US7060644B2 (en) 2004-01-08 2006-06-13 Saudi Basic Industries Corporation Aromatic alkylation catalyst and method
US6943131B1 (en) * 2004-03-02 2005-09-13 Saudi Basic Industries Corporation Selective zeolite catalyst modification
US7285511B2 (en) * 2004-04-23 2007-10-23 Saudi Basic Industries Corporation Method of modifying zeolite catalyst
US7399727B2 (en) * 2004-04-23 2008-07-15 Saudi Basic Industries Corporation Zeolite catalyst and method
WO2005123251A1 (en) * 2004-06-09 2005-12-29 Saudi Basic Industries Corporation Fluoride-modified zeolite catalyst and method
US7304194B2 (en) * 2005-05-05 2007-12-04 Saudi Basic Industries Corporation Hydrothermal treatment of phosphorus-modified zeolite catalysts
US7368410B2 (en) * 2005-08-03 2008-05-06 Saudi Basic Industries Corporation Zeolite catalyst and method of preparing and use of zeolite catalyst
US8993468B2 (en) * 2007-05-24 2015-03-31 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—Ge zeolites
US9233884B2 (en) * 2007-05-24 2016-01-12 Saudi Basic Industries Corporation Catalyst for conversion of hydrocarbons, process of making and process of using thereof—bimetallic deposition
AU2008335195B2 (en) * 2007-12-12 2011-03-10 Shell Internationale Research Maatschappij B.V. Process for the conversion of ethane or mixed lower alkanes to aromatic hydrocarbons
AU2009215686B2 (en) * 2008-02-18 2012-03-15 Shell Internationale Research Maatschappij B.V. Process for the conversion of ethane to aromatic hydrocarbons
MY156207A (en) 2008-02-18 2016-01-29 Shell Int Research Process for the conversion of ethane to aromatic hydrocarbons
CN101945702B (en) 2008-02-20 2014-05-28 国际壳牌研究有限公司 Process for the conversion of ethane to aromatic hydrocarbons
US8846559B2 (en) * 2008-11-03 2014-09-30 Saudi Basic Industries Corporation Stable shape-selective catalyst for aromatic alkylation and methods of using and preparing
US8062987B2 (en) * 2009-10-05 2011-11-22 Saudi Basic Industries Corporation Phosphorus-containing zeolite catalysts and their method of preparation
AU2010313369B2 (en) 2009-11-02 2014-02-13 Shell Internationale Research Maatschappij B.V. Process for the conversion of mixed lower alkanes to aromatic hydrocarbons
SG11201401524TA (en) 2011-10-17 2014-05-29 Exxonmobil Res & Eng Co Process for producing phosphorus modified zeolite catalysts
US9278342B2 (en) 2012-07-02 2016-03-08 Saudi Basic Industries Corporation Method of modifying a phosphorus-containing zeolite catalyst
EP3071326B1 (en) 2013-11-22 2022-08-24 Saudi Basic Industries Corporation Catalyst with improved activity/selectivity for light naphtha aromatization
WO2015094696A1 (en) 2013-12-20 2015-06-25 Exxonmobil Chemical Patents Inc. Process for converting oxygenates to aromatic hydrocarbons
CA2943612A1 (en) 2013-12-20 2015-06-25 Exxonmobil Research And Engineering Company Method for oxygenate conversion
WO2016105888A1 (en) * 2014-12-22 2016-06-30 Exxonmobil Research And Engineering Company Conversion of oxygenates to aromatics
WO2017052854A1 (en) * 2015-09-25 2017-03-30 Exxonmobil Upstream Research Company Aromatization of non-aromatic hydrocarbon
CN105749958A (en) * 2016-02-04 2016-07-13 中国海洋石油总公司 Movable bed methanol to olefin arene spherical catalyst and preparation method of movable bed methanol to olefin arene spherical catalyst

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3911041A (en) * 1974-09-23 1975-10-07 Mobil Oil Corp Conversion of methanol and dimethyl ether
FR2285176A1 (en) * 1974-09-23 1976-04-16 Mobil Oil CATALYST CONTAINING PHOSPHORUS, ITS METHOD OF PREPARATION AND ITS USE
US4088706A (en) * 1976-02-05 1978-05-09 Mobil Oil Corporation Methanol conversion to para-xylene using a zeolite catalyst containing an oxide of boron, magnesium, phosphorus, or mixtures
US4137195A (en) * 1976-10-21 1979-01-30 Mobil Oil Corporation Catalyst for disproportionation of toluene
US4356338A (en) * 1979-07-27 1982-10-26 Mobil Oil Corporation Extending catalyst life by treating with phosphorus and/or steam
US4379761A (en) * 1981-01-08 1983-04-12 Mobil Oil Corporation Catalyst and process for making said catalyst
US4590323A (en) * 1985-06-12 1986-05-20 Mobil Oil Corporation Conversion of paraffins to aromatics over zeolites modified with oxides of group IIIA, IVA and VA elements

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3760024A (en) * 1971-06-16 1973-09-18 Mobil Oil Corp Preparation of aromatics
US3899544A (en) * 1974-03-28 1975-08-12 Mobil Oil Corp Conversion of alcohols and ethers to hydrocarbons
US3945913A (en) * 1974-08-26 1976-03-23 Mobil Oil Corporation Manufacture of lower aromatic compounds
US3972832A (en) * 1974-09-23 1976-08-03 Mobil Oil Corporation Phosphorus-containing zeolite catalyst
US4044065A (en) * 1974-09-23 1977-08-23 Mobile Oil Corporation Conversion utilizing a phosphorus-containing zeolite catalyst
US4016219A (en) * 1975-08-22 1977-04-05 Mobil Oil Corporation Disproportionation of toluene
GB1561590A (en) * 1976-12-20 1980-02-27 British Petroleum Co Zeolites containing gallium
GB1537780A (en) * 1976-12-20 1979-01-04 British Petroleum Co Dehydrocyclodimerising c3-c8 hydrocarbons
US4078990A (en) * 1977-03-04 1978-03-14 Mobil Oil Corporation Manufacture of lower aromatic compounds
US4152364A (en) * 1978-01-19 1979-05-01 Mobil Oil Corporation Selective production of para-xylene
US4182923A (en) * 1978-02-24 1980-01-08 Mobil Oil Corporation Disproportionation of toluene
US4197214A (en) * 1978-10-10 1980-04-08 Mobil Oil Corporation Crystalline zeolite catalysts of chemical reactions
US4384155A (en) * 1980-04-11 1983-05-17 Mobil Oil Corporation Shape selective reactions with cadmium-modified zeolite catalysts
US4329533A (en) * 1980-05-05 1982-05-11 Mobil Oil Corporation Shape selective reactions with zeolite catalysts modified with group IA metals
US4341622A (en) * 1980-12-04 1982-07-27 Mobil Oil Corporation Manufacture of benzene, toluene and xylene
US4350835A (en) * 1981-02-19 1982-09-21 Mobil Oil Corporation Process for converting ethane to aromatics over gallium-activated zeolite
US4458097A (en) * 1982-04-30 1984-07-03 Union Carbide Corporation Conversion of certain hydrocarbons using divalent-copper-containing ZSM-5 type catalyst
US4469909A (en) * 1982-06-18 1984-09-04 Mobil Oil Corporation Heavy aromatics process
US4590321A (en) * 1985-06-12 1986-05-20 Mobil Oil Corporation Aromatization reactions with zeolites containing phosphorus oxide

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3911041A (en) * 1974-09-23 1975-10-07 Mobil Oil Corp Conversion of methanol and dimethyl ether
FR2285176A1 (en) * 1974-09-23 1976-04-16 Mobil Oil CATALYST CONTAINING PHOSPHORUS, ITS METHOD OF PREPARATION AND ITS USE
US4088706A (en) * 1976-02-05 1978-05-09 Mobil Oil Corporation Methanol conversion to para-xylene using a zeolite catalyst containing an oxide of boron, magnesium, phosphorus, or mixtures
US4137195A (en) * 1976-10-21 1979-01-30 Mobil Oil Corporation Catalyst for disproportionation of toluene
US4356338A (en) * 1979-07-27 1982-10-26 Mobil Oil Corporation Extending catalyst life by treating with phosphorus and/or steam
US4379761A (en) * 1981-01-08 1983-04-12 Mobil Oil Corporation Catalyst and process for making said catalyst
US4590323A (en) * 1985-06-12 1986-05-20 Mobil Oil Corporation Conversion of paraffins to aromatics over zeolites modified with oxides of group IIIA, IVA and VA elements

Also Published As

Publication number Publication date
CA1262363A (en) 1989-10-17
AU5527386A (en) 1987-01-15
EP0205300B1 (en) 1991-07-03
AU595508B2 (en) 1990-04-05
US4665251A (en) 1987-05-12
EP0205300A2 (en) 1986-12-17
DE3680034D1 (en) 1991-08-08

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