EP0064295A1 - Method of improving the corrosion resistance of chemical conversion coated aluminum - Google Patents
Method of improving the corrosion resistance of chemical conversion coated aluminum Download PDFInfo
- Publication number
- EP0064295A1 EP0064295A1 EP19820103813 EP82103813A EP0064295A1 EP 0064295 A1 EP0064295 A1 EP 0064295A1 EP 19820103813 EP19820103813 EP 19820103813 EP 82103813 A EP82103813 A EP 82103813A EP 0064295 A1 EP0064295 A1 EP 0064295A1
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- EP
- European Patent Office
- Prior art keywords
- aluminum
- solution
- deoxidizer
- deoxidizing
- chromated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/78—Pretreatment of the material to be coated
Definitions
- This invention relates in general to improving the corrosion resistance of chemical conversion coated aluminum, and more specifically to a method for treating deoxidized aluminum prior to conversion coating which improves the ability of the aluminum to pass rigid corrosion resistant requirements.
- Conversion coated aluminum has been used by airframe and other manufacturers, including the military, to improve aluminum's corrosion resistance and paint adhesion properties.
- the aluminum is deoxidized using a chromated deoxidizer, and then coated in the conversion process with a coating resistant to corrosion.
- a stringent corrosion resistant test must be met as outlined in Military Specifications MIL-C-5541 and MIL-C-81706. These tests require subjecting the finished aluminum product to a salt spray for a lengthy period of time, such as 164 to 328 hours, respectively.
- This composition contains sodium nitrite; however, it is not obvious from Thornhill that this compositon would have good results when combined with chemical conversion coating.
- Shick in U .S. Patent No. 3,433,577, uses a composition containing sodium nitrite for protecting metal parts from corrosion. The purpose of this composition is for vapor phase corrosion inhibitors during storage, and does not anticipate or is applicable to the present invention.
- U . S . Patent No. 3,445,400 issued to Everhart contains a chromated formulation which the present invention seeks to avoid.
- Bland et al, in U.S. Patent No. 3,510,430 discloses a ferric sulfate non-chromated deoxidizer which would not satisfactorily meet salt spray tests.
- U.S. Patent No. 3,802,973 teaches an oxidizing agent to uniformly etch aluminum in an alkaline solution for the purpose of hiding surface defects, and does not directly relate to the present invention.
- Harris et al in U.S. Published Patent Application 265,369, shows a metal exposed continuously to a rust inhibitor as others in the search have shown, and again does not anticipate the present invention.
- the present invention discloses a method for treating aluminum metal to enhance corrosion resistance, and especially to meet salt spray test requirements imposed by the military.
- the method includes deoxidizing the aluminum with deoxidizing means, rinsing the aluminum and exposing the aluminum to a sodium nitrite solution with a pH lower than 5.
- the aluminum is then rinsed and coated with a chemical conversion coating such as "Alodine 1200S" and dried by suitable drying means such as warm air.
- suitable drying means such as warm air.
- the present invention teaches that the sodium nitrite treatment is especially effective if that solution is maintained at a pH between 3 and 4. Further, it is preferable to use a deoxidizing solution of 25% to 50% nitric acid. Drying temperatures in the range of 110°F and 130°F give the best results.
- the object of the present invention to provide a method for treating aluminum which uses a non-chromated deoxidizer and a chemical conversion coating with the final product able to withstand the salt spray requirements of the military specification.
- Another object of the present invention is to provide a method for treating aluminum which eliminates an effluent stream containing chromate.
- a further object of the present invention is to allow aluminum to be conversion coated without the use of a chromated deoxidizer.
- Vapor degreasing of the aluminum metal can be performed by standard techniques known to one skilled in the art. Similarly, alkaline cleaning and rinsing of the aluminum are steps commonly known to those skilled in the aYt and insure a clean aluminum surface prior to deoxidization.
- the deoxidization step which is the next step is preferably produced with a non-chromated deoxidizer.
- a chromated deoxidizer is undesirable from a pollution standpoint since chrome or chrome ions are toxic, and the effluent stream may be released to open bodies of water.
- the invention can be practiced, however, using a chromated deoxidizer if desired and the resulting product will readily meet the salt spray requirements of the military.
- a non-chromated deoxidizer that can be used for beneficial results by way of example, a nitric acid solution containing the fluoride ion.
- the fluoride ion would be present in the deoxidizing solution in an adequate and normally practical amount to obtain an etch rate of the aluminum surface of up to approximately 0.6 mils/side/hr.
- the fluoride ion could be obtained from hydrofluoric acid or any suitable salt containing the ion.
- Nitric acid can typically be used in a concentration of 25% to 50% HN0 3 to inhibit the redeposit or copper, commonly called "smut.”
- the fluoride ion is preferred since it is one of the best etching agents of unfinished aluminum metal, and can etch uniformly without pitting.
- nitric acid is used to remove undissolved silicon from the aluminum surface and prevent the formation of smut.
- Other non-chromated deoxidizers may be used in the practice of the invention without losing the beneficial effects of treating aluminum in the manner taught by the inventor.
- the aluminum may be immersed in the deoxidizer for approximately 5 minutes to 60 minutes or greater, depending on the difficulty of scale removal.
- the nitric acid deoxidizer performs best when a freshly prepared solution is buffered with some dissolved metallic aluminum.
- the aluminum is then rinsed with cold water, and a supplemental treatment, differing from the prior art, is performed to allow the final conversion coated product to pass salt spray requirements.
- the deoxidized aluminum is rinsed with a sodium nitrite solution.
- the aluminum may either be immersed in the solution or sprayed with the solution.
- the sodium nitrite solution is maintained at a pH less than 5 and preferably at pH3 or below.
- Nitric acid can supply the necessary hydrogen ion concentration.
- the concentration of sodium nitrite is not critical, assuming the pH is less than 5, and beneficial results can be obtained with a sodium nitrite solution of 1%.
- a water rinse of the aluminum is performed prior to chemical conversion coating. It should also be noted that potassium nitrite may be used in place of sodium nitrite with beneficial results.
- the chemical conversion coating can be done with any of the coating solutions known to the prior art. It has been found that Alodine 1200S, manufactured by Amchem Products, Inc., Ambler, PA, works satisfactorily.
- the aluminum is dried by warm air.
- the drying temperature will be in the range of 110°F to 130°F with an optimum at 120 0 F.
- Bare aluminum alloy specimens (10" by 3") were used in this and all other examples. Table 1 shows the results of this series of samples which illustrates the effect of sodium nitrite treatment on the salt spray test results.
- a partially depleted chromate-type deoxidizer was used called Am Chem 6-17, a product of Amchem Products, Inc., Ambler, PA.
- each specimen was first cleaned using an alkaline cleaner called Turco 2623, a product of the Turco Products Division of Purex Corporation Ltd., W ilmington, California. The alkaline cleaning was conducted for 30 minutes at l40 o F. Deoxidation occurred in Amchem 6-17 with the etch rate adjusted to 0.25 mils/side/hr with hydrogen fluoride.
- the next processing step for the bottom four specimens on Table 1 was an immersion in the sodium nitrite solution for 30 minutes.
- the solution had a pH of 3 and a concentration of 3%.
- the top four specimens did not receive a sodium nitrite immersion.
- All specimens were then immersed in Alodine 1200S and dried for 30 minutes at a temperature of 110° - 130°F. It should be noted that all specimens in all examples were rinsed with tap water after each processing step.
- Table 1 shows that only the specimens which were immersed in the sodium nitrite solution passed the salt spray test, i.e. the top four specimens of Table 1 had one or more corrosion pits visible to the unaided eye, indicating failure, while the bottom four specimens had no visible corrosion pits, indicating passing results.
- Example 2 Bare alloy specimens similar to those used in Example 1 were used in Example 2. The main difference in the two examples was the use of a non-chromated ferrous ion-type deoxidizer instead of a chromated deoxidizer.
- the deoxidizer in this example was Isoprep 184, a product of Allied-Kelite Products Division, Los Angeles, California. It was used in a 25% concentration with an etch rate of 0.25 mils/side/hr maintained with hydrogen fluoride addition.
- the sodium nitrite solution was 2.3% sodium nitrite with a pH of 3.0. This example illustrates that the only specimens which passed the salt spray test (no pits visible to the unaided eye) were those immersed in the sodium nitrite solution.
- Example 3 is similar to Examples 1 and 2, differing only in the deoxidizer used.
- a nitric acid - fluoride ion type non-chromate deoxidizer was used.
- the specimens were processed in the same manner as Examples 1 and 2.
- the deoxidizer consisted of 40 % by volume of concentrated nitric acid (technical grade) with a sufficient fluoride ion concentration to produce an etch rate of 0.25 mils/side/hr.
- the sodium nitrite solution was of a 2.3% concentration with a pH of 3.3
- the results outlined in the table show that the specimens passing the salt spray test were those which were t immersed in sodium nitrite. The specimens which were not immersed in the sodium nitrite solution failed the test.
- Example 4 a nitric acid - fluoride ion type non-chromated deoxidizer was used as in Example 3. Instead of immersion in a sodium nitrite solution after this processing step, a potassium nitrite solution of 2.3% concentration with a 3.0 pH was used. The results show that the specimens which were not immersed in the potassium nitrite solution failed to pass the salt spray test. The specimens that were immersed in potassium nitrite, however, passed the salt spray test.
- Example 5 uses Isoprep 184, a ferrous ion-type non-chromated deoxidizer as did Example 2. Instead of sodium nitrite, potassium nitrite was used in the next processing step. The solution was of 2.3% concentration with a pH of 3.0. As seen in Table 5, the only specimens passed were those treated with potassium nitrite.
- Bare aluminum 2024-T3 panels were processed in a conversion coating line, using a chromated deoxidizer and a conversion coating solution of Alodine 1200S. Immersion time in the Alodine 1200S varied slightly between 21 ⁇ 2 and 3 minutes. All of the panels after drying were aged for 3 days prior to salt spray testing for 336 hours. Drying temperatures were varied from ambient temperature to 160° F . The results are summarized in Table 6. The panels dried at 120° F suffered no corrosion damage, and no detectable change was evident in color of the panels or surface finish. After the 336 hour salt spray test, the panels were resubjected to salt spray until failure. Three of the four panels dried at 120°F exceeded five weeks of salt spray when the tests were suspended.
- the panels dried at 140°F failed in one week, which is typical of the results obtained prior to discovering the critical temperature factor.
- the panels dried at 100°F had marginal resistance to corrosion, while those dried at 70°F-75°F failed the test in a random pattern, perhaps due to insufficient time necessary for conditioning the Alodine 120 0S coating at lower temperatures.
Abstract
Description
- This invention relates in general to improving the corrosion resistance of chemical conversion coated aluminum, and more specifically to a method for treating deoxidized aluminum prior to conversion coating which improves the ability of the aluminum to pass rigid corrosion resistant requirements.
- Conversion coated aluminum has been used by airframe and other manufacturers, including the military, to improve aluminum's corrosion resistance and paint adhesion properties. In the prior art, the aluminum is deoxidized using a chromated deoxidizer, and then coated in the conversion process with a coating resistant to corrosion. When coated aluminum is manufactured for use in military applications, a stringent corrosion resistant test must be met as outlined in Military Specifications MIL-C-5541 and MIL-C-81706. These tests require subjecting the finished aluminum product to a salt spray for a lengthy period of time, such as 164 to 328 hours, respectively.
- Prior to the present invention, it was extremely difficult to pass the salt spray requirement imposed by the military for aluminum hardware. Special conversion coatings were developed, and various deoxidizers used. In general, the aluminum was treated using a chromated deoxidizer to etch away the natural and heat-treat oxide so that the finished product has a uniform color and texture. A chemical conversion coating is applied to the aluminum. One typical coating is "Alodine 1200S" manufactured by the Amchem Products, Inc., Ambler, PA. This conversion coating consists of a corrosion resistant brown iridescent layer. This film has potentially good resistance to normal corrosion; however, in highly corrosive environments such as that required by the salt spray test, the film may succumb to corrosion and not meet military specifications. In general, the prior art relied upon chromated deoxidizers to meet the stringent corrosion requirement tests. Non-chromated deoxidizers were tested, but failed to meet the military specification requirements after being chemically conversion coated. Deoxidizers containing the chromate ion, although producing better results in salt spray test requirements, have a pollution problem due to the effluent stream. Heavy metals, such as chrome, are highly toxic to the environment, and are therefore undesirable for release into closed or open bodies of water. Previous to the present invention, a workable non-chromated treatment process prior to chemical conversion coating aluminum was lacking if salt spray requirements were to be consistently met.
-
- None of these patents singularly or in combination anticipate the present invention. Taking each of the above individually, U.S. Patent No. 2,351,465 issued to Wachter deals with the use of sodium nitrite as an inhibitor to corrosion inside steel pipelines carrying petroleum distillates. This invention, specifically, needed to protect the pipelines from distillates containing hydrocarbon oils; and not salt spray as the present invention. Ferguson, in U.S. Patent No. 2,671,717 teaches the use of sodium nitrite in brightening aluminum, not for corrosion resistance. Hulpert, in U.S. Patent No. 2,883,371 teaches a chromated deoxidizer which the present invention would eliminate as a pollution problem. A non-chromated aluminum deoxidizer is disclosed in U.S. Patent No. 3,140,203 issued to Grunwald; however, this patent does not teach the applicability and compatability of this deoxidizer with a conversion coating. U.S. Patent No. 3,275,562, issued to Smith, shows one formulation of a non-chromated aluminum de-smutter, and does not teach the method of the present invention. Hatch, in U.S. Patent No. 3,335,096, deals with a corrosion protective chemical in a closed system which protects the metal surface only while in contact with the surface, and does not anticipate the present invention. As in the previously cited patent, Thornhill (U.S. Patent No. 3,340,001) teaches a composition for protecting metal from corrosion which is constantly in contact with the metal. This composition contains sodium nitrite; however, it is not obvious from Thornhill that this compositon would have good results when combined with chemical conversion coating. Shick, in U.S. Patent No. 3,433,577, uses a composition containing sodium nitrite for protecting metal parts from corrosion. The purpose of this composition is for vapor phase corrosion inhibitors during storage, and does not anticipate or is applicable to the present invention. U.S. Patent No. 3,445,400 issued to Everhart contains a chromated formulation which the present invention seeks to avoid. Bland et al, in U.S. Patent No. 3,510,430 discloses a ferric sulfate non-chromated deoxidizer which would not satisfactorily meet salt spray tests. The nitrites in this formulation are used to prevent pitting during deoxidization which is different from the function in the present invention. U.S. Patent No. 3,802,973 teaches an oxidizing agent to uniformly etch aluminum in an alkaline solution for the purpose of hiding surface defects, and does not directly relate to the present invention. Harris et al, in U.S. Published Patent Application 265,369, shows a metal exposed continuously to a rust inhibitor as others in the search have shown, and again does not anticipate the present invention.
- The present invention discloses a method for treating aluminum metal to enhance corrosion resistance, and especially to meet salt spray test requirements imposed by the military. The method includes deoxidizing the aluminum with deoxidizing means, rinsing the aluminum and exposing the aluminum to a sodium nitrite solution with a pH lower than 5. The aluminum is then rinsed and coated with a chemical conversion coating such as "Alodine 1200S" and dried by suitable drying means such as warm air. The present invention teaches that the sodium nitrite treatment is especially effective if that solution is maintained at a pH between 3 and 4. Further, it is preferable to use a deoxidizing solution of 25% to 50% nitric acid. Drying temperatures in the range of 110°F and 130°F give the best results.
- It is, therefore, the object of the present invention to provide a method for treating aluminum which uses a non-chromated deoxidizer and a chemical conversion coating with the final product able to withstand the salt spray requirements of the military specification.
- Another object of the present invention is to provide a method for treating aluminum which eliminates an effluent stream containing chromate.
- A further object of the present invention is to allow aluminum to be conversion coated without the use of a chromated deoxidizer.
- These and other objects and advantages will become more apparent from the following detailed description of the invention, incuding tables and examples.
- The present invention may be practiced on the following sequence of operation:
- 1) vapor degreasing the aluminum;
- 2) alkaline cleaning the aluminum;
- 3) rinsing the aluminum with water;
- 4) deoxidizing the aluminum, preferably with a non-chromated deoxidizer;
- 5) rinsing the deoxidized aluminum with water;
- 6) exposing the aluminum to a sodium nitrite solution;
- 7) rinsing the aluminum with water;
- 8) chemical conversion coating the aluminum; and
- 9) drying the aluminum.
- Vapor degreasing of the aluminum metal can be performed by standard techniques known to one skilled in the art. Similarly, alkaline cleaning and rinsing of the aluminum are steps commonly known to those skilled in the aYt and insure a clean aluminum surface prior to deoxidization.
- The deoxidization step which is the next step is preferably produced with a non-chromated deoxidizer. A chromated deoxidizer is undesirable from a pollution standpoint since chrome or chrome ions are toxic, and the effluent stream may be released to open bodies of water. The invention can be practiced, however, using a chromated deoxidizer if desired and the resulting product will readily meet the salt spray requirements of the military. A non-chromated deoxidizer that can be used for beneficial results, by way of example, a nitric acid solution containing the fluoride ion. In the preferred embodiment of the invention, the fluoride ion would be present in the deoxidizing solution in an adequate and normally practical amount to obtain an etch rate of the aluminum surface of up to approximately 0.6 mils/side/hr. The fluoride ion could be obtained from hydrofluoric acid or any suitable salt containing the ion. Nitric acid can typically be used in a concentration of 25% to 50% HN03 to inhibit the redeposit or copper, commonly called "smut."
- The fluoride ion is preferred since it is one of the best etching agents of unfinished aluminum metal, and can etch uniformly without pitting. To supplement the etching action of the fluoride ion, nitric acid is used to remove undissolved silicon from the aluminum surface and prevent the formation of smut. Other non-chromated deoxidizers may be used in the practice of the invention without losing the beneficial effects of treating aluminum in the manner taught by the inventor. The aluminum may be immersed in the deoxidizer for approximately 5 minutes to 60 minutes or greater, depending on the difficulty of scale removal. The nitric acid deoxidizer performs best when a freshly prepared solution is buffered with some dissolved metallic aluminum.
- After deoxidization, the aluminum is then rinsed with cold water, and a supplemental treatment, differing from the prior art, is performed to allow the final conversion coated product to pass salt spray requirements. In this step, the deoxidized aluminum is rinsed with a sodium nitrite solution. The aluminum may either be immersed in the solution or sprayed with the solution. The sodium nitrite solution is maintained at a pH less than 5 and preferably at pH3 or below. Nitric acid can supply the necessary hydrogen ion concentration. The concentration of sodium nitrite is not critical, assuming the pH is less than 5, and beneficial results can be obtained with a sodium nitrite solution of 1%. After the sodium nitrite treatment, a water rinse of the aluminum is performed prior to chemical conversion coating. It should also be noted that potassium nitrite may be used in place of sodium nitrite with beneficial results.
- The chemical conversion coating can be done with any of the coating solutions known to the prior art. It has been found that Alodine 1200S, manufactured by Amchem Products, Inc., Ambler, PA, works satisfactorily.
- To coat the aluminum,. immersion in the coating solution is allowed to take place for a relatively short time such as up to five minutes.
- After conversion coating, the aluminum is dried by warm air. In the preferred embodiment of the invention, the drying temperature will be in the range of 110°F to 130°F with an optimum at 1200F. The present invention may be further understood by reference to the following examples and accompanying tables.
- Bare aluminum alloy specimens (10" by 3") were used in this and all other examples. Table 1 shows the results of this series of samples which illustrates the effect of sodium nitrite treatment on the salt spray test results. A partially depleted chromate-type deoxidizer was used called Am Chem 6-17, a product of Amchem Products, Inc., Ambler, PA. As in all examples, each specimen was first cleaned using an alkaline cleaner called Turco 2623, a product of the Turco Products Division of Purex Corporation Ltd., Wilmington, California. The alkaline cleaning was conducted for 30 minutes at l40oF. Deoxidation occurred in Amchem 6-17 with the etch rate adjusted to 0.25 mils/side/hr with hydrogen fluoride. The next processing step for the bottom four specimens on Table 1 was an immersion in the sodium nitrite solution for 30 minutes. The solution had a pH of 3 and a concentration of 3%. The top four specimens did not receive a sodium nitrite immersion. All specimens were then immersed in Alodine 1200S and dried for 30 minutes at a temperature of 110° - 130°F. It should be noted that all specimens in all examples were rinsed with tap water after each processing step. Table 1 shows that only the specimens which were immersed in the sodium nitrite solution passed the salt spray test, i.e. the top four specimens of Table 1 had one or more corrosion pits visible to the unaided eye, indicating failure, while the bottom four specimens had no visible corrosion pits, indicating passing results.
- In this example, as in all other examples, the tests were concluded after one week of salt spray immersion for visual examination and other evaluation tests.
- Bare alloy specimens similar to those used in Example 1 were used in Example 2. The main difference in the two examples was the use of a non-chromated ferrous ion-type deoxidizer instead of a chromated deoxidizer. The deoxidizer in this example was Isoprep 184, a product of Allied-Kelite Products Division, Los Angeles, California. It was used in a 25% concentration with an etch rate of 0.25 mils/side/hr maintained with hydrogen fluoride addition. The sodium nitrite solution was 2.3% sodium nitrite with a pH of 3.0. This example illustrates that the only specimens which passed the salt spray test (no pits visible to the unaided eye) were those immersed in the sodium nitrite solution.
- Example 3 is similar to Examples 1 and 2, differing only in the deoxidizer used. In Example 3, a nitric acid - fluoride ion type non-chromate deoxidizer was used. The specimens were processed in the same manner as Examples 1 and 2. The deoxidizer consisted of 40% by volume of concentrated nitric acid (technical grade) with a sufficient fluoride ion concentration to produce an etch rate of 0.25 mils/side/hr. The sodium nitrite solution was of a 2.3% concentration with a pH of 3.3 The results outlined in the table show that the specimens passing the salt spray test were those which were t immersed in sodium nitrite. The specimens which were not immersed in the sodium nitrite solution failed the test.
- In Example 4, a nitric acid - fluoride ion type non-chromated deoxidizer was used as in Example 3. Instead of immersion in a sodium nitrite solution after this processing step, a potassium nitrite solution of 2.3% concentration with a 3.0 pH was used. The results show that the specimens which were not immersed in the potassium nitrite solution failed to pass the salt spray test. The specimens that were immersed in potassium nitrite, however, passed the salt spray test.
- Example 5 uses Isoprep 184, a ferrous ion-type non-chromated deoxidizer as did Example 2. Instead of sodium nitrite, potassium nitrite was used in the next processing step. The solution was of 2.3% concentration with a pH of 3.0. As seen in Table 5, the only specimens passed were those treated with potassium nitrite.
- Bare aluminum 2024-T3 panels were processed in a conversion coating line, using a chromated deoxidizer and a conversion coating solution of Alodine 1200S. Immersion time in the Alodine 1200S varied slightly between 2½ and 3 minutes. All of the panels after drying were aged for 3 days prior to salt spray testing for 336 hours. Drying temperatures were varied from ambient temperature to 160°F. The results are summarized in Table 6. The panels dried at 120°F suffered no corrosion damage, and no detectable change was evident in color of the panels or surface finish. After the 336 hour salt spray test, the panels were resubjected to salt spray until failure. Three of the four panels dried at 120°F exceeded five weeks of salt spray when the tests were suspended. The panels dried at 140°F failed in one week, which is typical of the results obtained prior to discovering the critical temperature factor. The panels dried at 100°F had marginal resistance to corrosion, while those dried at 70°F-75°F failed the test in a random pattern, perhaps due to insufficient time necessary for conditioning the Alodine 1200S coating at lower temperatures.
- The invention may be embodied in other forms without departing from the spirit or essential characteristics thereof. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.
Claims (14)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US26037081A | 1981-05-04 | 1981-05-04 | |
US260370 | 1981-05-04 |
Publications (2)
Publication Number | Publication Date |
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EP0064295A1 true EP0064295A1 (en) | 1982-11-10 |
EP0064295B1 EP0064295B1 (en) | 1985-11-21 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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EP19820103813 Expired EP0064295B1 (en) | 1981-05-04 | 1982-05-04 | Method of improving the corrosion resistance of chemical conversion coated aluminum |
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EP (1) | EP0064295B1 (en) |
DE (1) | DE3267535D1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0156853A1 (en) * | 1983-09-16 | 1985-10-09 | H.H. Robertson Company | Method for providing environmentally stable aluminum surfaces for painting and adhesive bonding, and product produced |
EP0230903A2 (en) * | 1986-01-21 | 1987-08-05 | HENKEL CORPORATION (a Delaware corp.) | Process for cleaning aluminium containers |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3779818A (en) * | 1971-04-01 | 1973-12-18 | Bethlehem Steel Corp | Method for preventing the formation of rust on the surface of coiled steel strip and an inhibitor for accomplishing same |
US4098720A (en) * | 1973-10-25 | 1978-07-04 | Chemed Corporation | Corrosion inhibition |
US4108689A (en) * | 1973-06-09 | 1978-08-22 | Daimler-Benz Aktiengesellschaft | Process for improving the surfaces of roller bodies and balls |
DE3030815A1 (en) * | 1979-08-15 | 1981-03-26 | Fuji Photo Film Co., Ltd., Minami-Ashigara, Kanagawa | ELECTROLYTIC GRIT PROCESS |
-
1982
- 1982-05-04 DE DE8282103813T patent/DE3267535D1/en not_active Expired
- 1982-05-04 EP EP19820103813 patent/EP0064295B1/en not_active Expired
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3779818A (en) * | 1971-04-01 | 1973-12-18 | Bethlehem Steel Corp | Method for preventing the formation of rust on the surface of coiled steel strip and an inhibitor for accomplishing same |
US4108689A (en) * | 1973-06-09 | 1978-08-22 | Daimler-Benz Aktiengesellschaft | Process for improving the surfaces of roller bodies and balls |
US4098720A (en) * | 1973-10-25 | 1978-07-04 | Chemed Corporation | Corrosion inhibition |
DE3030815A1 (en) * | 1979-08-15 | 1981-03-26 | Fuji Photo Film Co., Ltd., Minami-Ashigara, Kanagawa | ELECTROLYTIC GRIT PROCESS |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0156853A1 (en) * | 1983-09-16 | 1985-10-09 | H.H. Robertson Company | Method for providing environmentally stable aluminum surfaces for painting and adhesive bonding, and product produced |
EP0156853A4 (en) * | 1983-09-16 | 1986-02-10 | Robertson Co H H | Method for providing environmentally stable aluminum surfaces for painting and adhesive bonding, and product produced. |
EP0230903A2 (en) * | 1986-01-21 | 1987-08-05 | HENKEL CORPORATION (a Delaware corp.) | Process for cleaning aluminium containers |
EP0230903A3 (en) * | 1986-01-21 | 1989-02-08 | Parker Chemical Company | Process for cleaning aluminium containers |
Also Published As
Publication number | Publication date |
---|---|
DE3267535D1 (en) | 1986-01-02 |
EP0064295B1 (en) | 1985-11-21 |
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