EP0034273A3 - Process for preparing electrically conductive polyaromatic substances and their use in electrotechnics and in the antistatic equipment of synthetics - Google Patents

Process for preparing electrically conductive polyaromatic substances and their use in electrotechnics and in the antistatic equipment of synthetics Download PDF

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Publication number
EP0034273A3
EP0034273A3 EP81100583A EP81100583A EP0034273A3 EP 0034273 A3 EP0034273 A3 EP 0034273A3 EP 81100583 A EP81100583 A EP 81100583A EP 81100583 A EP81100583 A EP 81100583A EP 0034273 A3 EP0034273 A3 EP 0034273A3
Authority
EP
European Patent Office
Prior art keywords
polyaromatics
electrotechnics
synthetics
electrically conductive
antistatic equipment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP81100583A
Other languages
German (de)
French (fr)
Other versions
EP0034273A2 (en
Inventor
Herbert Dr. Naarmann
Klaus Dr. Penzien
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of EP0034273A2 publication Critical patent/EP0034273A2/en
Publication of EP0034273A3 publication Critical patent/EP0034273A3/en
Withdrawn legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/06Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances
    • H01B1/12Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of other non-metallic substances organic substances
    • H01B1/124Intrinsically conductive polymers
    • H01B1/128Intrinsically conductive polymers comprising six-membered aromatic rings in the main chain, e.g. polyanilines, polyphenylenes

Abstract

Die Erfindung betrifft ein Verfahren zur Herstellung leit­ fähigen Polyaromaten mit elektrischen Leitfähigkeitswerten größer als 10⁻²S/cm, wobei man Polyaromaten unter Aus­ chluß von Wasserfeuchtigkeit und von Sauerstoff 0,5 bis 5 Gew.% an Natrium, Kalium, Rubidium, Cäsium oder deren Amiden, bevorzugt in Hilfsflüssigkeiten, wie Tetrahydrofuran, Dimethoxyglykol, Anthazen, Naphthalin oder 2-Methylstyrol zugesetzt werden. Die erhaltenen leitfähigen Polyaromaten können zur Herstellung von Sonnenzellen, zur Umwandlung und Fixierung von Strahlung, zur Herstellung elektrischer und magnetischer Schalter und zur antistatischen Ausrüstung von Kunststoffen verwendet werden. The invention relates to a method for producing conductive capable polyaromatics with electrical conductivity values greater than 10⁻²S / cm, with polyaromatics under Aus Conclusion of water moisture and oxygen 0.5 to 5 % By weight of sodium, potassium, rubidium, cesium or their Amides, preferably in auxiliary liquids, such as tetrahydrofuran, Dimethoxyglycol, anthazen, naphthalene or 2-methylstyrene be added. The conductive polyaromatics obtained can be used to manufacture solar cells, for conversion and fixation of radiation, for the production of electrical and magnetic switch and for the antistatic equipment of Plastics are used.

EP81100583A 1980-02-13 1981-01-28 Process for preparing electrically conductive polyaromatic substances and their use in electrotechnics and in the antistatic equipment of synthetics Withdrawn EP0034273A3 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE3005300 1980-02-13
DE19803005300 DE3005300A1 (en) 1980-02-13 1980-02-13 METHOD FOR THE PRODUCTION OF ELECTRICALLY CONDUCTIVE POLYAROMATS AND THEIR USE IN ELECTROTECHNICS AND FOR THE ANTISTATIC EQUIPMENT OF PLASTICS

Publications (2)

Publication Number Publication Date
EP0034273A2 EP0034273A2 (en) 1981-08-26
EP0034273A3 true EP0034273A3 (en) 1981-11-18

Family

ID=6094468

Family Applications (1)

Application Number Title Priority Date Filing Date
EP81100583A Withdrawn EP0034273A3 (en) 1980-02-13 1981-01-28 Process for preparing electrically conductive polyaromatic substances and their use in electrotechnics and in the antistatic equipment of synthetics

Country Status (2)

Country Link
EP (1) EP0034273A3 (en)
DE (1) DE3005300A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1178529B (en) * 1963-04-11 1964-09-24 Basf Ag Use of organic polycondensation products as electrical, especially light-electrical, semiconductor bodies
EP0016305A1 (en) * 1979-03-20 1980-10-01 Allied Corporation Electrically conducting compositions derived from poly(phenylene), and shaped article comprising such a composition
EP0023595A1 (en) * 1979-07-20 1981-02-11 BASF Aktiengesellschaft Process for preparing electrically conductive polyphenylenes and their use in electrical engineering and in rendering plastics antistatic

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1178529B (en) * 1963-04-11 1964-09-24 Basf Ag Use of organic polycondensation products as electrical, especially light-electrical, semiconductor bodies
EP0016305A1 (en) * 1979-03-20 1980-10-01 Allied Corporation Electrically conducting compositions derived from poly(phenylene), and shaped article comprising such a composition
EP0023595A1 (en) * 1979-07-20 1981-02-11 BASF Aktiengesellschaft Process for preparing electrically conductive polyphenylenes and their use in electrical engineering and in rendering plastics antistatic

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JOURNAL CHEMICAL PHYSICS, Band 71, Nr. 3, 1. August 1979 (US) D.M. IVORY et al.: "Highly conducting charge-transfer complexes of poly (p-phenylene)", Seiten 1506 und 1507 *

Also Published As

Publication number Publication date
DE3005300A1 (en) 1981-08-20
EP0034273A2 (en) 1981-08-26

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PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

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Effective date: 19811022

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18W Application withdrawn

Withdrawal date: 19830728

RIN1 Information on inventor provided before grant (corrected)

Inventor name: PENZIEN, KLAUS, DR.

Inventor name: NAARMANN, HERBERT, DR.