EP0020275A1 - Process for improving the recovery of clean coal from flotation circuits - Google Patents
Process for improving the recovery of clean coal from flotation circuits Download PDFInfo
- Publication number
- EP0020275A1 EP0020275A1 EP80400775A EP80400775A EP0020275A1 EP 0020275 A1 EP0020275 A1 EP 0020275A1 EP 80400775 A EP80400775 A EP 80400775A EP 80400775 A EP80400775 A EP 80400775A EP 0020275 A1 EP0020275 A1 EP 0020275A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- coal
- flotation
- improving
- recovery
- clean coal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/016—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L9/00—Treating solid fuels to improve their combustion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; specified applications
- B03D2203/02—Ores
- B03D2203/04—Non-sulfide ores
- B03D2203/08—Coal ores, fly ash or soot
Definitions
- Flotation processes have been used for some time in the coal industry to recover coal fines from previously discarded aqueous streams generated by processing raw coal.
- the flotation feed consists of fine coal and clay which results from prior coarse separation steps such as baths, jigs, dewatering screens, sieve bends and cyclones.
- the feed is normally 28 x 0 mesh and contains 4 to 12 percent solids.
- the flotation circuit consists of four to eight cells in a single bank with the number of banks proportional to the total tonnage to be processed.
- the concentrate produced in the flotation cells goes to a vacuum filter where it is concentrated to approximately 75 to 80 percent solids.
- the tailings from the flotation process are discharged to a waste pond or a refuse vacuum filter.
- the very fine clay that is in the circuit often becomes entrapped in and/or adsorbed on the coal being floated and increases the amount of ash in the final product.
- the polymer may be added to the feed to the flotation circuit or to the individual cells by conventional feeding means and it is believed that it functions by flocculating the fine coal fraction.
- the polymer may be used in dosages of between 0.025 and 1 pound per ton, preferably at least 0.05 pounds per ton, based on the weight of the dry flotation feed.
- Suitable polymers which may be used in accordance with the teachings of this invention are water soluble, partially hydrolyzed polyacrylamides having a degree of hydrolysis of from 1 percent to 50 percent and a molecular weight of at least 50,000, and preferably at least 1,000,000.
Abstract
Adding an effective amount of a water soluble, partially hydrolyzed polyacrylamide to the coal being processed to decrease the amount of the clay being floated and removed from the cells with the fine coal.
Description
- Flotation processes have been used for some time in the coal industry to recover coal fines from previously discarded aqueous streams generated by processing raw coal. Generally, the flotation feed consists of fine coal and clay which results from prior coarse separation steps such as baths, jigs, dewatering screens, sieve bends and cyclones. The feed is normally 28 x 0 mesh and contains 4 to 12 percent solids.
- The flotation circuit consists of four to eight cells in a single bank with the number of banks proportional to the total tonnage to be processed. The concentrate produced in the flotation cells goes to a vacuum filter where it is concentrated to approximately 75 to 80 percent solids. The tailings from the flotation process are discharged to a waste pond or a refuse vacuum filter. During the flotation process, the very fine clay that is in the circuit often becomes entrapped in and/or adsorbed on the coal being floated and increases the amount of ash in the final product.
- Accordingly, it is an object of this invention to improve the operation of the coal flotation circuit by improving the overall yield of coal.
- It is another object of this invention to improve the operation of the coal flotation circuit by improving the overall yield of coal.
- It is another object of this invention to improve the operation of the coal flotation circuit by decreasing the ash content of the coal.
- These and other objects of this invention are accomplished by the addition of the partially hydrolyzed polyacrylamides to coal flotation circuits.
- The polymer may be added to the feed to the flotation circuit or to the individual cells by conventional feeding means and it is believed that it functions by flocculating the fine coal fraction. The polymer may be used in dosages of between 0.025 and 1 pound per ton, preferably at least 0.05 pounds per ton, based on the weight of the dry flotation feed.
- Suitable polymers which may be used in accordance with the teachings of this invention are water soluble, partially hydrolyzed polyacrylamides having a degree of hydrolysis of from 1 percent to 50 percent and a molecular weight of at least 50,000, and preferably at least 1,000,000.
- The following examples will illustrate this invention.
-
-
Claims (1)
1. A process for improving the recovery of clean coal from flotation circuits which comprises adding an effective amount of a water soluble, partially hydrolyzed polyacrylamide to the coal being processed to decrease the amount of the clay being floated and removed from the cells with the fine coal.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US4473679A | 1979-06-01 | 1979-06-01 | |
US44736 | 1979-06-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
EP0020275A1 true EP0020275A1 (en) | 1980-12-10 |
Family
ID=21934041
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP80400775A Withdrawn EP0020275A1 (en) | 1979-06-01 | 1980-05-30 | Process for improving the recovery of clean coal from flotation circuits |
Country Status (2)
Country | Link |
---|---|
EP (1) | EP0020275A1 (en) |
AU (1) | AU5856080A (en) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2502028A1 (en) * | 1981-03-23 | 1982-09-24 | American Cyanamid Co | METHOD FOR DECREASING THE FLOATABILITY OF SYLVINITE MINERALS IN A FLOTATION SYSTEM USING AS DEPRESSING A LOW MOLECULAR MASS COPOLYMER |
FR2525494A1 (en) * | 1982-04-26 | 1983-10-28 | American Cyanamid Co | SYLVITY CONCENTRATION PROCESS IN A SYLVINITE ORE FLOTATION SYSTEM |
US4533465A (en) * | 1982-04-26 | 1985-08-06 | American Cyanamid Company | Low molecular weight copolymers as depressants in sylvinite ore flotation |
EP0246105A2 (en) * | 1986-05-14 | 1987-11-19 | Fospur Limited | Recovering coal fines |
US4830740A (en) * | 1988-04-19 | 1989-05-16 | The Dow Chemical Company | Pyrite depressants useful in the separation of pyrite from coal |
US4857221A (en) * | 1986-05-14 | 1989-08-15 | Fospur Limited | Recovering coal fines |
US4859318A (en) * | 1987-10-16 | 1989-08-22 | Fospur Limited | Recovering coal fines |
US4956077A (en) * | 1987-11-17 | 1990-09-11 | Fospur Limited | Froth flotation of mineral fines |
US5402894A (en) * | 1993-10-18 | 1995-04-04 | Chemical Dewatering Technology, Inc. | Coal conditioning process |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3717574A (en) * | 1971-09-21 | 1973-02-20 | American Cyanamid Co | Flocculation of coal slimes |
SU362568A1 (en) * | 1970-05-12 | 1973-09-17 | FSH | LCHPN 1 "Ofei ^ R! And ITj ^ M.Posypayko, A.I. Olfert, A.M. Yakovenko, V.X. Kontorovich, and Cherepovets Order of Lenin Iron and Steel Works | |
US4141691A (en) * | 1977-12-12 | 1979-02-27 | Calgon Corporation | Use of water soluble polymers in coal flotation circuits |
BE873001A (en) * | 1977-12-23 | 1979-06-22 | American Cyanamid Co | COAL RECOVERY PROCESS BY FLOTATION |
-
1980
- 1980-05-20 AU AU58560/80A patent/AU5856080A/en not_active Abandoned
- 1980-05-30 EP EP80400775A patent/EP0020275A1/en not_active Withdrawn
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU362568A1 (en) * | 1970-05-12 | 1973-09-17 | FSH | LCHPN 1 "Ofei ^ R! And ITj ^ M.Posypayko, A.I. Olfert, A.M. Yakovenko, V.X. Kontorovich, and Cherepovets Order of Lenin Iron and Steel Works | |
US3717574A (en) * | 1971-09-21 | 1973-02-20 | American Cyanamid Co | Flocculation of coal slimes |
US4141691A (en) * | 1977-12-12 | 1979-02-27 | Calgon Corporation | Use of water soluble polymers in coal flotation circuits |
EP0002633A1 (en) * | 1977-12-12 | 1979-06-27 | Calgon Corporation | Use of water soluble polymers in coal flotation circuits and process for its preparation |
BE873001A (en) * | 1977-12-23 | 1979-06-22 | American Cyanamid Co | COAL RECOVERY PROCESS BY FLOTATION |
GB2010702A (en) * | 1977-12-23 | 1979-07-04 | American Cyanamid Co | Froth flotation of coal |
DE2853410A1 (en) * | 1977-12-23 | 1979-07-05 | American Cyanamid Co | PROCESS FOR COAL PROCESSING BY FLOTATION |
FR2412350A1 (en) * | 1977-12-23 | 1979-07-20 | American Cyanamid Co | COAL RECOVERY PROCESS BY FLOTATION |
Non-Patent Citations (2)
Title |
---|
CHEMICAL ABSTRACTS, Vol. 74, Nr. 26, 1971, page 142, Abstract 144265r. Columbus, Ohio, USA KAL'CHENKO, D.A. et al. "Improvement in the water slurry scheme of a coal concentrating mill". & Koks Khim. 1971 (4), 11-12. * Whole Abstract * * |
CHEMICAL ABSTRACTS, Vol. 83, Nr. 18, 1975, page 178, Abstract 150081e. Columbus, Ohio. USA BIMBEREKOV, A. "Mechanism of the reaction between 47% hydrolysed polyacrylamide and coal flotation residues". & Vopr. Obogashch. Polezn. Iskop. Sib. 1974, 71-80. * Whole Abstract * * |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2502028A1 (en) * | 1981-03-23 | 1982-09-24 | American Cyanamid Co | METHOD FOR DECREASING THE FLOATABILITY OF SYLVINITE MINERALS IN A FLOTATION SYSTEM USING AS DEPRESSING A LOW MOLECULAR MASS COPOLYMER |
FR2525494A1 (en) * | 1982-04-26 | 1983-10-28 | American Cyanamid Co | SYLVITY CONCENTRATION PROCESS IN A SYLVINITE ORE FLOTATION SYSTEM |
US4533465A (en) * | 1982-04-26 | 1985-08-06 | American Cyanamid Company | Low molecular weight copolymers as depressants in sylvinite ore flotation |
US4857221A (en) * | 1986-05-14 | 1989-08-15 | Fospur Limited | Recovering coal fines |
EP0246105A3 (en) * | 1986-05-14 | 1989-04-05 | Fospur Limited | Recovering coal fines |
EP0246105A2 (en) * | 1986-05-14 | 1987-11-19 | Fospur Limited | Recovering coal fines |
US4859318A (en) * | 1987-10-16 | 1989-08-22 | Fospur Limited | Recovering coal fines |
US4956077A (en) * | 1987-11-17 | 1990-09-11 | Fospur Limited | Froth flotation of mineral fines |
US5051199A (en) * | 1987-11-17 | 1991-09-24 | Fospur Limited | Froth flotation of mineral fines |
US4830740A (en) * | 1988-04-19 | 1989-05-16 | The Dow Chemical Company | Pyrite depressants useful in the separation of pyrite from coal |
EP0338778A2 (en) * | 1988-04-19 | 1989-10-25 | The Dow Chemical Company | Pyrite depressants useful in the separation of pyrite from coal |
WO1989010200A1 (en) * | 1988-04-19 | 1989-11-02 | The Dow Chemical Company | Pyrite depressants useful in the separation of pyrite from coal |
EP0338778A3 (en) * | 1988-04-19 | 1991-01-16 | The Dow Chemical Company | Pyrite depressants useful in the separation of pyrite from coal |
US5402894A (en) * | 1993-10-18 | 1995-04-04 | Chemical Dewatering Technology, Inc. | Coal conditioning process |
Also Published As
Publication number | Publication date |
---|---|
AU5856080A (en) | 1980-12-04 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE FR GB IT LU NL SE |
|
ITCL | It: translation for ep claims filed |
Representative=s name: SOCIETA' ITALIANA BREVETTI S.P.A. |
|
17P | Request for examination filed |
Effective date: 19810513 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: THE APPLICATION IS DEEMED TO BE WITHDRAWN |
|
18D | Application deemed to be withdrawn |
Effective date: 19820924 |
|
RIN1 | Information on inventor provided before grant (corrected) |
Inventor name: BELL, HUGH L. Inventor name: SNOW, GLEN F. |