DE69923340D1 - Ionische katalysatorzusammensetzungen auf träger - Google Patents
Ionische katalysatorzusammensetzungen auf trägerInfo
- Publication number
- DE69923340D1 DE69923340D1 DE69923340T DE69923340T DE69923340D1 DE 69923340 D1 DE69923340 D1 DE 69923340D1 DE 69923340 T DE69923340 T DE 69923340T DE 69923340 T DE69923340 T DE 69923340T DE 69923340 D1 DE69923340 D1 DE 69923340D1
- Authority
- DE
- Germany
- Prior art keywords
- support
- catalyst compositions
- ionic catalyst
- ionic
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US184389 | 1998-11-02 | ||
US09/184,389 US6143686A (en) | 1994-08-03 | 1998-11-02 | Supported ionic catalyst compositions |
PCT/US1999/025650 WO2000026266A1 (en) | 1998-11-02 | 1999-11-02 | Supported ionic catalyst compositions |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69923340D1 true DE69923340D1 (de) | 2005-02-24 |
DE69923340T2 DE69923340T2 (de) | 2006-04-06 |
Family
ID=22676688
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69923340T Expired - Lifetime DE69923340T2 (de) | 1998-11-02 | 1999-11-02 | Ionische katalysatorzusammensetzungen auf träger |
Country Status (5)
Country | Link |
---|---|
US (1) | US6143686A (de) |
EP (1) | EP1127082B1 (de) |
DE (1) | DE69923340T2 (de) |
ES (1) | ES2235536T3 (de) |
WO (1) | WO2000026266A1 (de) |
Families Citing this family (72)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6395847B2 (en) | 1999-11-19 | 2002-05-28 | Exxonmobil Chemical Patents Inc. | Supported organometallic catalysts and their use in olefin polymerization |
WO2002016681A1 (en) * | 2000-08-22 | 2002-02-28 | Exxonmobil Chemical Patents Inc. | Polypropylene fibers and fabrics |
US7098277B2 (en) * | 2000-08-22 | 2006-08-29 | Exxonmobil Chemical Patents Inc. | Polypropylene films |
US20030236365A1 (en) * | 2002-06-24 | 2003-12-25 | Fina Technology, Inc. | Polyolefin production with a high performance support for a metallocene catalyst system |
US8008412B2 (en) | 2002-09-20 | 2011-08-30 | Exxonmobil Chemical Patents Inc. | Polymer production at supersolution conditions |
US20040102311A1 (en) * | 2002-11-21 | 2004-05-27 | Abbas Razavi | Bridged metallocene catalyst component, method of making, polyolefin catalyst having C1, C2, or Cs symmetry, methods of making, methods of polymerizing, olefins and products made thereof |
US7205363B2 (en) * | 2003-06-11 | 2007-04-17 | Exxon Mobil Chemical Patents Inc. | Polymerization processes using antistatic agents |
US20050234198A1 (en) * | 2004-04-20 | 2005-10-20 | Fina Technology, Inc. | Heterophasic copolymer and metallocene catalyst system and method of producing the heterophasic copolymer using the metallocene catalyst system |
JP4988568B2 (ja) * | 2004-07-08 | 2012-08-01 | エクソンモービル・ケミカル・パテンツ・インク | オレフィン重合触媒系およびその使用方法 |
US20070202285A1 (en) | 2004-12-15 | 2007-08-30 | Fina Technology, Inc. | Articles having improved clarity, prepared from propylene-ethylene copolymers |
US7053163B1 (en) | 2005-02-22 | 2006-05-30 | Fina Technology, Inc. | Controlled comonomer distribution along a reactor for copolymer production |
US7514510B2 (en) | 2006-07-25 | 2009-04-07 | Fina Technology, Inc. | Fluorenyl catalyst compositions and olefin polymerization process |
US7470759B2 (en) * | 2006-07-31 | 2008-12-30 | Fina Technology, Inc. | Isotactic-atactic polypropylene and methods of making same |
US8075830B2 (en) | 2006-12-15 | 2011-12-13 | Fina Technology, Inc. | Polypropylene blown film |
US8242237B2 (en) | 2006-12-20 | 2012-08-14 | Exxonmobil Chemical Patents Inc. | Phase separator and monomer recycle for supercritical polymerization process |
JP2010529253A (ja) | 2007-06-04 | 2010-08-26 | エクソンモービル・ケミカル・パテンツ・インク | 非常に均一なプロピレンの溶液重合法 |
ATE509967T1 (de) | 2007-06-14 | 2011-06-15 | Borealis Tech Oy | Verfahren zur herstellung von propylen- copolymeren mit hilfe eines vorpolymerisierten katalysators |
US8318875B2 (en) | 2008-01-18 | 2012-11-27 | Exxonmobil Chemical Patents Inc. | Super-solution homogeneous propylene polymerization and polypropylenes made therefrom |
US8859084B2 (en) * | 2008-01-29 | 2014-10-14 | Fina Technology, Inc. | Modifiers for oriented polypropylene |
US8283428B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polymacromonomer and process for production thereof |
US8399725B2 (en) | 2008-06-20 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Functionalized high vinyl terminated propylene based oligomers |
US8372930B2 (en) | 2008-06-20 | 2013-02-12 | Exxonmobil Chemical Patents Inc. | High vinyl terminated propylene based oligomers |
US8283419B2 (en) | 2008-06-20 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Olefin functionalization by metathesis reaction |
US8802797B2 (en) | 2008-06-20 | 2014-08-12 | Exxonmobil Chemical Patents Inc. | Vinyl-terminated macromonomer oligomerization |
US8105971B2 (en) * | 2009-04-02 | 2012-01-31 | Lummus Technology Inc. | Process for making catalysts useful for the conversion of paraffins to olefins |
GB0918736D0 (en) | 2009-10-26 | 2009-12-09 | Isis Innovation | Catalysts |
EP2322568B1 (de) | 2009-11-13 | 2013-05-15 | Borealis AG | Verfahren zur Herstellung eines Olefin-Polymerisationskatalysatoren |
WO2011058088A1 (en) | 2009-11-13 | 2011-05-19 | Borealis Ag | Process for recovering a transition metal compound |
EP2499168B1 (de) | 2009-11-13 | 2017-05-10 | Borealis AG | Verfahren zur Wiederherstellung einer Übergangsmetallverbindung |
CN102666601B (zh) | 2009-11-13 | 2014-04-23 | 博瑞立斯有限公司 | 烯烃聚合方法 |
EP2330136B1 (de) | 2009-12-07 | 2013-08-28 | Borealis AG | Verfahren zur Herstellung eines nicht geträgerten, festen Metallocenkatalysatorsystems und dessen Verwendung bei der Polymerisation von Olefinen |
EP2341086A1 (de) † | 2009-12-30 | 2011-07-06 | Borealis AG | BOPP-Folie |
CN102971454B (zh) | 2010-06-15 | 2015-05-27 | 埃克森美孚化学专利公司 | 由聚合物共混物制造的非织造织物及其制造方法 |
PT2495037T (pt) | 2011-03-02 | 2020-09-15 | Borealis Ag | Montagem de reator de alto rendimento para a polimerização de olefinas |
EP2495038B1 (de) | 2011-03-02 | 2020-09-02 | Borealis AG | Ein Verfahren zur Produktion von Polymeren |
US8940839B2 (en) | 2011-03-25 | 2015-01-27 | Exxonmobil Chemical Patents Inc. | Diblock copolymers prepared by cross metathesis |
US8785562B2 (en) | 2011-03-25 | 2014-07-22 | Exxonmobil Chemical Patents Inc. | Amphiphilic block polymers prepared by alkene metathesis |
US8455597B2 (en) | 2011-03-25 | 2013-06-04 | Exxonmobil Chemical Patents Inc. | Catalysts and methods of use thereof to produce vinyl terminated polymers |
US8835563B2 (en) | 2011-03-25 | 2014-09-16 | Exxonmobil Chemical Patents Inc. | Block copolymers from silylated vinyl terminated macromers |
WO2012134719A2 (en) * | 2011-03-25 | 2012-10-04 | Exxonmobil Chemical Patents Inc. | Novel catalysts and methods of use thereof to produce vinyl terminated polymers |
US8841397B2 (en) | 2011-03-25 | 2014-09-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
US8426659B2 (en) | 2011-03-25 | 2013-04-23 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin polymers and methods to produce thereof |
US8669326B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Amine functionalized polyolefin and methods for preparation thereof |
US8669330B2 (en) | 2011-03-25 | 2014-03-11 | Exxonmobil Chemical Patents Inc. | Olefin triblock polymers via ring-opening metathesis polymerization |
US8623974B2 (en) | 2011-03-25 | 2014-01-07 | Exxonmobil Chemical Patents Inc. | Branched vinyl terminated polymers and methods for production thereof |
US8501894B2 (en) | 2011-03-25 | 2013-08-06 | Exxonmobil Chemical Patents Inc. | Hydrosilyation of vinyl macromers with metallocenes |
US8399724B2 (en) | 2011-03-25 | 2013-03-19 | Exxonmobil Chemical Patents Inc. | Vinyl terminated higher olefin copolymers and methods to produce thereof |
EP2535372B1 (de) | 2011-06-15 | 2016-09-14 | Borealis AG | In-situ Reaktormischung eines Ziegler-Natta-katalysierten, nucleierten Polypropylens und metallocen-katalysiertes Polypropylen |
US8604148B2 (en) | 2011-11-29 | 2013-12-10 | Exxonmobil Chemical Patents Inc. | Functionalization of vinyl terminated polymers by ring opening cross metathesis |
US8796376B2 (en) | 2012-03-26 | 2014-08-05 | Exxonmobil Chemical Patents Inc. | Functionalized polymers and oligomers |
ES2796856T3 (es) | 2012-08-29 | 2020-11-30 | Borealis Ag | Conjunto de reactor y procedimiento para la polimerización de olefinas |
US9322114B2 (en) | 2012-12-03 | 2016-04-26 | Exxonmobil Chemical Patents Inc. | Polypropylene fibers and fabrics |
EP2745927A1 (de) | 2012-12-21 | 2014-06-25 | Borealis AG | Fließbettreaktor mit interner Wanderbettreaktionseinheit |
EP2745926A1 (de) | 2012-12-21 | 2014-06-25 | Borealis AG | Gasphasenpolymerisation und Reaktoranordnung mit einem Fließbettreaktor und einem externen Wanderbettreaktor |
GB201407000D0 (en) | 2014-04-17 | 2014-06-04 | Isis Innovation | Catalysts |
ES2635519T3 (es) | 2014-11-21 | 2017-10-04 | Borealis Ag | Procedimiento para producir gránulos de copolímeros blandos |
ES2790649T3 (es) | 2014-12-08 | 2020-10-28 | Borealis Ag | Procedimiento para producir gránulos de copolímeros de propileno |
JP6695341B2 (ja) | 2015-01-06 | 2020-05-20 | エスシージー ケミカルズ カンパニー,リミテッド | SiO2層状複水酸化物微小球、およびエチレン重合用の触媒担体としてのその使用 |
US10773246B2 (en) | 2015-01-06 | 2020-09-15 | Scg Chemicals Co., Ltd. | SiO2-layered double hydroxide microspheres and methods of making them |
EP3124567A1 (de) | 2015-07-30 | 2017-02-01 | Borealis AG | Polypropylenbasierte heissschmelzklebstoffzusammensetzung |
EP3178853B1 (de) | 2015-12-07 | 2018-07-25 | Borealis AG | Verfahren zur polymerisierung von alpha-olefin-monomeren |
GB201608384D0 (en) | 2016-05-12 | 2016-06-29 | Scg Chemicals Co Ltd | Unsymmetrical metallocene catalysts and uses thereof |
EP3243622B1 (de) | 2016-05-13 | 2020-09-09 | Borealis AG | Verfahren zum hydraulischen transportieren von polyolefinpellets |
WO2018102080A1 (en) | 2016-12-02 | 2018-06-07 | Exxonmobil Chemical Patens Inc. | Olefin polymerization catalyst systems and methods for making the same |
US11292899B2 (en) * | 2017-06-30 | 2022-04-05 | Mitsui Chemicals, Inc. | Propylene-based polymer, method for producing the same, propylene-based resin composition and molded article |
US20210277290A1 (en) | 2018-08-06 | 2021-09-09 | Borealis Ag | Propylene random copolymer based hot melt adhesive composition |
EP3608364A1 (de) | 2018-08-06 | 2020-02-12 | Borealis AG | Multimodale propylen-random-copolymer-basierte zusammensetzung zur verwendung als schmelzklebstoffzusammensetzung |
WO2020056119A1 (en) | 2018-09-14 | 2020-03-19 | Fina Technology, Inc. | Polyethylene and controlled rheology polypropylene polymer blends and methods of use |
US20220177613A1 (en) | 2018-11-30 | 2022-06-09 | Borealis Ag | Washing process |
JP2022522649A (ja) | 2019-02-20 | 2022-04-20 | フイナ・テクノロジー・インコーポレーテツド | 低い反りを有するポリマー組成物 |
CN117222697A (zh) | 2021-04-26 | 2023-12-12 | 弗纳技术股份有限公司 | 单位点催化的聚合物薄片材 |
EP4144435A1 (de) | 2021-09-01 | 2023-03-08 | Borealis AG | Gasphasenpolymerisationsverfahren mit verbesserter gasrückführung |
Family Cites Families (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE1067215B (de) * | 1957-08-02 | 1959-10-15 | Farbenfabriken Bayer Aktiengesellschaft, Leverkusen-Bayerwerk | Verfahren zur Polymerisation von ungesättigten Verbindungen |
US5384299A (en) * | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5198401A (en) * | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
US5001205A (en) * | 1988-06-16 | 1991-03-19 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene α-olefin elastomer with a metallocene alumoxane catalyst |
US5763547A (en) * | 1992-10-02 | 1998-06-09 | The Dow Chemical Company | Supported catalyst complexes for olefin in polymerization |
US5057475A (en) * | 1989-09-13 | 1991-10-15 | Exxon Chemical Patents Inc. | Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization |
US5763549A (en) * | 1989-10-10 | 1998-06-09 | Fina Technology, Inc. | Cationic metallocene catalysts based on organoaluminum anions |
EP0427697B1 (de) * | 1989-10-10 | 1996-05-08 | Fina Technology, Inc. | Metallocenkatalysator mit Lewissäure und Alkylaluminium |
US5036034A (en) * | 1989-10-10 | 1991-07-30 | Fina Technology, Inc. | Catalyst for producing hemiisotactic polypropylene |
ES2071086T5 (es) * | 1989-10-30 | 2002-01-16 | Fina Technology | Preparacion de catalizadores metalocenicos para polimerizacion de olefina. |
US5387568A (en) * | 1989-10-30 | 1995-02-07 | Fina Technology, Inc. | Preparation of metallocene catalysts for polymerization of olefins |
ATE186918T1 (de) * | 1990-01-02 | 1999-12-15 | Exxon Chemical Patents Inc | Ionische metallocenkatalysatoren auf träger für olefinpolymerisation |
US5801113A (en) * | 1990-06-22 | 1998-09-01 | Exxon Chemical Patents, Inc. | Polymerization catalyst systems, their production and use |
US5206197A (en) * | 1991-03-04 | 1993-04-27 | The Dow Chemical Company | Catalyst composition for preparation of syndiotactic vinyl aromatic polymers |
CA2069995C (en) * | 1991-05-31 | 1996-04-09 | Mitsui Chemicals, Incorporated | Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization |
US5721185A (en) * | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
US5288677A (en) * | 1991-06-28 | 1994-02-22 | Exxon Chemical Patents Inc. | Immobilized Lewis acid catalysts |
EP0522581B1 (de) * | 1991-07-11 | 1997-10-15 | Idemitsu Kosan Company Limited | Verfahren zur Herstellung von Polymeren auf Olefinbasis und Olefin-Polymerisationskatalysatoren |
CA2124187C (en) * | 1991-11-25 | 2001-08-07 | Howard William Turner | Polyonic transition metal catalyst composition |
US5453410A (en) * | 1992-01-06 | 1995-09-26 | The Dow Chemical Company | Catalyst composition |
WO1993019103A1 (en) * | 1992-03-16 | 1993-09-30 | Exxon Chemical Patents Inc. | IONIC CATALYST FOR THE PRODUCTION OF POLY-α-OLEFINS OF CONTROLLED TACTICITY |
US5296433A (en) * | 1992-04-14 | 1994-03-22 | Minnesota Mining And Manufacturing Company | Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom |
WO1994000500A1 (en) * | 1992-06-26 | 1994-01-06 | Exxon Chemical Patents Inc. | Solution phase polymerization process utilizing metallocene catalyst with production of olefin polymers |
EP0702700B1 (de) * | 1992-08-05 | 2001-11-07 | ExxonMobil Chemical Patents Inc. | Ionische übergangsmetallkatalysatoreren auf träger für olefinpolymerisation |
JPH08502093A (ja) * | 1992-10-02 | 1996-03-05 | ザ・ダウ・ケミカル・カンパニー | オレフィン重合用の担持均一触媒錯体 |
TW298593B (de) * | 1993-02-12 | 1997-02-21 | Hoechst Ag | |
IT1264680B1 (it) * | 1993-07-07 | 1996-10-04 | Spherilene Srl | Catalizzatori supportati per la polimerizzazione delle olefine |
US5428120A (en) * | 1993-10-08 | 1995-06-27 | The Dow Chemical Company | Process for preparation of syndiotactic vinylidene aromatic polymers using chain transfer agent |
US5498582A (en) * | 1993-12-06 | 1996-03-12 | Mobil Oil Corporation | Supported metallocene catalysts for the production of polyolefins |
KR970701211A (ko) * | 1994-03-01 | 1997-03-17 | 더니스 피. 산티니 | 올레핀 중합 촉매(olefin polymerization catalysts) |
US5502017A (en) * | 1994-03-10 | 1996-03-26 | Northwestern University | Metallocene catalyst containing bulky organic group |
US5972823A (en) * | 1994-08-03 | 1999-10-26 | Exxon Chemical Patents Inc | Supported ionic catalyst composition |
US5643847A (en) * | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
US5500398A (en) * | 1994-11-09 | 1996-03-19 | Northwestern University | Homogeneous α-olefin dimerization catalysts |
JPH08134122A (ja) * | 1994-11-11 | 1996-05-28 | Idemitsu Kosan Co Ltd | 重合用触媒及びそれを用いたスチレン系重合体の製造方法 |
US5939347A (en) * | 1995-01-25 | 1999-08-17 | W.R. Grace & Co. -Conn. | Supported catalytic activator |
IT1272939B (it) * | 1995-02-01 | 1997-07-01 | Enichem Spa | Catalizzatore metallocenico supportato per la (co)polimerizzazione delle olefine |
EP0727443B1 (de) * | 1995-02-20 | 2001-01-17 | Tosoh Corporation | Katalysator für die Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymerisaten |
US5721183A (en) * | 1995-03-10 | 1998-02-24 | The Dow Chemical Company | Catalyst system comprising amine or phosphine adducts of tris(organyl)borane compounds |
ATE233790T1 (de) * | 1995-03-10 | 2003-03-15 | Dow Global Technologies Inc | Geträgerter katalysatorbestandteil, trägerkatalysator, herstellungsverfahren, polymerisationsverfahren, komplexverbindungen und ihre herstellung |
US6143682A (en) * | 1995-06-07 | 2000-11-07 | Exxon Chemical Patents Inc. | Bimetallocyclic transition metal catalyst systems |
JP3582181B2 (ja) * | 1995-10-04 | 2004-10-27 | 住友化学工業株式会社 | オレフィン重合触媒用担体、オレフィン重合触媒及びオレフィン重合体の製造方法 |
US6194341B1 (en) * | 1996-06-17 | 2001-02-27 | Exxon Chemical Patents Inc. | Mixed transition metal catalyst systems for olefin polymerization |
US5783512A (en) * | 1996-12-18 | 1998-07-21 | The Dow Chemical Company | Catalyst component dispersion comprising an ionic compound and solid addition polymerization catalysts containing the same |
US5851945A (en) * | 1997-02-07 | 1998-12-22 | Exxon Chemical Patents Inc. | Olefin polymerization catalyst compositions comprising group 5 transition metal compounds stabilized in their highest metal oxidation state |
-
1998
- 1998-11-02 US US09/184,389 patent/US6143686A/en not_active Expired - Lifetime
-
1999
- 1999-11-02 DE DE69923340T patent/DE69923340T2/de not_active Expired - Lifetime
- 1999-11-02 EP EP99956828A patent/EP1127082B1/de not_active Expired - Lifetime
- 1999-11-02 ES ES99956828T patent/ES2235536T3/es not_active Expired - Lifetime
- 1999-11-02 WO PCT/US1999/025650 patent/WO2000026266A1/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
EP1127082B1 (de) | 2005-01-19 |
WO2000026266A1 (en) | 2000-05-11 |
EP1127082A1 (de) | 2001-08-29 |
ES2235536T3 (es) | 2005-07-01 |
US6143686A (en) | 2000-11-07 |
DE69923340T2 (de) | 2006-04-06 |
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