DE69426659T2 - Funktionalisierung von Polymeren - Google Patents
Funktionalisierung von PolymerenInfo
- Publication number
- DE69426659T2 DE69426659T2 DE69426659T DE69426659T DE69426659T2 DE 69426659 T2 DE69426659 T2 DE 69426659T2 DE 69426659 T DE69426659 T DE 69426659T DE 69426659 T DE69426659 T DE 69426659T DE 69426659 T2 DE69426659 T2 DE 69426659T2
- Authority
- DE
- Germany
- Prior art keywords
- functionalization
- polymers
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
- C07C251/04—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C251/10—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of an unsaturated carbon skeleton
- C07C251/12—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of an unsaturated carbon skeleton being acyclic
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C229/00—Compounds containing amino and carboxyl groups bound to the same carbon skeleton
- C07C229/02—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton
- C07C229/30—Compounds containing amino and carboxyl groups bound to the same carbon skeleton having amino and carboxyl groups bound to acyclic carbon atoms of the same carbon skeleton the carbon skeleton being acyclic and unsaturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/091,489 US5525662A (en) | 1993-07-14 | 1993-07-14 | Functionalization of polymers via enamine of acetoacetate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE69426659D1 DE69426659D1 (de) | 2001-03-15 |
| DE69426659T2 true DE69426659T2 (de) | 2001-06-21 |
Family
ID=22228053
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE69426659T Expired - Lifetime DE69426659T2 (de) | 1993-07-14 | 1994-06-28 | Funktionalisierung von Polymeren |
Country Status (12)
| Country | Link |
|---|---|
| US (5) | US5525662A (de) |
| EP (1) | EP0634425B1 (de) |
| JP (1) | JP3787168B2 (de) |
| KR (2) | KR100365104B1 (de) |
| CN (2) | CN1051319C (de) |
| AU (1) | AU687398B2 (de) |
| BR (1) | BR9402671A (de) |
| CA (1) | CA2127570A1 (de) |
| DE (1) | DE69426659T2 (de) |
| IL (1) | IL110136A (de) |
| RU (1) | RU94026093A (de) |
| ZA (1) | ZA944717B (de) |
Families Citing this family (72)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5539073A (en) * | 1995-04-12 | 1996-07-23 | Eastman Chemical Company | Waterborne polymers having pendant allyl groups |
| US5783626A (en) * | 1995-04-12 | 1998-07-21 | Taylor; James Wayne | Waterborne polymers with pendant crosslinkable groups |
| US5772988A (en) * | 1996-05-10 | 1998-06-30 | Revlon Consumer Products Corporation | Nail enamel compositions from acetoacetoxy methacrylate copolymer |
| US6417267B1 (en) | 1996-05-28 | 2002-07-09 | Eastman Chemical Company | Adhesive compositions containing stable amino-containing polymer latex blends |
| US5998543A (en) * | 1996-05-28 | 1999-12-07 | Eastman Chemical Company | Stable amino-containing polymer latex blends |
| CA2255702C (en) | 1996-05-28 | 2003-06-17 | Eastman Chemical Company | Surfactant-containing acetoacetoxy-functional and enamine-functional polymers |
| US6028155A (en) * | 1997-05-21 | 2000-02-22 | Eastman Chemical Company | Surfactant-containing acetoacetoxy-functional and enamine-functional polymers |
| US5891950A (en) * | 1996-05-28 | 1999-04-06 | Eastman Chemical Company | Use of stable amino-functional latexes in water-based inks |
| US5962556A (en) * | 1996-10-22 | 1999-10-05 | Eastman Chemical Company | Functional latexes resistant to hydrolysis |
| US6512042B1 (en) | 1996-12-18 | 2003-01-28 | Rohm And Haas Company | Waterborne crosslinkable coating compositions |
| US5922790A (en) * | 1997-01-09 | 1999-07-13 | Eastman Chemical Company | Non-polymeric acetoacetates as adhesion promoting coalescing agents |
| US5913970A (en) * | 1997-01-16 | 1999-06-22 | Eastman Chemical Company | Stabilized non-polymeric acetoacetate esters that promote adhesion to metallic and oxidized substrates |
| GB2323599A (en) | 1997-03-18 | 1998-09-30 | Courtaulds Plc | Compositions curable by a Michael reaction |
| JP4242930B2 (ja) * | 1997-05-21 | 2009-03-25 | イーストマン ケミカル カンパニー | フィルム形成まで化学的及び物理的に安定な反応性ラテックスブレンドを調製する方法 |
| BR9811167A (pt) | 1997-08-12 | 2000-07-25 | Eastman Chem Co | Alquìdico modificado com acrìlico, látex a base de água, processo de preparação do mesmo, e, composição de revestimento |
| US6333378B1 (en) | 1997-08-12 | 2001-12-25 | Eastman Chemical Company | Acrylic modified waterborne alkyd or uralkyd dispersions |
| US6201048B1 (en) | 1997-09-18 | 2001-03-13 | Eastman Chemical Company | Stable waterborne polymer compositions containing poly(alkyleneimines) |
| US5990224A (en) * | 1997-09-18 | 1999-11-23 | Eastman Chemical Company | Stable low foam waterborne polymer compositions containing poly(alkyleneimines) |
| US6005035A (en) * | 1997-09-18 | 1999-12-21 | Eastman Chemical Company | Stable waterborne polymer compositions containing poly(alkylenimines) |
| US6649679B1 (en) | 1997-09-18 | 2003-11-18 | Eastman Chemical Company | Stable waterborne polymer compositions containing poly(alkylenimines) |
| US6348623B2 (en) | 1997-10-23 | 2002-02-19 | Eastman Chemical Company | Polymers of 3-butene esters, their preparation and use |
| US6121400A (en) * | 1997-10-23 | 2000-09-19 | Eastman Chemical Company | Polymers of 3-butene esters, their preparation and use |
| US6121399A (en) * | 1997-10-23 | 2000-09-19 | Eastman Chemical Company | Polymers of 3-butene esters, their preparation and use |
| US6277358B1 (en) | 1997-12-15 | 2001-08-21 | Revlon Consumer Products Corporation | Cosmetic compositions containing crosslinkable polymers |
| US6037390A (en) * | 1997-12-31 | 2000-03-14 | E. I. Du Pont De Nemours And Company | Smear resistant pigmented ink jet inks containing β-diketone or ureido dispersants |
| WO2000031196A1 (en) | 1998-11-20 | 2000-06-02 | The Sherwin-Williams Company | Curable compositions comprising acetoacetoxy and imine functionality |
| US6221976B1 (en) | 1999-01-25 | 2001-04-24 | The Dow Chemical Company | Polymers containing partially neutralized silanols |
| US6337106B1 (en) | 1999-06-01 | 2002-01-08 | Rohm And Haas | Method of producing a two-pack fast-setting waterborne paint composition and the paint composition therefrom |
| JP3816697B2 (ja) * | 1999-07-07 | 2006-08-30 | 大日精化工業株式会社 | 重合体が結合した機能剤、その製造方法、それらの使用方法及びそれらを使用した物品 |
| US6229007B1 (en) * | 1999-09-30 | 2001-05-08 | Basf Corporation | Amine functional cellulose ester compounds and methods of making the same |
| ATE308577T1 (de) * | 2000-04-12 | 2005-11-15 | Akzo Nobel Coatings Int Bv | Wässrige vernetzbare zusammensetzung aus zwei komponenten |
| GB0015245D0 (en) * | 2000-06-22 | 2000-08-16 | Avecia Ltd | Composition and process |
| US6521715B1 (en) | 2000-08-22 | 2003-02-18 | E. I. Du Pont De Nemours And Company | Graft copolymer pigment dispersants |
| US6524656B2 (en) * | 2001-02-23 | 2003-02-25 | Rohm And Haas Company | Coating method |
| US7396871B2 (en) * | 2002-01-14 | 2008-07-08 | Eastman Chemical Comapny | Rubber modified acrylic and/or vinyl hybrid resins |
| US6893722B2 (en) | 2002-04-29 | 2005-05-17 | Exxonmobil Oil Corporation | Cationic, amino-functional, adhesion-promoting polymer for curable inks and other plastic film coatings, and plastic film comprising such polymer |
| US7195818B2 (en) * | 2002-05-01 | 2007-03-27 | Exxonmobil Oil Corporation | Sealable multi-layer opaque film |
| US20040105994A1 (en) * | 2002-12-03 | 2004-06-03 | Pang-Chia Lu | Thermoplastic film structures with a low melting point outer layer |
| EP1431328A1 (de) * | 2002-12-19 | 2004-06-23 | Sika Technology AG | 3-(N-Silyalkyl)-amino-propenat-Gruppen enthaltendes Polymer und dessen Verwendung |
| EP1697470B1 (de) | 2003-12-06 | 2008-10-08 | FUJIFILM Imaging Colorants Limited | Verfahren zur herstellung modifizierter teilchenförmiger feststoffe und sie enthaltende tinten |
| US20050131176A1 (en) * | 2003-12-10 | 2005-06-16 | Cheng-Le Zhao | Process for production of polymer dispersions containing an acetoacetate moiety |
| GB0413630D0 (en) | 2004-06-18 | 2004-07-21 | Avecia Ltd | Process |
| US20060046005A1 (en) * | 2004-08-24 | 2006-03-02 | Mcgee Dennis E | Coating for polymeric labels |
| US7402624B2 (en) * | 2004-11-08 | 2008-07-22 | E.I. Du Pont De Nemours & Company | Graft copolymers with segmented arms and their preparation and use |
| AU2007201184B8 (en) * | 2006-04-11 | 2013-02-07 | Rohm And Haas Company | Dirt pickup resistant coating binder having high adhesion to substrates |
| TW200815556A (en) * | 2006-06-01 | 2008-04-01 | Akzo Nobel Coatings Int Bv | Adhesive system |
| US20080134893A1 (en) * | 2006-12-08 | 2008-06-12 | Thauming Kuo | Particulate filter media |
| US7855261B2 (en) | 2006-12-08 | 2010-12-21 | Eastman Chemical Company | Aldehyde removal |
| US20080135058A1 (en) * | 2006-12-08 | 2008-06-12 | Ted Calvin Germroth | Tobacco smoke filter and method for removal of aldehydes from tobacco smoke |
| US8906703B2 (en) | 2006-12-21 | 2014-12-09 | 3M Innovative Properties Company | Surface-bound fluorinated esters for amine capture |
| US8357540B2 (en) * | 2006-12-21 | 2013-01-22 | 3M Innovative Properties Company | Polymeric substrates with fluoroalkoxycarbonyl groups for amine capture |
| US20090163635A1 (en) * | 2007-12-19 | 2009-06-25 | Eastman Chemical Company | Aqueous dispersions of adhesion promoters |
| US20100081752A1 (en) * | 2008-09-26 | 2010-04-01 | E. I. Du Pont De Nemours And Company | Process for producing block copolymer pigment dispersants |
| EP2382241B1 (de) * | 2009-01-23 | 2016-11-23 | Bridgestone Corporation | Mit polycyan-verbindungen funktionalisierte polymere |
| US8962606B2 (en) | 2009-10-21 | 2015-02-24 | Bayer Intellectual Property Gmbh | Substituted benzosulphonamides |
| KR101797788B1 (ko) * | 2010-01-22 | 2017-11-15 | 가부시키가이샤 브리지스톤 | 보호된 아미노기를 함유하는 니트릴 화합물로 관능화된 중합체 |
| US9029451B2 (en) | 2010-12-15 | 2015-05-12 | Eastman Chemical Company | Waterborne coating compositions that include 2,2,4-trimethyl-3-oxopentanoate esters as reactive coalescents |
| US8809446B2 (en) | 2010-12-15 | 2014-08-19 | Eastman Chemical Company | Substituted 3-oxopentanoates and their uses in coating compositions |
| US8809447B2 (en) | 2010-12-15 | 2014-08-19 | Eastman Chemical Company | Acetoacetate-functional monomers and their uses in coating compositions |
| WO2012134695A1 (en) | 2011-03-29 | 2012-10-04 | Exxonmobil Oil Corporation | Film coatings based on polyalkylimine condensation polymers |
| US20140141262A1 (en) * | 2011-06-29 | 2014-05-22 | Sun Chemical Corporation | Vinyl alcohol polymers with silane side chains and compositions comprising the same |
| US20130084437A1 (en) | 2011-09-29 | 2013-04-04 | Dennis E. McGee | Film Coatings Based on Polyalkylimine Condensation Polymers |
| KR101821157B1 (ko) | 2011-10-11 | 2018-03-08 | 롬 앤드 하스 캄파니 | 수성 폴리머 분산물 |
| US20130224404A1 (en) * | 2012-02-28 | 2013-08-29 | Cray Valley Usa, Llc | Isocyanate-free insulated glass sealant and insulated glass units using the same |
| EP2748237A1 (de) | 2012-05-01 | 2014-07-02 | Jindal Films Americas, LLC | Epoxydierte polyalkylenimin-filmbeschichtungen |
| EP2945994B1 (de) | 2013-01-18 | 2018-07-11 | Basf Se | Beschichtungszusammensetzungen auf basis von acryldispersionen |
| KR101518504B1 (ko) | 2013-10-17 | 2015-05-11 | 제일모직주식회사 | 편광판용 접착제 조성물, 이를 포함하는 편광판용 접착 필름, 이를 포함하는 편광판 및 이를 포함하는 광학 표시 장치 |
| EP3286247A4 (de) | 2015-04-24 | 2018-12-26 | The Penn State Research Foundation | Klickbare wasserbasierte polymere und klickvernetzte wasserbasierte polymere |
| ES2930250T3 (es) | 2018-10-10 | 2022-12-09 | Dow Global Technologies Llc | Composición a base de agua |
| KR20220047288A (ko) * | 2019-08-09 | 2022-04-15 | 신쏘머 에스디엔. 비에이치디. | 자기-회복 특성을 갖는 탄성 필름을 제조하기 위한 폴리머 라텍스 조성물 |
| CN111349393A (zh) * | 2020-02-25 | 2020-06-30 | 江西科技师范大学 | 一种新型植物油基的有机-无机杂化涂层材料的制备方法 |
| CN113372479B (zh) * | 2021-07-20 | 2023-04-28 | 安徽工程大学 | 利用可功能化酰胺动态共价键制备的交联乙酰乙酸基甲基丙烯酸乙酯共聚物及制备方法 |
Family Cites Families (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3328325A (en) * | 1966-03-09 | 1967-06-27 | Rohm & Haas | Floor polish and method of use |
| GB1185216A (en) * | 1966-05-28 | 1970-03-25 | Basf Ag | Production of coated, impregnated or bonded articles |
| US3467610A (en) * | 1967-11-29 | 1969-09-16 | Rohm & Haas | Aqueous floor polish compositions containing a water-insoluble addition polymer and a polyvalent metal chelate |
| US4150005A (en) * | 1977-03-17 | 1979-04-17 | Rohm And Haas Company | Internally plasticized polymer latex |
| US4254279A (en) * | 1979-09-24 | 1981-03-03 | Fmc Corporation | Ester resolution process |
| JPS6121171A (ja) * | 1984-07-09 | 1986-01-29 | Hoechst Gosei Kk | 速硬化水性接着剤と接着方法 |
| US4626567A (en) * | 1985-10-25 | 1986-12-02 | Beecham Home Improvement Products Inc. | Water-resistant clear and colored acrylic latex sealant |
| US4908403A (en) * | 1986-05-02 | 1990-03-13 | Union Oil Of California | Pressure sensitive adhesives of acetoacetoxy-alkyl acrylate polymers |
| JPH0757863B2 (ja) * | 1987-12-29 | 1995-06-21 | 日本合成化学工業株式会社 | 感圧性接着剤組成物 |
| GB8811436D0 (en) * | 1988-05-13 | 1988-06-15 | Polyvinyl Chemie Holland Bv | Aqueous coating compositions |
| DE68919600T2 (de) * | 1988-08-26 | 1995-05-11 | Nippon Oils & Fats Co Ltd | Pigmentdispergiermittel. |
| US4960924A (en) * | 1988-10-31 | 1990-10-02 | Rohm And Haas Company | Mercaptoalkyl acetoacetates |
| US5055506A (en) * | 1988-12-30 | 1991-10-08 | Union Oil Company Of California | Polymer systems and methods for their production |
| EP0390370B1 (de) * | 1989-03-29 | 1993-06-09 | Zeneca Limited | Wässrige Beschichtungsmassen |
| JPH036236A (ja) * | 1989-06-01 | 1991-01-11 | Nippon Oil & Fats Co Ltd | 反応性樹脂粒子 |
| US5017676A (en) * | 1989-12-18 | 1991-05-21 | Texaco Chemical Company | Acetoacetoxyethyl methacrylate in the cure of epoxy resins |
| GB9101205D0 (en) * | 1990-02-14 | 1991-02-27 | Ici Plc | Incorporation of desired groups into polymers,the polymers so produced and composition containing them |
| DE4034279A1 (de) * | 1990-10-27 | 1992-04-30 | Bayer Ag | Verwendung von alkoxysilylaminen als haerter fuer acetoacetat- oder acetoacetamidgruppen aufweisende kunststoffvorlaeufer |
| NL9002380A (nl) * | 1990-11-01 | 1992-06-01 | Stamicarbon | Bindmiddelsamenstelling op basis van een acrylaatpolymeer en een kruisvernetter op basis van een acetoacetaatverbinding. |
| US5124384A (en) * | 1990-11-16 | 1992-06-23 | Air Products And Chemicals, Inc. | Transparent caulks containing fumed silica |
| JPH04189874A (ja) * | 1990-11-22 | 1992-07-08 | Nippon Oil & Fats Co Ltd | 塗料用樹脂組成物 |
| DE69124354T3 (de) * | 1990-12-21 | 2003-04-24 | Rohm & Haas | Lufthärtende Polymerzusammensetzung |
| US5391624A (en) * | 1992-02-10 | 1995-02-21 | S. C. Johnson & Son, Inc. | Thermosettable compositions |
| AT396934B (de) * | 1992-02-14 | 1993-12-27 | Vianova Kunstharz Ag | Verfahren zur herstellung von wässrigen, selbstvernetzenden polymerdispersionen und ihre verwendung als bindemittel für lagerstabile einkomponentenlacke |
| US5362816A (en) * | 1992-06-04 | 1994-11-08 | Rohm And Haas Company | High cohesive strength pressure-sensitive adhesives incorporating acetoacetate |
| US5349026A (en) * | 1992-11-20 | 1994-09-20 | Rohm And Haas Company | Reactive coalescents |
-
1993
- 1993-07-14 US US08/091,489 patent/US5525662A/en not_active Expired - Lifetime
-
1994
- 1994-06-27 IL IL11013694A patent/IL110136A/xx not_active IP Right Cessation
- 1994-06-28 DE DE69426659T patent/DE69426659T2/de not_active Expired - Lifetime
- 1994-06-28 EP EP94304727A patent/EP0634425B1/de not_active Expired - Lifetime
- 1994-06-30 ZA ZA944717A patent/ZA944717B/xx unknown
- 1994-07-07 AU AU67318/94A patent/AU687398B2/en not_active Expired
- 1994-07-07 CA CA002127570A patent/CA2127570A1/en not_active Abandoned
- 1994-07-08 RU RU94026093/04A patent/RU94026093A/ru unknown
- 1994-07-11 BR BR9402671A patent/BR9402671A/pt not_active IP Right Cessation
- 1994-07-13 CN CN94108298A patent/CN1051319C/zh not_active Expired - Lifetime
- 1994-07-13 JP JP18305894A patent/JP3787168B2/ja not_active Expired - Lifetime
- 1994-07-13 KR KR1019940016888A patent/KR100365104B1/ko not_active IP Right Cessation
-
1995
- 1995-06-06 US US08/466,871 patent/US5494961A/en not_active Expired - Lifetime
- 1995-06-06 US US08/467,116 patent/US5548024A/en not_active Expired - Lifetime
- 1995-06-06 US US08/466,870 patent/US5494975A/en not_active Expired - Lifetime
- 1995-06-06 US US08/467,115 patent/US5616764A/en not_active Expired - Lifetime
-
1999
- 1999-04-23 CN CN99105032A patent/CN1238342A/zh active Pending
-
2002
- 2002-06-05 KR KR1020020031571A patent/KR100393405B1/ko not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0634425A1 (de) | 1995-01-18 |
| KR100365104B1 (ko) | 2003-03-03 |
| IL110136A0 (en) | 1994-10-07 |
| RU94026093A (ru) | 1996-05-27 |
| CN1102414A (zh) | 1995-05-10 |
| CN1051319C (zh) | 2000-04-12 |
| EP0634425B1 (de) | 2001-02-07 |
| US5494975A (en) | 1996-02-27 |
| KR960014165A (ko) | 1996-05-22 |
| AU6731894A (en) | 1995-01-27 |
| JP3787168B2 (ja) | 2006-06-21 |
| CN1238342A (zh) | 1999-12-15 |
| US5616764A (en) | 1997-04-01 |
| BR9402671A (pt) | 1995-05-02 |
| ZA944717B (en) | 1995-01-18 |
| JPH07138317A (ja) | 1995-05-30 |
| US5548024A (en) | 1996-08-20 |
| CA2127570A1 (en) | 1995-01-15 |
| US5525662A (en) | 1996-06-11 |
| IL110136A (en) | 1999-09-22 |
| AU687398B2 (en) | 1998-02-26 |
| US5494961A (en) | 1996-02-27 |
| KR100393405B1 (ko) | 2003-07-31 |
| DE69426659D1 (de) | 2001-03-15 |
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