DE69021114T2 - Zusatzstoffe, die eine reduzierte Schrumpfung der photohärtbaren Zusammensetzungen gewähren. - Google Patents

Zusatzstoffe, die eine reduzierte Schrumpfung der photohärtbaren Zusammensetzungen gewähren.

Info

Publication number
DE69021114T2
DE69021114T2 DE69021114T DE69021114T DE69021114T2 DE 69021114 T2 DE69021114 T2 DE 69021114T2 DE 69021114 T DE69021114 T DE 69021114T DE 69021114 T DE69021114 T DE 69021114T DE 69021114 T2 DE69021114 T2 DE 69021114T2
Authority
DE
Germany
Prior art keywords
additives
photocurable compositions
reduced shrinkage
allow reduced
allow
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69021114T
Other languages
English (en)
Other versions
DE69021114D1 (de
Inventor
Eustathios Vassiliou
Mario Grossa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Koninklijke DSM NV
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Application granted granted Critical
Publication of DE69021114D1 publication Critical patent/DE69021114D1/de
Publication of DE69021114T2 publication Critical patent/DE69021114T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/004—Photosensitive materials
    • G03F7/027—Non-macromolecular photopolymerisable compounds having carbon-to-carbon double bonds, e.g. ethylenic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
    • B29C64/10—Processes of additive manufacturing
    • B29C64/106—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
    • B29C64/124—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified
    • B29C64/129—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask
    • B29C64/135—Processes of additive manufacturing using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material using layers of liquid which are selectively solidified characterised by the energy source therefor, e.g. by global irradiation combined with a mask the energy source being concentrated, e.g. scanning lasers or focused light sources
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C9/00—Stereo-photographic or similar processes
    • G03C9/08—Producing three-dimensional images
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03F—PHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR
    • G03F7/00—Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
    • G03F7/0037—Production of three-dimensional images
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/08—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation
    • B29C35/0805—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation
    • B29C2035/0833—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould by wave energy or particle radiation using electromagnetic radiation using actinic light
    • G—PHYSICS
    • G05—CONTROLLING; REGULATING
    • G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
    • G05B2219/00—Program-control systems
    • G05B2219/30—Nc systems
    • G05B2219/49—Nc machine tool, till multiple
    • G05B2219/49013—Deposit layers, cured by scanning laser, stereo lithography SLA, prototyping
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S430/00—Radiation imagery chemistry: process, composition, or product thereof
    • Y10S430/1053—Imaging affecting physical property or radiation sensitive material, or producing nonplanar or printing surface - process, composition, or product: radiation sensitive composition or product or process of making binder containing
    • Y10S430/1055—Radiation sensitive composition or product or process of making
    • Y10S430/106—Binder containing
    • Y10S430/108—Polyolefin or halogen containing
DE69021114T 1989-04-21 1990-04-19 Zusatzstoffe, die eine reduzierte Schrumpfung der photohärtbaren Zusammensetzungen gewähren. Expired - Fee Related DE69021114T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US07/341,868 US5128235A (en) 1989-04-21 1989-04-21 Method of forming a three-dimensional object comprising additives imparting reduction of shrinkage to photohardenable compositions

Publications (2)

Publication Number Publication Date
DE69021114D1 DE69021114D1 (de) 1995-08-31
DE69021114T2 true DE69021114T2 (de) 1996-01-25

Family

ID=23339356

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69021114T Expired - Fee Related DE69021114T2 (de) 1989-04-21 1990-04-19 Zusatzstoffe, die eine reduzierte Schrumpfung der photohärtbaren Zusammensetzungen gewähren.

Country Status (8)

Country Link
US (1) US5128235A (de)
EP (1) EP0393672B1 (de)
JP (1) JP2610692B2 (de)
KR (1) KR900016810A (de)
CN (1) CN1046614A (de)
AU (1) AU636140B2 (de)
CA (1) CA2014808A1 (de)
DE (1) DE69021114T2 (de)

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US5182715A (en) * 1989-10-27 1993-01-26 3D Systems, Inc. Rapid and accurate production of stereolighographic parts
US5167882A (en) * 1990-12-21 1992-12-01 Loctite Corporation Stereolithography method
US5399624A (en) * 1990-12-21 1995-03-21 Loctite Corporation High purity resins for thiol-ene polymerizations and method for producing same
US5460758A (en) * 1990-12-21 1995-10-24 Eos Gmbh Electro Optical Systems Method and apparatus for production of a three-dimensional object
DE59101958D1 (de) * 1990-12-21 1994-07-21 Eos Electro Optical Syst Verfahren und vorrichtung zum herstellen eines dreidimensionalen objekts.
US5512162A (en) * 1992-08-13 1996-04-30 Massachusetts Institute Of Technology Method for photo-forming small shaped metal containing articles from porous precursors
DE4433118A1 (de) * 1994-09-16 1996-03-21 Eos Electro Optical Syst Verfahren zur Herstellung eines dreidimensionalen Objektes
US5633021A (en) * 1994-10-19 1997-05-27 Bpm Technology, Inc. Apparatus for making a three-dimensional article
US5572431A (en) * 1994-10-19 1996-11-05 Bpm Technology, Inc. Apparatus and method for thermal normalization in three-dimensional article manufacturing
US5717599A (en) * 1994-10-19 1998-02-10 Bpm Technology, Inc. Apparatus and method for dispensing build material to make a three-dimensional article
US5555176A (en) * 1994-10-19 1996-09-10 Bpm Technology, Inc. Apparatus and method for making three-dimensional articles using bursts of droplets
JP3117394B2 (ja) * 1994-11-29 2000-12-11 帝人製機株式会社 光学的立体造形用樹脂組成物
US5763503A (en) * 1995-06-07 1998-06-09 Esschem, Inc. Radiation-curable, moldable material, methods for curing it and molded articles obtained therefrom
US5784279A (en) * 1995-09-29 1998-07-21 Bpm Technology, Inc. Apparatus for making three-dimensional articles including moving build material reservoir and associated method
US5700406A (en) * 1996-04-26 1997-12-23 Bpm Technology, Inc. Process of and apparatus for making a three-dimensional article
US7332537B2 (en) 1996-09-04 2008-02-19 Z Corporation Three dimensional printing material system and method
WO2000051761A1 (en) * 1998-11-20 2000-09-08 Allison Engine Company, Inc. Method and apparatus for production of a cast component
WO2001034371A2 (en) 1999-11-05 2001-05-17 Z Corporation Material systems and methods of three-dimensional printing
US7300619B2 (en) 2000-03-13 2007-11-27 Objet Geometries Ltd. Compositions and methods for use in three dimensional model printing
EP1741545B1 (de) * 2000-03-13 2013-07-17 Stratasys Ltd. Zusammensetzungen zum dreidimensionalen Drucken eines Modells
US6569373B2 (en) * 2000-03-13 2003-05-27 Object Geometries Ltd. Compositions and methods for use in three dimensional model printing
US8481241B2 (en) * 2000-03-13 2013-07-09 Stratasys Ltd. Compositions and methods for use in three dimensional model printing
US20010050031A1 (en) 2000-04-14 2001-12-13 Z Corporation Compositions for three-dimensional printing of solid objects
KR101120156B1 (ko) 2003-05-21 2012-02-22 제트 코포레이션 3ｄ 인쇄 시스템으로부터의 외관 모형용 열가소성 분말물질 시스템
US7261542B2 (en) 2004-03-18 2007-08-28 Desktop Factory, Inc. Apparatus for three dimensional printing using image layers
WO2008073297A2 (en) 2006-12-08 2008-06-19 Z Corporation Three dimensional printing material system and method using peroxide cure
JP5129267B2 (ja) 2007-01-10 2013-01-30 スリーディー システムズ インコーポレーテッド 改良された色、物品性能及び使用の容易さ、を持つ３次元印刷材料システム
US7968626B2 (en) 2007-02-22 2011-06-28 Z Corporation Three dimensional printing material system and method using plasticizer-assisted sintering
CN107108773B (zh) * 2014-11-04 2019-05-17 三键有限公司 光固化性树脂组合物及其固化物、以及固化物的制造方法
JP2021516180A (ja) * 2018-03-02 2021-07-01 フォームラブス, インコーポレーテッドFormlabs, Inc. 潜在性硬化樹脂および関連する方法
CN108912287B (zh) * 2018-07-17 2020-11-06 深圳摩方新材科技有限公司 一种改善打印层纹的双引发固化体系及其制备方法
US11155039B2 (en) * 2019-10-08 2021-10-26 Thermwood Corporation Warp compensation for additive manufacturing

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US3701748A (en) * 1966-07-20 1972-10-31 Rohm & Haas Unsaturated polyester resinous compositions
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US4005244A (en) * 1974-09-30 1977-01-25 Ppg Industries, Inc. Ultraviolet light curable opacifying compositions
US4078229A (en) * 1975-01-27 1978-03-07 Swanson Wyn K Three dimensional systems
US4151219A (en) * 1977-05-11 1979-04-24 The Dow Chemical Company Vinyl ester resins containing polyoxyalkylene low profile additives
US4288861A (en) * 1977-12-01 1981-09-08 Formigraphic Engine Corporation Three-dimensional systems
US4245068A (en) * 1977-12-27 1981-01-13 The Dow Chemical Company Low profile additives for unsaturated polyester resins
DE3363163D1 (en) * 1982-07-06 1986-05-28 Basf Ag Process for producing low-shrink polyamide moulded articles
US4575330A (en) * 1984-08-08 1986-03-11 Uvp, Inc. Apparatus for production of three-dimensional objects by stereolithography
JPS61217036A (ja) * 1985-03-22 1986-09-26 Kuraray Co Ltd 水溶性感光性組成物
DE3537380A1 (de) * 1985-10-21 1987-04-23 Hoechst Ag Photopolymerisierbares gemisch und dieses enthaltendes photopolymerisierbares aufzeichnungsmaterial
ATE113746T1 (de) * 1986-06-03 1994-11-15 Cubital Ltd Gerät zur entwicklung dreidimensionaler modelle.
JPS62288667A (ja) * 1986-06-09 1987-12-15 Nippon Kayaku Co Ltd 塗料組成物
US4752498A (en) * 1987-03-02 1988-06-21 Fudim Efrem V Method and apparatus for production of three-dimensional objects by photosolidification
JPH0791171B2 (ja) * 1987-03-20 1995-10-04 株式会社クラレ 矯正用光硬化型樹脂複合組成物
US4942112A (en) * 1988-01-15 1990-07-17 E. I. Du Pont De Nemours And Company Photopolymerizable compositions and elements for refractive index imaging
US4945032A (en) * 1988-03-31 1990-07-31 Desoto, Inc. Stereolithography using repeated exposures to increase strength and reduce distortion
JPH07103218B2 (ja) * 1988-09-13 1995-11-08 旭電化工業株式会社 光学的造形用樹脂組成物
US4942060A (en) * 1989-04-21 1990-07-17 E. I. Du Pont De Nemours And Company Solid imaging method utilizing photohardenable compositions of self limiting thickness by phase separation

Also Published As

Publication number Publication date
EP0393672B1 (de) 1995-07-26
DE69021114D1 (de) 1995-08-31
JPH0320315A (ja) 1991-01-29
JP2610692B2 (ja) 1997-05-14
KR900016810A (ko) 1990-11-14
AU5376790A (en) 1990-10-25
CN1046614A (zh) 1990-10-31
EP0393672A3 (de) 1992-05-27
US5128235A (en) 1992-07-07
EP0393672A2 (de) 1990-10-24
CA2014808A1 (en) 1990-10-21
AU636140B2 (en) 1993-04-22

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Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8327 Change in the person/name/address of the patent owner

Owner name: DSM N.V., HEERLEN, NL

8339 Ceased/non-payment of the annual fee