DE69015369T2 - Olefinpolymerisationskatalysator aus einer trialkylaluminiummischung, kieselsäuregel und metallocen. - Google Patents

Olefinpolymerisationskatalysator aus einer trialkylaluminiummischung, kieselsäuregel und metallocen.

Info

Publication number
DE69015369T2
DE69015369T2 DE69015369T DE69015369T DE69015369T2 DE 69015369 T2 DE69015369 T2 DE 69015369T2 DE 69015369 T DE69015369 T DE 69015369T DE 69015369 T DE69015369 T DE 69015369T DE 69015369 T2 DE69015369 T2 DE 69015369T2
Authority
DE
Germany
Prior art keywords
metallocen
polymerization catalyst
olefin polymerization
catalyst made
trialkyl aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69015369T
Other languages
English (en)
Other versions
DE69015369D1 (de
Inventor
Main Chang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Chemical Patents Inc
Original Assignee
Exxon Chemical Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc
Publication of DE69015369D1 publication Critical patent/DE69015369D1/de
Application granted granted Critical
Publication of DE69015369T2 publication Critical patent/DE69015369T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03B—APPARATUS OR ARRANGEMENTS FOR TAKING PHOTOGRAPHS OR FOR PROJECTING OR VIEWING THEM; APPARATUS OR ARRANGEMENTS EMPLOYING ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ACCESSORIES THEREFOR
    • G03B2227/00—Photographic printing apparatus
    • G03B2227/32—Projection printing apparatus, e.g. enlarging apparatus, copying camera
    • G03B2227/325—Microcapsule copiers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE69015369T 1989-10-16 1990-10-09 Olefinpolymerisationskatalysator aus einer trialkylaluminiummischung, kieselsäuregel und metallocen. Expired - Lifetime DE69015369T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/422,357 US5006500A (en) 1988-10-27 1989-10-16 Olefin polymerization catalyst from trialkylaluminum mixture, silica gel and a metallocene
PCT/US1990/005769 WO1991005810A1 (en) 1989-10-16 1990-10-09 Olefin polymerization catalyst from trialkylaluminum mixture, silica gel and a metallocene

Publications (2)

Publication Number Publication Date
DE69015369D1 DE69015369D1 (de) 1995-02-02
DE69015369T2 true DE69015369T2 (de) 1996-01-11

Family

ID=23674542

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69015369T Expired - Lifetime DE69015369T2 (de) 1989-10-16 1990-10-09 Olefinpolymerisationskatalysator aus einer trialkylaluminiummischung, kieselsäuregel und metallocen.

Country Status (12)

Country Link
US (1) US5006500A (de)
EP (1) EP0495849B1 (de)
JP (1) JPH0713100B2 (de)
KR (1) KR927003650A (de)
AR (1) AR244711A1 (de)
AU (1) AU6530890A (de)
BR (1) BR9007756A (de)
CA (1) CA2067177C (de)
DE (1) DE69015369T2 (de)
IL (1) IL95982A0 (de)
PT (1) PT95599A (de)
WO (1) WO1991005810A1 (de)

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US5910464A (en) * 1992-06-18 1999-06-08 Montell Technology Company Bv Catalysts for the polymerization of olefins
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US5602067A (en) * 1992-12-28 1997-02-11 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
US5332706A (en) * 1992-12-28 1994-07-26 Mobil Oil Corporation Process and a catalyst for preventing reactor fouling
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US5414180A (en) * 1993-07-14 1995-05-09 Phillips Petroleum Company Organo-aluminoxy product and use
US5455741A (en) * 1993-10-26 1995-10-03 Pulse Engineering, Inc. Wire-lead through hole interconnect device
US5614456A (en) * 1993-11-15 1997-03-25 Mobil Oil Corporation Catalyst for bimodal molecular weight distribution ethylene polymers and copolymers
US5491207A (en) * 1993-12-14 1996-02-13 Exxon Chemical Patents Inc. Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system
US5525678A (en) * 1994-09-22 1996-06-11 Mobil Oil Corporation Process for controlling the MWD of a broad/bimodal resin produced in a single reactor
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US5882750A (en) * 1995-07-03 1999-03-16 Mobil Oil Corporation Single reactor bimodal HMW-HDPE film resin with improved bubble stability
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US6486089B1 (en) 1995-11-09 2002-11-26 Exxonmobil Oil Corporation Bimetallic catalyst for ethylene polymerization reactions with uniform component distribution
US5752362A (en) * 1996-03-12 1998-05-19 Tenneco Packaging Stretch wrap films
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US5976682A (en) * 1996-03-12 1999-11-02 Tenneco Packaging Stretch wrap films
US5749202A (en) * 1996-03-12 1998-05-12 Tenneco Packaging Stretch wrap films
US5902684A (en) * 1996-03-12 1999-05-11 Tenneco Packaging Inc. Multilayered Metallocene stretch wrap films
US5814399A (en) * 1996-03-12 1998-09-29 Tenneco Packaging Stretch wrap films
US6417130B1 (en) 1996-03-25 2002-07-09 Exxonmobil Oil Corporation One pot preparation of bimetallic catalysts for ethylene 1-olefin copolymerization
AU3505497A (en) * 1996-07-15 1998-02-09 Mobil Oil Corporation Comonomer pretreated bimetallic catalyst for blow molding and film applications
US5851070A (en) * 1996-12-05 1998-12-22 Tenneco Packaging Inc. Seals for plastic bags
US6376035B1 (en) 1996-12-05 2002-04-23 Pactiv Corporation Zipper fins for plastic bags
US5919535A (en) * 1996-12-05 1999-07-06 Tenneco Packaging Fins for plastic bags
US5989725A (en) * 1997-01-16 1999-11-23 Tenneco Packaging Clear high molecular weight film
FI972230A (fi) 1997-01-28 1998-07-29 Borealis As Uusi homogeeninen olefiinien polymerointikatalysaattorikoostumus
FI970349A (fi) 1997-01-28 1998-07-29 Borealis As Uudet metalloseeniyhdisteiden aktivaattorisysteemit
US6005463A (en) * 1997-01-30 1999-12-21 Pulse Engineering Through-hole interconnect device with isolated wire-leads and component barriers
US6013378A (en) * 1997-03-17 2000-01-11 Tenneco Packaging HMW HDPE film with improved impact strength
US5907942A (en) * 1997-05-21 1999-06-01 Tenneco Packaging Stretch wrap films
US6093480A (en) * 1997-05-21 2000-07-25 Tenneco Packaging Stretch wrap films
US5907943A (en) * 1997-06-11 1999-06-01 Tenneco Packaging Inc. Stretch wrap films
US5922441A (en) * 1997-06-11 1999-07-13 Tenneco Packaging Inc. Stretch wrap films
US6153551A (en) 1997-07-14 2000-11-28 Mobil Oil Corporation Preparation of supported catalyst using trialkylaluminum-metallocene contact products
US6051525A (en) * 1997-07-14 2000-04-18 Mobil Corporation Catalyst for the manufacture of polyethylene with a broad or bimodal molecular weight distribution
US5990035A (en) * 1997-10-21 1999-11-23 Koeppl; Alexander Polymerization catalyst systems, their preparation, and use
US6083611A (en) * 1997-11-12 2000-07-04 Tenneco Packaging, Inc. Roll wrap film
DE69922488T2 (de) * 1998-02-04 2005-12-15 Japan As Represented By Director General Of Agency Of Industrial Science And Technology Butadienpolymere und verfahren zur herstellung konjugierter dienpolymere
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EP1352913B1 (de) * 2002-04-08 2016-06-01 Tosoh Finechem Corporation Verfahren zur Herstellung von modifiertem Methylaluminoxan als Olefinpolymerisationskatalysatorbestandteil
US6884749B2 (en) 2002-10-17 2005-04-26 Equistar Chemicals L.P. Supported catalysts which reduce sheeting in olefin polymerization, process for the preparation and the use thereof
ATE360037T1 (de) * 2002-12-17 2007-05-15 Ineos Europe Ltd Geträgerter olefin polymerisationskatalysator
US8028588B2 (en) 2009-09-25 2011-10-04 Rosemount Inc. Flow measurement using near field microwaves
WO2014078919A1 (pt) 2012-11-26 2014-05-30 Braskem S.A. Catalisador metaloceno suportado em suporte híbrido, processo de obtenção do mesmo, processo de polimerização para obtenção de um homopolímero ou copolímero de etileno com distribuição de massa molar ampla ou bimodal, uso do catalisador de metaloceno suportado e polímero de etileno com distribuição de massa molar ampla ou bimodal
US11161922B2 (en) 2017-10-31 2021-11-02 Exxonmobil Chemical Patents Inc. Toluene free silica supported single-site metallocene catalysts from in-situ supported MAO formation in aliphatic solvents
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Also Published As

Publication number Publication date
IL95982A0 (en) 1991-07-18
DE69015369D1 (de) 1995-02-02
AU6530890A (en) 1991-05-16
EP0495849A1 (de) 1992-07-29
AR244711A1 (es) 1993-11-30
KR927003650A (ko) 1992-12-18
WO1991005810A1 (en) 1991-05-02
JPH0713100B2 (ja) 1995-02-15
BR9007756A (pt) 1992-10-06
US5006500A (en) 1991-04-09
EP0495849B1 (de) 1994-12-21
JPH05501424A (ja) 1993-03-18
PT95599A (pt) 1991-09-13
CA2067177A1 (en) 1991-04-17
CA2067177C (en) 2000-03-14

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8364 No opposition during term of opposition