DE60215830D1 - Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen - Google Patents

Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen

Info

Publication number
DE60215830D1
DE60215830D1 DE60215830T DE60215830T DE60215830D1 DE 60215830 D1 DE60215830 D1 DE 60215830D1 DE 60215830 T DE60215830 T DE 60215830T DE 60215830 T DE60215830 T DE 60215830T DE 60215830 D1 DE60215830 D1 DE 60215830D1
Authority
DE
Germany
Prior art keywords
sub
ethylene
ligands
alpha olefins
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE60215830T
Other languages
English (en)
Other versions
DE60215830T2 (de
Inventor
Boer Johannes De
Der Heijden Harry Van
Wijk Cornelia Verhoef-Van
Zon Arie Van
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of DE60215830D1 publication Critical patent/DE60215830D1/de
Application granted granted Critical
Publication of DE60215830T2 publication Critical patent/DE60215830T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/02—Iron compounds
    • C07F15/025—Iron compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/06—Cobalt compounds
    • C07F15/065—Cobalt compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
DE60215830T 2001-08-01 2002-07-29 Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen Expired - Fee Related DE60215830T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP01306607 2001-08-01
EP01306607 2001-08-01
PCT/EP2002/008636 WO2003011876A1 (en) 2001-08-01 2002-07-29 Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins

Publications (2)

Publication Number Publication Date
DE60215830D1 true DE60215830D1 (de) 2006-12-14
DE60215830T2 DE60215830T2 (de) 2007-06-06

Family

ID=8182162

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60215830T Expired - Fee Related DE60215830T2 (de) 2001-08-01 2002-07-29 Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen

Country Status (12)

Country Link
US (2) US7049442B2 (de)
EP (1) EP1427740B1 (de)
JP (1) JP2004536154A (de)
CN (1) CN1255419C (de)
AT (1) ATE344268T1 (de)
CA (1) CA2455853A1 (de)
CZ (1) CZ2004163A3 (de)
DE (1) DE60215830T2 (de)
ES (1) ES2272770T3 (de)
RU (1) RU2292343C2 (de)
WO (1) WO2003011876A1 (de)
ZA (1) ZA200400405B (de)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6710006B2 (en) 2000-02-09 2004-03-23 Shell Oil Company Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins
US7037988B2 (en) * 2000-10-03 2006-05-02 Shell Oil Company Process for the co-oligomerisation of ethylene and alpha olefins
RU2292343C2 (ru) * 2001-08-01 2007-01-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Лиганды и включающие их каталитические системы для олигомеризации этилена с получением линейных альфа-олефинов
US7087686B2 (en) * 2001-08-06 2006-08-08 Bp Chemicals Limited Chain growth reaction process
US8426535B2 (en) * 2001-08-06 2013-04-23 Ineos Europe Limited Chain growth reaction process
US6911506B2 (en) 2001-12-10 2005-06-28 Chevron Phillips Chemical Company Lp Catalyst composition and olefin polymerization using same
JP2006501067A (ja) * 2002-09-25 2006-01-12 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エチレンをオリゴマー化して直鎖α−オレフィンを合成するための触媒系
EP1562705A4 (de) * 2002-11-21 2007-04-25 Fina Technology Neue katalysatorstruktur zur dieolefinpolymerisation
US7045632B2 (en) 2003-03-04 2006-05-16 Chevron Phillips Chemical Company, Lp Composition and method for a hexadentate ligand and bimetallic complex for polymerization of olefins
US20050014983A1 (en) * 2003-07-07 2005-01-20 De Boer Eric Johannes Maria Process for producing linear alpha olefins
US7034157B2 (en) * 2003-10-23 2006-04-25 Fina Technology, Inc. Catalyst components, process for their preparation and their use as catalyst components in polymerization of olefins
US20050187418A1 (en) 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20070043181A1 (en) 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
US20050187098A1 (en) 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
ES2299015T3 (es) * 2004-03-24 2008-05-16 Shell Internationale Research Maatschappij B.V. Complejos de metales de transicion.
AR049714A1 (es) * 2004-07-13 2006-08-30 Shell Int Research Proceso de preparacion de alfa olefinas lineales
US7456284B2 (en) 2004-12-10 2008-11-25 Chevron Phillips Chemical Company Lp Methods for producing a hexadentate bimetallic complex
US7268096B2 (en) 2005-07-21 2007-09-11 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
SG163602A1 (en) * 2005-07-21 2010-08-30 Chevron Phillips Chemical Co Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7129304B1 (en) 2005-07-21 2006-10-31 Chevron Phillips Chemical Company Lp Dimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7271121B2 (en) 2005-07-21 2007-09-18 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization
US7727926B2 (en) 2005-07-21 2010-06-01 Chevron Phillips Chemical Company Lp Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization
US7378537B2 (en) 2006-07-25 2008-05-27 Chevron Phillips Chemical Company Lp Olefin oligomerization catalysts and methods of using same
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
FR2926078B1 (fr) * 2008-01-04 2009-12-18 Inst Francais Du Petrole Nouveaux composes organiques azotes utilisables comme precurseurs de composition catalytique.
US7858817B2 (en) * 2008-03-10 2010-12-28 Exxonmobil Chemical Patents Inc. Metallocene-substituted pyridyl amines, their metal complexes, and processes for production and use thereof
EP2552973A1 (de) 2010-03-29 2013-02-06 E.I. Du Pont De Nemours And Company Verbessertes olefinpolymerisationsverfahren
US9273165B2 (en) * 2011-02-05 2016-03-01 Bridgestone Corporation Lanthanide complex catalyst and polymerization method employing same
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US9944661B2 (en) 2016-08-09 2018-04-17 Chevron Phillips Chemical Company Lp Olefin hydroboration
US20180186708A1 (en) 2016-12-29 2018-07-05 Chevron Phillips Chemical Company Lp Ethylene Oligomerization Processes
US10407360B2 (en) 2017-12-22 2019-09-10 Chevron Phillips Chemical Company Lp Ethylene oligomerization processes
US10604457B2 (en) 2016-12-29 2020-03-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization processes
RU2672868C1 (ru) * 2017-12-07 2018-11-20 Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) Способ получения производных 2,6-бис[1-(фенилимино)этил]пиридина с электроноакцепторными заместителями
RU2729622C1 (ru) * 2019-12-20 2020-08-11 Федеральное государственное бюджетное учреждение науки Новосибирский институт органической химии им. Н.Н. Ворожцова Сибирского отделения Российской академии наук (НИОХ СО РАН) Компонент катализатора для полимеризации этилена в высоколинейный полиэтилен, термостабильный катализатор и способ его приготовления
AR124332A1 (es) 2020-12-15 2023-03-15 Shell Int Research UN PROCESO PARA PRODUCIR a-OLEFINAS
AR124325A1 (es) * 2020-12-15 2023-03-15 Shell Int Research UN PROCESO PARA PRODUCIR a-OLEFINAS

Family Cites Families (67)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SU418462A1 (ru) 1971-08-16 1974-03-05 СПОСОБ ПОЛУЧЕНИЯ СМЕСИ ОЛЕФИНОВ С^—С^1Изобретение относитс к способу получени смеси олефинов С4—Се с преобладанием альфа-изомеров, которые наход т широкое применение в качестве мономеров и промежуточных продуктов при синтезе пластмасс и кау- чуков.Известен способ получени смеси олефииов С4—Сб содимеризацией этилена с пропиленом при температуре 100—160°С и давлении 40 атм в присутствии триалкилалюмини , например триэтилалюмини или диэтилалюми- нийхлорида, и соединени переходного металла, например хлорида никел или его окиси.К недостаткам известного способа относ тс низкий выход альфа-олефинов и недостаточно высока степень конверсии пропилена.С целью повышени выхода альфа-олефинов предлагаетс в качестве соединени переходного .металла использовать пальмитат никел .Пример. 250 мл (180 г) катализатора, состо щего из 3%-ного раствора триэтилалю-5 мини в н-декапе и пальмитата никел (А1 : N1 = 500 : 1), помещают в предварительно освобожденный от влаги и кислорода автоклав емкостью 2 л, снабженный магнитной мешалкой (1400 об/мин). Затем подают 235 г10 пропилена (чистота 99,5%) и 157 г этилена (чистота 99,8%). Мольное соотношение 1:1. Нагревают до нужной температуры и перемешивают 20 час. Вместе с альфа-олефинами С4—Сб образуетс небольшое количество аль-15 фа-олефинов Cs—Сэ
US4728583A (en) * 1984-08-31 1988-03-01 Fuji Photo Film Co., Ltd. Radiation image storage panel and process for the preparation of the same
EP0233497B1 (de) * 1986-01-21 1990-05-09 Fuji Photo Film Co., Ltd. Strahlungsbildspeicherplatte
EP0308728B1 (de) 1987-09-21 1991-06-05 Siemens Aktiengesellschaft Verfahren zum Betreiben eines Durchlaufdampferzeugers
US4822911A (en) 1987-09-25 1989-04-18 Shell Oil Company Process for the selective separation of vinylidene olefins from mixtures with other olefins
US4912333A (en) * 1988-09-12 1990-03-27 Eastman Kodak Company X-ray intensifying screen permitting an improved relationship of imaging speed to sharpness
JPH042999A (ja) * 1990-04-20 1992-01-07 Fuji Photo Film Co Ltd 放射線像変換パネル
ES2085000T3 (es) * 1990-12-27 1996-05-16 Exxon Chemical Patents Inc Un compuesto de amido-metal de transicion y un sistema catalitico para la produccion de polipropileno isotactico.
JP3115345B2 (ja) 1991-04-26 2000-12-04 三菱化学株式会社 オレフィン重合体の製造法
CN1079700C (zh) * 1995-03-08 2002-02-27 国际壳牌研究有限公司 催化剂组合物中的桥双-氨基第4族金属化合物
JP3479574B2 (ja) * 1995-07-04 2003-12-15 富士写真フイルム株式会社 フロント側用放射線増感スクリーン及び放射線増感スクリーン組体
US5830629A (en) * 1995-11-01 1998-11-03 Eastman Kodak Company Autoradiography assemblage using transparent screen
DE19547210A1 (de) * 1995-12-18 1997-06-19 Basf Ag 1,7-Disubstituierte Perylen-3,4,9-10-tetracarbonsäuren, deren Dianhydride und Diimide
DE69730838T2 (de) * 1996-07-23 2006-02-16 E.I. Du Pont De Nemours And Co., Wilmington Polymerisationsverfahren für olefinen
EP0927201B1 (de) 1996-09-06 2004-04-14 Hyundai Petrochemical Co., Ltd. Katalysatorsystem für die (co)polymerisierung von olefinen und verfahren zur herstellung von olefin-(co)polymeren unter verwendung des katalysatorsystems
US6214761B1 (en) * 1996-12-17 2001-04-10 E. I. Du Pont De Nemours And Company Iron catalyst for the polymerization of olefins
US6423848B2 (en) * 1996-12-17 2002-07-23 E. I. Du Pont De Nemours And Company Tridentate ligand
US6432862B1 (en) * 1996-12-17 2002-08-13 E. I. Du Pont De Nemours And Company Cobalt catalysts for the polymerization of olefins
US6417305B2 (en) * 1996-12-17 2002-07-09 E. I. Du Pont De Nemours And Company Oligomerization of ethylene
IL129929A0 (en) * 1996-12-17 2000-02-29 Du Pont Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt
WO1998030612A1 (en) * 1997-01-13 1998-07-16 E.I. Du Pont De Nemours And Company Polymerization of propylene
US5905014A (en) * 1997-03-19 1999-05-18 Agfa-Gevaert, N.V. Radiation image storage panel comprising a colorant
US6103946A (en) * 1997-07-15 2000-08-15 E. I. Du Pont De Nemours And Company Manufacture of α-olefins
US6740715B2 (en) * 1997-07-15 2004-05-25 E. I. Du Pont De Nemours And Company Manufacture of alpha-olefins
ID24448A (id) * 1997-09-05 2000-07-20 Bp Chemical Ltd Katalis-katalis polimerisasi
US6559252B1 (en) * 1997-10-29 2003-05-06 Basell Technology Company Bv Catalysts and processes for the polymerization of olefins
WO2000032643A1 (fr) * 1998-12-02 2000-06-08 Idemitsu Petrochemical Co., Ltd. Catalyseur pour la polymerisation d'olefines et procede de production d'un polymere d'olefines a l'aide de ce catalyseur
DZ2737A1 (fr) * 1998-03-12 2003-09-01 Bp Chem Int Ltd Catalyseurs de polymérisation.
ID27209A (id) * 1998-03-12 2001-03-08 Bp Chem Int Ltd Katalis-katalis polimerisasi
CA2323457A1 (en) * 1998-03-12 1999-09-16 Bp Chemicals Limited Homopolymer of ethylene
US6232259B1 (en) * 1998-03-31 2001-05-15 E. I. Du Pont De Nemours And Company Preparation of transition metal imine complexes
US6063881A (en) 1998-04-02 2000-05-16 E. I. Du Pont De Nemours And Company Oligomerization of propylene
EP0952165A1 (de) * 1998-04-24 1999-10-27 Fina Research S.A. Herstellung von Polyethylene mit verbesserten mechanischen Eigenschaften
BR9911200A (pt) 1998-05-29 2001-10-09 Du Pont Processo de polimerização e copolìmero de etileno e uma ou mais olefinas da fórmula h2c=chr21
GB9817004D0 (en) * 1998-08-06 1998-09-30 Bp Chem Int Ltd Preparation of polymerisation catalysts
GB9819847D0 (en) * 1998-09-12 1998-11-04 Bp Chem Int Ltd Novel compounds
WO2000020427A1 (en) * 1998-10-02 2000-04-13 Bp Chemicals Limited Polymerisation catalysts
WO2000024788A1 (en) * 1998-10-26 2000-05-04 Bp Chemicals Limited Polymerisation catalysts
WO2000032641A1 (en) * 1998-11-30 2000-06-08 Bp Chemicals Limited Polymerisation process
US6395668B1 (en) * 1998-12-15 2002-05-28 Basell Technology Company Bv Catalyst system for olefin polymerization
US6583237B1 (en) * 1999-01-22 2003-06-24 Mitsui Chemicals, Inc. Process for producing olefin polymer and olefin polymers
US6545108B1 (en) * 1999-02-22 2003-04-08 Eastman Chemical Company Catalysts containing N-pyrrolyl substituted nitrogen donors
CA2363628A1 (en) * 1999-02-22 2000-08-31 James Allen Ponasik Jr. Catalysts containing n-pyrrolyl substituted nitrogen donors
GB9906296D0 (en) * 1999-03-18 1999-05-12 Bp Chem Int Ltd Polymerisation catalysts
DE19931873A1 (de) * 1999-04-14 2000-10-19 Bayer Ag Katalysatorsystem zur Olefinpolymerisation
US6365690B1 (en) * 1999-05-06 2002-04-02 E. I. Du Pont De Nemours And Company Polymerization of ethylene
US6825297B1 (en) * 1999-05-14 2004-11-30 The Dow Chemical Company Transition metal complexes and olefin polymerization process
US6479601B1 (en) * 1999-08-06 2002-11-12 The Goodyear Tire & Rubber Company Transition metal catalysts for diene polymerizations
US6458905B1 (en) * 1999-08-16 2002-10-01 Phillips Petroleum Company Complexes of pyridldiimines with vanadium and other transition metals, and their use as olefin oligomerization and polymerization catalysts
US6441117B1 (en) * 1999-09-01 2002-08-27 E. I. Du Pont De Nemours And Company High density polyethylene packaging
BR0007190A (pt) 1999-09-02 2001-08-14 Idemitsu Petrochemical Co Composto de metal de transição, catalisador para produção de alfa-olefinas e processo para produção de alfa-olefinas
US6407188B1 (en) * 1999-09-29 2002-06-18 E. I. Du Pont De Nemours And Company Polymerization of olefins
DE60045557D1 (de) 1999-11-11 2011-03-03 Idemitsu Kosan Co Übergangsmetall-verbindung, katalysator zur olefin polymerisation und ein verfahren zur polymerisation von olefinen
KR100900931B1 (ko) * 2000-01-26 2009-06-08 미쓰이 가가쿠 가부시키가이샤 올레핀 중합체 및 그의 제조 방법
US6710006B2 (en) * 2000-02-09 2004-03-23 Shell Oil Company Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins
TW572969B (en) 2000-02-10 2004-01-21 Hayashibara Biochem Lab Trimethine cyanine dye, light absorbent, light-resistant improver and optical recording medium containing same, and process for producing same
US6605677B2 (en) * 2000-02-18 2003-08-12 Eastman Chemical Company Olefin polymerization processes using supported catalysts
GC0000291A (en) * 2000-06-30 2006-11-01 Shell Int Research Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
US6555723B2 (en) * 2000-07-18 2003-04-29 E. I. Du Pont De Nemours And Company Continuous manufacturing process for alpha-olefins
US6534691B2 (en) * 2000-07-18 2003-03-18 E. I. Du Pont De Nemours And Company Manufacturing process for α-olefins
US7037988B2 (en) * 2000-10-03 2006-05-02 Shell Oil Company Process for the co-oligomerisation of ethylene and alpha olefins
US6706891B2 (en) * 2000-11-06 2004-03-16 Eastman Chemical Company Process for the preparation of ligands for olefin polymerization catalysts
US6521329B2 (en) * 2001-06-18 2003-02-18 Eastman Kodak Company Radiographic phosphor panel having reflective polymeric supports
ES2278933T3 (es) * 2001-06-20 2007-08-16 Shell Internationale Research Maatschappij B.V. Procedimiento para la preparacion de oligomeros.
RU2292343C2 (ru) 2001-08-01 2007-01-27 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Лиганды и включающие их каталитические системы для олигомеризации этилена с получением линейных альфа-олефинов
JP2006501067A (ja) 2002-09-25 2006-01-12 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー エチレンをオリゴマー化して直鎖α−オレフィンを合成するための触媒系
US20050014983A1 (en) * 2003-07-07 2005-01-20 De Boer Eric Johannes Maria Process for producing linear alpha olefins

Also Published As

Publication number Publication date
US7049442B2 (en) 2006-05-23
WO2003011876A1 (en) 2003-02-13
RU2292343C2 (ru) 2007-01-27
EP1427740A1 (de) 2004-06-16
DE60215830T2 (de) 2007-06-06
US7304159B2 (en) 2007-12-04
RU2004105958A (ru) 2005-03-27
ES2272770T3 (es) 2007-05-01
EP1427740B1 (de) 2006-11-02
US20030119921A1 (en) 2003-06-26
CN1545520A (zh) 2004-11-10
JP2004536154A (ja) 2004-12-02
ZA200400405B (en) 2004-10-19
CN1255419C (zh) 2006-05-10
US20050159601A1 (en) 2005-07-21
CZ2004163A3 (cs) 2004-09-15
ATE344268T1 (de) 2006-11-15
CA2455853A1 (en) 2003-02-13

Similar Documents

Publication Publication Date Title
DE60215830D1 (de) Liganden und diese enthaltende katalysatorsysteme fur die herstellung von linearen alpha-olefinen aus ethylen
ATE291963T1 (de) Liganden und katalysatorsysteme für die oligomerisierung von ethylen zu linearen alpha olefinen
DE50211846D1 (de) NEUE PHOSPHITVERBINDUNGEN UND DEREN Rh-KOMPLEXE
NO20050092L (no) Gruppe 4 metallkomplekser inneholdende 4-aryl-substituerte trisykliske indenyl derivater
DE60305715D1 (de) Katalysatorsysteme für die ethylen-oligomerisierung zu linearen alpha-olefinen
DE69220061T2 (de) Herstellung von chiralen phospholanen aus chiralen zyklischen sulfaten von 1,4-diolen
MY133958A (en) Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins
ATE423784T1 (de) Bisindenyl-zirconium-komplexe zur olefinpolymerisation
ATE407154T1 (de) Katalysatorsystem zur polymerisation von olefinen
ATE251635T1 (de) Heteroligand
MY127091A (en) Process for the selective oligomerization of ethylene
DE60100252D1 (de) Verfahren zur herstellung von hex-1-en
DE60334073D1 (de) Übergangsmetallkomplexe, liganden, katalysatoren für die polymerisation von olefinen und verfahren zur herstellung von olefinpolymeren
DE60306672D1 (de) Verwendung von metallkomplexverbindungen als oxidationskatalysatoren
DE59509910D1 (de) Verfahren zur Herstellung von Alkylhydrogenchlorsilanen
WO2004014550A3 (de) Neue nickel-, palladium- und platin-carbenkomplexe, ihre herstellung und verwendung in katalytischen reaktionen
DK1047669T3 (da) Perfluor-N-alkylsulfonsyrederivater
ES2143515T3 (es) Combinaciones ciclicas del fosforo trivalente.
ATE420095T1 (de) Liganden für asymmetrische reaktionen
ATE334997T1 (de) Metallkomplexe von iminohydroxamsäuren
EA200100940A1 (ru) Водорастворимые трансплатиновые комплексы, обладающие противораковым действием, способ их получения и способ лечения
TH43376A3 (th) เมทัลโลซินที่ถูกเชื่อมต่อโดยเมทิลีน ขบวนการเพื่อการเตรียมของมัน และการใช้ของมันเป็นองค์ประกอบแคทาลีสท์ในการทำโพลีเมอไรเซชันของโอลีฟิน
DK1392707T3 (da) Nye anioniske og neutrale komplekser af rithenium (II) med nitrogenoxid
TH58884B (th) ฟอสฟอไนต์
TH38914A3 (th) สารผสมตัวเร่งปฏิกิริยาและวิธีการสำหรับการเตรียมและการใช้ของมันในกรรมวิธีการพอลิเมอไรซ์

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee