DE60115684D1 - Verfahren zur herstellung von poly(1,4-cyclohexylendimethylen-1,4-cyclohexandicarboxylat) und reaktorqualitätspolyester - Google Patents

Verfahren zur herstellung von poly(1,4-cyclohexylendimethylen-1,4-cyclohexandicarboxylat) und reaktorqualitätspolyester

Info

Publication number
DE60115684D1
DE60115684D1 DE60115684T DE60115684T DE60115684D1 DE 60115684 D1 DE60115684 D1 DE 60115684D1 DE 60115684 T DE60115684 T DE 60115684T DE 60115684 T DE60115684 T DE 60115684T DE 60115684 D1 DE60115684 D1 DE 60115684D1
Authority
DE
Germany
Prior art keywords
diacid
phosphorus
mole percent
cyclohexylendimethylene
cyclohexandicarboxylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE60115684T
Other languages
English (en)
Other versions
DE60115684T2 (de
Inventor
Rice Quillen
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Chemical Co
Original Assignee
Eastman Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Application granted granted Critical
Publication of DE60115684D1 publication Critical patent/DE60115684D1/de
Publication of DE60115684T2 publication Critical patent/DE60115684T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/199—Acids or hydroxy compounds containing cycloaliphatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
DE60115684T 2000-10-13 2001-10-04 Verfahren zur herstellung von poly(1,4-cyclohexylendimethylen-1,4-cyclohexandicarboxylat) und reaktorqualitätspolyester Expired - Lifetime DE60115684T2 (de)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US24043200P 2000-10-13 2000-10-13
US240432P 2000-10-13
US09/764,931 US6458915B1 (en) 2000-10-13 2001-01-18 Process for producing poly(1,4-cyclohexylenedimethylene 1,4-cyclohexanedicarboxylate) and the reactor grade polyester therefrom
US764931 2001-01-18
PCT/US2001/031194 WO2002031020A2 (en) 2000-10-13 2001-10-04 Process for producing poly(1,4-cyclohexylenedimethylene 1,4-cyclohexanedicarboxylate) and the reactor grade polyester therefrom

Publications (2)

Publication Number Publication Date
DE60115684D1 true DE60115684D1 (de) 2006-01-12
DE60115684T2 DE60115684T2 (de) 2006-06-22

Family

ID=26933404

Family Applications (1)

Application Number Title Priority Date Filing Date
DE60115684T Expired - Lifetime DE60115684T2 (de) 2000-10-13 2001-10-04 Verfahren zur herstellung von poly(1,4-cyclohexylendimethylen-1,4-cyclohexandicarboxylat) und reaktorqualitätspolyester

Country Status (9)

Country Link
US (1) US6458915B1 (de)
EP (1) EP1325055B1 (de)
JP (1) JP4125591B2 (de)
CN (1) CN1217973C (de)
AT (1) ATE312128T1 (de)
BR (1) BR0113910A (de)
DE (1) DE60115684T2 (de)
MX (1) MXPA03002877A (de)
WO (1) WO2002031020A2 (de)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI20021293A1 (it) * 2002-06-12 2003-12-12 Gen Electric Metodo per preparare poli(cicloesan-1,4-dicarbossilato) (i) da acido cicloesan-1,4-bicarbossilico e composizione
EP1557439B1 (de) * 2002-10-31 2008-04-30 Mitsubishi Chemical Corporation Polyesterharz, polyesterharzzusammensetzung, flächengebilde oder film daraus und geformter hohler behälter
JP4048955B2 (ja) * 2003-01-10 2008-02-20 三菱化学株式会社 ポリエステル及びその製造法
US20040143041A1 (en) * 2003-01-13 2004-07-22 Pearson Jason Clay Polyester compositions
DE10322099A1 (de) * 2003-05-15 2005-01-27 Dupont Sabanci Polyester Europe B.V. Polymerisationskatalysator für die Herstellung von Polyestern, Verfahren zur Herstellung von Polyethylenterephthalat und Verwendung des Polymerisationskatalysators
US7169880B2 (en) 2003-12-04 2007-01-30 Eastman Chemical Company Shaped articles from cycloaliphatic polyester compositions
WO2005108461A1 (ja) * 2004-05-11 2005-11-17 Mitsubishi Chemical Corporation ポリエステル樹脂及びその製造方法
CN100436502C (zh) * 2004-05-11 2008-11-26 三菱化学株式会社 聚酯树脂及其制备方法
US20100184940A1 (en) * 2005-03-02 2010-07-22 Eastman Chemical Company Polyester Compositions Which Comprise Cyclobutanediol and Certain Thermal Stabilizers, and/or Reaction Products Thereof
US7807775B2 (en) 2005-06-17 2010-10-05 Eastman Chemical Company Point of purchase displays comprising polyester compositions formed from 2,2,4,4-tetramethyl-1, 3,-cyclobutanediol and 1,4-cyclohexanedimethanol
US8557950B2 (en) 2005-06-16 2013-10-15 Grupo Petrotemex, S.A. De C.V. High intrinsic viscosity melt phase polyester polymers with acceptable acetaldehyde generation rates
WO2006138739A2 (en) * 2005-06-17 2006-12-28 Tolerx, Inc. Ilt3 binding molecules and uses therefor
US7704605B2 (en) 2006-03-28 2010-04-27 Eastman Chemical Company Thermoplastic articles comprising cyclobutanediol having a decorative material embedded therein
US20090215933A1 (en) * 2005-07-12 2009-08-27 Mitsubishi Chemical Corporation Alicyclic Polyester and Process for Producing the Same, and Resin Composition Using the Same
US7932345B2 (en) * 2005-09-16 2011-04-26 Grupo Petrotemex, S.A. De C.V. Aluminum containing polyester polymers having low acetaldehyde generation rates
US8431202B2 (en) 2005-09-16 2013-04-30 Grupo Petrotemex, S.A. De C.V. Aluminum/alkaline or alkali/titanium containing polyesters having improved reheat, color and clarity
US20070106054A1 (en) * 2005-10-28 2007-05-10 Crawford Emmett D Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and high glass transition temperature and articles made therefrom
US8193302B2 (en) 2005-10-28 2012-06-05 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain phosphate thermal stabilizers, and/or reaction products thereof
US8586701B2 (en) * 2005-10-28 2013-11-19 Eastman Chemical Company Process for the preparation of copolyesters based on 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
CA2625817A1 (en) * 2005-10-28 2007-05-10 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
WO2007050118A1 (en) * 2005-10-28 2007-05-03 Eastman Chemical Company Restaurant smallware comprising polyester compositions formed from 2,2,4,4-tetramethyl-1,3-cyclobutanediol and 1,4-cyclohexanedimethanol
US9598533B2 (en) 2005-11-22 2017-03-21 Eastman Chemical Company Polyester compositions containing cyclobutanediol having a certain combination of inherent viscosity and moderate glass transition temperature and articles made therefrom
US7737246B2 (en) 2005-12-15 2010-06-15 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol, cyclohexanedimethanol, and ethylene glycol and manufacturing processes therefor
US9169388B2 (en) 2006-03-28 2015-10-27 Eastman Chemical Company Polyester compositions which comprise cyclobutanediol and certain thermal stabilizers, and/or reaction products thereof
US7211634B1 (en) * 2006-04-28 2007-05-01 Eastman Chemical Company Process for the preparation of polyesters containing 1,4-cyclohexanedimethanol
US7745368B2 (en) 2006-07-28 2010-06-29 Eastman Chemical Company Non-precipitating alkali/alkaline earth metal and aluminum compositions made with organic hydroxyacids
US7709595B2 (en) * 2006-07-28 2010-05-04 Eastman Chemical Company Non-precipitating alkali/alkaline earth metal and aluminum solutions made with polyhydroxyl ether solvents
US7709593B2 (en) 2006-07-28 2010-05-04 Eastman Chemical Company Multiple feeds of catalyst metals to a polyester production process
US8563677B2 (en) 2006-12-08 2013-10-22 Grupo Petrotemex, S.A. De C.V. Non-precipitating alkali/alkaline earth metal and aluminum solutions made with diols having at least two primary hydroxyl groups
EP2225084B1 (de) 2007-11-21 2013-05-29 Eastman Chemical Company Babyflaschen aus kunststoff, andere blasgeformte artikel und verfahren für ihre herstellung
US8501287B2 (en) 2007-11-21 2013-08-06 Eastman Chemical Company Plastic baby bottles, other blow molded articles, and processes for their manufacture
US8198371B2 (en) 2008-06-27 2012-06-12 Eastman Chemical Company Blends of polyesters and ABS copolymers
KR101099127B1 (ko) * 2008-10-16 2011-12-26 한화케미칼 주식회사 60%이상의 시스 디(ｃ4-ｃ20)알킬 시클로헥산-1,4-디카르복실레이트의 제조방법
US20100099828A1 (en) * 2008-10-21 2010-04-22 Eastman Chemical Company Clear Binary Blends of Aliphatic Polyesters and Aliphatic-Aromatic Polyesters
US8895654B2 (en) * 2008-12-18 2014-11-25 Eastman Chemical Company Polyester compositions which comprise spiro-glycol, cyclohexanedimethanol, and terephthalic acid
US8420868B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8394997B2 (en) 2010-12-09 2013-03-12 Eastman Chemical Company Process for the isomerization of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US8420869B2 (en) 2010-12-09 2013-04-16 Eastman Chemical Company Process for the preparation of 2,2,4,4-tetraalkylcyclobutane-1,3-diols
US20130217830A1 (en) 2012-02-16 2013-08-22 Eastman Chemical Company Clear Semi-Crystalline Articles with Improved Heat Resistance
KR102123151B1 (ko) * 2017-06-13 2020-06-15 (주)휴이노베이션 친환경 가소제 및 이를 포함하는 수지 조성물

Family Cites Families (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2465319A (en) 1941-07-29 1949-03-22 Du Pont Polymeric linear terephthalic esters
BE592181A (de) 1955-12-22
US2891930A (en) 1957-03-25 1959-06-23 Eastman Kodak Co Fiber-forming polyesters from trans-1, 4-cyclohexanedicarboxylic compounds and 1, 1-cyclohexane dimethanol
NL285283A (de) 1961-11-10
US4349469A (en) 1981-02-17 1982-09-14 Eastman Kodak Company Copolyesterethers
US4897453A (en) 1988-07-29 1990-01-30 Eastman Kodak Company Compatible blends of polyester-ethers and polycarbonates
US5486562A (en) 1990-07-12 1996-01-23 General Electric Company Modifications of poly(alkylene cyclohexanedicarboxylate) blends
US5399661A (en) 1990-07-12 1995-03-21 General Electric Company Poly(alkylene cyclohexanedicarboxylate)-(alkylene terephthalate) copolyesters
US5231218A (en) 1992-10-23 1993-07-27 Eastman Kodak Company Isomerization of dimethylcyclohexanedicarboxylate
US5453479A (en) 1993-07-12 1995-09-26 General Electric Company Polyesterification catalyst
US5498668A (en) 1994-10-31 1996-03-12 Eastman Chemical Company Blends of certain polyesters with acrylics
TW381104B (en) * 1996-02-20 2000-02-01 Eastman Chem Co Process for preparing copolyesters of terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol
US5907026A (en) 1997-08-27 1999-05-25 General Electric Company Polycarbonate compositions comprising polyester resins and ultraviolet light absorbers
SG70651A1 (en) 1997-09-15 2000-02-22 Gen Electric Aliphatic polyester-acrylic blend molding composition having good ductility and weatherability
US5939519A (en) 1998-05-11 1999-08-17 General Electric Co. Polyesteramides of high crystallinity and reagents for their preparation
US5986040A (en) 1998-09-03 1999-11-16 General Electric Company Crystalline polyester resins and process for their preparation
US6084055A (en) 1999-03-30 2000-07-04 General Electric Company Method for preparing poly(1,4-cyclohexanedicarboxylates)

Also Published As

Publication number Publication date
WO2002031020A3 (en) 2002-06-20
DE60115684T2 (de) 2006-06-22
CN1468272A (zh) 2004-01-14
ATE312128T1 (de) 2005-12-15
EP1325055B1 (de) 2005-12-07
JP4125591B2 (ja) 2008-07-30
US20020132963A1 (en) 2002-09-19
US6458915B1 (en) 2002-10-01
EP1325055A2 (de) 2003-07-09
BR0113910A (pt) 2003-07-22
JP2004511594A (ja) 2004-04-15
WO2002031020A2 (en) 2002-04-18
MXPA03002877A (es) 2003-07-14
CN1217973C (zh) 2005-09-07

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