DE4432081A1 - Radiation welding of thermoplastics and non melting materials using laser light - Google Patents

Radiation welding of thermoplastics and non melting materials using laser light

Info

Publication number
DE4432081A1
DE4432081A1 DE4432081A DE4432081A DE4432081A1 DE 4432081 A1 DE4432081 A1 DE 4432081A1 DE 4432081 A DE4432081 A DE 4432081A DE 4432081 A DE4432081 A DE 4432081A DE 4432081 A1 DE4432081 A1 DE 4432081A1
Authority
DE
Germany
Prior art keywords
welding
radiation
parts
energy
thermoplastics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
DE4432081A
Other languages
German (de)
Inventor
Martin Welz
Roland Roos
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Priority to DE4432081A priority Critical patent/DE4432081A1/en
Publication of DE4432081A1 publication Critical patent/DE4432081A1/en
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/82Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps
    • B29C66/826Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps without using a separate pressure application tool, e.g. the own weight of the parts to be joined
    • B29C66/8264Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps without using a separate pressure application tool, e.g. the own weight of the parts to be joined using the thermal expansion of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16Laser beams
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16Laser beams
    • B29C65/1629Laser beams characterised by the way of heating the interface
    • B29C65/1635Laser beams characterised by the way of heating the interface at least passing through one of the parts to be joined, i.e. laser transmission welding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/56Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using mechanical means or mechanical connections, e.g. form-fits
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/56Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor using mechanical means or mechanical connections, e.g. form-fits
    • B29C65/58Snap connection
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/72Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by combined operations or combined techniques, e.g. welding and stitching
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/11Joint cross-sections comprising a single joint-segment, i.e. one of the parts to be joined comprising a single joint-segment in the joint cross-section
    • B29C66/114Single butt joints
    • B29C66/1142Single butt to butt joints
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/122Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
    • B29C66/1222Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a lapped joint-segment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/05Particular design of joint configurations
    • B29C66/10Particular design of joint configurations particular design of the joint cross-sections
    • B29C66/12Joint cross-sections combining only two joint-segments; Tongue and groove joints; Tenon and mortise joints; Stepped joint cross-sections
    • B29C66/122Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section
    • B29C66/1224Joint cross-sections combining only two joint-segments, i.e. one of the parts to be joined comprising only two joint-segments in the joint cross-section comprising at least a butt joint-segment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/32Measures for keeping the burr form under control; Avoiding burr formation; Shaping the burr
    • B29C66/324Avoiding burr formation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/01General aspects dealing with the joint area or with the area to be joined
    • B29C66/342Preventing air-inclusions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/51Joining tubular articles, profiled elements or bars; Joining single elements to tubular articles, hollow articles or bars; Joining several hollow-preforms to form hollow or tubular articles
    • B29C66/53Joining single elements to tubular articles, hollow articles or bars
    • B29C66/534Joining single elements to open ends of tubular or hollow articles or to the ends of bars
    • B29C66/5346Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat
    • B29C66/53461Joining single elements to open ends of tubular or hollow articles or to the ends of bars said single elements being substantially flat joining substantially flat covers and/or substantially flat bottoms to open ends of container bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/50General aspects of joining tubular articles; General aspects of joining long products, i.e. bars or profiled elements; General aspects of joining single elements to tubular articles, hollow articles or bars; General aspects of joining several hollow-preforms to form hollow or tubular articles
    • B29C66/61Joining from or joining on the inside
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/73General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/739General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset
    • B29C66/7392General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic
    • B29C66/73921General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the intensive physical properties of the material of the parts to be joined, by the optical properties of the material of the parts to be joined, by the extensive physical properties of the parts to be joined, by the state of the material of the parts to be joined or by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of the parts to be joined being a thermoplastic or a thermoset characterised by the material of at least one of the parts being a thermoplastic characterised by the materials of both parts being thermoplastics
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/82Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps
    • B29C66/826Pressure application arrangements, e.g. transmission or actuating mechanisms for joining tools or clamps without using a separate pressure application tool, e.g. the own weight of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/1403Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation characterised by the type of electromagnetic or particle radiation
    • B29C65/1412Infrared [IR] radiation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16Laser beams
    • B29C65/1603Laser beams characterised by the type of electromagnetic radiation
    • B29C65/1612Infrared [IR] radiation, e.g. by infrared lasers
    • B29C65/1616Near infrared radiation [NIR], e.g. by YAG lasers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16Laser beams
    • B29C65/1603Laser beams characterised by the type of electromagnetic radiation
    • B29C65/1612Infrared [IR] radiation, e.g. by infrared lasers
    • B29C65/1619Mid infrared radiation [MIR], e.g. by CO or CO2 lasers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16Laser beams
    • B29C65/1629Laser beams characterised by the way of heating the interface
    • B29C65/1648Laser beams characterised by the way of heating the interface radiating the edges of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C65/00Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor
    • B29C65/02Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure
    • B29C65/14Joining or sealing of preformed parts, e.g. welding of plastics materials; Apparatus therefor by heating, with or without pressure using wave energy, i.e. electromagnetic radiation, or particle radiation
    • B29C65/16Laser beams
    • B29C65/1677Laser beams making use of an absorber or impact modifier
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/70General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material
    • B29C66/71General aspects of processes or apparatus for joining preformed parts characterised by the composition, physical properties or the structure of the material of the parts to be joined; Joining with non-plastics material characterised by the composition of the plastics material of the parts to be joined
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C66/00General aspects of processes or apparatus for joining preformed parts
    • B29C66/80General aspects of machine operations or constructions and parts thereof
    • B29C66/84Specific machine types or machines suitable for specific applications
    • B29C66/863Robotised, e.g. mounted on a robot arm
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2023/00Use of polyalkenes or derivatives thereof as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2033/00Use of polymers of unsaturated acids or derivatives thereof as moulding material
    • B29K2033/04Polymers of esters
    • B29K2033/12Polymers of methacrylic acid esters, e.g. PMMA, i.e. polymethylmethacrylate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/003PET, i.e. poylethylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2067/00Use of polyesters or derivatives thereof, as moulding material
    • B29K2067/006PBT, i.e. polybutylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2077/00Use of PA, i.e. polyamides, e.g. polyesteramides or derivatives thereof, as moulding material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2081/00Use of polymers having sulfur, with or without nitrogen, oxygen or carbon only, in the main chain, as moulding material
    • B29K2081/06PSU, i.e. polysulfones; PES, i.e. polyethersulfones or derivatives thereof

Abstract

The parts to be connected are first interlocked or held together by internal stresses, locked into the correct end position, to bring the joint surfaces into contact. They are then irradiated to melt them together, and the bond is cooled. Blunt contacting surfaces may be joined, avoiding irradiation of surrounding edge regions. Laser light with a wavelength between 0.5 and 10.90 mu m, pref. between 0.70 and 10.64 mu m is used. To weld non-thermoplastics, their joining surfaces are coated with thermoplastic.

Description

Die Erfindung betrifft ein Verfahren zum Schweißverbinden von Kunststoffteilen mit Hilfe von Strahlungsenergie.The invention relates to a method for welding joining of Plastic parts using radiation energy.

Formteile aus thermoplastischen Kunststoffen können nach unter­ schiedlichen Schweißverfahren miteinander verbunden werden, wobei für das Aufschmelzen der Fügeflächen viele Energiearten einge­ setzt werden, z. B. Warmgas, IR-Strahlung, beheizte Platten oder Formteile, Reibung durch Rotation oder Vibration, Ultraschall und hochfrequente elektromagnetische Felder.Molded parts made of thermoplastics can be found under different welding processes are connected to each other, whereby many types of energy are used to melt the joining surfaces be set, e.g. B. warm gas, IR radiation, heated plates or Molded parts, friction by rotation or vibration, ultrasound and high-frequency electromagnetic fields.

Für die Serienfertigung von kleinen Formteilen bis etwa 150 mm Durchmesser, wird bevorzugt das Ultraschallschweißverfahren ein­ gesetzt, da es mit Schweißzeiten unter einer Sekunde sehr wirt­ schaftlich arbeitet. Bei größeren Formteilen wird das Vibrations­ schweißverfahren mit Schweißzeiten von wenigen Sekunden bevor­ zugt. Das Rotationsreibschweißverfahren ist auf rotationssymmetrische Teile beschränkt, und das Heizelementschweißen benötigt lange Aufheizzeiten.For the series production of small molded parts up to approximately 150 mm Diameter, the ultrasonic welding process is preferred set because it is very economical with welding times of less than one second works economically. With larger molded parts, the vibration welding process with welding times of a few seconds before moves. The rotary friction welding process is based on rotationally symmetrical Parts limited, and heating element welding required long heating times.

Die genannten Schweißverfahren benötigen spezielle, zum Teil sehr aufwendige Werkzeuge für die Fixierung und ggf. auch zur Ener­ gieeinbringung, z. B. Heizelemente, Sonotroden usw., da ins­ besondere bei den Reibschweißverfahren hohe Kräfte aufgebracht werden müssen. Beim Ultraschallschweißen und beim Vibrations­ schweißen werden zusätzlich die Teile und gegebenenfalls darin enthaltene Funktionsteile, z. B. Elektronik durch hohe Beschleuni­ gungskräfte belastet und möglicherweise beschädigt. Beim Heizele­ mentschweißen ist eine Schädigung durch Wärmestrahlung oder Kon­ vektion oft nicht auszuschließen.The welding processes mentioned require special, sometimes very much elaborate tools for fixation and if necessary also for energy pouring, e.g. B. heating elements, sonotrodes etc., because ins high forces applied especially in the friction welding process Need to become. For ultrasonic welding and vibration will also weld the parts and, if necessary, in them included functional parts, e.g. B. Electronics through high acceleration forces and possibly damaged. With Heizele Mental welding is damage from heat radiation or con vection often cannot be excluded.

Vorliegender Erfindung liegt dementsprechend die Aufgabe zu­ grunde, ein Verfahren zum Schweißverbinden von Kunststoffteilen mit Hilfe von Strahlungsenergie zu entwickeln, welches ohne Vor­ richtungen zur Fixierung der zu verbindenden Teile und ohne auf­ wendige Einrichtungen zum Einbringen der Schweißenergie auskommt.The present invention is accordingly the task reasons, a process for welding plastic parts to develop with the help of radiation energy, which without any directions for fixing the parts to be connected and without manoeuvrable facilities for introducing welding energy.

Die Lösung der Aufgabe besteht in einem Verfahren der genannten Art, bei dem gemäß der Erfindung die zu verbindenden Teile zuerst durch Formschluß oder inneren Kraftschluß in der richtigen End­ lage miteinander fixiert und die Fügeflächen dabei in Kontakt ge­ bracht und anschließend mit Strahlungsenergie beaufschlagt wer­ den.The solution to the problem is a method of the above Type in which according to the invention the parts to be connected first by positive locking or internal frictional connection in the right end fixed to each other and the joining surfaces in contact  brought and then exposed to radiation energy the.

Weitere Einzelheiten und Vorteile des Verfahrens nach der Erfin­ dung sind anhand in der Zeichnung schematisch dargestellter Aus­ führungsbeispiele nachfolgend beschrieben.Further details and advantages of the process according to the inven tion are shown schematically in the drawing from management examples described below.

Es zeigenShow it

Fig. 1 eine formschlüssige Fixierung der zu verbindenden Füge­ teile und Beaufschlagung mit Strahlungsenergie Fig. 1 is a positive fixation of the joint to be joined parts and exposure to radiation energy

Fig. 2 das Verbinden stumpf aufeinander stoßender Fügeflächen mittels Strahlungsenergie. Fig. 2 the connection of butt joint surfaces by means of radiation energy.

Das Verbinden von Formteilen aus Thermoplasten durch Schweißen mit energiereicher Strahlung ist einfach auszuführen, wenn ein Fügeteil 1 (Fig. 1) aus Strahlung gut absorbierendem und das zweite 2 aus Strahlung zumindest teilweise durchlässigem aber mit dem ersten Teil gut verschweißbarem Material besteht.The joining of molded parts made of thermoplastics by welding with high-energy radiation is easy to carry out if one joining part 1 ( FIG. 1) consists of radiation-absorbing material and the second 2 consists of radiation which is at least partially transparent but can be welded well to the first part.

Durch die energiereiche Strahlung 3, beispielsweise Laserstrah­ len, die durch das durchlässige bzw. teildurchlässige Fügeteil auf die Fügefläche 4 des absorbierenden Fügeteils 1 dringt, wird letztere aufgeschmolzen und erwärmt auch die Fügefläche des nicht absorbierenden Teils 2, da die Schmelze - bedingt durch die Aus­ dehnung auf ein größeres Volumen - auch in der Lage ist, kleinere Spalte zu überbrücken. So wird bei Erzeugung eines ausreichenden Schmelzevolumens ein Schweißdruck von innen aufgebaut. Bei Abküh­ lung der Teile baut sich dieser Druck wieder ab.Due to the high-energy radiation 3 , for example laser beams which penetrate through the permeable or partially transparent joining part onto the joining surface 4 of the absorbent joining part 1 , the latter is melted and also heats the joining surface of the non-absorbing part 2 , since the melt - due to the out expansion to a larger volume - is also able to bridge smaller gaps. Thus, when generating a sufficient melt volume, a welding pressure is built up from the inside. When the parts cool down, this pressure is reduced again.

Beim Schweißen mit energiereichen Strahlen wird im Gegensatz zu anderen Schweißverfahren, wie Vibration oder Ultraschall, nur ein kleiner Bereich der Fügezone aufgeschmolzen (Fig. 2), die restli­ che Fügezone wirkt dabei als Abstandshalter, die die von außen aufgebrachte Schweißkraft abfängt. Es ist daher wichtig, daß keine Schmelze durch Austrieb verloren geht, damit beim Abkühlen keine Vakuolen oder Eigenspannungen durch Schrumpfung entstehen.When welding with high-energy beams, in contrast to other welding methods, such as vibration or ultrasound, only a small area of the joining zone is melted ( Fig. 2), the remaining joining zone acts as a spacer that absorbs the welding force applied from the outside. It is therefore important that no melt is lost due to flashing, so that no vacuoles or internal stresses due to shrinkage occur during cooling.

Ferner ist die Vermeidung von Schmelzeaustrieb hinsichtlich des Aussehens und der Funktion der Formteile von großem Vorteil und erspart eine sonst notwendige Nacharbeit. Konstruktive Maßnahmen, wie sie zum Verdecken des Austriebs erforderlich sind, können so­ mit entfallen. Beispielsweise wird bei stumpf aufeinanderstoßen­ den Fügeflächen nach allen Seiten ein von der Energiestrahlung nicht beaufschlagter Randbereich 5 (Fig. 2) eingehalten. Furthermore, the avoidance of melt expulsion is of great advantage with regard to the appearance and function of the molded parts and saves any rework that would otherwise be necessary. Constructive measures, such as are necessary to cover the shoots, can also be omitted. For example, if the joining surfaces abut each other on all sides, an edge region 5 ( FIG. 2) not acted upon by the energy radiation is observed.

Das gegenseitige Fixieren der Fügeteile 1 und 2 erfolgt erfindungsgemäß durch Formschluß, z. B. durch Einrastverbindungen oder Gewinde oder inneren Kraftschluß, wie Verschraubungen oder Magnete. Diese Fixierung braucht nur so dimensioniert werden, daß der örtlich entstehende Schweißdruck, der sich mit der Strahlfüh­ rung entlang der Nahtkontur bewegt, aufgenommen wird. Die Teile können dann, beispielsweise von einem Roboter, so geführt werden, daß die Schweißnahtkontur vom energiereichen Strahl immer frei erreichbar ist. Eine von außen aufzubringende Fixierung würde beide Fügeteile erfassen und daher die Strahlführung erheblich behindern und die Teile mechanisch belasten. Die Relativgeschwin­ digkeit zwischen Schweißstrahl und der zu schweißenden Naht, die Vorschubgeschwindigkeit also, hängt vom Material und dessen Wand­ stärke sowie von der Nahtbreite und der Strahlleistung ab und liegt gewöhnlich zwischen 0,5 und 10 m/min.The mutual fixing of the joining parts 1 and 2 takes place according to the invention by positive locking, z. B. by snap connections or threads or internal frictional connection, such as screw connections or magnets. This fixation only needs to be dimensioned so that the locally occurring welding pressure, which moves along the seam contour with the beam guide, is absorbed. The parts can then be guided, for example by a robot, in such a way that the weld seam contour is always freely accessible from the high-energy beam. A fixation to be applied from the outside would grip both parts to be joined and would therefore considerably impede the beam guidance and mechanically stress the parts. The Relativgeschwin speed between the welding beam and the seam to be welded, i.e. the feed rate, depends on the material and its wall thickness as well as on the seam width and the beam power and is usually between 0.5 and 10 m / min.

Für das Schweißen mit energiereichen Strahlen sind fast alle Thermoplaste geeignet. Die Durchlässigkeit bzw. Absorption der Strahlung ist sowohl vom Thermoplasttyp und den Zusätzen, wie Füllstoffe und Pigmente als auch von der Wellenlänge und Energie­ dichte der eingesetzten Strahlen abhängig. Zum Verbinden von nichtthermoplastischen Fügeteilen können diese mit thermoplastischen Beschichtungen an den Fügeflächen versehen wer­ den.Almost everyone is for welding with high-energy beams Suitable for thermoplastics. The permeability or absorption of the Radiation is both of the thermoplastic type and the additives, such as Fillers and pigments as well as wavelength and energy density of the rays used. To connect non-thermoplastic joining parts can do this with thermoplastic coatings on the joining surfaces the.

Für das erfindungsgemäße Schweißverfahren und die dafür bevorzugt eingesetzten Strahlen eines Nd:YAG - Lasers sind als durchlässige oder teildurchlässige Thermoplaste insbesondere geeignet:
Polyolefine, Polyamide, Polyformaldehyd, PMMA, PBT, PET. Weiter­ hin sind auch Styrolpolymere und -copolymere, Polysulfone u. a. geeignet.
For the welding process according to the invention and the beams of an Nd: YAG laser that are preferably used for this purpose, the following are particularly suitable as permeable or partially permeable thermoplastics:
Polyolefins, polyamides, polyformaldehyde, PMMA, PBT, PET. Styrene polymers and copolymers, polysulfones and others are also suitable.

Die erforderliche Strahlenabsorption von Thermoplasten ist durch verschiedene Zusätze auf die gewünschte Strahleindringtiefe ein­ stellbar. Dabei haben sich die verschiedensten Farbmittel, ins­ besondere aber Ruß oder Nigrosin in einer Konzentration von 0,01 bis 0,10% bewährt.The required radiation absorption of thermoplastics is through various additives to the desired penetration depth adjustable. The most diverse colorants, ins especially soot or nigrosine in a concentration of 0.01 proven to 0.10%.

Andere Zusätze, beispielsweise Glasfasern, Glaskugeln und andere Füllstoffe, erhöhen zwar die Streuung der Strahlung in den Teilen und verkleinern damit die Eindringtiefe, verhindern aber nicht vollständig die Durchdringung, so daß auch derartige Materialien für zu durchstrahlende Teile bedingt geeignet sind. Auch diese gefüllten Thermoplaste sind durch spezielle Zusätze so einstell­ bar, daß sie die energiereiche Strahlung in der Oberfläche absor­ bieren.Other additives, for example glass fibers, glass balls and others Fillers increase the scatter of radiation in the parts and reduce the depth of penetration, but do not prevent completely penetration, so that even such materials are conditionally suitable for parts to be irradiated. This too filled thermoplastics can be adjusted using special additives  bar that they absorbed the high-energy radiation in the surface beers.

Als energiereiche Strahlung werden Laserstrahlen beispielsweise einer Wellenlänge zwischen 0,50 und 10,90 µm, vorzugsweise zwi­ schen 0,70 und 3 µm eingesetzt. Die Erzeugung der Strahlung und deren Eigenschaften sind in der einschlägigen Literatur beschrie­ ben. Dabei sind alle Laserquellen einzusetzen, die Thermoplaste erwärmen können, insbesondere Laser, die im Infrarotbereich emittieren. Bevorzugt wird für das Schweißen von Thermoplasten der Nd:YAG - Laser eingesetzt, für viele Anwendungen ist aber auch der CO₂-Laser geeignet.Laser beams are used as high-energy radiation, for example a wavelength between 0.50 and 10.90 microns, preferably between between 0.70 and 3 µm. The generation of radiation and their properties are described in the relevant literature ben. All laser sources must be used, the thermoplastics can heat, especially lasers in the infrared range emit. It is preferred for welding thermoplastics the Nd: YAG laser is used, but for many applications the CO₂ laser is also suitable.

Bei einer Kombination von Fügeteilen aus nicht absorbierendem und absorbierendem Material wird die Fügefläche des absorbierenden Unterteils durch das Oberteil hindurch bestrahlt und durch die Absorption in der Oberfläche aufgeheizt und aufgeschmolzen. Dabei ist es von Vorteil, wenn der Einfallswinkel α möglichst klein ist, um Verluste durch Reflexion gering zu halten.With a combination of non-absorbent and absorbent material becomes the joining surface of the absorbent Irradiated lower part through the upper part and through the Absorption in the surface heated and melted. Here it is advantageous if the angle of incidence α is as small as possible is to minimize losses due to reflection.

Beim Verschweißen von Fügeteilen aus stark absorbierenden Mate­ rialien und bei Stumpfschweißnähten ist auch eine Bestrahlung in der Schweißebene möglich. Die Nahtbreite entspricht dann der Ein­ dringtiefe des Strahles.When welding joining parts made of highly absorbent mate rialien and with butt welds is also a radiation in the welding plane possible. The seam width then corresponds to the on penetration depth of the beam.

Claims (4)

1. Verfahren zum Schweißverbinden von Kunststoffteilen mit Hilfe von Strahlungsenergie, dadurch gekennzeichnet, daß die zu verbindenden Teile zuerst durch Formschluß oder inneren Kraftschluß in der richtigen Endlage miteinander fixiert und die Fügeflächen dabei in Kontakt gebracht und anschließend so lange mit Strahlungsenergie beaufschlagt werden, bis in der vorgesehenen Schweißzone die Kunststoffteile aufgeschmolzen sind, sich dabei verbinden, und die auf diese Weise verbunde­ nen Kunststoffmaterialien durch Abkühlen verfestigt werden.1. A method for welding plastic parts with the aid of radiation energy, characterized in that the parts to be connected are first fixed to one another in the correct end position by positive locking or internal frictional connection and the joining surfaces are brought into contact and then exposed to radiation energy until in the intended welding zone, the plastic parts are melted, thereby joining, and the plastic materials connected in this way are solidified by cooling. 2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß bei stumpf aufeinander stoßenden Fügeflächen nach allen Seiten ein von der Energiestrahlung nicht beaufschlagter Randbereich eingehalten wird.2. The method according to claim 1, characterized in that at butt joint surfaces on all sides an edge area not affected by the energy radiation is observed. 3. Verfahren nach Anspruch 1 und 2, dadurch gekennzeichnet, daß als Energiestrahlung Laserstrahlen einer Wellenlänge zwischen 0,50 und 10,90 µm, vorzugsweise zwischen 0,70 und 10,64 µm eingesetzt werden.3. The method according to claim 1 and 2, characterized in that as energy radiation laser beams of a wavelength between 0.50 and 10.90 µm, preferably between 0.70 and 10.64 µm be used. 4. Verfahren nach Anspruch 1 bis 3, dadurch gekennzeichnet, daß zum Schweißverbinden von nichtthermoplastischen Kunststoff­ teilen diese an den Fügeflächen mit thermoplastischem Kunst­ stoffmaterial beschichtet werden.4. The method according to claim 1 to 3, characterized in that for welding non-thermoplastic plastic divide these on the joining surfaces with thermoplastic art be coated material.
DE4432081A 1994-09-09 1994-09-09 Radiation welding of thermoplastics and non melting materials using laser light Ceased DE4432081A1 (en)

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US10200516B2 (en) 2014-08-28 2019-02-05 Apple Inc. Interlocking ceramic and optical members
WO2016092208A1 (en) * 2014-12-11 2016-06-16 Arkema France Black polymer composition suitable for laser welding
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DE102015109183A1 (en) 2015-06-10 2016-12-15 Fachhochschule Schmalkalden Method for joining two joining partners made of plastic
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