DE4138214A1 - Metallisation of aluminium nitride ceramic - involves ceramic treatment to remove glass surface film - Google Patents
Metallisation of aluminium nitride ceramic - involves ceramic treatment to remove glass surface filmInfo
- Publication number
- DE4138214A1 DE4138214A1 DE19914138214 DE4138214A DE4138214A1 DE 4138214 A1 DE4138214 A1 DE 4138214A1 DE 19914138214 DE19914138214 DE 19914138214 DE 4138214 A DE4138214 A DE 4138214A DE 4138214 A1 DE4138214 A1 DE 4138214A1
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- ceramic
- ceramic surface
- treatment
- chemical
- metallization
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1851—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
- C23C18/1855—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by mechanical pretreatment, e.g. grinding, sanding
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1851—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
- C23C18/1862—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by radiant energy
- C23C18/1865—Heat
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1851—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
- C23C18/1872—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by chemical pretreatment
- C23C18/1886—Multistep pretreatment
- C23C18/1893—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
Abstract
Description
Die Erfindung betrifft ein Verfahren zur haftfesten Metal lisierung von Aluminiumnitridkeramik gemäß dem Oberbegriff des Patentanspruchs 1. Die Erfindung betrifft insbesondere AlN-Keramikteile, die aufgrund ihrer Herstellungstechnik eine Art Oberflächenglasur besitzen und in metallisierter Form als Substrate für hochintegrierte Logikschaltungen und für die Leistungselektronik eingesetzt werden.The invention relates to a method for adherent metal lization of aluminum nitride ceramics according to the generic term of claim 1. The invention relates in particular AlN ceramic parts, due to their manufacturing technology have a kind of surface glaze and in metallized Form as substrates for highly integrated logic circuits and be used for power electronics.
Die Metallisierung von Keramikteilen dient ganz allgemein der Veränderung, der Verbesserung oder der Vermehrung funktioneller Eigenschaften wie z. B. der elektrischen Leitfähigkeit oder der Wärmeleitfähigkeit, der Korrosionsbeständigkeit, der mechanischen Beständigkeit oder der Kontaktierbarkeit. Von zentraler Bedeutung ist dabei die Haftfestigkeit zwischen dem relativ spröden Ke ramikmaterial mit geringer thermischer Ausdehnung und dem relativ duktilen Metall mit höherer thermischer Ausdeh nung. Um eine ausreichend hohe Haftfestigkeit auch bei Lötprozessen und hohen Betriebstemperaturen der fertigen Bauteile zu gewährleisten, müssen Haftmechanismen auf starken chemischen Bindungen und/oder starken und zahlrei chen mechanischen Verzahnungen bzw. Verankerungen beruhen.The metallization of ceramic parts serves in general the change, the improvement or the increase functional properties such as B. the electrical Conductivity or thermal conductivity, the Corrosion resistance, mechanical resistance or the contactability. It is central the adhesive strength between the relatively brittle Ke ceramic material with low thermal expansion and relatively ductile metal with higher thermal expansion nung. To ensure a sufficiently high adhesive strength also Soldering processes and high operating temperatures of the finished To ensure components, adhesive mechanisms must be in place strong chemical bonds and / or strong and numerous Chen mechanical gears or anchorages are based.
Es hat nicht an Versuchen gefehlt, in Analogie zur Alumi niumoxidkeramik, Metallisierungsverfahren für AlN-Keramik zu entwickeln. Neben den klassischen Dünnfilmaufdampf-, Sputter- und Dickschichttechniken sind dies z. B. auch Ein brennmetallisierungen auf der Basis Molybdän, Wolfram oder Tantal (siehe EP-A- 02 35 682), Metallisierung einer künstlich erzeugten Haftvermittlerschicht aus Aluminiumo xid (DE-OS 38 44 264) sowie chemogalvanische Metallisie rung nach einer ätzenden Vorbehandlung der AlN-Keramik (DE-PS 38 14 224, DE-OS 36 39 642).There was no lack of attempts, analogous to the Alumi nium oxide ceramics, metallization process for AlN ceramics to develop. In addition to the classic thin film evaporation, Sputtering and thick film techniques are e.g. B. also A Firing metallizations based on molybdenum, tungsten or Tantalum (see EP-A-02 35 682), metallization of a Artificially created adhesive layer made of aluminum xid (DE-OS 38 44 264) and chemogalvanische Metallisie after a caustic pretreatment of the AlN ceramic (DE-PS 38 14 224, DE-OS 36 39 642).
Diese bekannten Verfahren sind im allgemeinen auf be stimmte Anwendungsfälle und spezielle Materialkombinatio nen beschränkt. Zur Erzielung einer guten Haftung müssen besondere Haftvermittler abgeschieden werden, die immer aus einem anderen Material als die zu beschichtenden Kör per und die gewünschte Beschichtung bestehen, so daß zwangsläufig neue, oft unpassende Eigenschaften auftreten oder daß eine massive Verschlechterung erwünschter Eigen schaften erfolgt. So verringern haftvermittelnde Zwischen schichten z. B. die hervorragende Wärmeleitfähigkeit der AlN-Keramik zur Metallauflage ganz erheblich. Eine zuver lässige Wärmeableitung von Hochleistungsbauelementen ist jedoch nur bei einer direkten Metallisierung des AlN-Kera miksubstrates möglich.These known methods are generally based on agreed use cases and special material combination limited. To achieve good liability special bonding agents that are always deposited made of a different material than the body to be coated per and the desired coating, so that inevitably new, often inappropriate properties occur or that a massive deterioration of desired property is done. So reduce adhesion mediators layers e.g. B. the excellent thermal conductivity of the AlN ceramics for the metal support quite considerably. One reliable is casual heat dissipation from high-performance components however only with direct metallization of the AlN-Kera micro substrates possible.
Eine direkte Metallisierung mit z. B. Nickel oder Kupfer ist auf chemogalvanischem Wege möglich, führt jedoch auch bei saurer und/oder alkalischer Vorbehandlung der AlN-Ke ramik zu sehr unzuverlässigen Haftfestigkeiten. Insbeson dere in sogenannter Trockenpreßtechnik und erst recht in der noch wirtschaftlicheren Foliengießtechnik hergestellte AlN-Keramikteile haben stark wechselnde Zusammensetzungen und Dicken ihrer glasurähnlichen Oberflächenbereiche. Beim Sintern der "grünen Keramik" reichern sich die Sinter hilfsmittel (z. B. Y2O3 oder CaO) unterschiedlich stark auf der Keramikoberfläche an, so daß bei einer Vorbehandlung durch Ätzen extrem verschiedene Rauhigkeiten auf einer Substratseite, zwischen den Substratseiten und zwischen einzelnen Substraten auftreten. Das hat zur Folge, daß un abhängig vom Metallisierungsverfahren ebenso extreme Un terschiede bezüglich Auflösung und Kantenschärfe feiner Leiterzüge sowie von deren Haftfestigkeit auftreten.A direct metallization with e.g. B. nickel or copper is possible by electroplating, but leads to very unreliable adhesive strengths even with acidic and / or alkaline pretreatment of the AlN-Ke ceramic. In particular in so-called dry pressing technology and even more so in the even more economical film casting technology, AlN ceramic parts have strongly changing compositions and thicknesses of their glaze-like surface areas. When sintering the "green ceramic", the sintering aids (e.g. Y 2 O 3 or CaO) accumulate to different extents on the ceramic surface, so that when pretreated by etching, extremely different roughness on one side of the substrate, between the sides of the substrate and between individual substrates occur. The consequence of this is that, depending on the metallization process, there are also extreme differences with regard to resolution and sharpness of edges of fine conductor tracks and their adhesive strength.
Der Erfindung liegt die Aufgabe zugrunde, ein Verfahren zur Vorbehandlung von AlN-Keramikoberflächen für gleich mäßige und haftfeste chemogalvanische Metallisierungen an zugeben, das ohne Einsatz eines Haftvermittlers auskommt und bei geringer Aufrauhung der Keramikoberfläche die Her stellung von Feinleitern gestattet.The invention has for its object a method for the pretreatment of AlN ceramic surfaces for the same moderate and adhesive chemogalvanic metallizations admit that works without the use of an adhesion promoter and with little roughening of the ceramic surface the Her fine conductors permitted.
Die Aufgabe wird erfindungsgemäß gelöst durch die im kenn zeichnenden Teil des Patentanspruchs 1 angegebenen Merk male. Zweckmäßige Ausgestaltungen sind den Unteransprüchen zu entnehmen.The object is achieved by the in the kenn drawing part of claim 1 specified note times. Expedient configurations are the subclaims refer to.
Bei dem erfindungsgemäßen Verfahren wird in vorteilhafter Weise durch eine mechanische Einwirkung, z. B. Schleifen, Läppen, Polieren oder Sandstrahlen die auf der Keramiko berfläche befindliche Glashaut entfernt bzw. durchlöchert, so daß beispielsweise durch ein alkalisches Ätzmittel ein gleichmäßiger Ätzangriff auf alle an der Keramikoberfläche befindlichen AlN-Körner stattfindet. Außerdem ist von Vor teil, daß durch eine relativ langsame Abscheidung zu Be ginn der Metallisierung eine hohe Haftfestigkeit bzw. eine intensive Verankerung der Metallschicht erzielt wird. Wenn durch dieses Verfahren alle Poren und Spalten in der Kera mikoberfläche sorgfältig mit Metall gefüllt sind, wird in schnell abscheidenden galvanischen Bädern die Metall schicht verstärkt.The method according to the invention is advantageous Way by mechanical action, e.g. B. grinding, Lapping, polishing or sandblasting on the ceramic removed or perforated glass skin, so that, for example, by an alkaline etchant uniform etching attack on all on the ceramic surface located AlN grains takes place. Also is from before partly that by a relatively slow separation to Be a high level of adhesive strength or a intensive anchoring of the metal layer is achieved. If through this process all the pores and crevices in the kera surface is carefully filled with metal rapidly depositing galvanic baths the metal layer reinforced.
Die galvanische Abscheidung erfolgt durch eine erste alka lische, autokatalytische Abscheidung in einem Kupfer-Form aldehydbad oder in einem Nickel-Hypophosphitbad, sowie durch eine zweite galvanische Dickmetallisierung mit Kup fer in einem schwefelsauren Kupferbad.The galvanic deposition is carried out by a first alka Mechanical, autocatalytic deposition in a copper form aldehyde bath or in a nickel hypophosphite bath, as well through a second galvanic thick metallization with Kup fer in a sulfuric acid copper bath.
Die Erfindung wird anhand folgender Ausführungsbeispiele näher erläutert.The invention is based on the following exemplary embodiments explained in more detail.
Aluminiumnitridkeramiksubstrate (98% AlN), die in Trocken proezßtechnik hergestellt sind, haben Abmessungen von 1′′·1′′·0,635mm und eine gemittelte Rauhtiefe RZ von ca. 4 µm. Diese Substrate werden mittels eines motorgetriebenen Vor schubs mit 0,5 cm/s in einem Abstand von 6 cm unter einer Sandstrahldüse hindurchgefahren. Der Sandstrahl wird durch Korundteilchen (Al2O3-Körner < 50 µm) in einem Stickstoff strom mit 60 psi gebildet. Die Substrate werden an schließend in einem Neutralreiniger (Mukasol) bei Ultra schallunterstützung sowie in demineralisiertem Wasser ge spült. Nach einer Trocknung bei 125°C wird durch Rückwä gung eine Gewichtsabnahme von 0,36 mg/cm2 festgestellt. Die gemittelte Rauhigkeit RZ hat sich auf ca. 5,5 µm erhöht. Nach einer Ätzung in 1n-NaOH-Lösung bei 80°C für 15 min, Spülung in demineralisiertem Wasser mit Ultra schallunterstützung und Trocknung bei 125°C hat eine Ge wichtsabnahme der Substrate von 1,8 mg/cm2 stattgefunden. Die gemittelte Rauhtiefe RZ hat auf ca. 8 µm zugenommen. Nach der Erzeugung einer katalytischen Keimschicht gemäß dem bekannten Zinnchlorid-Palladiumchlorid-Verfahren wird aus einem handelsüblichen chemischen Kupfer-Formaldehydbad (Printoganth, Fa. Schering) eine erste Kupferschicht von ca 3 µm Dicke während 1,5 Stunden abgeschieden. Diese Schicht wird in einem galvanischen Kupfersulfatbad (Sloto coup Cu20, Fa. Schlötter) während 40 min auf ca. 20 µm ver stärkt. Zur Beurteilung der Haftfestigkeit werden ätztech nisch 1 mm breite Streifen erzeugt und in einer Zugprüfma schine deren Schälkräfte gemessen. Diese betragen an allen Substraten mindestens 0,8 N/mm.Aluminum nitride ceramic substrates (98% AlN), which are manufactured in dry process technology, have dimensions of 1 '' · 1 '' · 0.635mm and an average roughness depth R Z of approx. 4 µm. These substrates are moved by means of a motor-driven thrust at 0.5 cm / s at a distance of 6 cm under a sandblasting nozzle. The sandblast is formed by corundum particles (Al 2 O 3 grains <50 µm) in a nitrogen stream at 60 psi. The substrates are then rinsed in a neutral cleaner (Mukasol) with ultrasound support and in demineralized water. After drying at 125 ° C, a weight loss of 0.36 mg / cm 2 is found by reweighing. The average roughness R Z has increased to approximately 5.5 µm. After etching in 1N NaOH solution at 80 ° C for 15 min, rinsing in demineralized water with ultrasound support and drying at 125 ° C, the weight of the substrates decreased by 1.8 mg / cm 2 . The average roughness depth R Z has increased to approx. 8 µm. After the generation of a catalytic seed layer using the known tin chloride-palladium chloride process, a first copper layer of approximately 3 μm thick is deposited over a period of 1.5 hours from a commercially available chemical copper-formaldehyde bath (Printoganth, Schering). This layer is strengthened in a galvanic copper sulfate bath (Sloto coup Cu20, Schlötter) for 40 minutes to approx. 20 µm. To assess the adhesive strength, 1 mm wide strips are produced using etching technology and their peeling forces are measured in a tensile testing machine. These are at least 0.8 N / mm on all substrates.
Aluminiumnitridkeramiksubstrate, mit den gleichen Abmes sungen wie in Beispiel 1, die aber in Foliengießtechnik hergestellt sind, haben eine gemittelte Rauhtiefe von ca. 2,3 µm. Diese Substrate werden wie in Beispiel 1 in einer Sandstrahlanlage, aber mit Siliciumcarbidpulver der Kör nung < 29 µm, behandelt. Die Substrate werden anschließend in siedendem Wasser für 12 min gereinigt und dann in demi neralisiertem Wasser nachgespült. Nach einer Trocknung bei 125°C wird durch Rückwägung eine Gewichtsabnahme von 0,45 mg/cm2 festgestellt. Die gemittelte Rauhtiefe RZ hat auf ca. 2,9 µm zugenommen. Nach einer Ätzung in 1n-NaOH-Lö sung bei 65°C für 30 min, Spülung und Trocknung wie in Bei spiel 1, hat eine Gewichtsabnahme von 1,6 mg/cm2 stattge funden und die gemittelte Rauhtiefe RZ hat auf 4,2 µm zu genommen. Nach der Erzeugung der katalytischen Keimschicht (wie in Beispiel 1) wird aus einem alkalischen Nickel-Hy pophosphitbad bei einem pH-Wert von 9,5 in 2 Stunden eine ca 2 µm dicke Nickel-Phosphorschicht abgeschieden. Diese wird wie in Beispiel 1 mit Kupfer verstärkt und Schäl streifen erzeugt. An allen derartig beschichteten Substra ten werden Schälkräfte von mindestens 0,9 N/mm gemessen.Aluminum nitride ceramic substrates, with the same dimensions as in Example 1, but which are manufactured using the film casting technique, have an average roughness depth of approx. 2.3 µm. These substrates are treated in a sandblasting system as in Example 1, but with silicon carbide powder with a grain size of <29 μm. The substrates are then cleaned in boiling water for 12 minutes and then rinsed in demineralized water. After drying at 125 ° C, a weight loss of 0.45 mg / cm 2 is determined by reweighing. The average roughness depth R Z has increased to approx. 2.9 µm. After etching in 1N NaOH solution at 65 ° C for 30 min, rinsing and drying as in Example 1, a weight loss of 1.6 mg / cm 2 has taken place and the average roughness depth R Z has decreased to 4. 2 µm increased. After the catalytic seed layer has been produced (as in Example 1), an approximately 2 μm-thick nickel-phosphorus layer is deposited from an alkaline nickel hyphosphite bath at a pH of 9.5 in 2 hours. As in Example 1, this is reinforced with copper and peeling strips are produced. Peeling forces of at least 0.9 N / mm are measured on all substrates coated in this way.
Claims (10)
- - daß die Glashaut durch mechanische Vorbehandlung und eine Zwischenbehandlung entfernt oder durchlö chert wird,
- - daß durch eine chemische Nachbehandlung die Kera mikoberfläche fein aufgerauht wird, und
- - daß eine zweistufige Metallisierung der Keramiko berfläche derart erfolgt, daß Metallschicht und Keramikoberfläche haftfest miteinander verankert werden.
- - that the glass skin is removed or perforated by mechanical pretreatment and an intermediate treatment,
- - That the Kera mic surface is finely roughened by chemical aftertreatment, and
- - That a two-stage metallization of the ceramic surface takes place in such a way that the metal layer and the ceramic surface are firmly anchored to one another.
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DE19914138214 DE4138214A1 (en) | 1991-11-21 | 1991-11-21 | Metallisation of aluminium nitride ceramic - involves ceramic treatment to remove glass surface film |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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DE19833593A1 (en) * | 1998-07-25 | 2000-01-27 | Daimler Chrysler Ag | Selective metallization of e.g. ceramic, glass or plastic, e.g. for circuit board or electromagnetically screened housing, comprising mechanically depositing seeds on a rough substrate surface and then chemical plating |
DE19946195C1 (en) * | 1999-09-27 | 2001-04-05 | Epcos Ag | Removal of alumina particle layer sintered onto sintered multilayer ceramic substrate, employs two stages of dry grit blasting followed by electrostatic repulsion of submicron residue |
DE10147897C1 (en) * | 2001-09-28 | 2003-01-23 | Epcos Ag | Process for directly galvanizing contact layers onto ceramic components comprises activating the regions to be galvanized using an aqueous solution containing phosphoric acid, and applying the contact layers on the treated components |
EP2011779A1 (en) * | 2007-07-06 | 2009-01-07 | Vita Zahnfabrik H. Rauter GmbH & Co. KG | Ceramic body and method for its production |
EP3375767A1 (en) * | 2017-03-16 | 2018-09-19 | Infineon Technologies AG | Electrochemically robust ceramic substrates |
EP2543653B2 (en) † | 2011-07-04 | 2023-01-11 | Comadur S.A. | Method for manufacturing a matt ceramic |
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1991
- 1991-11-21 DE DE19914138214 patent/DE4138214A1/en not_active Ceased
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DE19833593A1 (en) * | 1998-07-25 | 2000-01-27 | Daimler Chrysler Ag | Selective metallization of e.g. ceramic, glass or plastic, e.g. for circuit board or electromagnetically screened housing, comprising mechanically depositing seeds on a rough substrate surface and then chemical plating |
DE19833593C2 (en) * | 1998-07-25 | 2002-03-14 | Daimler Chrysler Ag | Selective metallization process |
DE19946195C1 (en) * | 1999-09-27 | 2001-04-05 | Epcos Ag | Removal of alumina particle layer sintered onto sintered multilayer ceramic substrate, employs two stages of dry grit blasting followed by electrostatic repulsion of submicron residue |
DE10147897C1 (en) * | 2001-09-28 | 2003-01-23 | Epcos Ag | Process for directly galvanizing contact layers onto ceramic components comprises activating the regions to be galvanized using an aqueous solution containing phosphoric acid, and applying the contact layers on the treated components |
EP2011779A1 (en) * | 2007-07-06 | 2009-01-07 | Vita Zahnfabrik H. Rauter GmbH & Co. KG | Ceramic body and method for its production |
WO2009007338A1 (en) * | 2007-07-06 | 2009-01-15 | Vita Zahnfabrik H. Rauter Gmbh & Co. Kg | Ceramic body and process for the preparation thereof |
JP2010532305A (en) * | 2007-07-06 | 2010-10-07 | ビタ・ゼーンファブリク・ハー・ラウター・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング・ウント・コー・カーゲー | Ceramic body and manufacturing method thereof |
US8257606B2 (en) | 2007-07-06 | 2012-09-04 | Vita Zahnfabrik H. Rauter Gmbh & Co. Kg | Ceramic body and process for the preparation thereof |
EP3453693A1 (en) | 2007-07-06 | 2019-03-13 | VITA-ZAHNFABRIK H. Rauter GmbH & Co. KG | Ceramic body and process for the preparation thereof |
EP2543653B2 (en) † | 2011-07-04 | 2023-01-11 | Comadur S.A. | Method for manufacturing a matt ceramic |
EP3375767A1 (en) * | 2017-03-16 | 2018-09-19 | Infineon Technologies AG | Electrochemically robust ceramic substrates |
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