DE3316550A1 - Pigment-containing mixture - Google Patents

Pigment-containing mixture

Info

Publication number
DE3316550A1
DE3316550A1 DE19833316550 DE3316550A DE3316550A1 DE 3316550 A1 DE3316550 A1 DE 3316550A1 DE 19833316550 DE19833316550 DE 19833316550 DE 3316550 A DE3316550 A DE 3316550A DE 3316550 A1 DE3316550 A1 DE 3316550A1
Authority
DE
Germany
Prior art keywords
mixture according
weight
water
polyacrylate
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
DE19833316550
Other languages
German (de)
Other versions
DE3316550C2 (en
Inventor
Karl-Heinz Weinert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHEMULACK CHEMISCHE LACKFABRIK
Original Assignee
CHEMULACK CHEMISCHE LACKFABRIK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHEMULACK CHEMISCHE LACKFABRIK filed Critical CHEMULACK CHEMISCHE LACKFABRIK
Priority to DE3316550A priority Critical patent/DE3316550C2/en
Priority to DE19843440537 priority patent/DE3440537A1/en
Priority to DE3440534A priority patent/DE3440534A1/en
Priority to DE19843440535 priority patent/DE3440535A1/en
Publication of DE3316550A1 publication Critical patent/DE3316550A1/en
Application granted granted Critical
Publication of DE3316550C2 publication Critical patent/DE3316550C2/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D17/00—Pigment pastes, e.g. for mixing in paints
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2375/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2433/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04—Polyurethanes

Abstract

The invention relates to a pigment- and binder-containing mixture for priming plastics. The invention consists in that the binder is a water-dispersed aliphatic polyurethane and a water-dispersed polyacrylate. A mixture of this type does not attack plastic and is environmentally friendly.

Description

DIPL.-1 NQ. I)ItThR JANRER DR.-1 Ng. MAN I RH) IUfNINl)DIPL. -1 NQ. I) ItThR JANRER DR.-1 Ng. MAN I RH) IUfNINl)

PATtN f AN WAL I tPATtN f AN WAL I t

"Pigmenthaltige Mischung""Mixture containing pigments"

Die Erfindung "betrifft eine pigment- und bindemittelhaltige Mischung zum Grundieren von Kunststoffen.The invention "relates to a pigment and binder-containing Mixture for priming plastics.

Bisher hat man solche Mischungen zum Grundieren von Kunststoffen verwendet, die mit organischen Lösungsmitteln versetzt sind. Letztere wirken jedoch mehr oder weniger stark zerstörend auf die Kunststoffe ein. Hinzu kommt, daß das verdunstende Lösungsmittel umweltfeindlich ist.So far, such mixtures have been used for priming plastics that have been mixed with organic solvents are. However, the latter have a more or less destructive effect on the plastics. In addition, that evaporating solvents are harmful to the environment.

Der Erfindung liegt die Aufgabe zugrunde, eine Mischung der eingangs erwähnten Art zu schaffen, die einerseits den Kunst stoff nicht angreift und andererseits umweltfreundlich ist.The invention is based on the object of creating a mixture of the type mentioned at the outset which, on the one hand, is art does not attack the substance and on the other hand is environmentally friendly.

Diese Aufgabe wird erfindungsgemäß gelöst durch in Wasser dispergiertes, aliphatisches Polyurethan und in ¥asser dispergiertes Polyacrylat als Bindemittel.According to the invention, this object is achieved by aliphatic polyurethane dispersed in water and dispersed in water Polyacrylate as a binder.

Als Polyurethane und Polyacrylate kommen all jene Stoffe in Frage, die in Wasser dispergiert (als Dispersion oder Hydrosol) sind, oberhalb von O0C filmbildende Eigenschaften aufweisen, pigmentverträglich und lagerstabil sind und die reaktionsfähige Carboxylgruppen enthalten. Ferner müssen beide Produkte scherkraftstabil sein, um auf handelsüblichen Dispergiergeräten (z.B. Perlmühlen) verarbeitet werden zu können.Suitable polyurethanes and polyacrylates are all those substances which are dispersed in water (as a dispersion or hydrosol), have film-forming properties above 0 ° C., are pigment-compatible and storage-stable, and which contain reactive carboxyl groups. Furthermore, both products must be stable to shear force in order to be able to be processed on commercially available dispersing devices (e.g. bead mills).

Die Polyurethan-Dispersionen weisen bei einem Festkörpergehalt (Gew.-%) von 25-50 %, vorzugsweise 35-40 %, eine Konsistenz von < 1000 mPas, vorzugsweise 100-500 mPas, auf. Das Polyacrylat Hydrosol hat bei einem Festkörperanteil in Gew.-% von 35-55 %, vorzugsweise 45 %, eine Konsistenz von < 400 mPas, vorzugsweise <; 200 mPas.The polyurethane dispersions have a solids content (% by weight) of 25-50 %, preferably 35-40 %, a consistency of <1000 mPas, preferably 100-500 mPas. The polyacrylate hydrosol has a solids content in wt -% of 35-55%, preferably 45%, a consistency of <400 mPas, preferably <. 200 mPas.

4 -4 -

DIPL.-INQ. DItTtR JANDtR DR.-INQ. ΜΛΝΙ RtP BÜNINQDIPL.-INQ. DItTtR JANDtR DR.-INQ. ΜΛΝΙ RtP BÜNINQ

PAIENTANWALTfPAIENTANWALTF

Eine solche vollständig oder weitgehend von Lösungsmitteln organischer Art freie Mischung greift den Kunststoff, der mit der Mischung grundiert wird, nicht an. Hinzu kommt, daß die erfindungsgemäße Mischung keine Verunreinigung der Atmosphäre bewirken kann.Such a mixture, which is completely or largely free of organic solvents, attacks the plastic primed with the mixture does not apply. In addition, the mixture according to the invention does not pollute the atmosphere can cause.

Die erfindungsgemäße Mischung kann mit und ohne Härtungsbeschleuniger verwendet werden. Als Pigment können die sonst üblichen Pigmente eingesetzt werden. Alle üblichen Auftragsverfahren kommen auch für die erfindungsgemaße Mischung in Frage.The mixture according to the invention can be used with or without a curing accelerator be used. The otherwise customary pigments can be used as the pigment. All usual application processes are also suitable for the mixture according to the invention.

Claims (7)

DlPL-INg. DIETER JANDER DR.-INQ. MANFRED rATHNTANWAI.Tl· Ι-ιιιιΐ|ΐι;αη Ι'.Ίΐππ Aiiiiiik'vn KUKhUHSUNDAMM BB 1 HiKlIN Ib I i.-li-lmi ΙΙ.ΊΟ H 8.1 ΊΟ /1 I i!l»;q ι a IM mt. C υπ ·.· 'it! r () I inn Kr 887/19 282 DE 3. Mai 1983 Anmeldung der Firma CHEMULACK Chemische- und Lackfabrik G.m.b.H. & Co.KG. Goerzallee 303 1ooo Berlin 37 Ansprüche:DlPL-INg. DIETER JANDER DR.-INQ. MANFRED rATHNTANWAI.Tl · Ι-ιιιιΐ | ΐι; αη Ι'.Ίΐππ Aiiiiiik'vn KUKhUHSUNDAMM BB 1 HiKlIN Ib I i.-li-lmi ΙΙ.ΊΟ H 8.1 ΊΟ / 1 I i! L »; q ι a IM mt . C υπ ·. · 'It! r () I inn Kr 887/19 282 DE May 3, 1983 Registration of the company CHEMULACK Chemische- und Lackfabrik G.m.b.H. & Co.KG. Goerzallee 303 1ooo Berlin 37 Claims: 1. Pigment- und bindemittelhaltige Mischung zum Grundieren von Kunststoffen, gekennzeichnet durch in Wasser dispergiertes, aliphatisches Polyurethan und in Wasser dispergiertes Polyacrylat als Bindemittel.1. Mixture containing pigments and binders for priming of plastics, characterized by aliphatic polyurethane dispersed in water and in water dispersed polyacrylate as a binder. 2. Mischung nach Anspruch 1, dadurch gekennzeichnet, daß das Verhältnis von Polyurethan zu Polyacrylat im Festen zwischen 90;10 und 10:90, insbesondere zwischen 70:30 und 30:70 liegt, insbesondere 50:50 ist.2. Mixture according to claim 1, characterized in that that the ratio of polyurethane to polyacrylate in the solid is between 90; 10 and 10:90, in particular between 70:30 and 30:70, in particular 50:50. PoMn:lii!tkkonto BaMm W«M Konio 1743 84 100 βϋιΐιπβι Bank A ti.. Kniito 01 109? 1 1)00PoMn: lii! Tkkonto BaMm W «M Konio 1743 84 100 βϋιΐιπβι Bank A ti .. Kniito 01 109? 1 1) 00 DII'L.-INl/. DItTm IANI^R DR.-INl). MAN! RH) HC)NINgDII'L.-INl /. DItTm IANI ^ R DR.-INl). MAN! RH) HC) NINg PA TfN TANVVAL rfPA TfN TANVVAL rf 3. Mischung nach Anspruch 1 oder 2, dadurch g e k e η η -3. Mixture according to claim 1 or 2, characterized in that g e k e η η - ζ e i chnet, daß der Festkorperanteil 35-70 Gew. %, insbesondere 52-58 Gew. % beträgt.ζ ei chnet that the solids content is 35-70 wt. %, In particular 52-58 wt. % . 4. Mischung nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, daß ein Härter, insbesondere Alkyl-Aziridin zugesetzt ist.4. Mixture according to one of claims 1 to 3, characterized in that a hardener, in particular Alkyl aziridine is added. 5· Mischung nach Anspruch 4, dadurch gekennzeichnet, daß 0,5-4 Gew.%, insbesondere 2 Gew.% Härter zugesetzt sind.5 x mixture according to claim 4, characterized in that 0.5-4 wt.%, Especially 2 wt.% Curing agent are added. 6. Mischung nach einem der Ansprüche 1 bis 5> dadurch gekennzeichnet, daß der Lösungsmittelanteil aus 75-99 Gew. %, insbesondere 81-92 Gew % Wasser, und 25-1 Gew.JO, insbesondere 19-8 Gew. %t organischen Lösungsmitteln und Neutralisationsmitteln besteht.6. Mixture according to one of claims 1 to 5> characterized in that the solvent content of 75-99 wt.%, In particular 81-92 wt% of water, and 25-1 Gew.JO, in particular 19-8 weight organic.% T Solvents and neutralizing agents. 7. Mischung nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, daß der Festkörper aus 5-80 Gew. %, insbesondere 50 Gev.%, Pigmenten und Extender und 95-20 Gew.#, insbesondere 50 Gew.%, Polyurethan und Polyacrylat besteht.7. Mixture according to one of claims 1 to 6, characterized in that the solid consists of 5-80% by weight , in particular 50 % by weight, pigments and extenders and 95-20% by weight, in particular 50% by weight , polyurethane and Consists of polyacrylate.
DE3316550A 1983-05-03 1983-05-03 Process for priming plastics Expired DE3316550C2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
DE3316550A DE3316550C2 (en) 1983-05-03 1983-05-03 Process for priming plastics
DE19843440537 DE3440537A1 (en) 1983-05-03 1984-11-02 Process for coating plastic parts
DE3440534A DE3440534A1 (en) 1983-05-03 1984-11-02 Process for coating plastics
DE19843440535 DE3440535A1 (en) 1983-05-03 1984-11-02 Process for priming plastics

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE3316550A DE3316550C2 (en) 1983-05-03 1983-05-03 Process for priming plastics
DE19843440537 DE3440537A1 (en) 1983-05-03 1984-11-02 Process for coating plastic parts
DE3440534A DE3440534A1 (en) 1983-05-03 1984-11-02 Process for coating plastics
DE19843440535 DE3440535A1 (en) 1983-05-03 1984-11-02 Process for priming plastics

Publications (2)

Publication Number Publication Date
DE3316550A1 true DE3316550A1 (en) 1984-11-08
DE3316550C2 DE3316550C2 (en) 1985-07-25

Family

ID=37831451

Family Applications (4)

Application Number Title Priority Date Filing Date
DE3316550A Expired DE3316550C2 (en) 1983-05-03 1983-05-03 Process for priming plastics
DE19843440535 Ceased DE3440535A1 (en) 1983-05-03 1984-11-02 Process for priming plastics
DE3440534A Ceased DE3440534A1 (en) 1983-05-03 1984-11-02 Process for coating plastics
DE19843440537 Ceased DE3440537A1 (en) 1983-05-03 1984-11-02 Process for coating plastic parts

Family Applications After (3)

Application Number Title Priority Date Filing Date
DE19843440535 Ceased DE3440535A1 (en) 1983-05-03 1984-11-02 Process for priming plastics
DE3440534A Ceased DE3440534A1 (en) 1983-05-03 1984-11-02 Process for coating plastics
DE19843440537 Ceased DE3440537A1 (en) 1983-05-03 1984-11-02 Process for coating plastic parts

Country Status (1)

Country Link
DE (4) DE3316550C2 (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3440537A1 (en) * 1983-05-03 1986-05-07 Chemulack Chemische Lackfabrik Process for coating plastic parts
WO1986002655A1 (en) * 1984-11-02 1986-05-09 Chemulack Chemische-Und Lackfabrik Gmbh & Co. Kg Process for providing plastics with a primer
US4880867A (en) * 1986-08-19 1989-11-14 501 Herberts Gesellschaft Mit Beschrankter Aqueous coating compositions, a process for their preparation and method of using the same
EP0350157A2 (en) * 1988-05-30 1990-01-10 Dainippon Ink And Chemicals, Inc. Aqueous coating composition
DE3844435C1 (en) * 1988-12-31 1990-08-23 Kurz, Geb. Sendtko, Waldtraud, 8011 Vaterstetten, De
US5620789A (en) * 1990-05-21 1997-04-15 The Dow Chemical Company Cure inhibited epoxy resin compositions and laminates prepared from the compositions
US6613830B2 (en) * 1999-01-29 2003-09-02 Michael J. Stevenson Aqueous base coating composition for polyolefin surfaces

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU607955B2 (en) * 1986-12-26 1991-03-21 Mitsui Chemicals, Inc. Molded articles of thermoplastic elastomer
US5916960A (en) * 1993-12-21 1999-06-29 The Sherwin-Williams Company Water-based, storage stable, self-curing coating composition
US6180181B1 (en) 1998-12-14 2001-01-30 Ppg Industries Ohio, Inc. Methods for forming composite coatings on substrates
WO2015057397A2 (en) * 2013-10-14 2015-04-23 Ticona Llc Coatings for polyoxymethylene polymer molded articles
CN104212321B (en) * 2014-07-31 2016-04-20 昆山市大地化工新技术开发有限公司 Two component multifunctional type priming paint of PU and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4092286A (en) * 1975-11-14 1978-05-30 Bayer Aktiengesellschaft Production of water-dispersible polyurethanes having ionic groups and hydrophilic side chains
US4278578A (en) * 1979-11-05 1981-07-14 Hillyard Enterprises, Inc. Coating composition for synthetic plastic substrates and methods for preparing and using same
US4301053A (en) * 1980-01-29 1981-11-17 General Electric Company Polyurethane resin coating composition

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3316550C2 (en) * 1983-05-03 1985-07-25 Chemulack Chemische- Und Lackfabrik Gmbh & Co Kg, 1000 Berlin Process for priming plastics

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4092286A (en) * 1975-11-14 1978-05-30 Bayer Aktiengesellschaft Production of water-dispersible polyurethanes having ionic groups and hydrophilic side chains
US4278578A (en) * 1979-11-05 1981-07-14 Hillyard Enterprises, Inc. Coating composition for synthetic plastic substrates and methods for preparing and using same
US4301053A (en) * 1980-01-29 1981-11-17 General Electric Company Polyurethane resin coating composition

Non-Patent Citations (7)

* Cited by examiner, † Cited by third party
Title
Am.Chem.Soc., Dirision of Organic Coatings and Plastics 1974, Bd.36, Nr.2, S.431-436 *
Journal of coceted Fabrics, Vol.3 (1974), S. 181-193 *
Lieferprogramm Polyvinyl Chemie, Jan.1979 *
Techn. Merkblatt, Exausol-Versuchsprodukt KL-5-2524 *
Technical Information Polyvinyl Chemie 4426-B *
Technical Information Polyvinyl Chemie, Formulation 4270 *
Textilbericht 1974, Referat T.3098/74 *

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3440537A1 (en) * 1983-05-03 1986-05-07 Chemulack Chemische Lackfabrik Process for coating plastic parts
WO1986002655A1 (en) * 1984-11-02 1986-05-09 Chemulack Chemische-Und Lackfabrik Gmbh & Co. Kg Process for providing plastics with a primer
US4880867A (en) * 1986-08-19 1989-11-14 501 Herberts Gesellschaft Mit Beschrankter Aqueous coating compositions, a process for their preparation and method of using the same
EP0350157A2 (en) * 1988-05-30 1990-01-10 Dainippon Ink And Chemicals, Inc. Aqueous coating composition
EP0350157A3 (en) * 1988-05-30 1991-07-03 Dainippon Ink And Chemicals, Inc. Aqueous coating composition
US5141983A (en) * 1988-05-30 1992-08-25 Dainippon Ink & Chemicals, Inc. Aqueous coating composition
DE3844435C1 (en) * 1988-12-31 1990-08-23 Kurz, Geb. Sendtko, Waldtraud, 8011 Vaterstetten, De
US5620789A (en) * 1990-05-21 1997-04-15 The Dow Chemical Company Cure inhibited epoxy resin compositions and laminates prepared from the compositions
US6613830B2 (en) * 1999-01-29 2003-09-02 Michael J. Stevenson Aqueous base coating composition for polyolefin surfaces

Also Published As

Publication number Publication date
DE3440535A1 (en) 1986-05-07
DE3440534A1 (en) 1986-05-07
DE3316550C2 (en) 1985-07-25
DE3440537A1 (en) 1986-05-07

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