DE3270812D1 - Catalysts for the production of alcohols from olefins and synthesis gas and process employing such catalysts - Google Patents

Catalysts for the production of alcohols from olefins and synthesis gas and process employing such catalysts

Info

Publication number
DE3270812D1
DE3270812D1 DE8282306570T DE3270812T DE3270812D1 DE 3270812 D1 DE3270812 D1 DE 3270812D1 DE 8282306570 T DE8282306570 T DE 8282306570T DE 3270812 T DE3270812 T DE 3270812T DE 3270812 D1 DE3270812 D1 DE 3270812D1
Authority
DE
Germany
Prior art keywords
catalysts
olefins
alcohols
production
synthesis gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8282306570T
Other languages
English (en)
Inventor
Marcus William Blaskie
Joseph Robert Fox
Frederick Anthony Pesa
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23296441&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE3270812(D1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Standard Oil Co filed Critical Standard Oil Co
Application granted granted Critical
Publication of DE3270812D1 publication Critical patent/DE3270812D1/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/10—Monohydroxylic acyclic alcohols containing three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/12—Monohydroxylic acyclic alcohols containing four carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/46—Ruthenium, rhodium, osmium or iridium
    • B01J23/464—Rhodium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/60—Platinum group metals with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6522—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/656—Manganese, technetium or rhenium
    • B01J23/6562—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8906—Iron and noble metals
DE8282306570T 1981-12-18 1982-12-09 Catalysts for the production of alcohols from olefins and synthesis gas and process employing such catalysts Expired DE3270812D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/332,036 US4361711A (en) 1981-12-18 1981-12-18 Alcohols from olefins and synthesis gas

Publications (1)

Publication Number Publication Date
DE3270812D1 true DE3270812D1 (en) 1986-05-28

Family

ID=23296441

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8282306570T Expired DE3270812D1 (en) 1981-12-18 1982-12-09 Catalysts for the production of alcohols from olefins and synthesis gas and process employing such catalysts

Country Status (5)

Country Link
US (2) US4361711A (de)
EP (1) EP0082641B1 (de)
JP (1) JPS58116431A (de)
CA (1) CA1195677A (de)
DE (1) DE3270812D1 (de)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
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US4361711A (en) * 1981-12-18 1982-11-30 The Standard Oil Company Alcohols from olefins and synthesis gas
US4590314A (en) * 1983-12-30 1986-05-20 Union Carbide Corporation Catalytic process for the production of alcohols from carbon monoxide, hydrogen and olefins
US5082977A (en) * 1990-02-15 1992-01-21 University Of Akron Aldehydes by olefin hydroformylation
US5162285A (en) * 1990-11-28 1992-11-10 Princeton University Preparing catalyst for the catalytic oxidation of olefins to carbonyl compounds
US5466634A (en) * 1994-12-20 1995-11-14 International Business Machines Corporation Electronic modules with interconnected surface metallization layers and fabrication methods therefore
US5900636A (en) * 1997-05-30 1999-05-04 Adac Laboratories Dual-mode gamma camera system utilizing single-photon transmission scanning for attenuation correction of PET data
US6333016B1 (en) * 1999-06-02 2001-12-25 The Board Of Regents Of The University Of Oklahoma Method of producing carbon nanotubes
US7816709B2 (en) * 1999-06-02 2010-10-19 The Board Of Regents Of The University Of Oklahoma Single-walled carbon nanotube-ceramic composites and methods of use
US20030091496A1 (en) * 2001-07-23 2003-05-15 Resasco Daniel E. Method and catalyst for producing single walled carbon nanotubes
US6413487B1 (en) * 2000-06-02 2002-07-02 The Board Of Regents Of The University Of Oklahoma Method and apparatus for producing carbon nanotubes
US6919064B2 (en) * 2000-06-02 2005-07-19 The Board Of Regents Of The University Of Oklahoma Process and apparatus for producing single-walled carbon nanotubes
US7829622B2 (en) * 2002-06-19 2010-11-09 The Board Of Regents Of The University Of Oklahoma Methods of making polymer composites containing single-walled carbon nanotubes
US7153903B1 (en) 2002-06-19 2006-12-26 The Board Of Regents Of The University Of Oklahoma Carbon nanotube-filled composites prepared by in-situ polymerization
CN1729050A (zh) * 2002-12-20 2006-02-01 本田技研工业株式会社 用于氢产生的含铂－钌催化剂配方
WO2005065100A2 (en) * 2003-12-15 2005-07-21 Resasco Daniel E Rhenium catalysts and methods for production of single-walled carbon nanotubes
AU2004314423A1 (en) * 2004-01-09 2005-08-04 The Board Of Regents Of The University Of Oklahoma Carbon nanotube pastes and methods of use
JP5443756B2 (ja) 2005-06-28 2014-03-19 ザ ボード オブ リージェンツ オブ ザ ユニバーシティ オブ オクラホマ カーボンナノチューブを成長および収集するための方法
WO2011046781A1 (en) 2009-10-16 2011-04-21 Dow Technology Investments Llc Gas phase hydroformylation process
BR112013007281A2 (pt) 2010-10-11 2016-06-14 Dow Global Technologies Inc processo para converter uma corrente de alimentação compreendendo gás de síntese e etileno em uma corrente de produto que compreende pelo menos um oxigenado de três átomos de carbono
WO2012108973A1 (en) 2011-02-11 2012-08-16 Dow Global Technologies Llc Heterogeneous catalyst and its use
CN103071500B (zh) * 2013-01-21 2015-02-04 中国科学院上海高等研究院 一种用于由合成气制备c6以上醇的催化剂及其制备方法和应用
CN104262088A (zh) * 2014-08-29 2015-01-07 中国科学院山西煤炭化学研究所 一种醋酸合成异丙醇的方法
CN106622376B (zh) * 2016-12-08 2019-10-11 武汉凯特立斯科技有限公司 一种内烯烃的异构化与氢甲酰化反应方法和催化剂
CN109847741A (zh) * 2017-11-30 2019-06-07 中国科学院大连化学物理研究所 一种单原子铑催化剂及其制备和应用

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US2683177A (en) * 1949-10-29 1954-07-06 Standard Oil Co Single stage process for preparing alcohols from co, h2 and olefins
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US3501531A (en) * 1964-12-15 1970-03-17 Ethyl Corp Hydroformylation process
US3733362A (en) * 1968-03-19 1973-05-15 Union Oil Co Vapor phase carbonylation
US3557219A (en) * 1968-04-15 1971-01-19 Ethyl Corp Process for preparaing alcohols and aldehydes
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Also Published As

Publication number Publication date
US4456694A (en) 1984-06-26
EP0082641A1 (de) 1983-06-29
EP0082641B1 (de) 1986-04-23
US4361711A (en) 1982-11-30
CA1195677A (en) 1985-10-22
JPS58116431A (ja) 1983-07-11

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Legal Events

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8363 Opposition against the patent
8331 Complete revocation