DE3269746D1 - Selective dewaxing of hydrocarbon oil using surface modified zeolites - Google Patents

Selective dewaxing of hydrocarbon oil using surface modified zeolites

Info

Publication number
DE3269746D1
DE3269746D1 DE8282306695T DE3269746T DE3269746D1 DE 3269746 D1 DE3269746 D1 DE 3269746D1 DE 8282306695 T DE8282306695 T DE 8282306695T DE 3269746 T DE3269746 T DE 3269746T DE 3269746 D1 DE3269746 D1 DE 3269746D1
Authority
DE
Germany
Prior art keywords
hydrocarbon oil
surface modified
modified zeolites
selective dewaxing
dewaxing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
DE8282306695T
Other languages
English (en)
Inventor
Ian Alfred Cody
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of DE3269746D1 publication Critical patent/DE3269746D1/de
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/061—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing metallic elements added to the zeolite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/10—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing iron group metals, noble metals or copper
    • B01J29/12—Noble metals
    • B01J29/126—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/12—After treatment, characterised by the effect to be obtained to alter the outside of the crystallites, e.g. selectivation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/14—After treatment, characterised by the effect to be obtained to alter the inside of the molecular sieve channels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/32—Reaction with silicon compounds, e.g. TEOS, siliconfluoride
DE8282306695T 1981-12-16 1982-12-15 Selective dewaxing of hydrocarbon oil using surface modified zeolites Expired DE3269746D1 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US06/331,262 US4390414A (en) 1981-12-16 1981-12-16 Selective dewaxing of hydrocarbon oil using surface-modified zeolites

Publications (1)

Publication Number Publication Date
DE3269746D1 true DE3269746D1 (en) 1986-04-10

Family

ID=23293242

Family Applications (1)

Application Number Title Priority Date Filing Date
DE8282306695T Expired DE3269746D1 (en) 1981-12-16 1982-12-15 Selective dewaxing of hydrocarbon oil using surface modified zeolites

Country Status (7)

Country Link
US (2) US4390414A (de)
EP (1) EP0082019B1 (de)
JP (1) JPS58108292A (de)
AU (1) AU554542B2 (de)
CA (1) CA1207697A (de)
DE (1) DE3269746D1 (de)
MX (1) MX167253B (de)

Families Citing this family (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4839025A (en) * 1979-10-15 1989-06-13 Union Oil Company Of California Mild hydrocracking with a catalyst containing non-hydrolyzable halogen
US4477583A (en) * 1983-06-09 1984-10-16 Mobil Oil Corporation Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes
CA1214449A (en) * 1983-06-09 1986-11-25 Paul G. Rodewald Silica-modified catalyst and use for selective production of para-dialkyl substituted benzenes
US4541919A (en) * 1984-08-07 1985-09-17 Mobil Oil Corporation Shape selective dewaxing using coke modified large pore zeolites
CA1275400C (en) * 1984-12-18 1990-10-23 Frank Peter Gortsema Dewaxing catalysts and processes employing non- zeolitic molecular sieves
US4960504A (en) * 1984-12-18 1990-10-02 Uop Dewaxing catalysts and processes employing silicoaluminophosphate molecular sieves
GB8511048D0 (en) * 1985-05-01 1985-06-12 Unilever Plc Inorganic structures
LU86269A1 (fr) * 1986-01-28 1987-09-03 Labofina Sa Procede pour enlever les cires des gasoils
US4803186A (en) * 1986-12-04 1989-02-07 Mobil Oil Corporation Shape selective crystalline silicate zeolite containing intermetallic component and use as catalyst in hydrocarbon conversions
JPH0660117B2 (ja) * 1987-12-18 1994-08-10 丸善石油化学株式会社 パラエチルフェノールの製造方法
US4895997A (en) * 1988-08-31 1990-01-23 Shell Oil Company Olefin isomerization process
US4906599A (en) * 1988-12-30 1990-03-06 Exxon Research & Engineering Co. Surface silylated zeolite catalysts, and processes for the preparation, and use of said catalysts in the production of high octane gasoline
US4985135A (en) * 1988-12-30 1991-01-15 Exxon Research And Engineering Company Surface silylated zeolite cataysts, and processes for the preparation, and use of said catalysts in the production of high octane gasoline
US5015361A (en) * 1989-01-23 1991-05-14 Mobil Oil Corp. Catalytic dewaxing process employing surface acidity deactivated zeolite catalysts
US5378440A (en) * 1990-01-25 1995-01-03 Mobil Oil Corp. Method for separation of substances
US5156829A (en) * 1990-01-25 1992-10-20 Mobil Oil Corporation Method for stabilizing synthetic mesoporous crystalline material
US5220101A (en) * 1990-01-25 1993-06-15 Mobil Oil Corp. Sorption separation over modified synthetic mesoporous crystalline material
US5145816A (en) * 1990-12-10 1992-09-08 Mobil Oil Corporation Method for functionalizing synthetic mesoporous crystalline material
US5200058A (en) * 1990-01-25 1993-04-06 Mobil Oil Corp. Catalytic conversion over modified synthetic mesoporous crystalline material
US5365003A (en) * 1993-02-25 1994-11-15 Mobil Oil Corp. Shape selective conversion of hydrocarbons over extrusion-modified molecular sieve
US5403800A (en) * 1993-05-28 1995-04-04 Mobil Oil Corp. Multiple impregnation technique for the preparation of ex situ selectivated zeolite catalysts
US5476823A (en) * 1993-05-28 1995-12-19 Mobil Oil Corp. Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and method to increase the activity thereof
US5726114A (en) * 1993-10-27 1998-03-10 Mobil Oil Corporation Method of preparation of ex situ selectivated zeolite catalysts for enhanced shape selective applications and methods to increase the activity thereof
US5625104A (en) * 1995-06-06 1997-04-29 Mobil Oil Corporation Alkali metal ion exchanged selectivated zeolite catalyst
US5612270A (en) * 1995-05-15 1997-03-18 Mobil Oil Corporation Ammonium treated selectivated zeolite catalyst
US5849968A (en) * 1995-06-06 1998-12-15 Mobil Oil Corporation Hydrocarbon conversion process with alkaline earth metal ion exchanged selectivated zeolite catalyst
MY125670A (en) * 1995-06-13 2006-08-30 Shell Int Research Catalytic dewaxing process and catalyst composition
US5602066A (en) * 1995-06-29 1997-02-11 Mobil Oil Corporation Method of making a liquid washed selectivated zeolite catalyst
US6296757B1 (en) 1995-10-17 2001-10-02 Exxon Research And Engineering Company Synthetic diesel fuel and process for its production
US5689031A (en) 1995-10-17 1997-11-18 Exxon Research & Engineering Company Synthetic diesel fuel and process for its production
US5800696A (en) * 1996-11-12 1998-09-01 Phillips Petroleum Company Method for inhibiting the rate of coke formation during the zeolite catalyzed aromatization of hydrocarbons
AU705513B2 (en) * 1996-11-12 1999-05-27 Phillips Petroleum Company Composition useful in converting non-aromatic hydrocarbons to aromatics and olefins
US5766274A (en) 1997-02-07 1998-06-16 Exxon Research And Engineering Company Synthetic jet fuel and process for its production
DE19901302A1 (de) * 1999-01-15 2000-07-20 Degussa Alkylhalogensilan enthaltene Zeolithpulver
US6448197B1 (en) * 2000-07-13 2002-09-10 Exxonmobil Chemical Patents Inc. Method for making a metal containing small pore molecular sieve catalyst
DE60023358T2 (de) 2000-08-18 2006-07-13 Invista Technologies S.A.R.L., Wilmington Verbesserter hydroperoxid zersetzungskatalysator
US6864200B2 (en) * 2001-01-23 2005-03-08 Indian Petrochemicals Corporation Limited Selectivated metallosilicate catalyst composite for alkylaromatic conversion, process for the preparation thereof, and use thereof in hydrocarbon conversion
US6759360B2 (en) * 2002-03-29 2004-07-06 Exxonmobil Chemical Patent Inc. Interior surface modifications of molecular sieves with organometallic reagents and the use thereof for the conversion of oxygenates to olefins
JP4632787B2 (ja) * 2002-09-13 2011-02-16 オートモーティブ システムズ ラボラトリー インコーポレーテッド インフレータ
US6875339B2 (en) * 2003-03-07 2005-04-05 Conocophillips Company Octane improvement of a hydrocarbon stream
CN100358979C (zh) * 2003-06-27 2008-01-02 国际壳牌研究有限公司 制备润滑基础油的方法
JP2008503629A (ja) * 2004-06-25 2008-02-07 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 潤滑基油の製造方法及びその使用法
US20060182888A1 (en) * 2005-01-10 2006-08-17 Cody Ian A Modifying steel surfaces to mitigate fouling and corrosion
US20060219598A1 (en) * 2005-01-10 2006-10-05 Cody Ian A Low energy surfaces for reduced corrosion and fouling
FR2909906B1 (fr) 2006-12-13 2009-02-06 Inst Francais Du Petrole Procede d'isomerisation des composes c8 aromatiques en presence d'un catalyseur comprenant une zeolithe euo modifiee
FR2951190B1 (fr) 2009-10-13 2012-08-17 Inst Francais Du Petrole Procede d'hydrotraitement et d'hydroisomerisation de charges issues de source renouvelable mettant en oeuvre une zeolithe modifiee
FR2951193B1 (fr) 2009-10-13 2011-12-09 Inst Francais Du Petrole Procede d'hydrocraquage mettant en oeuvre une zeolithe modifiee
FR2951192B1 (fr) 2009-10-13 2011-12-30 Inst Francais Du Petrole Procede de production de distillat moyen a partir de cires fischer tropsch utilisant un catalyseur a base de zeolithe modifiee
FR2952379B1 (fr) * 2009-11-10 2012-05-11 Inst Francais Du Petrole Procede d'hydrocraquage mettant en oeuvre une zeolithe modifiee par un traitement basique
US8575055B2 (en) 2010-03-30 2013-11-05 Uop Llc Surface-modified zeolites and methods for preparing the same
CN102407118B (zh) * 2010-09-21 2013-06-05 中国石油化工股份有限公司 不饱和烃加氢的催化剂及其应用
CN103071490A (zh) * 2011-10-26 2013-05-01 中国石油化工股份有限公司 一种用于不饱和烃加氢的钯催化剂及其应用
CN104169242B (zh) * 2011-12-08 2017-07-14 Gtc科技美国有限责任公司 通过芳族化合物的甲基化制备二甲苯
JP6013259B2 (ja) * 2013-04-03 2016-10-25 日揮触媒化成株式会社 水素化処理触媒用担体、その製造方法、水素化処理触媒、およびその製造方法
WO2019026053A2 (en) * 2017-08-04 2019-02-07 Fernando Thome Kreutz RUBBER COMPOSITIONS AND ASSOCIATED METHODS

Family Cites Families (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2722504A (en) * 1950-12-04 1955-11-01 Union Oil Co Silicone coated catalyst and use thereof
NL238953A (de) * 1958-05-08
US3207699A (en) * 1961-05-04 1965-09-21 Air Prod & Chem Trimethylsilane treatment of dry calcined silica-alumina
US3213156A (en) * 1962-05-18 1965-10-19 Air Prod & Chem Selective isomerization of an alkene with a silane catalyst
US3280096A (en) * 1963-05-31 1966-10-18 Cabot Corp Polymerization catalysts
US3389092A (en) * 1964-07-13 1968-06-18 Sinclair Research Inc Process for preparing silica-alumina
US3309892A (en) * 1964-12-28 1967-03-21 Gen Motors Corp Flexible belt-type ice maker
US3578398A (en) * 1968-04-01 1971-05-11 Mobil Oil Corp Synthetic crystalline zeolite and preparation thereof
US3725302A (en) * 1969-06-17 1973-04-03 Texaco Inc Silanized crystalline alumino-silicate
US3658696A (en) * 1969-06-17 1972-04-25 Texaco Inc Selected adsorption with a silanized crystalline alumino-silicate
US3647681A (en) * 1969-09-09 1972-03-07 Chevron Res Catalytic dewaxing
US3644220A (en) * 1969-11-13 1972-02-22 Exxon Research Engineering Co Metal halide containing zeolites and method for their preparation
GB1342876A (en) * 1969-12-19 1974-01-03 British Petroleum Co Catalyst supports and transition metal catalysts supported thereon
US3682996A (en) * 1970-02-24 1972-08-08 Mobil Oil Corp Zeolite esters
US3698157A (en) * 1971-06-01 1972-10-17 Mobil Oil Corp Separation of mixtures with modified zeolites
US3724170A (en) * 1971-09-13 1973-04-03 Mobil Oil Corp Staged separations of aromatic mixtures with zeolites
BE789628A (fr) 1971-10-04 1973-04-03 Ici Ltd Zeolites
US3702293A (en) * 1971-12-30 1972-11-07 Universal Oil Prod Co Hydrocarbon conversion process with a bimetallic catalyst
US4002697A (en) * 1973-12-03 1977-01-11 Mobil Oil Corporation Selective production of para-xylene
US4053534A (en) * 1974-02-19 1977-10-11 Mobil Oil Corporation Organic compound conversion
US3980586A (en) * 1974-08-28 1976-09-14 Mobil Oil Corporation Modified solid catalyst materials
US3965210A (en) * 1975-01-06 1976-06-22 Mobil Oil Corporation Selective production of para-xylene and catalyst therefor
US4090981A (en) * 1976-09-23 1978-05-23 Mobile Oil Corporation Catalyst for selective production of para dialkyl substituted benzenes
US4100219A (en) * 1976-03-31 1978-07-11 Mobil Oil Corporation Silica-modified zeolite catalyst and conversion therewith
US4080284A (en) * 1976-04-12 1978-03-21 Mobil Oil Corporation Hydrocarbon conversion with modified solid catalyst materials
US4088605A (en) * 1976-09-24 1978-05-09 Mobil Oil Corporation ZSM-5 containing aluminum-free shells on its surface
US4138363A (en) * 1977-09-14 1979-02-06 Pq Corporation Silane-zeolite compositions
US4259174A (en) * 1979-03-19 1981-03-31 Mobil Oil Corporation Catalytic dewaxing of hydrocarbon oils
US4247388A (en) * 1979-06-27 1981-01-27 Mobil Oil Corporation Hydrodewaxing catalyst performance
US4376036A (en) * 1981-03-06 1983-03-08 Mobil Oil Corporation Production of high V. I. lubricating oil stock
US4402867A (en) * 1981-12-22 1983-09-06 Mobil Oil Corporation Silica-modified zeolite catalysts

Also Published As

Publication number Publication date
CA1207697A (en) 1986-07-15
MX167253B (es) 1993-03-12
EP0082019A2 (de) 1983-06-22
US4451572A (en) 1984-05-29
US4390414A (en) 1983-06-28
JPH0546399B2 (de) 1993-07-13
AU554542B2 (en) 1986-08-28
AU1176183A (en) 1984-08-30
EP0082019B1 (de) 1986-03-05
JPS58108292A (ja) 1983-06-28
EP0082019A3 (en) 1983-07-20

Similar Documents

Publication Publication Date Title
DE3269746D1 (en) Selective dewaxing of hydrocarbon oil using surface modified zeolites
JPS57139182A (en) Hydrocarbon oil catalytic dewaxing process
JPS55145793A (en) Contact dewaxing method of hydrocarbon oil
GB8327628D0 (en) Thermal hydrogenation of hydrocarbon liquids
DE3363675D1 (en) Method of selective hydrogenation of hydrocarbons
GB8321720D0 (en) Thermal cracking of heavy oil
JPS6466292A (en) Hydrogenation of hydrocarbon oil
DE3477375D1 (en) Hydrocarbon cracking process
GB8328232D0 (en) Desalting crude oil
GB8401584D0 (en) Thermal cracking of hydrocarbon oils
GB8402860D0 (en) Hydrocracking of heavy oils
JPS5780484A (en) Conversion of heavy hydrocarbon oil
YU21983A (en) Process for obtaining hydrocarbons from oil shales
ZA815188B (en) Fluid catalytic cracking
DE3571457D1 (en) Method for dewaxing hydrocarbon oil
GB8307522D0 (en) Wax-containing crude oil
JPS56136893A (en) Improvement of heavy hydrocarbon oil
GB2084606B (en) Treating crude oil
GB8323635D0 (en) Continuous thermal cracking of hydrocarbon oils
GB2138840B (en) Thermal cracking of heavy hydrocarbon oils
GB8318438D0 (en) Fluid catalytic of hydrocarbons
JPS57164195A (en) Regeneration of used lubricant oil
JPS57192490A (en) Hydrogenation of heavy oil
GB8618574D0 (en) Catalytic dewaxing of hydrocarbon oil
DE3474967D1 (en) Process for the dewaxing of hydrocarbon fractions

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee