DE1745939B2 - Verfahren zum modifizieren von carboxylgruppen enthaltenden aethylenpolymeren - Google Patents

Verfahren zum modifizieren von carboxylgruppen enthaltenden aethylenpolymeren

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DE1745939B2
DE1745939B2 DE1965P0036184 DEP0036184A DE1745939B2 DE 1745939 B2 DE1745939 B2 DE 1745939B2 DE 1965P0036184 DE1965P0036184 DE 1965P0036184 DE P0036184 A DEP0036184 A DE P0036184A DE 1745939 B2 DE1745939 B2 DE 1745939B2
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acid
copolymer
metal
mixing
zone
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DE1745939A1 (de
DE1745939C3 (de
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Richard Watkin Wilmington Del Rees (VStA)
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E I du Pont de Nemours and Co , Wilmington, Del (VStA)
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C08K5/098—Metal salts of carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10743—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing acrylate (co)polymers or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/17—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
    • C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
    • C08L23/0869—Acids or derivatives thereof
    • C08L23/0876—Neutralised polymers, i.e. ionomers
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    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S260/00—Chemistry of carbon compounds
    • Y10S260/31—Ionic cross-link
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    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

Description

Bndin vrelcher die flüchtigen Materialien, z. B. Wasser und Sätie (die sieh bildet, wenn man das Mischpolymerisat mit einem Salz umsetzt), verdampft und entfernt werden. In der vierten Zone wird das Polymerisat aus dem Entgasungsextruder entfernt. In dem Extruder können natürlich mehr als eine Zone des jeweiligen Typs vorliegen; auch können die Zonen unterschiedliche Abmessungen haben.
Der Vorteil des erfindungsgemäßen Verfahrens gegenübej: dem Verfahren unter Verwendung eines Kautschukmahlwerkes liegt in der größeren Gleichmäßigkeit der Endprodukte und der viel kürzeren Reaktionszeit
Beispiele 1 bis 8
In die Zuführungsöffnung eines 5-cm-Entgasungsextruders gibt man in getrennten Strömen Teilchen eines Mischpolymerisats aus Äthylen und Methacrylsäure und eine Metallverbindung, die im wesentlichen in dem geschmolzenen Polymerisat unlöslich ist. Die Zuführungsgeschwindigkeit des Mischpolymerisates variiert von 6,8 bis 10,0 kg/Std. Die Schnecke erstreckt sich über einen Plastifizierabschnitt, der 8mal so lang ist wie der Durchmesser, einem Mischabschnitt, wie er in der USA.-Patentschrift 3006029 beschrieben ist und der 13,5mal so lang ist wie der Durchmesser, einem Drosselring, der es erlaubt, in dem Mischabschnitt einen Druck aufrechtzuerhalten, (einem Entga&ungsabschnitt, der 5mal so lang ist wie der Durchmesser und einem Pumpabschnitt, der 4mal so lang ist wie der Durchmesser. Dort, wo der Mischabschnitt beginnt, spritzt man in das geschmolzene Harz eine Säurelösung ein. Die Schmelztemperatur beträgt an dieser Stelle 156° C und der Druck 28,1 kg/cm*. Das Gemisch läßt man im Mischabschnitt reagieren; anschließend leitet man das 210° C heiße, geschmolzene Gemisch über den Drosselring in die Entgasungszone. Die Schmelze entdampft man im Vakuum (686 mm Hg). Anschließend extrudiert man das getrocknete geschmolzene, durch Ionen vernetzte Mischpolymerisat; den erhaltenen Strang kühlt man in
ao Wasser und granuliert ihn.
Die einzelnen Arbeitsweisen, die eingesetzten Reagentien und einige der beeinflußten Polymerisateigenschaften sind in Tabelle I angegeben.
Tabelle I
·' 6 Saures Mischpolymerisat Steifig Metall verbindung Zu-
führungs-		 Säurelösung Typ wäßrige Zu-
führungs-		 Pro-
duktions-		 Produkt Steifig
Bei
spiel		 Meth
acryl		 Schmelz keit, geschwin- lösung geschwin- geschwin- Schmelz keit,
säure, index, Typ digkeit Volum digkeit digkeit index,
Gewichts kg/cm* kg/Std. Propion prozent cm'/Min. kg/Std. kg/cm*
1 7 ' prozent g/10 Min. 361,3 0,363 säure 50 5,29 7,48 g/10Min. 3139,7
15 71 ZnO Essig 11,52
2 8 < 861,3 0,476 säure 100 6,0 8,39 3689,8
15 71 ZnO Meth 0,28
3 861,3 0,676 acryl 60 9,17 7,94 3779,4
15 71 ZnO säure 0,19
Milch
4 861,3 0,535 säure*) 60 5,85 7,17 4241,9
15 71 ZnO Essig 0,29
5 1705,0 0,508 säure 50 5,22 9,98 3728,8
15,3 6,3 ZnO Isopro- 0,13
panol 25
Heptan-
1705,0 0,485 säure 61,9 9,0 9,98 3168,1
15,3 6,3 ZnO Essig 0,16
säure 22,7
Essig- :
— 0,404 säure 50 4,83 8,66 64 —
10**) 90 ZnO Essig 2,46
— 0,163 säure 50 5,5 6,12 —
9***) 178 ZnO 25
*) Die Milchsäure löst ZnO unter den Reaktionsbedingungen nicht vollständig. Ein weiteres Mischen ergibt eine vollständige Lösung. **) Terpolymerisat aus 67% Äthylen, 24% Vinylacetat und 10% Methacrylsäure. ***) Terpolymerisat aus 70% Äthylen, 20 V0 Vinylacetat und 90% Methacrylsäure. ■;
Beispiele 9 bis 16
In die Zuführungsöffnung eines 8,9-cm-Entgasungsextruders gibt man in getrennten Strömen Teilchen eines Mischpolymerisates aus Äthylen und Methacrylsäure und eine trockne pulverartige Mischung (bezeichnet als Vorgemisch), die aus einer oder mehreren Metallverbindungen, feinzerteiltem Mischpolymerisat und gleichen Teilen Dilaurylthiodipropionat und Dodecylpentaerythritol-Diphosphait ails Stabilisator besteht. Der erste Plastifizierabschnitt im Extruder ist 7mal so lang wie der Durchmesser und wird auf einer Temperatur von etwa 158°C gehalten. Dort, wo der Mischabschnitt beginnt, spritzt man eine Säurelösung in die geschmolzene Masse mit Hilfe einer Düse. Der Mischabschnitt (entsprechend USA.-Patentschrift 3 006 029) ist 13mal so lang wie der Durchmesser und wird auf 270 bis 2800C gehalten. Dort findet die Reak-
tion der Polymerisatschmelze unter Neutralisation der Säuregruppen statt
'■■ Hinter dem Mischabsehnitt wild die Masse, die aus ionisch vernetztem Mischpolymerisat und aus Neben· produkten besteht, die sich infolge der Umsetzung ge- S bildet haben, durch ein Druck-Lenkungsventil und ein Rohr in den Entgasungsabschnitt geleitet« der einen Durchmesser von 5 ein hat. Die Temperatur der Masse vor äem Ventil beträgt 2800G und der Druck 52,7 kg/ cm1. Im Entgasungsabschnitt sind zwei Entgasung?- zoaen, wobei jede etwa 4mal so lang wie der Durchmesser ist In der ersten Entgasungszone hält man ein
Vakuum von 686 und in 4er zweiten eins von 711 mm Hg aufrecht Die Temperatur der SchmaJae hält man zwischen 270 und 280° G In der Entgasjingszone werden die flüchtigen Bestandteile aus dem geschmolzenen, durch Ionen vernetzten Mischpolymerisat entfernt. Das anschließend in Form von Strategen extrudierte Polymerisat kühlt man in Wasser und granuliert es.
Die einzelnen Arbeitebedingungenj 4ie eingesetzten Reagentien und einige der beeinflußten Polymerisateigenschaften ersieht man aus der nachstehend angeführten Tabelle Π.
Tabelle II
Methacrylsäure-MischpoI/merisat S·) Steifigkeit, Misch
polymerisat, 		Vorgernisch ZnO Teile Stabilisator Z*·)
Beispiel Säure,
Gewichts 		kg/cm1 teile Metall verbindung Mg(OH8) teile
prozent 45 843,7 Typ Mg(C2H3O2), ■ 4,54 0,80
9 9,5 45 843,7 8,74 4H2O 4,20 0,14 1,41
10 9,5 Mg(OH2)
Mg(C8H8O2), · 4,54
45 843,7 8,74 4H„O 4,20 0,14 1,11
11 9,5 ZnO
Mg(OH)2 9,08
45 843,7 9,08 Mg(C4H3O1), ■ 5,0 0,15 1,39
12 9,5 5t9 1293,6 7,5 4H2O 0,20 1,43
13 11,7 LiOH · H8O
ZnO 4,41
4,3 984,3 8,64 Mg(OH)2 4,23 0,07 0,75
14 9,5 Mg(CaH,O2)2 · 4,54
6,3 1705,0 8,74 4H8O 0,14 0,95
15 15,3 LiOH · H8O
ZnO 4,41
6,3 1705,0 8,64 0,07 0,79
16 15,3
(Fortsetzung)
wäßrige Lösung Von Säure Z**·) Geschwindig
keit 		Produkt Steifigkeit,
Beispiel Essigsäure Volumprozent 13,8 kg/Std. kg/cms
Essigsäure 40 13,0 24,9 * I 2573,2
9 rissigsäure 40 13,5 21,3 0,7 2698,7
10 Essigsäure 40 13,5 21,3 0,52 2668,5
11 Milchsäure 37 24,5 1,52 2419,5
12 Essigsäure 3,8 13,0 1,72
Essigsäure 40 13,8 25,9 2601,0
13 Essigsäure 40 13,8 27,2 0,37 2327,0
14 Essigsäure 40 13,8 26,8 1,2 3719,3
15 40 26,3 1,25 4366,0
16 0,84
S ·) Schmelzindex, g/10 Min. Z.**) Zuführungsgeschwindigkeit, kg/Std. Z·*·) Zufuhrungsgeschwindigkeit, cm'/Min.

Claims (3)

ι 2 enthaltenden Äthylenpotymeren durch homogenes Patentansprüche: Vermischen der Polymerisate mit solchen ionischen, ein- bis dreiwertigen, wasserlöslichen Metallverbin-
1. Verfahren zum Modifizieren von Carboxyl- düngen, deren Nichtmetallrest mit dem Wasserstoffgruppen enthaltenden Äthylenpolymeren durch 5 atom aus der Carbonsäure bei Reaktionsbedingungen homogenesVermischenderPolymerisatemitsolchen entfernt werden kann, unter gleichzeitiger Neutralisaionischen, ein- bis dreiwertigen, wasserlöslichen tion von wenigstens 10% der Carboxylgruppen, das Metallverbindungen, deren Nichtmetallrest mit dadurch gekennzeichnet ist, daß man als Carboxyldem Wasserstoffatom aus der Carbonsäure bei gruppen enthaltendes Äthylenpolymerisat ein Misch-Reaktionsbedingungen entfernt werden kann, un- io polymerisat mit einem Schmelzindex von 0,1 bis ter gleichzeitiger Neutralisation von wenigstens 100 g/10 Minuten einsetzt, das wenigstens 50 MoI-10% der Carboxylgruppen, bei dem man als Carb1- i '.Prozent Ätbyleneinhjeiteii und 0,2 bis 25 Molprozent oxylgruppen enthaltendes Äthylenpolymerisat ein Einheiten von ajS-ungesättigten Monocarbonsäuren, Mischpolymerisat mit einem Schmelzindex von gegebenenfalls Einheiten eines mischpolymerisier-0,1 bis 100 g/10 Minuten einsetzt, das wenigstens 15 baren, einfach ungesättigten dritten Comonomeren 50 MolprozentÄthyleneinheitenund 0,2 bis 25MoI- enthält und in bekannter Weise durch direkte Mischprozent Einheiten Von «,^-ungesättigten Mono- polymerisation der Monomeren hergestellt worden ist. carbonsäuren, gegebenenfalls Einheiten eines misch- Nach dem Hauptpatent wird die Vernetzungsreakpolymeriaierbaren, einfach ungesättigten dritten tion bei Bedingungen durchgeführt, welche eine-homo-Comonomeren enthält, und in bekannter Weise 20 gene Verteilung des Vernetzungsmittels in der Mischdurch direkte Mischpolymerisation der Mono- polymerisat-Grundlage erlauben. Beispielsweise kann meren hergestellt worden ist, nach Patent 1520 506, das Carboxylgruppen enthaltende Mischpolymerisat dadurch gekennzeichnet, daß man mit der Metallverbindung schmelzvermischt werden, das Vermischen des Mischpolymerisates mit der Aufgabe der Erfindung ist es, für das Verfahren Metallverbindung in einem Entgasungsextruder 25 des Hauptpatentes eine besonders vorteilhafte Verfahvornimmt. rensweise zum Schmelzvennischen des Carboxyl-
2. Verfahren nach Anspruch 1, dadurch gekenn- gruppen enthaltenden Mischpolymerisates mit der zeichnet, daß man bei einer Temperatur zwischen Metallverbindung zur Verfügung zu stellen.
100 und 290° C und unter einem Druck von 7 bis Es wurde nämlich gefunden, daß das Vermischen
700 kg/cm2 arbeitet. 30 besonders vorteilhaft vorgenommen werden kann,
3. Verfahren nach Anspruch 1 oder 2, dadurch wenn man das Mischpolymerisat mit der Metallvergekennzeichnet, daß man die Metallverbindung bindung kontinuierlich in einem Entgasungsextruder in situ erzeugt, indem man eine im wesentlichen mischt.
wasserunlösliche Metallverbindung in das ge- Das Vermischen wird vorzugsweise bei einer Tem-
schmolzene Mischpolymerisat einmischt, dann 35 peratur zwischen 100 und 290° C und einem Druck
dieser geschmolzenen Masse eine Säurelösung ein- zwischen 7 bis 700 kg/cm* vorgenommen,
verleibt und anschließend die Schmelze unter ver- Das Kationen bildende Material gibt man zum
minderten! Druck von flüchtigen Bestandteilen · Mischpolymerisat als wäßrige Lösung oder in einer
befreit. im wesentlichen trockenen Form hinzu.
40 Nach einer anderen Ausführungsform kann man
die für das erfindungsgemäße Verfahren geeignete
'■■'· "·..·. Metallverbindung auch in situ erzeugen, indem man
eine im wesentlichen wasserunlösliche Metallverbin-
Mischpolymerisate aus Äthylen oder anderen α-Öle- dung in das geschmolzene Mischpolymerisat ein- ;finen mit α,/9-ungesättigten Carbonsäuren sind be- 45 mischt, dann dieser geschmolzenen Masse eine Säurekannt. Aus der französischen Patentschrift 1 255 077 lösung einverleibt und anschließend die Schmelze ist es weiterhin bekannt, solche Mischpolymerisate unter vermindertem Druck von flüchtigen Bestandteilen mit Oxiden oder Hydroxiden von mehrwertigen Me- befreit. Zu solchen, im wesentlichen wasserunlöslichen tallen oder mit Säuresalzen von Metallen zu, ver- ;. Metallverbindungen, gehören beispielsweise Metallmischen, wodurch man eine Vernetzung der Poly- S'ö oxyde, -hydroxyde und -carbonate. Zu geeigneten merisate erzielt. Verwendet man jedoch, wie dies in Säuren gehören beispielsweise Essigsäure, Milchsäure, der genannten französischen Patentschrift beschrieben Propionsäure und Mischungen dieser Säuren,
wird, solche Mischpolymerisate aus Äthylen und Unter den angegebenen Temperatur- und Druck- <%,/J-ungesättigten Carbonsäuren, welche durch Auf- r bedingungen erhält man durch die Mischwirkung des pfropfen der α,/3-äthylenisch ungesättigten Carbon*·''^'Extruders ein anscheinend einphasiges Gemiseh und säure auf ein Polyolefin erhalten worden sind, s,o sind demzufolge einen gleichmäßigen Neutralisationsgrad, die erzielten Ergebnisse noch nicht voll befriedigend. Das Verfahren im Entgasungsextruder kann man in Insbesondere sind die mit den vorgenannten Metall- vier Stufen entsprechend vier Zonen einteilen. In der verbindungen vernetzten Pfropfpolymerisate aus einem ersten Zone wird das Mischpolymerisat bei hohem Polyolefin und einer darauf aufgepfropften α,/9-äthy- 60 Druck gründlich gemischt und auf eine Temperatur lenisch ungesättigten Carbonsäure nicht durchsichtig, oberhalb seines Schmelzpunktes gebracht; das Katioso daß man aus diesen an sich in ihren Theologischen nen bildende Material kann in die erste Zone gegeben und weiteren physikalischen Eigenschaften verbesser- werden. In der zweiten Zone findet die Neutralisation ten Massen keine dickwandigen, durchsichtigen Kör- der Carbonsäuregruppen statt. Falls das Kationen per, wie Flaschen, dicke Folien u. dgl, herstellen 65 bildende Material in der ersten Zone noch nicht zukann, gegeben worden ist, fügt man es in der zweiten Zone Gegenstand des Hauptpatentes I 520 506 ist ein zu. Das Mischpolymerisat leitet man dann in eine Verfahren zum Modifizieren von Carboxylgruppen dritte Zone, in welcher ein verminderter Druck herrscht,
DE1745939A 1961-08-31 1965-03-01 Verfahren zum Modifizieren von Carboxylgruppen enthaltenden Äthylenpolymeren Expired DE1745939C3 (de)

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US13514761A 1961-08-31 1961-08-31
US16883962A 1962-01-25 1962-01-25
US27147763 US3264272A (en) 1961-08-31 1963-04-08 Ionic hydrocarbon polymers
US34829364 US3404134A (en) 1961-08-31 1964-02-28 Process of crosslinking polymers

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DE1745939A1 DE1745939A1 (de) 1971-01-14
DE1745939B2 true DE1745939B2 (de) 1973-07-19
DE1745939C3 DE1745939C3 (de) 1974-02-21

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DE1962P0030096 Pending DE1520506B2 (de) 1961-08-31 1962-08-27 Verfahren zum modifizieren von carboxylgruppen enthaltenden aethylenpolymeren
DE1963P0031004 Pending DE1520518B2 (de) 1961-08-31 1963-01-24 Verfahren zur herstellung von modifizierten copolymerisaten aus ungesaettigten kohlenwasserstoffen und ungesaettigten carbonsaeuren
DE1520601A Granted DE1520601B2 (de) 1961-08-31 1964-04-08 Verfahren zum Modifizieren von Carboxylgruppen enthaltenden Äthylenpolymeren
DE1595112A Expired DE1595112C3 (de) 1961-08-31 1965-03-01 Verfahren zur Herstellung von modifizierten Copolymerisaten aus ungesättigten Kohlenwasserstoffen und ungesättigten Carbonsäuren
DE1745939A Expired DE1745939C3 (de) 1961-08-31 1965-03-01 Verfahren zum Modifizieren von Carboxylgruppen enthaltenden Äthylenpolymeren
DE1965P0036183 Granted DE1745938B2 (de) 1961-08-31 1965-03-01 Verfahren zum modifizieren von carboxylgruppen enthaltenden aethylenpolymeren

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DE1962P0030096 Pending DE1520506B2 (de) 1961-08-31 1962-08-27 Verfahren zum modifizieren von carboxylgruppen enthaltenden aethylenpolymeren
DE1963P0031004 Pending DE1520518B2 (de) 1961-08-31 1963-01-24 Verfahren zur herstellung von modifizierten copolymerisaten aus ungesaettigten kohlenwasserstoffen und ungesaettigten carbonsaeuren
DE1520601A Granted DE1520601B2 (de) 1961-08-31 1964-04-08 Verfahren zum Modifizieren von Carboxylgruppen enthaltenden Äthylenpolymeren
DE1595112A Expired DE1595112C3 (de) 1961-08-31 1965-03-01 Verfahren zur Herstellung von modifizierten Copolymerisaten aus ungesättigten Kohlenwasserstoffen und ungesättigten Carbonsäuren

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Families Citing this family (729)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5622804A (en) * 1994-05-30 1997-04-22 Fuji Xerox Co., Ltd. Liquid developer for electrophotography, process for producing the same, and process for image formation using the same
US3876452A (en) * 1961-08-14 1975-04-08 Gulf Oil Corp Articles coated with hydralyzed copolymer of ethylene and alkyl acrylate
NL128027C (de) * 1961-08-31 1900-01-01
US3471460A (en) * 1961-08-31 1969-10-07 Du Pont Amine-modified hydrocarbon polymers
US3344014A (en) * 1963-02-28 1967-09-26 Du Pont Safety glass
GB1089907A (en) * 1963-09-27 1967-11-08 Union Carbide Corp Plasticized ethylene-acrylic acid copolymers
US3355319A (en) * 1964-03-17 1967-11-28 Du Pont Self-supporting film with a heat-sealable coating of an ionic copolymer of an olefin and carboxylic acid with metal ions distributed throughout
US3338739A (en) * 1964-03-17 1967-08-29 Du Pont Ionic copolymer coated with vinylidene chloride copolymer
US3375126A (en) * 1964-11-04 1968-03-26 Du Pont Composite film structure and process
US3423212A (en) * 1964-11-20 1969-01-21 Union Carbide Corp Method for packaging food products
US3476532A (en) * 1964-11-25 1969-11-04 Allied Chem Metal-containing complexes of oxidized polyethylene
US3321819A (en) * 1964-12-24 1967-05-30 Union Carbide Corp Process for sizing and desizing textile fibers
US3523930A (en) * 1964-12-31 1970-08-11 Du Pont Modified polyolefin copolymer composition
GB1087566A (en) * 1965-02-10 1967-10-18 Dunlop Rubber Co Improvements in and relating to golf balls
US3475267A (en) * 1965-03-04 1969-10-28 Monsanto Co Laminates bonded with an ethylene/crotonic acid copolymer salt
US3491075A (en) * 1965-10-13 1970-01-20 Union Oil Co Crosslinking of polymers having dependent ester groups with polyvalent metal alkoxides
US3421766A (en) * 1965-12-13 1969-01-14 Uniroyal Inc Composition of matter and golf ball made therefrom
US3496061A (en) * 1966-01-28 1970-02-17 Continental Can Co Flexible packages containing nonfusible high peel strength heat seals
US3454676A (en) * 1966-02-01 1969-07-08 Du Pont Blends of ionomer resins and elastomers
US3384612A (en) * 1966-02-01 1968-05-21 Du Pont Golf ball
US3427280A (en) * 1966-07-13 1969-02-11 Union Carbide Corp Curable carboxyl-containing olefin polymer compositions
US3447460A (en) * 1966-07-28 1969-06-03 Dow Chemical Co Process for making laminated printing plates
US3427733A (en) * 1966-10-03 1969-02-18 Beckwith Arden Inc Ionomeric resin stiffening element
US3548408A (en) * 1966-10-26 1970-12-15 Monsanto Chemicals Process for esterification of polymers containing alcoholic groups
US3437718A (en) * 1967-01-23 1969-04-08 Du Pont Polymer blends
US3503824A (en) * 1967-04-19 1970-03-31 Du Pont Ion linked copolymer for extrusion coating
US3493550A (en) * 1967-07-03 1970-02-03 American Cyanamid Co Plasticized associated polymers
US3532604A (en) * 1967-10-03 1970-10-06 Alfred Bloch Biological package
US3532708A (en) * 1967-11-02 1970-10-06 Monsanto Co Crosslinkable pressure-sensitive adhesive resins
US3575092A (en) * 1969-05-22 1971-04-13 Clarence S Freeman Highway divider button
BE757247A (fr) * 1969-10-09 1971-04-08 Union Carbide Corp Polymeres thermoplastiques charges avec des particules d'oxydesminerau
US4092452A (en) * 1969-11-28 1978-05-30 Nitto Electric Industrial Co., Ltd. Plastic laminated metallic foil and method for preparing the same
US4049904A (en) * 1969-11-28 1977-09-20 Nitto Electric Industrial Co., Ltd. Plastic laminated metallic foil and method for preparing the same
US3687909A (en) * 1970-02-09 1972-08-29 Dow Chemical Co Reactive beta-lactone-containing polymers and a method for their preparation
US3836386A (en) * 1970-03-02 1974-09-17 Kerr Glass Mfg Corp Coating of glassware to improve its abrasion resistance
US3649578A (en) * 1970-03-25 1972-03-14 Du Pont Process for preparing ionomers
US3933737A (en) * 1970-08-22 1976-01-20 Kabel-Und Metallwerke Gutehoffnungshutte Aktiengesellschaft Polymer composition for bonding to copper
US3992348A (en) * 1970-09-21 1976-11-16 Trw Systems And Energy Method for the preparation of moldable filled polymetal acrylate
US3940146A (en) * 1971-02-03 1976-02-24 Uniroyal Inc. Golf ball cover
US4022960A (en) * 1971-03-15 1977-05-10 Agency Of Industrial Science & Technology Polymers with high transparency and refractive index and process for production thereof
GB1346782A (en) * 1971-03-25 1974-02-13 Ethylene Plastique Sa Copolymers
US3998994A (en) * 1971-03-25 1976-12-21 Ethylene Plastique Modified copolymers
US3775239A (en) * 1971-05-24 1973-11-27 Rap Ind Inc Packaging material, packages and method of making same
US3849165A (en) * 1971-06-03 1974-11-19 Eastman Kodak Co Liquid electrographic development process
US4132857A (en) * 1971-08-12 1979-01-02 Union Carbide Corporation Electrical cable
CA988831A (en) * 1971-10-11 1976-05-11 Kenichi Hattori Adhesive resins
CA978697A (en) * 1971-10-11 1975-11-25 Hideo Kinoshita Process for producing metal-containing ethylenic copolymer
US3998990A (en) * 1971-10-11 1976-12-21 Asahi-Dow Limited Substrates adhered via ionomer resins
US3860441A (en) * 1972-01-14 1975-01-14 Dow Chemical Co Process and composition for water proofing substrates
US4143185A (en) * 1972-02-25 1979-03-06 Exxon Research & Engineering Co. Fabrication of coatings from thermoplastic ionomers
US3898170A (en) * 1972-03-21 1975-08-05 Eastman Kodak Co Electrographic carrier vehicle and developer composition
US3886125A (en) * 1972-05-12 1975-05-27 Airwick Ind Polymer Complexes
US3870841A (en) * 1972-10-02 1975-03-11 Exxon Research Engineering Co Flexible polymeric compositions comprising a normally plastic polymer sulfonated to about 0.2 to about 10 mole % sulfonate
US3900670A (en) * 1972-12-15 1975-08-19 Du Pont Laminated film structure
US3904806A (en) * 1973-02-28 1975-09-09 Du Pont Composite films of glassine-polyolefin copolymer resins exhibiting high oxygen barrier characteristics
US3899624A (en) * 1973-04-26 1975-08-12 Gen Dynamics Corp Method for protecting surfaces against environmental damage and the resultant products
US3922450A (en) * 1973-06-28 1975-11-25 Owens Illinois Inc Coated glass container and method for coating same
US3864151A (en) * 1973-07-02 1975-02-04 Anchor Hocking Corp Glass article coated with plastic and lubricity coatings and method of coating
GB1446586A (en) * 1973-07-30 1976-08-18 Ici Ltd Thermoplastic polyurethanes mixed with ehtylene copolymers
GB1462757A (en) * 1973-09-07 1977-01-26 Ici Ltd Resin derivatives
US3968311A (en) * 1973-09-10 1976-07-06 Continental Can Company, Inc. Metal coated with compositions prepared from aqueous dispersions of carboxylic acid resin and an aliphatic amine
US3969434A (en) * 1973-10-29 1976-07-13 E. I. Du Pont De Nemours And Company Process for preparing ionically crosslinked copolymers
US3959539A (en) * 1973-11-28 1976-05-25 E. I. Du Pont De Nemours And Companny Coating material of polymers and salts of fatty acids
US4056653A (en) * 1973-11-28 1977-11-01 E. I. Du Pont De Nemours And Company Spherical-shaped particles from ionomer resins and ethylene/carboxylic acid copolymer resins
US3984608A (en) * 1974-04-17 1976-10-05 Kerr Glass Manufacturing Corporation Glassware having improved resistance to abrasion
USRE30726E (en) * 1974-07-05 1981-09-01 Tower Products, Inc. Polymer film having linear tear properties
US4098406A (en) * 1974-07-05 1978-07-04 Tower Products, Inc. Polymer film having linear tear properties
US4014847A (en) * 1974-07-11 1977-03-29 Exxon Research And Engineering Company Ionic polymer plasticized with preferential plasticizers
US3976627A (en) * 1974-10-04 1976-08-24 The B.F. Goodrich Company Vulcanizable compositions of carboxyl-containing polymers
US4055530A (en) * 1975-02-27 1977-10-25 Standard Oil Company (Indiana) Aqueous dispersion of addition polymer of an alpha-beta-ethylenically unsaturated monomer and suspended polypropylene particles
JPS5199673A (ja) * 1975-02-28 1976-09-02 Asahi Glass Co Ltd Denkaihoho
JPS5223673B2 (de) * 1975-03-18 1977-06-25
US4196267A (en) * 1975-03-25 1980-04-01 Asahi-Dow Limited Extrusion foamed article and process for producing the same
US4020966A (en) * 1975-03-28 1977-05-03 W. R. Grace & Co. Plastisol composition and container closure gasket made therefrom
JPS51125451A (en) * 1975-04-03 1976-11-01 Asahi Chem Ind Co Ltd Polyamide composition
JPS524566A (en) * 1975-07-01 1977-01-13 Asahi Dow Ltd Thermoplastic resin foam
US3979540A (en) * 1975-12-22 1976-09-07 E. I. Du Pont De Nemours And Company Ionomer resin substrates coated with an epoxy primer and finished with an acrylic coating
US4188441A (en) * 1976-02-17 1980-02-12 Crown Zellerbach Corporation Flexible packaging films of high density polyethylene capable of forming easily openable heatseals
JPS52135385A (en) * 1976-05-08 1977-11-12 Sumitomo Chem Co Ltd Improved laminates
JPS52135392A (en) * 1976-05-08 1977-11-12 Sumitomo Chem Co Ltd Ionically crosslinked ethylene copolymers
US4078014A (en) * 1976-06-10 1978-03-07 E. I. Du Pont De Nemours And Company Composition of polyamide, polyethylene ionomer copolymer
JPS52154088A (en) * 1976-06-16 1977-12-21 Sumitomo Chemical Co Laminated sheath cable with improved adhesive property
US4056208A (en) * 1976-08-11 1977-11-01 George Wyatt Prejean Caustic-resistant polymer coatings for glass
JPS5369253A (en) * 1976-11-30 1978-06-20 Bayer Ag Thermoplastic molding composition
US4083824A (en) * 1977-04-20 1978-04-11 Armstrong Cork Company Non-vinyl surface covering composition
US4121956A (en) * 1977-07-15 1978-10-24 E. I. Du Pont De Nemours And Company Method for labelling a package
JPS60225B2 (ja) * 1978-03-31 1985-01-07 東洋インキ製造株式会社 積層体の製造方法
US4335223A (en) * 1978-06-12 1982-06-15 Allied Corporation High impact molding compositions
US4217430A (en) * 1978-08-01 1980-08-12 E. I. Du Pont De Nemours And Company Graft copolymer of neutralized acid copolymer trunk and polyamide oligomeric branches and method for making such copolymer
US4274637A (en) * 1979-01-31 1981-06-23 Questor Corporation Golf ball having cellular cover
NZ192617A (en) * 1979-01-31 1983-02-15 Questor Corp Golf ball with a cellular cover
US4321337A (en) * 1979-02-02 1982-03-23 E. I. Du Pont De Nemours And Company Ionic hydrocarbon polymers having improved adhesion to nylon
DE2908397A1 (de) * 1979-03-03 1980-09-04 Akerlund & Rausing Ab Verfahren zum verschliessen eines kartonbehaelters und vorrichtung zur durchfuehrung des verfahrens
US4410482A (en) * 1979-03-06 1983-10-18 E. I. Du Pont De Nemours & Co. Process for making laminar articles of polyolefin and a condensation polymer
US4248990A (en) * 1979-04-05 1981-02-03 E. I. Du Pont De Nemours & Company Nonrandom copolymers of ethylene and unsaturated acid
US4252924A (en) * 1979-04-05 1981-02-24 E. I. Du Pont De Nemours And Company Continuous process for the preparation of nonrandom ethylene/acid copolymer
US4220733A (en) * 1979-05-01 1980-09-02 E. I. Du Pont De Nemours And Company Thermally stable, flame-retardant polymers
WO1980002429A1 (en) * 1979-05-07 1980-11-13 Du Pont Improved hot melt adhesive composition
US4284542A (en) * 1979-05-07 1981-08-18 E. I. Du Pont De Nemours And Company Hot melt adhesive composition
JPS56140197A (en) * 1980-03-31 1981-11-02 Mitsui Petrochemical Ind Aluminum laminated paper
CA1147617A (en) * 1979-06-29 1983-06-07 Akira Hayashi Metal-deposited paper and method for production thereof
US4247563A (en) * 1979-10-23 1981-01-27 American Can Company Labelled package for low temperature use
US4293664A (en) * 1979-12-27 1981-10-06 Union Carbide Corporation Cook-in film containing a blend of ionomer and elastomer
US4366291A (en) * 1980-03-24 1982-12-28 The Firestone Tire & Rubber Company Thermally reversible copolymers and process for the preparation thereof
US4307210A (en) * 1980-03-24 1981-12-22 The Firestone Tire & Rubber Company Thermally reversible copolymers and process for the preparation thereof
US4373068A (en) * 1980-03-24 1983-02-08 The Firestone Tire & Rubber Company Thermally reversible copolymers and process for the preparation thereof
US4363897A (en) * 1980-03-24 1982-12-14 The Firestone Tire & Rubber Company Thermally reversible copolymers and process for the preparation thereof
US4414359A (en) * 1980-03-24 1983-11-08 The Firestone Tire & Rubber Company Diene-containing rubber compositions having improved green strength
DE3115860A1 (de) * 1980-04-22 1982-02-04 Konishiroku Photo Industry Co., Ltd., Tokyo "waermeempfindliches aufzeichnungsmaterial und unter seiner verwendung durchgefuehrtes aufzeichnungsverfahren"
AR243919A1 (es) * 1980-07-03 1993-09-30 Akzo Nv Composicion de recubrimiento de secado fisico.
US4346196A (en) * 1980-09-10 1982-08-24 E. I. Du Pont De Nemours And Company Heat seal composition comprising a blend of metal neutralized polymers
US4469754A (en) * 1980-09-10 1984-09-04 E. I. Du Pont De Nemours And Company Heat seal composition
US4283317A (en) * 1980-09-15 1981-08-11 E. I. Du Pont De Nemours And Company Wax-free, hot melt adhesive compositions
US4478978A (en) * 1980-10-20 1984-10-23 E. I. Du Pont De Nemours And Company Toughened polyamide blends
JPS6056724B2 (ja) * 1980-10-22 1985-12-11 株式会社クラレ 吸水性樹脂の製造方法
US4337298A (en) * 1980-11-19 1982-06-29 Gulf Oil Corporation Polymer compositions and laminates produced by bonding or coextrusion
US4359440A (en) * 1980-11-24 1982-11-16 Gulf Oil Corporation Coextrusion process for preparing a composite polymer film construction
US4412040A (en) * 1981-01-02 1983-10-25 Allied Corporation Low molecular weight copolymer salts as lubricants in plastics
DE3174146D1 (en) * 1980-12-22 1986-04-24 Allied Corp Low molecular weight copolymer salts
US4381376A (en) * 1980-12-29 1983-04-26 Allied Corporation Preparation of low molecular weight copolymer salts
DE3122424C2 (de) * 1980-12-24 1985-05-30 Gust. Alberts Gmbh & Co Kg, 5974 Herscheid Sicherungsbeschlag gegen unbefugtes Hochschieben eines Rolladens
US4302511A (en) * 1980-12-29 1981-11-24 Allied Corporation Polyamide laminates containing copper salts
US4327199A (en) * 1981-01-19 1982-04-27 Monsanto Company Thermoplastic crystalline polyester modified acrylic copolymer rubber
US4387188A (en) * 1981-02-23 1983-06-07 E. I. Du Pont De Nemours And Company Molding resins based on blends of acid copolymer/linear polyolefin/reinforcing fiber
US4338411A (en) * 1981-02-26 1982-07-06 Monsanto Company Modified resins
US4444817A (en) * 1981-03-04 1984-04-24 E. I. Du Pont De Nemours And Company Laminar articles of polyolefin and a condensation polymer
DE3108983C2 (de) * 1981-03-10 1986-02-20 Gebr. Sträb GmbH & Co, 7317 Wendlingen Rolladensicherung
US4348501A (en) * 1981-04-27 1982-09-07 Monsanto Company Thermoplastic compositions of epichlorohydrin rubber and carboxy-ethylene polymer resin
US4371583A (en) * 1981-05-04 1983-02-01 A. Schulman, Inc. Modified ionomer blend and laminated article
US4438162A (en) 1981-05-04 1984-03-20 A. Schulman, Inc. Modified ionomer blend and application thereof
US4404325A (en) * 1981-05-11 1983-09-13 Allied Corporation High impact nylon composition containing copolymer esters and ionic copolymers
US4442158A (en) * 1981-06-01 1984-04-10 Distler James A Food package of plastic laminate
US4409287A (en) * 1981-06-09 1983-10-11 Harrison Thomas B Ski protective device
US4367113A (en) * 1981-06-29 1983-01-04 Gulf Oil Corporation Multicomponent polymer compositions
US4603172A (en) * 1981-09-25 1986-07-29 Allied Corporation Low molecular weight copolymer salts as dispersion aids in plastics
US4401256A (en) * 1981-12-10 1983-08-30 Mobil Oil Corporation Laminar thermoplastic films, bags thereof
US4399263A (en) * 1981-12-24 1983-08-16 E. I. Du Pont De Nemours & Co. Modification of ethylene/acrylate/carboxylic polymer
AU1338883A (en) * 1982-02-05 1983-08-25 Sheldon M. Atlas Antistatic fabrics incorporating specialty textile fibers having high moisture regain and articles produced therefrom
US4420580A (en) * 1982-02-08 1983-12-13 The Dow Chemical Company Method for preparing filled polyolefin resins and the resin made therefrom
US5120369A (en) * 1982-04-15 1992-06-09 The United States Of America As Represented By The Secretary Of The Navy Hazardous material removal using strippable coatings
US4486319A (en) * 1982-09-27 1984-12-04 Armco, Inc. Microporous ionomer polymer lubricating composition
DE3373909D1 (en) * 1982-12-28 1987-11-05 Du Pont Ionomers having improved low temperature properties
US4690981A (en) * 1983-03-21 1987-09-01 E. I. Du Pont De Nemours And Company Ionomers having improved low temperature properties
US4517330A (en) * 1983-03-30 1985-05-14 Rohm And Haas Company Floor polish composition having improved durability
JPS60501201A (ja) * 1983-05-03 1985-08-01 ボルトン、ネルソン・ピ− 積層安全ガラス
US4663228A (en) * 1983-05-03 1987-05-05 Advanced Glass Systems Corp. Laminated safety glass
US4668574A (en) * 1983-05-03 1987-05-26 Advanced Glass Systems, Corp. Laminated safety glass
US4550141A (en) * 1983-08-22 1985-10-29 E. I. Du Pont De Nemours And Company Blends of ionomer with propylene copolymer
US4539263A (en) * 1983-08-22 1985-09-03 E. I. Du Pont De Nemours And Company Blends of ionomer with propylene copolymer and articles
US4631308A (en) * 1983-09-01 1986-12-23 The Dow Chemical Company Adhesive and coating composition
AU3249984A (en) * 1983-09-01 1985-03-07 Dow Chemical Company, The Hot melt adhesive and coating composition
JPS60110703A (ja) * 1983-10-27 1985-06-17 イー・アイ・デユポン・デ・ニモアス・アンド・カンパニー １００％以上中和した強靭で透明な鉛イオノマー
EP0145000B1 (de) * 1983-12-12 1987-03-25 Takeda Chemical Industries, Ltd. Durch Wärme klebende Harzzusammensetzung und damit laminierte Aluminiumplatte
JPS60155206A (ja) * 1983-12-22 1985-08-15 イ−・アイ・デユポン・デ・ニモアス・アンド・カンパニ− 改善された耐低温屈曲きれつ性を有するアイオノマ−及びその製造法
US4674170A (en) * 1984-01-11 1987-06-23 Athlone Industries, Inc. Method of making a ball having a foamed spherical center core, windings and cover
US4569865A (en) * 1984-03-23 1986-02-11 Susan Shoe Industries Limited Bumper fascia and process to bond ionomers to metal
US4619973A (en) * 1984-08-17 1986-10-28 Advanced Glass Systems, Inc. Ionomer resin films
US4732944A (en) * 1984-08-17 1988-03-22 Advanced Glass Systems, Inc. Ionomer resin films
US4666988A (en) * 1984-10-18 1987-05-19 The Dow Chemical Company Ethylene copolymers reacted with metal oxides
US5231133A (en) * 1984-11-30 1993-07-27 Dupont Mitsui Polychemicals Co., Ltd. Thermoplastic reaction product of ethylene/unsaturated carboxylic acid copolymer, amine compound and polyepoxy resin
US4851473A (en) * 1985-01-15 1989-07-25 E. I. Du Pont De Nemours And Company High impact resistant polyamide
DE3506682A1 (de) * 1985-02-26 1986-09-25 Basf Ag, 6700 Ludwigshafen Verfahren zur ionischen vernetzung eines ethylencopolymerisats
DE3506685A1 (de) * 1985-02-26 1986-08-28 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung eines ionisch vernetzten ethylencopolymerisates
JPS61209205A (ja) * 1985-03-13 1986-09-17 Nippon Petrochem Co Ltd 架橋された低分子量３元共重合体
US4623692A (en) 1985-03-14 1986-11-18 S. C. Johnson & Son, Inc. Process for preparing an aqueous cut of a ligand-free monomer/maleic anhydride polymer and product
US4730019A (en) * 1985-03-14 1988-03-08 S. C. Johnson & Son, Inc. Process for preparing an aqueous cut of a ligand-free monomer/maleic anhydride polymer and product
GB8508461D0 (en) * 1985-04-01 1985-05-09 Nicholson J W Coating processes
US4954568A (en) * 1985-08-16 1990-09-04 Shell Oil Company Impact resistant blends of thermoplastic polyesters and modified block copolymers
US4988765A (en) * 1985-08-16 1991-01-29 Shell Oil Company High impact resistant blends of thermoplastic polyamides and modified diblock copolymers
US4695055A (en) * 1985-11-04 1987-09-22 Newcomb Nelson F Illuminated translucent golf ball
DE3631005A1 (de) * 1985-11-21 1987-05-27 Erdoelchemie Gmbh Ionomermodifiziertes polyethylen, verfahren zu seiner herstellung und seine verwendung als folienmaterial
US4766174A (en) * 1986-01-02 1988-08-23 E. I. Du Pont De Nemours And Company Process for preparing melt-processible aluminum ionomer blends
US4878674A (en) * 1986-01-06 1989-11-07 Newcomb Nelson F Illuminated translucent golf ball
US5061757A (en) * 1986-02-14 1991-10-29 Bemis Company, Inc. High impact strength polyamide blends and method for preparation thereof
US4702985A (en) * 1986-04-28 1987-10-27 E. I. Du Pont De Nemours And Company Aminoalcohols as adjuvant for liquid electrostatic developers
US4663264A (en) * 1986-04-28 1987-05-05 E. I. Du Pont De Nemours And Company Liquid electrostatic developers containing aromatic hydrocarbons
US4702984A (en) * 1986-04-30 1987-10-27 E. I. Dupont De Nemours And Company Polybutylene succinimide as adjuvant for electrostatic liquid developer
US4933405A (en) * 1986-06-10 1990-06-12 The Dow Chemical Company Homogeneous copolymerization of non-polar monomers with ionic amphiphilic monomers
US5159035A (en) * 1986-06-10 1992-10-27 The Dow Chemical Company Homogenous copolymerization of non-polar monomers with ionic amphiphilic monomers
US4716202A (en) * 1986-08-22 1987-12-29 E. I. Du Pont De Nemours And Company Preparation of aluminum ionomers of carboxylic acid copolymers
US4789386A (en) * 1986-09-18 1988-12-06 The Dow Chemical Company Metal ionomer membranes for gas separation
US4758630A (en) * 1986-10-27 1988-07-19 Richardson-Vicks Inc. Denture stabilizing zinc and strontium salts of ave/ma copolymer
US5189120A (en) * 1986-11-20 1993-02-23 Basf Aktiengesellschaft Peroxide-free grafting of homopolymers and copolymers of ethylene having densities less than 0.930 g/cm3, and use of the graft copolymers for the preparation of ionomers or adhesion promoters
US5194509A (en) * 1986-11-20 1993-03-16 Basf Aktiengesellschaft Peroxide-free grafting of homopolymers and copolymers of ethylene having densities equal to or greater than 0.930 g/cm3, and use of the graft copolymers for the preparation of ionomers of adhesion promoters
GB8628658D0 (en) * 1986-12-01 1987-01-07 Du Pont Canada Dyeing of polymers
US4870197A (en) * 1986-12-12 1989-09-26 Exxon Chemical Patents Inc. Method for preparing salts of polyolefinic substituted dicarboxylic acids
JP2682623B2 (ja) * 1987-03-13 1997-11-26 株式会社リコー 電子写真用現像剤
JPH0678384B2 (ja) * 1987-04-30 1994-10-05 出光興産株式会社 アイオノマ−樹脂およびその製造法
DE3718447A1 (de) * 1987-06-02 1988-12-15 Basf Ag Polymerisat-ammoniumsalze
US4871823A (en) 1987-09-11 1989-10-03 S. C. Johnson & Son, Inc. 1-Alkene/excess maleic anhydride polymers
US4859752A (en) * 1987-09-11 1989-08-22 S. C. Johnson & Son, Inc. Alkene/excess maleic anhydride polymer manufacture
US4802886A (en) * 1987-09-25 1989-02-07 Du Pont Canada Inc. Continuous process for the dyeing of polymers
USH1485H (en) * 1987-12-31 1995-09-05 Shell Oil Co. High impact resistant blends of thermoplastic polyamides and modified triblock copolymers
US4884814A (en) * 1988-01-15 1989-12-05 Spalding & Evenflo Companies, Inc. Golf ball
US5082697A (en) * 1988-02-17 1992-01-21 The Dow Chemical Company Polymer salt complex for fiber or fabric treatment
JP2591646B2 (ja) * 1988-03-24 1997-03-19 日本ゼオン株式会社 耐寒性が改良されたゴム組成物
DE3822069A1 (de) * 1988-06-30 1990-01-18 Basf Ag Verfahren zur ionischen vernetzung eines ethylencopolymerisates, ionisch vernetzte ethylencopolymerisate und deren verwendung als haftvermittler, spritzgussartikel oder beschichtungsfolie
DE3822067A1 (de) * 1988-06-30 1990-02-22 Basf Ag Verfahren zur herstellung von ionisch vernetzten ethylencopolymerisaten, ionisch vernetzte ethylencopolymerisate und deren verwendung als folien, kabelummantelungen und haftvermittler
DE3822068A1 (de) * 1988-06-30 1990-03-01 Basf Ag Verfahren zur ionischen vernetzung eines ethylencopolymerisats, ionisch vernetzte ethylencopolymerisate und deren verwendung als haftvermittler, spritzgussartikel, beschichtungsfolien oder kabelisoliermaterialien
DE3830008A1 (de) * 1988-09-03 1990-03-15 Basf Ag Elektrische kabel, die isolierungen auf basis von ethylenpolymerisaten mit hoher widerstandsfaehigkeit gegenueber der bildung von wasserbaeumchen enthalten
DE3830007A1 (de) * 1988-09-03 1990-03-15 Basf Ag Verfahren zur herstellung von aminmodifizierten ethylen-carbonsaeure-copolymerisaten, derartige copolymerisate und ihre verwendung fuer haftvermittler und kabelummantelungen
US4944906A (en) * 1988-10-11 1990-07-31 Spirex Corporation Methods of injection molding and extruding wet hygroscopic ionomers
DE3837324A1 (de) * 1988-11-03 1990-05-10 Basf Ag Lichtempfindliches aufzeichnungsmaterial
US4956412A (en) * 1988-11-09 1990-09-11 Shell Oil Company Polymer blend
US4929407A (en) * 1988-12-06 1990-05-29 Acushnet Company Process of making a golf ball cover
US4870133A (en) * 1988-12-16 1989-09-26 Shell Oil Company Polymer blend of polyketone polymers with tetrafluoroethylene
US4983673A (en) * 1988-12-22 1991-01-08 Shell Oil Company High impact resistant blends of thermoplastic polyamides and modified diblock copolymers
US4900789A (en) * 1988-12-22 1990-02-13 Shell Oil Company Polymer blend of carbon monoxide/olefin copolymer and conjugated alkadiene
JP3124533B2 (ja) * 1989-02-06 2001-01-15 住友ゴム工業株式会社 ゴルフボール
DE3905947A1 (de) * 1989-02-25 1990-09-06 Basf Ag Optisch transparente polymerlegierung und ihre verwendung in formmassen, formteilen, folien, ueberzuegen, klebmitteln und lichtempfindlichen aufzeichnungselementen
US5150906A (en) * 1989-03-10 1992-09-29 Lisco, Inc. Multi-piece golf balls and methods of manufacture
US5084515A (en) * 1989-03-31 1992-01-28 Shell Oil Company Polymer blend
US5071916A (en) * 1989-04-17 1991-12-10 Shell Oil Company Blends of linear alternating polyketones and partially neutralized acidic polymers
US5003012A (en) * 1989-04-28 1991-03-26 Shell Oil Company Neutralization of polymeric acid sites
US5000459A (en) * 1989-07-05 1991-03-19 Acushnet Company Golf ball cover
US5036134A (en) * 1989-08-23 1991-07-30 The Glidden Company Ionomeric coatings
US5155162A (en) * 1989-08-23 1992-10-13 The Glidden Company Ionomeric coatings
US5034452A (en) * 1989-08-23 1991-07-23 The Glidden Company Ionomeric coatings neutralized with zinc carbonate
US5157073A (en) * 1989-08-23 1992-10-20 The Glidden Company Ionomerice coatings neutralized with zinc carbonate
FR2651793B1 (fr) * 1989-09-14 1991-12-06 Cassou Robert Tubes ou paillettes pour la conservation cryogenique d'echantillons biologiques tels que virus, et procede de remplissage.
US4992486A (en) * 1989-11-14 1991-02-12 E. I. Du Pont De Nemours And Company White-pigmented, melt-stable ethylene/carboxylic acid copolymer compositions
US5298258A (en) * 1989-12-28 1994-03-29 Nitto Denko Corporation Acrylic oily gel bioadhesive material and acrylic oily gel preparation
US5120791A (en) * 1990-07-27 1992-06-09 Lisco, Inc. Golf ball cover compositions
US6407176B1 (en) * 1990-07-27 2002-06-18 Spalding Sports Worldwide, Inc. Golf ball cover compositions
US6193616B1 (en) 1990-07-27 2001-02-27 Spalding Sports Worldwide, Inc. Low modulus covered golf balls
US5328959A (en) * 1990-07-27 1994-07-12 Lisco, Inc. Golf ball cover compositions
US5197740A (en) * 1990-08-02 1993-03-30 Ram Golf Corporation Golf ball having improved cover composition
US5294672A (en) * 1990-08-08 1994-03-15 Exxon Research & Engineering Co. Polyethylene reinforced elastomeric blend compositions
US5140710A (en) * 1990-09-04 1992-08-25 Mark Rademacher Bilayer X-ray eye shield
US5492972A (en) * 1990-12-10 1996-02-20 Acushnet Company Golf ball cover
US5837775A (en) * 1990-12-10 1998-11-17 Acushnet Company Golf ball composition
EP0571526B1 (de) * 1991-02-14 1997-04-02 S.C. JOHNSON &amp; SON, INC. Polymermischungen
US5160536A (en) * 1991-04-18 1992-11-03 Acushnet Company Printing ink for golf balls
WO1992019656A1 (en) * 1991-04-25 1992-11-12 Technical Coatings Laboratory, Inc. Coating composition and method
BE1004795A3 (fr) * 1991-05-07 1993-02-02 Eurofloor Sa Procede de production de revetements de sols ou de murs a base de polyolefines et produits obtenus.
US5292794A (en) * 1991-07-01 1994-03-08 Alliedsignal Inc. Removable protective coating composition for spray painting areas
US5314187A (en) * 1991-07-26 1994-05-24 Wilson Sporting Goods Co. Golf ball with improved cover
CA2076727A1 (en) * 1991-08-30 1993-03-01 Richard T. Mayes Alkaline-etch resistant dry film photoresist
US5516847A (en) * 1991-09-03 1996-05-14 Lisco, Inc. Golf ball cover having an ionic copolymer/non-ionic copolymer blend
DE4205418C2 (de) * 1992-02-22 1993-11-18 Du Pont Bei der Verarbeitung in der Schmelze verbrauchbare Packung
US5223573A (en) * 1992-02-28 1993-06-29 General Electric Company PC/ABS blends exhibiting reduced gloss
ZA933185B (en) 1992-05-08 1994-05-23 Dick Co Ab Encapsulated magnetic particles pigments and carbon black compositions and methods related thereto
FR2694538B1 (fr) * 1992-08-10 1994-12-23 Matieres Plastiques Ste Lorrai Procédé et dispositif d'emballage d'objets à ouverture rapide.
US5562989A (en) * 1992-08-18 1996-10-08 E. I. Du Pont De Nemours And Company Method of protecting metal against corrosion with thermoplatic coatings
US5284489A (en) * 1992-08-19 1994-02-08 United States Surgical Corporation Filament fabricated from a blend of ionomer resin and nonionic thermoplastic resin
US5385957A (en) * 1992-08-24 1995-01-31 Videojet Systems International, Inc. Hotmelt ink jet comprising ionomers having melting points from about 50° C. to about 130° or a softening point below about 80° C., and an image-forming agent
CA2105947A1 (en) * 1992-09-14 1994-03-15 Cheng-Kung Liu Ionomeric suture its manufacture and method of use
JP2737587B2 (ja) * 1992-12-11 1998-04-08 富士ゼロックス株式会社 静電写真用液体現像剤
US5266133A (en) * 1993-02-17 1993-11-30 Sika Corporation Dry expansible sealant and baffle composition and product
US5883188A (en) * 1993-04-28 1999-03-16 The Dow Chemical Company Paintable olefinic interpolymer compositions
US6261193B1 (en) 1993-04-28 2001-07-17 Spalding Sports Worldwide, Inc. Low spin golf ball utilizing perimeter weighting
US6193618B1 (en) 1993-04-28 2001-02-27 Spalding Sports Worldwide, Inc. Low spin golf ball comprising a mantle with a cellular or liquid core
US6162134A (en) 1993-04-28 2000-12-19 Spalding Sports Worldwide, Inc. Low spin golf ball comprising silicone material
US6676876B2 (en) 1993-04-28 2004-01-13 The Top-Flite Golf Company Method of molding a low spin golf ball comprising silicone material
EP0622433B1 (de) * 1993-04-30 1997-04-23 Rohm And Haas Company Verbesserte Adhäsiv-Zusammensetzungen für Laminate
US5529874A (en) * 1993-05-07 1996-06-25 Fuji Xerox Co., Ltd. Liquid developer for electrophotography
US6648777B2 (en) 1993-06-01 2003-11-18 Callaway Golf Company Multi-layer golf ball
US6663508B1 (en) 1993-06-01 2003-12-16 Callaway Golf Company Multi-layer golf ball with reaction injection molded polyurethane component
US6824476B2 (en) 1993-06-01 2004-11-30 Callaway Golf Company Multi-layer golf ball
US7494427B2 (en) * 2001-11-05 2009-02-24 Callaway Golf Company Multi-layer golf ball
US6290614B1 (en) 1998-03-18 2001-09-18 Spalding Sports Worldwide, Inc. Golf ball which includes fast-chemical-reaction-produced component and method of making same
US6506130B2 (en) 1993-06-01 2003-01-14 Spalding Sports Worldwide, Inc. Multi layer golf ball
US6210293B1 (en) 1993-06-01 2001-04-03 Spalding Sports Worldwide, Inc. Multi-layer golf ball
US6695718B2 (en) 1993-06-01 2004-02-24 The Top-Flite Golf Company Golf ball with sulfur cured inner core component
US6548618B2 (en) * 1993-06-01 2003-04-15 Spalding Sports Worldwide, Inc. Golf ball having dual core and thin polyurethane cover formed by RIM
US6855073B1 (en) * 1998-03-18 2005-02-15 Callaway Golf Company Golf ball which includes fast-chemical-reaction-produced component and method of making same
US6287217B1 (en) 1993-06-01 2001-09-11 Spalding Sports Worldwide, Inc. Multi-layer golf ball
US6638185B2 (en) 1993-06-01 2003-10-28 The Top-Flite Golf Company Multi-layer golf ball
US5691418A (en) * 1993-06-18 1997-11-25 E. I. Du Pont De Nemours And Company Soft ionomer compositions and blends thereof and use thereof as golf ball structural materials
JP2910516B2 (ja) 1993-07-08 1999-06-23 ブリヂストンスポーツ株式会社 スリーピースソリッドゴルフボール
EP1184166A3 (de) * 1993-09-20 2004-05-12 The Amtico Company Limited Bodenbeläge
AU1084495A (en) * 1993-10-27 1995-05-22 Chevron Chemical Company Low-haze ionomers of copolymers of alpha-olefins, carboxylic acid esters, and optional comonomers, and processes for making and acidifying these ionomers
US5631328A (en) * 1993-10-27 1997-05-20 Chevron Chemical Company Low-haze ionomers of copolymers of alpha-olefins, carboxylic acid esters, and optional comonomers, and processes for making and acidifying these ionomers
US5731387A (en) * 1994-07-11 1998-03-24 Adhesives Research, Inc. Ionically-crosslinked water-absorbent graft copolymer
US5554120A (en) * 1994-07-25 1996-09-10 Advanced Cardiovascular Systems, Inc. Polymer blends for use in making medical devices including catheters and balloons for dilatation catheters
EP0797625B1 (de) * 1994-12-14 2002-06-05 Du Pont-Mitsui Polychemicals Co., Ltd. Thermoplastische harzzusammensetzung und seine verwendung
US5494883A (en) * 1994-12-21 1996-02-27 Eastman Kodak Company Extruded receiver of a transition metal ion salt of a copolymer
AU2856195A (en) 1995-01-17 1996-07-25 Wilson Sporting Goods Company Golf ball with clear cover
US5631324A (en) * 1995-06-07 1997-05-20 Acushnet Company Golf ball covers
US6391955B1 (en) 1995-06-07 2002-05-21 Acushnet Company Golf ball compositions containing oxa esters
US7041721B2 (en) * 1995-06-07 2006-05-09 Acushnet Company Highly neutralized polymer golf ball compositions including oxa acids and methods of making same
US6255361B1 (en) 1995-11-21 2001-07-03 Acushnet Company Golf ball compositions and method of making same
US5580927A (en) * 1995-09-29 1996-12-03 E. I. Du Pont De Nemours And Company Ionomers with improved high temperature properties and improved moldability
WO1997019114A1 (en) * 1995-11-21 1997-05-29 Acushnet Company Golf ball cover compositions and method of making same
US6486250B1 (en) 1995-11-21 2002-11-26 Acushnet Company Golf ball compositions comprising saponified polymer and polyamide blends
US6469105B1 (en) 1995-11-21 2002-10-22 Acushnet Company Compositions useful for forming the layers of a golf ball and method of making same
JPH09160309A (ja) * 1995-12-14 1997-06-20 Fuji Xerox Co Ltd 静電写真用液体現像剤及び画像形成方法
US6517451B2 (en) 1996-02-23 2003-02-11 Christopher Cavallaro Golf ball composition
US6218453B1 (en) 1998-02-23 2001-04-17 Acushnet Company Golf ball composition
US5902869A (en) * 1996-03-22 1999-05-11 E. I. Du Pont De Nemours And Company Thermally stable ethylene/acid copolymers
US6090454A (en) * 1996-03-28 2000-07-18 E.I. Du Pont De Nemours And Company Polymer coating for low electrically conductive materials
EP0798053A1 (de) * 1996-03-28 1997-10-01 Du Pont De Nemours International S.A. Beschichtigungsverfahren mit Polymeren auf Substraten mit geringer elektrischer Leitfähigkeit
US6576305B2 (en) 1996-06-07 2003-06-10 Saint-Gobain Vetrotex America, Inc. Package having a multilayer film disposed around a layered coil of filament strands
US5962140A (en) * 1996-06-25 1999-10-05 Acushnet Company Golf ball comprising fluoropolymer
US5691066A (en) * 1996-06-25 1997-11-25 Acushnet Company Golf ball comprising fluoropolymer and method of making same
US6465107B1 (en) * 1996-09-13 2002-10-15 Dupont Canada Inc. Silicone-containing polyolefin film
US6120393A (en) * 1996-09-16 2000-09-19 Spalding Sports Worldwide, Inc. Low spin golf ball comprising a mantle having a hollow interior
US6689483B1 (en) 1996-12-12 2004-02-10 E. I. Du Pont De Nemours And Company Packaging composition
US6100340A (en) * 1997-01-16 2000-08-08 Acushnet Company Golf ball compositions containing high crystalline acid copolymers and their ionomer derivatives
US5973046A (en) * 1997-02-18 1999-10-26 E. I. Du Pont De Nemours And Company Modified-ionomers having improved properties and processability
US5789475A (en) * 1997-02-18 1998-08-04 E. I. Du Pont De Nemours And Company Adipic acid modified-ionomers having improved properties and processability
US6207760B1 (en) 1997-02-25 2001-03-27 Acushnet Company Golf ball cover compositions
CA2250011A1 (en) * 1997-02-28 1998-09-03 E.I. Du Pont De Nemours And Company New ionomers based on copolymers of ethylene with both mono- and dicarboxylic acids and polyamide blends containing these ionomers
AR012582A1 (es) 1997-04-14 2000-11-08 Dow Global Technologies Inc Composiciones polimericas de elongacion mejorada y formulaciones adhesivas de fusion en caliente que incluyen dicha composicion
US6100321A (en) * 1997-04-15 2000-08-08 E. I. Du Pont De Nemours And Company Stearic-modified ionomers for golf balls
US6565457B1 (en) 1997-07-14 2003-05-20 Spalding Sports Worldwide, Inc. Golf ball containing high density fillers in the core and cover
US6277037B1 (en) 1997-10-03 2001-08-21 Performance Dynamics Llc Golf ball with water immersion indicator
US6358160B1 (en) * 1997-10-03 2002-03-19 Performance Dynamics Llc Golf ball with water immersion indicator
US6103787A (en) * 1998-03-03 2000-08-15 Acushnet Company Golf ball cover compositions
US20050282659A1 (en) * 1998-03-18 2005-12-22 Kennedy Thomas J Iii High compression multi-layer RIM golf balls
US7320648B2 (en) * 1998-03-18 2008-01-22 Callaway Golf Company Golf ball
US20050049082A1 (en) * 1998-03-18 2005-03-03 Callaway Golf Company Golf ball
US20030176619A1 (en) * 1998-03-18 2003-09-18 Viktor Keller Polyurethane covered golf balls
US6716954B2 (en) 1998-03-18 2004-04-06 Callaway Golf Company Golf ball formed from a polyisocyanate copolymer and method of making same
CA2439715A1 (en) * 1998-03-18 2002-09-26 The Top-Flite Golf Company Apparatus and method for making a golf ball
US7244196B2 (en) * 1998-03-18 2007-07-17 Callaway Golf Company Golf ball which includes fast-chemical-reaction-produced component and method of making same
US7160210B2 (en) * 1998-03-18 2007-01-09 Callaway Golf Company Golf ball which includes fast-chemical-reaction-produced component and method of making same
DE69902586D1 (en) * 1998-04-08 2002-09-26 Du Pont Expandierte ethylencopolymere
US6077593A (en) * 1998-04-17 2000-06-20 Armstrong World Industries, Inc. Durable edge ceiling board
EP1759832A1 (de) 1998-05-14 2007-03-07 E.I.Du pont de nemours and company Glaslaminate für bedrohungssichere Fenstersysteme
US6114455A (en) 1998-05-18 2000-09-05 Acushnet Company Golf ball composition comprising high acid and VLMI ionomers
WO2000006619A1 (en) 1998-07-27 2000-02-10 E.I. Du Pont De Nemours And Company Mixed-metal-neutralized-copolymer-resins for metal coating powder applications
US6207784B1 (en) 1998-07-28 2001-03-27 Acushnet Company Golf ball comprising anionic polyurethane or polyurea ionomers and method of making the same
DE19838668A1 (de) * 1998-08-26 2000-03-02 Basf Ag Metallsalz vernetzte Klebstoffe
US6399684B1 (en) 1998-08-26 2002-06-04 E. I. Du Pont De Nemours & Company Polymer-polyamide blends having a phosphorous containing additive
US6632518B1 (en) 1998-10-14 2003-10-14 E. I. Du Pont De Nemours And Company Fluoropolymer film structures and laminates produced therefrom
US6953820B2 (en) * 1999-10-21 2005-10-11 E. I. Du Pont De Nemours And Company Highly-neutralized ethylene copolymers and their use in golf balls
US20050267240A1 (en) * 1999-10-21 2005-12-01 Chen John C Moisture resistant highly-neutralized ethylene copolymers and their use in golf balls
US6777472B1 (en) * 1998-10-21 2004-08-17 E. I. Du Pont De Nemours And Company Highly-neutralized ethylene copolymers
US6653382B1 (en) * 1999-10-21 2003-11-25 E. I. Du Pont De Nemours And Company Highly-neutralized ethylene copolymers and their use in golf balls
DE19957843A1 (de) * 1998-12-03 2000-06-08 Sumitomo Chemical Co Mehrschichtfolie
JP2000279554A (ja) 1999-03-30 2000-10-10 Bridgestone Sports Co Ltd ゴルフボール
US6284840B1 (en) * 1999-04-02 2001-09-04 Acushnet Company Golf ball core compositions containing high Vicat softening temperature, resilient thermoplastic materials
US6737151B1 (en) 1999-04-22 2004-05-18 E. I. Du Pont De Nemours And Company Glass laminates having improved structural integrity against severe impacts
EP1175340B2 (de) 1999-04-30 2006-03-08 E.I. Du Pont De Nemours And Company Verpackung zum verlängern der haltbarkeit von nahrungsmitteln
WO2000073384A2 (en) 1999-06-01 2000-12-07 E.I. Du Pont De Nemours And Company Soft ionomer compositions and blends thereof for golf ball covers
US6608136B1 (en) 1999-07-26 2003-08-19 E. I. Du Pont De Nemours And Company Polyphenylene sulfide alloy composition
WO2001009199A1 (en) 1999-07-28 2001-02-08 E.I. Du Pont De Nemours And Company High melt swell polymer
US6152836A (en) * 1999-10-06 2000-11-28 Wilson Sporting Goods Co. Golf ball with a cover which includes polyurethane rubber
NL1013280C1 (nl) 1999-10-13 2001-04-17 Adrianus Theodorus Josephus Va Werkwijze en polymeerfolies voor het verpakken van vers vlees.
JP3729243B2 (ja) * 1999-10-25 2005-12-21 ブリヂストンスポーツ株式会社 ゴルフボール用材料及びゴルフボール
US7202303B2 (en) * 1999-12-03 2007-04-10 Acushnet Company Golf ball layers formed of polyurethane-based and polyurea-based compositions incorporating block copolymers
US20040266971A1 (en) * 1999-12-03 2004-12-30 Shenshen Wu Golf equipment incorporating polyamine/carbonyl adducts as chain extenders and methods of making same
US8455609B2 (en) 1999-12-03 2013-06-04 Acushnet Company Castable polyurea formulation for golf ball covers
US6476176B1 (en) 1999-12-17 2002-11-05 Acushnet Company Golf ball comprising saturated polyurethanes and methods of making the same
US6835794B2 (en) * 1999-12-17 2004-12-28 Acushnet Company Golf balls comprising light stable materials and methods of making the same
US6958379B2 (en) 1999-12-03 2005-10-25 Acushnet Company Polyurea and polyurethane compositions for golf equipment
US6435986B1 (en) 1999-12-03 2002-08-20 Acushnet Company Golf ball comprising water resistant polyurethane elastomers and methods of making the same
US7786243B2 (en) 2002-02-06 2010-08-31 Acushnet Company Polyurea and polyurethane compositions for golf equipment
US6964621B2 (en) * 1999-12-03 2005-11-15 Acushnet Company Water resistant polyurea elastomers for golf equipment
US7211624B2 (en) 1999-12-03 2007-05-01 Acushnet Company Golf ball layers formed of polyurethane-based and polyurea-based compositions incorporating block copolymers
US7214738B2 (en) * 1999-12-03 2007-05-08 Acushnet Company Golf ball layers formed of polyurethane-based and polyurea-based compositions incorporating block copolymers
US7772354B2 (en) * 1999-12-03 2010-08-10 Acushnet Company Golf ball layer compositions comprising modified amine curing agents
US7217764B2 (en) 1999-12-03 2007-05-15 Acushnet Company Golf ball layers formed of polyurethane-based and polyurea-based compositions incorporating block copolymers
US6867279B2 (en) * 1999-12-17 2005-03-15 Acushnet Company Golf ball comprising saturated polyurethanes and methods of making the same
US8227565B2 (en) * 1999-12-17 2012-07-24 Acushnet Company Polyurethane compositions for golf balls
US7041769B2 (en) * 1999-12-17 2006-05-09 Acushnet Company Polyurethane compositions for golf balls
US6369125B1 (en) 1999-12-23 2002-04-09 Spalding Sports Worldwide, Inc. Game balls with cover containing post crosslinkable thermoplastic polyurethane and method of making same
US7148266B2 (en) * 1999-12-23 2006-12-12 Callaway Golf Company Game balls with cover containing post crosslinkable thermoplastic polyurethane and method of making same
JP3758922B2 (ja) 1999-12-24 2006-03-22 ブリヂストンスポーツ株式会社 ゴルフボール用材料及びゴルフボール
JP3772251B2 (ja) 2000-02-10 2006-05-10 ブリヂストンスポーツ株式会社 マルチピースゴルフボールの製造方法
JP3772252B2 (ja) 2000-02-10 2006-05-10 ブリヂストンスポーツ株式会社 マルチピースゴルフボールの製造方法
NL1014426C2 (nl) * 2000-02-18 2001-08-22 Dsm Nv Ionomere thermoplastische rubber.
US20020033589A1 (en) * 2000-03-13 2002-03-21 Barnes John A. Laminated fabric for airbag
WO2001078981A1 (en) 2000-04-14 2001-10-25 E.I. Dupont De Nemours And Company Multilayer, co-extruded, ionomeric decorative surfacing
JP4793516B2 (ja) 2000-06-09 2011-10-12 ブリヂストンスポーツ株式会社 ゴルフボール用樹脂組成物及びゴルフボール
US6805956B2 (en) 2000-07-20 2004-10-19 E.I. Du Pont De Nemours And Company Process for coating a wire or cable with polyphenylene sulfide alloy and resulting coated wire
US6645623B2 (en) 2000-07-20 2003-11-11 E. I. Du Pont De Nemours And Company Polyphenylene sulfide alloy coated wire
US6391380B1 (en) 2000-08-03 2002-05-21 Stanbee Company, Inc. Stiffener material with self adhesive properties
US6761825B2 (en) 2000-08-04 2004-07-13 I. Du Pont De Nemours And Company Method for removing odors in sterilized water
US6630528B2 (en) 2000-08-10 2003-10-07 E. I. Du Pont De Nemours And Company Antistatic ionomer blend
US6746345B2 (en) * 2000-09-11 2004-06-08 Bridgestone Sports Co., Ltd. Multi-piece solid golf ball
US6723008B2 (en) 2000-09-11 2004-04-20 Bridgestone Sports Co., Ltd. Multi-piece solid golf ball
US6756446B2 (en) * 2002-10-15 2004-06-29 Solvay Engineered Polymers Engineered polyolefin materials with enhanced surface durability
US6403721B1 (en) 2000-09-29 2002-06-11 Solvay Engineered Polymers Engineered polyolefin materials with enhanced surface durability
US6509416B2 (en) 2000-09-29 2003-01-21 Solvay Engineered Polymers Engineered polyolefin materials with enhanced surface durability and methods of making same
US6914094B2 (en) * 2000-09-29 2005-07-05 Solvay Engineered Polymers, Inc. Engineered polyolefin materials with enhanced surface durability
US7351468B2 (en) * 2000-10-26 2008-04-01 E. I. Du Pont De Nemours And Company Interlayers for laminated safety glass with superior de-airing and laminating properties and process for making the same
JP3767683B2 (ja) * 2000-11-22 2006-04-19 ブリヂストンスポーツ株式会社 ゴルフボール用材料の製造方法
JP3767678B2 (ja) 2000-12-13 2006-04-19 ブリヂストンスポーツ株式会社 ゴルフボール用材料の製造方法
US20020146509A1 (en) * 2001-02-06 2002-10-10 Kodokian George K. Micronization process and polymer particles produced therefrom
US6670423B2 (en) * 2001-02-20 2003-12-30 E. I. Du Pont De Nemours And Company Polar ethylene-based polymer, cycloolefin polymer blends
US6696524B2 (en) 2001-02-20 2004-02-24 E. I. Du Pont De Nemours And Company Low Tg ethylene-based polymer, cycloolefin polymer blends
PT1372956E (pt) * 2001-03-08 2008-08-05 Biolog Insel Lothar Moll Gmbh Utilização de ionómeros para impermeabilização de materiais isolantes
US20040161623A1 (en) 2001-03-29 2004-08-19 Domine Joseph D Ionomer laminates and articles formed from ionomer laminates
KR20030085079A (ko) 2001-03-29 2003-11-01 엑손모빌 케미칼 패턴츠 인코포레이티드 이오노머 적층체 및 이오노머 적층체로부터 제조된 제품
US20030114565A1 (en) * 2001-03-29 2003-06-19 Chen John Chu Soft and resilient ethylene copolymers and their use in golf balls
US7429220B2 (en) * 2001-04-13 2008-09-30 Acushnet Company Golf balls containing interpenetrating polymer networks
US6719053B2 (en) 2001-04-30 2004-04-13 Bj Services Company Ester/monoester copolymer compositions and methods of preparing and using same
US20060211518A1 (en) * 2001-06-26 2006-09-21 Sullivan Michael J Multi-Layer Golf Balls Comprising Ionomers with a Percent Neutralization Gradient
US6706816B2 (en) 2001-07-11 2004-03-16 Best Manufacturing Company Accelerator free latex formulations, methods of making same and articles made from same
CA2355972C (en) 2001-08-24 2009-11-17 Shawcor Ltd. Ionomer-insulated electrical connectors
EP1454924B1 (de) * 2001-09-21 2009-03-18 Zeon Corporation Verfahren zur hydrierung von polymeren auf basis von konjugierten dienen, hydrierkatalysatorsysteme und zusammensetzung von basischem polymer auf basis von konjugierten dienen
JP2005533136A (ja) 2001-11-06 2005-11-04 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 抗菌ポリオレフィン製品およびそれらの製造方法
CA2465785A1 (en) * 2001-11-19 2003-05-30 Exxonmobil Chemical Patents Inc. Impact resistant compositions
US6855077B2 (en) * 2001-12-04 2005-02-15 Callaway Golf Company Process and apparatus for producing a golf ball with deep dimples
US20060038321A1 (en) * 2001-12-04 2006-02-23 Callaway Golf Company Method and apparatus for forming deep apertures in a golf ball, and golf ball
US7427193B2 (en) * 2001-12-04 2008-09-23 Callaway Golf Company Method and apparatus for forming a golf ball
US20050215718A1 (en) * 2002-01-04 2005-09-29 Murali Rajagopalan Nanocomposite ethylene copolymer compositions for golf balls
US6569947B1 (en) 2002-01-25 2003-05-27 E. I. Du Pont De Nemours And Company Ionomer/high density polyethylene blends with improved impact
US6596815B1 (en) 2002-01-25 2003-07-22 E. I. Du Pont De Nemours And Company Ionomer/high density polyethylene blends with improved flow
US6756443B2 (en) 2002-01-25 2004-06-29 E. I. Du Pont De Nemours And Company Ionomer/polyamide blends with improved flow and impact properties
US7438940B2 (en) * 2002-04-19 2008-10-21 E. I. Du Pont De Nemours And Company Film and film structures having improved oxygen transmission, forming, and puncture resistances
DE10239985B4 (de) * 2002-08-27 2006-03-30 Ökologische Bausysteme B.I. Moll GmbH & Co. KG Für die Bautechnik geeignete Abdichtungsbänder
US20040043221A1 (en) * 2002-08-30 2004-03-04 3M Innovative Properties Company Method of adhering a film and articles therefrom
US20040202820A1 (en) * 2002-08-30 2004-10-14 3M Innovative Properties Company Perforated electret articles and method of making the same
US6805048B2 (en) 2002-08-30 2004-10-19 3M Innovative Properties Company Method of marking a substrate using an electret stencil
JP2005537358A (ja) * 2002-08-30 2005-12-08 スリーエム イノベイティブ プロパティズ カンパニー 消去可能な物品の製造方法およびその物品
US20040040652A1 (en) * 2002-08-30 2004-03-04 3M Innovative Properties Company Methods for electrostatically adhering an article to a substrate
ES2315558T3 (es) * 2002-12-04 2009-04-01 Key-Tech, Inc. Procedimiento para la impresion termica de una imagen de color sobre un objeto tridimensional utilizando una lamina portadora de colorantes.
DE10341163A1 (de) * 2002-12-19 2004-07-01 Tesa Ag Leicht reißbares Wickelband mit Alkalimetallionen
US6967057B2 (en) * 2002-12-19 2005-11-22 E.I. Du Pont De Nemours And Company Poly(trimethylene dicarboxylate) fibers, their manufacture and use
US20040221526A1 (en) * 2003-04-03 2004-11-11 Rinehart David M. Glass laminates having improved structural integrity against severe stresses for use in stopless glazing applications
US7138166B2 (en) * 2003-04-04 2006-11-21 E. I. Du Pont De Nemours And Company Glass laminates having improved structural integrity against severe stresses for use in external pressure plate glazing applications
US7334371B2 (en) * 2003-04-04 2008-02-26 E.I. Du Pont De Nemours And Company Glass laminates having improved structural integrity against severe stresses for use in external pressure plate glazing applications
US6943214B2 (en) * 2003-05-13 2005-09-13 E. I. Du Pont De Nemours And Company Toughened polyoxymethylene-poly(lactic acid) compositions
US8076000B2 (en) 2003-05-27 2011-12-13 Exxonmobil Chemical Patents Inc. Tie-layer materials for use with ionomer-based films and sheets as skins on other materials
WO2004106058A1 (en) 2003-05-27 2004-12-09 Exxonmobil Chemical Patents Inc. Tie-layer materials for use with ionomer-based films and sheets as skins on other materials
WO2004106057A1 (en) 2003-05-27 2004-12-09 Exxonmobil Chemical Patents Inc. Backing layers and substrates for articles formed from ionomer laminates
WO2004113445A1 (en) * 2003-06-05 2004-12-29 E.I. Dupont De Nemours And Company Scuff resistant compositions comprising ethylene acid copolymers and polyamides
DE602004008466T2 (de) * 2003-06-26 2008-05-15 Key-Tech, Inc. Verfahren zum thermischen drucken eines farbstoffbildes auf ein dreidimensionales objekt durch verwendung flexibler heizelemente
JP4032033B2 (ja) 2003-06-30 2008-01-16 ローム アンド ハース カンパニー 高純度メタクリル酸の製造法
US7091162B2 (en) * 2003-07-03 2006-08-15 Johnsondiversey, Inc. Cured lubricant for container coveyors
JP4304443B2 (ja) * 2003-08-07 2009-07-29 ブリヂストンスポーツ株式会社 ゴルフボール
DE10341123A1 (de) * 2003-09-06 2005-03-31 Tesa Ag Leicht reißbares Wickelband aus coextrudierter Folie
US7151148B2 (en) * 2003-09-16 2006-12-19 Acushnet Company Castable golf ball components using acrylate functional resins
CN1890095A (zh) * 2003-10-07 2007-01-03 纳幕尔杜邦公司 具有改进耐天候性的多层离聚物片材
JP4918360B2 (ja) * 2003-10-07 2012-04-18 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 耐候性表層を有する多層シート
US20060057392A1 (en) * 2003-10-07 2006-03-16 Smillie Benjamin A Multi-layer sheet having a weatherable surface layer
US20050106386A1 (en) * 2003-10-07 2005-05-19 Vogel Randall A. Thermoformable multi-layer sheet
KR20060134920A (ko) * 2003-10-07 2006-12-28 이 아이 듀폰 디 네모아 앤드 캄파니 이오노머 층을 포함하는 다층 시트
US7834092B2 (en) 2003-12-12 2010-11-16 E. I. Du Pont De Nemours And Company Article comprising poly(hydroxyalkanoic acid)
US7381772B2 (en) * 2003-12-12 2008-06-03 E. I. Du Pont De Nemours And Company Toughened poly(lactic acid) compositions
US7595363B2 (en) * 2003-12-12 2009-09-29 E.I. Du Pont De Nemours And Company Toughened poly(hydroxyalkanoic acid) compositions
US20080027178A1 (en) * 2006-07-27 2008-01-31 Julius Uradnisheck Article comprising poly(hydroxyalkanoic acid)
WO2005059290A1 (en) * 2003-12-15 2005-06-30 E.I. Dupont De Nemours And Company Blast resistant glass laminates having improved structural integrity against severe impacts
WO2005058596A1 (en) * 2003-12-16 2005-06-30 E.I. Dupont De Nemours And Company Glass laminates having improved structural integrity against severe impacts comprising a flexible attachment
US7074494B2 (en) 2004-02-19 2006-07-11 E. I. Du Pont De Nemours And Company Flame retardant surface coverings
US7462113B2 (en) * 2004-05-10 2008-12-09 Taylor Made Golf Company, Inc. Two-piece golf ball having an improved core composition
EP1747250A1 (de) * 2004-05-20 2007-01-31 E.I.Du pont de nemours and company Polymere brennstoffsystemkomponenten
AU2005248405B2 (en) * 2004-05-24 2010-07-01 E.I. Dupont De Nemours And Company Polymer blends for peelable and/or permanent seals
US7160954B2 (en) * 2004-06-25 2007-01-09 Acushnet Company Golf ball compositions neutralized with ammonium-based and amine-based compounds
US7767759B2 (en) * 2004-07-16 2010-08-03 Taylor Made Golf Company, Inc. Composition for use in golf balls
US20060030693A1 (en) * 2004-07-27 2006-02-09 Martens Marvin M Process for the preparation of thermoplastic polyamide and polyester compositions exhibiting increased melt flow and articles formed therefrom
US20060025504A1 (en) * 2004-07-29 2006-02-02 Oriani Steven R Process aid for melt processable polymers that contain hindered amine light stabilizer
US20060025510A1 (en) * 2004-08-02 2006-02-02 Dean David M Flame retardant polymer blend and articles thereof
US7135529B2 (en) * 2004-08-09 2006-11-14 Acushnet Company Golf ball comprising saturated rubber/ionomer block copolymers
US20060062850A1 (en) * 2004-09-13 2006-03-23 Chen John C Controlled release antimicrobial polymer compositions
WO2006038505A1 (ja) * 2004-10-07 2006-04-13 Toyo Boseki Kabushiki Kaisha 釣糸
JP5252923B2 (ja) * 2004-10-29 2013-07-31 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 透明なラミネートでの使用に好適な熱可塑性樹脂組成物
AU2005304620A1 (en) * 2004-11-08 2006-05-18 E.I. Dupont De Nemours And Company Toughened polyamide for food packaging and health care applications
US7897685B2 (en) * 2004-12-07 2011-03-01 E. I. Du Pont De Nemours And Company Thermoplastic elastomer compositions
US8709705B2 (en) 2004-12-13 2014-04-29 Pryog, Llc Metal-containing compositions and method of making same
WO2006065660A2 (en) * 2004-12-13 2006-06-22 Hybrid Plastics, Inc. Metal-containing compositions
TW200632019A (en) * 2004-12-20 2006-09-16 Tohcello Co Ltd Stretched film of olefin polymer
AU2005319883B2 (en) * 2004-12-23 2010-07-01 Posco Chrome free composition for metal surface treatment and surface-treated metal sheet
US7156755B2 (en) * 2005-01-26 2007-01-02 Callaway Golf Company Golf ball with thermoplastic material
US7819761B2 (en) 2005-01-26 2010-10-26 Taylor Made Golf Company, Inc. Golf ball having cross-core hardness differential and method for making it
US7591740B2 (en) * 2005-01-26 2009-09-22 Callaway Golf Company Golf ball which includes fast-chemical-reaction-produced component and method of making same
US7175543B2 (en) 2005-01-26 2007-02-13 Callaway Golf Company Golf ball and thermoplastic material
US8177665B2 (en) * 2005-02-01 2012-05-15 Taylor Made Golf Company, Inc. Multi-layer golf ball
US7312267B2 (en) * 2005-02-23 2007-12-25 Callaway Golf Company Golf ball and thermoplastic material
US7612134B2 (en) * 2005-02-23 2009-11-03 Callaway Golf Company Golf ball and thermoplastic material
US20060205832A1 (en) * 2005-03-09 2006-09-14 Dean David M Polymer-ionomer blends and foams thereof
US7264560B2 (en) * 2005-03-10 2007-09-04 Callaway Golf Company Golf ball
US7442736B2 (en) * 2005-06-09 2008-10-28 Acushnet Company Use of nucleating agents to increase the flexural modulus of ionomers
US20070003675A1 (en) * 2005-06-30 2007-01-04 Rau Allen H Packaging materials and structures for compositions including an exothermic agent and a volatile agent
US7909194B2 (en) * 2005-07-01 2011-03-22 Exxonmobil Chemical Patents Inc. Thermoplastic vulcanizates and sealing devices made therewith
US20070020416A1 (en) * 2005-07-22 2007-01-25 Dean David M Blow molded hollow articles and bottles made from trivalent cation neutralized ionomers
US20070035063A1 (en) * 2005-08-10 2007-02-15 Lavallee Gerald A Two-stage reaction injection molded golf ball
US7393289B2 (en) * 2005-08-26 2008-07-01 Bridgestone Sports Co., Ltd. Golf ball material, golf ball and method for preparing golf ball material
US20070069424A1 (en) * 2005-08-30 2007-03-29 Veilleux Thomas A Reaction injection molding assembly for manufacturing a golf ball component
US7524251B2 (en) * 2005-08-30 2009-04-28 Callaway Golf Company Golf products produced by a stoichiometrically imbalanced RIM system
US7306529B2 (en) * 2005-10-07 2007-12-11 Callaway Golf Company Multi-layer golf ball
US20070135235A1 (en) * 2005-10-13 2007-06-14 Kennedy Thomas J Iii Fast-Chemical-Reaction-Produced Golf Product Comprising a Caprolactam Polyol
CN101291809B (zh) * 2005-10-21 2013-04-03 纳幕尔杜邦公司 混合离子离聚物片材和由其生产的高强度层压材料
US7445683B2 (en) * 2005-11-30 2008-11-04 E. I. Du Pont De Nemours And Company Thermoplastic resin compositions suitable for use in laminated safety glass
US7678441B2 (en) 2005-12-02 2010-03-16 E.I. Du Pont De Nemours And Company Interlayers for laminated safety glass with superior de-airing and laminating properties and process for making the same
US7629424B2 (en) * 2005-12-09 2009-12-08 Pryog, Llc Metal-containing compositions and method of making same
US8030411B2 (en) * 2005-12-21 2011-10-04 Taylor Made Golf Company, Inc. Polymer compositions comprising peptizers, sports equipment comprising such compositions, and method for their manufacture
US8617003B2 (en) 2006-01-18 2013-12-31 Acushnet Company Golf ball having specific spin, moment of inertia, lift, and drag relationship
US7612135B2 (en) 2006-02-17 2009-11-03 Callaway Golf Company Golf ball and thermoplastic material
US9668476B2 (en) * 2006-02-23 2017-06-06 Lanxess Corporation Removable antimicrobial coating compositions and methods of use
US20070238849A1 (en) * 2006-04-10 2007-10-11 Shenshen Wu Durene isocyanate-based elastomers for golf ball layer compositions
US20070289693A1 (en) * 2006-06-15 2007-12-20 Anderson Jerrel C Thermoplastic resin compositions suitable for use in transparent laminates
US8003202B2 (en) * 2006-06-16 2011-08-23 E.I. Du Pont De Nemours And Company Semiaromatic polyamide composite article and processes for its preparation
EP2035470A1 (de) * 2006-06-20 2009-03-18 E.I. Du Pont De Nemours And Company Thermoplastische harzzusammensetzungen, die zur verwendung in transparenten laminaten geeignet sind
US8772624B2 (en) * 2006-07-28 2014-07-08 E I Du Pont De Nemours And Company Solar cell encapsulant layers with enhanced stability and adhesion
US20080044666A1 (en) 2006-08-17 2008-02-21 Anderson Jerrel C Amine-neutralized ethylene acid copolymers, shaped articles and laminates produced therefrom
US8399101B2 (en) * 2006-09-19 2013-03-19 E I Du Pont De Nemours And Company Toughened poly(hydroxyalkanoic acid) compositions
US20080102236A1 (en) * 2006-10-27 2008-05-01 Fish Robert B Pipes containing nanoclays and method for their manufacture
EP2087014B1 (de) * 2006-11-02 2010-05-19 Dow Global Technologies Inc. Verfahren zur herstellung hochqualitativer ionomere
US20080119603A1 (en) * 2006-11-22 2008-05-22 Georgios Topoulos Mobile telephone housing comprising polyamide resin composition
US8853324B2 (en) * 2006-11-22 2014-10-07 E I Du Pont De Nemours And Company Mobile telephone housing comprising polyamide resin composition
US8859665B2 (en) * 2006-12-05 2014-10-14 E I Du Pont De Nemours And Company Polyamide housings for portable electronic devices
US20080176079A1 (en) * 2006-12-19 2008-07-24 Elia Andri E Process for coating vehicle exterior parts made from thermoplastic composite articles
US20080176090A1 (en) * 2006-12-19 2008-07-24 Elia Andri E Composite thermoplastic articles
US8691372B2 (en) * 2007-02-15 2014-04-08 E I Du Pont De Nemours And Company Articles comprising high melt flow ionomeric compositions
US20080196760A1 (en) 2007-02-15 2008-08-21 Richard Allen Hayes Articles such as safety laminates and solar cell modules containing high melt flow acid copolymer compositions
AR071144A1 (es) * 2007-03-15 2010-06-02 Du Pont Peliculas metalizadas
US20080233412A1 (en) * 2007-03-19 2008-09-25 Smith Rebecca L High contrast high strength decorative films and laminates
US20080233377A1 (en) * 2007-03-19 2008-09-25 Smith Rebecca L High contrast high strength decorative sheets and laminates
US20080233371A1 (en) * 2007-03-19 2008-09-25 Richard Allen Hayes Decorative safety glass
US20080268214A1 (en) * 2007-04-30 2008-10-30 Richard Allen Hayes Decorative safety glass
US7834089B2 (en) * 2007-05-08 2010-11-16 E. I. Du Pont De Nemours And Company Ionomeric ethylene vinyl alcohol compositions
CN101687967B (zh) * 2007-05-29 2013-02-27 汉森集团公司 适用于高尔夫球的组合物
US8557947B2 (en) 2007-05-29 2013-10-15 The Hanson Group, Llc Compositions useful in golf balls
JP2008310052A (ja) * 2007-06-14 2008-12-25 Seiko Epson Corp 液体現像剤および画像形成装置
US8182734B1 (en) 2007-08-20 2012-05-22 E. I. Du Pont De Nemours And Company Thermoformed articles and compositions of poly(hydroxyalkanoic acid) and polyoxymethylene
US8637150B2 (en) * 2007-10-01 2014-01-28 E I Du Pont De Nemours And Company Multilayer acid terpolymer encapsulant layers and interlayers and laminates therefrom
CA2703162C (en) * 2007-10-31 2012-09-11 E.I. Du Pont De Nemours And Company Highly abrasion-resistant ionomer pipes
US8044136B2 (en) 2007-11-01 2011-10-25 E.I. Du Pont De Nemours And Company Golf balls with cores or intermediate layers prepared from highly-neutralized ethylene copolymers and organic acids
US20090126859A1 (en) * 2007-11-16 2009-05-21 Cadwallader Robert J Process for producing glass laminates
US8319094B2 (en) * 2007-11-16 2012-11-27 E I Du Pont De Nemours And Company Multilayer terionomer encapsulant layers and solar cell laminates comprising the same
WO2009067413A1 (en) * 2007-11-19 2009-05-28 E. I. Du Pont De Nemours And Company Use of polyamide compositions for making molded articles having improved adhesion, molded articles thereof and methods for adhering such materials
DE102007056440A1 (de) 2007-11-23 2009-05-28 Clariant International Limited Ionomere aus Poly-1-Olefinwachsen
DE102007056533A1 (de) 2007-11-23 2009-05-28 Clariant International Limited Wachsartige Ionomere
US20090151772A1 (en) * 2007-12-14 2009-06-18 E.I. Du Pont De Nemours And Company Terionomer Films or Sheets and Solar Cell Modules Comprising the Same
US20090151773A1 (en) * 2007-12-14 2009-06-18 E. I. Du Pont De Nemours And Company Acid Terpolymer Films or Sheets and Articles Comprising the Same
US9174099B2 (en) 2007-12-19 2015-11-03 Taylor Made Golf Company, Inc. Golf club face
US8628434B2 (en) 2007-12-19 2014-01-14 Taylor Made Golf Company, Inc. Golf club face with cover having roughness pattern
US20090163289A1 (en) * 2007-12-19 2009-06-25 Taylor Made Golf Company, Inc. Method of creating scorelines in club face insert
US8211976B2 (en) 2007-12-21 2012-07-03 Taylor Made Golf Company, Inc. Sports equipment compositions comprising a polyurethane, polyurea or prepolymer thereof and a polyfunctional modifier
US8096899B2 (en) 2007-12-28 2012-01-17 Taylor Made Golf Company, Inc. Golf ball comprising isocyanate-modified composition
US20090183773A1 (en) * 2008-01-21 2009-07-23 E.I. Du Pont De Nemours And Company Amine-neutralized ionomer encapsulant layers and solar cell laminates comprising the same
EP2257431A1 (de) * 2008-03-26 2010-12-08 E. I. du Pont de Nemours and Company Laminierter artikel mit hoher splitterschutzleistung
EP2265671A1 (de) * 2008-04-16 2010-12-29 E. I. du Pont de Nemours and Company Alkylacrylat-gehärtete poly(hydroxyalkansäure)zusammensetzungen
US8236880B2 (en) 2008-04-23 2012-08-07 Taylor Made Golf Company, Inc. Compositions comprising an amino triazine and ionomer or ionomer precursor
KR20110004902A (ko) * 2008-05-08 2011-01-14 이 아이 듀폰 디 네모아 앤드 캄파니 재생가능한 폴리아미드 수지 조성물을 포함하는 휴대용 전자 장치 커버
EP2286465B1 (de) 2008-06-02 2019-08-14 E. I. du Pont de Nemours and Company Solarzellenmodul mit einer einkapselungsschicht von geringer opazität
US7641965B1 (en) 2008-06-30 2010-01-05 E.I. Du Pont De Nemours And Company Transparent light-weight safety glazings
US7939602B2 (en) * 2008-06-30 2011-05-10 E.I. Du Pont De Nemours And Company Golf balls containing ionomers and polyamines or tertiary polyamides
EP2154207A1 (de) 2008-07-28 2010-02-17 Dupont Polymer Powders Switzerland Sarl Pulverbeschichtungszusammensetzung für thermoplastische Verbundstoffe
US8361577B2 (en) * 2008-07-30 2013-01-29 Ticona Llc Long-term heat aging resistant impact modified poly(cyclohexylene-dimethylene) terephthalate compositions
EP2151316B1 (de) 2008-07-31 2012-06-06 E.I. Du Pont De Nemours And Company Mehrfilmstrukturen für die Wärmeisolierung
EP2326744B1 (de) * 2008-08-07 2022-06-01 Pryog, LLC Metallzusammensetzungen und verfahren zu ihrer herstellung
JP5390806B2 (ja) * 2008-08-08 2014-01-15 古河電気工業株式会社 ケーブルの梱包形態
BRPI0913170B1 (pt) * 2008-08-25 2019-05-21 Dow Global Technologies Llc Processo isento de água e peróxido para reticular um polímero contendo grupos carboxila, artigo e aditivo plástico
JP5611827B2 (ja) * 2008-09-01 2014-10-22 三井化学株式会社 アイオノマー樹脂およびこれを含んでなる樹脂組成物ならびにこれらの用途
US8298659B2 (en) * 2008-09-30 2012-10-30 E I Du Pont De Nemours And Company Polysiloxane coatings doped with aminosilanes
WO2010051419A1 (en) * 2008-10-31 2010-05-06 E. I. Du Pont De Nemours And Company Highly abrasion-resistant polyolefin pipe
US20100112354A1 (en) * 2008-10-31 2010-05-06 E. I. Du Pont De Nemours And Company Articles with abrasion-resistant terionomer layers
MX2011004485A (es) * 2008-10-31 2011-05-23 Du Pont Articulos laminados de alta transparencia que comprenden una capa ionomerica intermedia.
CN102203143B (zh) * 2008-10-31 2014-05-07 纳幕尔杜邦公司 高透明度离聚物组合物和包含其的制品
JP6076598B2 (ja) 2008-10-31 2017-02-08 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ 低ヘイズ封入材を含む太陽電池モジュール
US8288467B2 (en) * 2008-12-08 2012-10-16 Nike, Inc. Zinc ionomer rubber activator
US8124681B2 (en) * 2008-12-12 2012-02-28 Acushnet Company Golf ball with high moisture barrier properties
US7695381B1 (en) 2008-12-12 2010-04-13 Acushnet Company Golf ball with high moisture barrier properties
US20100154867A1 (en) 2008-12-19 2010-06-24 E. I. Du Pont De Nemours And Company Mechanically reliable solar cell modules
US8399566B2 (en) * 2008-12-23 2013-03-19 Taylor Made Golf Company, Inc. Modified ionomer composition
US8809428B2 (en) * 2008-12-23 2014-08-19 Taylor Made Golf Company, Inc. Golf ball
EP2376549B1 (de) 2008-12-30 2013-12-25 E. I. du Pont de Nemours and Company Hochreine ionomergemischzusammensetzungen und artikel damit
WO2010077427A1 (en) 2008-12-31 2010-07-08 E. I. Du Pont De Nemours And Company Laminates comprising ionomer interlayers with low haze and high moisture resistance
CN102272946B (zh) * 2008-12-31 2013-11-27 纳幕尔杜邦公司 包括具有低雾度和高耐湿性的包封片材的太阳能电池模块
CN102325812A (zh) * 2008-12-31 2012-01-18 纳幕尔杜邦公司 具有低雾度和高耐湿性的离聚物组合物以及包含该组合物的制品
US8187121B2 (en) * 2009-01-29 2012-05-29 Acushnet Company Casing layer for polyurethane-covered and polyurea-covered golf balls
US8241146B2 (en) * 2009-01-29 2012-08-14 Acushnet Company Casing layer for polyurethane-covered and polyurea-covered golf balls
CN102341454A (zh) 2009-03-03 2012-02-01 纳幕尔杜邦公司 聚(对苯二甲酸丙二醇酯)模塑树脂和由其制得的模塑制品
WO2010102282A1 (en) 2009-03-06 2010-09-10 E. I. Du Pont De Nemours And Company Light weight glass laminates
US8202925B2 (en) * 2009-05-26 2012-06-19 E. I. Du Pont De Nemours And Company Golf balls with cores or intermediate layers prepared from highly-neutralized ethylene terpolymers and organic acids
US20110177146A1 (en) * 2009-07-27 2011-07-21 E. I. Du Pont De Nemours And Company Removable antimicrobial coating compositions containing cationic rheology agent and methods of use
US20110028638A1 (en) * 2009-07-28 2011-02-03 Kelly Mark B Powder Coating Composition For Thermoplastic Composites
US20110024433A1 (en) 2009-07-30 2011-02-03 E.I. Du Pont De Nemours And Company Thermal insulation unit
US20110039470A1 (en) * 2009-07-30 2011-02-17 E.I. Du Pont De Nemours And Company Overmolded heat resistant polyamide composite structures and processes for their preparation
US20110027571A1 (en) * 2009-07-30 2011-02-03 E.I. Du Pont De Nemours And Company Heat resistant polyamide composite structures and processes for their preparation
US20110028060A1 (en) * 2009-07-30 2011-02-03 E .I. Du Pont De Nemours And Company Heat resistant semi-aromatic polyamide composite structures and processes for their preparation
JP5650737B2 (ja) * 2009-07-31 2015-01-07 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ 光起電力セル用の架橋性封止材
JP5165724B2 (ja) * 2009-10-16 2013-03-21 ダンロップスポーツ株式会社 ゴルフボール用樹脂組成物およびこれを用いたゴルフボール
US8389604B2 (en) * 2009-11-02 2013-03-05 E I Du Pont De Nemours And Company Method for providing toughened poly(trimethylene terephthalate) molding resins
US20110105644A1 (en) * 2009-11-02 2011-05-05 E. I. Du Pont De Nemours And Company Toughened poly(trimethylene terephthalate) molding resins and molded articles therefrom
US20110113534A1 (en) 2009-11-17 2011-05-19 E.I.Du Pont De Nemours And Company Impact Resistant Composite Article
US8895138B2 (en) 2009-11-17 2014-11-25 E I Du Pont De Nemours And Company Impact resistant composite article
DE102009047256A1 (de) 2009-11-27 2011-06-01 Tesa Se Verwendung eines handeinreißbaren Klebebands für Bauanwendungen
US20110143003A1 (en) 2009-12-16 2011-06-16 E. I. Du Pont De Nemours And Company Non-porous moisture and gas permeable films
EP2338461A1 (de) * 2009-12-22 2011-06-29 Dupont Polymer Powders Switzerland Sarl Farbiges, mikronisiertes, kugelförmiges Polymerpulver und kosmetische Zusammensetzung davon
US8410219B2 (en) * 2009-12-22 2013-04-02 E I Du Pont De Nemours And Company Method for increasing melt flow of a bimodal ionomer composition
US8680204B2 (en) * 2009-12-23 2014-03-25 Hyun J. Kim Crosslinked ionomer compositions
US20110312238A1 (en) 2009-12-29 2011-12-22 E.I. Du Pont De Nemours And Company Enhanced lightweight ballistic materials
US8674023B2 (en) 2009-12-31 2014-03-18 Taylor Made Golf Company, Inc. Ionomer compositions for golf balls
US8629228B2 (en) 2009-12-31 2014-01-14 Taylor Made Golf Company, Inc. Ionomer compositions for golf balls
US8575278B2 (en) 2009-12-31 2013-11-05 Taylor Made Golf Company, Inc. Ionomer compositions for golf balls
KR20130062908A (ko) 2010-03-22 2013-06-13 이 아이 듀폰 디 네모아 앤드 캄파니 중합체성 구조물의 경화 촉진
US8308861B2 (en) 2010-05-13 2012-11-13 E I Du Pont De Nemours And Company Phase change material compositions
US20110300273A1 (en) 2010-06-03 2011-12-08 E.I. Du Pont De Nemours And Company Non-Porous Moisture and Gas Permeable Films
US8211264B2 (en) 2010-06-07 2012-07-03 E I Du Pont De Nemours And Company Method for preparing transparent multilayer film structures having a perfluorinated copolymer resin layer
US8211265B2 (en) 2010-06-07 2012-07-03 E. I. Du Pont De Nemours And Company Method for preparing multilayer structures containing a perfluorinated copolymer resin layer
BR112012027724A2 (pt) 2010-06-11 2016-09-06 Du Pont composição de termoplásticos, sistema de proteção de balística e método para reforço de um tecido de balística
CA2799222A1 (en) 2010-06-11 2011-12-15 E. I. Du Pont De Nemours And Company Enhanced flexible lightweight ballistic, stab and spike resistant materials
KR101161360B1 (ko) * 2010-07-13 2012-06-29 엘에스전선 주식회사 공간전하 저감 효과를 갖는 직류용 전력 케이블
US8609980B2 (en) 2010-07-30 2013-12-17 E I Du Pont De Nemours And Company Cross-linkable ionomeric encapsulants for photovoltaic cells
US8409379B2 (en) 2010-07-30 2013-04-02 E I Du Pont De Nemours And Company Multilayer structures containing a fluorinated copolymer resin layer and an ethylene terpolymer layer
WO2012016127A1 (en) 2010-07-30 2012-02-02 E. I. Du Pont De Nemours And Company Crosslinkable materials for safety laminates
EP2603558B1 (de) 2010-08-09 2015-04-15 Styrolution Europe GmbH Thermoplastische formgebungszusammensetzungen mit verbesserter anhaftung einer galvanisierten metallschicht
US20120178325A1 (en) 2010-08-10 2012-07-12 E. I. Du Pont De Nemours And Company Polyamide composite structures and processes for their preparation
US8691917B2 (en) 2010-10-08 2014-04-08 E I Du Pont De Nemours And Company Ionomers modified with imidized acrylic resins
US8475932B2 (en) 2010-10-12 2013-07-02 E I Du Pont De Nemours And Company Compositions of organic acid modified ionomers filled with silica
WO2012058359A1 (en) 2010-10-29 2012-05-03 E. I. Du Pont De Nemours And Company Composite structures having improved heat aging and interlayer bond strength
US20120283039A1 (en) 2010-11-03 2012-11-08 E.I. Du Pont De Nemours And Company Compositions of dicarboxylic acid modified ionomers
US8444508B2 (en) 2010-11-12 2013-05-21 Acushnet Company Golf balls comprising highly- and partially-neutralized alternate copolymers
US9650506B2 (en) 2010-12-16 2017-05-16 Ineos Styrolution Europe Gmbh Thermoplastic moulding compositions for metal plated articles with improved resistance against repeated impact
US20130065059A1 (en) 2011-03-07 2013-03-14 E. I. Du Pont De Nemours And Company Method of adhering ionomer to metal
US8932691B2 (en) 2011-03-07 2015-01-13 E I Du Pont De Nemours And Company Multilayer protective liner
US20130018153A1 (en) 2011-07-11 2013-01-17 E I Du Pont De Nemours And Company Polychloroprene compositions with improved adhesion properties
CN103648765B (zh) 2011-07-27 2017-06-06 纳幕尔杜邦公司 用于可重新闭合的包装的多层膜
US8815363B2 (en) 2011-08-30 2014-08-26 E I Du Pont De Nemours And Company Multilayer protective liner
US8907022B2 (en) 2011-09-01 2014-12-09 E I Du Pont De Nemours And Company Method to form an aqueous dispersion of an ionomer
US20130095716A1 (en) 2011-10-17 2013-04-18 E. I. Du Pont De Nemours And Company Composite material; a ballistic resistant article made from same and method of making the article
US20130284004A1 (en) 2011-10-17 2013-10-31 E I Du Pont De Nemours And Company Composite material; a ballistic resistant article made from same and method of making the article
EP2771183B1 (de) 2011-10-26 2021-08-11 Performance Materials NA, Inc. Mehrlagige folienstruktur mit materialien aus erneuerbaren quellen
US8841379B2 (en) 2011-11-07 2014-09-23 E I Du Pont De Nemours And Company Method to form an aqueous dispersion of an ionomer-polyolefin blend
US20130149930A1 (en) * 2011-12-12 2013-06-13 E I Du Pont De Nemours And Company Methods to form an ionomer coating on a substrate
US8858365B2 (en) 2011-12-23 2014-10-14 Taylor Made Golf Company, Inc. Multi-layer golf ball construction
US20130171394A1 (en) 2011-12-30 2013-07-04 E. I. Du Pont De Nemours And Company Polyamide Composition Containing Ionomer
US20130171390A1 (en) 2011-12-30 2013-07-04 E. I. Du Pont De Nemours And Company Thermoplastic Powder Compositions
US8906479B2 (en) 2011-12-30 2014-12-09 E I Du Pont De Nemours And Company Compositions of polyamide and ionomer
CN104080820B (zh) * 2012-01-20 2016-05-11 东洋油墨Sc控股株式会社 水蒸气阻隔树脂、水蒸气阻隔涂布剂、水蒸气阻隔膜及水蒸气阻隔层叠体
WO2013116445A1 (en) 2012-01-31 2013-08-08 E. I. Du Pont De Nemours And Company Multilayer film comprising cyclic olefin copolymer
US20140113104A1 (en) 2012-02-23 2014-04-24 E I Du Pont De Nemours And Company Fiber-resin composite sheet and article comprising the same
US9085123B2 (en) 2012-02-29 2015-07-21 E I Du Pont De Nemours And Company Ionomer-poly(vinylalcohol) coatings
IN2014DN06526A (de) 2012-02-29 2015-06-12 Du Pont
US20130225021A1 (en) 2012-02-29 2013-08-29 E.I. Du Pont De Nemours And Company Highly viscous ionomer-poly(vinylalcohol) coatings
BR112014028931B1 (pt) * 2012-05-21 2020-12-22 Lubrizol Advanced Materials, Inc. liga de um poliuretano termoplástico e uma poliolefina
US9409362B2 (en) 2012-09-18 2016-08-09 Taylor Made Golf Company, Inc. Golf ball molds and related systems
US20150251384A1 (en) 2012-10-12 2015-09-10 E.I.Du Pont De Nemours And Company Glass laminates with nanofilled ionomer interlayers
JP2016501743A (ja) 2012-10-25 2016-01-21 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニーＥ．Ｉ．Ｄｕ Ｐｏｎｔ Ｄｅ Ｎｅｍｏｕｒｓ Ａｎｄ Ｃｏｍｐａｎｙ 印刷可能保護層
WO2014066715A1 (en) * 2012-10-26 2014-05-01 E. I. Du Pont De Nemours And Company Thermoplastic composite muffler
US8859094B2 (en) 2012-11-09 2014-10-14 The Procter & Gamble Company Combination of elastomeric film composition and adhesive for a stretch laminate
US20140134910A1 (en) 2012-11-09 2014-05-15 The Procter & Gamble Company Combination of Elastomeric Film Composition and Adhesive for a Stretch Laminate
WO2014100301A1 (en) 2012-12-19 2014-06-26 E. I. Du Pont De Nemours And Company Cross-linked polymers and their use in photovoltaic modules
US9731465B2 (en) 2012-12-27 2017-08-15 Taylor Made Golf Company, Inc. Mold base for curing parts for golf ball applications
BR112015017270A2 (pt) 2013-03-05 2017-07-11 Total Res & Technology Feluy artigos rotomoldados
JP6158434B2 (ja) 2013-06-20 2017-07-05 ザ プロクター アンド ギャンブル カンパニー 活性化に適した積層体を有する吸収性物品
US20150135937A1 (en) 2013-11-18 2015-05-21 E I Du Pont De Nemours And Company Method to produce ballistic and stab resistant structures for garments and structures produced by the method
US20150158986A1 (en) 2013-12-06 2015-06-11 E.I. Du Pont De Nemours And Company Polymeric interlayer sheets and light weight laminates produced therefrom
WO2015130376A2 (en) 2013-12-16 2015-09-03 E. I. Du Pont De Nemours And Company Ballistic composite article
US20150203615A1 (en) 2014-01-22 2015-07-23 E I Du Pont De Nemours And Company Alkali metal-zinc ionomer compositions
US20150203704A1 (en) 2014-01-22 2015-07-23 E I Du Pont De Nemours And Company Alkali metal-magnesium ionomer compositions
WO2015127048A1 (en) 2014-02-24 2015-08-27 E. I. Du Pont De Nemours And Company Plasticized polyamide compositions
WO2015168073A1 (en) 2014-04-29 2015-11-05 E. I. Du Pont De Nemours And Company Solar cell modules with improved backsheet
CN106457789A (zh) 2014-04-29 2017-02-22 纳幕尔杜邦公司 具有改善的多层背板的光伏电池
CN106232725A (zh) 2014-04-29 2016-12-14 纳幕尔杜邦公司 具有改善的背板的光伏电池
CN106233395B (zh) 2014-05-01 2019-09-03 纳幕尔杜邦公司 由相变材料制成的缆线
US20150325729A1 (en) 2014-05-09 2015-11-12 E. I. Du Pont De Nemours And Company Encapsulant composition comprising a copolymer of ethylene, vinyl acetate and a third comonomer
WO2015179291A1 (en) 2014-05-20 2015-11-26 E. I. Du Pont De Nemours And Company Collation shrink film protective structure
US20150376310A1 (en) 2014-06-26 2015-12-31 E.I. Du Pont De Nemours And Company Ethylene acid copolymers, their ionomers, and their use in packaging films and injection molded articles
US10421258B2 (en) 2014-08-13 2019-09-24 Performance Materials Na, Inc. Multilayer structure comprising polypropylene
WO2016038181A1 (en) 2014-09-11 2016-03-17 Total Research & Technology Feluy Multilayered rotomoulded articles
WO2016051363A1 (en) * 2014-10-01 2016-04-07 Ticona Gmbh Polyoxymethylene polymer composition for fluidized bed coating processes and products made therefrom
US20180264787A1 (en) 2014-10-03 2018-09-20 E I Du Pont De Nemours And Company Multilayer food casing or food film
JP6750936B2 (ja) 2014-10-15 2020-09-02 日本ポリエチレン株式会社 エチレン系アイオノマーの製造方法及びエチレン系アイオノマー
EP3158001A1 (de) 2014-11-13 2017-04-26 Total Research & Technology Feluy Rotationsgegossene artikel mit metallocenkatalysiertem polyethylenharz
WO2016075165A1 (en) 2014-11-13 2016-05-19 Total Research & Technology Feluy Rotomolded articles comprising at least one layer comprising a metallocene-catalyzed polyethylene resin
WO2016094281A1 (en) 2014-12-11 2016-06-16 E. I. Du Pont De Nemours And Company Stretch wrapping film
AU2015375353B2 (en) 2015-01-05 2020-01-30 Avery Dennison Corporation Inherently printable polymeric material and related methods
WO2016123209A1 (en) 2015-01-28 2016-08-04 E. I. Du Pont De Nemours And Company Multilayer film structures comprising renewable polyester compositions
US10323908B2 (en) 2015-05-08 2019-06-18 E I Du Pont De Nemours And Company Ballistic and stab resistant composite
US10030132B2 (en) 2015-06-12 2018-07-24 E. I. Du Pont De Nemours And Company Ethylene copolymer-modified plastisol
EP3120722B1 (de) 2015-07-24 2020-05-20 Performance Materials NA, Inc. Thermoformbares polyamidionomermaterial für fersenkappe und schuhspitze
WO2017040388A1 (en) 2015-08-28 2017-03-09 E.I. Du Pont De Nemours And Company Multilayer bottles with reduced permanent static effect for cosmetic packaging
JP6615237B2 (ja) 2015-09-29 2019-12-04 プライオグ リミテッド ライアビリティ カンパニー 金属組成物及びその製法
US20180334775A1 (en) 2015-11-03 2018-11-22 E I Du Pont De Nemours And Company Cables made of phase change material
US10150011B2 (en) 2016-03-17 2018-12-11 Acushnet Company Golf ball incorporating at least three adjacent ionomeric and/or HNP-based layers having multiple related property gradients there between
US10150012B2 (en) 2016-03-17 2018-12-11 Acushnet Company Golf ball incorporating at least three adjacent ionomeric and/or HNP-based layers having multiple related property gradients there between
US9925425B2 (en) 2016-03-17 2018-03-27 Acushnet Company Golf ball incorporating at least three adjacent ionomeric and/or HNP-based layers having multiple related property gradients there between
US9643062B1 (en) 2016-03-17 2017-05-09 Acushnet Company Golf ball incorporating at least three adjacent ionomeric and/or HNP-based layers having multiple related property gradients there between
CA3022335A1 (en) 2016-04-27 2017-11-02 Basf Se Laminated lighting unit
WO2017196707A1 (en) 2016-05-09 2017-11-16 Kuraray America, Inc. Multilayer interlayer and glass laminate
EP3878922A1 (de) 2016-06-09 2021-09-15 E. I. du Pont de Nemours and Company Wärmespeicherkabel mit verschlusssystem
EP3290353A1 (de) 2016-08-30 2018-03-07 Amcor Flexibles Kreuzlingen Ltd. Blisterpackung
PL3512913T3 (pl) * 2016-09-14 2020-12-14 Basf Se Poliester do wytłaczania profili i/lub wytłaczania rur
WO2018081570A1 (en) 2016-10-28 2018-05-03 Kuraray America, Inc. Wedge-shaped multilayer interlayer and glass laminate
WO2018106574A1 (en) 2016-12-05 2018-06-14 E. I. Du Pont De Nemours And Company Polyamide compositions
US10773500B2 (en) 2016-12-12 2020-09-15 Trex Company, Inc. Laminated wood polymer composite article and method of making a laminated wood polymer composite article
WO2018141742A1 (en) 2017-02-03 2018-08-09 Basf Se Laminated glazing comprising a composite structure of laminated layers
WO2018178323A1 (en) 2017-03-31 2018-10-04 Solvay Specialty Polymers Usa, Llc Foam material comprising polyphenylene sulfide polymer (pps)
EP3601420A1 (de) 2017-03-31 2020-02-05 Solvay Specialty Polymers USA, LLC Schaumstoffmaterial aus polyphenylensulfidpolymer (pps)
WO2018215308A1 (en) 2017-05-24 2018-11-29 Basf Se Glazing with luminous coating and method for producing a glazing having a luminous coating
WO2019011677A1 (en) 2017-07-13 2019-01-17 Basf Se LAMINATED GLAZING, LIGHTING UNIT AND METHOD FOR MANUFACTURING LAMINATED GLAZING
CN116675925A (zh) 2017-07-31 2023-09-01 可乐丽美国股份有限公司 粘附特性增强的离聚物夹层
WO2019042955A1 (en) 2017-08-30 2019-03-07 Basf Se HIGH-COLOR HOMOGENEITY LIGHTED ELEMENT
EP3681913B1 (de) 2017-09-11 2021-12-01 Nutrition & Biosciences USA 4, Inc. Poly-alpha-1,3-glucan-verbindungen
WO2019126189A1 (en) 2017-12-22 2019-06-27 E. I. Du Pont De Nemours And Company Thermoplastic adhesive composition
WO2019126129A1 (en) 2017-12-22 2019-06-27 E. I. Du Pont De Nemours And Company Thermoplastic adhesive composition
WO2019131291A1 (ja) 2017-12-25 2019-07-04 日本ポリエチレン株式会社 多元系極性基含有オレフィン共重合体
US10682553B2 (en) 2018-04-18 2020-06-16 Acushnet Company Golf ball incorporating melt processable highly-crosslinked ethylene acid copolymer(s) and/or ionomer(s)
US10773132B2 (en) 2018-04-18 2020-09-15 Acushnet Company Golf ball incorporating melt processable highly-crosslinked rubber-containing ionomer(s)
EP3802045B1 (de) 2018-05-31 2023-07-19 Dow Global Technologies LLC Formartikel und verfahren dafür
CN112424279A (zh) 2018-07-31 2021-02-26 性能材料北美股份有限公司 具有增强抗蠕变性的乙烯酸共聚物的离聚物
BR112021000469A2 (pt) 2018-07-31 2021-04-06 Performance Materials Na, Inc. Ionômero
WO2020025317A1 (en) 2018-07-31 2020-02-06 Sabic Global Technologies B.V. Polyethylene with ionomeric groups for increased environmental stress cracking resistance
WO2020028023A1 (en) 2018-07-31 2020-02-06 E. I. Du Pont De Nemours And Company Ionomer compositions
CN112888731A (zh) 2018-09-28 2021-06-01 性能材料北美股份有限公司 聚酰胺泡沫的制备
JP7432603B2 (ja) 2018-12-10 2024-02-16 ダウ グローバル テクノロジーズ エルエルシー 少なくとも１つの二成分繊維を有するエアレイド基材
CN113518801B (zh) 2018-12-20 2023-09-01 陶氏环球技术有限责任公司 水离聚分散体及其方法
US11708501B2 (en) 2018-12-20 2023-07-25 Dow Global Technologies Llc Aqueous ionomeric dispersions, and methods thereof
JP2020117712A (ja) 2019-01-28 2020-08-06 日本ポリエチレン株式会社 極性基含有オレフィン共重合体
US20200251082A1 (en) 2019-02-04 2020-08-06 Kuraray America, Inc. Hurricane-resistant acoustic glazing
CN113454127B (zh) 2019-03-04 2024-03-26 日本聚乙烯株式会社 多元离聚物
WO2020204063A1 (ja) 2019-04-02 2020-10-08 日本ポリエチレン株式会社 特定のアイオノマーを含むポリアミド樹脂組成物
WO2020223137A1 (en) 2019-05-02 2020-11-05 Dow Global Technologies Llc Printing systems and methods including multilayer films
WO2020247173A1 (en) 2019-06-05 2020-12-10 Dow Global Technologies Llc Metal ionomer compositions and methods of making the same
US20220251268A1 (en) 2019-06-24 2022-08-11 Japan Polyethylene Corporation Resin composition for injection molding or compression molding
CN114096571A (zh) 2019-06-24 2022-02-25 日本聚乙烯株式会社 膜状成型体用树脂以及由该树脂构成的成型品
US20220251430A1 (en) 2019-06-24 2022-08-11 Japan Polyethylene Corporation Polymer composition for lamination and laminated body using same
AR119189A1 (es) 2019-06-28 2021-12-01 Dow Global Technologies Llc Laminados de películas de envasado flexible y método para elaborarlos mediante laminación térmica
AR119229A1 (es) 2019-06-28 2021-12-01 Dow Global Technologies Llc Películas multicapa de polietileno resistentes al calor para líneas de embalaje flexible de alta velocidad
BR112021026680A2 (pt) 2019-07-02 2022-02-15 Dow Global Technologies Llc Artigo moldado, e, método para preparar um artigo moldado
EP3999562A1 (de) 2019-07-18 2022-05-25 SABIC Global Technologies, B.V. Copolymer aus ethylen und ionenpaarverbindung
AR119443A1 (es) 2019-07-31 2021-12-15 Dow Global Technologies Llc Polietileno de baja densidad con papel adhesivo de aluminio mejorado mediante la mezcla de resinas de copolímero ácido
AR119441A1 (es) 2019-07-31 2021-12-15 Dow Global Technologies Llc Polietileno de baja densidad con resistencia de adhesión en caliente y adhesión al metal mejoradas mediante la adición de ionómeros
WO2021021551A1 (en) 2019-08-01 2021-02-04 Dow Global Technologies Llc Multilayer structures having improved recyclability
JP2022546354A (ja) 2019-08-29 2022-11-04 ダウ グローバル テクノロジーズ エルエルシー 改善された熱特性を有するポリマーブレンド
WO2021053411A1 (en) 2019-09-20 2021-03-25 Sabic Global Technologies B.V. High-density polyethylene with increased transparency
KR102169618B1 (ko) 2020-05-07 2020-10-23 방만혁 접착제 조성물과, 그 제조 방법, 이 접착제 조성물을 이용한 복합관, 및 적층 쉬트
US20210362468A1 (en) 2020-05-22 2021-11-25 Kuraray America, Inc. Interlayer And Laminate With Controlled Debonding Zone Treatments With Enhanced Performance
WO2021239883A2 (en) 2020-05-28 2021-12-02 Total Research & Technology Feluy Process for producing skin/foam/skin structure with high surface finish
EP4178797A1 (de) 2020-07-08 2023-05-17 Kuraray Europe GmbH Verbundglas mit fälschungssicheren eigenschaften
EP3974182A1 (de) 2020-09-28 2022-03-30 Kuraray Europe GmbH Mehrschichtige schalldämpfende zwischenschichtfolien mit ethylenvinylacetalen
WO2022132418A2 (en) 2020-12-16 2022-06-23 Kuraray Europe Gmbh Laminated structures with composite adhesive polymeric interlayer comprising cohesive debonding zones for enhanced performance
CN115368721B (zh) * 2021-05-17 2023-09-19 金发科技股份有限公司 一种抗静电母粒及其制备方法和应用
CN115368722A (zh) * 2021-05-17 2022-11-22 金发科技股份有限公司 一种抗静电母粒及其制备方法和应用
WO2023076366A1 (en) 2021-10-28 2023-05-04 Dow Global Technologies Llc Injection molded closure article comprising a composition blend of at least one substantially linear polyolefin elastomer component and at least one partially neutralized ethylene acid copolymer resin component
WO2023081743A1 (en) 2021-11-05 2023-05-11 Dow Global Technologies Llc Polymer blends having improved thermal resistance
WO2023096879A1 (en) 2021-11-23 2023-06-01 Kuraray Europe Gbmh Interlayer and laminate with controlled debonding zone treatments
WO2023121791A1 (en) * 2021-12-23 2023-06-29 Arkema Inc. Cross-linkable fluoropolymer
EP4230402A1 (de) 2022-02-18 2023-08-23 Kuraray Europe GmbH Verbundglasscheibe, die ein vogelschutzmuster umfasst
WO2023239891A1 (en) 2022-06-10 2023-12-14 Lubrizol Advanced Materials, Inc. Thermoplastic polyurethanes with high temperature stability and uses thereof
WO2023249853A1 (en) 2022-06-22 2023-12-28 Kuraray America, Inc. Ionomer resin composition
WO2024044585A1 (en) 2022-08-22 2024-02-29 Dow Global Technologies Llc Ionomer dispersant for making aqueous polyolefin dispersions

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2646425A (en) * 1953-07-21 Ereparation of ethylene polymers
US2607762A (en) * 1948-12-07 1952-08-19 Monsanto Chemicals Dry process manufacture of watersoluble derivatives of styrenemaleic anhydride type heteropolymers
US2757153A (en) * 1949-12-14 1956-07-31 Monsanto Chemicals Process for water-soluble styrenemaleic anhydride derivatives
US2599123A (en) * 1950-08-18 1952-06-03 Du Pont Copolymers of ethylene with an alkyl acrylate and an alkyl monoester of a butene-1,4-dioic acid
US2798053A (en) * 1952-09-03 1957-07-02 Goodrich Co B F Carboxylic polymers
US2757106A (en) * 1953-05-28 1956-07-31 Rohm & Haas Coated paper products and method of making
DE1016228B (de) * 1955-09-06 1957-09-26 Monsanto Chemicals Verfahren zum Schlichten von Polyamidfaeden oder -garnen
US2999056A (en) * 1956-10-04 1961-09-05 Du Pont Irradiation bonding of acidic compounds to shaped polymeric structures
US3132120A (en) * 1961-02-03 1964-05-05 Du Pont Method for the preparation of ethylene copolymers
NL128027C (de) * 1961-08-31 1900-01-01

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BE627537A (de) 1900-01-01
SE303882B (de) 1968-09-09
FR1430478A (fr) 1966-03-04
DK125713B (da) 1973-03-26
DE1745939A1 (de) 1971-01-14
DE1595112C3 (de) 1974-03-14
DE1745939C3 (de) 1974-02-21
NL288151A (de) 1900-01-01
CH445861A (de) 1967-10-31
SE311229B (de) 1969-06-02
NL128027C (de) 1900-01-01
DE1520518B2 (de) 1971-07-22
NL129542C (de) 1900-01-01
US3264272A (en) 1966-08-02
GB1063436A (en) 1967-03-30
DE1595112B2 (de) 1973-07-05
DE1520506B2 (de) 1971-06-09
GB1011981A (en) 1965-12-01
BE621846A (de) 1900-01-01
GB1029035A (en) 1966-05-11
GB1034268A (en) 1966-06-29
DE1520506A1 (de) 1970-02-19
DE1520518A1 (de) 1969-07-03
CH435741A (de) 1967-05-15
DE1745938B2 (de) 1973-07-19
DE1595112A1 (de) 1970-04-09
US3404134A (en) 1968-10-01
DE1520601A1 (de) 1970-05-14
DE1745938A1 (de) 1971-01-14
DE1520601B2 (de) 1973-01-04
NL282755A (de) 1900-01-01
DE1745938C3 (de) 1974-02-21

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E77 Valid patent as to the heymanns-index 1977