DE10357389B4 - Process for cleaning soapstone - Google Patents

Process for cleaning soapstone Download PDF

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Publication number
DE10357389B4
DE10357389B4 DE10357389A DE10357389A DE10357389B4 DE 10357389 B4 DE10357389 B4 DE 10357389B4 DE 10357389 A DE10357389 A DE 10357389A DE 10357389 A DE10357389 A DE 10357389A DE 10357389 B4 DE10357389 B4 DE 10357389B4
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Prior art keywords
alkali
soapstone
cleaner
glycol monobutyl
monobutyl ether
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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DE10357389A
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German (de)
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DE10357389A1 (en
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Juergen Michael Benda
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Individual
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Individual
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Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/044Hydroxides or bases
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/04Water-soluble compounds
    • C11D3/08Silicates
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/20Organic compounds containing oxygen
    • C11D3/2068Ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/24Hydrocarbons
    • C11D7/241Hydrocarbons linear
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22Organic compounds
    • C11D7/24Hydrocarbons
    • C11D7/247Hydrocarbons aromatic
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02Anionic compounds
    • C11D1/12Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29Sulfates of polyoxyalkylene ethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/72Ethers of polyoxyalkylene glycols
    • C11D2111/24
    • C11D2111/44

Abstract

Verfahren zur Reinigung von Specksteinen dadurch gekennzeichnet, dass dieser zunächst mit einem wässrigen Reiniger
1) enthaltend
0,5–10% Diethylenglykolmonobutylether
0,5 –10% Ethylenglykolmonobutylether
0,1–1% Alkalihydroxide
0,1–1% Alkalisilikate
0,5–10% Alkaliphosphate
0,5–10% Alkaliisopropylbenzolsulfonate
0,5–10% Isotridecanolethoxylate
0,5–10% n-Alkylbenzolsulfonate, Ethersulfonate, Fettalkoholethoxylate
0,5–10% Fettsäureseifen (Alkali)
und anschließend mit einem wasserfreien Reiniger
2) enthaltend
10–50% Cycloparaffin
10–50% Isoparaffin (C8-C10)
1–10% n-Paraffin (C6-C8)
behandelt wird.
Process for the purification of soapstone, characterized in that this first with an aqueous cleaner
1) containing
0.5-10% diethylene glycol monobutyl ether
0.5-10% ethylene glycol monobutyl ether
0.1-1% alkali hydroxides
0.1-1% alkali silicates
0.5-10% alkali phosphates
0.5-10% alkali isopropylbenzenesulfonates
0.5-10% isotridecanol ethoxylates
0.5-10% n-alkylbenzenesulfonates, ether sulfonates, fatty alcohol ethoxylates
0.5-10% fatty acid soaps (alkali)
and then with an anhydrous cleaner
2) containing
10-50% cycloparaffin
10-50% isoparaffin (C 8 -C 10 )
1-10% n-paraffin (C 6 -C 8 )
is treated.

Description

Die Erfindung betrifft ein Verfahren zur nicht mechanischen Reinigung von Speckstein, mit dem eine möglichst einfache Alternative zur herkömmlichen Fleckenbeseitigung sichergestellt werden soll.The The invention relates to a method for non-mechanical cleaning of soapstone, with the one possible simple alternative to conventional Stain removal should be ensured.

Bekannt ist, dass bislang nur das Entfernen von Fettflecken bei Speckstein durch Aceton sicher gestellt ist. Alle anderen Verschmutzungen sind nur auf mechanischem Wege durch Abschleifen mit Nass-Schleifpapier bis hin zum neu Aufschleifen und Aufpolieren durch einen Steinmetz möglich. Ein zufrieden stellendes Ergebnis setzt hier fachmännische Kenntnisse voraus, verbunden mit dem Entstehen von dadurch resultierendem erhöhten Kostenaufwand. Außerdem kann trotz fachkundigem Arbeiten der ursprüngliche Zustand nach erfolgter mechanischer Behandlung nicht hundertprozentig sichergestellt werden.Known is that so far only removing grease stains on soapstone is ensured by acetone. All other dirt is only by mechanical means by grinding with wet sandpaper up to the new grinding and polishing by a stonemason possible. A satisfactory result sets here expert knowledge associated with the emergence of resulting increased cost. Furthermore can, despite expert work, the original state after successful mechanical treatment can not be guaranteed one hundred percent.

Aufgabe der Erfindung ist es somit, das Entfernen von Verschmutzungen bei Speckstein auf nicht mechanischem Wege zu ermöglichen und somit eine leichte Reinigung, die von jedermann durchgeführt werden kann, sicherzustellen.task The invention is thus, the removal of dirt at Soapstone non-mechanical way to allow and thus a light To ensure that cleaning can be done by anyone.

Die Beseitigung von Verschmutzungen wird durch die Verwendung einer Kombination eines wässrigen Reinigers zur Vorbehandlung und eines wasserfreien Reinigers zur Hauptbehandlung in dem erfindungsgemäßen Verfahren zur Reinigung von Specksteinen sichergestellt. Die Kombination dieser beiden Reiniger ermöglicht es, die unterschiedlichsten Arten von Verschmutzungen mit nur einer Reinigungskombination entfernen zu können.The Elimination of contamination is by the use of a Combination of an aqueous Pre-treatment cleaner and an anhydrous cleaner for Main treatment in the inventive method for cleaning ensured by soapstone. The combination of these two cleaners allows it, the most diverse types of pollution with only one To be able to remove the cleaning combination.

Diese nicht mechanische Reinigung hat den Vorteil, dass für die Beseitigung unterschiedlichster Verschmutzungen nur ein Kombinationsprodukt benötigt wird, wobei der Speckstein innerhalb kürzester Zeit in den Zustand vor der Verunreinigung zurückgebracht wird.These not mechanical cleaning has the advantage of being for the elimination different soiling only a combination product needed is, with the soapstone within a short time in the state brought back before the contamination becomes.

Das erfindungsgemäße Verfahren ist dadurch gekennzeichnet, dass es kostengünstiger als die mechanische Beseitigung von Flecken durchgeführt werden kann. Ein weiterer Aspekt ist, dass das Entfernen der Verschmutzung sofort und ohne jegliche Fremdhilfe durchgeführt werden kann. Auch und gerade der daraus resultierende positive wirtschaftliche Aspekt ist in Betracht zu ziehen.The inventive method is characterized in that it is cheaper than the mechanical Elimination of stains done can be. Another aspect is that removing the pollution can be done immediately and without any external assistance. Also and straight the resulting positive economic aspect is in To consider.

Die vorliegende Erfindung betrifft somit ein Verfahren zur Reinigung von Specksteinen dadurch gekennzeichnet, dass dieser zunächst mit einem wässrigen Reiniger

  • 1) enthaltend 0,5–10% Diethylenglykolmonobutylether 0,5–10% Ethylenglykolmonobutylether 0,1–1% Alkalihydroxide 0,1–1% Alkalisilikate 0,5–10% Alkaliphosphate 0,5–10% Alkaliisopropylbenzolsulfonate 0,5–10% Isotridecanolethoxylate 0,5–10% n-Alkylbenzolsulfonate, Ethersulfonate, Fettalkoholethoxylate 0,5–10% Fettsäureseifen (Alkali) und anschließend mit einem wasserfreien Reiniger
  • 2) enthaltend 10–50% Cycloparaffin 10–50% Isoparaffin (C8-C10) 1–10% n-Paraffin (C6C8) behandelt wird.
The present invention thus relates to a process for the purification of soapstone, characterized in that this first with an aqueous cleaner
  • 1) containing 0.5-10% diethylene glycol monobutyl ether 0.5-10% ethylene glycol monobutyl ether 0.1-1% alkali hydroxides 0.1-1% alkali silicates 0.5-10% alkali phosphates 0.5-10% alkali isopropylbenzenesulfonates 0.5-10 % Isotridecanol ethoxylates 0.5-10% n-alkylbenzenesulfonates, ether sulfonates, fatty alcohol ethoxylates 0.5-10% fatty acid soaps (alkali) and then with an anhydrous cleaner
  • 2) containing 10-50% cycloparaffin 10-50% isoparaffin (C 8 -C 10 ) 1-10% n-paraffin (C 6 C 8 ).

Dabei stellt die Behandlung des Specksteins mit dem wässrigen Reiniger eine Vorbehandlung dar. Dieser Vorbehandlung schließt sich eine Hauptbehandlung mit dem wasserfreien Reiniger an.there The treatment of the soapstone with the aqueous cleaner pretreatment This pretreatment completes a major treatment with the anhydrous cleaner on.

Bei der Entfernung von Flecken bei Speckstein kann z.B., wie folgt, vorgegangen werden:
Zur Reinigung der verschmutzten Flächen sollten sich diese auf Raumtemperatur befinden, um eine optimale Reinigungswirkung zu erzielen.
When removing stains from soapstone, you can, for example, proceed as follows:
To clean the soiled surfaces, they should be at room temperature for optimum cleaning effect.

Der wässrige Reiniger wird auf die verschmutzte Fläche aufgetragen und eingearbeitet. Hierzu sollte möglichst ein Gegenstand, wie eine Bürste, ein Schwamm oder ähnliches benutzt werden. Nach der Einarbeitung wird die überflüssige Flüssigkeit abgewischt und Reiniger kann kurz einwirken.Of the aqueous Cleaner is applied to the soiled area and incorporated. For this should be possible an object, like a brush, a sponge or something similar to be used. After incorporation, the excess liquid is wiped off and cleaner can act briefly.

Anschließend wird der sich in einer Sprühflasche befindliche wasserfreie Reiniger benutzt. Die zu behandelnde Fläche wird hierzu in kurzem Abstand eingesprüht. Hierbei ist zu beachten, dass die Fläche mit dem wasserfreien Reiniger gut benetzt wird. Eventuell ablaufende Flüssigkeit abwischen und anschließend die Fläche trocknen lassen.Subsequently, will in a spray bottle used anhydrous cleaners. The area to be treated becomes sprayed in a short distance. Please note that the area with the anhydrous cleaner is well wetted. Eventually expiring liquid wipe and then the area let dry.

Hierdurch wird mit einem einfachen Verfahren die Reinigung von Specksein von verschiedenen Verschmutzungen erzielt.hereby is used to clean bacon with a simple procedure achieved different pollution.

Claims (1)

Verfahren zur Reinigung von Specksteinen dadurch gekennzeichnet, dass dieser zunächst mit einem wässrigen Reiniger 1) enthaltend 0,5–10% Diethylenglykolmonobutylether 0,5 –10% Ethylenglykolmonobutylether 0,1–1% Alkalihydroxide 0,1–1% Alkalisilikate 0,5–10% Alkaliphosphate 0,5–10% Alkaliisopropylbenzolsulfonate 0,5–10% Isotridecanolethoxylate 0,5–10% n-Alkylbenzolsulfonate, Ethersulfonate, Fettalkoholethoxylate 0,5–10% Fettsäureseifen (Alkali) und anschließend mit einem wasserfreien Reiniger 2) enthaltend 10–50% Cycloparaffin 10–50% Isoparaffin (C8-C10) 1–10% n-Paraffin (C6-C8) behandelt wird.Process for purifying soapstone, characterized in that it first with an aqueous cleaner 1) containing 0.5-10% diethylene glycol monobutyl ether 0.5-10% ethylene glycol monobutyl ether 0.1-1% alkali hydroxides 0.1-1% alkali silicates 0.5-10% alkali phosphates 0.5-10% alkali isopropylbenzenesulfonates 0.5-10% isotridecanol ethoxylates 0.5-10% n- Alkylbenzenesulfonates, ether sulfonates, fatty alcohol ethoxylates 0.5-10% fatty acid soaps (alkali) and then with an anhydrous detergent 2) containing 10-50% cycloparaffin 10-50% isoparaffin (C 8 -C 10 ) 1-10% n-paraffin (C 6 -C 8 ).
DE10357389A 2003-12-07 2003-12-07 Process for cleaning soapstone Expired - Fee Related DE10357389B4 (en)

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Application Number Priority Date Filing Date Title
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DE10357389B4 true DE10357389B4 (en) 2005-12-15

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Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3511707A (en) * 1967-05-08 1970-05-12 North American Detergent Corp Method of cleaning a stone surface and composition therefor
DE2204903A1 (en) * 1971-08-31 1973-08-02 Chvatal Theodor Dr Ing Stonework cleaning - using pastes of strong acids and abrasive powders
FR2277146A1 (en) * 1974-07-05 1976-01-30 Guilabert Emmanuel All-purpose cleaner - contg. lauric and alkylaryl polyglycolic esters and trimethylcetyl chloride
GB2006256A (en) * 1977-10-04 1979-05-02 Secr Education & Science Cleaning stone
DE2900368A1 (en) * 1979-01-05 1980-07-10 Esto Klinker Ebersdorfer Scham Stone cleaning and maintenance compsn. - contains acrylic! resin and solvent mixt. contg. chloro-hydrocarbon
DE3432581A1 (en) * 1984-09-05 1986-03-06 Heinz 7140 Ludwigsburg Meyer Surface cleaner, especially for stone
EP0215451A2 (en) * 1985-09-20 1987-03-25 Henkel Kommanditgesellschaft auf Aktien Cleaning product for hard surfaces
EP0411708A2 (en) * 1989-07-31 1991-02-06 Colgate-Palmolive Company Safe acidic hard surface cleaner
DE4326112A1 (en) * 1993-08-04 1995-02-09 Henkel Kgaa Detergent for hard surfaces
WO1995010593A1 (en) * 1993-10-12 1995-04-20 Munford Finance S.A. Anti-adhesive liquid cleaning composition
WO1997005230A1 (en) * 1995-07-28 1997-02-13 Philippe Lutringer Liquid cleaning composition
WO1998022563A2 (en) * 1996-11-20 1998-05-28 Dieter Krattenmacher Detergents for universal and special cleaning operations
WO1998038143A1 (en) * 1997-02-26 1998-09-03 S.C. Johnson Commercial Markets, Inc. Cream crystallizer stone floor maintenance composition and method
US5977042A (en) * 1998-10-01 1999-11-02 S. C. Johnson Commercial Markets, Inc. Concentrated stripper composition and method

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3511707A (en) * 1967-05-08 1970-05-12 North American Detergent Corp Method of cleaning a stone surface and composition therefor
DE2204903A1 (en) * 1971-08-31 1973-08-02 Chvatal Theodor Dr Ing Stonework cleaning - using pastes of strong acids and abrasive powders
FR2277146A1 (en) * 1974-07-05 1976-01-30 Guilabert Emmanuel All-purpose cleaner - contg. lauric and alkylaryl polyglycolic esters and trimethylcetyl chloride
GB2006256A (en) * 1977-10-04 1979-05-02 Secr Education & Science Cleaning stone
DE2900368A1 (en) * 1979-01-05 1980-07-10 Esto Klinker Ebersdorfer Scham Stone cleaning and maintenance compsn. - contains acrylic! resin and solvent mixt. contg. chloro-hydrocarbon
DE3432581A1 (en) * 1984-09-05 1986-03-06 Heinz 7140 Ludwigsburg Meyer Surface cleaner, especially for stone
EP0215451A2 (en) * 1985-09-20 1987-03-25 Henkel Kommanditgesellschaft auf Aktien Cleaning product for hard surfaces
EP0411708A2 (en) * 1989-07-31 1991-02-06 Colgate-Palmolive Company Safe acidic hard surface cleaner
DE4326112A1 (en) * 1993-08-04 1995-02-09 Henkel Kgaa Detergent for hard surfaces
WO1995010593A1 (en) * 1993-10-12 1995-04-20 Munford Finance S.A. Anti-adhesive liquid cleaning composition
WO1997005230A1 (en) * 1995-07-28 1997-02-13 Philippe Lutringer Liquid cleaning composition
WO1998022563A2 (en) * 1996-11-20 1998-05-28 Dieter Krattenmacher Detergents for universal and special cleaning operations
WO1998038143A1 (en) * 1997-02-26 1998-09-03 S.C. Johnson Commercial Markets, Inc. Cream crystallizer stone floor maintenance composition and method
US5977042A (en) * 1998-10-01 1999-11-02 S. C. Johnson Commercial Markets, Inc. Concentrated stripper composition and method

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Jahrbuch für den Praktiker 2001, Augsburg: Verlag für chemische Industrie, H. Ziolkowsky GmbH, 2001, S. 113-117, ISBN: 3-87846-218-2
Jahrbuch für den Praktiker 2001, Augsburg: Verlag für chemische Industrie, H. Ziolkowsky GmbH, 2001,S. 113-117, ISBN: 3-87846-218-2 *
JP 03182596 A (abstract), In: Pat. Abstr. of Jp., [CD-ROM] *

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