DE10357389A1 - Non-mechanical cleaning of soapstone and other stones, using aqueous cleaner, applied first, and a non-aqueous cleaner - Google Patents

Non-mechanical cleaning of soapstone and other stones, using aqueous cleaner, applied first, and a non-aqueous cleaner Download PDF

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Publication number
DE10357389A1
DE10357389A1 DE10357389A DE10357389A DE10357389A1 DE 10357389 A1 DE10357389 A1 DE 10357389A1 DE 10357389 A DE10357389 A DE 10357389A DE 10357389 A DE10357389 A DE 10357389A DE 10357389 A1 DE10357389 A1 DE 10357389A1
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percentage points
alkali
soapstone
cleaning
aqueous
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DE10357389A
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DE10357389B4 (en
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Juergen Michael Benda
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/044—Hydroxides or bases
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00—Compositions of detergents, not provided for by one single preceding group
    • C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/08—Silicates
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/2068—Ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/24—Hydrocarbons
    • C11D7/241—Hydrocarbons linear
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
    • C11D7/22—Organic compounds
    • C11D7/24—Hydrocarbons
    • C11D7/247—Hydrocarbons aromatic
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C11D2111/24—
    • C11D2111/44—

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)

Abstract

Non-mechanical method for cleaning soapstone and/or other stones using two cleaning compositions, one aqueous and the other non-aqueous. Non-mechanical method for cleaning soapstone and/or other stones using two cleaning compositions, one aqueous, applied first for a pretreatment, and the other non-aqueous, for the main treatment. The first composition comprises 0.5-10% diethylene glycol monobutyl ether; 0.5-10% ethylene glycol monobutyl ether; 0.1-% each of alkali hydroxide and alkali silicate; 0-5-10% each of alkali phosphate, alkali isopropylbenzene sulfonate, and isotridecanol ethoxylate; 0.5-10% n-alkylbenzene sulfonate, ether sulfonate or fatty alcohol ethoxylate and 0.5-10% fatty acid soap (alkali); and the second composition contains 10-50% each of 'meta-naphatene' and 8-10C isopraffins, and 10% 6-8C n-paraffins. An independent claim is also included for a device that ensures successful cleaning only by correct combination of the two compositions.

Description

Die Erfindung betrifft das Verfahren zur nicht mechanischen Reinigung von Speckstein und/oder andern Steinen mit dem eine möglichst einfache Alternative zur herkömmlichen Fleckenbeseitigung sichergestellt werden soll.The The invention relates to the method for non-mechanical cleaning of soapstone and / or other stones with the one possible simple alternative to conventional Stain removal should be ensured.

Bekannt ist, das bislang nur das Entfernen von Fettflecken an Speckstein und/oder anderen Steinen durch Aceton sichergestellt ist. Alle anderen Verschmutzungen sind nur auf dem mechanischen Wege durch abschleifen mit Nass-Schleifpapier bis hin zum neu aufschleifen oder aufpolieren durch einen Steinmetz möglich. Ein zufriedenstellendes Ergebnis setzt hier fachmännische Kenntnisse voraus, verbunden mit dem Entstehen von dadurch resultierenden erhöhtem Kostenaufwand. Außerdem kann trotz fachkundigem Arbeiten der ursprüngliche Zustand nach erfolgter mechanischer Behandlung nicht hundertprozentig sichergestellt werden.Known is, so far only the removal of grease stains on soapstone and / or other stones is ensured by acetone. All other dirt are only by mechanical means by sanding with wet sandpaper up to the new grind up or polish up by a stonemason possible. A satisfactory result sets here expert Knowledge precedes, associated with the emergence of resulting increased Cost. Furthermore can, despite expert work, the original state after successful mechanical treatment can not be guaranteed one hundred percent.

Aufgabe der Erfindung ist es, das Entfernen von Verschmutzungen an Speckstein und/oder Steinen auf nichtmechanischem Wege und somit eine leichte Reinigung, anwendbar durch jedermann, sicherzustellen.task The invention is the removal of dirt on soapstone and / or stones by non-mechanical means and thus a light Cleaning, applicable by anyone, to make sure.

Die Beseitigung von Verschmutzungen wird durch die Kombination eines wässrigen Reinigers zur Vorbehandlung und einem wasserfreien Reiniger zur Hauptbehandlung sichergestellt. Die Verknüpfung dieser beiden Reiniger ermöglicht es, unterschiedlichste Arten von Verschmutzungen mit nur einem Produkt entfernen zu können.The Elimination of contamination is by combining a aqueous Pre-treatment cleaner and an anhydrous primary treatment cleaner ensured. The linkage of this allows both cleaners it, all kinds of soiling with only one product to be able to remove.

Diese nicht mechanische Reinigung hat den Vorteil, für die Beseitigung unterschiedlichster Verschmutzungen nur ein Kombinationsprodukt zu benötigen, welches den Specksteins und/oder anderen Stein innerhalb kürzester Zeit in den Zustand vor der Verunreinigung zurückbringt.These non-mechanical cleaning has the advantage for the removal of various Pollutions only need a combination product, which the soapstone and / or other stone within the shortest time Time back to the state before the pollution.

Diese Lösungsmöglichkeit ist zum einen dadurch gekennzeichnet, kostengünstiger als die mechanische Beseitigung von Flecken zu sein. Ein weiterer Aspekt ist, das die Verschmutzungsentfernung sofort und ohne jegliche Fremdhilfe angewandt werden kann. Auch und gerade der daraus resultierende positive wirtschaftliche Aspekt ist in Betracht zu ziehen.These possible solution on the one hand characterized, cheaper than the mechanical To be removal of stains. Another aspect is that the Pollution removal applied immediately and without any external assistance can be. Also and especially the resulting positive economic Aspect is to be considered.

Bei der Entfernung von Flecken an Speckstein und/oder anderen Steinen ist wie folgt vorzugehen:
Zur Reinigung der verschmutzen Flächen sollten sich diese auf Raumtemperatur befinden, um eine optimale Reinigungswirkung zu erzielen.When removing stains from soapstone and / or other stones, proceed as follows:
To clean the dirty surfaces, they should be at room temperature for optimum cleaning effect.

Der wässrige Reiniger wird auf die verschmutzte Fläche aufgetragen und eingearbeitet. Hierzu sollte möglichst ein Gegenstand wie eine Bürste, ein Schwamm oder ähnliches benutzt werden. Nach der Einarbeitung überflüssige Flüssigkeit einfach abwischen und das Ganze kurz einwirken lassen.Of the aqueous Cleaner is applied to the soiled area and incorporated. For this should be possible an object like a brush, a sponge or something similar to be used. After incorporation simply wipe off excess liquid and let it work for a short time.

Als nächstes wird der sich in einer Sprühflasche befindliche, wasserfreie Reiniger benutzt. Die zu behandelnde Fläche wird hierzu in kurzem Abstand eingesprüht. Hierbei ist zu beachten, dass die Fläche mit dem wasserfreien Reiniger gut benetzt wird. Hierbei ablaufende Flüssigkeit abwischen und anschließend die Fläche abtrocknen lassen.When next will be in a spray bottle used, anhydrous cleaners used. The area to be treated becomes sprayed in a short distance. Please note that the area is wetted well with the anhydrous cleaner. Hereby expiring liquid wipe and then the area let dry.

Claims (1)

Die Erfindung betrifft das Verfahren zur nicht mechanischen Reinigung von Speckstein und/oder andern Steinen mit dem eine möglichst einfache Alternative zur herkömmlichen Fleckenbeseitigung sichergestellt werden soll. Diese Reinigung erfolgt durch die Vorbehandlung des Speckstein und/oder anderen Stein anhand eines wässrigen Reinigers und die Hauptbehandlung seitens eines wasserfreien Reinigers. Das Verfahren der nichtmechanischen Reinigung von Speckstein und/oder anderen Natursteinen ist dadurch gekennzeichnet das das Material mit einem 1) wässrigen Reiniger enthaltend 0,5 – 10 Prozentpunkte Diethylenglykolmonobutylether 0,5 – 10 Prozentpunkte Ethylenglykolmonobutylether 0,1 – 1 Prozentpunkte Alkalihydroxide 0,1 – 1 Prozentpunkte Alkalisilikate 0,5 – 10 Prozentpunkte Alkaliphosphate 0,5 – 10 Prozentpunkte Alkaliisopropylbenzolsulfonate 0,5 – 10 Prozentpunkte Isotridecanolethoxylate 0,5 – 10 Prozentpunkte N-Alkylbenzolsulfonate, Ethersulfonate, Fettalkoholethoxylate 0,5 – 10 Prozentpunkte Fettsäureseifen (Alkali) und 2) wasserfreier Reiniger enthaltend 10 – 50 Prozentpunkte meta-Naphatene 10 – 50 Prozentpunkte Isoparaffine C8-C10 1 – 10 Prozentpunkte n-Paraffine C6-C8 3) Vorrichtung nach Anspruch 1 und 2 ist dadurch gekennzeichnet, das das Reinigungsergebnis nur durch die korrekte Kombination dieser beiden Reiniger sichergestellt werden kann.The invention relates to the method for non-mechanical cleaning of soapstone and / or other stones with the simplest possible alternative to conventional stain removal is to be ensured. This cleaning is done by pretreating the soapstone and / or other stone using an aqueous cleaner and the main treatment by an anhydrous cleaner. The method of non-mechanical cleaning of soapstone and / or other natural stones is characterized in that the material with a 1) aqueous cleaner containing 0.5 - 10 percentage points of diethylene glycol monobutyl ether 0.5 - 10 percentage points of ethylene glycol monobutyl ether 0.1 - 1 percentage points alkali hydroxides 0.1 - 1 percentage points of alkali metal silicates 0.5 - 10 percentage points of alkali phosphates 0.5 - 10 percentage points of alkali isopropylbenzenesulfonates 0.5 - 10 percentage points of isotridecanol ethoxylates 0.5 - 10 percentage points N-alkylbenzenesulfonates, ether sulfonates, fatty alcohol ethoxylates 0.5 - 10 percentage points of fatty acid soaps (alkali) and 2) Anhydrous cleaner containing 10 - 50 percentage points meta-naphatene 10 - 50 percentage points isoparaffins C 8 -C 10 1 - 10 percentage points n-paraffins C 6 -C 8 3) Device according to claim 1 and 2 characterized in that the cleaning result only by the correct combination of these two cleaners can be ensured.
DE10357389A 2003-12-07 2003-12-07 Process for cleaning soapstone Expired - Fee Related DE10357389B4 (en)

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Application Number Priority Date Filing Date Title
DE10357389A DE10357389B4 (en) 2003-12-07 2003-12-07 Process for cleaning soapstone

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DE10357389B4 DE10357389B4 (en) 2005-12-15

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Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3511707A (en) * 1967-05-08 1970-05-12 North American Detergent Corp Method of cleaning a stone surface and composition therefor
DE2204903A1 (en) * 1971-08-31 1973-08-02 Chvatal Theodor Dr Ing Stonework cleaning - using pastes of strong acids and abrasive powders
FR2277146A1 (en) * 1974-07-05 1976-01-30 Guilabert Emmanuel All-purpose cleaner - contg. lauric and alkylaryl polyglycolic esters and trimethylcetyl chloride
GB2006256A (en) * 1977-10-04 1979-05-02 Secr Education & Science Cleaning stone
DE2900368A1 (en) * 1979-01-05 1980-07-10 Esto Klinker Ebersdorfer Scham Stone cleaning and maintenance compsn. - contains acrylic! resin and solvent mixt. contg. chloro-hydrocarbon
DE3432581A1 (en) * 1984-09-05 1986-03-06 Heinz 7140 Ludwigsburg Meyer Surface cleaner, especially for stone
EP0215451A2 (en) * 1985-09-20 1987-03-25 Henkel Kommanditgesellschaft auf Aktien Cleaning product for hard surfaces
EP0411708A2 (en) * 1989-07-31 1991-02-06 Colgate-Palmolive Company Safe acidic hard surface cleaner
DE4326112A1 (en) * 1993-08-04 1995-02-09 Henkel Kgaa Detergent for hard surfaces
WO1995010593A1 (en) * 1993-10-12 1995-04-20 Munford Finance S.A. Anti-adhesive liquid cleaning composition
WO1997005230A1 (en) * 1995-07-28 1997-02-13 Philippe Lutringer Liquid cleaning composition
WO1998022563A2 (en) * 1996-11-20 1998-05-28 Dieter Krattenmacher Detergents for universal and special cleaning operations
WO1998038143A1 (en) * 1997-02-26 1998-09-03 S.C. Johnson Commercial Markets, Inc. Cream crystallizer stone floor maintenance composition and method
US5977042A (en) * 1998-10-01 1999-11-02 S. C. Johnson Commercial Markets, Inc. Concentrated stripper composition and method

Patent Citations (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3511707A (en) * 1967-05-08 1970-05-12 North American Detergent Corp Method of cleaning a stone surface and composition therefor
DE2204903A1 (en) * 1971-08-31 1973-08-02 Chvatal Theodor Dr Ing Stonework cleaning - using pastes of strong acids and abrasive powders
FR2277146A1 (en) * 1974-07-05 1976-01-30 Guilabert Emmanuel All-purpose cleaner - contg. lauric and alkylaryl polyglycolic esters and trimethylcetyl chloride
GB2006256A (en) * 1977-10-04 1979-05-02 Secr Education & Science Cleaning stone
DE2900368A1 (en) * 1979-01-05 1980-07-10 Esto Klinker Ebersdorfer Scham Stone cleaning and maintenance compsn. - contains acrylic! resin and solvent mixt. contg. chloro-hydrocarbon
DE3432581A1 (en) * 1984-09-05 1986-03-06 Heinz 7140 Ludwigsburg Meyer Surface cleaner, especially for stone
EP0215451A2 (en) * 1985-09-20 1987-03-25 Henkel Kommanditgesellschaft auf Aktien Cleaning product for hard surfaces
EP0411708A2 (en) * 1989-07-31 1991-02-06 Colgate-Palmolive Company Safe acidic hard surface cleaner
DE4326112A1 (en) * 1993-08-04 1995-02-09 Henkel Kgaa Detergent for hard surfaces
WO1995010593A1 (en) * 1993-10-12 1995-04-20 Munford Finance S.A. Anti-adhesive liquid cleaning composition
WO1997005230A1 (en) * 1995-07-28 1997-02-13 Philippe Lutringer Liquid cleaning composition
WO1998022563A2 (en) * 1996-11-20 1998-05-28 Dieter Krattenmacher Detergents for universal and special cleaning operations
WO1998038143A1 (en) * 1997-02-26 1998-09-03 S.C. Johnson Commercial Markets, Inc. Cream crystallizer stone floor maintenance composition and method
US5977042A (en) * 1998-10-01 1999-11-02 S. C. Johnson Commercial Markets, Inc. Concentrated stripper composition and method

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Jahrbuch für den Praktiker 2001, Augsburg: Verlag für chemische Industrie, H. Ziolkowsky GmbH, 2001, S. 113-117, ISBN: 3-87846-218-2
Jahrbuch für den Praktiker 2001, Augsburg: Verlag für chemische Industrie, H. Ziolkowsky GmbH, 2001,S. 113-117, ISBN: 3-87846-218-2 *
JP 03182596 A (abstract), In: Pat. Abstr. of Jp., [CD-ROM] *

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