DE102012205218A1 - Antiperspirant compositions with cycloaliphatic diols and zirconium salts - Google Patents

Abstract

The present application relates to antiperspirant compositions containing at least one aluminum-zirconium compound and at least one cycloaliphatic diol and having improved residue masking.

Description

The present application relates to antiperspirant compositions containing at least one aluminum-zirconium compound and at least one cycloaliphatic diol and having improved residue masking.

State of the art

Commercially available antiperspirant compositions, also referred to below as antiperspirants, contain as antiperspirant active ingredient at least one water-soluble astringent salt of aluminum or at least one water-soluble astringent aluminum-zirconium mixed salt. The antiperspirant active ingredients have no direct influence on the activity of the sweat glands, but minimize the narrowing of the discharge channels sweat secretion. The Al salts or Al-Zr salts cause sweat inhibition on the treated skin surfaces by superficial blockage of the sweat gland ducts as a result of precipitation of Al mucopolysaccharides or Al-Zr mucopolysaccharides.

Antiperspirant compositions are usually applied and applied in the armpit area. Upon drying of the composition on the skin or on the clothing which has come into contact with the skin after application of the antiperspirant, the antiperspirant salt is often seen as a white residue. This also occurs in aqueous compositions in which the antiperspirant salt is initially in dissolved form. The white residues are perceived by the consumer as a very negative product feature. For masking Al-salt or Al-Zr salt residues of aqueous compositions, both water-soluble constituents, in particular 1,2-propylene glycol, and oils, in particular ester oils, such as isopropyl palmitate or alkyl benzoates, are known in the prior art. Such masking agents wet the antiperspirant salt and do not evaporate even after application to the skin, as do, for example, water and cyclomethicones. As a result, the antiperspirant salt dries much slower, and the occurrence of visible residues is delayed. The masking can be further improved by selecting a masking agent whose refractive index n _D lies in the range of the refractive index n _{D of} typical antiperspirant salts or typically used aqueous solutions of antiperspirant salts, ie in the range of n _D ²⁰ = 1.4 to 1 ,. 6 The disadvantage of the known water-soluble masking agents, such as sorbitol and highly concentrated aqueous sorbitol solutions (50 to 70 wt .-% wt .-% sorbitol), is in particular that they give the antiperspirant composition a sticky feel on the skin. High-masking oils have the disadvantage of causing fabric staining. The use of masking oils in formulations with a high proportion of aqueous phase is limited because of the difficulty of incorporation, compatibility with the formulation and stability of the formulation. For formulations with a high proportion of aqueous phase and low proportion of oil phase, in particular Rollon formulations, the masking is carried out essentially by sequestering the aqueous phase, which leads to a particularly high tackiness of the formulation at the required high concentrations.

Aluminum zirconium chlorohydrate shows a stronger antiperspirant effect compared to aluminum chlorohydrate. However, the additional effectiveness of zirconium is partially reversed in many formulations by the use of 1,2-propylene glycol. 1,2-propylene glycol is often used in antiperspirants as a solvent. In certain cases, 1,2-propylene glycol is also needed to reduce white residues or to match the refractive index of water and oil phases on clear gels. 1,2-propylene glycol and other glycols, such as 1,2-hexanediol, interact as a compex ligand with the zirconium ion and can thus reduce the antiperspirant efficacy of the aluminum-zirconium chlorohydrates. Cycloaliphatic diols, such as. B. 1,4-bis (hydroxymethyl) cyclohexane, 1,2-propylene glycol can replace completely or partially in antiperspirant formulations. This leads to a significantly improved antiperspirant effectiveness, since the ability to complex on Zr ⁴⁺ ion by the cycloaliphatic bridge between the two hydroxyl groups is repealed.

For formulations with a high proportion of aqueous phase, there is often the problem of lack of temperature stability, especially at very low temperatures.

Furthermore, there is often the problem of poor perfume adhesion in formulations with a high proportion of aqueous phase. A good perfume adhesion is particularly important for the commercial success of an antiperspirant product, because it is equated by the consumer with the antiperspirant effect of the product. To improve the perfume adhesion of water-containing compositions cationic surfactants are often used, however, affect the skin compatibility of the product can. The use of encapsulated perfume also extends the perfume liability, but increases the cost of raw materials.

Antiperspirant compositions containing water or at least one water-soluble organic solvent or mixtures of these substances are available in various dosage forms, for example as dibenzylidenalditol-based gel, or as water-in-oil emulsion, polyol-in-oil emulsion, An alcohol-in-oil emulsion, in particular an ethanol-in-oil emulsion, that is to say as an emulsion with a continuous oil phase and dispersed hydrophilic phase in which the antiperspirant active ingredient is dissolved or at least solubilized. Such compositions may be in the form of a viscous gel, in particular a transparent viscous gel, a liquid roll-on or a solid stick.

There is a continuing need for antiperspirant compositions containing water or at least one water-soluble organic solvent or mixtures of these substances which have good residue masking, reduced visible residue, reduced tack, reduced fiber soiling, improved temperature stability and prolonged perfume adhesion.

US 7569530 discloses 1,2-cyclohexanedimethanol as an antimicrobial agent. In US 7591861 Cyclohexanedimethanol (without indication of substitution positions) is disclosed as a glycolic solvent having a logP value of 0.5 to 4.0 for hair pretreatment, which improves the penetration of a subsequently applied dye into the hair.

task

An object of the present invention was to provide zirconium-containing antiperspirant compositions containing water or at least one water-soluble organic solvent or mixtures of these substances with high residue masking and reduced visible residues.

Another object of the present invention has been to provide zirconium-containing antiperspirant compositions containing water or at least one water-soluble organic solvent or mixtures of these substances with reduced tackiness.

Another object of the present invention was to provide zirconium-containing antiperspirant compositions containing water or at least one water-soluble organic solvent or mixtures of these substances with reduced fiber soiling. Another object of the present invention was to provide zirconium-containing antiperspirant compositions containing water or at least one water-soluble organic solvent or mixtures of these substances with improved temperature stability, especially at low temperatures.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht.

Another object of the present invention was to provide zirconium-containing antiperspirant compositions containing water or at least one water-soluble organic solvent or mixtures of these substances with prolonged perfume adhesion. Surprisingly, it has been found that the stated objects are achieved by at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• - q stands for the number 0, 1, 2, 3, 4 or 5.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel; ausgenommen die folgenden Zusammensetzungen A, B, C, D, E und F (alle Mengenangaben in Gew.-%):
die Öl-in-Wasser-Emulsionen A und B: A B ALUMINUM ZIRCONIUM TETRACHLOROHYDREX GLY 23,7 23,7 STEARETH-2 2,4 2,4 STEARETH-21 1,6 1,6 PARFUM 1,2 1,2 PPG-15 STEARYL ETHER 0,5 0,5 ALUMINUM STARCH OCTENYLSUCCINATE 0,1 0,1 TOCOPHERYL ACETATE 0,5 0,5 1,4-Cyclohexandimethanol 5,0 2,0 Wasser, vollentsalzt ad 100,0 ad 100,0 die sprühfähigen, transluzenten Antitranspirant-Mikroemulsionen C, D und E: C D E Plantaren^® 1200 1,71 1,71 - Plantaren^® 2000 1,14 1,39 2,40 Glycerinmonooleat 0,71 0,71 - Dioctylether 4,00 4,00 0,09 Octyldodecanol 1,00 1,00 0,02 Parfümöl 1,00 1,00 1,00 Aluminium-Zirconium Tetrachlorohydrex Gly 20,0 20,0 20,0 1,4-Cyclohexandimethanol 3,0 5,0 4,0 1,2-Propylenglycol 2,0 - - Glycerin - - 1,00 Phenoxyethanol - 1,0 1,0 Wasser ad 100 ad 100 ad 100 Plantaren^® 1200 LAURYL GLUCOSIDE, ca. 50 % Aktivsubstanz Plantaren^® 2000 DECYL GLUCOSIDE, ca. 50 % Aktivsubstanz und der Wasser-in-Öl-Emulsions-Antitranspirant-Stift F: F Dow Corning 345 Fluid 23,7 Finsolv TN 12,6 Isostearylalkohol 11,5 N-Lauroyl-L-glutaminsäure-di-n-butylamid (GP-1 von Ajinomoto, Schmelzpunkt 155– 163 °C) 3,8 Abil EM 90 0,95 Aluminium-Zirconium Tetrachlorohydrex Gly 20 Glycerin, 99,5 Gew.-% 5,0 1,4-Cyclohexandimethanol 5,0 Wasser 20,0 Dow Corning 345 Fluid Cyclomethicone (Decamethylcyclopentasiloxan, Dodecamethylcyclohexasiloxan) Finsolv TN C12-15 ALKYL BENZOATE Abil EM 90 Cetyl PEG/PPG-10/1 Dimethicone An object of the present application is therefore an antiperspirant composition comprising at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents; excluding the following compositions A, B, C, D, E and F (all amounts in% by weight):
the oil-in-water emulsions A and B: A B ALUMINUM ZIRCONIUM TETRACHLOROHYDREX GLY 23.7 23.7 STEARETH-2 2.4 2.4 STEARETH-21 1.6 1.6 PERFUME 1.2 1.2 PPG-15 STEARYL ETHER 0.5 0.5 ALUMINUM STARCH OCTENYLSUCCINATE 0.1 0.1 TOCOPHERYL ACETATE 0.5 0.5 1,4-cyclohexanedimethanol 5.0 2.0 Water, demineralized ad 100.0 ad 100.0 the sprayable, translucent antiperspirant microemulsions C, D and E: C D e Plantar ^® 1200 1.71 1.71 - Plantar ^® 2000 1.14 1.39 2.40 Glycerol monooleate 0.71 0.71 - dioctyl 4.00 4.00 0.09 octyldodecanol 1.00 1.00 0.02 perfume oil 1.00 1.00 1.00 Aluminum-Zirconium Tetrachlorohydrex Gly 20.0 20.0 20.0 1,4-cyclohexanedimethanol 3.0 5.0 4.0 1,2-propylene glycol 2.0 - - glycerin - - 1.00 phenoxyethanol - 1.0 1.0 water ad 100 ad 100 ad 100 Plantar ^® 1200 LAURYL GLUCOSIDE, approx. 50% active substance Plantar ^® 2000 DECYL GLUCOSIDE, approx. 50% active substance and the water-in-oil emulsion antiperspirant stick F: F Dow Corning 345 Fluid 23.7 Finsolv TN 12.6 isostearyl 11.5 N-Lauroyl-L-glutamic acid-di-n-butylamide (GP-1 from Ajinomoto, m.p. 155-163 ° C) 3.8 Abil EM 90 0.95 Aluminum-Zirconium Tetrachlorohydrex Gly 20 Glycerol, 99.5% by weight 5.0 1,4-cyclohexanedimethanol 5.0 water 20.0 Dow Corning 345 Fluid Cyclomethicone (decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane) Finsolv TN C12-15 ALKYL BENZOATE Abil EM 90 Cetyl PEG / PPG-10/1 dimethicone

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, in einer Antitranspirant-Zusammensetzung, enthaltend

mindestens eine Aluminium-Zirconium-Verbindung und mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, zur Reduzierung der Sichtbarkeit von Rückständen. Another object of the present application is the use of at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q is the number 0, 1, 2, 3, 4 or 5, in an antiperspirant composition containing

at least one aluminum-zirconium compound and at least one liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, to reduce the visibility of residues.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, in einer Antitranspirant-Zusammensetzung, enthaltend

mindestens eine Aluminium-Zirconium-Verbindung und mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, zur Reduzierung der Klebrigkeit der Zusammensetzung. Another object of the present application is the use of at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q is the number 0, 1, 2, 3, 4 or 5, in an antiperspirant composition containing

at least one aluminum-zirconium compound and at least one liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, to reduce the stickiness of the composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, in einer Antitranspirant-Zusammensetzung, enthaltend

mindestens eine Aluminium-Zirconium-Verbindung und mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, zur Reduzierung der Faseranschmutzung. Another object of the present application is the use of at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q is the number 0, 1, 2, 3, 4 or 5, in an antiperspirant composition containing

at least one aluminum-zirconium compound and at least one solvent which is liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms, and mixtures of these solvents, for reducing fiber soiling.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, in einer Antitranspirant-Zusammensetzung, enthaltend

mindestens eine Aluminium-Zirconium-Verbindung und mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, zur Verbesserung der Temperaturstabilität der Zusammensetzung, insbesondere bei niedrigen Temperaturen. Another object of the present application is the use of at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q is the number 0, 1, 2, 3, 4 or 5, in an antiperspirant composition containing

at least one aluminum-zirconium compound and at least one liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, for improving the temperature stability of the composition, especially at low temperatures.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, in einer Antitranspirant-Zusammensetzung, enthaltend

mindestens eine Aluminium-Zirconium-Verbindung und mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, und mindestens ein Riechstoff, zur Verlängerung der Riechstoffhaftung. Another object of the present application is the use of at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q is the number 0, 1, 2, 3, 4 or 5, in an antiperspirant composition containing

at least one aluminum-zirconium compound and at least one liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one perfume, to extend the fragrance adhesion.

"Normal conditions" in the sense of the present application, a temperature of 20 ° C and a pressure of 1013.25 mbar. Melting point data also refer to a pressure of 1013.25 mbar.

Unless stated otherwise, all quantities are based on the total weight of the antiperspirant composition according to the invention.

Preferred compositions according to the invention comprise at least one compound of the formula R ¹ -YR ² , in which Y is cyclohexane-1,4-diyl, cyclohexane-1,3-diyl, cyclohexane-1,2-diyl, cyclopentane-1,2-diyl or cyclopentane-1,3-diyl. Particularly preferred compositions according to the invention contain at least one compound of the formula R ¹ -YR ² in which Y is cyclohexane-1,4-diyl.

Further preferred compositions according to the invention comprise at least one compound of the formula R ¹ -YR ² , in which q is the number 0.

Further preferred compositions according to the invention comprise at least one compound of the formula R ¹ -YR ² , in which R ^{3 is} a hydrogen atom.

Further preferred compositions according to the invention contain at least one compound of the formula R ¹ -YR ² in which R ^{4 is} a hydrogen atom or a methyl group.

Further preferred compositions according to the invention comprise at least one compound of the formula R ¹ -YR ² , in which p is the number 1, 2 or 3, preferably 1.

Further preferred compositions according to the invention comprise at least one compound of the formula R ¹ -YR ² , in which q is the number 0, 1, 2, 3, 4 or 5, preferably 0.

In this case, it is again particularly preferred if q is the number 0, p is the number 1 and Y is a cyclohexane-1,4-diyl group. Extraordinary preference is given to compositions comprising at least one compound of the formula R ¹ -YR ² in which q is the number 0, p is the number 1, R ^{3 is} a hydrogen atom and Y is a cyclohexane-1,4-diyl group. The resulting cycloalkane 1,4-bis (hydroxymethyl) cyclohexane is very particularly preferably suitable as component (b) of compositions according to the invention.

1,4-bis (hydroxymethyl) cyclohexane (also referred to as 1,4-dimethylolcyclohexane or cyclohexane-1,4-dimethanol) has the following structural formula:

For the effects according to the invention it is irrelevant whether 1,4-bis (hydroxymethyl) cyclohexane is used as pure cis isomer, as pure trans isomer or as isomeric mixture of cis and trans isomers.

Commercially available 1,4-bis (hydroxymethyl) cyclohexane (Verityl AB-1000 from Eastman) is present as a cis / trans isomer mixture. This isomer mixture has the CAS no. 105-08-8. A preferred isomer mixture according to the invention contains 29-33% by weight of cis isomer (CAS No. 3236-47-3, melting point: 43 ° C.) and 71-67% by weight of trans isomer (CAS No. 3236-). 48-4, melting point: 67 ° C) and has a refractive index n _D ²⁰ of 1.487.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, in einer Gesamtmenge von 0,1 bis 50 Gew.-%, bevorzugt 1–20 Gew.-%, besonders bevorzugt 2–15 Gew.-%, außerordentlich bevorzugt 5–10 Gew.-%, jeweils bezogen auf das Gesamtgewicht der erfindungsgemäßen Zusammensetzung.

Antiperspirant compositions preferred according to the invention contain at least one compound of the formula R ¹ -YR ² in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• - q is the number 0, 1, 2, 3, 4 or 5, in a total amount of 0.1 to 50 wt .-%, preferably 1-20 wt .-%, particularly preferably 2-15 wt .-% , most preferably 5-10 wt .-%, each based on the total weight of the composition according to the invention.

According to the invention particularly preferred antiperspirant compositions contain, based on their total weight, a total of 0.1 to 50 wt .-%, preferably 1-20 wt .-%, more preferably 2-15 wt .-%, most preferably 5-10 wt. -%, of 1,4-bis (hydroxymethyl) cyclohexane.

Surprisingly, it has been found that water-in-oil emulsions according to the invention have a particularly high temperature stability.

Antiperspirant components

The compositions according to the invention contain as antiperspirant active ingredient at least one aluminum-zirconium compound, which is preferably water-soluble.

According to the invention, water solubility is understood as meaning a solubility of at least 3% by weight at 20 ° C., ie amounts of at least 3 g of the antiperspirant active in 97 g of water, preferably amounts of at least 5 g of the antiperspirant active in 95 g Water, are soluble at 20 ° C.

Preferred antiperspirant aluminum-zirconium compounds are selected from aluminum zirconium glycol complexes, e.g. B. aluminum zirconium 1,2-propylene glycol complexes, further selected from Aluminiumzirconiumchlorhydraten as Aluminiumzirconiumtrichlorhydrat, Aluminiumzirconiumtetrachlorhydrat, Aluminiumzirconiumpentachlorhydrat, Aluminiumzirconiumoctachlorhydrat, aluminum-zirconium chlorohydrate glycine complexes, such as Aluminiumzirconiumtrichlorhydrexglycin, Aluminiumzirconiumtetrachlorhydrexglycin, Aluminiumzirconiumpentachlorhydrexglycin and Aluminiumzirconiumoctachlorhydrexglycin.

According to the invention particularly preferred antiperspirant active ingredients are selected from so-called "activated" aluminum-zirconium compounds, which are also referred to as "antiperspirant active ingredients" with increased activity (English: enhanced activity). Such agents are known in the art and are also commercially available. Their production is for example in US 4775528 and US 6010688 disclosed. Activated aluminum-zirconium compounds are typically produced by heat treating a relatively dilute solution of the salt (eg, about 10% by weight of salt) to increase its HPLC peak 4-to-peak 3 area ratio. The activated salt can then be dried to a powder, in particular spray-dried. In addition to the spray drying z. B. also suitable for drum drying.

Activated aluminum-zirconium compounds typically have a HPLC peak 4-to-peak 3 area ratio of at least 0.4, preferably at least 0.7, more preferably at least 0.9, with at least 70% of the aluminum attributable to these peaks. Antiperspirant active ingredients which are likewise preferred according to the invention are nonaqueous solutions or solubilisates of an activated antiperspirant aluminum-zirconium salt, for example according to US 6010688 , in a polyhydric alcohol containing 3 to 6 carbon atoms and 3 to 6 hydroxyl groups, preferably propylene glycol, sorbitol and pentaerythritol.

For example, preferred are weight percent (USP) compositions: 18-45% by weight of an activated aluminum-zirconium salt, 55-82% by weight of at least one anhydrous polyhydric alcohol having 3 to 6 carbon atoms, and 3 to 6 hydroxyl groups , preferably propylene glycol, butylene glycol, diethylene glycol, dipropylene glycol, glycerol, sorbitol and pentaerythritol, more preferably propylene glycol.

Also particularly preferred are complexes of activated aluminum-zirconium antiperspirant salts with a polyhydric alcohol containing 20-50% by weight, more preferably 20-42% by weight, activated antiperspirant aluminum-zirconium salt and 2-16% by weight molecularly-bonded water the remainder being 100% by weight of at least one polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 Is hydroxyl groups. Propylene glycol, propylene glycol / sorbitol mixtures and propylene glycol / pentaerythritol mixtures are preferred such alcohols. Such inventively preferred complexes of an activated antiperspirant aluminum zirconium salt with a polyhydric alcohol are, for. B. disclosed in US 5643558 and US 6245325.

Further preferred antiperspirant active compounds are aluminum-zirconium complexes, as described, for example, in US Pat US 4017599 are disclosed, which are buffered with salts of amino acids, in particular with alkali and Erdalkaliglycinaten.

Further preferred antiperspirant active ingredients are activated aluminum-zirconium salts, as used, for example, in US Pat US 6245325 or US 6042816 containing 5-78% by weight (USP) of an activated aluminum-zirconium antiperspirant salt, an amino acid or hydroxyalkanoic acid in such an amount as to give an (amino acid or hydroxyalkanoic acid) (Al + Zr) weight ratio of 2: 1 1:20 and preferably 1: 1 to 1:10, and a water-soluble calcium salt in such an amount to have a Ca: (Al + Zr) weight ratio of 1: 1-1: 28 and preferably 1: 2-1: 25 to provide. Particularly preferred solid activated antiperspirant salt compositions, for example according to US 6245325 or US 6042816 containing 48-78 wt .-% (USP), preferably 66-75 wt .-% of an activated aluminum-zirconium salt and 1-16 wt .-%, preferably 4-13 wt .-% molecularly bound water (water of hydration), further enough water-soluble calcium salt that the Ca: (Al + Zr) weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and so much amino acid that the amino acid becomes (Al + Zr) weight ratio 2 : 1-1: 20, preferably 1: 1-1: 10.

Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6245325 or US 6042816 containing 48-78 wt .-% (USP), preferably 66-75 wt .-% of an activated aluminum-zirconium salt and 1-16 wt .-%, preferably 4-13 wt .-% molecularly bound water (water of hydration), further sufficient water-soluble calcium salt that the Ca: (Al + Zr) weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and so much glycine that the glycine to (Al + Zr) weight ratio of 2 : 1-1: 20, preferably 1: 1-1: 10.

Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6245325 or US 6042816 , contain 48-78 wt .-% (USP), preferably 66-75 wt .-% of an activated aluminum-zirconium salt and 1-16 wt .-%, preferably 4-13 wt .-% molecularly bound water, further as much water-soluble Calcium salt that the Ca: (Al + Zr) weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and so much hydroxyalkanoic that the hydroxyalkanoic acid to (Al + Zr) weight ratio 2: 1 1:20, preferably 1: 1-1: 10.

Preferred water-soluble calcium salts for the stabilization of antiperspirant salts are selected from calcium chloride, calcium bromide, calcium nitrate, calcium citrate, calcium formate, calcium acetate, calcium gluconate, calcium ascorbate, calcium lactate, calcium glycinate, calcium carbonate, calcium sulfate, calcium hydroxide, and mixtures thereof.

Preferred amino acids for the stabilization of the antiperspirant salts are selected from glycine, alanine, leucine, isoleucine, β-alanine, valine, cysteine, serine, tryptophan, phenylalanine, methionine, β-amino-n-butanoic acid and γ-amino-n-butanoic acid and the salts thereof, each in the d-form, the l-form and the dl-form; Glycine is particularly preferred.

Preferred hydroxyalkanoic acids for the stabilization of the antiperspirant salts are selected from glycolic acid and lactic acid.

Further preferred antiperspirant active ingredients are activated aluminum-zirconium salts, as used, for example, in US Pat US 6902723 containing 5-78% by weight (USP) of an activated aluminum-zirconium antiperspirant salt, an amino acid or hydroxyalkanoic acid in such an amount as to give an (amino acid or hydroxyalkanoic acid) (Al + Zr) weight ratio of 2: 1 1:20 and preferably 1: 1 to 1:10, and a water-soluble strontium salt in such an amount to have a Sr: (Al + Zr) weight ratio of 1: 1-1: 28 and preferably 1: 2-1: 25 to provide.

Particularly preferred solid antiperspirant activated salt compositions, for example according to US 6902723 , contain 48-78 wt .-% (USP), preferably 66-75 wt .-% of an activated aluminum-zirconium salt and 1-16 wt .-%, preferably 4-13 wt .-% molecularly bound water, further as much water-soluble Strontium salt that has the Sr: (Al + Zr) weight ratio 1: 1-1: 28, preferably 1: 2-1: 25, and the amount of amino acid that the amino acid is to (Al + Zr) weight ratio 2: 1-1: 20, preferably 1: 1-1: 10. Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6902723 , contain 48-78 wt .-% (USP), preferably 66-75 wt .-% of an activated aluminum-zirconium salt and 1-16 wt .-%, preferably 4-13 wt .-% molecularly bound water, further as much water-soluble Strontium salt that the Sr: (Al + Zr) weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and so much glycine that the glycine to (Al + Zr) weight ratio 2: 1 1:20, preferably 1: 1-1: 10.

Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6902723 , contain 48-78 wt .-% (USP), preferably 66-75 wt .-% of an activated aluminum-zirconium salt and 1-16 wt .-%, preferably 4-13 wt .-% molecularly bound water, further as much water-soluble Strontium salt that the Sr: (Al + Zr) weight ratio is 1: 1-1: 28, preferably 1: 2-1: 25, and so much hydroxyalkanoic that the hydroxyalkanoic acid to (Al + Zr) weight ratio 2: 1 1:20, preferably 1: 1-1: 10. Preferred activated aluminum-zirconium salts are those which are mixtures or complexes of the aluminum salts described above with zirconium salts of the formula ZrO (OH) _2-pb Y _b represent wherein Y is Cl, Br, I, NO ₃ or SO _4, b is a rational number from 0.8 to 2 and p is the valence of Y, as described, for example, in US 6074632 are disclosed. The zirconium salts also typically associate some hydration water associatively, typically 1 to 7 moles of water per mole of salt. Preferably, the zirconium salt is zirconyl hydroxychloride of the formula ZrO (OH) _2-b Cl _b , wherein b is a rational number of from 0.8 to 2, preferably from 1.0 to 1.9. Preferred aluminum-zirconium salts have an Al: Zr molar ratio of 2 to 10 and a metal: (X + Y) ratio of 0.73 to 2.1, preferably 0.9 to 1.5. A particularly preferred salt is aluminum-zirconium chlorohydrate (ie, X and Y are Cl) which has an Al: Zr ratio of 2 to 10 and a molar metal: Cl ratio of 0.9 to 2.1. The term aluminum-zirconium chlorohydrate includes the tri-, tetra-, penta- and octachlorohydrate forms.

Other preferred aluminum-zirconium antiperspirant compounds are disclosed in U.S. Pat US 6663854 disclosed.

The aluminum-zirconium compounds may be in both dissolved and solubilized form. The aluminum-zirconium compounds can be used as aqueous solutions, non-aqueous solutions or as glycolic solubilisates.

Preferred aluminum zirconium salts have a metal-to-chloride molar ratio of 0.9-1.3, preferably 0.9-1.1, more preferably 0.9-1.0.

Preferred aluminum zirconium chlorohydrates generally have the empirical formula Al _n Zr (OH) _{[3n + 4-m (n + 1)]} (Cl) _{[m (n + 1)]} where n = 2.0-10.0, preferably 3 , 0-8.0, m = 0.77-1.11 (corresponding to a molar metal (Al + Zr) to chloride ratio of 1.3-0.9), preferably m = 0.91-1 , 11 (corresponding to M: Cl = 1.1-0.9), and particularly preferably m = 1.00-1.11 (corresponding to M: Cl = 1.0-0.9), furthermore very preferably m = 1 , 02-1.11 (corresponding to M: Cl = 0.98-0.9) and very preferably m = 1.04-1.11 (corresponding to M: Cl = 0.96-0.9).

In general, some of the water of hydration is associatively bound to these salts, typically 1-6 moles of water per mole of salt, corresponding to 1-16% by weight, preferably 4-13% by weight of water of hydration.

Usually, the preferred aluminum zirconium chlorohydrates are associated with an amino acid to prevent polymerization of the zirconium species during manufacture. Preferred stabilizing amino acids are selected from glycine, alanine, leucine, isoleucine, β-alanine, cysteine, valine, serine, tryptophan, phenylalanine, methionine, β-amino-n-butanoic acid and γ-amino-n-butanoic acid and the salts thereof, each in the d-form, the l-form and the dl-form; Glycine is particularly preferred. The amino acid is contained in the salt in an amount of 1-3 moles, preferably 1.3-1.8 moles, per mole of zirconium.

Preferred antiperspirant salts are aluminum zirconium tetrachlorohydrate (Al: Zr = 2-6, M: Cl = 0.9-1.3), in particular salts having a molar metal to chloride ratio of 0.9-1.1, preferably 0.9 -1.0.

Also preferred according to the invention are aluminum zirconium chlorohydrate-glycine salts which are stabilized with betaine ((CH ₃ ) ₃ N ⁺ -CH ₂ -COO ^- ). Particularly preferred corresponding compounds have a total molar (betaine + glycine) / Zr ratio of (0.1-3.0): 1, preferably (0.7-1.5): 1, and a betaine molar ratio Glycine of at least 0.001: 1 on. Corresponding compounds are disclosed in, for example US 7105691 ,

In a particularly preferred embodiment according to the invention, the particularly effective antiperspirant salt comprises a so-called "activated" salt, in particular one with a high HPLC peak 5-aluminum content, in particular with a peak 5 surface of at least 33%, particularly preferred at least 45%, based on the total area under peaks 2-5, measured by HPLC of a 10% by weight aqueous solution of the active ingredient under conditions in which the aluminum species are resolved into at least 4 consecutive peaks (with peaks 5). Preferred aluminum zirconium salts having a high HPLC peak 5-aluminum content (also referred to as "E ⁵ AZCH") are disclosed, for example, in US Pat US 6436381 and US 6649152 , Furthermore, those activated "E ⁵ AZCH" salts whose HPLC peak has a 4-to-peak 3 area ratio of at least 0.4, preferably at least 0.7, particularly preferably at least 0.9, are preferred.

Further particularly preferred aluminum-zirconium compounds are those aluminum zirconium salts having a high HPLC peak 5-aluminum content, which are additionally stabilized with a water-soluble strontium salt and / or with a water-soluble calcium salt. Corresponding salts are, for example, in US 6923952 disclosed.

Particularly preferred compositions according to the invention are characterized in that the at least one aluminum-zirconium compound in a total amount of 5-40 wt .-%, preferably 10-35 wt .-%, particularly preferably 15-28 wt .-% and exceptionally preferred 23-27 wt .-%, based on the total weight of the water-free active substance (USP) in the total composition.

As a third obligatory component, the compositions according to the invention comprise at least one solvent which is liquid under normal conditions and is selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents.

The at least one liquid under normal conditions, which is selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, is preferably in a total amount of 0.5-70 wt .-%, particularly preferably 5 -60 wt .-%, preferably extraordinarily 10-50 wt .-%, more preferably still 20-35 wt .-%, each based on the total weight of the composition according to the invention, included.

Of the monohydric alcohols having 2 to 20 carbon atoms, which are liquid under normal conditions, ethanol, 1-propanol and 2-propanol are preferred according to the invention. A particularly preferred monohydric alcohol having 2 to 20 carbon atoms is ethanol. Compositions preferred according to the invention comprise at least one monohydric alcohol having 2 to 20 carbon atoms, which is liquid under normal conditions, in a total amount of 0.5-70% by weight, preferably 5-60% by weight, particularly preferably 10-50% by weight. -%, most preferably 20-35 wt .-%, each based on the total weight of the composition according to the invention.

Further compositions preferred according to the invention comprise ethanol in a total amount of 0.5-70% by weight, preferably 5-60% by weight, more preferably 10-50% by weight, most preferably 20-35% by weight, in each case based on the total weight of the composition according to the invention.

Polyhydric alcohols having 2 to 20 carbon atoms which are suitable according to the invention and which are liquid under normal conditions are selected from 1,2-propylene glycol, 1,3-propylene glycol, 2-methyl-1,3-propanediol, glycerol, 1,2-butylene glycol, 1 , 3-butylene glycol, 1,4-butylene glycol, pentylene glycols such as 1,2-pentanediol and 1,5-pentanediol, hexanediols such as 1,2-hexanediol and 1,6-hexanediol, hexanetriols such as 1,2,6-hexanetriol, 1 , 2-octanediol, 1,8-octanediol, dipropylene glycol, tripropylene glycol, diglycerol, triglycerol, PEG-3, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, and mixtures of aforementioned substances. According to the invention, preference is given to 1,2-propylene glycol, glycerol, 1,3-butylene glycol, dipropylene glycol, tripropylene glycol, diglycerol, triglycerol, PEG-8, and mixtures of the abovementioned substances. Most preferred is 1,2-propylene glycol. Compositions preferred according to the invention comprise at least one polyhydric alcohol having 2 to 20 carbon atoms, which is liquid under normal conditions, in a total amount of 2-70% by weight, preferably 5-60% by weight, particularly preferably 10-50% by weight. . exceptionally preferably 15-40% by weight, in each case based on the total weight of the composition according to the invention.

Further inventively preferred compositions contain 1,2-propylene glycol in a total amount of 2-70 wt .-%, preferably 5-60 wt .-%, particularly preferably 10-50 wt .-%, most preferably 15-40 wt .-% , in each case based on the total weight of the composition according to the invention.

Water is another preferred solvent according to the invention. Compositions preferred according to the invention contain water in a total amount of 2-80% by weight, preferably 5-60% by weight, particularly preferably 10-50% by weight, most preferably 15-40% by weight, based in each case on the Total weight of the composition according to the invention.

Water of crystallization or water of hydration, which is molecularly bound in the antiperspirant active ingredients, is not taken into account in the calculation of the amount of water which is free (in the present application also referred to as "free water") and thus available as a solvent.

Solvent mixtures which are preferred according to the invention are selected from water / ethanol, water / 1,2-propylene glycol, water / glycerol, water / 2-methyl-1,3-propanediol, water / 1,2-hexanediol, water / 1,6-hexanediol, Water / dipropylene glycol, water / tripropylene glycol, water / diglycerol, water / triglycerol, water / PEG-8, water / ethanol / 1,2-propylene glycol, water / ethanol / glycerol, water / ethanol // 2-methyl-1,3 propanediol, water / ethanol / 1,2-hexanediol, water / ethanol / 1,6-hexanediol, water / ethanol / dipropylene glycol, water / ethanol / tripropylene glycol, water / ethanol / diglycerol, water / ethanol / triglycerol, water / ethanol / PEG-8, water / 1,2-propylene glycol / glycerin, water / 1,2-propylene glycol / 1,2-hexanediol, water / 1,2-propylene glycol / 1,6-hexanediol, water / 1,2-propylene glycol / Dipropylene glycol, water / 1,2-propylene glycol / tripropylene glycol, water / 1,2-propylene glycol / diglycerol and water / 1,2-propylene glycol / triglycerol.

Solvent mixtures which are preferred according to the invention are selected from water / ethanol in a weight ratio of 1: 9 to 9: 1, preferably 1: 4 to 4: 1, more preferably 1: 2 to 2: 1, most preferably 1: 1, water / 1.2 Propylene glycol in a weight ratio of 1: 9 to 9: 1, preferably 1: 4 to 4: 1, more preferably 1: 2 to 2: 1, most preferably 1: 1, water / glycerol in a weight ratio of 1: 9 to 9: 1, preferably 1: 4 to 4: 1, more preferably 1: 2 to 2: 1, most preferably 1: 1, water / 2-methyl-1,3-propanediol in a weight ratio of 1: 9 to 9: 1, preferably 1: 4 to 4: 1, particularly preferably 1: 2 to 2: 1, very preferably 1: 1, water / 1,2-hexanediol in a weight ratio of 1: 9 to 9: 1, preferably 1: 4 to 4: 1, particularly preferably 1: 2 to 2: 1, most preferably 1: 1, water / 1,6-hexanediol in a weight ratio of 1: 9 to 9: 1, preferably 1: 4 to 4: 1, more preferably 1: 2 to 2: 1, exceptionally preferred 1: 1, water / dipropylene glycol in a weight ratio of 1: 9 to 9: 1, preferably 1: 4 to 4: 1, more preferably 1: 2 to 2: 1, most preferably 1: 1, water / tripropylene glycol in a weight ratio of 1: 9 to 9: 1, preferably 1: 4 to 4: 1 , more preferably 1: 2 to 2: 1, most preferably 1: 1, water / diglycerol in a weight ratio of 1: 9 to 9: 1, preferably 1: 4 to 4: 1, more preferably 1: 2 to 2: 1, extraordinarily preferably 1: 1, water / triglycerol in a weight ratio of 1: 9 to 9: 1, preferably 1: 4 to 4: 1, more preferably 1: 2 to 2: 1, most preferably 1: 1.

Further preferred embodiments of the invention are characterized in that the composition according to the invention is present in stick form, as a liquid or gel roll-on application, cream, lotion, solution or gel.

Antiperspirant sticks may be in gelled form based on a W / O emulsion based on an O / W emulsion based on a water-oil multiple emulsion based on a nanoemulsion and on a microemulsion basis, wherein the Oil phase contain at least one silicone component or may consist of at least one silicone component. Furthermore, the compositions according to the invention, which are formulated as antiperspirant sticks, based on a polyol-in-oil emulsion, based on an oil-in-polyol emulsion, based on a polyol-oil multiple emulsion, based on a Nanoemulsion and based on a microemulsion, wherein the polyol phase may have only a low water content (eg., 5-10 wt .-%, based on the total composition). Gel sticks can be formulated on the basis of fatty acid soaps, alditols, especially dibenzylidenesorbitol, N-acylamino acid amides, 12-hydroxystearic acid, polyamides, polyamide derivatives, polysaccharides such as xanthan, polyglucomannans, guar, konjac, celluloses or starches, polyacrylates, polyacrylate derivatives and other gelling agents.

Roll-on applications and creams can be as water-in-oil emulsion, water-in-silicone oil emulsions, oil-in-water emulsion, silicone oil-in-water emulsion, water-in-oil microemulsion, oil in-water microemulsion, silicone oil-in-water microemulsion, polyol-in-oil emulsion, oil-in-polyol emulsion, polyol-oil multiple emulsion, alcoholic solution, especially ethanolic solution, hydroalcoholic solution, in particular Solutions containing more than 50% by weight of a water-ethanol mixture, glycolic solution, in particular as a solution in propylene glycol, glycerol, dipropylene glycol and (under normal conditions) liquid polyethylene glycols, hydroglycolic solution, polyol solution, water-polyol solution and as aqueous Gel present. All said compositions may be thickened, for example, based on fatty acid soaps, dibenzylidenesorbitol, N-acylamino acid amides, 12-hydroxystearic acid, carbomer and carbopol type polyacrylates, polyacrylamides and polysaccharides, which may be chemically and / or physically modified.

The compositions of the invention may be transparent, translucent or opaque. If the compositions according to the invention are in the form of a stick, they preferably contain a wax matrix comprising at least one wax component with a melting point> 50 ° C. Linear alkanols with a melting point> 50 ° C do not count in the context of the present application to the wax components.

Preferred compositions according to the invention, in particular those in the form of a stick, contain at least one wax component with a melting point> 50 ° C. in a total amount of 4-18% by weight, preferably 6-15% by weight, particularly preferably 8%. 13 wt .-%, most preferably 9-11 wt .-%, each based on the total composition.

Preference according to the invention, for example, natural vegetable waxes, z. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. Beeswax, shellac wax and spermaceti. For the purposes of the invention, it may be particularly preferred to use hydrogenated or hardened waxes. As a wax component and chemically modified waxes, especially the hard waxes, such as. As montan ester waxes, hydrogenated jojoba waxes and Sasol waxes used. The synthetic waxes which are likewise preferred according to the invention include polyalkylene waxes, in particular polyethylene waxes, and preferably polyethylene waxes having a molecular weight of 400-3000, more preferably polyethylene waxes having a molecular weight of 500-600, furthermore polyethylene glycol waxes, C ₂₀ -C ₄₀ dialkyl esters of Dimer acids, C _30-50 alkyl beeswax and alkyl and alkylaryl esters of dimer fatty acids.

A particularly preferred wax component is selected from polyethylene waxes having a molecular weight of 400-3000, more preferably having a molecular weight of 500-600.

Particularly preferred compositions according to the invention which are in the form of a stick contain at least one wax component with a melting point> 50 ° C., selected from polyethylene waxes having a molecular weight of 400-3000, particularly preferably having a molecular weight of 500-600, in a total amount of 4 -18 wt .-%, preferably 6-15 wt .-%, particularly preferably 8-13 wt .-%, most preferably 9-11 wt .-%, each based on the total composition.

A further preferred wax component is selected from at least one ester of a saturated, monohydric C ₁₆ -C ₆₀ -alcohol and a saturated C ₈ -C ₃₆ -monocarboxylic acid. For this purpose also include lactides, the cyclic double esters of alpha-hydroxycarboxylic acids of the corresponding chain length. Esters of fatty acids and long chain alcohols have been found to be particularly advantageous for the composition of the present invention because they impart excellent sensory properties to the antiperspirant formulation and high stability to sticks. The esters are composed of saturated branched or unbranched monocarboxylic acids and saturated branched or unbranched monohydric alcohols. Also esters of aromatic carboxylic acids or hydroxycarboxylic acids (eg 12-hydroxystearic acid) and saturated branched or unbranched alcohols can be used according to the invention, provided that the wax component has a melting point> 50 ° C. It is particularly preferred to choose the wax components from the group of esters of saturated branched or unbranched alkanecarboxylic acids having a chain length of 12 to 24 carbon atoms and the saturated branched or unbranched alcohols having a chain length of 16 to 50 carbon atoms and having a melting point> 50 ° C have.

In particular, C _{16-36 alkyl} stearates and C _18-38 alkyl hydroxystearoyl stearates, C _20-40 alkyl erucates and cetearyl behenate may be advantageous as the wax component. The wax or the wax components have a melting point> 50 ° C, preferably> 60 ° C, on.

A particularly preferred embodiment according to the invention in stick form contains as wax component a C ₂₀ -C ₄₀ -alkyl stearate. This ester is known under the name Kester ^® K82H or Kesterwachs ^® K80H and is sold by Koster Keunen Inc.. Another particularly preferred embodiment of the invention in stick form contains as wax component cetearyl behenate, ie mixtures of cetyl behenate and stearyl behenate. This ester is known under the name Kester ^® K62 and is sold by Koster Keunen Inc..

Further preferred wax components having a melting point> 50 ° C are the triglycerides of saturated and optionally hydroxylated C _12-30 fatty acids, such as hardened triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryl tri-12-hydroxystearate synthetic full esters of fatty acids and glycols or polyols having 2-6 carbon atoms, as long as they have a melting point above 50 ° C, for example preferably C ₁₈ -C ₃₆ Acid triglycerides (Syncrowax ^® HGL-C). According to the invention, hydrogenated castor oil is particularly preferred as the wax component.

Further preferred wax components with a melting point> 50 ° C are the saturated linear C ₁₄ -C ₃₆ carboxylic acids, in particular myristic acid, palmitic acid, stearic acid and behenic acid and mixtures of these compounds, eg. B. Syncrowax ^® AW 1C (C ₁₈ -C ₃₆ fatty acids) or Cutina ^® FS 45 (palmitic and stearic acid).

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, sowie mindestens eine Wachskomponente, die ausgewählt ist aus Polyethylenwachsen mit einem Molekulargewicht von 400–3000, besonders bevorzugt mit einem Molekulargewicht von 500–600, Estern aus einem gesättigten, einwertigen C₁₆-C₆₀-Alkanol und einer gesättigten C₈-C₃₆-Monocarbonsäure, insbesondere Cetylbehenat, Stearylbehenat und C₂₀-C₄₀-Alkylstearat, Glycerintriestern von gesättigten linearen C₁₂-C₃₀-Carbonsäuren, die hydroxyliert sein können, Candelillawachs, Carnaubawachs, Bienenwachs, gesättigten linearen C₁₄-C₃₆-Carbonsäuren sowie Mischungen der vorgenannten Substanzen. Preferred antiperspirant compositions according to the invention, in particular antiperspirant sticks, comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one wax component selected from polyethylene waxes having a molecular weight of 400-3000, particularly preferably having a molecular weight from 500-600, esters of a saturated, monohydric C ₁₆ -C ₆₀ alkanol and a saturated C ₈ -C ₃₆ monocarboxylic acid, especially cetyl behenate, stearyl behenate and C ₂₀ -C ₄₀ alkyl stearate, glycerol triesters of saturated linear C ₁₂ -C ₃₀ -Carbonsäuren, which may be hydroxylated, candelilla wax, carnauba wax, beeswax, saturated linear C ₁₄ -C ₃₆ carboxylic acids and mixtures of the aforementioned substances.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, sowie mindestens eine Wachskomponente, die ausgewählt ist aus Polyethylenwachsen mit einem Molekulargewicht von 400–3000, besonders bevorzugt mit einem Molekulargewicht von 500–600. Particularly preferred antiperspirant compositions according to the invention, in particular antiperspirant sticks, comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one wax component selected from polyethylene waxes having a molecular weight of 400-3000, particularly preferably having a molecular weight from 500-600.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, sowie eine Wachskomponenten-Mischung, die ausgewählt ist aus Mischungen von Cetylbehenat, Stearylbehenat, gehärtetem Rizinusöl, Palmitinsäure und Stearinsäure. Further particularly preferred antiperspirant compositions contain at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and a wax component mixture which is selected from mixtures of cetyl behenate, stearyl behenate, hardened castor oil, palmitic acid and stearic acid.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, sowie eine Wachskomponenten-Mischung, die ausgewählt ist aus Mischungen von C₂₀-C₄₀-Alkylstearat, gehärtetem Rizinusöl, Palmitinsäure und Stearinsäure. Further particularly preferred compositions contain at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and a wax component mixture selected from mixtures of C ₂₀ -C ₄₀ alkyl stearate, hardened castor oil, Palmitic acid and stearic acid.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, sowie insgesamt 4–20 Gew.-%, bevorzugt 8–15 Gew.-%, mindestens einer Wachskomponente, die ausgewählt ist aus Estern aus einem gesättigten, einwertigen C₁₆-C₆₀-Alkanol und einer gesättigten C₈-C₃₆-Monocarbonsäure, insbesondere Cetylbehenat, Stearylbehenat und C₂₀-C₄₀-Alkylstearat, Glycerintriestern von gesättigten linearen C₁₂-C₃₀-Carbonsäuren, die hydroxyliert sein können, Candelillawachs, Carnaubawachs, Bienenwachs, gesättigten linearen C₁₄-C₃₆-Carbonsäuren sowie Mischungen der vorgenannten Substanzen, wobei sich alle Mengenangaben auf das Gesamtgewicht der Antitranspirant-Zusammensetzung beziehen. Preferred antiperspirant compositions according to the invention, in particular antiperspirant sticks, based on an oil-in-water emulsion, comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one liquid solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and a total of 4-20 wt .-%, preferably 8-15 wt .-%, of at least one wax component, which is selected from esters of a saturated, monohydric C ₁₆ -C ₆₀ -alkanol and a saturated C ₈ -C ₃₆ -monocarboxylic acid, in particular cetylbehenate, stearyl behenate and C ₂₀ -C ₄₀ -alkyl stearate, glycerol triesters of saturated linear C ₁₂ -C ₃₀ -carboxylic acids which may be hydroxylated, candelilla wax, carnauba wax, beeswax, saturated linear C ₁₄ -C ₃₆ -carboxylic acids and mixtures of the abovementioned substances , Wherein all amounts are based on the total weight of the antiperspirant composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, sowie mindestens einen Ester aus einem gesättigten, einwertigen C₁₆-C₆₀-Alkohol und einer gesättigten C₈-C₃₆-Monocarbonsäure, der eine Wachskomponente darstellt, in einer Gesamtmenge von 2–10 Gew.-%, bevorzugt 2–6 Gew.-%, jeweils bezogen auf die Gesamtzusammensetzung. In a particularly preferred embodiment, the antiperspirant compositions according to the invention, in particular antiperspirant sticks, contain at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one ester of a saturated, monohydric C ₁₆ -C ₆₀ -alcohol and a saturated C ₈ -C _36- Monocarboxylic acid, which is a wax component, in a total amount of 2-10 wt .-%, preferably 2-6 wt .-%, each based on the total composition.

Preferred antiperspirant compositions according to the invention, in particular antiperspirant sticks, comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, particularly preferably 2 to 15% by weight, extraordinarily preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, further at least one liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and Mixtures of these solvents, and at least one wax component selected from polyethylene waxes having a molecular weight of 400-3000, more preferably having a molecular weight of 500-600, esters of a saturated, monohydric C ₁₆ -C ₆₀ alkanol and a saturated C ₈ -C ₃₆ monocarboxylic acid, in particular cetyl behenate, stearyl behenate and C ₂₀ -C ₄₀ alkyl, glycerol triesters of saturated linear C ₁₂ -C ₃₀ -carboxylic acids, which may be hydroxylated, candelilla wax, carnauba wax, beeswax, saturated linear C ₁₄ -C ₃₆ carboxylic acids, and mixtures of the aforementioned wax components.

Particularly preferred antiperspirant compositions according to the invention, in particular antiperspirant sticks, comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, particularly preferably 2 to 15% by weight, extremely preferably 5-10% by weight, based in each case on their total weight, of 1,4-bis (hydroxymethyl) cyclohexane, furthermore at least one solvent which is liquid under normal conditions, selected from water and a monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one wax component selected from polyethylene waxes having a molecular weight of 400-3000, particularly preferably having a molecular weight of 500-600.

Further particularly preferred antiperspirant compositions comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5 to 10% by weight .-%, in each case based on their total weight, of 1,4-bis (hydroxymethyl) cyclohexane, further at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and a wax component mixture which is selected from mixtures of cetyl behenate, stearyl behenate, hardened castor oil, palmitic acid and stearic acid.

Further particularly preferred compositions comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5 to 10% by weight. %, in each case based on their total weight, of 1,4-bis (hydroxymethyl) cyclohexane, furthermore at least one liquid solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and a wax component Mixture selected from mixtures of C ₂₀ -C ₄₀ alkyl stearate, hardened castor oil, palmitic acid and stearic acid.

Preferred antiperspirant compositions according to the invention, in particular antiperspirant sticks, based on an oil-in-water emulsion contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1-20% by weight, especially preferably 2-15 wt .-%, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, further at least one liquid under normal conditions, selected from water and a solvent or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and a total of 4-20 wt .-%, preferably 8-15 wt .-%, of at least one wax component which is selected from esters of a saturated, monovalent C ₁₆ - C ₆₀ alkanol and a saturated C ₈ -C ₃₆ monocarboxylic acid, in particular cetyl behenate, stearyl behenate and C ₂₀ -C ₄₀ alkyl stearate, glycerol triesters of saturated linear C ₁₂ -C ₃₀ carboxylic acids which may be hydroxylated en, candelilla wax, carnauba wax, beeswax, saturated linear C ₁₄ -C ₃₆ carboxylic acids and mixtures of the abovementioned substances, all quantities being based on the total weight of the antiperspirant composition.

In a particularly preferred embodiment, the antiperspirant compositions according to the invention, in particular antiperspirant sticks, comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight .-%, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, further at least one liquid under normal conditions, solvent selected from water and a monohydric or polyhydric alcohol with 2 to 20 carbon atoms and mixtures of these solvents, and at least one ester of a saturated, monohydric C ₁₆ -C ₆₀ alcohol and a saturated C ₈ -C ₃₆ monocarboxylic acid, which is a wax component, in a total amount of 2-10 wt. -%, preferably 2-6 wt .-%, each based on the total composition.

Oil-in-water emulsifiers

The compositions of the present invention, formulated as an emulsion, especially as an oil-in-water or oil-in-polyol emulsion, preferably contain at least one nonionic oil-in-water emulsifier having an HLB greater than 7 These are emulsifiers generally known to the person skilled in the art, as are described, for example, in US Pat Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd ed., 1979, Vol. 8, pp. 913-916 , are listed. For ethoxylated products, the HLB value is calculated according to the formula HLB = (100-L): 5, where L is the weight fraction of the lipophilic groups, that is the fatty alkyl or fatty acyl groups, in the ethylene oxide adducts, expressed in weight percent.

In selecting nonionic oil-in-water emulsifiers which are suitable according to the invention, it is particularly preferable to use a mixture of nonionic oil-in-water emulsifiers in order to be able to optimally adjust the stability of O / W emulsion compositions according to the invention. The individual emulsifier components thereby deliver a proportion to the total HLB value or average HLB value of the oil-in-water emulsifier mixture in accordance with their weight proportion of the total weight of the nonionic and optionally present ionic oil-in-water emulsifiers. According to the invention, the mean HLB value of the oil-in-water emulsifier mixture is 10-19, preferably 12-18 and particularly preferably 14-17. In order to achieve such average HLB values, preference is given to combining oil-in-water emulsifiers from the HLB value ranges 10-14, 14-16 and optionally 16-19. In another preferred embodiment, the antiperspirant compositions of the present invention may also contain only a single nonionic oil-in-water emulsifier having an HLB in the range of 10-19. Preferred antiperspirant compositions according to the invention are characterized in that the nonionic oil-in-water emulsifiers are selected from ethoxylated C ₈ -C ₂₄ -alkanols with an average of 10-100 moles of ethylene oxide per mole, ethoxylated C ₈ -C ₂₄ -carboxylic acids with an average 10-100 moles of ethylene oxide per mole, silicone copolyols having ethylene oxide units or with ethylene oxide and propylene oxide units, alkyl mono- and oligoglycosides having 8 to 22 carbon atoms in the alkyl radical and their ethoxylated analogs, ethoxylated sterols, partial esters of polyglycerols with 2 to 10 glycerol units and esterified with 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C ₈ -C ₃₀ fatty acid residues, provided that they have an HLB value of more than 7, and mixtures of the aforementioned substances.

The ethoxylated C ₈ -C ₂₄ alkanols have the formula R ¹ O (CH ₂ CH ₂ O) _n H, where R ¹ is a linear or branched alkyl and / or alkenyl radical having 8-24 carbon atoms and n, the middle number of Ethylene oxide units per molecule, for numbers of 10-100, preferably 10-30 moles of ethylene oxide to 1 mole of caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, isocetyl alcohol, palmitoleyl alcohol, stearyl alcohol,

Isostearyl alcohol, oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol, and technical mixtures thereof. Adducts of 10-100 moles of ethylene oxide with technical fatty alcohols having 12-18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty alcohol, are suitable.

The ethoxylated C ₈ -C ₂₄ -carboxylic acids have the formula R ¹ (OCH ₂ CH ₂ ) _n OH, where R ¹ is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide Units per molecule, for numbers of 10-100, preferably 10-30 moles of ethylene oxide to 1 mole of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, arachidic acid, Gadoleic acid, behenic acid, erucic acid and brassidic acid and their technical mixtures. Also adducts of 10-100 moles of ethylene oxide with technical fatty acids having 12-18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty acid, are suitable. Particularly preferred are PEG-50 monostearate, PEG-100 monostearate, PEG-50 monooleate, PEG-100 monooleate, PEG-50 monolaurate and PEG-100 monolaurate.

Particular preference is given to using the C ₁₂ -C ₁₈ -alkanols or the C ₁₂ -C ₁₈ -carboxylic acids with in each case 10-30 units of ethylene oxide per molecule and mixtures of these substances, in particular ceteth-12, ceteth-20, ceteth-30, isoceteth- 20, steareth-12, steareth-20, steareth-21, steareth-30, ceteareth-12, ceteareth-20, ceteareth-30, laureth-12 and beheneth-20.

Furthermore, preference is given to using C ₈ -C ₂₂ -alkyl mono- and -oligoglycosides. C ₈ -C ₂₂ -alkyl mono- and -oligoglycosides are known, commercially available surfactants and emulsifiers. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8-22 carbon atoms. With regard to the glycoside radical, both monoglycosides in which a cyclic sugar radical is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of up to about 8, preferably 1-2, are suitable. The degree of oligomerization is a statistical mean, which is based on a homolog distribution typical for such technical products. Products which are obtainable under the trademark Plantacare ^®, a glucosidically bonded C ₈ -C ₁₆ alkyl group containing at an oligoglucoside whose average degree of oligomerization at 1-2, particularly at 1.1-1.4, is located. Particularly preferred C ₈ -C ₂₂ alkyl mono- and oligoglycosides are selected from octyl glucoside, decyl glucoside, lauryl glucoside, palmityl glucoside, isostearyl glucoside, stearyl glucoside, arachidyl glucoside and behenyl glucoside and mixtures thereof. The glucamine-derived acylglucamides are also suitable as non-ionic oil-in-water emulsifiers.

Ethoxylated sterols, in particular ethoxylated soy sterols, are suitable oil-in-water emulsifiers according to the invention. The degree of ethoxylation must be greater than 5, preferably at least 10, in order to have an HLB value greater than 7. Suitable commercial products are, for. PEG-10 Soy Sterol, PEG-16 Soy Sterol and PEG-25 Soy Sterol.

Furthermore, preferably partial esters of polyglycerols with 2 to 10 glycerol units and with 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C ₈ -C ₃₀ fatty acid esters esterified used, provided that they have an HLB value of more than 7. Particularly preferred Diglycerinmonocaprylat, Diglycerinmonocaprat, diglycerol, Triglycerinmonocaprylat, Triglycerinmonocaprat, triglycerol, Tetraglycerinmonocaprylat, Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocaprylat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglycerinmonocaprat, hexa are glycerol, Hexaglycerinmonomyristat, Hexaglycerinmonostearat, Decaglycerinmonocaprylat, Decaglycerinmonocaprat, decaglyceryl monolaurate, decaglyceryl monomyristate, Decaglycerinmonoisostearat, decaglycerol monostearate, Decaglycerinmonooleat, Decaglycerinmonohydroxystearat, Decaglycerindicaprylat, Decaglycerindicaprat, Decaglycerindilaurat, Decaglycerindimyristat, Decaglycerindiisostearat, Decaglycerindistearat, Decaglycerindioleat, Decaglycerindihydroxystearat, Decaglycerintricaprylat, Decaglycerintricaprat, Decaglycerintrilaurat, Decaglycerintrimyristat, Decaglycerintriisostearat, Decaglycerintristearat, Decaglyce rintrioleate and decaglycerol trihydroxystearate.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, sowie mindestens einen nichtionischen Öl-in-Wasser-Emulgator in einer Gesamtmenge von 0,5–10 Gew.-%, besonders bevorzugt 1–4 Gew.-% und außerordentlich bevorzugt 1,5–3 Gew.-%, jeweils bezogen auf die Gesamtzusammensetzung. Particularly preferred antiperspirant compositions according to the invention, in particular antiperspirant sticks, comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one liquid solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one nonionic oil-in-water emulsifier in a total amount of 0.5-10 wt. %, more preferably 1-4 wt .-% and exceptionally preferably 1.5-3 wt .-%, each based on the total composition.

Further particularly preferred antiperspirant compositions according to the invention, in particular antiperspirant sticks, comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, particularly preferably 2 to 15% by weight. , most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, further at least one liquid under normal conditions, solvent selected from water and a mono- or polyhydric alcohol having 2 to 20 Carbon atoms and mixtures of these solvents, and at least one nonionic oil-in-water emulsifier in a total amount of 0.5-10 wt .-%, more preferably 1-4 wt .-% and most preferably 1.5-3 wt. -%, in each case based on the total composition. Water-in-oil emulsifier

Preferred compositions according to the invention, which are formulated as an emulsion, in particular as a water-in-oil emulsion or as an ethanol-in-oil emulsion or as a polyol-in-oil emulsion, contain at least one water-in-oil emulsifier with an HLB Value greater than 1.0 and less than or equal to 7.0, preferably at least one nonionic water-in-oil emulsifier having an HLB value greater than 1.0 and ≦ 7.0.

According to the invention, it may be preferable to use only a single water-in-oil emulsifier. In another preferred embodiment, the compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers.

Some of these suitable emulsifiers are for example in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd Ed., 1979, Vol. 8, page 913 , listed. For ethoxylated adducts, the HLB value, as already mentioned, can also be calculated.

• – lineare gesättigte Alkanole mit 12-30 Kohlenstoffatomen, insbesondere mit 16-22 Kohlenstoffatomen, insbesondere Cetylalkohol, Stearylalkohol, Arachidylalkohol, Behenylalkohol und Lanolinalkohol oder Gemische dieser Alkohole, wie sie bei der technischen Hydrierung von pflanzlichen und tierischen Fettsäuren erhältlich sind,
• – Ester und insbesondere Partialester aus einem Polyol mit 3-6 C-Atomen und linearen gesättigten und ungesättigten Fettsäuren mit 12–30, insbesondere 14-22 C-Atomen, die hydroxyliert sein können. Solche Ester oder Partialester sind z. B. die Mono- und Diester von Glycerin oder die Monoester von Propylenglycol mit linearen gesättigten und ungesättigten C₁₂-C₃₀-Carbonsäuren, die hydroxyliert sein können, insbesondere diejenigen mit Palmitin- und Stearinsäure, die Sorbitanmono-, -di- oder -triester von linearen gesättigten und ungesättigten C₁₂- C₃₀-Carbonsäuren, die hydroxyliert sein können, insbesondere diejenigen von Myristinsäure, Palmitinsäure, Stearinsäure oder von Mischungen dieser Fettsäuren und die Methylglucosemono- und -diester von linearen gesättigten und ungesättigten C₁₂-C₃₀-Carbonsäuren, die hydroxyliert sein können;
• – Sterine, also Steroide, die am C3-Atom des Steroid-Gerüstes eine Hydroxylgruppe tragen und sowohl aus tierischem Gewebe (Zoosterine, z. B. Cholesterin, Lanosterin) wie auch aus Pflanzen (Phytosterine, z. B. Ergosterin, Stigmasterin, Sitosterin) und aus Pilzen und Hefen (Mykosterine) isoliert werden und die niedrig ethoxyliert (1–5 EO) sein können;
• – Alkanole und Carbonsäuren mit jeweils 8-24 C-Atomen, insbesondere mit 16-22 C-Atomen, in der Alkylgruppe und 1–4 Ethylenoxid-Einheiten pro Molekül, die einen HLB-Wert größer 1,0 und kleiner/gleich 7,0 aufweisen,
• – Glycerinmonoether gesättigter und/oder ungesättigter, verzweigter und/oder unverzweigter Alkohole einer Kettenlänge von 8–30, insbesondere 12-18 Kohlenstoffatomen.
• – Partialester von Polyglycerinen mit n = 2 bis 10 Glycerineinheiten und mit 1 bis 5 gesättigten oder ungesättigten, linearen oder verzweigten, gegebenenfalls hydroxylierten C₈-C₃₀-Fettsäureresten verestert, sofern sie einen HLB-Wert von kleiner/gleich 7 aufweisen,
• – sowie Mischungen der vorgenannten Substanzen.

Preferred water-in-oil emulsifiers having an HLB value greater than 1.0 and ≦ 7.0 are selected from the mono and diesters of ethylene glycol and the mono-, di-, tri- and tetra-esters of pentaerythritol with linear saturated fatty acids with 12-30, especially 14-22, carbon atoms which may be hydroxylated, as well as mixtures thereof. According to the invention, the mono- and diesters are preferred. C ₁₂ -C ₃₀ fatty acid radicals preferred according to the invention are selected from lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid and behenic acid radicals; particularly preferred is the stearic acid residue. Nonionic water-in-oil emulsifiers particularly preferred according to the invention having an HLB value greater than 1.0 and ≦ 7.0 are selected from pentaerythrityl monostearate, pentaerythrityl distearate, pentaerythrityl tristearate, pentaerythrityl tetrastearate, ethylene glycol monostearate, ethylene glycol distearate and mixtures thereof. According to the invention, particularly preferred water-in-oil emulsifiers having an HLB value greater than 1.0 and ≤ 7.0, for example as commercial products Cutina ^® PES (INCI: Pentaerythrityl distearate), Cutina ^® AGS (INCI: distearate glycol) or Cutina ^® EGMS (INCI: Glycol stearate) available. These commercial products are already mixtures of mono- and diesters (in the pentaerythrityl esters are also tri- and tetraesters contain). Under a technical mixture, for example, a commercial product such as Cutina ^® understood PES. Other preferred water-in-oil emulsifiers are:

• Linear saturated alkanols with 12-30 carbon atoms, in particular with 16-22 carbon atoms, in particular cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol and lanolin alcohol or mixtures of these alcohols, as obtainable in the industrial hydrogenation of vegetable and animal fatty acids,
• - Esters and in particular partial esters of a polyol having 3-6 C-atoms and linear saturated and unsaturated fatty acids having 12-30, in particular 14-22 C-atoms, which may be hydroxylated. Such esters or partial esters are, for. The mono- and diesters of glycerol or the monoesters of propylene glycol with linear saturated and unsaturated C ₁₂ -C ₃₀ carboxylic acids which may be hydroxylated, especially those with palmitic and stearic acid, the sorbitan mono-, di- or triesters of linear saturated and unsaturated C ₁₂ - C ₃₀ carboxylic acids, which may be hydroxylated, especially those of myristic acid, palmitic acid, stearic acid or of mixtures of these fatty acids and the monoesters and diesters of Methylglucosemono- linear saturated and unsaturated C ₁₂ -C ₃₀ carboxylic acids which may be hydroxylated;
• Sterols, ie steroids, which carry a hydroxyl group at the C3 atom of the steroid skeleton and both from animal tissue (zoosterols, eg cholesterol, lanosterol) as well as from plants (phytosterols, eg ergosterol, stigmasterol, sitosterol ) and from fungi and yeasts (mycosterols) which may be low ethoxylated (1-5 EO);
• Alkanols and carboxylic acids having in each case 8-24 C atoms, in particular having 16-22 C atoms, in the alkyl group and 1-4 ethylene oxide units per molecule which have an HLB value greater than 1.0 and less than or equal to 7, Have 0,
• - Glycerinmonoether of saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 8-30, in particular 12-18 carbon atoms.
• Esterified partial esters of polyglycerols with n = 2 to 10 glycerol units and with 1 to 5 saturated or unsaturated, linear or branched, optionally hydroxylated C ₈ -C ₃₀ fatty acid residues, if they have an HLB value of less than or equal to 7,
• - And mixtures of the aforementioned substances.

Particularly advantageous usable water-in-oil emulsifiers are stearyl alcohol, cetyl alcohol, glyceryl monostearate, glyceryl distearate, Glycerylmonocaprinat, glyceryl monocaprylate, glyceryl monolaurate, glyceryl monomyristate, glyceryl monopalmitate, Glycerylmonohydroxystearat, glyceryl monooleate, Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, glyceryl dioleate, propylene glycol monostearate, propylene glycol monolaurate, sorbitan monocaprylate, sorbitan monolaurate, sorbitan monomyristate , sorbitan monopalmitate, sorbitan monostearate, Sorbitansesquistearat, sorbitan distearate, sorbitan dioleate, sorbitan sesquioleate, sucrose distearate, arachidyl alcohol, behenyl alcohol, polyethylene glycol (2) stearyl ether (steareth-2), steareth-5, oleth-2, diglycerol monostearate, diglycerol monoisostearate, diglycerol monooleate, Diglycerindihydroxystearat, diglycerol distearate, diglyceryl dioleate, Triglycerol distearate, tetraglycerol monostearate, tetraglycerol distearate, tetraglycerol tristearate, decaglycerol pentastearate, Decaglyc erinpentahydroxystearate, decaglycerol pentaisostearate, decaglycerol pentaoleate, soy sterol, PEG-1 soy sterol, PEG-5 soy sterol, PEG-2 monolaurate, and PEG-2 monostearate.

Further inventively preferred W / O emulsifiers are silicone-free polymeric water-in-oil emulsifiers, in particular PEG-30 dipolyhydroxystearate, available for. B. under the trade name Arlacel P 135 from Uniqema. In particular, with the help of this emulsifier can be formulated low viscosity water-in-oil emulsions.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, und mindestens einen Silicon-freien Wasser-in-Öl-Emulgator in einer Gesamtmenge von 0,1–15 Gew.-%, bevorzugt 0,5–8,0 Gew.-%, und besonders bevorzugt 1–4 Gew.-%, jeweils bezogen auf die Gesamtzusammensetzung. Weiterhin können Gesamtmengen an mindestens einem Silicon-freien Wasser-in-Öl-Emulgator von 2 bis 3 bis 3,5 Gew.-%, bezogen auf das Gesamtgewicht der Zusammensetzung, erfindungsgemäß außerordentlich bevorzugt sein. Particularly preferred antiperspirant compositions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one silicone-free water-in-oil emulsifier in a total amount of 0.1-15 wt .-%, preferably 0.5-8.0 wt .-%, and particularly preferably 1-4 wt .-%, each based on the total composition. Furthermore, total amounts of at least one silicone-free water-in-oil emulsifier of from 2 to 3 to 3.5% by weight, based on the total weight of the composition, may be extremely preferred according to the invention.

Further particularly preferred antiperspirant compositions according to the invention comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1-20% by weight, more preferably 2-15% by weight, most preferably 5-10 % By weight, based in each case on their total weight, of 1,4-bis (hydroxymethyl) cyclohexane, furthermore at least one solvent which is liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one silicone-free water-in-oil emulsifier in a total amount of 0.1-15 wt .-%, preferably 0.5-8.0 wt .-%, and particularly preferably 1-4 wt .-% , in each case based on the total composition. Furthermore, total amounts of at least one silicone-free water-in-oil emulsifier of from 2 to 3 to 3.5% by weight, based on the total weight of the composition, may be extremely preferred according to the invention.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, und mindestens ein Polysaccharid. Further preferred antiperspirant compositions according to the invention comprise, at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one polysaccharide.

Further preferred antiperspirant compositions according to the invention contain, based in each case on their total weight, at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, particularly preferably 2 to 15% by weight. , most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, further at least one liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one polysaccharide.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, weiterhin 0,5–6,5 Gew.-%, jeweils bezogen auf ihr Gesamtgewicht, Öl- oder Fettphase, umfassend mindestens eine bei 20 °C flüssige Ölkomponente, ausgewählt aus linearen und verzweigten gesättigten ein- oder mehrwertigen C₃-C₃₀-Alkanolen, die mit mindestens einer Propylenoxid-Einheit pro Molekül verethert sind, Propylenglycolmonoestern von verzweigten gesättigten C₆-C₃₀-Alkancarbonsäuren und verzweigten gesättigten C₁₀-C₃₀-Alkanolen. Further preferred antiperspirant compositions according to the invention are packaged as an oil-in-water emulsion, which is not a microemulsion, and contain at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one liquid under normal conditions, selected from water and a monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, further 0.5-6.5 wt .-%, each based on their total weight, oil or fat phase composition comprising at least one 20 ° C liquid oil component selected from linear and branched saturated mono- or polyhydric C ₃ -C ₃₀ alkanols etherified with at least one propylene oxide unit per molecule, propylene glycol monoesters of branched saturated C ₆ -C ₃₀ Alkanecarboxylic acids and branched saturated C ₁₀ -C ₃₀ alkanols.

Polysaccharides (glycans, polyglycans) is the collective term for macromolecular carbohydrates whose molecules consist of a large number (at least> 10, but usually significantly more) of glycosidically linked monosaccharide molecules (glycoses).

The preferred polysaccharides according to the invention include, in particular, the biopolymers starch, cellulose and dextran, which can be regarded as the polycondensation product of D-glucose (polyglucosans, glucans), inulin as polycondensate of D-fructose (polyfructosan, fructan), chitin and alginic acid.

Under polysaccharides suitable according to the invention are both unmodified polysaccharides such as xanthan or starch, and chemically modified polysaccharide derivatives such as Aluminiumstärkeoctenylsuccinat, hydroxypropylmethylcellulose or dehydrated xanthan (INCI: dehydroxanthan gum), as well as physically modified polysaccharides, for example by thermal Treatment pregelatinized starch, understood. Preferred polysaccharides according to the invention are selected from starches, in particular from corn, potatoes and wheat, their constituents such as amylose and amylopectin, starch hydrolysates and starch degradation products, such as maltodextrin, the physically or chemically modified starch derivatives, in particular the anionic starch derivatives Aluminiumstärkeoctenylsuccinat, Natriumstärkeoctenylsuccinat, Calciumstärkeoctenylsuccinat, Distärkephosphaten, Hydroxyethylstärkephosphaten , Hydroxypropyl starch phosphates, sodium carboxymethyl starches and sodium starch glycolate, cellulose, the chemically modified cellulose derivatives methyl cellulose, hydroxypropyl cellulose, hydroxyethyl cellulose, hydroxypropylmethyl cellulose, hydroxypropyl ethyl cellulose, hydroxyethyl methyl cellulose and carboxymethyl cellulose. Polysaccharides that form gums or gums, such as guar gum, xanthan gum, dehydroxanthan gum, alginates, especially sodium alginate, gum arabic, karaya gum, carrageenans, locust bean gum, linseed gums, and agar-agar, may also be included. but are less preferred. In a particularly preferred embodiment, the compositions according to the invention are free of polysaccharide gums. In a further particularly preferred embodiment, the compositions according to the invention are free of guar gum, xanthan gum, dehydroxanthan gum, alginates, in particular sodium alginate, gum arabic, karaya gum, carrageenans, locust bean gum, linseed gums and agar agar.

Particularly preferred antiperspirant compositions according to the invention, in particular those in the form of oil-in-water emulsions, are characterized in that the at least one polysaccharide is selected from anionic and nonionic polysaccharides and mixtures thereof.

Further particularly preferred antiperspirant compositions according to the invention, in particular those in the form of oil-in-water emulsions, are characterized in that the at least one polysaccharide is selected from anionic and nonionic polysaccharides which do not form polysaccharide gums.

Further particularly preferred antiperspirant compositions according to the invention, in particular those in the form of oil-in-water emulsions, are characterized in that the anionic polysaccharide is selected from aluminum starch octenyl succinate, sodium starch octenyl succinate, calcium starch octenyl succinate, distarch phosphates, hydroxyethyl starch phosphates, hydroxypropyl starch phosphates, sodium carboxymethyl starches, sodium starch glycolate and mixtures thereof , An anionic polysaccharide extraordinarily preferred according to the invention is aluminum starch octenylsuccinate.

Further particularly preferred antiperspirant compositions according to the invention, in particular those in the form of oil-in-water emulsions, are characterized in that the nonionic polysaccharide is selected from starches, starch hydrolysates, cellulose, methylcellulose, hydroxypropylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose, hydroxypropylethylcellulose, hydroxyethylmethylcellulose and Mixtures thereof.

Further particularly preferred antiperspirant compositions according to the invention, in particular those in the form of oil-in-water emulsions, are characterized in that the at least one Polysaccharide in a total amount of 0.01-1.0 wt .-%, preferably 0.05-0.5 and particularly preferably 0.09-0.2 wt .-%, each based on the total weight of the emulsion ,

Antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one linear or branched saturated mono- or polyhydric C ₃ -C ₃₀ -alkanol which has been etherified with at least one propylene oxide unit per molecule , is selected from adducts of at least 6 propylene oxide units per molecule of mono- or polyhydric C _3-30 alkanols, in particular butanol, butanediol, myristyl alcohol and stearyl alcohol. Particularly preferred such compounds are selected from PPG-13 butyl ether, PPG-14 butyl ether, PPG-9 butyl ether, PPG-10-butanediol and PPG-15 stearyl ether and mixtures thereof.

Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one propylene glycol monoester of branched saturated C ₆ -C ₃₀ -alkanecarboxylic acids is selected from propylene glycol monoisostearate, propylene glycol monoisopalmitate, propylene glycol monoisobehenate, propylene glycol monoisoarachinate, propylene glycol monoisomyryrate, propylene glycol monoisocaprate, Propylene glycol monoisocaprinate and propylene glycol monoisocaprylate and mixtures thereof. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one branched saturated C ₁₀ -C ₃₀ -alkanol is selected from isostearyl alcohol, isocetyl alcohol, isomyristyl alcohol, isotridecyl alcohol, isoarachidyl alcohol, isobehenyl alcohol, isocapryl alcohol, Isocaprinyl alcohol, isocaprylyl alcohol, and mixtures thereof.

Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 3-6 is present. More preferably, the at least one nonionic emulsifier having an HLB value in the range of 3-6 is selected from linear saturated and unsaturated C ₁₂ -C ₃₀ alkanols etherified with 1-4 ethylene oxide units per molecule, which are highly preferred from steareth, ceteth, myristeth, laureth, trideceth, arachideth and beheneth, each containing 1-4 ethylene oxide units per molecule, in particular steareth-2, steareth-3, steareth-4, ceteth-2, ceteth-3, ceteth-4, Myristeth-2, myristeth-3, myristeth-4, laureth-2, laureth-3, laureth-4, trideceth-2, trideceth-3 and trideceth-4, and mixtures thereof.

Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 3-6 in a total amount of 1.8-3% by weight, based on the total weight of the composition according to the invention. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 3-6, selected from steareth-2, steareth-3, steareth-4 , Ceteth-2, ceteth-3, ceteth-4, myristeth-2, myristeth-3, myristeth-4, laureth-2, laureth-3, laureth-4, trideceth-2, trideceth-3 and trideceth-4 and mixtures thereof, in a total amount of 1.8-3 wt .-%, based on the total weight of the composition according to the invention is included. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 12 to 18 is contained. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one nonionic emulsifier having an HLB value in the range of 12-18 is selected from linear saturated and unsaturated C ₁₂ -C ₂₄ - Alkanols etherified with 7-40 ethylene oxide units per molecule. The aforementioned emulsifiers are particularly preferably selected from steareth, ceteth, myristeth, laureth, trideceth, arachideth and beheneth, each having 7-40 ethylene oxide units per molecule, in particular steareth-10, steareth-20, steareth-21, steareth-30, steareth -40, ceteth-10, ceteth-20, ceteth-21, ceteth-30, ceteth-40, laureth-10, laureth-20, laureth-30, trideceth-10, trideceth-20 and trideceth-30 and mixtures thereof.

Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 12-18, which is preferably selected from steareth-10, steareth-20, Steareth-21, steareth-30, steareth-40, ceteth-10, ceteth-20, ceteth-21, ceteth-30, ceteth-40, laureth-10, laureth-20, laureth-30, trideceth-10, trideceth- 20 and trideceth-30 and mixtures thereof, in a total amount of 1-2 wt .-%, based on the total weight of the composition according to the invention.

Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 3-6 and at least one nonionic emulsifier having an HLB value in the range of 12 -18 are included.

Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 3-6 in a total amount of 1.8-3 wt .-% and at least one nonionic emulsifier having an HLB value in the range of 12-18 in a total amount of 1-2 wt .-%, wherein the amounts are in each case based on the total weight of the composition according to the invention.

Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that they have a nonionic emulsifier with an HLB value in the range from 3 to 6 steareth-2 and at the same time as a nonionic emulsifier with an HLB value in the range from 12-18 steareth-21 is included.

Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that steareth-2, steareth-21 and PPG-15 stearyl ether are present.

Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one polysaccharide selected from aluminum starch octenyl succinate and distarch phosphates is present. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that steareth-2, steareth-21, PPG-15 stearyl ether and aluminum starch octenylsuccinate are contained.

Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the weight ratio of nonionic emulsifiers having an HLB value in the range of 3-6 and nonionic emulsifiers having an HLB value in the range of 12- 18 is from 0.9 to 3, preferably 1.3 to 1.9. Further inventively preferred antiperspirant compositions in the form of oil-in-water emulsions are characterized in that a total of at most 3 wt .-%, preferably at most 1 wt .-% and particularly preferably 0 wt .-%, each based on the total weight the composition of the invention, monovalent C ₁ -C ₃ alkanols, such as ethanol or isopropanol.

The following table summarizes various oil-in-water emulsifiers and water-in-oil emulsifiers and their HLB values. The HLB values can also be calculated according to Griffin, as for example in the RÖMPP Chemie Lexikon, especially in the online version of November 2003, and the manuals cited under the keyword "HLB system" by Fiedler, Kirk-Othmer and Janistyn is shown or tabulated. If there are different details in the literature about the HLB value of a substance, that HLB value should be used for the teaching according to the invention which comes closest to the value calculated according to Griffin. If no definite HLB value can be determined in this way, the HLB value which the manufacturer of the emulsifier specifies must be used for the teaching according to the invention. If this is not possible, the HLB value must be determined experimentally.

HLB value Chemical name

(out H. Janistyn, Handbook of cosmetics and fragrances, Hüthig-Verlag Heidelberg, 3rd edition, 1978, Volume 1, page 470 and Volume 3, pages 68-78 )) 1 Triglycerides of saturated fatty acids glyceryl trioleate 1.5 Ethylene glycol 1.6 Pur-Celli oil 1.8 trioleate dioleate 2.1 sorbitan 2.4 Propylenglycollactostearat 2.7 Glycerol monooleate Sorbitdioleat 2.8 glycerol Propylene glycol mono- / distearate, not self-emulsifying 2.9 ethylene glycol 3.0 Decaglycerindecaoleat Decaglycerindecastearat Generol 122 (Rapeseed Sterols) sucrose distearate 3.1 Decaglycerindecaoleat glyceryl Pentaerythritylmonostearat Pentaerythritylsesquioleat 3.2 Ethylene glycol monodistearate, not self-emulsifying Glycol 3.3 glycerol 3.4 propylene glycol 3.5 ethylene glycol Pentaerythritylmonooleat Polyethylene glycol (100) monooleate 3.6 Glycerol mono- / dioleate, not self-emulsifying Monoethoxylaurylether 3.7 Sorbitan sesquioleate (Dehymuls SSO) 3.8 Glycerol monodistearate, not self-emulsifying Polyethylene glycol (100) monostearate Diglycerinsesquioleat N, N-Dimethylcaproamid Pentaerythritmonotallat propylene glycol 4.0 Decaglycerinoctaoleat 4.3 Sorbitan monooleate (Dehymuls SMO) diethylene glycol monostearate 4.4 1.2-propylene glycol monodistearate, self-emulsifying 4.5 Glycerol monostearate palmitate (90%), not self-emulsifying propylene glycol 4.7 Sorbitan monostearate (Dehymuls SMS) Diethylenglycolmonooleat 4.8 Pentaerythritmonolaurat 4.9 Polyoxyethylene (2) oleyl alcohol (polyoxyethylene (2) oleyl ether) Polyoxyethylene (2) stearyl alcohol (polyoxyethylene (2) stearyl ether) 5.0 Ethylenglycolmonodistearat Generol 122 E 5 (PEG-5 Soy Sterol) Polyethylene glycol (100) monoricinoleate Polyethylene glycol (200) distearate Polyglyceryl-3-isostearates (eg Isolan GI 34 from Tego) 5.9 Polyethylene glycol (200) dilaurate 6.0 decaglycerol tetraoleate Polyethylene glycol (100) monolaurate Polyethylene glycol (200) dioleate 6.1 Diethylene glycol monolaurate (diglycollaurate) 6.3 Polyethylene glycol (300) dilaurate 6.4 glyceryl Glycerinsorbitanmonolaurat 6.5 Diethylenglycolmonolaurat Sodium stearoyl-2-lactylate 6.7 sorbitan 6.8 Glycerinmonococoat glycerol 7.0 Polyoxyethylene (2) C10-C14 fatty alcohol ether, Laureth-2 (Dehydol LS 2) sucrose 7.2 Polyethylene glycol (400) dioleate Saccharosedioleat 7.4 Polyethylene glycol (100) monolaurate Saccharosedipalmitat 7.5 Saccharosedipalmitat 7.6 Glycerinsorbitanlaurat 7.8 Polyethylene glycol (400) distearate 7.9 Polyethylene glycol (200) monostearate Polyoxyethylene (3) tridecyl alcohol 8-8.2 Polyethylene glycol (400) distearate 8.0 Polyoxyethylene (3) C10-C14 fatty alcohol ether, Laureth-3 (Dehydol LS 3) NN-dimethyllauramide Sodium lauroyl lactylate, sodium lauroyl-2-lactylate Polyethylene glycol (200) monooleate Polyethylene glycol (220) monotallate Polyethylene glycol (1500) dioleate Polyoxyethylene (4) oleyl alcohol Polyoxyethylene (4) stearylcetylether 8.2 triglycerol 8.3 Diethylenglycolmonolaurat 8.4 Polyoxyethylene (4) cetyl ether Polyoxyethylene glycol (400) dioleate 8.5 Natriumcaproyllactylat Polyethylene glycol (200) monostearate sorbitan 8.6 Sorbitan monolaurate (Dehymuls SML) Polyethylene glycol (200) monolaurate 8.8 Polyoxyethylene (4) myristyl ether Polyethylene glycol (400) dioleate 8.9 Nonylphenol, polyoxyethylated with 4 moles of EO 9.0 Oleth-5 (eg Eumulgin O 5) 9.2 to 9.7 Polyoxyethylene (4) lauryl alcohol (depending on the commercial product, eg Brij 30, Dehydol LS 4) 9.3 Polyoxyethylene (4) tridecyl alcohol 9.6 Polyoxyethylene (4) sorbitan monostearate 9.8 Polyethylenglyco1 (200) monolaurate 10-11 Polyethylene glycol (400) monooleate 10.0 didodecyldimethylammonium 10.0 Polyethylene glycol (200) monolaurate Polyethylene glycol (400) dilaurate Polyethylene glycol (600) dioleate Polyoxyethylene (4) sorbitan monostearate Polyoxyethylene (5) sorbitan monooleate 10.2 Polyoxyethylene (40) sorbitol hexaoleate 10.4 to 10.6 Polyoxyethylene glycol (600) distearate 10.5 Polyoxyethylene (20) sorbitan tristearate 10.6 sucrose monostearate 10.7 sucrose monooleate 11 to 11.4 Polyethylene glycol (400) monooleate 11.0 Polyethylene glycol (350) monostearate Polyethylene glycol (400) monotallate Polyoxyethylene (7) monostearate Polyoxyethylene glycol (8) monooleate Polyoxyethylene (20) sorbitan trioleate Polyoxyethylene (6) tridecyl alcohol 11.1 Polyethylene glycol (400) monostearate 11.2 Polyoxyethylene (9) monostearate sucrose monooleate sucrose monostearate 11.4 Polyoxyethylene (50) sorbitol hexaoleate Saccharosemonotallat Saccharosestearatpalmitat 11.6 Polyoxyethylene (400) monoricinoleate 11.7 Saccharosemonomyristat of sucrose 12.0 PEG-10 Soy Sterol (eg Generol 122 E 10) triethanolamine 12.2 to 12.3 Nonylphenol, ethoxylated with 8 moles of EO 12.2 Saccharosemonomyristat 12.4 saccharose Polyoxyethylene (10) oleyl alcohol, polyoxyethylene (10) oleyl ether Polyoxyethylene (10) stearyl alcohol, polyoxyethylene (10) stearyl ether 12.5 Polyoxyethylene (10) stearylcetylether 12.7 tridecyl alcohol polyoxyethylene (8) 12.8 Polyoxyethylene glycol (400) monolaurate Saccharosemonococoat 12.9 Polyoxyethylene (10) cetyl ether 13 Glycerol monostearate, ethoxylated (20 mol EO) 13.0 Eumulgin O 10 Eumulgin 286 Eumulgin B 1 (Ceteareth-12) 13.0 C12 fatty amines, ethoxylated (5 moles EO) 13.1 Nonylphenol, ethoxylated (9.5 mol EO) 13.2 Polyethylene glycol (600) monostearate Polyoxyethylene (16) tall oil 13.3 Polyoxyethylene (4) sorbitan monolaurate 13.5 Nonylphenol, ethoxylated (10.5 mol EO) Polyethylene glycol (600) monooleate 13.7 Polyoxyethylene (10) tridecyl alcohol Polyethylene glycol (660) monotallate Polyethylene glycol (1500) monostearate Polyoxyethylene (1500) dioleate 13.9 Polyethylene glycol (400) monococoate Polyoxyethylene (9) monolaurate 14-16 Eumulgin HRE 40 (castor oil, ethoxylated with 40 EO and hydrogenated) 14.0 Polyoxyethylene (12) lauryl ether tridecyl alcohol polyoxyethylene (12) 14.2 Polyoxyethylene (15) stearyl alcohol 14.3 Polyoxyethylene (15) stearylcetylether 14.4 Mixture of C12-C15 fatty alcohols with 12 moles EO 14.5 Polyoxyethylene (12) lauryl alcohol 14.8 Polyoxyethylene glycol (600) monolaurate 14.9 to 15.2 Sorbitan monostearate ethoxylated with 20 EO (eg Eumulgin SMS 20) 15 to 15.9 Sorbitan monooleate, ethoxylated with 20 EO (eg Eumulgin SMO 20) 15.0 PEG-20 glyceryl stearate (eg Cutina E 24) PEG-40 Castor Oil (eg Eumulgin RO 40) Decylglucoside (Oramix NS 10) Dodecylglucoside (Plantaren APG 600) dodecyltrimethylammonium Nonylphenol, ethoxylated with 15 moles of EO Polyethylene glycol (1000) monostearate Polyoxyethylene (600) monooleate 15-17 Eumulgin HRE 60 (castor oil, ethoxylated with 60 EO and hydrogenated) 15.3 C12 fatty amines, polyoxyethylated with 12 moles of EO Polyoxyethylene (20) oleyl alcohol, polyoxyethylene (20) oleyl ether 15.4 Polyoxyethylene (20) stearyl cetyl ether (eg, eumulgin B 2 (ceteareth-20)) 15.5 stearyl polyoxyethylene (20) 15.6 Polyoxyethylene glycol (1000) monostearate Polyoxyethylene (20) sorbitan monopalmitate 15.7 Polyoxyethylene (20) cetyl ether 15.9 Dinatriumtriethanolamindistearylheptaglycolethersulfosuccinat 16.0 Nonylphenol ethoxylated with 20 moles of EO Polyoxyethylene (25) propylene glycol stearate 16 to 16.8 Polyoxyethylene (30) monostearate 16.3 to 16.9 Polyoxyethylene (40) monostearate 16.5 to 16.7 Polyoxyethylene (20) sorbitan monolaurate (eg Eumulgin SML 20) 16.6 sorbitol polyoxyethylene (20) 16.7 C18 fatty amines, polyoxyethylated with 5 moles EO Polyoxyethylene (23) lauryl alcohol 17.0 Ceteareth-30, z. B. Eumulgin B 3 Octylglucoside (Triton CG 110) Polyoxyethylene (30) glyceryl monolaurate 17.1 Nonylphenol, ethoxylated with 30 moles of EO 17.4 Polyoxyethylene (40) stearyl alcohol

Further preferred compositions according to the invention are characterized in that the total content of nonionic and ionic emulsifiers and / or surfactants with an HLB value above 8 not more than 20 wt .-%, preferably at most 15 wt .-%, particularly preferably at most 10 wt .-% , particularly preferably at most 7 wt .-%, more preferably at most 4 wt .-% and most preferably at most 3 wt .-%, each based on the total composition of the invention is.

oils

Preferred compositions according to the invention preferably further contain at least one oil which is liquid at 20 ° C. and which is not a fragrance component and does not represent an essential oil. Oils preferred according to the invention are selected from branched saturated or unsaturated fatty alcohols having 6-30 carbon atoms. These alcohols are also often referred to as Guerbet alcohols, as they are obtainable by the Guerbet reaction. Preferred alcohol oils are hexyldecanol, octyldodecanol and 2-ethylhexyl alcohol. Further preferred oil components are mixtures of Guerbet alcohols and Guerbet alcohol esters, preferably mixtures of hexyldecanol and hexyldecyl laurate, the z. B. are available as a commercial product Cetiol ^® PGL. Further oils preferred according to the invention are selected from the triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C _8-30 fatty acids. Particularly suitable may be the use of natural oils, for example soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, olive oil, rapeseed oil, sesame oil, thistle oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil and the like. Also suitable are synthetic triglyceride oils with unbranched fatty acid residues, in particular Capric / Caprylic triglycerides, and synthetic triglyceride oils with branched fatty acid residues, in particular glyceryl triisostearin.

Further oils which are particularly preferred according to the invention are selected from the dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, in particular diisopropyl adipate, di-n-butyl adipate, di (2-ethylhexyl) adipate, dioctyl adipate, diethyl / di-n-butyl / Dioctyl sebacate, diisopropyl sebacate, dioctyl malate, dioctyl maleate, dicaprylyl maleate, diisooctyl succinate, di-2-ethylhexyl succinate and di- (2-hexyldecyl) succinate.

Further oils which are particularly preferred _{according to the} invention are selected from the addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 -alkanols, such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. PPG-2 myristyl ether and PPG-3 myristyl ether.

Further oil components preferred according to the invention are selected from the esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms, which may be hydroxylated. Preferred oils of this type are hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, Isononyl isononanoate, 2-ethylhexyl palmitate and 2-ethylhexyl stearate. Further according to the invention preferred oil components are isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyl octanoic acid-2-butyl octanoate, Diisotridecylacetat , n-butyl stearate, n-hexyl laurate, n-decyl oleate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, ethylene glycol dioleate and ethylene glycol dipalmitate.

Further oil components preferred according to the invention are selected from the adducts of at least 6 ethylene oxide and / or propylene oxide units with monohydric or polyhydric C _3-22 alkanols, such as butanol, butanediol, myristyl alcohol and stearyl alcohol, eg. PPG-14 butyl ether, PPG-9 butyl ether, PPG-10-butanediol and PPG-15 stearyl ether.

Further oil components which are particularly preferred according to the invention are selected from the esters of linear or branched saturated or unsaturated fatty alcohols having 6 to 22 carbon atoms with benzoic acid. These ester oils have a particularly high refractive index n _D at 20.degree. C. (measured at λ = 589 nm) of 1.47 and above, owing to the aromatic substituent, and are therefore particularly suitable for masking residues of the aluminum-zirconium compound on the skin and skin suitable for textiles. Particularly preferred are C12-C15-alkyl benzoate, commercially z. Example under the name Finsolv TN ^®, 2-Octyldodecylbenzoat and isostearyl, and C12-C15 alkyl benzoate is available extraordinarily preferred.

Further preferred oil components according to the invention are selected from the C ₈ -C ₂₂ -fatty alcohol esters of monohydric or polyhydric C ₂ -C ₇ -hydroxycarboxylic acids, in particular the esters of glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and salicylic acid. Such esters based on linear C _14/15 alkanols, eg. B. C ₁₂ -C ₁₅ alkyl lactate, and branched in the 2-position C _12/13 alkanols can be obtained under the trademark Cosmacol ^® by the company Nordmann, Rassmann GmbH & Co, Hamburg, in particular the commercial products Cosmacol ^® ESI , Cosmacol® ^® EMI and Cosmacol® ^® EIT.

Further inventively preferred oil components are selected from the symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, eg. B. dicaprylyl carbonate or the esters of DE 19756454 A1 ,

Further preferred oil components according to the invention are selected from the esters of dimers of unsaturated C ₁₂ -C ₂₂ -fatty acids (dimer fatty acids) with monovalent linear, branched or cyclic C ₂ -C ₁₈ -alkanols or with polyvalent linear or branched C ₂ -C ₆ -alkanols.

It may be extraordinarily preferred according to the invention to use mixtures of the abovementioned oils.

Further oil components preferred according to the invention are selected from silicone oils and hydrocarbon oils.

In the case of cosmetic oils, a distinction is made between volatile and non-volatile oils. Non-volatile oils are understood as meaning oils having a vapor pressure of less than 2.66 Pa (0.02 mm Hg) at 20 ° C and an ambient pressure of 1013 hPa. Volatile oils are understood as meaning oils which, at 20 ° C. and an ambient pressure of 1013 hPa, have a vapor pressure of 2.66 Pa-40,000 Pa (0.02 mm-300 mm Hg), preferably 10-12000 Pa (0.1- 90 mm Hg), more preferably 13-3000 Pa, most preferably 15-500 Pa.

Volatile cosmetic oils are usually selected from cyclic silicone oils having the INCI name Cyclomethicone. The INCI name Cyclomethicone is understood in particular as meaning cyclotrisiloxane (hexamethylcyclotrisiloxane), cyclotetrasiloxane (octamethylcyclotetrasiloxane), cyclopentasiloxane (decamethylcyclopentasiloxane) and cyclohexasiloxane (dodecamethylcyclohexasiloxane). These oils have at 20 ° C a vapor pressure of about 13-15 Pa. Cyclomethicones are known in the art as well-suited oils for cosmetic compositions, in particular for deodorant compositions. Due to their persistence in the environment, it may be preferred according to the invention to dispense with the use of cyclomethicones. In a particularly preferred embodiment, the compositions according to the invention and used according to the invention contain from 0 to less than 1% by weight, preferably at most 0.1% by weight, of cyclomethicones, based on the weight of the composition. A cyclomethicone substitute preferred according to the invention is a mixture of C ₁₃ -C ₁₆ isoparaffins, C ₁₂ -C ₁₄ isoparaffins and C ₁₃ -C ₁₅ alkanes whose viscosity at 25 ° C. is in the range of 2-6 mPas and which a vapor pressure at 20 ° C in the range of 10-150 Pa, preferably 100-150 Pa. Such a mixture is z. B. under the name SiClone SR-5 from Presperse Inc. available.

Further preferred volatile silicone oils are selected from volatile linear silicone oils, in particular volatile linear silicone oils having 2-10 siloxane units, such as hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), as described e.g. B. in the commercial products DC 2-1184, Dow Corning ^® 200 (0.65 cSt), and Dow Corning ^® 200 (1.5 cSt) from Dow Corning are contained, and low molecular weight phenyl trimethicone having a vapor pressure at 20 ° C of about 2000 Pa, as it is z. From GE Bayer Silicones / Momentive under the name Baysilone Fluid PD 5.

Preferred antiperspirant compositions of the present invention contain at least one volatile silicone oil, which may be cyclic or linear, because of the drier skin feel and faster drug release.

Other preferred compositions of the present invention contain at least one volatile non-silicone oil because of the drier skin feel and faster release of the antiperspirant active. Preferred volatile non-silicone oils are selected from C ₈ -C ₁₆ isoparaffins, in particular from isononane, isodecane, isoundecane, isododecane, isotridecane, isotetradecane, isopentadecane and isohexadecane, and mixtures thereof. Preference is given to C ₁₀ -C ₁₃ isoparaffine mixtures, in particular those having a vapor pressure at 20 ° C. of 10-400 Pa, preferably 13-100 Pa.

Further inventively preferred silicone oils are selected from non-volatile higher molecular weight linear dimethylpolysiloxanes, commercially available z. Example under the name Dow Corning ^® 190, Dow Corning ^® 200 fluid having kinematic viscosities in the range of 5-100 cSt, preferably 5-50 cSt, or even 5-10 cSt, and Baysilon ^® 350 M, where the values of the kinematic Refer viscosity to a temperature of 25 ° C.

According to the invention preferred natural and synthetic hydrocarbons are selected from iso-alkanes, C ₈ -C ₁₆ -Isoalkanen, C ₁₀ -C ₁₃ -Isoalkanen, paraffinic oils, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, for example, under the designation Emery ^® 3004, 3006 , 3010, or under the name ^® from Albemarle Ethylflo or Nexbase ^® 2004G available from Nestle, and 1,3-di- (2-ethylhexyl) -cyclohexane.

Particularly preferred antiperspirant compositions according to the invention are characterized in that the oil (s) liquid at 20 ° C in a total amount of 0.05-60% by weight, preferably 0.1-50% by weight, especially preferably 1-40 wt .-% and most preferably 7-20 wt .-%, each based on the total weight of the composition, is / are. In a further preferred embodiment of the invention, a proportion of the oil components of at least 80% by weight, based on the total weight of oil (s), has a refractive index n _D of 1.39-1.51. It is particularly preferred if 5 to 40 to 50 wt .-%, most preferably 10 to 12 to 25 to 30 wt .-% of the oil components has a refractive index n _D of 1.43-1.58, preferably 1.44-1 , 51, more preferably 1.45-1.50, exceptionally preferably 1.47-1.49, at 20 ° C (measured at λ = 589 nm), the quantities given are based on the total weight of oil (s) in refer to the composition of the invention.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, und mindestens einen Wasser-in-Öl-Emulgator auf Siliconbasis in einer Gesamtmenge von 0,1–5 Gew.-%, besonders bevorzugt 0,5–3,5 Gew.-%, außerordentlich bevorzugt 1,0–3 Gew.-%, weiterhin außerordentlich bevorzugt 1,2–2,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Antitranspirant-Zusammensetzung. Antiperspirant compositions in the form of a water-in-oil emulsion which are preferred according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one silicone-based water-in-oil emulsifier in a total amount of 0.1-5 wt. %, more preferably 0.5-3.5% by weight, most preferably 1.0-3% by weight, still more preferably 1.2-2.5% by weight, based in each case on the total weight of antiperspirant composition.

Further preferred antiperspirant compositions according to the invention in the form of a water-in-oil emulsion contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1-20% by weight, more preferably 2-15% by weight. %, most preferably 5-10 wt .-%, of 1,4-bis (hydroxymethyl) cyclohexane, further at least one liquid under normal conditions, solvent selected from water and a monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents and at least one silicone-based water-in-oil emulsifier in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, most preferably 1.0-3% by weight. -%, still more preferably 1.2-2.5 wt .-%, each based on the total weight of the antiperspirant composition. A particularly preferred group of water-in-oil emulsifiers based on silicone according to the invention are the poly (C ₂ -C ₃ ) alkylene glycol-modified silicones whose earlier INCI name was Dimethicone Copolyol, with the current INCI names PEG-x Dimethicone (with x = 2-20, preferably 3-17, more preferably 11-12), bis-PEG-y dimethicones (with y = 3-25, preferably 4-20), PEG / PPG a / b dimethicones (where a and b independently of one another represent numbers of 2-30, preferably 3-30 and particularly preferably 12-20, in particular 14-18,), bis-PEG / PPG-c / d dimethicones (wherein c and d independently of one another represent numbers of 10-25, preferably 14-20 and most preferably 14-16) and bis-PEG / PPG-e / f PEG / PPG g / h dimethicones (where e, f, g and h independently of one another represent numbers of 10- 20, preferably 14-18 and more preferably 16, stand). Particularly preferred are PEG / PPG-18/18 dimethicones, z. B. in a 1: 9 mixture with Cyclomethicone under the name Dow Corning 3225 C or Dow Corning 5225 C is commercially available, PEG / PPG-18/18 Dimethicone, the z. B. in a 1: 3 mixture with non-volatile dimethicone as Dow Corning ES 5227 DM Formulation Aid is commercially available, PEG / PPG-4/12 Dimethicone, the z. B. under the name Abil B 8852 is available, and bis-PEG / PPG-14/14 Dimethicone, the z. B. in a mixture with Cyclomethicone as Abil EM 97 (Evonik) is commercially available Bis-PEG / PPG-20/20 Dimethicone, the z. B. under the name Abil B 8832, PEG / PPG-5/3 trisiloxanes (eg Silsoft 305), and PEG / PPG-20/23 Dimethicone (eg Silsoft 430 and Silsoft 440).

Other silicone-based w / o emulsifiers which are preferred according to the invention are poly (C ₂ -C ₃ ) alkylene glycol-modified silicones which are hydrophobically modified with C ₄ -C ₁₈ -alkyl groups, particularly preferably cetyl PEG / PPG-10/1 dimethicones ( Previous: Cetyl dimethicone copolyol, eg available as Abil EM 90 or in a mixture of polyglyceryl-4-isostearate, cetyl PEG / PPG-10/1 dimethicone and hexyl laurate under the trade name Abil WE 09), furthermore alkyl methicone copolyol.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, und den Silicon-basierten Wasser-in-Öl-Emulgator PEG/PPG-18/18 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Antitranspirant- Zusammensetzung. Particularly preferred antiperspirant compositions according to the invention in the form of a water-in-oil emulsion comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and the silicone-based water-in-oil emulsifier PEG / PPG-18/18 Dimethicone in a total amount of from 0.5 to 5% by weight, more preferably from 1.0 to 3.5% by weight, most preferably from 1.2 to 3% by weight, based in each case on the total weight of the antiperspirant composition.

Further particularly preferred antiperspirant compositions according to the invention are in the form of a water-in-oil emulsion and contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 5% by weight. 15 wt .-%, most preferably 5-10 wt .-%, of 1,4-bis (hydroxymethyl) cyclohexane, further at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and the silicone-based water-in-oil emulsifier PEG / PPG-18/18 Dimethicone in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 wt. -%, most preferably 1.2-3 wt .-%, each based on the total weight of the antiperspirant composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, und den Silicon-basierten Wasser-in-Öl-Emulgator Cetyl PEG/PPG-10/1 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Antitranspirant-Zusammensetzung. Particularly preferred antiperspirant compositions according to the invention in the form of a water-in-oil emulsion comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and the silicone-based water-in-oil emulsifier cetyl PEG / PPG-10/1 Dimethicone in one Total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 wt .-%, most preferably 1.2-3 wt .-%, each based on the total weight of the antiperspirant composition.

Further particularly preferred antiperspirant compositions according to the invention are in the form of a water-in-oil emulsion and contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 5% by weight. 15 wt .-%, most preferably 5-10 wt .-%, of 1,4-bis (hydroxymethyl) cyclohexane, further at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and the silicone-based water-in-oil emulsifier cetyl PEG / PPG-10/1 Dimethicone in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 wt .-%, most preferably 1.2-3 wt .-%, each based on the total weight of the antiperspirant composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel in einer Gesamtmenge von 0,5–70 Gew.-%, besonders bevorzugt 5–60 Gew.-%, bevorzugt außerordentlich 10–50 Gew.-%, weiter außerordentlich bevorzugt 20–35 Gew.-%, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, weiterhin mindestens einen Wasser-in-Öl-Emulgator, insbesondere einen Silicon-basierten Wasser-in-Öl-Emulgator, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further particularly preferred antiperspirant compositions according to the invention are in the form of a water-in-oil emulsion and contain at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent which is liquid under normal conditions in a total amount of 0.5-70% by weight, particularly preferably 5-60% by weight, preferably extraordinarily 10-50% by weight, more preferably still 20-35% by weight selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, furthermore at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil, wherein the amounts are each based on the total weight of the antiperspirant composition ,

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, mindestens einen Wasser-in-Öl-Emulgator, insbesondere einen Silicon-basierten Wasser-in-Öl-Emulgator, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further particularly preferred antiperspirant compositions according to the invention are in the form of a water-in-oil emulsion and contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 5% by weight. 15 wt .-%, most preferably 5-10 wt .-%, of 1,4-bis (hydroxymethyl) cyclohexane, at least one liquid under normal conditions solvent in a total amount of 0.5-70 wt .-%, particularly preferably 5 -60 wt .-%, preferably extraordinarily 10-50 wt .-%, more preferably still 20-35 wt .-%, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, further at least a water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil, wherein the amounts given in each case on the total weight of the antiperspirant composition b are attracted. Further particularly preferred antiperspirant compositions according to the invention are in the form of a gelatinous water-in-oil emulsion and comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent which is liquid under normal conditions and is selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil, wherein the amounts are in each case based on the total weight of the antiperspirant composition.

Further particularly preferred antiperspirant compositions according to the invention are in the form of a gelatinous water-in-oil emulsion and comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 -15% by weight, most preferably 5-10% by weight, of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent which is liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic Oil, wherein the amounts are each based on the total weight of the antiperspirant composition.

Such gelatinous water-in-oil emulsions in a preferred embodiment have a dynamic viscosity at 25 ° C in the range of 15,000 to 300,000 mPas, preferably 30,000 to 150,000 mPas, and most preferably 40,000 to 100,000 mPas. In a further preferred embodiment, the gel-like water-in-oil emulsions according to the invention with a dynamic viscosity at 25 ° C. in the range from 15,000 to 300,000 mPas, preferably 30,000 to 150,000 mPas and exceptionally preferably 40,000 to 100,000 mPas are transparent. Transparent compositions are those having a turbidity of not more than 100 NTU, preferably not more than 70 NTU, more preferably not more than 50 NTU, measured in each case at 25 ° C. The transparency is preferably achieved by setting the refractive index of the aqueous phase and the oil phase to the same value before mixing. For particularly high transparency, it is necessary to match the refractive indices to ± 0.001, preferably ± 0.0005 or better. Preferred compositions of the invention, which are formulated as a water-in-oil emulsion as gel or stick, contain free water in a total amount of 10-70% by weight, preferably 15-60% by weight, particularly preferably 20-50% by weight %, more preferably 25-55% by weight, still more preferably 30-40% by weight, based in each case on the total weight of the total composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, mindestens einen Wasser-in-Öl-Emulgator, insbesondere einen Silicon-basierten Wasser-in-Öl-Emulgator, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6-22 Kohlenstoffatomen mit Benzoesäure, verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6-30 Kohlenstoffatomen, Dicarbonsäureestern von linearen oder verzweigten C₂-C₁₀-Alkanolen, Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C_8-22-Alkanole, Anlagerungsprodukten von mindestens 6 Ethylenoxid und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C_3-22-Alkanole, Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit 2-30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2-30 Kohlenstoffatomen, die hydroxyliert sein können, Dicaprylylcarbonat, Octamethylcyclotetrasiloxan, Decamethylcyclopentasiloxan, Dodecamethylcyclohexasiloxan, Hexamethyldisiloxan (L₂), Octamethyltrisiloxan (L₃), Decamethyltetrasiloxan (L₄), Dodecamethylpentasiloxan (L₅), sowie beliebigen Zweier-, Dreier und Vierermischungen aus L₂, L₃, L₄ und/oder L₅, weiterhin ausgewählt aus linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt, wobei sich die Werte der kinematischen Viskosität auf eine Temperatur von 25°C beziehen, C₈-C₁₆-Isoalkanen, C₁₀-C₁₃-Isoalkanen, Isohexadecan, Isoeicosan, Polyisobutenen, hydrierten Polyisobutenen und Polydecenen, sowie Mischungen der vorgenannten Öle, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. The outer phase of water-in-oil emulsions according to the invention comprises at least one cosmetic oil. Oils which are preferred as constituents of preferred water-in-oil emulsions according to the invention have already been mentioned above. Water-in-oil emulsions preferred according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one solvent which is liquid under normal conditions and is selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols having 6-22 carbon atoms with benzoic acid, branched saturated or unsaturated fatty alcohols with 6 -30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 -alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units to a - or polyhydric C _3-22 alkanols, esters of linear or branched saturated or unsaturated fatty alcohols n with 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ) , Dodecamethylpentasiloxan (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ , further selected from linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt, wherein the values the kinematic viscosity to a temperature of 25 ° C, C ₈ -C ₁₆ -Isoalkanen, C ₁₀ -C ₁₃ -Isoalkanen, Isohexadecan, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and mixtures of the aforementioned oils, wherein the amounts given in each case on the total weight of the antiperspirant composition.

Water-in-oil emulsions which are particularly preferred according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10% by weight, of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent which is liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one water in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols having 6-22 carbon atoms with benzoic acid, branched saturated or unsaturated fatty alcohols having 6-30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 alkanols, adducts of at least 6 ethylene oxide and / or propylene oxide units of mono- or polyhydric C _3-22 alkanols, esters of linear or branched saturated or unsaturated fatty alcohols with 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), and any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ , further selected from linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt, wherein the values of the kinematic Viscosity to a temperature of 25 ° C, C ₈ -C ₁₆ isoalkanes, C ₁₀ -C _13- isoalkanes, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and mixtures of the aforementioned oils, wherein the amounts are in each case based on the total weight of the antiperspirant composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

10–70 Gew.-%, bevorzugt 15–60 Gew.-%, besonders bevorzugt 20–50 Gew.-%, außerordentlich bevorzugt 25–55 Gew.-%, weiterhin außerordentlich bevorzugt 30–40 Gew.-%, freies Wasser und mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, mindestens einen Wasser-in-Öl-Emulgator, insbesondere einen Silicon-basierten Wasser-in-Öl-Emulgator, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₈-C₁₆-Isoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 0,5–100 cSt (25°C), Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6-22 Kohlenstoffatomen mit Benzoesäure und Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit 2-30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2-30 Kohlenstoffatomen, die hydroxyliert sein können, enthalten. Due to the particularly favorable residue properties, water-in-oil emulsions are preferred according to the invention, which, based in each case on their total weight, at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in the

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

10-70 wt%, preferably 15-60 wt%, more preferably 20-50 wt%, most preferably 25-55 wt%, still more preferably 30-40 wt%, free water and at least one solvent under normal conditions, selected from a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from C ₈ -C ₁₆ isoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 0.5-100 cSt (25 ° C), esters of linear or branched saturated or unsaturated fatty alcohols having 6-22 carbon atoms with benzoic acid and esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, mindestens einen Wasser-in-Öl-Emulgator, insbesondere einen Silicon-basierten Wasser-in-Öl-Emulgator, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₁₀-C₁₃-Isoalkanen, Cyclomethiconen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 0,5–100 cSt (25°C) und Estern, ausgewählt aus C12-15-Alkylbenzoat, Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, enthalten. Particularly preferred are water-in-oil emulsions which, based in each case on their total weight, at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in the

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one liquid under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier , and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 0.5-100 cSt (25 ° C) and esters selected from C12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate , Isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoa t, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, mindestens einen Silicon-freien Wasser-in-Öl-Emulgator wie vorstehend beschrieben in einer Gesamtmenge von 0,1–15 Gew.-%, bevorzugt 0,5–8,0 Gew.-%, und besonders bevorzugt 1–4 Gew.-%, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit Benzoesäure, verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6-30 Kohlenstoffatomen, Dicarbonsäureestern von linearen oder verzweigten C₂-C₁₀-Alkanolen, Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C_8-22-Alkanole, Anlagerungsprodukten von mindestens 6 Ethylenoxid und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C_3-22-Alkanole, Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit 2-30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2-30 Kohlenstoffatomen, die hydroxyliert sein können, Dicaprylylcarbonat, Octamethylcyclotetrasiloxan, Decamethylcyclopentasiloxan, Dodecamethylcyclohexasiloxan, Hexamethyldisiloxan (L₂), Octamethyltrisiloxan (L₃), Decamethyltetrasiloxan (L₄), Dodecamethylpentasiloxan (L₅), sowie beliebigen Zweier-, Dreier- und Vierermischungen aus L₂, L₃, L₄ und/oder L₅, weiterhin ausgewählt aus linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt, wobei sich die Werte der kinematischen Viskosität auf eine Temperatur von 25°C beziehen, C₈-C₁₆-Isoalkanen, C₁₀-C₁₃-Isoalkanen, Isohexadecan, Isoeicosan, Polyisobutenen, hydrierten Polyisobutenen und Polydecenen, sowie Mischungen der vorgenannten Öle, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one silicone-free water-in-oil emulsifier as described above in a total amount of 0.1 -15% by weight, preferably 0.5-8.0% by weight, and particularly preferably 1-4% by weight, and in total 1-40% by weight, preferably 7-20% by weight, at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols with benzoic acid, branched saturated or unsaturated fatty alcohols having 6-30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, addition products of 1 to 5 propylene oxide Units of mono- or polyhydric C _8-22 alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units to mono- or polyhydric C _3-22 alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, Octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ further selected from linear dimethylpolysiloxanes having kinematic viscosities in the range 5-100 cSt, kinematic viscosity values being at 25 ° C, C ₈ -C ₁₆ isoalkanes, C ₁₀ -C ₁₃ Isoalkanes, Isohexadecan, Isoeicosan, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and mixtures of the aforementioned oils, wherein the amounts are each based on the total weight of the antiperspirant composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, mindestens einen Wasser-in-Öl-Emulgator auf Siliconbasis wie vorstehend beschrieben in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit Benzoesäure, verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6-30 Kohlenstoffatomen, Dicarbonsäureestern von linearen oder verzweigten C₂-C₁₀-Alkanolen, Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C_8-22-Alkanole, Anlagerungsprodukten von mindestens 6 Ethylenoxid und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C_3-22-Alkanole, Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit 2-30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2-30 Kohlenstoffatomen, die hydroxyliert sein können, Dicaprylylcarbonat, Octamethylcyclotetrasiloxan, Decamethylcyclopentasiloxan, Dodecamethylcyclohexasiloxan, Hexamethyldisiloxan (L₂), Octamethyltrisiloxan (L₃), Decamethyltetrasiloxan (L₄), Dodecamethylpentasiloxan (L₅), sowie beliebigen Zweier-, Dreier und Vierermischungen aus L₂, L₃, L₄ und/oder L₅, weiterhin ausgewählt aus linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt, wobei sich die Werte der kinematischen Viskosität auf eine Temperatur von 25°C beziehen, C₈-C₁₆-Isoalkanen, C₁₀-C₁₃-Isoalkanen, Isohexadecan, Isoeicosan, Polyisobutenen, hydrierten Polyisobutenen und Polydecenen, sowie Mischungen der vorgenannten Öle, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one silicone-based water-in-oil emulsifier as described above in a total amount of 0.5- 5 wt .-%, particularly preferably 1.0-3.5 wt .-%, most preferably 1.2-3 wt .-%, and a total of 1-40 wt .-%, preferably 7-20 wt .-% , at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols with benzoic acid, branched saturated or unsaturated fatty alcohols having 6-30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, addition products of 1 to 5 propylene oxide _{Units of} mono- or polyhydric C _8-22 alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units of mono- or polyhydric C _3-22 alkane ole, esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ , further selected from linear dimethylpolysiloxanes with kinematic viscosities in the range from 5 to 100 cSt, wherein the values of the kinematic viscosity refer to a temperature of 25 ° C, C ₈ -C ₁₆ isoalkanes, C ₁₀ -C ₁₃ isoalkanes, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and Mixtures of the aforesaid oils, the quantities given being based on the total weight t of the antiperspirant composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, einen Wasser-in-Öl-Emulgator auf Siliconbasis, ausgewählt aus PEG/PPG-18/18 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit Benzoesäure, verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6-30 Kohlenstoffatomen, Dicarbonsäureestern von linearen oder verzweigten C₂-C₁₀-Alkanolen, Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C_8-22-Alkanole, Anlagerungsprodukten von mindestens 6 Ethylenoxid und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C_3-22-Alkanole, Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit 2-30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2-30 Kohlenstoffatomen, die hydroxyliert sein können, Dicaprylylcarbonat, Octamethylcyclotetrasiloxan, Decamethylcyclopentasiloxan, Dodecamethylcyclohexasiloxan, Hexamethyldisiloxan (L₂), Octamethyltrisiloxan (L₃), Decamethyltetrasiloxan (L₄), Dodecamethylpentasiloxan (L₅), sowie beliebigen Zweier-, Dreier und Vierermischungen aus L₂, L₃, L₄ und/oder L₅, weiterhin ausgewählt aus linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt, wobei sich die Werte der kinematischen Viskosität auf eine Temperatur von 25°C beziehen, C₈-C₁₆-Isoalkanen, C₁₀-C₁₃-Isoalkanen, Isohexadecan, Isoeicosan, Polyisobutenen, hydrierten Polyisobutenen und Polydecenen, sowie Mischungen der vorgenannten Öle, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, a water-in-oil emulsifier based on silicone, selected from PEG / PPG-18/18 dimethicones in a total amount of 0.5-5 wt%, more preferably 1.0-3.5 wt%, most preferably 1.2-3 wt%, and a total of 1-40 wt%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols with benzoic acid, branched saturated or unsaturated fatty alcohols having 6-30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ alkanols , _Addition products of 1 to 5 propylene oxide units to mono- or polyhydric C _8-22 -alkanols, adducts of at least 6 ethylene oxide and / or propylene oxide units to mono- or polyvalent C _3-22 - Alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ , further selected from linear dimethylpolysiloxanes with kinematic viscosities in the range from 5 to 100 cSt, wherein the values of the kinematic viscosity refer to a temperature of 25 ° C, C ₈ -C ₁₆ isoalkanes, C ₁₀ -C ₁₃ isoalkanes, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and Mixtures of the aforesaid oils, the amounts given being based on the total g Not related to the antiperspirant composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, einen Wasser-in-Öl-Emulgator auf Siliconbasis, ausgewählt aus Cetyl PEG/PPG-10/1 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit Benzoesäure, verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6-30 Kohlenstoffatomen, Dicarbonsäureestern von linearen oder verzweigten C₂-C₁₀-Alkanolen, Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C_8-22-Alkanole, Anlagerungsprodukten von mindestens 6 Ethylenoxid und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C_3-22-Alkanole, Estern von linearen oder verzweigten gesättigten oder ungesättigten Fettalkoholen mit 2-30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2-30 Kohlenstoffatomen, die hydroxyliert sein können, Dicaprylylcarbonat, Octamethylcyclotetrasiloxan, Decamethylcyclopentasiloxan, Dodecamethylcyclohexasiloxan, Hexamethyldisiloxan (L₂), Octamethyltrisiloxan (L₃), Decamethyltetrasiloxan (L₄), Dodecamethylpentasiloxan (L₅), sowie beliebigen Zweier-, Dreier und Vierermischungen aus L₂, L₃, L₄ und/oder L₅, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt, wobei sich die Werte der kinematischen Viskosität auf eine Temperatur von 25°C beziehen, C₈-C₁₆-Isoalkanen, C₁₀-C₁₃-Isoalkanen, Isohexadecan, Isoeicosan, Polyisobutenen, hydrierten Polyisobutenen und Polydecenen, sowie Mischungen der vorgenannten Öle, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, a silicone-based water-in-oil emulsifier, selected from cetyl PEG / PPG-10/1 Dimethicone in a total amount of 0.5-5% by weight, more preferably 1.0-3.5% by weight, most preferably 1.2-3% by weight, and a total of 1-40% by weight, preferably 7-20 wt .-%, of at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols with benzoic acid, branched saturated or unsaturated fatty alcohols having 6-30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ - Alkanols, addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units of monovalent or polyvalent C _{3 -22-} alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), Octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ , linear dimethylpolysiloxanes with kinematic viscosities in the range from 5 to 100 cSt, wherein the values of the kinematic viscosity refer to a temperature of 25 ° C, C ₈ -C ₁₆ isoalkanes, C ₁₀ -C ₁₃ isoalkanes, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and Mixtures of the aforesaid oils, the amounts given being based on the total weight of the antiperspirant irant composition are related.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, mindestens einen Silicon-freien Wasser-in-Öl-Emulgator wie vorstehend beschrieben in einer Gesamtmenge von 0,1–15 Gew.-%, bevorzugt 0,5–8,0 Gew.-%, und besonders bevorzugt 1–4 Gew.-%, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₁₀-C₁₃-Isoalkanen, Cyclomethiconen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt (25°C) und Estern, ausgewählt aus C12-15-Alkylbenzoat, Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one silicone-free water-in-oil emulsifier as described above in a total amount of 0.1 -15% by weight, preferably 0.5-8.0% by weight, and particularly preferably 1-4% by weight, and in total 1-40% by weight, preferably 7-20% by weight, at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C 12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate , Isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoa t, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the amounts given being based on the total weight of the antiperspirant composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, mindestens einen Wasser-in-Öl-Emulgator auf Siliconbasis wie vorstehend beschrieben in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₁₀-C₁₃-Isoalkanen, Cyclomethiconen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt (25°C) und Estern, ausgewählt aus C12-15-Alkylbenzoat, Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one silicone-based water-in-oil emulsifier as described above in a total amount of 0.5- 5 wt .-%, particularly preferably 1.0-3.5 wt .-%, most preferably 1.2-3 wt .-%, and a total of 1-40 wt .-%, preferably 7-20 wt .-% , at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C 12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, Isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotr idecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the amounts given being based on the total weight of the antiperspirant composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, einen Wasser-in-Öl-Emulgator auf Siliconbasis, ausgewählt aus PEG/PPG-18/18 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₁₀-C₁₃-Isoalkanen, Cyclomethiconen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt (25°C) und Estern, ausgewählt aus C12-15-Alkylbenzoat, Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, a water-in-oil emulsifier based on silicone, selected from PEG / PPG-18/18 dimethicones in a total amount of 0.5-5 wt%, more preferably 1.0-3.5 wt%, most preferably 1.2-3 wt%, and a total of 1-40 wt%, preferably 7-20% by weight of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C12-15 Alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, Isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the amounts given being based on the total weight of the antiperspirant composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, einen Wasser-in-Öl-Emulgator auf Siliconbasis, ausgewählt aus Cetyl PEG/PPG-10/1 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, und insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₁₀-C₁₃-Isoalkanen, Cyclomethiconen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt (25°C) und Estern, ausgewählt aus C12-15-Alkylbenzoat, Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, a silicone-based water-in-oil emulsifier, selected from cetyl PEG / PPG-10/1 Dimethicone in a total amount of 0.5-5% by weight, more preferably 1.0-3.5% by weight, most preferably 1.2-3% by weight, and a total of 1-40% by weight, preferably 7-20% by weight, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters selected from C 12- 15-alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononane oat, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the amounts given being based on the total weight of the antiperspirant composition are.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, mindestens einen Silicon-freien Wasser-in-Öl-Emulgator wie vorstehend beschrieben in einer Gesamtmenge von 0,1–15 Gew.-%, bevorzugt 0,5–8,0 Gew.-%, und besonders bevorzugt 1–4 Gew.-%, insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus Isoceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1–3 Gew.-%, bevorzugt 0,5–1,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Antitranspirant-Zusammensetzung, enthalten. In a further preferred embodiment, the water-in-oil emulsions preferred according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one silicone-free water-in-oil emulsifier as described above in a total amount of 0.1 -15% by weight, preferably 0.5-8.0% by weight, and particularly preferably 1-4% by weight, in total 1-40% by weight, preferably 7-20% by weight, at least a cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from Isoceteth-20, wherein the amounts are in each case based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, einen Wasser-in-Öl-Emulgator auf Siliconbasis, ausgewählt aus PEG/PPG-18/18 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, weiterhin insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus Isoceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1–3 Gew.-%, bevorzugt 0,5–1,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Antitranspirant-Zusammensetzung, enthalten. In a further preferred embodiment, the water-in-oil emulsions preferred according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, a water-in-oil emulsifier based on silicone, selected from PEG / PPG-18/18 dimethicones in a total amount of 0.5-5% by weight, more preferably 1.0-3.5% by weight, most preferably 1.2-3% by weight, further preferably a total of 1-40% by weight, preferably 7-20 wt .-%, of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from Isoceteth-20, wherein the amounts are in each case based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, einen Wasser-in-Öl-Emulgator auf Siliconbasis ausgewählt aus Cetyl PEG/PPG-10/1 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, weiterhin insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus Isoceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1–3 Gew.-%, bevorzugt 0,5–1,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Antitranspirant-Zusammensetzung, enthalten. In a further preferred embodiment, the water-in-oil emulsions preferred according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, a silicone-based water-in-oil emulsifier selected from cetyl PEG / PPG-10/1 Dimethicone in a total amount of 0.5-5% by weight, more preferably 1.0-3.5% by weight, most preferably 1.2-3% by weight, further preferably a total of 1-40% by weight, preferably 7-20 wt .-%, of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from Isoceteth-20, wherein the amounts are in each case based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, mindestens einen Wasser-in-Öl-Emulgator auf Siliconbasis wie vorstehend beschrieben in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₁₀-C₁₃-Isoalkanen, Cyclomethiconen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt (25°C) und Estern, ausgewählt aus C12-15-Alkylbenzoat, Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus Isoceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1–3 Gew.-%, bevorzugt 0,5–1,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Antitranspirant-Zusammensetzung, enthalten. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent which is liquid under normal conditions and is selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one water-in-oil emulsifier based on silicone as described above in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 wt .-%, most preferably 1.2-3 wt .-%, a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate , Isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl aurate, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from Isoceteth-20, wherein the amounts are each based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, einen Wasser-in-Öl-Emulgator auf Siliconbasis, ausgewählt aus PEG/PPG-18/18 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, weiterhin insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₁₀-C₁₃-Isoalkanen, Cyclomethiconen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt (25°C) und Estern, ausgewählt aus C12-15-Alkylbenzoat, Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus Isoceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1–3 Gew.-%, bevorzugt 0,5–1,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Antitranspirant-Zusammensetzung, enthalten. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, a water-in-oil emulsifier based on silicone, selected from PEG / PPG-18/18 dimethicones in a total amount of 0.5-5% by weight, more preferably 1.0-3.5% by weight, most preferably 1.2-3% by weight, further preferably a total of 1-40% by weight, preferably 7-20% by weight of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C12-15 Alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononone noate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, and at least one nonionic polyalkylene glycol ether having an HLB value> 7 , which is preferably selected from Isoceteth-20, wherein the amounts are each based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und mindestens einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, einen Wasser-in-Öl-Emulgator auf Siliconbasis ausgewählt aus Cetyl PEG/PPG-10/1 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, weiterhin insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₁₀-C₁₃-Isoalkanen, Cyclomethiconen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5–100 cSt (25°C) und Estern, ausgewählt aus C12-15-Alkylbenzoat, Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus Isoceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1–3 Gew.-%, bevorzugt 0,5–1,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Antitranspirant-Zusammensetzung, enthalten. Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, a silicone-based water-in-oil emulsifier selected from cetyl PEG / PPG-10/1 Dimethicone in a total amount of 0.5-5% by weight, more preferably 1.0-3.5% by weight, most preferably 1.2-3% by weight, further preferably a total of 1-40% by weight, preferably 7-20% by weight of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C12-15 Alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl iso nonanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, and at least one nonionic polyalkylene glycol ether having an HLB value> 7 , which is preferably selected from Isoceteth-20, wherein the amounts are each based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

Due to the particularly favorable residue properties, water-in-oil emulsions are preferred according to the invention, which, based on their total weight, at least one aluminum-zirconium compound, 0.1 to 50 wt .-%, preferably 1-20 wt .-% , more preferably 2-15 wt .-%, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, 10-70 wt .-%, preferably 15-60 Wt .-%, particularly preferably 20-50 wt .-%, most preferably 25-55 wt .-%, still more preferably 30-40 wt .-%, free water and at least one liquid under normal conditions, selected from a solvent or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and a total of 1-40 wt .-%, preferably 7- 20 wt .-%, of at least one cosmetic oil selected from C ₁₀ C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C), esters of linear or branched saturated or unsaturated fatty alcohols having 6-22 carbon atoms with benzoic acid and esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated.

Particular preference is given to water-in-oil emulsions which, based in each case on their total weight, contain at least one aluminum-zirconium compound, from 0.1 to 50% by weight, preferably from 1 to 20% by weight, more preferably 2% 15 wt .-%, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one mono- or polyhydric Alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate , 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate.

Further preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures this solvent, at least one silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15 wt .-%, preferably 0.5-8.0 wt .-%, and particularly preferably 1- 4 wt .-%, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols with benzoic acid, branched saturated or unsaturated fatty alcohols with 6-30 carbon fatomen, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 -alkanols, adducts of at least 6 ethylene oxide and / or propylene oxide units on and polyhydric C _3-22 alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ , further selected from linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt, wherein the di e values of kinematic viscosity to a temperature of 25 ° C, C ₈ -C ₁₆ isoalkanes, C ₁₀ -C ₁₃ isoalkanes, Isohexadecan, Isoeicosan, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and mixtures of the aforementioned oils, wherein the amounts each on the Total weight of the antiperspirant composition are related.

Further preferred water-in-oil emulsions according to the invention comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures this solvent, at least one water-in-oil emulsifier based on silicone as described above in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 wt .-%, most preferably 1.2 -3 wt .-%, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols with benzoic acid, branched saturated or unsaturated fatty alcohols With 6-30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 -alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units mono- or polyhydric C _3-22 -alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, Dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ , further selected from linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt in which the values of the kinematic viscosity relate to a temperature of 25 ° C., C ₈ -C ₁₆ isoalkanes, C ₁₀ -C ₁₃ isoalkanes, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and mixtures of the abovementioned oils, wherein the amounts are each based on the total weight of the antiperspirant composition. Further preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures this solvent, a water-in-oil emulsifier based on silicone, selected PEG / PPG-18/18 dimethicones in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 wt .-% , most preferably 1.2-3 wt .-%, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols with benzoic acid , branched saturated or unsaturated fatty alcohols mi T 6-30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 -alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units mono- or polyhydric C _3-22 alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane , Dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ , further selected from linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 c St, wherein the values of the kinematic viscosity relate to a temperature of 25 ° C, C ₈ -C ₁₆ isoalkanes, C ₁₀ -C ₁₃ isoalkanes, Isohexadecan, Isoeicosan, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and mixtures of the aforementioned oils , wherein the amounts are each based on the total weight of the antiperspirant composition. Further preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures this solvent, a water-in-oil emulsifier based on silicone, selected cetyl PEG / PPG-10/1 dimethicone in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 wt. %, most preferably 1.2-3 wt .-%, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols with Benzoic acid, branched saturated or unsaturated fatty alcohol en with 6-30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 -alkanols, adducts of at least 6 ethylene oxide and / or propylene oxide Units of mono- or polyhydric C _3-22 -alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, Decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ further selected from linear dimethylpolysiloxanes having kinematic viscosities in the range of 5- 100 cSt, wherein the values of the kinematic viscosity relate to a temperature of 25 ° C, C ₈ -C ₁₆ isoalkanes, C ₁₀ -C ₁₃ isoalkanes, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and mixtures of the abovementioned Oils, wherein the amounts are each based on the total weight of the antiperspirant composition. Further preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures this solvent, at least one silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15 wt .-%, preferably 0.5-8.0 wt .-%, and particularly preferably 1- 4 wt .-%, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C12-15 alkylb enzoat, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl, 2- Ethylhexyl cocoate, 2-octyldodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the amounts given being based on the total weight of the antiperspirant composition.

Further preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight, of 1,4-bis (hydroxymethyl) cyclohexane, at least one liquid under normal conditions, selected from water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, at least one silicone-based water-in-oil emulsifier as described above in a total amount of 0.5-5 wt.%, particularly preferably 1.0 -3.5% by weight, exceptionally preferably 1.2-3% by weight, and in total 1-40% by weight, preferably 7-20% by weight, of at least one cosmetic oil selected from C ₁₀ - C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C 12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate , Isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethyl lhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the amounts given being based on the total weight of the antiperspirant composition.

Further preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures this solvent, a water-in-oil emulsifier based on silicone, selected from PEG / PPG-18/18 Dimethicone in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 wt. %, even more preferably 1.2-3% by weight, and in total 1-40% by weight, preferably 7-20% by weight, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters, selected hlt of C12-15-alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the amounts given being based on the total weight of the antiperspirant composition.

Further preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures this solvent, at least one silicone-based water-in-oil emulsifier selected from cetyl PEG / PPG-10/1 Dimethicone, in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 Wt .-%, most preferably 1.2-3 wt .-%, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes , Cyclomethicones, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C) and Esters selected from C12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2- Ethyl hexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the amounts given being based on the total weight of the antiperspirant composition.

In a further preferred embodiment, the water-in-oil emulsions preferred according to the invention comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight. %, most preferably 5-10% by weight, based in each case on their total weight, of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent which is liquid under normal conditions and selected from water and at least one mono- or polyhydric alcohol with 2 to 20 carbon atoms and mixtures of these solvents, at least one silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15 wt .-%, preferably 0.5-8.0 wt .-%, and particularly preferably 1-4% by weight, in total 1-40% by weight, preferably 7-20% by weight, of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected is from isoceteth-20, where the quantities j each based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

In a further preferred embodiment, the preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50 wt .-%, preferably 1-20 Wt .-%, more preferably 2-15 wt .-%, most preferably 5-10 wt .-%, each based on their total weight, of 1,4-bis (hydroxymethyl) cyclohexane, at least one liquid under normal conditions, selected solvent water and at least one mono- or polyhydric alcohol having 2 to 20 carbon atoms, and mixtures of these solvents, a silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones in a total amount of 0.5-5 Wt .-%, particularly preferably 1.0-3.5 wt .-%, most preferably 1.2-3 wt .-%, further a total of 1-40 wt .-%, preferably 7-20 wt .-%, at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from isoceteth-20, wherein the amounts are in each case based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

In a further preferred embodiment, the water-in-oil emulsions preferred according to the invention comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight. %, most preferably 5-10% by weight, based in each case on their total weight, of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent which is liquid under normal conditions and selected from water and at least one mono- or polyhydric alcohol with 2 to 20 carbon atoms and mixtures of these solvents, at least one water-in-oil emulsifier based on silicone, selected from cetyl PEG / PPG-10/1 Dimethicone, in a total amount of 0.5-5 wt .-%, particularly preferably 1, 0-3.5 wt .-%, exceptionally preferably 1.2-3 wt .-%, further a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil, and at least one nonionic Polyalkylene glycol ethers having an HLB value> 7, preferably selected t is from isoceteth-20, the amounts given being based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

Further preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures this solvent, at least one water-in-oil emulsifier based on silicone as described above in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 wt .-%, most preferably 1.2 -3 wt .-%, a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from C ₁₀ - C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C12-15-alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2- Ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, and at least one nonionic polyalkylene glycol ether having an HLB> 7, which is preferably selected from isoceteth-20; Quantities are each based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

Further preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures this solvent, at least one silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 Dimethicone, in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 wt .-%, most preferably 1.2-3 wt .-%, further totaling 1-40 wt. %, preferably 7-20 wt .-%, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C12-15-alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2- Ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, and at least one nonionic polyalkylene glycol Her with an HLB value> 7, which is preferably selected from isoceteth-20, wherein the amounts are in each case based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

Further preferred water-in-oil emulsions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5-10 wt .-%, each based on their total weight of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and at least one monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures this solvent, at least one silicone-based water-in-oil emulsifier selected from cetyl PEG / PPG-10/1 Dimethicone, in a total amount of 0.5-5 wt .-%, particularly preferably 1.0-3.5 Wt .-%, most preferably 1.2-3 wt .-%, further total 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes , Cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt (25 ° C) and esters selected from C12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate , 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from isoceteth-20, the amounts given being based on the total weight of the antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably contained in a total amount of 0.1-3% by weight, preferably 0.5-1.5% by weight, in each case based on the total weight of the antiperspirant composition ,

Surprisingly, it has been found that such emulsions have a particularly high temperature stability.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel in einer Gesamtmenge von 0,5–70 Gew.-%, besonders bevorzugt 5–60 Gew.-%, bevorzugt außerordentlich 10–50 Gew.-%, weiter außerordentlich bevorzugt 20–35 Gew.-%, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, weiterhin mindestens einen Wasser-in-Öl-Emulgator, insbesondere einen Silicon-basierten Wasser-in-Öl-Emulgator in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, weiterhin insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₁₀-C₁₃-Isoalkanen, Cyclomethiconen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 0,5–100 cSt (25°C) und Estern, ausgewählt aus C12-15-Alkylbenzoat, Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, weiterhin mindestens eine Wachskomponente mit einem Schmelzpunkt > 50°C, ausgewählt aus Polyethylenwachsen mit einem Molekulargewicht von 400–3000, besonders bevorzugt mit einem Molekulargewicht von 500–600, in einer Gesamtmenge von 4–18 Gew.-%, bevorzugt 6–15 Gew.-%, besonders bevorzugt 8–13 Gew.-%, außerordentlich bevorzugt 9–11 Gew.-%, enthalten, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further particularly preferred antiperspirant compositions according to the invention are present as a water-in-oil emulsion in stick form and comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent which is liquid under normal conditions in a total amount of 0.5-70% by weight, particularly preferably 5-60% by weight, preferably extraordinarily 10-50% by weight, more preferably still 20-35% by weight selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, furthermore at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier in a total amount of 0.5-5 wt.%, particularly preferably 1.0-3.5 wt.%, extraordinarily preferably 1.2-3% by weight, furthermore a total of 1-40% by weight, preferably 7-20% by weight, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range 0.5-100 cSt (25 ° C) and esters selected from C12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, Isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecylaceta t, n-butyl stearate and n-hexyl laurate, furthermore at least one wax component with a melting point> 50 ° C, selected from polyethylene waxes with a molecular weight of 400-3000, particularly preferably with a molecular weight of 500-600, in a total amount of 4-18 Wt .-%, preferably 6-15 wt .-%, more preferably 8-13 wt .-%, most preferably 9-11 wt .-%, wherein the amounts are in each case based on the total weight of the antiperspirant composition.

Further particularly preferred antiperspirant compositions according to the invention are present as a water-in-oil emulsion in stick form and comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1-20% by weight, more preferably 2-15 wt .-%, most preferably 5-10 wt .-%, of 1,4-bis (hydroxymethyl) cyclohexane, at least one liquid under normal conditions, in a total amount of 0.5-70 wt .-%, especially preferably 5-60 wt.%, preferably extraordinarily 10-50 wt.%, even more preferably 20-35 wt.%, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, furthermore at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, in a total amount of 0.5-5 wt.%, particularly preferably 1.0-3.5 wt. , most preferably 1.2-3 wt .-%, further total 1-40 wt .-%, preferably 7 20 wt .-% of at least one cosmetic oil selected from C ₁₀ -C ₁₃ -Isoalkanen, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range 0.5-100 cSt (25 ° C) and esters selected from C12-15 -alkyl, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl, 2 Ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, furthermore at least one wax component with a melting point> 50 ° C., selected from polyethylene waxes having a molecular weight of 400-3000, particularly preferably one Molecular weight of 500-600, in a total of v on 4-18% by weight, preferably 6-15% by weight, particularly preferably 8-13% by weight, most preferably 9-11% by weight, the amounts given being based on the total weight of the antiperspirant Composition are related.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht,

mindestens ein unter Normalbedingungen flüssiges Lösemittel in einer Gesamtmenge von 0,5–70 Gew.-%, besonders bevorzugt 5–60 Gew.-%, bevorzugt außerordentlich 10 – 50 Gew.-%, weiter außerordentlich bevorzugt 20–35 Gew.-%, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, weiterhin einen Silicon-basierten Wasser-in-Öl-Emulgator, ausgewählt aus Cetyl PEG/PPG-10/1 Dimethicone in einer Gesamtmenge von 0,5–5 Gew.-%, besonders bevorzugt 1,0–3,5 Gew.-%, außerordentlich bevorzugt 1,2–3 Gew.-%, weiterhin insgesamt 1–40 Gew.-%, bevorzugt 7–20 Gew.-%, mindestens eines kosmetischen Öls, ausgewählt aus C₁₀-C₁₃-Isoalkanen, Cyclomethiconen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 0,5–100 cSt (25°C) und Estern, ausgewählt aus C12-15-Alkylbenzoat, Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, weiterhin mindestens eine Wachskomponente mit einem Schmelzpunkt > 50°C, ausgewählt aus Polyethylenwachsen mit einem Molekulargewicht von 400–3000, besonders bevorzugt mit einem Molekulargewicht von 500–600, in einer Gesamtmenge von 4–18 Gew.-%, bevorzugt 6–15 Gew.-%, besonders bevorzugt 8–13 Gew.-%, außerordentlich bevorzugt 9–11 Gew.-%, enthalten, wobei die Mengenangaben jeweils auf das Gesamtgewicht der Antitranspirant-Zusammensetzung bezogen sind. Further particularly preferred antiperspirant compositions according to the invention are present as a water-in-oil emulsion in stick form and comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5,

at least one solvent which is liquid under normal conditions in a total amount of 0.5-70% by weight, particularly preferably 5-60% by weight, preferably extraordinarily 10-50% by weight, moreover still more preferably 20-35% by weight selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, furthermore a silicone-based water-in-oil emulsifier selected from cetyl PEG / PPG-10/1 Dimethicone in a total amount of 0 , 5-5% by weight, more preferably 1.0-3.5% by weight, most preferably 1.2-3% by weight, furthermore a total of 1-40% by weight, preferably 7-20% by weight, of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 0.5-100 cSt (25 ° C) and esters selected from C12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, Isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, furthermore at least one wax component with a melting point> 50 ° C., selected from Polyethylene waxes having a molecular weight of 400-3000, particularly preferably with a Moleku large weight of 500-600, in a total amount of 4-18 wt .-%, preferably 6-15 wt .-%, particularly preferably 8-13 wt .-%, most preferably 9-11 wt .-%, wherein the quantities are each based on the total weight of the antiperspirant composition.

Further particularly preferred antiperspirant compositions according to the invention are present as a water-in-oil emulsion in stick form and comprise at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1-20% by weight, more preferably 2-15 wt .-%, most preferably 5-10 wt .-%, of 1,4-bis (hydroxymethyl) cyclohexane, at least one liquid under normal conditions, in a total amount of 0.5-70 wt .-%, especially preferably 5-60 wt.%, preferably extraordinarily 10-50 wt.%, even more preferably 20-35 wt.%, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, furthermore a silicone-based water-in-oil emulsifier selected from cetyl PEG / PPG-10/1 dimethicone in a total amount of 0.5-5 wt.%, particularly preferably 1.0-3.5 wt. %, most preferably 1.2-3 wt .-%, further total 1-40 wt .-%, preferably 7-20 wt % of at least one cosmetic oil selected from C ₁₀ -C ₁₃ isoalkanes, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 0.5-100 cSt (25 ° C) and esters selected from C 12-15 alkyl benzoate , hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl, 2-ethylhexyl cocoate , 2-octyldodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, furthermore at least one wax component with a melting point> 50 ° C, selected from polyethylene waxes having a molecular weight of 400-3000, particularly preferably having a molecular weight of 500-600, in a total of 4- 18 wt .-%, preferably 6-15 wt .-%, particularly preferably 8-13 wt .-%, most preferably 9-11 wt .-%, wherein the amounts are in each case based on the total weight of the antiperspirant composition ,

Further preferred compositions according to the invention are characterized in that they are formulated as dibenzylidenalditol-based gel, in particular as dibenzylidenesorbitol-based gel. Corresponding gels, which are normally so strong that they are sold as a pen, are disclosed, for example, in US Pat US 5705171 . US 5939055 . US 5725846 . EP 812183 and EP 1269977 , The carrier is an anhydrous polyhydric alcohol having 3 to 9 carbon atoms, which is liquid under normal conditions. These include 1,2-propylene glycol, 2-methyl-1,3-propanediol, glycerol, 1,2-butylene glycol, 1,3-butylene glycol and 1,4-butylene glycol, pentylene glycols such as 1,2-pentanediol and 1,5-butanediol. Pentanediol, hexanediols such as 1,2-hexanediol and 1,6-hexanediol, hexanetriols such as 1,2,6-hexanetriol, 2-ethyl-2-hydroxymethyl-1,3-propanediol, diethylene glycol, triethylene glycol, dipropylene glycol, tripropylene glycol, diglycerol and triglycerol. Particularly preferred is 1,2-propylene glycol. Highly preferred is 1,2-propylene glycol, which is 20-80% by weight, preferably 25-60% by weight, more preferably 30-50% by weight of the total stick weight. This solvent is gelled with a dibenzylidene alditol, especially with dibenzylidenesorbitol (DBS). As similarly structured gelling agents are also suitable Dibenzylidenxylitol and Dibenzylidenribitol, DBS is preferred. This gelling agent is preferably used in a total amount of 0.3-2% by weight, more preferably 0.5-1.8% by weight, most preferably 0.8-1.5% by weight, based on the total weight the composition added.

Particularly preferably, the dibenzylidenalditol-based gels are transparent. In a further preferred embodiment, further additives, such as, in particular, antiperspirant or deodorant active ingredients, oils and emulsifiers, are selected such that they do not impair the transparency of the end product.

Furthermore, compositions according to the invention in the form of a dibenzylidenalditol-based gel preferably contain at least one cosmetic oil. In principle, all the oils mentioned above are suitable. In view of skin feel and transparency, preferred oils are selected from the addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, e.g. As PPG-2-myristyl ether and PPG-3-myristyl ether and the addition products of at least 6 ethylene oxide and / or propylene oxide units of mono- or polyhydric C _3-22 alkanols such as glycerol, butanol, butanediol, myristyl alcohol and stearyl alcohol, the if desired, may be esterified, e.g. PPG-14 butyl ether, PPG-9-butyl ether, PPG-10-butanediol, PPG-15 stearyl ether and glycereth-7-diisononanoate.

Further preferred oils are selected from the dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, in particular diisopropyl adipate, di-n-butyl adipate, di (2-ethylhexyl) adipate, dioctyl adipate, diethyl / di-n-butyl / dioctyl sebacate , Diisopropyl sebacate, dioctyl malate, dioctyl maleate, dicaprylyl maleate, diisooctyl succinate, di-2-ethylhexyl succinate and di (2-hexyldecyl) succinate. Preferably, the at least one oil in a total amount of 0.1-5 wt .-%, particularly preferably 0.5-3 wt .-%, most preferably 0.8-1.5 wt .-%, based on the total weight the dibenzylidenalditol gelled composition.

As additional gelling agents preferred dibenzylidenalditol based gels according to the invention contain at least one substance selected from the group comprising cellulose ethers, especially hydroxyalkylcelluloses, especially hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose, methylhydroxyethylcellulose, furthermore xanthan gum, sclerotium gum, succinoglucans , Polygalactomannans, especially guar gums and locust bean gum, in particular guar gum and locust bean gum itself and the nonionic hydroxyalkyl guar derivatives and locust bean gum derivatives such as hydroxypropyl guar, carboxymethylhydroxypropyl guar, hydroxypropylmethyl guar, hydroxyethyl guar and carboxymethylguar, furthermore pectins, agar, carrageenans (Carrageenan), tragacanth, gum arabic, karaya gum, tara gum, Gellan, gelatin, casein, propylene glycol alginate, alginic acids and their salts, in particular sodium alginate, potassium alginate and calcium alginate. Particularly preferred according to the invention is hydroxypropylcellulose. This additional gelling agent is preferably in a total amount of 0.08-1 wt .-%, preferably 0.1 to 0.5 wt .-%, particularly preferably 0.2-0.4 wt .-%, most preferably 0, 3 wt .-%, each based on the total weight of the composition. In a further preferred embodiment, the dibenzylidenalditol-based gels according to the invention contain at least one complexing agent. Especially preferred as complexing agents are anhydrous ethylenediaminetetraacetic acid (EDTA) and its sodium salts, in particular the tetrasodium salt and the trisodium salt, anhydrous 1,3-propylenediaminetetraacetic acid (PDTA) and their sodium salts, in particular the tetrasodium salt and the trisodium salt, anhydrous hydroxyethylethylenediaminetetraacetic acid (HEDTA) and their sodium salts, in particular the tetrasodium salt and the trisodium salt, anhydrous diethylenetriamine pentaacetic acid (DTPA) and its sodium salts, in particular the pentasodium salt, the tetrasodium salt and the trisodium salt, nitrilotriacetic acid (NTA) and their sodium salts, β-alaninediacetic acid and its salts, the ethanoldiglycine disodium salt, the diethanolglycine sodium salt and phosphonic acids and their salts salts. The at least one complex-forming substance is preferably in a total amount of 0.05-2 wt .-%, more preferably 0.1-1, most preferably 0.2-0.5 wt .-%, based on the total weight of the composition according to the invention , contain.

In a further preferred embodiment, the dibenzylidenalditol-based gels according to the invention comprise at least one oil-in-water emulsifier. Preferred oil-in-water emulsifiers, in particular preferred nonionic oil-in-water emulsifiers, have already been described above.

Particularly preferred dibenzylidenalditol-based gel compositions according to the invention are characterized in that at least one oil-in-water emulsifier, preferably at least one nonionic oil-in-water emulsifier, in a total amount of 0.1-5% by weight, preferably 0.2-3% by weight, more preferably 0.3-2% by weight, most preferably 0.4-1% by weight, further preferably also 0.5, 0.6, 0.7, 0.8 and 0.9 wt .-%, based on the total composition.

Further compositions preferred according to the invention contain at least one hydrogel former. Such compositions have a surprisingly improved perfume adhesion and improved temperature stability due to 1,4-bis (hydroxymethyl) cyclohexane. Preferred hydrogel formers are selected from cellulose ethers, especially hydroxyalkylcelluloses, in particular hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose, methylhydroxyethylcellulose, furthermore xanthan gum, sclerotium gum, succinoglucans, polygalactomannans, in particular guar gum and locust bean gum, in particular guar gum and locust bean gum itself and the nonionic hydroxyalkyl guar derivatives and locust bean gum derivatives such as hydroxypropyl guar, carboxymethylhydroxypropyl guar, hydroxypropylmethyl guar, hydroxyethyl guar and carboxymethyl guar, pectins, agar, carrageenan, tragacanth, gum arabic, karaya gum, tara gum, gellan, Gelatin, casein, pectin, propylene glycol alginate, alginic acids and their salts, in particular sodium alginate, potassium alginate and calcium alginate, furthermore polyvinylpyrrolidones, polyvinyl alcohols n, polyacrylamides, further physical (e.g. B. by Vorverkleisterung) and / or chemically modified starches, especially hydroxypropylated starch phosphates and Octenylstärkesuccinaten and their aluminum, calcium or sodium salts, water-soluble acrylic acid-acrylate copolymers, acrylic acid-acrylamide copolymers, acrylic acid-vinylpyrrolidone copolymers, acrylic acid-vinylformamide Copolymers and polyacrylates.

Compositions preferred according to the invention contain at least one hydrogel former in a total amount of 0.1-3.0% by weight, preferably 0.3-2.0% by weight, more preferably 0.5-1.5% by weight and extremely preferably 0.7-1.0 wt .-%, each based on the total weight of the total composition of the invention.

In a further preferred embodiment, the compositions according to the invention are in the form of hydrogels and comprise at least one hydrogel former in a total amount of 0.1-3.0% by weight, preferably 0.3-2.0% by weight, more preferably 0, 5-1.5 wt .-% and most preferably 0.7-1.0 wt .-%, each based on the total weight of the total composition of the invention.

Compositions which are particularly preferred according to the invention furthermore preferably contain at least one skin-cooling active substance. According to the invention, skin-cooling active ingredients are compounds which, like l-menthol, stimulate the thermoreceptors in the skin and the mucous membranes in such a way that a cool sensory impression is created. In particular, the receptor CMR-1 ("cold and menthol-sensitive receptor"), which belongs to the family of TRP channels, is stimulated by the cooling agents, whereby a cold impression is generated. Skin-cooling active ingredients suitable according to the invention are, for example, menthol, isopulegol and menthol derivatives, eg. Menthyl lactate, menthyl glycolate, menthyl pyrrolidone carboxylic acid, menthyl methyl ether, menthoxypropanediol, menthone glycerol acetal (9-methyl-6- (1-methylethyl) -1,4-dioxaspiro (4.5) decane-2-methanol), monomethyl succinate and 2-hydroxymethyl-3,5 , 5-trimethylcyclohexanol. Preferred skin-cooling active ingredients are menthol, isopulegol, menthyl lactate, menthoxypropanediol and menthylpyrrolidonecarboxylic acid, and mixtures of these substances, in particular mixtures of menthol and menthyl lactate, menthol, menthol glycolate and menthyl lactate, menthol and menthoxypropanediol or menthol and isopulegol.

It is particularly preferred according to the invention for at least one skin-cooling active ingredient to be present in a total amount of 0.01-1% by weight, more preferably 0.02-0.5% by weight and most preferably 0.05-0.2-0.3% by weight %, in each case based on the total weight of the composition.

Low-melting lipid or wax component

Particularly preferred antiperspirant compositions according to the invention, in particular those in stick form, but also those which are suitable gel-like for use in a roll-on, are characterized in that at least one wax component having a melting point in the range from 25 to <50 ° C, selected from Kokosfettsäureglycerinmono-, di- and triesters, Butyrospermum Parkii (Shea butter) and esters of saturated, monohydric C ₈ -C ₁₈ alcohols with saturated C ₁₂ -C ₁₈ monocarboxylic acids and mixtures of these substances. These lower melting wax components allow consistency optimization of sticky, creamy or flowable products and minimize visible residue on the skin. Especially preferred are products sold under the INCI name Cocoglycerides, in particular the commercial products Novata ^® (ex Cognis), particularly preferably Novata AB ^®, a mixture of C ₁₂ -C ₁₈ mono-, di- and triglycerides, which in the range of 30- 32 ° C, as well as the products of the Softisan series (Sasol Germany GmbH) with the INCI name Hydrogenated Cocoglycerides, in particular Softisan 100, 133, 134, 138, 142. Further preferred esters of saturated, monohydric C ₁₂ -C ₁₈ - alcohols with saturated C ₁₂ -C ₁₈ monocarboxylic acids are stearyl laurate, cetearyl (z. B. Crodamol ^® CSS), cetyl palmitate (z. B. Cutina ^® CP) and myristyl myristate (z. B. Cetiol ^® MM).

Further particularly preferred antiperspirant compositions according to the invention, in particular those in stick form, are characterized in that the at least one wax component having a melting point in the range from 25 to <50 ° C. in amounts of from 0.01 to 20% by weight, preferably 0, 1-10 wt .-%, particularly preferably 0.5-5 wt .-% and most preferably 2-4 wt .-%, based on the total composition, is included. fillers

Particularly preferred antiperspirant compositions according to the invention are characterized in that they further contain at least one solid, water-insoluble particulate filler for improving the consistency and the sensory properties. In a highly preferred embodiment of this filler is selected from optionally modified starches (for. Example, of corn, rice, potatoes) and starch derivatives, which are, if desired, pregelatinized, in particular starch derivatives, such as Aluminum Starch Octenylsuccinate (z. B. DRY FLO ^®) Sodium Starch Octenyl succinates, cellulose and cellulose derivatives, silica, silicas, e.g. As Aerosil ^® types, spherical Polyalkylsesquisiloxan particles (especially Aerosil ^® R972 and Aerosil ^® 200V from Degussa), silica gels, talc, kaolin, clays, z. Bentonites, magnesium aluminum silicates, boron nitride, lactoglobulin derivatives, e.g. As sodium C _8-16 isoalkylsuccinyllactoglobulinsulfonate, glass powders, polymer powders, in particular of polyolefins, polycarbonates, polyurethanes, polyamides, eg. As nylon, polyesters, polystyrenes, polyacrylates, (meth) acrylate or (meth) acrylate-vinylidene copolymers, which may be crosslinked, or silicones, and mixtures of these substances.

Polymer powder based on a polymethacrylate copolymer are z. B. as a commercial product Polytrap ^® 6603 (Dow Corning) available. Other polymer powders, e.g. Example based on polyamides, obtainable under the name Orgasol ^® 1002 (polyamide-6) and Orgasol ^® 2002 (polyamide-12) from Elf Atochem. Other polymer powders which are suitable for the purpose according to the invention are, for. B. polymethacrylates (Micro Pearl ^® M from SEPPIC or Plastic Powder A of NIKKOL), styrene-divinylbenzene copolymers, polyethylene and polypropylene powder ^(® ACCUREL EP 400 from AKZO), or silicone polymers.

Particularly preferred antiperspirant compositions according to the invention are characterized in that they contain at least one solid, water-insoluble particulate filler in a total amount of from 0.01 to 30% by weight, preferably 5 to 20% by weight, more preferably 8 to 15% by weight. %, in each case based on the total composition. fragrances

Surprisingly, it has been found that a content of 1,4-bis (hydroxymethyl) cyclohexane in the antiperspirant compositions according to the invention leads to prolonged perfume adhesion or fragrance adhesion.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, und mindestens ein Riechstoff enthalten sind. Preferred antiperspirant compositions according to the invention are therefore characterized in that at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in the

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one liquid under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and at least one fragrance are included.

The definition of a fragrance within the meaning of the present application is in accordance with the expert definition, as they RÖMPP Chemie Lexikon, as of December 2007 , can be taken. Thereafter, a fragrance is a chemical compound with smell and / or taste that excites the hair cell receptors (adequate stimulus). The necessary physical and chemical properties are a low molecular weight of at most 300 g / mol, a high vapor pressure, minimal water and high lipid solubility and weak polarity and the presence of at least one osmophoric group in the molecule. In order to delineate volatile, low molecular weight substances which are usually and also not regarded as perfuming agents, but primarily as solvents, for example ethanol, propanol, isopropanol and acetone, according to the invention fragrances have a molecular weight of 74 to 300 g / mol, contain at least one osmophoric group in the molecule and have a smell and / or taste, that is, they excite the receptors of the hair cells of the olfactory system.

Perfumes, perfume oils, perfume oil components or individual perfume compounds can be used as fragrances. Perfume oils or fragrances can according to the invention individual fragrance compounds, eg. As the synthetic products of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons. Fragrance compounds of the ester type are e.g. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, benzylsalicylate, cyclohexylsalicylate, floramate, melusate and jasmecyclate. The ethers include, for example, benzyl ethyl ether and ambroxane, to the aldehydes e.g. the linear alkanals having 8-18 C atoms, citral, citronellal, citronellyloxyacetaldehyde, cyclamen aldehyde, lilial and bourgeonal, to the ketones e.g. the ionones, alpha-isomethylionone and methylcedryl ketone, the alcohols anethole, citronellol, eugenol, geraniol, linalool, phenylethyl alcohol, alpha-terpineol, beta-terpineol, gamma-terpineol, and delta-terpineol, the hydrocarbons mainly include the terpenes such as limonene and pinas. Preferably, however, mixtures of different fragrances are used, which together produce an attractive fragrance.

Such perfume oils may also contain natural fragrance mixtures such as are available from vegetable sources, e.g. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are Muskateller sage oil, chamomile oil, clove oil, lemon balm oil, mint oil, cinnamon leaf oil, lime blossom oil, juniper berry oil, vetiver oil, olibanum oil, galbanum oil and labdanum oil and orange blossom oil, neroli oil, orange peel oil and sandalwood oil.

In order to be perceptible, a fragrance must be volatile, whereby besides the nature of the functional groups and the structure of the chemical compound, the molecular weight also plays an important role. Thus, most fragrances have molecular weights up to about 200 daltons, while molecular weights of 300 daltons and more of an exception. Due to the different volatility of fragrances, the smell of a perfume or fragrance composed of several fragrances changes during evaporation, whereby the odor impressions in "top note", "middle note or body" and "base note" (end note or dry out). Since the smell perception is based to a large extent on the odor intensity, the top note of a perfume or fragrance does not consist solely of volatile compounds, while the base note for the most part consists of less volatile, ie adherent fragrances. For example, in the composition of perfumes, more volatile fragrances can be bound to certain fixatives, preventing them from evaporating too quickly. In the subsequent classification of the fragrances in "more volatile" or "adherent" fragrances so nothing about the olfactory impression and whether the corresponding fragrance is perceived as a head or middle note, nothing said.

Adhesion-resistant fragrances which can be used in the context of the present invention are, for example, the essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, bergamot oil, Champacablütenöl, Edel fir oil, Edeltannenzapfen oil, Elemiöl, eucalyptus oil, fennel oil, spruce needle oil, galbanum oil, geranium oil, ginger grass oil, Guaiac wood oil, gurdy balm oil, helichrysum oil, ho oil, ginger oil, iris oil, cajeput oil, calamus oil, chamomile oil, camphor oil, kanga oil, cardamom oil, cassia oil, pine oil, copaia balsam oil, coriander oil, spearmint oil, caraway oil, cumin oil, lavender oil, lemongrass oil, lime oil, tangerine oil, lemon balm oil, Musk Grain Oil, Myrrh Oil, Clove Oil, Neroli Oil, Niaouli Oil, Olibanum Oil, Orange Oil, Origanum Oil, Palmarosa Oil, Patchouli Oil, Peru Balsam Oil, Petitgrain Oil, Pepper Oil, Peppermint Oil, Pimento Oil, Pine Oil, Rose Oil, Rosemary Oil, Sandalwood Oil, Celery Oil, Spik Oil, Star Aniseed Oil, Turpentine Oil, Thuja Oil, Thyme oil, verb ena oil, vetiver oil, juniper berry oil, wormwood oil, wintergreen oil, ylang-ylang oil, hyssop oil, cinnamon oil, cinnamon oil, lemon oil, lemon oil and cypress oil. But the higher-boiling or solid fragrances of natural or synthetic origin can be used in the context of the present invention as adherent fragrances or fragrance mixtures, ie fragrances. These compounds include the following compounds and mixtures thereof: ambrettolide, allyl acetate, alpha-amylcinnamaldehyde, anethole, anisaldehyde, anisalcohol, anisole, methyl anthranilate, acetophenone, benzylacetone, benzaldehyde, ethyl benzoate, benzophenone, benzyl alcohol, benzyl acetate, benzyl benzoate, benzyl formate, benzyl valerate , Borneol, bornyl acetate, α-bromostyrene, n-decyl aldehyde, n-dodecyl aldehyde, eugenol, eugenol methyl ether, eucalyptol, farnesol, fenchone, fenchyl acetate, geranyl acetate, geranyl formate, heliotropin, heptincarboxylic acid methyl ester, heptaldehyde, hydroquinone dimethyl ether, hydroxycinnamaldehyde, hydroxycinnamyl alcohol, indole, iron , Isoeugenol, isoeugenol methyl ether, isosafrole, jasmon, camphor, Karvakrol, Karvon, p-cresol methyl ether, coumarin, p-methoxyacetophenone, methyl n-amyl ketone, methyl anthranilate, p-methylacetophenone, methylchavikole, p-methylquinoline, methyl-β-naphthyl ketone, methyl -n-nonylacetaldehyde, methyl-n-nonylketo n, Muskon, beta-naphtholethylether, beta-naphtholmethylether, nerol, nitrobenzene, n-nonylaldehyde, nonylalcohol, n-octylaldehyde, p-oxy-acetophenone, pentadecanolide, beta-phenylethylalcohol, phenylacetaldehyde-dimethylacetal, phenylacetic acid, pulegone, safrole, salicylic acid isoamylester, Salicylic acid methyl ester, salicylic acid hexyl ester, cyclohexyl salicylate, santalol, skatole, alpha-terpineol, beta-terpineol, gamma-terpineol, delta-terpineol, thymes, thymol, gamma undecalactone, vanillin, veratrum aldehyde, cinnamaldehyde, cinnamyl alcohol, cinnamic acid, cinnamic acid ethyl ester, cinnamic acid benzyl ester.

The more volatile fragrances include in particular the lower-boiling fragrances of natural or synthetic origin, which can be used alone or in mixtures. Examples of more readily volatile fragrances are alkyl isothiocyanates (alkyl mustard oils), butanedione, limonene, linalool, linalyl acetate, linalylpropionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal.

Particularly preferred antiperspirant compositions according to the invention are characterized in that at least one perfume component in a total amount of 0.00001 to 10 wt .-%, preferably 0.5-7 wt .-%, particularly preferably 1-5 wt .-%, respectively based on the total composition.

• – Y für eine Cycloalkandiyl-Gruppe mit 6, 5 oder 7 Kohlenstoffatomen steht und
• – die Reste R¹ und R² unabhängig voneinander für eine Gruppierung (G1)
  
  stehen, in der
• – R³ für ein Wasserstoffatom, eine Methyl- oder eine Ethylgruppe steht,
• – p für die Zahl 0, 1, 2, 3, 4 oder 5 steht,
• – R⁴ für ein Wasserstoffatom oder eine Methylgruppe steht, und
• – q für die Zahl 0, 1, 2, 3, 4 oder 5 steht, und

mindestens ein unter Normalbedingungen flüssiges Lösemittel, ausgewählt aus Wasser und einem ein- oder mehrwertigen Alkohol mit 2 bis 20 Kohlenstoffatomen sowie Mischungen dieser Lösemittel, und insgesamt 0,00001 bis 10 Gew.-%, bevorzugt 0,5–7 Gew.-%, besonders bevorzugt 1–5 Gew.-% mindestens eines leichter flüchtigen Riechstoffs, der bevorzugt ausgewählt ist aus Alkylisothiocyanaten (Alkylsenfölen), Butandion, Limonen, Linalool, Linalylacetat, Linalylpropionat, Menthol, Menthon, Methyl-n-heptenon, Phellandren, Phenylacetaldehyd, Terpinylacetat, Zitral, Zitronellal sowie Mischungen dieser Riechstoffe, wobei sich alle Mengenangaben auf das Gesamtgewicht der Antitranspirant-Zusammensetzung beziehen. Further preferred antiperspirant compositions according to the invention comprise at least one aluminum-zirconium compound, at least one compound of the formula R ¹ -YR ² , in which

• Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and
• The radicals R ¹ and R ² independently of one another represent a grouping (G1)
  
  stand in the
• R ^{3 represents} a hydrogen atom, a methyl or an ethyl group,
• P represents the number 0, 1, 2, 3, 4 or 5,
• R ^{4 is} a hydrogen atom or a methyl group, and
• Q represents the number 0, 1, 2, 3, 4 or 5, and

at least one liquid solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and a total of 0.00001 to 10 wt .-%, preferably 0.5-7 wt .-%, more preferably 1-5% by weight of at least one more volatile perfume, which is preferably selected from alkyl isothiocyanates (alkyl mustards), butanedione, limonene, linalool, linalyl acetate, linalylpropionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate , Citral, citronellal and mixtures of these fragrances, all amounts being based on the total weight of the antiperspirant composition.

Further preferred antiperspirant compositions according to the invention contain at least one aluminum-zirconium compound, 0.1 to 50% by weight, preferably 1 to 20% by weight, more preferably 2 to 15% by weight, most preferably 5 to 10% by weight .-%, in each case based on their total weight, of 1,4-bis (hydroxymethyl) cyclohexane, at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, and in total 0.00001 to 10 wt .-%, preferably 0.5-7 wt .-%, particularly preferably 1-5 wt .-% of at least one more volatile fragrance, which is preferably selected from alkyl isothiocyanates (alkyl mustards), butanedione, limonene, Linalool, linalyl acetate, linalylpropionate, menthol, menthone, methyl-n-heptenone, phellandrene, phenylacetaldehyde, terpinyl acetate, citral, citronellal and mixtures of these fragrances, all amounts being based on the total weight d refer to antiperspirant composition.

In a further preferred embodiment, the compositions according to the invention comprise at least one hair growth inhibiting substance. Preferred compositions according to the invention contain at least one hair growth inhibiting substance in a total amount of 0.0001-5 wt .-%, preferably 0.001-2 wt .-%, particularly preferably 0.01-1 wt .-%, and most preferably 0, 1-0.5 wt .-%, each based on the weight of the active substance of the hair growth inhibiting active substance / e and the total weight of the composition according to the invention.

embodiments

The following formulation examples are intended to illustrate the subject matter of the invention without limiting it thereto. Example 1: Antiperspirant stick Wt .-% AAZG 3111 39.0 Diisopropyl sebacate 1.0 Abil B 8851 0.25 1,4-bis (hydroxymethyl) cyclohexane (Eastman Verityl AB-1000 diol) 55.5 Tetrasodium EDTA 0.5 Dibenzylidene sorbitol 1.3 hydroxypropyl 0.3 Perfume 2.15 Example 2: Antiperspirant stick in the form of a water-in-oil emulsion Wt .-% AAZG 3109 61.4 1,4-bis (hydroxymethyl) cyclohexane (Eastman Verityl AB-1000 diol) 12.3 Cyclohexasiloxane (PMX-246) 6.0 Finsolv TN (C12-15 alkyl benzoate) 8.0 Abil EM 90 1.2 Performing 500 10.0 Performa V 343 0.1 Perfume 1.0 Example 3: Clear antiperspirant gel in the form of a water-in-oil emulsion Wt .-% Aluminum Zirconium Octachlorohydrex Gly (AAZG 3109) 55.0 Ethanol (96%) 11.0 water 10.9 Dow Corning 5225 C Formulation Aid 9.0 Xiameter PMX-2127 fluid 7.5 1,4-bis (hydroxymethyl) cyclohexane (Eastman Verityl AB-1000 diol) 6.2 Perfume 0.4 Used raw materials trade name INCI Manufacturer AAZG 3109 Aluminum Zirconium Octachlorohydrex Gly (22 wt.% USP), Glycine (4 wt.%), Sodium Glycinate (5 wt.%), Calcium Chloride (5.1 wt.%), Aqua (ad 100 wt. -%) Summit AAZG 3111 Aluminum Zirconium Tetrachlorohydrex Gly (22 wt.% USP), Aqua (6 wt.%), Glycine (4 wt.%), Sodium Glycinate (5 wt.%), 1,2-Propylene Glycol (ad 100 wt .-%) Summit Abil B 8851 PEG / PPG-14/4 Dimethicone Evonik Abil EM 90 Cetyl PEG / PPG 10/1 Dimethicone Evonik Dow Corning 5225 C Formulation Aid Cyclomethicone / PEG / PPG 18/18 dimethicone (weight ratio 9/1) Dow Corning Finsolv TN C12-15 alkyl benzoate Innospec Performing 500 Polyethylene (molecular weight: 500) New Phase Technologies Performa V 343 Synthetic Wax (Polyalphaolefins) New Phase Technologies PMX-2127 fluid Dimethicones, trisiloxanes (30-60% by weight of polydimethylsiloxanes, 15-40% by weight of decamethyltetrasiloxanes, 15-40% by weight of octamethyltrisiloxanes, 10-30% by weight of dodecamethylpentasiloxanes) Xiameter PMX-246 Cyclohexasiloxane Xiameter

QUOTES INCLUDE IN THE DESCRIPTION

This list of the documents listed by the applicant has been generated automatically and is included solely for the better information of the reader. The list is not part of the German patent or utility model application. The DPMA assumes no liability for any errors or omissions.

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• Kirk-Othmer, "Encyclopedia of Chemical Technology" 3rd ed., 1979, Vol. 8, pp. 913-916 [0098]
• Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd ed., 1979, Vol. 8, page 913 [0111]
• RÖMPP Chemie Lexikon, especially in the online version of November 2003, and the manuals cited under the keyword "HLB system" by Fiedler, Kirk-Othmer and Janistyn [0139]
• H. Janistyn, Handbook of cosmetics and fragrances, Hüthig-Verlag Heidelberg, 3rd edition, 1978, Volume 1, page 470 and Volume 3, pages 68-78 [0140]
• RÖMPP Chemie Lexikon, as of December 2007 [0227]

Claims (13)

An antiperspirant composition comprising a) at least one aluminum-zirconium compound, b) at least one compound of the formula (I), R ¹ -YR ² (I), in which - Y is a cycloalkanediyl group having 6, 5 or 7 carbon atoms and - the radicals R ¹ , R ² are each, independently of one another, a grouping (G ¹ )

in which - R ^{3 is} a hydrogen atom, a methyl or an ethyl group, - p is the number 0, 1, 2, 3, 4 or 5, - R ^{4 is} a hydrogen atom or a methyl group, and q is the number 0, 1, 2, 3, 4 or 5, and c) at least one solvent under normal conditions, selected from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, except the following Compositions A, B, C, D, E and F (all amounts in% by weight): the oil-in-water emulsions A and B: A B ALUMINUM ZIRCONIUM TETRACHLOROHYDREX GLY 23.7 23.7 STEARETH-2 2.4 2.4 STEARETH-21 1.6 1.6 PERFUME 1.2 1.2 PPG-15 STEARYL ETHER 0.5 0.5 ALUMINUM STARCH OCTENYLSUCCINATE 0.1 0.1 TOCOPHERYL ACETATE 0.5 0.5 1,4-cyclohexanedimethanol 5.0 2.0 Water, demineralized ad 100.0 ad 100.0 the sprayable, translucent antiperspirant microemulsions C, D and E: C D e Plantar ^® 1200 1.71 1.71 - Plantar ^® 2000 1.14 1.39 2.40 Glycerol monooleate 0.71 0.71 - dioctyl 4.00 4.00 0.09 octyldodecanol 1.00 1.00 0.02 perfume oil 1.00 1.00 1.00 Aluminum-Zirconium Tetrachlorohydrex Gly 20.0 20.0 20.0 1,4-cyclohexanedimethanol 3.0 5.0 4.0 1,2-propylene glycol 2.0 - - glycerin - - 1.00 phenoxyethanol - 1.0 1.0 water ad 100 ad 100 ad 100 Plantar ^® 1200 LAURYL GLUCOSIDE, approx. 50% active substance Plantar ^® 2000 DECYL GLUCOSIDE, approx. 50% active substance and the water-in-oil emulsion antiperspirant stick F: F Dow Corning 345 Fluid 23.7 Finsolv TN 12.6 isostearyl 11.5 N-Lauroyl-L-glutamic acid di-n-butylamide (GP-1 from Ajinomoto, m.p. 155-163 ° C) 3.8 Abil EM 90 0.95 Aluminum-Zirconium Tetrachlorohydrex Gly 20 Glycerol, 99.5% by weight 5.0 1,4-cyclohexanedimethanol 5.0 water 20.0 Dow Corning 345 Fluid Cyclomethicone (decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane) Finsolv TN C12-15 ALKYL BENZOATE Abil EM 90 Cetyl PEG / PPG-10/1 dimethicone A composition according to claim 1, characterized in that in the formula (I) Y is a 1,2-cyclopentylene, a 1,3-cyclopentylene, a 1,2-cyclohexylene, a 1,3-cyclohexylene or a 1,4-cyclohexylene group and the radicals R ¹ and R ² for identical groups

in which R ³ and R ^{4 are} hydrogen or a methyl group, p is an integer of 1-3 and q is an integer of 0-3. A composition according to claim 1 or 2, characterized in that in the formula (I) - Y is a 1,4-cyclohexylene group and - the radicals R ¹ and R ^{2 are the} same groupings

in which R ^{3 is} hydrogen and p is the numbers 1 to 3. Composition according to Claim 1, 2 or 3, characterized in that it contains as compound of the formula (I) 1,4-bis (hydroxymethyl) cyclohexane (Y = 1,4-cyclohexylene group; R ¹ , R ² = - (CHR ³ ) _p -OH; R ³ = H and p = 1). Composition according to Claim 1, 2, 3 or 4, characterized in that the compound (s) of the formula (I), in particular the 1,4-bis (hydroxymethyl) cyclohexane, are present as a cis / trans isomer mixture. A composition according to claim 1, 2, 3, 4 or 5, characterized in that, based on their total weight, a total of 0.1 to 50 wt .-%, preferably 1-20 wt .-%, particularly preferably 2-15 wt. -%, most preferably 5-10 wt .-%, of at least one compound of formula (I), which is preferably selected from 1,4-bis (hydroxymethyl) cyclohexane, is included. A composition according to claim 1, 2, 3, 4, 5 or 6, characterized in that the at least one aluminum-zirconium compound in a total amount of 5-40 wt .-%, preferably 10-35 wt .-%, particularly preferably 15-28 wt .-%, and most preferably 23-27 wt .-%, based on the total weight of the water-free active substance (USP) in the total composition. A composition according to claim 1, 2, 3, 4, 5, 6 or 7, characterized in that a total of 1-40 wt .-%, preferably 7-20 wt .-%, of at least one cosmetic oil selected from esters of linear or branched saturated or unsaturated fatty alcohols having 6-22 carbon atoms with benzoic acid, branched saturated or unsaturated fatty alcohols having 6-30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ alkanols, addition products of 1 to 5 propylene oxide units of monovalent or polyvalent C _8-22 alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units of mono- or polyhydric C _3-22 alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamet hylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ further selected from linear dimethylpolysiloxanes having kinematic viscosities in the range of 5-100 cSt, kinematic viscosity values relating to a temperature of 25 ° C, C ₈ -C ₁₆ isoalkanes, C ₁₀ -C ₁₃ isoalkanes, isohexadecane , Isoeicosan, polyisobutenes, hydrogenated polyisobutenes and polydecenes, as well as mixtures of the aforementioned oils, wherein the amounts are in each case based on the total weight of the antiperspirant composition. Composition according to one of claims 1, 2, 3, 4, 5, 6, 7 or 8, characterized in that at least one wax component with a melting point> 50 ° C in a total amount of 4-18 wt .-%, preferably 6- 15 wt .-%, particularly preferably 8-13 wt .-%, most preferably 9-11 wt .-%, each based on the total composition, is included, wherein linear alkanols having a melting point> 50 ° C does not count to the wax components , Composition according to any one of Claims 1, 2, 3, 4, 5, 6, 7, 8 or 9, characterized in that it is in the form of a stick-type water-in-oil emulsion containing at least one liquid solvent under normal conditions selected from Water and a monohydric or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, in a total amount of 0.5-70 wt .-%, particularly preferably 5-60 wt .-%, preferably extraordinarily 10-50 wt. more preferably 20-35% by weight, furthermore at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier in a total amount of 0.5-5% by weight, particularly preferably 1.0-3.5% by weight, exceptionally preferably 1.2-3% by weight, furthermore a total of 1-40% by weight, preferably 7-20% by weight, of at least one cosmetic oil, selected from C ₁₀ -C ₁₃ -Isoalkanen, cyclomethicones, linear dimethylpolysiloxanes having kinematic viscosities in the range of 0.5 100 cSt (25 ° C) and esters selected from C12-15 alkyl benzoate, hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, Isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, furthermore at least one wax component with a melting point> 50 ° C., selected from polyethylene waxes having a molecular weight of 400-3000, particularly preferably having a molecular weight of 500-600, in a total amount of 4-18% by weight, preferably 6-15% by weight, particularly preferably 8-13% by weight. %, most preferably 9-11 wt .-%, wherein the amounts given in each case on the total weight of Antiperspirant composition are related. Composition according to any one of Claims 1, 2, 3, 4, 5, 6, 7, 8 or 9, characterized in that the silicone-based water-in-oil emulsifier is cetyl PEG / PPG-10/1 dimethicone. Composition according to any one of Claims 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10, characterized in that it is in the form of a water-in-oil emulsion and at least one solvent which is liquid under normal conditions from water and a mono- or polyhydric alcohol having 2 to 20 carbon atoms and mixtures of these solvents, in a total amount of 0.5-70 wt .-%, particularly preferably 5-60 wt .-%, preferably extraordinarily 10-50 wt. more preferably 20-35% by weight, a silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones in a total amount of 0.5-5% by weight, especially preferably 1.0-3.5 wt .-%, most preferably 1.2-3 wt .-%, and a total of 1-40 wt .-%, preferably 7-20 wt .-%, selected from at least one cosmetic oil from esters of linear or branched saturated or unsaturated fatty alcohols with benzoic acid, branched saturated or unsaturated fatty alcohol en with 6-30 carbon atoms, dicarboxylic acid esters of linear or branched C ₂ -C ₁₀ -alkanols, addition products of 1 to 5 propylene oxide units of mono- or polyhydric C _8-22 -alkanols, adducts of at least 6 ethylene oxide and / or propylene oxide Units of mono- or polyhydric C _3-22 -alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2-30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, Decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L ₂ ), octamethyltrisiloxane (L ₃ ), decamethyltetrasiloxane (L ₄ ), dodecamethylpentasiloxane (L ₅ ), as well as any two, three and four mixtures of L ₂ , L ₃ , L ₄ and / or L ₅ further selected from linear dimethyl polysiloxanes having kinematic viscosities in the range of 5-1 00 cSt, wherein the values of the kinematic viscosity relate to a temperature of 25 ° C, C ₈ -C ₁₆ isoalkanes, C ₁₀ -C ₁₃ isoalkanes, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and mixtures of the aforementioned Oils, wherein the amounts are each based on the total weight of the antiperspirant composition. A composition according to any one of claims 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12, characterized in that the cosmetic oil is selected from C12-C15 alkyl benzoate.