DE102004034269A1 - Producing a channeled substrate for a catalytic converter or particulate filter for a motor vehicle engine comprises building up the substrate by screen printing - Google Patents
Producing a channeled substrate for a catalytic converter or particulate filter for a motor vehicle engine comprises building up the substrate by screen printing Download PDFInfo
- Publication number
- DE102004034269A1 DE102004034269A1 DE102004034269A DE102004034269A DE102004034269A1 DE 102004034269 A1 DE102004034269 A1 DE 102004034269A1 DE 102004034269 A DE102004034269 A DE 102004034269A DE 102004034269 A DE102004034269 A DE 102004034269A DE 102004034269 A1 DE102004034269 A1 DE 102004034269A1
- Authority
- DE
- Germany
- Prior art keywords
- substrate
- screen printing
- screen
- exhaust gas
- mask
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000758 substrate Substances 0.000 title claims abstract description 56
- 238000007650 screen-printing Methods 0.000 title claims abstract description 30
- 230000003197 catalytic effect Effects 0.000 title claims abstract description 7
- 238000000034 method Methods 0.000 claims description 20
- 239000003054 catalyst Substances 0.000 claims description 10
- 238000002485 combustion reaction Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- 238000003825 pressing Methods 0.000 claims description 4
- 229910010293 ceramic material Inorganic materials 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 239000000835 fiber Substances 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 108091006146 Channels Proteins 0.000 description 17
- 238000001125 extrusion Methods 0.000 description 3
- 238000005096 rolling process Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
Classifications
-
- B01J35/56—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C64/00—Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
- B29C64/10—Processes of additive manufacturing
- B29C64/141—Processes of additive manufacturing using only solid materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/12—Stencil printing; Silk-screen printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M3/00—Printing processes to produce particular kinds of printed work, e.g. patterns
Abstract
Description
Die Erfindung betrifft ein Verfahren zur Herstellung eines Substrats für einen Katalysator und/oder einen Partikelfilter gemäß dem Oberbegriff des Anspruchs 1, ein durch ein derartiges Verfahren hergestelltes Substrat gemäß dem Oberbegriff des Anspruch 9, sowie einen ein derartiges Substrat aufweisender Katalysator und/oder Partikelfilter gemäß dem Oberbegriff des Anspruchs 12.The The invention relates to a method for producing a substrate for one Catalyst and / or a particulate filter according to the preamble of the claim 1, a substrate produced by such a method according to the preamble of claim 9, as well as having such a substrate Catalyst and / or particle filter according to the preamble of the claim 12th
Katalysatoren und/oder Partikelfilter werden zur Abgasreinigung insbesondere für mager betreibbare Otto-Brennkraftmaschinen und Diesel-Brennkraftmaschinen benötigt und eingesetzt. Dabei weisen derartige Katalysatoren ein Substrat auf, das mit einer geeigneten katalytischen Beschichtung zur Umwandlung, Speicherung und Reinigung der vorhandenen Abgaskomponenten versehen ist. Ein derartiges Substrat, das auch als Monolith bezeichnet wird, ist in Durchströmrichtung des Abgases von einer Vielzahl von Kanälen durchzogen. Im Fall eines Partikelfilters sind die Wände der Kanäle porös und die Kanäle sind wechselseitig verschlossen, so dass das Abgas gezwungen ist, die porösen Wände zu durchqueren, wodurch die Filterwirkung hinsichtlich der Abgaspartikel hervorgerufen wird. Ferner sind im Fall des Partikelfilters auch katalytische Beschichtungen je nach Einsatzzweck auf und/oder in den Kanalwänden angeordnet.catalysts and / or particulate filters are used for emission control, especially for lean Operable Otto internal combustion engines and diesel internal combustion engines needed and used. Such catalysts have a substrate which, with a suitable catalytic coating for conversion, Storage and cleaning provided the existing exhaust gas components is. Such a substrate, which is also called a monolith, is in the flow direction of the exhaust gas traversed by a plurality of channels. In the case of a particulate filter are the walls of the channels porous and the channels are mutually closed so that the exhaust gas is forced the porous ones To cross walls whereby the filter effect with respect to the exhaust particles caused becomes. Furthermore, in the case of the particulate filter are also catalytic Depending on the application, coatings are arranged on and / or in the channel walls.
Derartige, von Kanälen durchzogene Substrate für Katalysatoren und Partikelfilter werden vorwiegend mittels Extrusions-Strangpressen hergestellt, wie dies beispielsweise in der DE-A-4215481 beschrieben ist. Eine katalytisch aktive keramische Masse wird darin zu einem mit wabenförmigen Kanälen mit vorgegebener Wanddicke durchzogenen Substrat extrudiert. Nachteilig dabei ist, dass die Querschnittsform der wabenförmigen Kanäle über deren Länge bei der Herstellung mittels eines Extrusionsverfahren nicht geändert werden kann. Durch diese gleichmäßige Wabenform der Kanäle stellt sich bei der Durchströmung des Substrats mit dem zu reinigenden Abgas sehr schnell eine laminare Strömung ein, welche die Konvertierung des Abgases an dem auf den Wänden des Substrats aufgebrachten Washcoat behindert.such, of channels crossed substrates for Catalysts and particle filters are predominantly produced by extrusion extrusion prepared, as described for example in DE-A-4215481 is. A catalytically active ceramic composition becomes a with honeycomb channels Extruded with predetermined wall thickness substrate extruded. adversely it is that the cross-sectional shape of the honeycomb channels over the length in the preparation by means of an extrusion process can not be changed. Due to this uniform honeycomb shape of the channels turns on the flow the substrate with the exhaust gas to be cleaned very quickly a laminar Flow, which the conversion of the exhaust gas to the on the walls of the Substrate applied Washcoat impeded.
Der Erfindung liegt daher die Aufgabe zugrunde, ein Verfahren zur Herstellung eines mit Kanälen durchzogenen Substrats zur Verwendung in einem Katalysator und/oder einem Partikelfilter zu schaffen, bei dem die Querschnittsform der Kanäle veränderbar ist. Ferner liegt der Erfindung die Aufgabe zugrunde, ein mit Kanälen durchzogenes Substrat der gattungsgemäßen Art mit variabler Querschnittsform zu schaffen.Of the The invention is therefore based on the object, a process for the preparation one with channels solid substrate for use in a catalyst and / or to provide a particulate filter, wherein the cross-sectional shape of the Channels changeable is. Further, the invention has the object, a traversed with channels Substrate of the generic type to provide variable cross-sectional shape.
Die Aufgabe wird durch ein Verfahren mit den Merkmalen des Anspruchs 1 und durch ein Substrat mit den Merkmalen des Anspruchs 9 gelöst. Bevorzugte Ausführungsformen der Erfindung sind Gegenstand der Unteransprüche.The The object is achieved by a method having the features of the claim 1 and solved by a substrate having the features of claim 9. preferred embodiments The invention are the subject of the dependent claims.
Bei dem erfindungsgemäßen Verfahren zur Herstellung eines Substrats für einen Katalysator oder einen Partikelfilter einer Brennkraftmaschine eines Kraftfahrzeugs, das in Strömungsrichtung des Abgases mit Kanälen durchzogen ist, wird das Substrat mittels eines Siebdruckverfahrens aufgebaut.at the method according to the invention for producing a substrate for a catalyst or a Particulate filter of an internal combustion engine of a motor vehicle, the in the flow direction the exhaust gas with channels is traversed, the substrate by means of a screen printing process built up.
Insbesondere wird das Substrat durch Hintereinanderausführung einer Vielzahl n, n>1, von Siebdruckschritten aufgebaut, wobei jeder Siebdruckschritt eine Siebdruckschicht des Substarts bildet.Especially is the substrate by successively performing a plurality n, n> 1, of screen printing steps constructed, each Siebdruckschritt a screen printing layer of the Substarts forms.
Vorzugsweise werden eine veränderliche Siebdruckmaske und/oder unterschiedliche Siebdruckmasken zur Erstellung der jeweiligen Siebdruckschicht verwendet.Preferably become a variable screenprint mask and / or different screen printing masks for creating the respective Screen printing layer used.
Insbesondere besteht der i-te Siebdruckschritt, i = 1...n, aus der Vielzahl n der Siebdruckschritte aus den folgenden Schritten:
- a) Anordnen einer Siebdruckmaske auf oder über einem durch die (i-1)-Siebdruckschritten gebildeten Substratblock,
- b) Füllen der Siebdruckmaske mit dem Substratmaterial, und
- c) Andrücken der gefüllten Siebdruckmaske auf dem Substratblock, wodurch die i-te Substratschicht auf dem Substratblock aufgetragen wird
- a) arranging a screen-printing mask on or above a substrate block formed by the (i-1) screen printing steps,
- b) filling the screen mask with the substrate material, and
- c) pressing the filled screen mask on the substrate block, whereby the i-th substrate layer is applied to the substrate block
Vorzugsweise ist der durch das erfindungsgemäße Verfahren erzeugte Substratblock auf einer höhenverstellbaren Plattform angeordnet, die nach dem Andrücken der i-ten Schicht, i = 1...n, um eine Schichtdicke nach unten bewegt wird.Preferably is the by the inventive method generated substrate block on a height-adjustable platform arranged after pressing the i-th layer, i = 1 ... n, moves down by one layer thickness becomes.
Wie bereits oben erwähnt, wird vorzugsweise eine Vielzahl unterschiedlicher Siebdruckmasken verwendet, die insbesondere auf einer Rolle angeordnet sein können.As already mentioned above, a variety of different screen masks is preferably used, which can be arranged in particular on a roll.
Vorzugsweise wird als Substratmaterial ein für den Siebdruck geeignetes keramisches Material und/oder Komposit-Fasern verwendet.Preferably is used as a substrate material for the screen printing suitable ceramic material and / or composite fibers used.
Ein erfindungsgemäßes Substrat, auch als Monolith bezeichnet, für einen Katalysator oder einen Partikelfilter einer Brennkraftmaschine eines Kraftfahrzeugs, das durch das im vorangegangenen beschriebene Verfahren hergestellt ist, ist in Strömungsrichtung des Abgases mit Kanälen durchzogen, wobei die Querschnittsform eines Kanals eine Funktion des Ortes in Substratdurchströmrichtung ist.An inventive substrate, also referred to as a monolith, for a catalyst or a particulate filter of an internal combustion engine of a motor vehicle, which is produced by the method described above, is durchzo in the flow direction of the exhaust gas with channels gene, wherein the cross-sectional shape of a channel is a function of the location in the substrate flow direction.
Dabei ist vorzugsweise die Änderung der Querschnittsform eines Kanals als Funktion des Ortes in Durchströmrichtung des Abgases in geeigneter Weise zur Erhöhung von Strömungsturbulenzen des Abgases ausgelegt, beispielsweise in dem die Kanäle einen oder mehrere Flaps oder Vorsprünge aufweisen, durch welche die Turbulenz im Kanal erhöht wird, so dass eine laminare Strömung vermieden wird.there is preferably the change the cross-sectional shape of a channel as a function of location in the direction of flow the exhaust gas suitably to increase flow turbulence designed the exhaust gas, for example, in which the channels a or more flaps or protrusions by which the turbulence in the channel is increased, so that a laminar flow is avoided.
Ein erfindungsgemäßer Katalysator und/oder Partikelfilter mit einem oben beschriebenen Substrat weist ein Gehäuse auf, in dem das Substrat angeordnet ist.One Inventive catalyst and / or Particulate filter with a substrate described above has a housing, in which the substrate is arranged.
Eine bevorzugte Ausführungsform de Erfindung wird nachfolgend anhand der Zeichnung erläutert.A preferred embodiment de invention will be explained below with reference to the drawing.
- 11
- Substratsubstratum
- 22
- Plattformplatform
- 33
- Siebdruckmaskescreen printing mask
- 44
- Andruckrollepinch
- 55
- Maskenbahnmask train
- 66
- Rollerole
- 77
- Rollvorrichtungrolling device
- 88th
- Rollvorrichtungrolling device
Claims (12)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004034269A DE102004034269A1 (en) | 2004-07-15 | 2004-07-15 | Producing a channeled substrate for a catalytic converter or particulate filter for a motor vehicle engine comprises building up the substrate by screen printing |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102004034269A DE102004034269A1 (en) | 2004-07-15 | 2004-07-15 | Producing a channeled substrate for a catalytic converter or particulate filter for a motor vehicle engine comprises building up the substrate by screen printing |
Publications (1)
Publication Number | Publication Date |
---|---|
DE102004034269A1 true DE102004034269A1 (en) | 2006-02-09 |
Family
ID=35612862
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE102004034269A Withdrawn DE102004034269A1 (en) | 2004-07-15 | 2004-07-15 | Producing a channeled substrate for a catalytic converter or particulate filter for a motor vehicle engine comprises building up the substrate by screen printing |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE102004034269A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2711163A1 (en) * | 2012-09-21 | 2014-03-26 | Hirschberg Engineering | Three-dimensional body |
CN106795794A (en) * | 2014-09-08 | 2017-05-31 | 大陆汽车有限责任公司 | Particulate filter and the method for manufacturing particulate filter |
US11065601B2 (en) | 2015-12-18 | 2021-07-20 | University Of Canterbury | Separation medium |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5059266A (en) * | 1989-05-23 | 1991-10-22 | Brother Kogyo Kabushiki Kaisha | Apparatus and method for forming three-dimensional article |
DE4205969A1 (en) * | 1992-02-27 | 1993-09-02 | Merck Patent Gmbh | METHOD FOR PRODUCING MOLDED BODIES WITH A PRE-DETERMINED PORE STRUCTURE |
DE69906772T2 (en) * | 1998-10-09 | 2004-03-11 | Motorola, Inc., Schaumburg | Process for the production of integrated multilayer microfluidic components |
-
2004
- 2004-07-15 DE DE102004034269A patent/DE102004034269A1/en not_active Withdrawn
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5059266A (en) * | 1989-05-23 | 1991-10-22 | Brother Kogyo Kabushiki Kaisha | Apparatus and method for forming three-dimensional article |
DE4205969A1 (en) * | 1992-02-27 | 1993-09-02 | Merck Patent Gmbh | METHOD FOR PRODUCING MOLDED BODIES WITH A PRE-DETERMINED PORE STRUCTURE |
DE69906772T2 (en) * | 1998-10-09 | 2004-03-11 | Motorola, Inc., Schaumburg | Process for the production of integrated multilayer microfluidic components |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2711163A1 (en) * | 2012-09-21 | 2014-03-26 | Hirschberg Engineering | Three-dimensional body |
WO2014043823A1 (en) * | 2012-09-21 | 2014-03-27 | Hirschberg Engineering | Three-dimensional moulding |
US10533807B2 (en) | 2012-09-21 | 2020-01-14 | Hirschberg Engineering | Three-dimensional moulding |
CN106795794A (en) * | 2014-09-08 | 2017-05-31 | 大陆汽车有限责任公司 | Particulate filter and the method for manufacturing particulate filter |
US20170284248A1 (en) * | 2014-09-08 | 2017-10-05 | Continental Automotive Gmbh | Particle filter and method for producing a particle filter |
US11065601B2 (en) | 2015-12-18 | 2021-07-20 | University Of Canterbury | Separation medium |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP3003537B1 (en) | Method for reducing harmful exhaust components from petrol engines | |
EP2038046B1 (en) | Two-layered three-way catalyst and its use | |
EP2322773B1 (en) | Method for cleaning combustion engine exhaust gases | |
DE69635641T2 (en) | Process for cleaning engine exhaust | |
DE102011050788A1 (en) | Exhaust gas aftertreatment device and method for a gasoline engine | |
DE602004011971T2 (en) | hONEYCOMB STRUCTURE | |
EP2247385B1 (en) | Method for coating a diesel particle filter and diesel particle filters produced thereby | |
DE102004040549A1 (en) | Catalytically coated particle filter and process for its preparation and its use | |
DE102014215112A1 (en) | Process for preparing a catalyst and catalyst articles | |
DE10238770A1 (en) | Device for removing soot particles from the exhaust gas of a diesel engine | |
DE102009051234A1 (en) | exhaust gas cleaning systems | |
EP1433519B1 (en) | Method for producing a particle filter with NOx storage function | |
EP2059660A1 (en) | Filter for removing particles from a gas stream and method for producing said filter | |
DE102019209304B4 (en) | Device for exhaust aftertreatment | |
EP1882090B1 (en) | Exhaust system with two exhaust treatment units | |
DE112013006485T5 (en) | Catalytic converter | |
EP1984607A1 (en) | Catalytic converter with improved start-up behaviour | |
DE102004034269A1 (en) | Producing a channeled substrate for a catalytic converter or particulate filter for a motor vehicle engine comprises building up the substrate by screen printing | |
DE102021100520A1 (en) | EXHAUST GAS PURIFICATION DEVICE | |
WO2006100090A1 (en) | Exhaust system with an exhaust gas treatment unit and a heat exchanger in an exhaust recycle line | |
DE19961483B4 (en) | Cleaning catalyst for the exhaust gas of an internal combustion engine | |
DE19912846A1 (en) | Catalyst body with a reduced wall thickness on the upstream side | |
DE102008004827B4 (en) | Catalytic converter optimization | |
DE202009018901U1 (en) | Catalytically active particulate filter for cleaning exhaust gases from internal combustion engines | |
EP1048828B1 (en) | Catalytic converter |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
OM8 | Search report available as to paragraph 43 lit. 1 sentence 1 patent law | ||
R005 | Application deemed withdrawn due to failure to request examination |
Effective date: 20110716 |