DE01908636T1 - Beschichtung mit makroskopischer textur sowie verfahren zu deren herstellung - Google Patents

Beschichtung mit makroskopischer textur sowie verfahren zu deren herstellung Download PDF

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Publication number
DE01908636T1
DE01908636T1 DE01908636T DE01908636T DE01908636T1 DE 01908636 T1 DE01908636 T1 DE 01908636T1 DE 01908636 T DE01908636 T DE 01908636T DE 01908636 T DE01908636 T DE 01908636T DE 01908636 T1 DE01908636 T1 DE 01908636T1
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DE
Germany
Prior art keywords
coating
substrate
coating mixture
hardened
mixture according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE01908636T
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English (en)
Inventor
C. Richard MACQUEEN
J. Loyd BURCHAM
A. Anthony PARKER
A. Deborah SCIANGOLA
B. Donald HENRY
C. Donald FERGUSON
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Congoleum Corp
Original Assignee
Congoleum Corp
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Publication date
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First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=23943778&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=DE01908636(T1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Congoleum Corp filed Critical Congoleum Corp
Publication of DE01908636T1 publication Critical patent/DE01908636T1/de
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • B05D5/02—Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures to obtain a matt or rough surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B44—DECORATIVE ARTS
    • B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C3/00—Processes, not specifically provided for elsewhere, for producing ornamental structures
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/244—Stepwise homogeneous crosslinking of one polymer with one crosslinking system, e.g. partial curing
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C09D133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/28—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes for wrinkle, crackle, orange-peel, or similar decorative effects
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/43—Thickening agents
    • C09D7/44—Combinations of two or more thickening agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/66—Additives characterised by particle size
    • C09D7/67—Particle size smaller than 100 nm
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
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    • C09D7/69—Particle size larger than 1000 nm
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
    • D06N3/08—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products with a finishing layer consisting of polyacrylates, polyamides or polyurethanes or polyester
    • E—FIXED CONSTRUCTIONS
    • E04—BUILDING
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    • E04F15/00—Flooring
    • E04F15/02—Flooring or floor layers composed of a number of similar elements
    • E04F15/02172—Floor elements with an anti-skid main surface, other than with grooves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/06—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation
    • B05D3/061—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by exposure to radiation using U.V.
    • B05D3/065—After-treatment
    • B05D3/067—Curing or cross-linking the coating
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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    • Y10T428/3192—Next to vinyl or vinylidene chloride polymer

Abstract

Vorgehärtetes Beschichtungsgemisch, umfassend:
ein härtbares Harz; und
einen Initiator;
wobei das strahlungshärtbare Harz und der Initiator ein vorgehärtetes Beschichtungsgemisch bilden, welches geeignet ist, bei Aufbringen des Gemischs auf ein Substrat eine makroskopische Textur zu bilden.

Claims (20)

  1. Vorgehärtetes Beschichtungsgemisch, umfassend: ein härtbares Harz; und einen Initiator; wobei das strahlungshärtbare Harz und der Initiator ein vorgehärtetes Beschichtungsgemisch bilden, welches geeignet ist, bei Aufbringen des Gemischs auf ein Substrat eine makroskopische Textur zu bilden.
  2. Vorgehärtetes Beschichtungsgemisch gemäß Anspruch 1, wobei das härtbare Harz ein strahlungshärtbares Harz ist.
  3. Vorgehärtetes Beschichtungsgemisch gemäß Anspruch 2, wobei das vorgehärtete Beschichtungsgemisch eine zur Bildung der makroskopischen Textur wirksame Viskosität aufweist.
  4. Vorgehärtetes Beschichtungsgemisch gemäß Anspruch 1, ferner umfassend ein Rheologie-Einstellmittel und wobei das härtbare Harz, der Initiator und das Rheologie-Einstellmittel das vorgehärtete Beschichtungsgemisch bilden.
  5. Vorgehärtetes Beschichtungsgemisch gemäß Anspruch 4, wobei das Rheologie-Einstellmittel ausgewählt ist aus der Gruppe bestehend aus anorganischen Partikeln, organischen Feststoffen und Gemischen davon.
  6. Vorgehärtetes Beschichtungsgemisch gemäß Anspruch 5, wobei die anorganischen Partikel ausgewählt sind aus der Gruppe bestehend aus Aluminiumoxid, Siliziumdioxid, pyrogenem Aluminiumoxid, pyrogenem Siliziumdioxid, Alumosilikat, mit Aluminiumoxid beschichtetem Siliziumdioxid, Metalloxiden, Metall, Carbonaten, Tonen und Gemischen davon.
  7. Vorgehärtetes Beschichtungsgemisch gemäß Anspruch 6, wobei die anorganischen Partikel eine ungefähre Größe im Bereich von 27 bis 56 Nanometern haben.
  8. Vorgehärtetes Beschichtungsgemisch gemäß Anspruch 5, wobei die anorganischen Partikel Aluminiumoxidpartikel von Nanometer-Größe sind.
  9. Vorgehärtetes Beschichtungsgemisch gemäß Anspruch 5, wobei die anorganischen Partikel ungefähr 1 bis 80 Gewichtsprozent des Beschichtungsgemischs umfassen.
  10. Vorgehärtetes Beschichtungsgemisch gemäß Anspruch 5, wobei die organischen Feststoffe ausgewählt sind aus der Gruppe bestehend aus Wachsen niederen Molekulargewichts, Polymeren von Ethylenglykol, Polymeren von Propylenglykol, natürlichen Polymeren, Polyamiden, Polypropylen und Gemischen davon.
  11. Vorgehärtetes Beschichtungsgemisch gemäß Anspruch 5, wobei die organischen Feststoffe ungefähr 1 bis 50 Gewichtsprozent des Beschichtungsgemischs umfassen.
  12. Beschichtetes Substrat, umfassend: ein Substrat; und eine gehärtete Beschichtung auf wenigstens einem Abschnitt des Substrats, wobei die Beschichtung eine inhärente makroskopische Textur umfasst.
  13. Beschichtetes Substrat gemäß Anspruch 12, wobei die Beschichtung ein strahlungsgehärtetes Harz umfasst.
  14. Beschichtetes Substrat gemäß Anspruch 12, wobei die Beschichtung ferner ein Rheologie-Einstellmittel umfasst.
  15. Beschichtetes Substrat gemäß Anspruch 14, wobei das Rheologie-Einstellmittel ausgewählt ist aus der Gruppe bestehend aus anorganischen Partikeln, organischen Feststoffen und Gemischen davon.
  16. Beschichtetes Substrat gemäß Anspruch 12, ferner umfassend: ein Mattierungmittel, welches 5 Mikron große Nylon-Partikel umfasst; mehrere Textur-erzeugende Partikel, umfassend 60 Mikron große Nylon-12-Partikel; ein Rheologie-Einstellmittel, umfassend mehrere Aluminiumoxid-Partikel mit einer Partikelgrößenverteilung im Bereich von 27 bis 56 Nanometern; einen Haftvermittler, umfassend vor-hydrolisiertes Silan; und wobei das Harz ein Gemisch von Urethanacrylat, ethoxyliertem Diacrylat, propoxyliertem Diacrylat, ethoxyliertem Trimethylolpropantriacrylat und Acylphosphinoxid umfasst.
  17. Beschichtetes Substrat gemäß Anspruch 12, wobei das Substrat ein Polyvinylchlorid-Substrat ist und die gehärtete Beschichtung eine strahlungsgehärtete Beschichtung auf wenigstens einem Abschnitt des Polyvinylchlorid-Substrats ist.
  18. Beschichtetes Substrat gemäß Anspruch 17, wobei das Polyvinylchlorid-Substrat Polyvinylchloridplastisol umfasst.
  19. Beschichtetes Substrat gemäß Anspruch 18, ferner umfassend: eine Filzschicht; eine Gelschicht mit einer Gelschichtunterseite, die auf der Filzschicht angeordnet ist; eine Druckschicht, welche auf einer Gelschichtoberseite der Gelschicht angeordnet ist; wobei eine Unterseite des Polyvinylchlorid-Substrats auf der Druckschicht angeordnet ist; und die strahlungsgehärtete Beschichtung auf einer Oberseite des Polyvinylchlorid-Substrats angeordnet ist.
  20. Verfahren zum Herstellen einer Beschichtung auf einem Substrat, umfassend die folgenden Schritte: Verteilen eines vorgehärteten Beschichtungsgemischs, welches ein strahlungshärtbares Harz und einen Initiator umfasst, auf wenigstens einem Abschnitt eines Substrats, um eine vorgehärtete Beschichtung zu bilden, die eine inhärente makroskopische Textur aufweist; und Härten der vorgehärteten Beschichtung, um eine gehärtete Beschichtung mit der makroskopischen Textur zu bilden.
DE01908636T 2000-01-21 2001-01-19 Beschichtung mit makroskopischer textur sowie verfahren zu deren herstellung Pending DE01908636T1 (de)

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US09/489,420 US6399670B1 (en) 2000-01-21 2000-01-21 Coating having macroscopic texture and process for making same
PCT/US2001/001805 WO2001053387A1 (en) 2000-01-21 2001-01-19 Coating having macroscopic texture and process for making same

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US20010038910A1 (en) 2001-11-08
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US20030180558A1 (en) 2003-09-25
CA2398746A1 (en) 2001-07-26
US20050009943A1 (en) 2005-01-13
AU2001236483A1 (en) 2001-07-31
US6790512B2 (en) 2004-09-14
US20080113182A1 (en) 2008-05-15
US6730388B2 (en) 2004-05-04

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