High-brightness nitride LED generating white light and preparation method thereof
Technical field: the present invention relates to a kind of high-brightness nitride LED generating white light and preparation method thereof.
Background technology: at present, the research and development of various light sources all develop to the energy-saving and environmental protection direction, though the electricity-saving lamp comparison energy savings of some fluorescence classes, useful life is shorter, and are making and contaminated environment when discarded.Generally the light-emitting diode of Shi Yonging has power saving, environmental protection, long service life, reliability advantages of higher, but generally can only send brightness lower red, yellow, blue light, is not suitable as light source and uses.White light-emitting diode is rarely found, and main cause is owing to its manufacturing process complexity, and the photochromic very difficult control of white light.The manufacture method of white light-emitting diode mainly contains:
One, utilize the chip of luminescent tube of multiple color to be combined into the white-light emitting pipe.
The luminescence chip of three kinds of colors of red, green, blue (or yellow, blue two kinds of colors) is contained in the light-emitting diode simultaneously, and the electric current of controlling respectively by each luminescence chip can produce white light.But voltage that the luminescence chip of different colours is required and the electric current that passes through are had nothing in common with each other, and control is difficulty comparatively, and white light colourity is also inhomogeneous; And, then can't obtain white light if one of them breaks down; In addition, use a plurality of chips simultaneously, cost also can increase, and is very unfavorable to practical application,
Two, the blue-light excited fluorescent material that can send sodium yellow that utilizes the nitride light-emitting chip to produce, the two can obtain white light after mixing.As:
1, the white light-emitting diodes (Japanese patent application publication No.: special flat 7--99345), mainly be to be filled in after fluorescent material and the mixed with resin in the V-type groove of the electrode suppor that is placed with luminescence chip of Ri Ya chemical company release.If luminescence chip is yellow for emission blue light, the fluorescent material of fluorescence resin, but then blue and yellow synthesize white light.
2, (Chinese patent application number: 97227697.1) be attached on the luminescence chip by proper proportion mixing preparation and drop with fluorescent material and liquid (as alcohol or water and a small amount of adhering liquid) on the blue led chips, luminescent powder can even mixed flow and be attached to luminescence chip the surface and around, treat after the solution evaporation, can form a phosphor laminate thin film that is coated on luminescence chip.
3, (Chinese patent application number: 00237186.3), be that coating one deck wavelength is the gold-tinted fluorescence coating (being mixed by epoxy resin and yttrium aluminate cerium or zinc-cadmium sulfide silver) of 530 nanometers on the gallium nitride blue chip of 430-470 nanometer at wavelength, the two forms white light.
The advantage of said method (1,2,3) is: manufacture craft and design of drive circuit are simple, power consumption is low, and production cost is lower, so adopt this legal system to make the white-light emitting pipe at present mostly;
Shortcoming is: 1, the fluorescent material coating is insecure also inhomogeneous, and fluorescent material distributes more around the luminescence chip, when the white light that causes this product to send is projeced on the white paper, can see that the yellow ring of light that has of the white point of throwing produces all around, illustrate that the purity of white light is not enough; 2, compare with the white-light emitting pipe that multi-color LED is combined into, brightness reduces.3, fluorescent material is owing to directly contact with tube core, and tube core when luminous temperature higher, can make the fluorescent material degeneration, generation optical maser wavelength moves, finally efficient, the color of white light-emitting diodes can change.
Summary of the invention:
The object of the present invention is to provide a kind of high-brightness nitride LED generating white light and preparation method thereof, improve luminous uniformity and stability; Strengthen the luminous intensity of white light-emitting diodes.
High-brightness nitride LED generating white light of the present invention comprises chip, spun gold, and transparent resin, chip are the iii-nitride light emitting devices chip; Transparent resin applies and is solidificated on iii-nitride light emitting devices chip and the spun gold, is the spherical crown shape; The mixture of fluorescent material and transparent resin is coated on the spherical crown shape transparent resin as fluorescence coating; Chip emission light is white light after passing fluorescence coating; Outer with the conventional encapsulation of transparent resin.
Described iii-nitride light emitting devices chip is selected from blue light, purple light or ultraviolet light chip.Fluorescent material is yellow fluorescent powder, is selected from cerium-doped yttrium aluminum garnet fluorescent powder or other yellow fluorescent powders or combination.
Thickness 0.02~the 0.8mm of fluorescence coating, the height 0.01~2mm of spherical crown, fluorescent material weight accounts for 45%-55% in the mixture of fluorescent material and transparent resin.
The method of the above-mentioned high-brightness nitride LED generating white light of preparation of the present invention, its step comprises
1, adopts the iii-nitride light emitting devices chip as transmitting illuminant, it is shelved, the welding spun gold;
2, transparent resin is applied and is solidificated on iii-nitride light emitting devices chip and the spun gold, form the spherical crown shape;
3, the mixture with transparent resin and fluorescent material is coated on the spherical crown shape transparent resin;
4, carry out the routine encapsulation with transparent resin.
Described iii-nitride light emitting devices chip is selected from blue light, purple light or ultraviolet light chip.Fluorescent material is yellow fluorescent powder, is selected from cerium-doped yttrium aluminum garnet fluorescent powder or other yellow fluorescent powders or combination.
Thickness 0.02~the 0.8mm of fluorescence coating, the height 0.01~2mm of spherical crown, fluorescent material weight accounts for 45%-55% in the mixture of fluorescent material and transparent resin.
The present invention utilizes the surface tension of liquid, makes the transparent resin that is coated on nitride diode chip and the spun gold be spherical, and following advantage is arranged
1, can improve coating uniformity of phosphor powder;
2, can effectively protect luminescence chip and spun gold, thereby strengthen the luminous intensity of white light-emitting diodes;
3, fluorescent material does not contact with tube core, and the luminous efficiency of having avoided the fluorescent material degeneration to cause reduces and glow color changes;
4, change the height of spherical crown, the spatial distribution of scalable luminous intensity;
5, regulate fluorescent material thickness, can change parameters such as chromaticity coordinates, colour temperature.
High-brightness nitride LED generating white light luminosity of the present invention is tall and big in 1 candela (1cd), its life-span can reach 100,000 hours, and its operating voltage is 3.5 volts a direct current, power consumption only be identical luminosity light source 1/10th, energy-saving effect is very remarkable, and the caloric value in the use is low, does not contain there are the pollutant that endangers in human body and environment.Can make with this white light-emitting diodes and to have total solids light source light, sturdy and durable, environmental protection, can be widely used in demonstration, family and background illumination, dynamic field such as demonstration, social benefit and economic benefit are very remarkable.
Description of drawings:
Fig. 1 high-brightness nitride LED generating white light structural representation of the present invention
The 1-chip; The 2-spun gold; The 3-transparent resin; The 4-fluorescence coating; The 5-pin; 6-spherical crown height
Embodiment:
At first the nitride blue LED chip 1 of 455-465 nanometer is shelved, welding spun gold 2 is encapsulated in chip 1 and spun gold 2 in the domed transparent resin 3, and spherical crown height 6 is 1 millimeter as shown in the figure.Selecting wavelength for use is the gold-tinted fluorescent material of 530 nanometers.Because the two forms white light blue chip and yellow fluorescence layer.Then transparent resin that mixes by specific proportions (fluorescent material 4 weight account for 45%-55%) and phosphor mixture are coated in formation fluorescence coating 4 on the chip 1, thick 0.5 millimeter intensification is solidified, and encapsulates with transparent resin at last.
At room temperature, 3.5 volts of forward voltages, forward current are 20 MAHs, and the axial luminous intensity of high-brightness nitride LED generating white light of the present invention is greater than 1cd.