CN1196719C - 包括二齿配体的前催化剂、催化剂体系及其在烯烃聚合中的用途 - Google Patents
包括二齿配体的前催化剂、催化剂体系及其在烯烃聚合中的用途 Download PDFInfo
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- CN1196719C CN1196719C CNB018063020A CN01806302A CN1196719C CN 1196719 C CN1196719 C CN 1196719C CN B018063020 A CNB018063020 A CN B018063020A CN 01806302 A CN01806302 A CN 01806302A CN 1196719 C CN1196719 C CN 1196719C
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- Prior art keywords
- acid
- ester
- methyl
- aluminium
- acid amides
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- 239000003054 catalyst Substances 0.000 title claims abstract description 39
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 38
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 26
- 239000003446 ligand Substances 0.000 title claims description 35
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract description 10
- 239000007787 solid Substances 0.000 claims abstract description 58
- 229910052782 aluminium Inorganic materials 0.000 claims description 77
- 239000004411 aluminium Chemical group 0.000 claims description 54
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 36
- 150000001450 anions Chemical class 0.000 claims description 32
- 125000004429 atom Chemical group 0.000 claims description 27
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- 125000000217 alkyl group Chemical group 0.000 claims description 23
- 239000000203 mixture Substances 0.000 claims description 22
- 239000010936 titanium Substances 0.000 claims description 22
- 229910052698 phosphorus Inorganic materials 0.000 claims description 20
- 239000011574 phosphorus Substances 0.000 claims description 19
- 229910052719 titanium Inorganic materials 0.000 claims description 19
- 229910052796 boron Inorganic materials 0.000 claims description 18
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical group [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 17
- 150000002736 metal compounds Chemical class 0.000 claims description 17
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 16
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 16
- 239000002168 alkylating agent Substances 0.000 claims description 16
- 239000000460 chlorine Substances 0.000 claims description 15
- 229910052757 nitrogen Inorganic materials 0.000 claims description 14
- 229940100198 alkylating agent Drugs 0.000 claims description 13
- 229910052801 chlorine Inorganic materials 0.000 claims description 13
- 238000007334 copolymerization reaction Methods 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 11
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical group [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 229910052733 gallium Inorganic materials 0.000 claims description 9
- 229910052738 indium Chemical group 0.000 claims description 9
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical group [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 239000005864 Sulphur Substances 0.000 claims description 8
- 239000000010 aprotic solvent Substances 0.000 claims description 8
- 229910052785 arsenic Inorganic materials 0.000 claims description 8
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 7
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 claims description 7
- 229910052787 antimony Inorganic materials 0.000 claims description 7
- 229910052797 bismuth Inorganic materials 0.000 claims description 7
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical group [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 7
- 150000002902 organometallic compounds Chemical class 0.000 claims description 7
- 229910052711 selenium Inorganic materials 0.000 claims description 7
- 239000011669 selenium Substances 0.000 claims description 7
- 229910052714 tellurium Inorganic materials 0.000 claims description 7
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052723 transition metal Inorganic materials 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 6
- 229910052735 hafnium Chemical group 0.000 claims description 6
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 claims description 6
- 150000003624 transition metals Chemical class 0.000 claims description 5
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 150000001399 aluminium compounds Chemical class 0.000 claims description 2
- LRPDOGHXAWETLI-UHFFFAOYSA-N antimony Chemical compound [Sb].[Sb].[Sb].[Sb] LRPDOGHXAWETLI-UHFFFAOYSA-N 0.000 claims 3
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 2
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 2
- 229910052794 bromium Inorganic materials 0.000 claims 2
- 125000001153 fluoro group Chemical group F* 0.000 claims 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims 2
- 238000005804 alkylation reaction Methods 0.000 claims 1
- 229910001502 inorganic halide Inorganic materials 0.000 claims 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims 1
- -1 polyethylene Polymers 0.000 description 336
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 72
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 70
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 62
- 150000001408 amides Chemical class 0.000 description 58
- 150000001875 compounds Chemical class 0.000 description 57
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical group CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 55
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 39
- 239000002253 acid Substances 0.000 description 37
- 239000002002 slurry Substances 0.000 description 37
- 238000003756 stirring Methods 0.000 description 32
- 239000001294 propane Substances 0.000 description 31
- 239000000126 substance Substances 0.000 description 30
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 29
- 150000002148 esters Chemical class 0.000 description 28
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 26
- 239000002585 base Substances 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 24
- 229910052799 carbon Inorganic materials 0.000 description 23
- 238000005660 chlorination reaction Methods 0.000 description 23
- 125000003118 aryl group Chemical group 0.000 description 22
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 21
- 230000000737 periodic effect Effects 0.000 description 21
- ZMZDMBWJUHKJPS-UHFFFAOYSA-N thiocyanic acid Chemical compound SC#N ZMZDMBWJUHKJPS-UHFFFAOYSA-N 0.000 description 21
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 20
- 125000001931 aliphatic group Chemical group 0.000 description 19
- 125000005842 heteroatom Chemical group 0.000 description 18
- 150000002527 isonitriles Chemical class 0.000 description 18
- 229910000085 borane Inorganic materials 0.000 description 17
- 241000894007 species Species 0.000 description 17
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 17
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 16
- 239000000969 carrier Substances 0.000 description 16
- 239000000843 powder Substances 0.000 description 16
- 229920006395 saturated elastomer Polymers 0.000 description 16
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 15
- 125000002723 alicyclic group Chemical group 0.000 description 15
- 238000001914 filtration Methods 0.000 description 15
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 14
- 239000011521 glass Substances 0.000 description 14
- 239000000377 silicon dioxide Substances 0.000 description 14
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical class NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 12
- 125000000623 heterocyclic group Chemical group 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- 150000003839 salts Chemical class 0.000 description 12
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 11
- 239000001257 hydrogen Substances 0.000 description 11
- 229910052739 hydrogen Inorganic materials 0.000 description 11
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical group CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 11
- DLFVBJFMPXGRIB-UHFFFAOYSA-N Acetamide Chemical compound CC(N)=O DLFVBJFMPXGRIB-UHFFFAOYSA-N 0.000 description 10
- 239000012190 activator Substances 0.000 description 10
- DUYAAUVXQSMXQP-UHFFFAOYSA-N ethanethioic S-acid Chemical compound CC(S)=O DUYAAUVXQSMXQP-UHFFFAOYSA-N 0.000 description 10
- 239000007789 gas Substances 0.000 description 10
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 10
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 9
- KEVMYFLMMDUPJE-UHFFFAOYSA-N diisoamyl Natural products CC(C)CCCCC(C)C KEVMYFLMMDUPJE-UHFFFAOYSA-N 0.000 description 9
- 125000000040 m-tolyl group Chemical group [H]C1=C([H])C(*)=C([H])C(=C1[H])C([H])([H])[H] 0.000 description 9
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 9
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 9
- 235000012239 silicon dioxide Nutrition 0.000 description 9
- 229960001866 silicon dioxide Drugs 0.000 description 9
- 239000002904 solvent Substances 0.000 description 9
- 241000370738 Chlorion Species 0.000 description 8
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 8
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 8
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 8
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 8
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 8
- GRHBQAYDJPGGLF-UHFFFAOYSA-N isothiocyanic acid Chemical compound N=C=S GRHBQAYDJPGGLF-UHFFFAOYSA-N 0.000 description 8
- 239000011777 magnesium Substances 0.000 description 8
- 239000000178 monomer Substances 0.000 description 8
- 229920000642 polymer Polymers 0.000 description 8
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 8
- 150000003457 sulfones Chemical class 0.000 description 8
- 125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 8
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 7
- 150000001335 aliphatic alkanes Chemical class 0.000 description 7
- 235000010290 biphenyl Nutrition 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 7
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 7
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 6
- XKTYXVDYIKIYJP-UHFFFAOYSA-N 3h-dioxole Chemical compound C1OOC=C1 XKTYXVDYIKIYJP-UHFFFAOYSA-N 0.000 description 6
- FWEOQOXTVHGIFQ-UHFFFAOYSA-N 8-anilinonaphthalene-1-sulfonic acid Chemical compound C=12C(S(=O)(=O)O)=CC=CC2=CC=CC=1NC1=CC=CC=C1 FWEOQOXTVHGIFQ-UHFFFAOYSA-N 0.000 description 6
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- 150000008065 acid anhydrides Chemical class 0.000 description 6
- 150000001299 aldehydes Chemical class 0.000 description 6
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 6
- 229940006461 iodide ion Drugs 0.000 description 6
- 150000002576 ketones Chemical class 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
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- 150000003462 sulfoxides Chemical class 0.000 description 6
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- 150000003568 thioethers Chemical class 0.000 description 6
- 150000007944 thiolates Chemical class 0.000 description 6
- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical class SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 6
- XPDWGBQVDMORPB-UHFFFAOYSA-N trifluoromethane acid Natural products FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 6
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 6
- 239000004711 α-olefin Substances 0.000 description 6
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 5
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 5
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 5
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 5
- 230000002378 acidificating effect Effects 0.000 description 5
- 230000004913 activation Effects 0.000 description 5
- 238000001994 activation Methods 0.000 description 5
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- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 5
- KKEYFWRCBNTPAC-UHFFFAOYSA-N benzene-dicarboxylic acid Natural products OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 5
- 150000001733 carboxylic acid esters Chemical class 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 125000004210 cyclohexylmethyl group Chemical group [H]C([H])(*)C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C1([H])[H] 0.000 description 5
- AOBOMOUUYYHMOX-UHFFFAOYSA-N diethylboron Chemical compound CC[B]CC AOBOMOUUYYHMOX-UHFFFAOYSA-N 0.000 description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 5
- ZTJBELXDHFJJEU-UHFFFAOYSA-N dimethylboron Chemical compound C[B]C ZTJBELXDHFJJEU-UHFFFAOYSA-N 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 description 5
- 150000005826 halohydrocarbons Chemical class 0.000 description 5
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 5
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 description 5
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
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- UIOXNNAWANDJCZ-UHFFFAOYSA-N 1,1-dimethoxypropane Chemical compound CCC(OC)OC UIOXNNAWANDJCZ-UHFFFAOYSA-N 0.000 description 4
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- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
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- 150000001266 acyl halides Chemical class 0.000 description 4
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- MHDVGSVTJDSBDK-UHFFFAOYSA-N dibenzyl ether Chemical compound C=1C=CC=CC=1COCC1=CC=CC=C1 MHDVGSVTJDSBDK-UHFFFAOYSA-N 0.000 description 4
- CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 4
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 4
- 235000019439 ethyl acetate Nutrition 0.000 description 4
- 125000004494 ethyl ester group Chemical group 0.000 description 4
- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 4
- UWNADWZGEHDQAB-UHFFFAOYSA-N i-Pr2C2H4i-Pr2 Natural products CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 description 4
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 4
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Classifications
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- C—CHEMISTRY; METALLURGY
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- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
Abstract
本发明描述了固体前催化剂、结合了所述固体前催化剂的催化剂体系以及所述催化剂体系在烯烃聚合和共聚中的用途。
Description
发明领域
本发明涉及有机金属化学的领域。具体地说,本发明涉及某种特别可用于烯烃聚合或共聚作用的新型载体上的有机金属固体前催化剂(procatalyst)和催化剂体系。
发明背景
一种制备聚乙烯聚合物的特别有用的聚合方法为气相法。在美国专利号3,709,853;4,003,712、4,011,382、4,302,566、4,543,399、4,882,400、5,352,749和5,541,270以及加拿大专利991,798号和比利时专利839,380号给出了这样的例子。
本领域熟知用于聚合烯烃的齐格勒-纳塔型催化剂体系,并且至少从美国专利号3,113,115发布之后就已知道这种体系。其后,发布了许多关于新型或改进的齐格勒-纳塔型催化剂的专利。这些专利的例子有美国专利号3,594,330、3,676,415、3,644,318、3,917,575、4,105,847、4,148,754、4,256,866、4,298,713、4,311,752、4,363,904、4,481,301和重新发布的33,683。
这些专利公开了齐格勒-纳塔型催化剂(本文称为ZNCs),众所周知这类催化剂一般由包括含过渡金属的前催化剂(一般包含钛)、有机金属助催化剂(一般为有机铝化合物)的催化剂体系组成。任选与所述催化剂一起使用的有活化剂(例如卤代烃)和活性改性剂(例如电子给体)。
在最早的涉及用于烯烃聚合的‘齐格勒-纳塔’催化剂的专利中,为了提供还原的固体,可用烷基金属处理卤化钛,所述还原的固体主要由TiCl3组成并且一般掺和了反应的副产物。在这些体系中,形成了主要为TiCl3的固体,用做烯烃聚合的前催化剂。有几类专利描述了固体TiCl3的制备。
也描述了可溶性齐格勒-纳塔催化剂。美国专利4,366,297号描述了用还原剂处理TiCl4的醚加合物以提供可溶性TiCl3物种的方法,还提出在没有醚时可形成沉淀物。美国专利3,862,257号描述了TiRCl3.AlC13的烃溶液,其中为了在溶液法中提供低分子量蜡,可通过加入改性剂除去AlCl3。美国专利4,319,010号描述了在高于110℃下使用可溶性催化剂制剂聚合烯烃的溶液法,该方法包括使钛(IV)化合物与由烷基铝增溶的镁化合物的反应产物反应,而美国专利4,540,756号证明了烷基铝活化剂与由羧酸镁增溶的四价过渡金属盐的反应产物的活性,其中四价过渡金属盐具体指TiCl4。美国专利5,037,997号描述了由Ti(OR)4+AlR3+MgR2的反应形成的乙烯的二聚催化剂,其活性小于10Kg/g Ti.h。美国专利5,039,766和5,134,104号描述了可溶性酰胺钛(titanium amido)催化剂,在存在底物烯烃时与烷基铝活化剂或铝氧烷反应。
几个专利描述了其它的载体上的可溶性催化剂。美国专利3,634,384号描述了在低温下制备可溶性卤化钛/烷基铝物种,往其中加入羟基化的固体载体,从而形成了Mg-O-Ti共价键。美国专利3,655,812号描述了相似的方法,通过在芳烃溶剂中生成还原钛物种并且加入卤化镁载体以增加活性。美国专利4,409,126号描述了通过含烷氧基过渡金属化合物与有机金属化合物的反应而获得的烃可溶的反应产物,该反应产物可用于制备烯烃聚合催化剂。在美国专利5,320,994号中描述了这个催化剂的变化,其中将烷氧基钛与烷基铝反应,随后加入镁化合物,在反应条件下形成MgCl2。这个例子还详细说明了α、ω-二卤代烷在防止过度还原成TiCl2方面的重要性。
美国专利2,981,725号论述了TiCl4与各种载体(如碳化硅)的反应,接着用助催化剂AlEt2Cl处理。载体上的催化剂与在非载体上的沉淀催化剂比较显示出少于两个因子的改进。美国专利4,426,315号描述了类似的载体上的催化剂的制备,其中将钛和铝化合物同时加到载体的淤浆中,任何反应仅在所述载体存在下发生。
已知某些可溶或“液体”的齐格勒-纳塔催化剂体系利用了钛螯合物。例如,美国专利3,737,416和3,737,417号描述了钛螯合物与卤化剂的反应,接着用烷基铝活化以提供将α-烯烃和丁二烯共聚的催化剂。这些活化作用在低至-78℃的温度和存在单体下实施。美国专利3,652,705号仅要求保护腈电子给体在用有机铝化合物处理前与TiCl4反应的用途。优选将这些催化剂用于芳烃溶液或淤浆。美国专利4,482,639、4,603,185和4,727,123号描述了带有单阴离子三齿螯合配体的双金属络合物,该络合物采用烷基铝活化以聚合烯烃、炔和二烯。美国专利5,021,595号描述了基于二齿螯合配体的可溶性三价金属(特别是钒)络合物的催化剂。这些可溶性络合物通过三价金属卤化物与包括酸性氢的化合物反应来制备,并且用烷基铝活化用于聚合烯烃。美国专利5,378,778号报道了将酰胺钛与具有酸性氢的有机含氧化合物反应,随后用烷基铝通过原位活化来给出高活性、非载体上的烯烃聚合催化剂。美国专利5,840,646号报道了具有螯和的双(烷氧基)(bis(alkoxide))配体的Ti、Zr或Hf的二烷基络合物,其中受限的(tethered)路易斯碱连在所述配体的骨架上。这些化合物可在存在生成阳离子络合物的活化剂下用于聚合烯烃,其中活化剂的例子有三苯甲基四(五氟苯基)硼酸盐或甲基铝氧烷。
烷基铝通常用作齐格勒-纳塔催化剂的活化剂或助催化剂,并且一些化合物的例子具有AlR3-nLn(n=1或2)的形式,其中L各自为单阴离子配体。美国专利3,489,736号举例说明了各种包括羧酸酰胺的铝氧化合物的用途,其可与作为路易斯酸的卤化铝联合用作齐格勒-纳塔催化剂(如TiCl3)的助催化剂。美国专利3,723,348号描述了带活化剂的钒化合物的用途,其中所述活化剂可为烃醇铝、酰胺、羧化物或乙酰丙酮化物。美国专利3,786,032号用有机铝或有机锌与肟或羟基酯的反应产物作为活化剂。美国专利3,883,493号用氨基甲酸铝与另一种有机铝化合物联合作助催化剂。与在美国专利3,948,869号中报道的一样,可用钛或钒卤化物、三烷基铝和少量二硫化碳的混合物聚合共轭二烯。美国专利4,129,702号公开了作为齐格勒-纳塔催化剂(任选吸附在载体上)的活化剂的羧酸酰胺的铝盐或锌盐在聚合乙烯基卤化物或亚乙烯基二卤化物中的用途,指出改进之处在于老化助催化剂以除去异氰酸酯。美国专利5,468,707号描述了二齿、二阴离子的第13族元素化合物作为助催化剂的用途。美国专利5,728,641号也描述了儿茶酸铝(aluminum catecholate)化合物作为四组分催化剂体系中的一个组分的用途,其中该体系包括具有两个或多个共轭双键的有机环状化合物。
铝螯合物也可用作外电子给体。美国专利3,313,791号公开了作为外电子给体的乙酰丙酮酸根合(acetylacetonato)烷氧基铝与三氯化钛和烷基铝二卤化物催化体系的用途。美国专利3,919,180号讨论了外电子给体的用途,所述外电子给体可为结合了钛催化剂或铝助催化剂的双配位基。美国专利5,777,120号描述了作为烯烃聚合的单活性部位催化剂的阳离子aluminum amidinate化合物的用途。
美国专利3,534,006号描述了用双(二烷基铝氧基(aluminoxy))烷化合物活化的包括第4-6族金属化合物的催化剂。该专利还要求保护另外的外电子给体或助催化剂的用途,其中另外的外电子给体或助催化剂包括范围广泛的含氮化合物。美国专利4,195,069号描述了具有络合剂的TiCl4络合物与具有络合剂的有机铝络合物的相互作用。这种相互作用导致将TiCl4还原成TiCl3沉淀。
发明概述
通过至少一种经验式MX4的过渡金属化合物与至少一种式LxERnYmHp的烷基化剂在至少一种非质子溶剂中反应以提供可溶性物种,随后将所述可溶性物种与载体接触来制备固体前催化剂,在式MX4中,M为钛、铪或锆,X为氟离子、氯离子、溴离子或碘离子,在式LxERnYmHp中,L各自独立为通过两个选自氧、硫、硒、碲、氮、磷、砷、锑和铋或其混合物的原子连接到E上的单阴离子二齿配体,E为硼、铝、镓或铟,R各自独立为烃基,Y各自独立为单阴离子单齿配体,0<x≤2,n>0,m≥0,p≥0,并且x+n+m+p=3。得到的固体前催化剂与助催化剂一起提供了适合聚合或共聚烯烃的催化剂体系。
发明的详细描述
通过至少一种经验式MX4的过渡金属化合物与至少一种式LxERnYmHp的烷基化剂在至少一种非质子溶剂中反应以提供可溶性物种,随后将所述可溶性物种与载体接触来制备固体前催化剂,在式MX4中,M为钛、铪或锆,X为氟离子、氯离子、溴离子或碘离子,在式LxERnYmHp中,L各自独立为通过两个选自氧、硫、硒、碲、氮、磷、砷、锑和铋或其混合物的原子连接到E上的单阴离子二齿配体,E为硼、铝、镓或铟,R各自独立为烃基,Y各自独立为单阴离子单齿配体,0<x≤2,n>0,m≥0,p≥0,并且x+n+m+p=3。将所述可溶性物种与载体接触包括在载体上沉积所述可溶性物种。优选MX4为TiCl4。得到的固体前催化剂与助催化剂一起提供了适合聚合或共聚烯烃的催化剂体系。
此处提及的所有元素周期表的各族的元素可参见1985年在“Chemical and Engineering News”,63(5),27中发表的元素周期表。在这个版本中,将族编号为1到18。本文使用了缩写Me(用于甲基)、Et(用于乙基)、TMA(用于三甲基铝)和TEAL(用于三乙基铝)。
本发明包括通过经验式MX4的过渡金属化合物与式LxERnYmHp的烷基化剂在非质子溶剂中的反应以提供可溶性物种,随后将所得的可溶性物种与载体接触来制备的固体前催化剂。如果在生成可溶性组分期间发生任何沉淀,那么在将可溶性物种与载体接触之前必须将所述沉淀重新溶解、过滤或将其除去。
烷基化剂与过渡金属化合物的摩尔比优选为大约0.1到大约100。优选烷基化剂与过渡金属化合物的摩尔比为大约0.25到大约15。更优选烷基化剂与过渡金属化合物的摩尔比为大约1到大约5。
至少一种用于本发明的方法中的过渡金属化物可为任何经验式:
MX4的化合物或其混合物,
其中M选自钛、锆和铪,X各自独立选自氟离子、氯离子、溴离子和碘离子。
优选此处用作过渡金属化合物的为钛卤化物和混合的卤化物,如TiF4、TiCl4、TiBr4、TiI4、TiFnCl4-n、TiFnBr4-n、TiFnI4-n、TiClnBr4-n、TiClnI4-n、TiBrnI4-n等,其中n大于0,或它们的混合物。
最优选用作此处的至少一种过渡金属化合物(MX4)为TiCl4。
至少一种用于本发明的烷基化剂可为任何具有以下经验式的有机金属化合物或其混合物:
LxERnYmHp,其中,
L各自独立为通过两个选自氧、硫、硒、碲、氮、磷、砷、锑和铋或其混合物的原子连接到E上的单阴离子二齿配体;
E选自硼、铝、镓和铟;
R各自独立为烃基,
Y各自独立为单阴离子单齿配体,
0<x≤2,n>0,m≥0,p≥0,并且
x+n+m+p=3。
此处使用的术语“烃基”表示单价、线性、支化、环状或多环的包括碳和氢原子的基团。所述烃基可任选包括除碳和氢之外的选自周期表第13、14、15、16和17族的原子。单价烃基的例子包括如下:C1-C30的烷基;被一个或多个选自C1-C30的烷基、C3-C15的环烷基或芳基取代的C1-C30的烷基;C3-C15的环烷基;被一个或多个选自C1-C20的烷基、C3-C15的环烷基或芳基取代的C3-C15的环烷基;C6-C15的芳基;和被一个或多个选自C1-C30的烷基、C3-C15的环烷基或芳基取代的C6-C15的芳基、其中芳基优选表示取代的或未取代的苯基、萘基(napthyl)或蒽基(anthracenyl)。
所述烷基化剂(LxERnYmHp)可在与烷基化剂接触之前产生和/或以任何方式引入非质子溶剂中,随后用烷基化剂处理,其中所述方法包括溶解纯净物或通过原位混合例如经验式ERn+1YmHp与配体(L)、配体的络合物或配体的盐。
连接到E上的单阴离子二齿配体L的例子有包含酸性氢的化合物的共轭碱和包含酸性碳-氢键的化合物的共轭碱。
可用于此处的连接到E上的单阴离子二齿配体L为包含酸性氢的化合物的共轭碱,其例子有羧酸、羧酸酰胺、羧酸磷化物、硫代羧酸、二硫代羧酸、硫代羧酸酰胺、硫代羧酸磷化物、碳酸、氨基甲酸、脲、硫代碳酸、硫脲、硫代氨基甲酸、二硫代氨基甲酸、羟基羧酸酯、羟基羧酸酰胺、氨基酸酯、羟基硫代羧酸酯、羟基二硫代羧酸酯、羟基硫代羧酸酰胺、羟基羧酸硫代酸酯、羟基硫代羧酸硫代酸酯、羟基二硫代羧酸硫代酸酯、巯基羧酸酯、巯基羧酸酰胺、巯基硫代羧酸酯、巯基二硫代羧酸酯、巯基硫代羧酸酰胺、巯基羧酸硫代酸酯、巯基硫代羧酸硫代酸酯、巯基二硫代羧酸硫代酸酯、羟基酮、羟基醛、羟基亚胺、巯基酮、巯基醛、巯基亚胺、羟基硫酮、羟基硫醛、巯基硫酮、巯基硫醛、2-羟基苯甲醛、2-巯基苯甲醛、2-氨基苯甲醛、2-羟基苯基硫醛、2-羟基苯甲酸酯、2-羟基苯甲酰胺、2-羟基苯甲酸硫代酸酯、2-羟基硫代苯甲酸酯、2-羟基硫代苯甲酰胺、2-羟基苯基硫醛、2-巯基苯基硫醛、2-氨基苯基硫醛、2-羟基芳酮、2-巯基芳酮、2-氨基芳基酮、2-羟基芳基亚胺、2-巯基芳基亚胺、2-氨基芳基亚胺、2-羟基芳基硫酮、2-巯基芳基硫酮、2-氨基芳基硫酮、苯偶姻、2-吡咯羧基醛、2-吡咯硫代羧基醛、2-吡咯羧基醛亚胺、烃基2-吡咯基酮、烃基2-吡咯基亚胺、烃基2-吡咯基硫酮、2-吲哚羧基醛、2-吲哚硫代羧基醛、2-吲哚羧基醛亚胺、烃基2-吲哚基酮、烃基2-吲哚基亚胺、烃基2-吲哚基硫酮、羟基喹啉、环庚三烯酚酮、氨基-环庚三烯酚酮、氨基环庚三烯酮亚胺等。
可用于此处的连接到E上的单阴离子二齿配体L为包含酸性碳-氢键的化合物的共轭碱,其例子有1,3-二酮、β-酮酸酯、β-酮酸酰胺、3-硝基酮、3-硝基酸酯、3-硝基酸酰胺、邻苯二甲酸单酯、二(2-呋喃基)烷、双(5-(2,3-二氢呋喃基))烷、二(2-硫代苯基)烷、双(5-(2,3-二氢硫代苯基))烷、二(2-吡啶基)烷、丙二酸二酯、β-酮亚胺、1,3-二亚胺、β-亚氨基酸酯、β-亚氨基酸酰胺、3-硝基亚胺、烷基亚硫酰乙酸酯、烷基硫酰乙酸酯、双(烷基亚硫酰基)烷、双(烷基硫酰基)烷等。
可用于此处的连接到E上的单阴离子二齿配体L的优选的例子有1,3-二酮的共轭碱,例如乙酰丙酮、3,5-庚二酮、2,6-二甲基-3,5-庚二酮、5,7-十一烷二酮、苯甲酰丙酮、二苯甲酰甲烷、1,1,1-三氟乙酰丙酮、1,1,1,5,5,5-六氟乙酰丙酮、2,2,6,6-四甲基-3,5-庚二酮、以上列出的1,3-二酮的单-和二-亚胺的类似物、2-羟基苯羧基醛、以上列出的化合物的亚胺的类似物等。
可将连接到E上的单阴离子二齿配体L的混合物用作连接到E上的单阴离子二齿配体L。
单阴离子单齿配体Y的例子包括卤素负离子、-OR、-OBR2、-OSR、-ONR2、-OPR2、-NR2、-N(R)BR2、-N(R)OR、-N(R)SR、-N(R)NR2、-N(R)PR2、-N(BR2)2、-N=CR2、-N=NR、-N=PR、-SR、-SBR2、-SOR、-SNR2、-SPR2、-PR2等。R各自独立为与上述定义一致的烃基。卤素负离子的例子有氟离子、氯离子、溴离子和碘离子。
醇盐的例子有甲醇盐、乙醇盐、正丙醇盐、异丙醇盐、环丙醇盐、正丁醇盐、异丁醇盐、仲丁醇盐、叔丁醇盐、环丁醇盐、正戊醇盐、异戊醇盐、仲戊醇盐、叔戊醇盐、新戊醇盐、环戊醇盐、正己醇盐、环己醇盐、庚醇盐、辛醇盐、壬醇盐、癸醇盐、十一烷醇盐、十二烷醇盐、2-乙基己醇盐、酚盐、2,6-二甲基酚盐、2,6-二异丙基酚盐、2,6-二苯基酚盐、2,6-二基酚盐、2,4,6-三甲基酚盐、2,4,6-三异丙基酚盐、2,4,6-三苯基酚盐、2,4,6-三基酚盐、苄醇盐(benzyloxide)、薄荷醇盐(menthoxide)等,以及卤代烷醇盐,例如三氟甲醇盐、三氟乙醇盐、三氟异丙醇盐、六氟异丙醇盐、七氟异丙醇盐、三氟叔丁醇盐、六氟叔丁醇盐、三氟甲醇盐、三氯乙醇盐、三氯异丙醇盐等。
硫醇盐的例子有甲硫醇盐、乙硫醇盐、正丙基硫醇盐、异丙基硫醇盐、环丙基硫醇盐、正丁基硫醇盐、异丁基硫醇盐、仲丁基硫醇盐、叔丁基硫醇盐、环丁基硫醇盐、正戊基硫醇盐、异戊基硫醇盐、仲戊基硫醇盐、叔戊基硫醇盐、新戊基硫醇盐、环戊基硫醇盐、正己基硫醇盐、环己基硫醇盐、苯基硫醇盐、2,6-二甲基苯基硫醇盐、2,6-二异丙基苯基硫醇盐、2,6-二苯基苯基硫醇盐、2,6-二基苯基硫醇盐、2,4,6-三甲基苯基硫醇盐、2,4,6-三异丙基苯基硫醇盐、2,4,6-三苯基苯基硫醇盐、2,4,6-三基苯基硫醇盐、苄基硫醇盐、庚基硫醇盐、辛基硫醇盐、壬基硫醇盐、癸基硫醇盐、十一烷基硫醇盐、十二烷基硫醇盐、2-乙基己基硫醇盐、基硫醇盐等,以及卤代烷基硫醇盐,例如三氟甲基硫醇盐、三氟乙基硫醇盐、三氟异丙基硫醇盐、六氟异丙基硫醇盐、七氟异丙基硫醇盐、三氟叔丁基硫醇盐、六氟叔丁基硫醇盐、三氟甲基硫醇盐、三氯乙基硫醇盐、三氯异丙基硫醇盐等。
酰胺的例子有二甲基酰胺、二乙基酰胺、二正丙基酰胺、二异丙基酰胺、二环丙基酰胺、二正丁基酰胺、二异丁基酰胺、二仲丁基酰胺、二叔丁基酰胺、二环丁基酰胺、二正戊基酰胺、二异戊基酰胺、二仲戊基酰胺、二叔戊基酰胺、二环戊基酰胺、二新戊基酰胺、二正己基酰胺、二环己基酰胺、二庚基酰胺、二辛基酰胺、二壬基酰胺、二癸基酰胺、二(十一烷基)酰胺、二(十二烷基)酰胺、二-2-乙基己基酰胺、二苯基酰胺、双-2,6-二甲基苯基酰胺、双-2,6-二异丙基苯基酰胺、双-2,6-二苯基苯基酰胺、双-2,6-二基苯基酰胺、双-2,4,6-三甲基苯基酰胺、双-2,4,6-三异丙基苯基酰胺、双-2,4,6-三苯基苯基酰胺、双-2,4,6-三基苯基酰胺、二苄基酰胺、二己基酰胺、二环己基酰胺、二辛基酰胺、二癸基酰胺、双十八烷基酰胺、二苯基酰胺、二苄基酰胺、双-2,6-二甲基苯基酰胺、2,6-双-异丙基苯基酰胺、双-2,6-二苯基苯基酰胺、二烯丙基酰胺、二丙烯基酰胺、N-甲基苯胺、N-乙基苯胺、N-丙基苯胺、N-异丙基苯胺、N-丁基苯胺、N-异丁基苯胺、N-戊基苯胺、N-异戊基苯胺、N-辛基苯胺、N-环己基苯胺等;以及甲硅烷基酰胺如双(三甲代甲硅烷基)酰胺、双(三乙代甲硅烷基)酰胺、双(二甲基苯基甲硅烷基)酰胺、双(叔丁基二甲基甲硅烷基)酰胺、双(叔丁基二苯基甲硅烷基)酰胺、苯基(三甲代甲硅烷基)酰胺、苯基(三乙代甲硅烷基)酰胺、苯基(三甲代甲硅烷基)酰胺、甲基(三甲代甲硅烷基)酰胺、乙基(三甲代甲硅烷基)酰胺、正丙基(三甲代甲硅烷基)酰胺、异丙基(三甲代甲硅烷基)酰胺、环丙基(三甲代甲硅烷基)酰胺、正丁基(三甲代甲硅烷基)酰胺、异丁基(三甲代甲硅烷基)酰胺、仲丁基(三甲代甲硅烷基)酰胺、叔丁基(三甲代甲硅烷基)酰胺、环丁基(三甲代甲硅烷基)酰胺、正戊基(三甲代甲硅烷基)酰胺、异戊基(三甲代甲硅烷基)酰胺、仲戊基(三甲代甲硅烷基)酰胺、叔戊基(三甲代甲硅烷基)酰胺、新戊基(三甲代甲硅烷基)酰胺、环戊基(三甲代甲硅烷基)酰胺、正己基(三甲代甲硅烷基)酰胺、环己基(三甲代甲硅烷基)酰胺、庚基(三甲代甲硅烷基)酰胺和三乙代甲硅烷基三甲代甲硅烷基酰胺等,以及杂环酰胺,例如吡咯、吡啶、哌啶、哌嗪、吲哚、咪唑、吡咯、噻唑、嘌呤、邻苯二甲酰亚胺、1-氮杂环庚烷、1-氮杂环辛烷、1-氮杂环壬烷、1-氮杂环癸烷、它们的取代衍生物的共轭碱等。
磷化物的例子有二甲基磷化物、二乙基磷化物、二丙基磷化物、二丁基磷化物、二戊基磷化物、二己基磷化物、二环己基磷化物、二苯基磷化物、二苄基磷化物、双-2,6-二甲基苯基磷化物、2,6-二异丙基苯基磷化物、2,6-二苯基苯基磷化物等,以及环状膦的共轭碱,例如磷杂环戊烷、磷杂环己烷、磷杂环庚烷、磷杂环辛烷、磷杂环壬烷、磷杂环癸烷等。
优选用于本文的单阴离子单齿配体Y为氟离子、氯离子、溴离子、甲醇盐、乙醇盐、正丙醇盐、异丙醇盐、丁醇盐、新戊醇盐、苄醇盐、三氟甲醇盐和三氟乙醇盐。
可将单阴离子单齿配体Y的混合物用作单阴离子单齿配体Y。
本文也可利用上述的烷基化剂的混合物作烷基化剂。
所述至少一种非质子溶剂为不含可在使用条件下被溶于所述溶剂中的任何物种以质子的形式除去的氢原子的溶剂。这种溶剂的例子包括脂族烃、芳族烃和卤代烃以及无机溶剂,其中脂族烃、芳族烃和卤代烃可任选包括第13、14、15或16族的其它元素,无机溶剂的例子有CS2、POCl3、SO2等。优选的溶剂为脂族烃、芳族烃或卤代烃。更优选所述溶剂为包括4到40个碳原子、任选包括最高可达10个杂原子的脂族烃、芳族烃或卤代烃。最优选的溶剂为戊烷、庚烷、己烷、苯、甲苯、二氯甲烷或1,2-二氯乙烷。
本发明可使用任何无机或有机载体。适合的无机载体的例子有粘土、金属氧化物、金属氢氧化物、金属卤化物或其它的金属盐,例如硫酸盐、碳酸盐、磷酸盐、硝酸盐和硅酸盐。适合用于本文的无机载体的其它例子为元素周期表第1和2族的金属化合物,例如钠或钾的盐和镁或钙的氧化物或盐,如钠、钾、镁或钙的氯化物、硫酸盐、碳酸盐、磷酸盐或硅酸盐,以及例如镁或钙的氧化物或氢氧化物。适合使用的也可为无机氧化物,例如二氧化硅、二氧化钛、氧化铝、氧化锆、氧化铬、氧化硼、硅烷化二氧化硅、二氧化硅水凝胶、二氧化硅干凝胶、二氧化硅气凝胶;和混合的氧化物,例如滑石粉、二氧化硅/氧化铬、二氧化硅/氧化铬/二氧化钛、二氧化硅/氧化铝、二氧化硅/二氧化钛、二氧化硅/氧化镁、二氧化硅/氧化镁/二氧化钛、磷酸铝凝胶、二氧化硅共凝胶等。所述无机氧化物可包括碳酸盐、硝酸盐、硫酸盐和氧化物,例如Na2CO3、K2CO3、CaCO3、MgCO3、Na2SO4、Al2(SO4)3、BaSO4、KNO3、Mg(NO3)2、Al(NO3)3、Na2O、K2O和Li2O。优选载体包括至少一种选自MgCl2、SiO2、Al2O3或其混合物作为主要组分的组分。
适合的有机载体的例子包括聚合物,例如功能化聚乙烯、功能化聚丙烯、功能化的乙烯和α-烯烃的共聚物、聚苯乙烯、功能化聚苯乙烯、聚酰胺和聚酯。
适合的聚合的无机载体的例子包括碳化硅氧烷(carbosiloxanes)、膦嗪、硅氧烷和杂化物材料如聚合物/二氧化硅杂化物。
优选用于本文的为无机氧化物、混合的氧化物、第2族的卤化物以及含有沉积或沉淀在上述氧化物表面上的氯化镁的无机氧化物载体,其中无机氧化物的例子有二氧化硅、二氧化钛、氧化铝,混合的氧化物的例子有滑石、二氧化硅/氧化铬、二氧化硅/氧化铬/二氧化钛、二氧化硅/氧化铝、二氧化硅/二氧化钛,第2族的卤化物的例子有氯化镁、溴化镁、氯化钙和溴化钙。
最优选用于本文的为含有沉积或沉淀在上述氧化物表面上的氯化镁,例如二氧化硅上的氯化镁的无机氧化物载体。
在本发明的另一个实施方案中,发现可制备如上所述的包括至少一个内电子给体的固体前催化剂。通过至少一种经验式MX4的过渡金属化合物与至少一种式LxERnYmHp的烷基化剂和至少一种内电子给体在至少一种非质子溶剂中反应以提供可溶性物种,随后将所得的可溶性物种与载体接触来制备固体前催化剂,在式MX4中,M为钛、锆或铪,X为氟离子、氯离子、溴离子或碘离子,在式LxERnYmHp中,L各自独立为通过两个选自氧、硫、硒、碲、氮、磷、砷、锑和铋或其混合物的原子连接到E上的单阴离子二齿配体,E为硼、铝、镓或铟,R各自独立为烃基,Y各自独立为单阴离子单齿配体,0<x≤2,n>0,m≥0,p≥0,并且x+n+m+p=3。将所述可溶性物种与所述载体接触包括将所述可溶性物种沉积在载体上。得到的固体前催化剂与助催化剂一起提供了适合烯烃聚合或共聚的催化剂体系。
内电子给体与过渡金属化合物的摩尔比优选为大约0.1到大约100。优选内电子给体与过渡金属化合物的摩尔比为大约0.25到大约15。更优选内电子给体与过渡金属化合物的摩尔比为大约1到大约5。
内电子给体的例子有羧酸酯、酸酐、酰基卤、醚、硫醚、醛、酮、亚胺、胺、酰胺、腈、异腈、氰酸酯、异氰酸酯、硫氰酸酯、异硫氰酸酯、硫代酸酯、二硫代酸酯、碳酸酯、烃基氨基甲酸酯、烃基硫代氨基甲酸酯、烃基二硫代氨基甲酸酯、氨基甲酸乙酯、膦、硫化物、氧膦、磷酰胺、亚砜、砜、磺酰胺、包括至少一个氧原子的有机硅化合物,和通过碳或氧原子连到有机基团上的氮、磷、砷或锑化合物。
可在本文中用作内电子给体的醚的例子有任何包括至少一个C-O-C醚键的化合物。包括在醚化合物的范围内的为包括杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。醚的例子有二烷基醚、二芳基醚、二烷芳基醚、二芳烷基醚、烷基芳基醚、烷基烷芳基醚、烷基芳烷基醚、芳基烷芳基醚、芳基芳烷基醚和烷芳基芳烷基醚。包括在醚范围内的为如下的化合物:二甲醚、二乙醚、二丙醚、二异丙醚、二丁醚、二异戊醚、二叔丁基醚、二苯醚、二苄基醚、二乙烯基醚、丁基甲醚、丁基乙醚、仲丁基甲醚、叔丁基甲醚、环戊基甲醚、环己基乙醚、叔戊基甲醚、仲丁基乙醚、氯甲基甲醚、三甲代甲硅烷基甲基甲基醚、双(三甲代甲硅烷基甲基)醚、双(2,2,2-三氟乙基)醚、甲基苯基醚、环氧乙烷、环氧丙烷、1,2-环氧丁烷、环戊烯化氧(cyclopentene oxide)、表氯醇、呋喃、2,3-二氢呋喃、2,5-二氢呋喃、四氢呋喃、2-甲基四氢呋喃、2,5-二甲基四氢呋喃、2-甲基呋喃、2,5-二甲基呋喃、四氢吡喃、1,2-环氧丁-3-烯、氧化苯乙烯、2-乙基呋喃、噁唑、1,3,4-氧二氮茂、3,4-二氯-1,2-环氧丁烷、3,4-二溴-1,2-环氧丁烷、二甲氧基甲烷、1,1-二甲氧基乙烷、1,1,1-三甲氧基甲烷、1,1,1-三甲氧基乙烷、1,1,2-三甲氧基乙烷、1,1-二甲氧基丙烷、1,2-二甲氧基丙烷、2,2-二甲氧基丙烷、1,3-二甲氧基丙烷、1,1,3-三甲氧基丙烷、1,4-二甲氧基丁烷、1,2-二甲氧基苯、1,3-二甲氧基苯、1,4-二甲氧基苯、乙二醇二甲醚、二甘醇二甲醚、二甘醇二乙醚、二甘醇二丁醚、二甘醇叔丁基甲基醚、三甘醇二甲醚、三甘醇二乙醚、四甘醇二甲醚、2,2-二乙基-1,3-二甲氧基丙烷、2-甲基-2-乙基-1,3-二甲氧基丙烷、2-甲氧基呋喃、3-甲氧基呋喃、1,3-二氧戊环、2-甲基-1,3-二氧戊环、2,2-二甲基-1,3-二氧戊环、2-乙基-2-甲基-1,3-二氧戊环、2,2-四亚甲基-1,3-二氧戊环、2,2-五亚甲基-1,3-二氧戊环、1,3-二氧杂环己烷、1,4-二氧杂环己烷、4-甲基-1,3-二氧杂环己烷、1,3,5-三氧杂环己烷和3,4-环氧四氢呋喃等。
优选在此处用作内电子给体的醚化合物为四氢呋喃、二乙醚、二丙醚、二异丙醚、二丁醚、二辛醚、叔丁基甲醚、氧杂环丁烷、1,2-二甲氧基乙烷、1,2-二甲氧基丙烷、1,3-二甲氧基丙烷、1,2-二甲氧基丁烷、1,3-二甲氧基丁烷、1,4-二甲氧基丁烷和四氢吡喃。
可在本文中用作内电子给体的硫醚的例子有任何包括至少一个C-S-C硫醚键的化合物。包括在硫醚化合物的范围内的为包括杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。硫醚的例子有二烷基硫醚、二芳基硫醚、二烷芳基硫醚、二芳烷基硫醚、烷基芳基硫醚、烷基烷芳基硫醚、烷基芳烷基硫醚、芳基烷芳基硫醚、芳基芳烷基硫醚和烷芳基芳烷基硫醚。包括如下的化合物:二甲硫醚、二乙硫醚、二丙硫醚、二异丙基硫醚、二丁硫醚、二戊硫醚、二己硫醚、二辛硫醚、二异戊基硫醚、二叔丁基硫醚、二苯基硫醚、二苄基硫醚、二乙烯基硫醚、二烯丙基硫醚、二炔丙基硫醚、二环丙基硫醚、二环戊基硫醚、二环己基硫醚、烯丙基甲基硫醚、烯丙基乙基硫醚、烯丙基环己基硫醚、烯丙基苯基硫醚、烯丙基苄基硫醚、烯丙基2-甲苯基硫醚、烯丙基3-甲苯基硫醚、苄基甲基硫醚、苄基乙基硫醚、苄基异戊基硫醚、苄基氯甲基硫醚、苄基环己基硫醚、苄基苯基硫醚、苄基1-萘基硫醚、苄基2-萘基硫醚、丁基甲基硫醚、丁基乙基硫醚、仲丁基甲基硫醚、叔丁基甲基硫醚、丁基环戊基硫醚、丁基2-氯乙基硫醚、环戊基甲基硫醚、环己基乙基硫醚、环己基乙烯基硫醚、叔-戊基甲基硫醚、仲丁基乙基硫醚、叔丁基乙基硫醚、叔戊基乙基硫醚、环十二烷基甲基硫醚、双(2-环戊烯-1-基)硫、1-甲硫基-1,3-环己二烯、1-甲硫基-1,4-环己二烯、氯甲基甲基硫醚、氯甲基乙基硫醚、双(2-甲苯基)硫醚、三甲代甲硅烷基甲基甲基硫醚、硫杂环丁烷、噻吩、2,3-二氢噻吩、2,5-二氢噻吩、四氢噻吩、2-甲基四氢噻吩、2,5-二甲基四氢噻吩、4,5-二氢-2-甲基噻吩、2-甲基噻吩、2,5-二甲基噻吩、3-溴噻吩、2,3-苯并噻吩、2-甲基苯并噻吩、二苯并噻吩、异苯并噻吩、1,1-双(甲硫基)乙烷、1,1,1-三(甲硫基)乙烷、1,1,2-三(甲硫基)乙烷、1,1-双(甲硫基)丙烷、1,2-双(甲硫基)丙烷、2,2-双(甲硫基)丙烷、1,3-双(甲硫基)丙烷、1,1,3-三(甲硫基)丙烷、1,4-双(甲硫基)丁烷、1,2-双(甲硫基)苯、1,3-双(甲硫基)苯、1,4-双(甲硫基)苯、乙二醇二甲基硫醚、乙二醇二乙基硫醚、乙二醇二乙烯基硫醚、乙二醇二苯基硫醚、乙二醇叔丁基甲基硫醚、乙二醇叔丁基乙基硫醚、2,5-双(甲硫基)噻吩、2-甲硫基噻吩、3-甲硫基噻吩、2-甲硫基四氢吡喃、3-甲硫基四氢吡喃、1,3-二硫戊环、2-甲基-1,3-二硫戊环、2,2-二甲基-1,3-二硫戊环、2-乙基-2-甲基-1,3-二硫戊环、2,2-四亚甲基-1,3-二硫戊环、2,2-五亚甲基-1,3-二硫戊环、2-乙烯基-1,3-二硫戊环、2-氯甲基-1,3-二硫戊环、2-甲硫基-1,3-二硫戊环、1,3-二噻烷、1,4-二噻烷、4-甲基-1,3-二噻烷、1,3,5-三噻烷、2-(2-乙基己基)-1,3-双(甲硫基)丙烷、2-异丙基-1,3-双(甲硫基)丙烷、2-丁基-1,3-双(甲硫基)丙烷、2-仲丁基-1,3-双(甲硫基)丙烷、2-叔丁基-1,3-双(甲硫基)丙烷、2-环己基-1,3-双(甲硫基)丙烷、2-苯基-1,3-双(甲硫基)丙烷、2-枯基-1,3-双(甲硫基)丙烷、2-(2-苯基乙基)-1,3-双(甲硫基)丙烷、2-(2-环己基乙基)-1,3-双(甲硫基)丙烷、2-(对氯苯基)-1,3-双(甲硫基)丙烷、2-(对氟苯基)-1,3-双(甲硫基)丙烷、2-(二苯基甲基)-1,3-双(甲硫基)丙烷、2,2-二环己基-1,3-双(甲硫基)丙烷、2,2-二乙基-1,3-双(甲硫基)丙烷、2,2-二丙基-1,3-双(甲硫基)丙烷、2,2-二异丙基-1,3-双(甲硫基)丙烷、2,2-二丁基-1,3-双(甲硫基)丙烷、2,2-二异丁基-1,3-双(甲硫基)丙烷、2-甲基-2-乙基-1,3-双(甲硫基)丙烷、2-甲基-2-丙基-1,3-双(甲硫基)丙烷、2-甲基-2-丁基-1,3-双(甲硫基)丙烷、2-甲基-2-苄基-1,3-双(甲硫基)丙烷、2-甲基-2-甲基环己基-1,3-双(甲硫基)丙烷、2-异丙基-2-异戊基-1,3-双(甲硫基)丙烷、2,2-双(2-环己基甲基)-1,3-双(甲硫基)丙烷等。
可将任何胺用作此处的内电子给体。包括含杂原子的胺化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。胺的例子有由伯、仲和叔烷基、芳基、烷芳基和芳烷基取代的胺。胺的例子有氨、甲胺、乙胺、丙胺、异丙胺、丁胺、异丁胺、戊胺、异戊胺、辛胺、环己胺、苯胺、二甲胺、二乙胺、二丙胺、二异丙胺、二丁胺、二异丁胺、二戊胺、二异戊胺、二辛胺、二环己胺、三甲胺、三乙胺、三丙胺、三异丙胺、三丁胺、三异丁胺、三戊胺、三异戊胺、三辛胺、三环己胺、N-甲基苯胺、N-乙基苯胺、N-丙基苯胺、N-异丙基苯胺、N-丁基苯胺、N-异丁基苯胺、N-戊基苯胺、N-异戊基苯胺、N-辛基苯胺、N-环己基苯胺、N,N-二甲基苯胺、N,N-二乙基苯胺、N,N-二丙基苯胺、N,N-二异丙基苯胺、N,N-二丁基苯胺、N,N-二异丁基苯胺、N,N-二戊基苯胺、N,N-二异戊基苯胺、N,N-二辛基苯胺、N,N-二环己基苯胺、氮杂环丁烷、1-甲基氮杂环丁烷、1-乙基氮杂环丁烷、1-丙基氮杂环丁烷、1-异丙基氮杂环丁烷、1-丁基氮杂环丁烷、1-异丁基氮杂环丁烷、1-戊基氮杂环丁烷、1-异戊基氮杂环丁烷、吡咯烷、N-甲基咪唑、1-甲基吡咯烷、1-乙基吡咯烷、1-丙基吡咯烷、1-异丙基吡咯烷、1-丁基吡咯烷、1-异丁基吡咯烷、1-戊基吡咯烷、1-异戊基吡咯烷、1-辛基吡咯烷、1-环己基吡咯烷、1-苯基吡咯烷、哌啶、1-甲基哌啶、1-乙基哌啶、1-丙基哌啶、1-异丙基哌啶、1-丁基哌啶、1-异丁基哌啶、1-戊基哌啶、1-异戊基哌啶、1-辛基哌啶、1-环己基哌啶、1-苯基哌啶、哌嗪、1-甲基哌嗪、1-乙基哌嗪、1-丙基哌嗪、1-异丙基哌嗪、1-丁基哌嗪、1-异丁基哌嗪、1-戊基哌嗪、1-异戊基哌嗪、1-辛基哌嗪、1-环己基哌嗪、1-苯基哌嗪、1,4-二甲基哌嗪、1,4-二乙基哌嗪、1,4-二丙基哌嗪、1,4-二异丙基哌嗪、1,4-二丁基哌嗪、1,4-二异丁基哌嗪、1,4-二戊基哌嗪、1,4-二异戊基哌嗪、1,4-二辛基哌嗪、1,4-二环己基哌嗪、1,4-二苯基哌嗪、吡啶、2-甲基吡啶、4-甲基吡啶、六甲基二硅氮烷、吗啉、N-甲基吗啉等。
可在此处中用作内电子给体的羧酸酯的例子有任何包括至少一个C(=O)-O-C酯键的羧酸酯化合物。羧酸酯的例子有含酯键的饱和或不饱和的脂族、脂环族或芳族化合物。包括在羧酸酯的范围内的为包括杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。羧酸酯的其它例子有甲酸甲酯、乙酸甲酯、乙酸乙酯、乙酸乙烯酯、乙酸丙酯、乙酸丁酯、乙酸异丙酯、乙酸异丁酯、乙酸辛酯、乙酸环己酯、丙酸乙酯、戊酸乙酯、氯乙酸甲基酯、二氯乙酸乙基酯、甲基丙烯酸甲酯、丁烯酸乙酯、新戊酸乙酯、苯甲酸甲酯、苯甲酸乙酯、苯甲酸丙酯、苯甲酸丁酯、苯甲酸异丁酯、苯甲酸异丙酯、苯甲酸辛酯、苯甲酸环己酯、苯甲酸苯酯、苯甲酸苄酯、2-甲基苯甲酸甲酯、2-甲基苯甲酸乙酯、2-甲基苯甲酸丙酯、2-甲基苯甲酸异丙酯、2-甲基苯甲酸丁酯、2-甲基苯甲酸异丁酯、2-甲基苯甲酸辛酯、2-甲基苯甲酸环己酯、2-甲基苯甲酸苯酯、2-甲基苯甲酸苄酯、3-甲基苯甲酸甲酯、3-甲基苯甲酸乙酯、3-甲基苯甲酸丙酯、3-甲基苯甲酸异丙酯、3-甲基苯甲酸丁酯、3-甲基苯甲酸异丁酯、3-甲基苯甲酸辛酯、3-甲基苯甲酸环己酯、3-甲基苯甲酸苯酯、3-甲基苯甲酸苄酯、4-甲基苯甲酸甲酯、4-甲基苯甲酸乙酯、4-甲基苯甲酸丙酯、4-甲基苯甲酸异丙酯、4-甲基苯甲酸丁酯、4-甲基苯甲酸异丁酯、4-甲基苯甲酸辛酯、4-甲基苯甲酸环己酯、4-甲基苯甲酸苯酯、4-甲基苯甲酸苄酯、邻-氯苯甲酸甲酯、邻-氯苯甲酸乙酯、邻-氯苯甲酸丙酯、邻-氯苯甲酸异丙酯、邻-氯苯甲酸丁酯、邻-氯苯甲酸异丁酯、邻-氯苯甲酸戊酯、邻-氯苯甲酸异戊酯、邻-氯苯甲酸辛酯、邻-氯苯甲酸环己酯、邻-氯苯甲酸苯酯、邻-氯苯甲酸苄酯、间-氯苯甲酸甲酯、间-氯苯甲酸乙酯、间-氯苯甲酸丙酯、间-氯苯甲酸异丙酯、间-氯苯甲酸丁酯、间-氯苯甲酸异丁酯、间-氯苯甲酸戊酯、间-氯苯甲酸异戊酯、间-氯苯甲酸辛酯、间-氯苯甲酸环己酯、间-氯苯甲酸苯酯、间-氯苯甲酸苄酯、对-氯苯甲酸甲酯、对-氯苯甲酸乙酯、对-氯苯甲酸丙酯、对-氯苯甲酸异丙酯、对-氯苯甲酸丁酯、对-氯苯甲酸异丁酯、对-氯苯甲酸戊酯、对-氯苯甲酸异戊酯、对-氯苯甲酸辛酯、对-氯苯甲酸环己酯、对-氯苯甲酸苯酯、对-氯苯甲酸苄酯、马来酸二甲酯、邻苯二甲酸二甲酯、邻苯二甲酸二乙酯、邻苯二甲酸二丙酯、邻苯二甲酸二丁酯、邻苯二甲酸二异丁酯、邻苯二甲酸甲基·乙基酯、邻苯二甲酸甲基·丙基酯、邻苯二甲酸甲基·丁基酯、邻苯二甲酸甲基·异丁基酯、邻苯二甲酸乙基·丙基酯、邻苯二甲酸乙基·丁基酯、邻苯二甲酸乙基·异丁基酯、邻苯二甲酸丙基·丁基酯、邻苯二甲酸丙基·异丁基酯、对苯二甲酸二甲酯、对苯二甲酸二乙酯、对苯二甲酸二丙酯、对苯二甲酸二丁酯、对苯二甲酸二异丁酯、对苯二甲酸甲基·乙基酯、对苯二甲酸甲基·丙基酯、对苯二甲酸甲基·丁基酯、对苯二甲酸甲基·异丁基酯、对苯二甲酸乙基·丙基酯、对苯二甲酸乙基·丁基酯、对苯二甲酸乙基·异丁基酯、对苯二甲酸丙基·丁基酯、对苯二甲酸丙基·异丁基酯、间苯二甲酸二甲酯、间苯二甲酸二乙酯、间苯二甲酸二丙酯、间苯二甲酸二丁酯、间苯二甲酸二异丁酯、间苯二甲酸甲基·乙基酯、间苯二甲酸甲基·丙基酯、间苯二甲酸甲基·丁基酯、间苯二甲酸甲基·异丁基酯、间苯二甲酸乙基·丙基酯、间苯二甲酸乙基·丁基酯、间苯二甲酸乙基·异丁基酯、间苯二甲酸丙基·丁基酯、间苯二甲酸丙基·异丁基酯、乙酸纤维素、丁酸纤维素、纤维素的混合酯等。
可在此处用作内电子给体的硫代酸酯的例子有包括至少一个C(=O)-S-C硫代酸酯键的化合物。硫代酸酯的例子有包括硫代酸酯键的饱和或不饱和的脂族、脂环族或芳族化合物。包括在硫代酸酯的范围内的有包括杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。硫代酸酯的例子有硫羟乙酸甲酯、硫羟乙酸乙酯、硫羟乙酸丙酯、硫羟乙酸异丙酯、硫羟乙酸丁酯、硫羟乙酸异丁酯、硫羟乙酸戊酯、硫羟乙酸异戊酯、硫羟乙酸辛酯、硫羟乙酸环己酯、硫羟乙酸苯酯、硫羟乙酸2-氯乙酯、硫羟乙酸3-氯丙酯、硫代苯甲酸甲酯、硫代苯甲酸乙酯、硫代苯甲酸丙酯、硫代苯甲酸异丙酯、硫代苯甲酸丁酯、硫代苯甲酸异丁酯、硫代苯甲酸戊酯、硫代苯甲酸异戊酯、硫代苯甲酸辛酯、硫代苯甲酸环己酯、硫代苯甲酸苯酯、硫代苯甲酸2-氯乙酯、硫代苯甲酸3-氯丙酯等。
可在此处用作内电子给体的酰胺的例子有包括至少一个C(=O)-N酰胺键的化合物。酰胺的例子有含有酰胺键的饱和或不饱和的脂族、脂环族或芳族化合物。包括在酰胺的范围内的有包括杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。酰胺的例子有甲酰胺、乙酰胺、丙酰胺、异丁酰胺、三甲基乙酰胺、己酰胺、十八酰胺、环己烷酰胺、1-金刚烷酰胺、丙烯酰胺、甲基丙烯酰胺、2-氟乙酰胺、2-氯乙酰胺、2-溴乙酰胺、2,2-二氯乙酰胺、2,2,2-三氟乙酰胺、2,2,2-三氯乙酰胺、2-氯丙酰胺、苯甲酰胺、N-甲基甲酰胺、N-乙基甲酰胺、N-丙基甲酰胺、N-丁基甲酰胺、N-异丁基甲酰胺、N-戊基甲酰胺、N-环己基甲酰胺、甲酰苯胺、N-甲基乙酰胺、N-乙基乙酰胺、N-丙基乙酰胺、N-丁基乙酰胺、N-异丁基乙酰胺、N-戊基乙酰胺、N-环己基乙酰胺、乙酰苯胺、N-甲基丙酰胺、N-乙基丙酰胺、N-丙基丙酰胺、N-丁基丙酰胺、N-异丁基丙酰胺、N-戊基丙酰胺、N-环己基丙酰胺、N-苯基丙酰胺、N-甲基异丁酰胺、N-甲基三甲基乙酰胺、N-甲基己酰胺、N-甲基十八酰胺、N-甲基丙烯酰胺、N-甲基甲基丙烯酰胺、N-甲基-2-氟乙酰胺、N-甲基-2-氯乙酰胺、N-甲基-2-溴乙酰胺、N-甲基-2,2-二氯乙酰胺、N-甲基-2,2,2-三氟乙酰胺、N-甲基-2,2,2-三氯乙酰胺、N-甲基-2-氯丙酰胺、N,N-二甲基甲酰胺、N,N-二乙基甲酰胺、N,N-二异丙基甲酰胺、N,N-二丁基甲酰胺、N-甲基甲酰苯胺、N,N-二甲基乙酰胺、N,N-二乙基乙酰胺、N,N-二异丙基乙酰胺、N,N-二丁基乙酰胺、N-甲基乙酰苯胺、N,N-二甲基丙酰胺、N,N-二乙基丙酰胺、N,N-二异丙基丙酰胺、N,N-二丁基丙酰胺、N,N-二甲基异丁酰胺、N,N-二甲基三甲基乙酰胺、N,N-二甲基己酰胺、N,N-二甲基十八酰胺、N,N-二甲基丙烯酰胺、N,N-二甲基甲基丙烯酰胺、N,N-二甲基-2-氟乙酰胺、N,N-二甲基-2-氯乙酰胺、N,N-二甲基-2-溴乙酰胺、N,N-二甲基-2,2-二氯乙酰胺、N,N-二甲基-2,2,2-三氟乙酰胺、N,N-二乙基-2,2,2-三氟乙酰胺、N,N-二异丙基-2,2,2-三氟乙酰胺、N,N-二丁基-2,2,2-三氟乙酰胺、N,N-二甲基-2,2,2-三氯乙酰胺、N,N-二乙基-2,2,2-三氯乙酰胺、N,N-二异丙基-2,2,2-三氯乙酰胺、N,N-二丁基-2,2,2-三氯乙酰胺、N,N-二甲基-2-氯丙酰胺、1-乙酰基氮杂环丁烷、1-乙酰基吡咯烷、1-乙酰基哌啶、1-乙酰基哌嗪、1-乙酰基哌嗪、1,4-二乙酰基哌嗪等。
可在此处用作内电子给体的酸酐的例子有包括至少一个C(=O)-O-C(=O)酸酐键的化合物。酸酐的例子有含有酸酐键的饱和或不饱和的脂族、脂环族或芳族化合物。包括在酸酐的范围内的有包括杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。酸酐的例子有乙酸酐、丙酸酐、丁酸酐、异丁酸酐、戊酸酐、三甲基乙酸酐、己酸酐、庚酸酐、癸酸酐、月桂酸酐、十四酸酐、十六酸酐、十八酸酐、二十二烷酸酐、丁烯酸酐、甲基丙烯酸酐、油酸酐、亚油酸酐、氯乙酸酐、碘乙酸酐、二氯乙酸酐、三氟乙酸酐、一氯二氟乙酸酐、三氯乙酸酐、五氟丙酸酐、七氟丁酸酐、琥珀酸酐、甲基琥珀酸酐、2,2-二甲基琥珀酸酐、衣康酸酐、马来酸酐、戊二酸酐、二乙醇酸酐、苯甲酸酐、苯基琥珀酸酐、苯基马来酸酐、高邻苯二酸酐、靛红酸酐、邻苯二甲酸酐、四氟邻苯二甲酸酐、四溴邻苯二甲酸酐、混合酸酐等。
可在此处用作内电子给体的酰基卤的例子有包括至少一个-C(=O)-X酰基卤基团的化合物,其中X为卤素。例子有含酰基卤基团的饱和或不饱和的脂族、脂环族或芳族化合物。包括在酰基卤的范围内的有含杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。酰基卤的例子有乙酰氯、乙酰溴、氯乙酰氯、二氯乙酰氯、三氯乙酰氯、三氟乙酰氯、三溴乙酰氯、丙酰氯、丙酰溴、丁酰氯、异丁酰氯、三甲基乙酰氯、3-环戊基丙酰氯、2-氯丙酰氯、3-氯丙酰氯、叔丁基乙酰氯、异戊酰氯、己酰氯、庚酰氯、癸酰氯、月桂酰氯、十四酰氯、十六酰氯、十八酰氯、油酰氯、环戊烷甲酰氯、乙二酰氯、丙二酰氯、琥珀酰氯戊二酰氯、己二酰氯、庚二酰氯、辛二酰氯、壬二酰氯、癸二酰氯、十二烷二酰氯、甲氧基乙酰氯、乙氧基乙酰氯等。
可在此处用作内电子给体的醛的例子有包括至少一个C-C(=O)-H醛基的化合物。例子有含醛基的饱和或不饱和的脂族、脂环族或芳族化合物。包括在醛的范围内的有包括杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。醛的例子有甲醛、乙醛、丙醛、异丁醛、三甲基乙醛、丁醛、2-甲基丁醛、戊醛、异戊醛、己醛、2-乙基己醛、庚醛、癸醛、丁烯醛、丙烯醛、异丁烯醛、2-乙基丙烯醛、氯乙醛、碘乙醛、二氯乙醛、三氟乙醛、一氯二氟乙醛、三氯乙醛、五氟丙醛、七氟丁醛、苯基乙醛、苯甲醛、邻-甲苯甲醛、间-甲苯甲醛、对-甲苯甲醛、反-肉桂醛、反-2-硝基肉桂醛、2-溴苯甲醛、2-氯苯甲醛、3-氯苯甲醛、4-氯苯甲醛等。
可在此处用作内电子给体的酮的例子有包括至少一个C-C(=O)-C酮键的化合物。例子有含酮键的饱和或不饱和的脂族、脂环族或芳族化合物。包括在酮的范围内的有含杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。酮的例子有丙酮、2-丁酮、3-甲基-2-丁酮、频哪酮、2-戊酮、3-戊酮、3-甲基-2-戊酮、4-甲基-2-戊酮、2-甲基-3-戊酮、4,4-二甲基-2-戊酮、2,4-二甲基-3-戊酮、2,2,4,4-四甲基-3-戊酮、2-己酮、3-己酮、5-甲基-2-己酮、2-甲基-3-己酮、2-庚酮、3-庚酮、4-庚酮、2-甲基-3-庚酮、5-甲基-3-庚酮、2,6-二甲基-4-庚酮、2-辛酮、3-辛酮、4-辛酮、苯乙酮、二苯甲酮、异亚丙基丙酮、六氟丙酮、全氟-2-丁酮、1,1,1-三氯丙酮等。
可在此处用作内电子给体的腈的例子有包括至少一个C-C≡N腈基的化合物。例子有含腈基的饱和或不饱和的脂族、脂环族或芳族化合物。包括在腈的范围内的有含杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。腈的例子有乙腈、丙腈、异丙腈、丁腈、异丁腈、戊腈、异戊腈、三甲基乙腈、己腈、庚腈、庚基氰(heptyl cyanide)、辛基氰(octyl cyanide)、十一腈、丙二腈、丁二腈、戊二腈、己二腈、癸二腈、烯丙基腈、丙烯腈、巴豆腈、甲基丙烯腈、富马腈、四氰乙烯、环戊烷腈、环己烷腈、二氯乙腈、氟乙腈、三氯乙腈、苄腈、苄基氰、2-甲基苄基氰、2-氯苄腈、3-氯苄腈、4-氯苄腈、邻-甲苯基氰、间-甲苯基氰、对-甲苯基氰等。
可在此处用作内电子给体的胩的例子有包括至少一个C-N≡C异腈基的化合物。例子有含异腈基的饱和或不饱和的脂族、脂环族或芳族化合物。包括在胩的范围内的有含杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。胩的例子有甲胩、乙胩、丙胩、异丙胩、正丁胩、叔丁胩、仲丁胩、戊基氰、己胩、庚胩、辛胩、壬胩、癸胩、十一胩、苄胩、2-甲基苄胩、2-氯苯并胩、3-氯苯并胩、4-氯苯并胩、邻-甲基苯甲胩、间-甲基苯甲胩、对-甲基苯甲胩、二氯苯基胩、1,4-亚苯基二胩等。
可在此处用作内电子给体的硫氰酸盐的例子有包括至少一个C-SCN硫氰酸根的化合物。例子有含硫氰酸根的饱和或不饱和的脂族、脂环族或芳族化合物。包括在硫氰酸盐的范围内的有含杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。硫氰酸盐的例子有硫氰酸甲酯、硫氰酸乙酯、硫氰酸丙酯、硫氰酸异丙酯、硫氰酸正丁酯、硫氰酸叔丁酯、硫氰酸仲丁酯、硫氰酸戊酯、硫氰酸己酯、硫氰酸庚酯、硫氰酸辛酯、硫氰酸壬酯、硫氰酸癸酯、硫氰酸十一烷基酯、硫氰酸苄酯、硫氰酸苯基酯、硫氰酸4’-溴苯基酰基酯、硫氰酸2-甲基苄基酯、2-氯苯并硫氰酸酯、3-氯苯并硫氰酸酯、4-氯苯并硫氰酸酯、邻-甲基苯甲硫氰酸酯、间-甲基苯甲硫氰酸酯、对-甲基苯甲硫氰酸酯等。
可在此处用作内电子给体的异硫氰酸盐的例子有含至少一个C- NCS异硫氰酸根的化合物。例子有含异硫氰酸根的饱和或不饱和的脂族、脂环族或芳族化合物。包括在异硫氰酸盐的范围内的有含杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。异硫氰酸盐的例子有异硫氰酸甲酯、异硫氰酸乙酯、异硫氰酸丙酯、异硫氰酸异丙酯、异硫氰酸正丁酯、异硫氰酸叔丁酯、异硫氰酸仲丁酯、异硫氰酸戊酯、异硫氰酸己酯、异硫氰酸庚酯、异硫氰酸辛酯、异硫氰酸壬酯、异硫氰酸癸酯、异硫氰酸十一烷基酯、异硫氰酸苯基酯、异硫氰酸苄酯、异硫氰酸苯乙基酯、异硫氰酸邻-甲苯基酯、异硫氰酸2-氟苯基酯、异硫氰酸3-氟苯基酯、异硫氰酸4-氟苯基酯、异硫氰酸2-硝基苯基酯、异硫氰酸3-硝基苯基酯、异硫氰酸4-硝基苯基酯、异硫氰酸2-氯苯基酯、异硫氰酸2-溴苯基酯、异硫氰酸3-氯苯基酯、异硫氰酸3-溴苯基酯、异硫氰酸4-氯苯基酯、异硫氰酸2,4-二氯苯基酯、异硫氰酸R-(+)-α-甲基苄基酯、异硫氰酸S-(-)-α-甲基苄基酯、异硫氰酸3-异丙烯基-α,α-二甲基苄基酯、反-2-苯基环丙基异硫氰酸酯、1,3-双(异氰酸根合甲基)-苯、1,3-双(1-异氰酸根合-1-甲基乙基)-苯、异硫氰酸2-乙基苯基酯、异硫氰酸苯甲酰基酯、异硫氰酸1-萘基酯、异硫氰酸苯甲酰基酯、异硫氰酸4-溴苯基酯、异硫氰酸2-甲氧基苯基酯、异硫氰酸间-甲苯基酯、α,α,α-三氟-间-甲苯基异硫氰酸酯、3-氟苯基异硫氰酸酯、3-氯苯基异硫氰酸酯、3-溴苯基异硫氰酸酯、1,4-亚苯基二异硫氰酸酯、1-异硫氰酸根合-4-(反-4-丙基环己基)苯、1-(反-4-己基环己基)-4-异硫氰酸根合苯、1-异硫氰酸根合-4-(反-4-辛基环己基)苯、异硫氰酸2-甲基苄基酯、2-氯苯并异硫氰酸酯、3-氯苯并异硫氰酸酯、4-氯苯并异硫氰酸酯、间-甲基苯甲异硫氰酸酯、对-甲基苯甲异硫氰酸酯等。
可在此处用作内电子给体的亚砜的例子有含至少一个C-S(=O)-亚砜(sulfoxo)基团的化合物。例子有含亚砜基团的饱和或不饱和的脂族、脂环族或芳族化合物。包括在亚砜的范围内的有含杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。亚砜的例子有甲基亚砜、乙基亚砜、丙基亚砜、丁基亚砜、戊基亚砜、己基亚砜、庚基亚砜、辛基亚砜、壬基亚砜、癸基亚砜、苯基亚砜、对-甲苯基亚砜、间-甲苯基亚砜、邻-甲苯基亚砜、甲基苯基亚砜、(R)-(+)-甲基对-甲苯基亚砜、(S)-(-)-甲基苯基亚砜、苯基乙烯基亚砜、4-氯苯基亚砜、甲基(苯基亚硫酰基)乙酸酯、苄基亚砜、四亚甲基亚砜、甲基甲基亚硫酰基甲基硫醚、dl-甲硫氨酸亚砜、dl-甲硫氨酸亚硫酰基亚胺(sulfoximine)等。
可在此处用作内电子给体的砜的例子有包括至少一个C-S(=O)2-C砜基的化合物。例子有含砜基的饱和或不饱和的脂族、脂环族或芳族化合物。包括在砜的范围内的有含杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。砜的例子有甲砜、乙砜、丙砜、丁砜、甲基乙烯基砜、乙基乙烯基砜、二乙烯基砜、苯基乙烯基砜、烯丙基苯基砜、顺-1,2-双(苯基磺酰)乙烯、2-(苯基磺酰)四氢吡喃、氯甲基苯基砜、溴甲基苯基砜、苯基三溴甲基砜、2-氯乙基苯基砜、甲基硫代甲基苯基砜、(苯基磺酰)乙腈、氯甲基对-甲苯基砜、N,N-双(对-甲苯基磺酰甲基)-乙胺、甲基硫代甲基对-甲苯基砜、2-(苯基磺酰)乙酰苯、甲基苯基磺酰乙酸酯、4-氟苯基甲基砜、4-氯苯基2-氯-1,1,2-三氟乙基砜、甲苯磺酰基甲基胩、苯基砜、苄基砜、苯基反-苯乙烯基砜、1-甲基-2-((苯基磺酰)甲基)-苯、1-溴甲基-2-((苯基磺酰)-甲基)苯、对-甲苯基砜、双(苯基磺酰)甲烷、4-氯苯基苯基砜、4-氟苯基砜、4-氯苯基砜、4,4’-磺酰基双(甲基苯甲酸酯)、9-氧代-9H-噻吨-3-腈10,10-二氧化物、四亚甲基砜、3-甲基环丁砜、2,4-二甲基环丁砜、反-3,4-二氯四氢噻吩1,1-二氧化物、反-3,4-二溴四氢噻吩1,1-二氧化物、3,4-环氧四氢噻吩-1,1-二氧化物、丁二烯砜、3-乙基-2,5-二氢噻吩-1,1-二氧化物等。
可在此处用作内电子给体的磷化合物的例子有饱和或不饱和的脂族、脂环族或芳族的、具有2到50个碳原子、包括至少一个磷原子的化合物。包括在磷化合物的范围内的有含杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。磷化合物的例子有三甲基膦、三乙基膦、亚磷酸三甲酯、亚磷酸三乙酯、六甲基磷三酰胺、六甲基磷酰胺、氧化三哌啶膦、三苯基膦、三-对甲苯基膦、三-间甲苯基膦、三-邻甲苯基膦、甲基二苯基膦、乙基二苯基膦、异丙基二苯基膦、烯丙基二苯基膦、环己基二苯基膦、苄基二苯基膦、二-叔丁基二甲基亚磷酰胺、二-叔丁基二乙基亚磷酰胺、二-叔丁基二异丙基亚磷酰胺;二烯丙基二异丙基亚磷酰胺等。
可在此处用作内电子给体的有机硅化合物的例子有饱和或不饱和的脂族、脂环族或芳族的、具有2到50个碳原子、包括至少一个氧原子的化合物。包括在有机硅化合物的范围内的有含杂原子的化合物,其中杂原子为除碳之外的选自元素周期表第13、14、15、16和17族的原子。有机硅化合物的例子有原硅酸四甲酯、原硅酸四乙酯、原硅酸四丙酯、原硅酸四丁酯、三氯甲氧基硅烷、三氯乙氧基硅烷、三氯丙氧基硅烷、三氯异丙氧基硅烷、三氯丁氧基硅烷、三氯异丁氧基硅烷、二氯二甲氧基硅烷、二氯二乙氧基硅烷、二氯二丙氧基硅烷、二氯二异丙氧基硅烷、二氯二丁氧基硅烷、二氯二异丁氧基硅烷、一氯三甲氧基硅烷、一氯三乙氧基硅烷、一氯三丙氧基硅烷、一氯三异丙氧基硅烷、一氯三丁氧基硅烷、一氯三异丁氧基硅烷、二甲基甲氧基硅烷、二乙基甲氧基硅烷、二丙基甲氧基硅烷、二异丙基甲氧基硅烷、二丁基甲氧基硅烷、二异丁基甲氧基硅烷、二戊基甲氧基硅烷、二环戊基甲氧基硅烷、二己基甲氧基硅烷、二环己基甲氧基硅烷、二苯基甲氧基硅烷、二甲基乙氧基硅烷、二乙基乙氧基硅烷、二丙基乙氧基硅烷、二异丙基乙氧基硅烷、二丁基乙氧基硅烷、二异丁基乙氧基硅烷、二戊基乙氧基硅烷、二环戊基乙氧基硅烷、二己基乙氧基硅烷、二环己基乙氧基硅烷、二苯基乙氧基硅烷、三甲基甲氧基硅烷、三乙基甲氧基硅烷、三丙基甲氧基硅烷、三异丙基甲氧基硅烷、三丁基甲氧基硅烷、三异丁基甲氧基硅烷、三戊基甲氧基硅烷、三环戊基甲氧基硅烷、三己基甲氧基硅烷、三环己基甲氧基硅烷、三苯基甲氧基硅烷、三甲基乙氧基硅烷、三乙基乙氧基硅烷、三丙基乙氧基硅烷、三异丙基乙氧基硅烷、三丁基乙氧基硅烷、三异丁基乙氧基硅烷、三戊基乙氧基硅烷、三环戊基乙氧基硅烷、三己基乙氧基硅烷、三环己基乙氧基硅烷、三苯基乙氧基硅烷、二甲基二甲氧基硅烷、二乙基二甲氧基硅烷、二丙基二甲氧基硅烷、二异丙基二甲氧基硅烷、二丁基二甲氧基硅烷、二异丁基二甲氧基硅烷、二戊基二甲氧基硅烷、二环戊基二甲氧基硅烷、二己基二甲氧基硅烷、二环己基二甲氧基硅烷、二苯基二甲氧基硅烷、二甲基二乙氧基硅烷、二乙基二乙氧基硅烷、二丙基二乙氧基硅烷、二异丙基二乙氧基硅烷、二丁基二乙氧基硅烷、二异丁基二乙氧基硅烷、二戊基二乙氧基硅烷、二环戊基二乙氧基硅烷、二己基二乙氧基硅烷、二环己基二乙氧基硅烷、二苯基二乙氧基硅烷、环戊基甲基二甲氧基硅烷、环戊基乙基二甲氧基硅烷、环戊基丙基二甲氧基硅烷、环戊基甲基二乙氧基硅烷、环戊基乙基二乙氧基硅烷、环戊基丙基二乙氧基硅烷、环己基甲基二甲氧基硅烷、环己基乙基二甲氧基硅烷、环己基丙基二甲氧基硅烷、环己基甲基二乙氧基硅烷、环己基乙基二乙氧基硅烷、环己基丙基二乙氧基硅烷、甲基三甲氧基硅烷、乙基三甲氧基硅烷、乙烯基三甲氧基硅烷、丙基三甲氧基硅烷、异丙基三甲氧基硅烷、丁基三甲氧基硅烷、异丁基三甲氧基硅烷、叔丁基三甲氧基硅烷、苯基三甲氧基硅烷、降冰片烷三甲氧基硅烷、甲基三乙氧基硅烷、乙基三乙氧基硅烷、乙烯基三乙氧基硅烷、丙基三乙氧基硅烷、异丙基三乙氧基硅烷、丁基三乙氧基硅烷、异丁基三乙氧基硅烷、叔丁基三乙氧基硅烷、苯基三乙氧基硅烷、降冰片烷三乙氧基硅烷、2,3-二甲基-2-(三甲氧基甲硅烷基)丁烷、2,3-二甲基-2-(三乙氧基甲硅烷基)丁烷、2,3-二甲基-2-(三丙氧基甲硅烷基)丁烷、2,3-二甲基-2-(三异丙氧基甲硅烷基)丁烷、2,3-二甲基-2-(三甲氧基甲硅烷基)戊烷、2,3-二甲基-2-(三乙氧基甲硅烷基)戊烷、2,3-二甲基-2-(三丙氧基甲硅烷基)戊烷、2,3-二甲基-2-(三异丙氧基甲硅烷基)戊烷、2-甲基-3-乙基-2-(三甲氧基甲硅烷基)戊烷、2-甲基-3-乙基-2-(三乙氧基甲硅烷基)戊烷、2-甲基-3-乙基-2-(三丙氧基甲硅烷基)戊烷、2-甲基-3-乙基-2-(三异丙氧基甲硅烷基)戊烷、2,3,4-三甲基-2-(三甲氧基甲硅烷基)戊烷、2,3,4-三甲基-2-(三乙氧基甲硅烷基)戊烷、2,3,4-三甲基-2-(三丙氧基甲硅烷基)戊烷、2,3,4-三甲基-2-(三异丙氧基甲硅烷基)戊烷、2,3-二甲基-2-(三甲氧基甲硅烷基)己烷、2,3-二甲基-2-(三乙氧基甲硅烷基)己烷、2,3-二甲基-2-(三丙氧基甲硅烷基)己烷、2,3-二甲基-2-(三异丙氧基甲硅烷基)己烷、2,4-二甲基-3-乙基-2-(三甲氧基甲硅烷基)戊烷、2,4-二甲基-3-乙基-2-(三乙氧基甲硅烷基)戊烷、2,4-二甲基-3-乙基-2-(三丙氧基甲硅烷基)戊烷、2,4-二甲基-3-乙基-2-(三异丙氧基甲硅烷基)戊烷、2,4-二甲基-3-异丙基-2-(三甲氧基甲硅烷基)戊烷、2,4-二甲基-3-异丙基-2-(三乙氧基甲硅烷基)戊烷、2,4-二甲基-3-异丙基-2-(三丙氧基甲硅烷基)戊烷、2,4-二甲基-3-异丙基-2-(三异丙氧基甲硅烷基)戊烷、六甲基二硅氧烷、1,1,1,3,3,3-六甲基二硅氮烷等。
本发明还提供了包括以下物质的催化剂体系:
(A)至少一种如上所述的固体前催化剂;和
(B)至少一种助催化剂
所述固体前催化剂可或可不包括如此处所述的内电子给体。
在所述固体前催化剂中,优选助催化剂与过渡金属的摩尔比为大约0.1到大约1000。在所述固体前催化剂中,优选所述助催化剂与过渡金属的摩尔比为大约1到大约250。在所述固体前催化剂中,最优选助催化剂与所述过渡金属的摩尔比为大约5到大约100。
用于本发明的至少一种助催化剂可为任何能在烯烃聚合或共聚中将所述固体前催化剂活化的有机金属化合物或其混合物。例如,所述助催化剂组分可包括上面参考的元素周期表的第1、2、11、12、13和/或14族的元素。这些元素的例子有锂、镁、铜、锌、硼、铝、硅、锡等。
优选地所述助催化剂为至少一种经验式:
RnEYmHp或(QER)q的化合物,或其混合物,
其中,
R各自独立为烃基;
E选自硼、铝、镓和铟;
Y各自独立为单阴离子单齿配体;
Q选自-O-、-S-、-N(R)-、-N(OR)-、-N(SR)-、-N(NR2)-、-N(PR2)-、-P(R)-、-P(OR)-、-P(SR)-和-P(NR2)-;
n>0,m≥0,p≥0,并且n+m+p=3;并且
q≥1。
此处所用术语“烃基”表示包括碳和氢原子的单价、线性、支化、环状或多环的基团。所述烃基可任选包括除碳和氢之外的选自周期表的第13、14、15、16和17族的原子。单价烃基的例子包括下面的基团:C1-C30的烷基;被一个或多个选自C1-C30的烷基、C3-C15的环烷基或芳基的基团取代的C1-C30的烷基;C3-C15的环烷基;被一个或多个选自C1-C20的烷基、C3-C15的环烷基或芳基的基团取代的C3-C15的环烷基;C6-C15的芳基;和被一个或多个选自C1-C30的烷基、C3-C15的环烷基或芳基的基团取代的C6-C15的芳基;其中芳基优选表示取代的或未取代的苯基、萘基或蒽基。
单阴离子单齿配体Y的例子包括卤素负离子、-OR、-OBR2、-OSR、-ONR2、-OPR2、-NR2、-N(R)BR2、-N(R)OR、-N(R)SR、-N(R)NR2、-N(R)PR2、-N(BR2)2、-N=CR2、-N=NR、-N=PR、-SR、-SBR2、-SOR、-SNR2、-SPR2、-PR2等。R各自独立为如上定义的烃基。卤素负离子的例子包括氟离子、氯离子、溴离子和碘离子。
醇盐的例子有甲醇盐、乙醇盐、正丙醇盐、异丙醇盐、环丙醇盐、正丁醇盐、异丁醇盐、仲丁醇盐、叔丁醇盐、环丁醇盐、正戊醇盐、异戊醇盐、仲戊醇盐、叔戊醇盐、新戊醇盐、环戊醇盐、正己醇盐、环己醇盐、庚醇盐、辛醇盐、壬醇盐、癸醇盐、十一烷醇盐、十二烷醇盐、2-乙基己醇盐、酚盐、2,6-二甲基酚盐、2,6-二-异丙基酚盐、2,6-二苯基酚盐、2,6-二基酚盐、2,4,6-三甲基酚盐、2,4,6-三异丙基酚盐、2,4,6-三苯基酚盐、2,4,6-三基酚盐、苄醚、薄荷醇盐等,以及卤代醇盐,例如三氟甲醇盐、三氟乙醇盐、三氟异丙醇盐、六氟异丙醇盐、七氟异丙醇盐、三氟叔丁醇盐、六氟叔丁醇盐、三氟甲醇盐、三氯乙醇盐、三氯异丙醇盐等。
硫醇盐的例子有甲基硫醇盐、乙基硫醇盐、正丙基硫醇盐、异丙基硫醇盐、环丙基硫醇盐、正丁基硫醇盐、异丁基硫醇盐、仲丁基硫醇盐、叔丁基硫醇盐、环丁基硫醇盐、正戊基硫醇盐、异戊基硫醇盐、仲戊基硫醇盐、叔戊基硫醇盐、新戊基硫醇盐、环戊基硫醇盐、正己基硫醇盐、环己基硫醇盐、苯基硫醇盐、2,6-二甲基苯基硫醇盐、2,6-二-异丙基苯基硫醇盐、2,6-二苯基苯基硫醇盐、2,6-二基苯基硫醇盐、2,4,6-三甲基苯基硫醇盐、2,4,6-三异丙基苯基硫醇盐、2,4,6-三苯基苯基硫醇盐、2,4,6-三基苯基硫醇盐、苄基硫醇盐、庚基硫醇盐、辛基硫醇盐、壬基硫醇盐、癸基硫醇盐、十一烷基硫醇盐、十二烷基硫醇盐、2-乙基己基硫醇盐、基硫醇盐等,以及卤代的烷基硫醇盐,例如三氟甲基硫醇盐、三氟乙基硫醇盐、三氟异丙基硫醇盐、六氟异丙基硫醇盐、七氟异丙基硫醇盐、三氟-叔-丁基硫醇盐、六氟-叔-丁基硫醇盐、三氟甲基硫醇盐、三氯乙基硫醇盐、三氯-异丙基硫醇盐等。
酰胺的例子有二甲基酰胺、二乙基酰胺、二-正丙基酰胺、二-异丙基酰胺、二环丙基酰胺、二-正丁基酰胺、二-异丁基酰胺、二-仲丁基酰胺、二-叔丁基酰胺、二环丁基酰胺、二-正戊基酰胺、二-异戊基酰胺、二-仲戊基酰胺、二-叔戊基酰胺、二环戊基酰胺、二新戊基酰胺、二-正己基酰胺、二环己基酰胺、二庚基酰胺、二辛基酰胺、二-壬基酰胺、二癸基酰胺、二(十一烷基)酰胺、二(十二烷基)酰胺、二-2-乙基己基酰胺、二苯基酰胺、双-2,6-二甲基苯基酰胺、双-2,6-二-异丙基苯基酰胺、双-2,6-二苯基苯基酰胺、双-2,6-二基苯基酰胺、双-2,4,6-三甲基苯基酰胺、双-2,4,6-三异丙基苯基酰胺、双-2,4,6-三苯基苯基酰胺、双-2,4,6-三基苯基酰胺、二苄基酰胺、二己基酰胺、二环己基酰胺、二辛基酰胺、二癸基酰胺、二(十八烷基)酰胺、二苯基酰胺、二苄基酰胺、双-2,6-二甲基苯基酰胺、2,6-二-异丙基苯基酰胺、双-2,6-二苯基苯基酰胺、二烯丙基酰胺、二丙烯基酰胺、N-甲基苯胺;N-乙基苯胺;N-丙基苯胺;N-异丙基苯胺;N-丁基苯胺;N-异丁基苯胺;N-戊基苯胺;N-异戊基苯胺;N-辛基苯胺;N-环己基苯胺等;以及甲硅烷基酰胺如双(三甲代甲硅烷基)酰胺、双(三乙代甲硅烷基)酰胺、双(二甲基苯基甲硅烷基)酰胺、双(叔丁基二甲代甲硅烷基)酰胺、双(叔丁基二苯基甲硅烷基)酰胺、苯基(三甲代甲硅烷基)酰胺、苯基(三乙代甲硅烷基)酰胺、苯基(三甲代甲硅烷基)酰胺、甲基(三甲代甲硅烷基)酰胺、乙基(三甲代甲硅烷基)酰胺、正丙基(三甲代甲硅烷基)酰胺、异丙基(三甲代甲硅烷基)酰胺、环丙基(三甲代甲硅烷基)酰胺、正丁基(三甲代甲硅烷基)酰胺、异丁基(三甲代甲硅烷基)酰胺、仲丁基(三甲代甲硅烷基)酰胺、叔丁基(三甲代甲硅烷基)酰胺、环丁基(三甲代甲硅烷基)酰胺、正戊基(三甲代甲硅烷基)酰胺、异戊基(三甲代甲硅烷基)酰胺、仲戊基(三甲代甲硅烷基)酰胺、叔戊基(三甲代甲硅烷基)酰胺、新戊基(三甲代甲硅烷基)酰胺、环戊基(三甲代甲硅烷基)酰胺、正己基(三甲代甲硅烷基)酰胺、环己基(三甲代甲硅烷基)酰胺、庚基(三甲代甲硅烷基)酰胺和三乙代甲硅烷基三甲代甲硅烷基酰胺等,以及杂环酰胺,例如吡咯、吡啶、哌啶、哌嗪、吲哚、咪唑、吡咯、噻唑、嘌呤、邻苯二甲酰亚胺、1-氮杂环庚烷、1-氮杂环辛烷、1-氮杂环壬烷、1-氮杂环癸烷、它们的取代衍生物的共轭碱等。
磷化物的例子有二甲基磷化物、二乙基磷化物、二丙基磷化物、二丁基磷化物、二戊基磷化物、二己基磷化物、二环己基磷化物、二苯基磷化物、二苄基磷化物、双-2,6-二甲基苯基磷化物2,6-二异丙基苯基磷化物、2,6-二苯基苯基磷化物等,以及环状膦的共轭碱,例如磷杂环戊烷、磷杂环己烷、磷杂环庚烷、磷杂环辛烷、磷杂环壬烷、磷杂环癸烷等。
优选用作单阴离子单齿配体Y的基团为氟离子、氯离子、溴离子、甲醇盐、乙醇盐、正丙醇盐、异丙醇盐、丁醇盐、新戊醇盐、苄醇盐、三氟甲醇盐和三氟乙醇盐。
可将单阴离子单齿配体Y的混合物用作单阴离子单齿配体Y。
可用在本发明的方法中的助催化剂,其中在式RnEYmHp中的E为硼的例子包括三甲基硼烷、三乙基硼烷、三正丙基硼烷、三正丁基硼烷、三正戊基硼烷、三异戊二烯基硼烷、三正己基硼烷、三正庚基硼烷、三正辛基硼烷、三异丙基硼烷、三异丁基硼烷、三(环己基甲基)硼烷、三苯基硼烷、三(五氟苯基)硼烷、二甲基硼烷、二乙基硼烷、二正丙基硼烷、二正丁基硼烷、二正戊基硼烷、二异戊二烯基硼烷、二正己基硼烷、二正庚基硼烷、二正辛基硼烷、二异丙基硼烷、二异丁基硼烷、双(环己基甲基)硼烷、二苯基硼烷、双(五氟苯基)硼烷、氯化二甲基硼、氯化二乙基硼、氯化二正丙基硼、氯化二正丁基硼、氯化二正戊基硼、氯化二异戊二烯基硼、氯化二正己基硼、氯化二正庚基硼、氯化二正辛基硼、氯化二异丙基硼、氯化二异丁基硼、氯化双(环己基甲基)硼、氯化二苯基硼、氯化双(五氟苯基)硼、氟化二乙基硼、溴化二乙基硼、碘化二乙基硼、甲氧基二甲基硼、乙氧基二甲基硼、乙氧基二乙基硼、甲氧基二甲基硼、乙氧基二甲基硼、乙氧基二乙基硼、二氯化甲基硼、二氯化乙基硼、二氯化正丙基硼、二氯化正丁基硼、二氯化正戊基硼、二氯化异戊二烯基硼、二氯化正己基硼、二氯化正庚基硼、二氯化正辛基硼、二氯化异丙基硼、二氯化异丁基硼、二氯化(环己基甲基)硼、二氯化苯基硼、二氯化五氟苯基硼、一氯甲氧基甲基硼、一氯乙氧基甲基硼、一氯乙氧基乙基硼等。
可用在本发明的方法中的助催化剂,其中在式RnEYmHp中E为铝包括三甲基铝、三乙基铝、三正丙基铝、三正丁基铝、三正戊基铝、三异戊二烯基铝、三正己基铝、三正庚基铝、三正辛基铝、三异丙基铝、三异丁基铝、三(环己基甲基)铝、二甲基氢化铝、二乙基氢化铝、二正丙基氢化铝、二正丁基氢化铝、二正戊基氢化铝、二异戊二烯基氢化铝、二正己基氢化铝、二正庚基氢化铝、二正辛基氢化铝、二异丙基氢化铝、二异丁基氢化铝、双(环己基甲基)氢化铝、氯化二甲基铝、氯化二乙基铝、氯化二正丙基铝、氯化二正丁基铝、氯化二正戊基铝、氯化二异戊二烯基铝、氯化二正己基铝、氯化二正庚基铝、氯化二正辛基铝、氯化二异丙基铝、氯化二异丁基铝、氯化双(环己基甲基)铝、氟化二乙基铝、溴化二乙基铝、碘化二乙基铝、甲氧基二甲基铝、乙氧基二甲基铝、乙氧基二乙基铝、二氯化甲基铝、二氯化乙基铝、二氯化正丙基铝、二氯化正丁基铝、二氯化正戊基铝、二氯化异戊二烯基铝、二氯化正己基铝、二氯化正庚基铝、二氯化正辛基铝、二氯化异丙基铝、二氯化异丁基铝、二氯化(环己基甲基)铝、氯甲氧基甲基铝、氯乙氧基甲基铝、氯乙氧基乙基铝等。
其它适合的助催化剂的例子包括铝氧烷,特别是甲基铝氧烷。其它适合的式(QER)q的助催化剂的例子包括alumimines。
优选用作此处的助催化剂的是三烷基铝,例如三甲基铝、三乙基铝、三正丙基铝、三正丁基铝、三异丁基铝、三正己基铝、三异己基铝、三-2-甲基戊基铝、三正辛基铝、三正癸基铝;和卤化二烷基铝,例如氯化二甲基铝、氯化二乙基铝、氯化二丁基铝、氯化二异丁基铝、溴化二乙基铝和碘化二乙基铝;以及烷基铝的倍半卤化物,例如甲基铝的倍半氯化物、乙基铝的倍半氯化物、正丁基铝的倍半氯化物、异丁基铝的倍半氯化物、乙基铝的倍半氟化物、乙基铝的倍半溴化物和乙基铝的倍半碘化物。
最优选用作此处的助催化剂为三烷基铝,例如三甲基铝、三乙基铝、三正丙基铝、三异丁基铝、三正辛基铝;和卤化二烷基铝,例如氯化二甲基铝、氯化二乙基铝、氯化二异丁基铝以及烷基铝的倍半卤化物,例如甲基铝的倍半氯化物和乙基铝的倍半氯化物。
上述助催化剂的混合物也可用作此处的助催化剂。
本发明的另一方面提供了使用本发明的催化剂体系来聚合或共聚烯烃的方法,其中所述催化剂体系包括此处阐述的固体前催化剂和助催化剂。
优选本发明提供的方法用于聚合乙烯和/或共聚乙烯和至少一种或多种其它的烯烃,该方法包括在聚合条件下将乙烯和/或乙烯与至少一种或多种烯烃和本发明的催化剂体系接触。
本发明的聚合或共聚法可使用任何常规的方法实施。例如,可利用在悬浮物、溶液、超临界流体或气相介质中的聚合或共聚。本领域熟知所有的这些聚合或共聚的方法。
根据本发明,特别符合要求的用于制备聚乙烯聚合物和共聚物的方法为气相聚合法,优选使用流化床反应器。这种类型的反应器和反应器的操作方法是为人熟知的并且在美国专利号3,709,853、4,003,712、4,011,382、4,012,573、4,302,566、4,543,399、4,882,400、5,352,749、5,541,270号;加拿大专利991,798号和比利时专利839,380号中进行了完全的描述。这些专利公开了气相聚合法,其中可将聚合介质进行机械搅拌或通过气相单体和稀释剂的连续流来流化。通过引用将这些专利的全部内容结合到本文中。
一般而言,本发明的聚合法可象连续气相法(如流化床法)一样实施。用于本发明的方法中的流化床反应器一般包括反应区和所谓的减速区。所述反应区包括使聚合物颗粒生长的床,形成的聚合物颗粒和少量催化剂颗粒可通过气相单体和稀释剂的连续流来流化,从而将聚合热从反应区中除去。当将循环气流重新送入反应区时,任选可冷却并压缩一些循环气体以形成了液体,这样可提高循环气流的除热能力。通过简单的实验可容易地确定出符合要求的气流速率。气态单体补充到循环气流中的速率等于颗粒状聚合物产物及其夹带的单体从所述反应器中排出的速率,并且调节流经所述反应器的气体的组成,以保持所述反应区中的气相组成处于基本稳定的状态。将离开反应区的气体送入减速区,在那里除去夹带的颗粒。较细的夹带颗粒和灰尘可在旋风分离器和/或细过滤器中除去。所述气体流经热交换器,在热交换器中除去聚合热,在压缩机中压缩,然后回到所述反应区。
更详细地说,此处的流化床法的反应器温度为大约30℃到大约110℃。通常反应器在考虑了反应器中的聚合物产物的烧结温度后认为可行的最高温度下操作。
本发明的方法适用于制备烯烃的聚合物和/或烯烃与至少一种或多种其它烯烃的共聚物。优选本发明的方法适用于制备乙烯的聚合物和/或乙烯与至少一种或多种其它烯烃的共聚物。优选的烯烃为α-烯烃。所述烯烃可例如包括2到16个碳原子。特别优选通过本发明的方法制备的是线性聚乙烯的聚合物和共聚物。这种线性聚乙烯聚合物或共聚物优选为乙烯的线性均聚物和乙烯与至少一种α-烯烃的线性共聚物,其中所述乙烯的含量占全部涉及的单体重量的至少大约50%。此处可周的α-烯烃的例子有丙烯、1-丁烯、1-戊烯、1-己烯、1-庚烯、1-辛烯、4-甲基戊-1-烯、1-癸烯、1-十二烯、1-十六烯等。此处也可使用多烯,例如1,3-己二烯、1,4-己二烯、环戊二烯、二环戊二烯、4-乙烯基环己-1-烯、1,5-环辛二烯、5-亚乙烯基-2-降冰片烯和5-乙烯基-2-降冰片烯,以及可在聚合或共聚介质中原位形成的烯烃。当烯烃在聚合或共聚介质中原位形成时,可形成线性聚乙烯聚合物或含有长支链的共聚物。
可用本发明的方法制备的聚合物或共聚物的例子包括乙烯的聚合物和乙烯与至少一种或多种具有3到16个碳原子的α-烯烃的共聚物,其中所述乙烯的含量占所有涉及的单体重量的至少大约50%。
本发明的烯烃聚合物或共聚物可通过本领域熟知的任何技术制成薄膜。例如,可通过熟知的流延薄膜、吹胀薄膜和挤出贴面技术制备薄膜。
此外,可通过任何熟知的技术将烯烃聚合物或共聚物制成其它的制品,例如模塑制品。
在本发明的方法中,可用本领域熟知的任何方法引入所述固体前催化剂、助催化剂或催化剂体系。例如,可将固体前催化剂以淤浆或干燥的自由流动粉末的形式直接引入聚合或共聚介质之中。也可以预聚体的形式来使用所述固体前催化剂,其中所述预聚体在存在助催化剂时通过将固体前催化剂与一种或多种烯烃接触而获得。
由本发明制备的烯烃聚合物或共聚物的分子量可用任何熟知的方法例如通过使用氢来控制。当在聚合或共聚介质中氢与乙烯的摩尔比提高时,由所述聚合物或共聚物的熔体指数(I2)的增加可证明分子量受到了控制。
参考下面的实施例可以更容易地理解本发明。当然,在充分公开本发明时,对于本领域的技术人员而言,本发明的许多其他形式将变得显而易见,并因此会认识到这些实施例仅仅是说明而并不意味对本发明的范围作任何限制。
实施例
在下面的实施例中,使用了下面列出的测试方法来评价此处聚合物的分析和物理性能。
a)乙烯/烯烃共聚物的分子量分布(MWD),即Mw/Mn比例用装备了Ultrastyrogel色谱柱和折光率检测器的Waters Gel PermeationChromatograph Series150来测定。将装置的操作温度设置在140℃,洗脱溶剂为邻二氯苯,校正标准物包括10个已知精确分子量的、分子量范围在1000至130万的聚苯乙烯,以及聚乙烯标准物NBS 1475;
b)熔体流动指数(MI),I2根据ASTM D-1238、条件E、在190℃下测定,并且报告的单位为分克/分钟;
c)高载荷熔体流动指数(HLMI),I21根据ASTM D-1238、在条件F测定,所用重量为上述熔体流动指数的10.0倍;
d)熔体流动指数的比例(MFR)=I21/I2或高载荷下的熔体流动指数/熔体流动指数。
实施例1到21在氮气填充的Vacuum Atmospheres He-43-2手套箱中实施。在进入所述手套箱之前,在172kPa(25psi)的氮气压力下,将溶剂和己烯通过活化的氧化铝的床,随后通过BASF R-311铜催化剂的床进行纯化。在进入所述手套箱之前,将乙烯和氢气通过BASFR-311铜催化剂的床进行纯化。用3.2mm(1/8英寸)的末端带球阀的钢管将溶剂和气体引入手套箱中。所有其它的试剂由商业途径获得并且使用时未做处理。在实施例2、4和8-21中,使用了Grace Davison的SylopolTM5550载体。
实施例1(对照)
在搅拌下将237mg(Me3C(N-2,6-(CHMe2)2-C6H3)2)AlEt2在2mL甲苯中的溶液加入到0.0258mL TiCl4在3.0mL甲苯中的溶液中。将所得的溶液搅拌120秒。
实施例2
在搅拌下将237mg(Me3C(N-2,6-(CHMe2)2-C6H3)2)AlEt2在2mL甲苯中的溶液加入到0.0258mL TiCl4在3.0mL甲苯中的溶液中。将所得的溶液搅拌120秒。将1.0mL得到的溶液加到搅拌着的500mgSylopolTM5550载体在6.0mL甲苯中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用戊烷清洗所得的固体前催化剂粉末并且在真空中干燥30分钟。
实施例3(对照)
通过将5mL 0.196mL的2,2,6,6-四甲基庚二酮在甲苯中的溶液以2-4滴/秒的速率加到0.090mL Me3Al在4mL甲苯中的溶液中来制备溶液。将得到的溶液搅拌60分钟。然后,将得到的溶液加到10mL的容量瓶中,随后加入甲苯制成10.0mL的溶液。
在搅拌下,将0.0258mL TiCl4加到5.0mL上述溶液中。将得到的溶液搅拌30秒。
实施例4
通过将5mL 0.196mL的2,2,6,6-四甲基庚二酮在甲苯中的溶液以2-4滴/秒的速率加到0.090mL的Me3Al在4mL甲苯中的溶液中来制备溶液。将得到的溶液搅拌60分钟。然后,将得到的溶液加到10mL的容量瓶中,随后加入甲苯制成10.0mL的溶液。
在搅拌下,将0.0258mL TiCl4加到5.0mL上述溶液中。将得到的溶液搅拌30秒。将1.0mL得到的溶液加到搅拌着的500mgSylopolTM5550载体在6.0mL甲苯中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用戊烷清洗所得的固体前催化剂的粉末并且在真空中干燥30分钟。
实施例5-10
在下面的实施例5-10中,使用实施例1-4中制备的材料来实施聚合反应。在12盎司Fischer-Porter气溶胶反应器中实施聚合反应。这是一个瓶形设计,使用了可密封玻璃的橡胶封口。装上的反应器头可提供能安全地保持690kPa(100psi)压力的密封。通过绕在不锈钢的金属保护网上的1”宽的加热带来加热。当需要时,可通过多孔添加头加入气体或液态单体。在加入容器之前,在来源处可将压力和体积都保持。
对照实施例5和8
使用下面的程序实施对照实施例5和8。将0.0075mL的三甲基铝加到15mL己烯在100mL庚烷中的溶液中,并将得到的溶液加热到90℃。然后加入实施例1或3中的任一种溶液并密封反应器。将多余的压力从所述反应容器中排出。加入压力为55.2kPa(8psi)的氢气。加入乙烯直到给出662kPa(96psi)的总压力,并且通过连续地加入乙烯将这个压力保持1小时。此后,排除反应容器的压力并将所述容器从手套箱中取出。将接近300mL的试剂级丙酮加到所得的淤浆中并冷却淤浆至室温。用掺合机混合所述淤浆、过滤,并且用丙酮洗涤。将得到的粉末在40-50℃的真空烘箱中干燥至少4小时。
实施例6、7、9和10
使用下面的程序实施实施例6、7、9和10。将100mL庚烷加到反应器中。将1.0mL所述庚烷加到实施例2或4的任一种固体前催化剂中形成淤浆,并且加入0.0075mL的三甲基铝。将得到的淤浆加入所述反应器中。将所述容器密封,并且加热到90℃。从所述反应容器中排出多余的压力。加入压力为55.2kPa(8psi)的氢气。用乙烯的压力加入己烯直到给出662kPa(96psi)的总压力。并且通过连续地加入乙烯将这个压力保持1小时。此后,排除反应容器的压力并将所述容器从手套箱中取出。将接近300mL的试剂级丙酮加到淤浆中并冷却淤浆至室温。用掺合机混合所述淤浆、过滤,并且用丙酮洗涤。将得到的粉末在40-50℃的真空烘箱中干燥至少4小时。
在表1中报道了关于实施例5-10的其它细节。
表1.聚合数据
实施例 | 来自以 催化剂 聚合物 Kg聚 Mg聚 MWD Mn Mw下实施 的用量 的产量 合物 合物 Mw/ K K例的催 (g) /gTi hr /molTi Mn化剂 hr |
5 | 1 1.0mL 5.6 2.5 0.12 11.0 8.4 92 |
67 | 2 4.5mg 3.7 183 8.7 5.5 26.7 1482 4.5mg 4.9 242 11.6 4.9 26.3 128 |
8 | 3 1.0mL 5.2 2.3 0.11 10.2 17.2 176 |
910 | 4 4.5mg 10.9 538 25.8 4.6 24.9 1134 4.5mg 10.5 519 24.8 4.4 24.6 108 |
从上面的数据可以看出,使用载体上的固体前催化剂产生的活性(Kg聚合物/gTi hr)与使用可溶性非载体上的前催化剂产生的活性相比得到提高。此外,可以看到使用载体上的固体前催化剂制备的聚合物的分子量分布(Mw/Mn)与使用可溶性非载体上的催化剂制备的聚合物的分子量分布相比得到降低。
在下面的实施例11-21中,描述了另外的固体前催化剂的制备。期望实施例11-21的固体前催化剂可用于制备在烯烃聚合和共聚中有用的催化剂体系。
实施例11
通过将5mL 0.196mL 2,2,6,6-四甲基庚二酮的甲苯溶液以2-4滴/秒的速率加入到0.090mL Me3Al在4mL甲苯中的溶液中来制备溶液。将得到的溶液搅拌60分钟。然后,将得到的溶液加到10mL的容量瓶中,随后加入甲苯制成10.0mL的溶液。
在搅拌下,将0.0258mL TiCl4加入到5.0mL上述溶液中。将得到的溶液搅拌30秒。将0.038mL四氢呋喃加到这个溶液中。将得到的溶液搅拌30秒。将1.0mL得到的溶液加到搅拌着的500mgSylopolTM5550载体在6.0mL甲苯中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用戊烷清洗所得的固体前催化剂的粉末并且在真空中干燥30分钟。
实施例12
通过将5mL 0.0065g 2-硝基苯酚的甲苯溶液以2-4滴/秒的速率加入到0.0064mL Et3Al在15mL甲苯中的溶液中来制备溶液。将得到的溶液搅拌60分钟。然后,将得到的溶液加到25mL的容量瓶中,随后加入甲苯制成25.0mL的溶液。
将5.0mL上述溶液加入到0.0052mL TiCl4在5.0mL甲苯的溶液中。将得到的溶液搅拌60秒。将得到的溶液加到搅拌着的500mgSylopolTM5550载体在5mL甲苯中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用庚烷清洗所得的固体前催化剂的粉末并且在真空中干燥。
实施例13
将63mgAlMe2[Me3C(NCHMe2)2]在1mL庚烷中的溶液加入到0.0143mL TiCl4在20mL庚烷的溶液中。将得到的溶液搅拌120秒。将得到的溶液加到搅拌着的2500mg SylopolTM5550载体在20mL庚烷中的淤浆中。将得到的淤浆搅拌20分钟并且使用烧结玻璃漏斗过滤。然后用庚烷清洗所得的固体前催化剂的粉末并且在真空中干燥。
实施例14
将75mg Et2Al[环-C7H5-1,2-(NCHMe2)2]在3mL庚烷中的溶液加入到0.0143mL TiCl4在15mL庚烷的溶液中。将得到的溶液搅拌120秒。将得到的溶液加到搅拌着的2500mg SylopolTM5550载体在20mL庚烷中的淤浆中。将得到的淤浆搅拌20分钟并且使用烧结玻璃漏斗过滤。然后用庚烷清洗所得的固体前催化剂的粉末并且在真空中干燥。
实施例15
将131mg Et2Al[环-C7H5-1,2-(NCHMe2)2]在8mL庚烷中的溶液加入到0.0143mL TiCl4在10mL庚烷的溶液中。将得到的溶液搅拌120秒。将得到的溶液加到搅拌着的2500mg SylopolTM5550载体在30mL庚烷中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用庚烷清洗所得的固体前催化剂的粉末并且在真空中干燥。
实施例16
将70mg Me2Al[Me3CC(NCMe3)2]在8mL庚烷中的溶液加入到0.0143mL TiCl4在60mL庚烷的溶液中。将得到的溶液搅拌120秒。将得到的溶液加到搅拌着的2500mg SylopolTM5550载体在30mL庚烷中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用庚烷清洗所得的固体前催化剂的粉末并且在真空中干燥。
实施例17
将35mg Me2Al[Me3CC(NCMe3)2]在4mL庚烷中的溶液加入到0.0143mL TiCl4在14mL庚烷的溶液中。将得到的溶液搅拌120秒。将得到的溶液加到搅拌着的2500mg SylopolTM5550载体在30mL庚烷中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用庚烷清洗所得的固体前催化剂的粉末并且在真空中干燥。
实施例18
将131mg Et2Al[Me3CC(N-2,6-(CHMe2)-C6H3)2]在10mL庚烷中的溶液加入到0.0143mL TiCl4在10mL庚烷的溶液中。将得到的溶液搅拌600秒。将得到的溶液加到搅拌着的2500mg SylopolTM5550载体在20mL庚烷中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用庚烷清洗所得的固体前催化剂的粉末并且在真空中干燥。
实施例19
将76mg Et2Al[Me3CC(N-2,6-(CHMe2)-C6H3)2]在20mL庚烷中的溶液加入到0.0143mL TiCl4在10mL庚烷的溶液中。将得到的溶液搅拌120秒。将得到的溶液加到搅拌着的2500mg SylopolTM5550载体在35mL庚烷中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用庚烷清洗所得的固体前催化剂的粉末并且在真空中干燥。
实施例20
将44mg Me2Al[O-[2-CH(N-2,6-(CHMe2)]-C6H3)C6H3)2]在2mL戊烷中的溶液加入到0.0143mL TiCl4在18mL戊烷的溶液中。将得到的溶液搅拌300秒。将得到的溶液加到搅拌着的2500mg SylopolTM5550载体在25mL戊烷中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用戊烷清洗所得的固体前催化剂的粉末并且在真空中干燥。
实施例21
将33mg Me2Al[O-[2-CH(NC6H5)]-C6H3)2]在3mL戊烷中的溶液加入到0.0143mL TiCl4在17mL戊烷的溶液中。形成了沉淀,通过加入25mL戊烷和4mL甲苯可将所述沉淀重新溶解。将得到的溶液加到搅拌着的2500mg SylopolTM5550载体在25mL戊烷中的淤浆中。将得到的淤浆搅拌30分钟并且使用烧结玻璃漏斗过滤。然后用庚烷清洗所得的固体前催化剂的粉末并且在真空中干燥。
应当清楚理解的是本发明此处的形式只具有示例性,并不用来限制本发明的范围。本发明包括属于下面权利要求范围内的所有各种改变。
Claims (19)
1.一种通过使以下i)与ii)接触来制备的固体前催化剂,其中:
i)通过使至少一种经验式MX4表示的过渡金属化合物与至少一种式LxERnYmHp表示的烷基化剂在至少一种非质子溶剂中反应而获得的可溶性物种,其中,在式MX4中,M选自钛、锆和铪,X为选自氟、氯、溴和碘的卤素,在式LxERnYmHp中,L各自独立为通过两个选自氧、硫、硒、碲、氮、磷、砷、锑和铋原子或其混合物的原子连接到E上的单阴离子二齿配体,E选自硼、铝、镓和铟,R各自独立为烃基,Y各自独立为单阴离子单齿配体,0<x≤2,n>0,m≥0,p≥0,并且x+n+m+p=3,其中x、n、m和p为整数,和
ii)载体。
2.权利要求1的固体前催化剂,其中所述烷基化剂的存在量使得其与过渡金属化合物的摩尔比为0.1到100。
3.权利要求1的固体前催化剂,其中所述M为钛。
4.权利要求3的固体前催化剂,其中所述MX4为四氯化钛。
5.权利要求1的固体前催化剂,其中所述至少一种烷基化剂为经验式LxERnYmHp表示的有机金属化合物,所述有机金属化合物可将MX4烷基化,
在式LxERnYmHp中
L各自独立为通过两个选自氧、硫、硒、碲、氮、磷、砷、锑和铋原子或其混合物的原子连接到E上的单阴离子二齿配体;
E选自硼、铝、镓和铟,
R各自独立为烃基,
Y各自独立为单阴离子单齿配体,
0<x≤2,n>0,m≥0,p≥0,并且
x+n+m+p=3,其中x、n、m和p为整数。
6.权利要求5的固体前催化剂,其中所述E为铝。
7.权利要求1的固体前催化剂,其中将所述可溶性物种沉积在载体上。
8.权利要求1的固体前催化剂,其中所述载体选自无机氧化物和无机卤化物。
9.一种通过使以下i)与ii)接触来制备的固体前催化剂,其中:
i)通过使至少一种经验式MX4表示的过渡金属化合物与至少一种式LxERnYmHp表示的烷基化剂和至少一种内电子给体在至少一种非质子溶剂中反应而获得的可溶性物种,其中,在式MX4中,M选自钛、锆和铪,X为选自氟、氯、溴或碘的卤素,在式LxERnYmHp中,L各自独立为通过两个选自氧、硫、硒、碲、氮、磷、砷、锑和铋原子或其混合物的原子连接到E上的单阴离子二齿配体,E选自硼、铝、镓和铟,R各自独立为烃基,Y各自独立为单阴离子单齿配体,0<x≤2,n>0,m≥0,p≥0,并且x+n+m+p=3,其中x、n、m和p为整数,和
ii)载体。
10.一种催化剂体系,所述催化剂体系包括:
i)权利要求1的固体前催化剂,和
ii)至少一种助催化剂。
11.权利要求10的催化剂体系,其中所述至少一种助催化剂为可在烯烃聚合或共聚中活化所述固体前催化剂的有机金属化合物。
12.权利要求11的催化剂体系,其中所述至少一种助催化剂选自具有以下经验式的有机金属化合物:
RnEYmHp和(QER)q,
其中,
R各自独立为烃基;
E选自硼、铝、镓和铟;
Y各自独立为单阴离子单齿配体;
Q选自-O-、-S-、-N(R)-、-N(OR)-、-N(SR)-、-N(NR2)-、-N(PR2)-、-P(R)-、-P(OR)-、-P(SR)-和-P(NR2)-;
n>0,m≥0,p≥0,并且n+m+p=3;和
q≥1,其中n、m、p和q为整数。
13.权利要求12的催化剂体系,其中所述E为铝。
14.权利要求13的催化剂体系,其中所述助催化剂为三烷基铝化合物。
15.权利要求10的催化剂体系,其中所述助催化剂的存在量使得其与所述固体前催化剂的过渡金属的摩尔比为0.1到1000。
16.一种催化剂体系,所述催化剂体系包括:
i)权利要求9的固体前催化剂,和
ii)至少一种助催化剂。
17.一种用于聚合至少一种或多种烯烃的方法,所述方法包括在聚合条件下,将至少一种或多种烯烃与权利要求10的催化剂体系接触。
18.一种用于聚合至少一种或多种烯烃的方法,所述方法包括在聚合条件下,将至少一种或多种烯烃与权利要求16的催化剂体系接触。
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US48162900A | 2000-01-12 | 2000-01-12 | |
US09/481,629 | 2000-01-12 | ||
US09/753,699 | 2001-01-03 | ||
US09/753,699 US6465383B2 (en) | 2000-01-12 | 2001-01-03 | Procatalysts, catalyst systems, and use in olefin polymerization |
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CN1196719C true CN1196719C (zh) | 2005-04-13 |
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US (1) | US6677410B2 (zh) |
CN (1) | CN1196719C (zh) |
BR (1) | BRPI0107604B1 (zh) |
CA (1) | CA2396736A1 (zh) |
WO (1) | WO2001051526A1 (zh) |
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-
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- 2001-01-11 BR BRPI0107604-3A patent/BRPI0107604B1/pt active IP Right Grant
- 2001-01-11 CN CNB018063020A patent/CN1196719C/zh not_active Expired - Lifetime
- 2001-01-11 WO PCT/US2001/001028 patent/WO2001051526A1/en active Application Filing
- 2001-01-11 CA CA002396736A patent/CA2396736A1/en not_active Abandoned
-
2002
- 2002-08-13 US US10/217,680 patent/US6677410B2/en not_active Expired - Lifetime
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CN1416439A (zh) | 2003-05-07 |
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