CN1183451A - Improved non-azeotropic operating medium using in thermal circulation - Google Patents

Improved non-azeotropic operating medium using in thermal circulation Download PDF

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CN1183451A
CN1183451A CN95117074A CN95117074A CN1183451A CN 1183451 A CN1183451 A CN 1183451A CN 95117074 A CN95117074 A CN 95117074A CN 95117074 A CN95117074 A CN 95117074A CN 1183451 A CN1183451 A CN 1183451A
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CN1083474C (en
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顾雏军
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    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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Abstract

A series of non-azeotropic mixed refrigerants containing two or more components for thermal circulation system features that it is suitable for 4 working temp ranges of refrigeration, air conditioner, heat pump and electric generation by hot fluid, existing apparatus is reformed only a little or even not, and energy is saved by 15-30%.

Description

The improved non-azeotropic operating medium that in thermodynamic cycle, uses
This invention relates to the relevant working medium of circulation system, particularly, it relates to the non-azeotropic of a class, useful mixture, for example, in contrary circulation device, there is higher coefficient of performance COP[COP to be defined as or exports the ratio of specific energy (with regard to heating) and total input energy only from clean exhaust energy rate (with regard to regard to the refrigeration) the surrounding environment, be expressed as a constant unit and Ratio Conditions], in the normal circulation device, higher mechanical efficiency is arranged.
At present on commercial and industrial, the working medium that is used for circulation system is some pure components normally, or azeotropic and non-azeotropic working medium.
Many such mixtures are made public, and for example, following reference: 1. United States Patent (USP) 2,641,580, are entitled as " 1, the composition of a 1-Tetrafluoroethane and a chloropentafluoroethane azeotrope refrigerant ", contriver: Lewis, patent approval day: June 9 nineteen fifty-three.2. United States Patent (USP) 3,203,194, are entitled as " refrigerant compression process ", contriver: Fuderer, patent approval day: August 31 nineteen sixty-five.3. United States Patent (USP) 4,303,536, are entitled as " comprising a chlorine tetrafluoromethane non-azeotropic refrigerant forms and using method ", contriver: Orfeo etc., patent approval day: on December 1st, 1981.4. United States Patent (USP) 4,603,002, are entitled as " being used for method and refrigerant on freezing and the stored prod ", contriver: Nikolsky etc., patent approval day: on July 29th, 1986.5. Japanese Patent 52-70466 is entitled as " composition of low boiling point refrigerant ", and contriver: Kokai was published in DaKogyo KK in 1977.6. " refrigeration and air-conditioning ", author: B.C.Langly, nineteen eighty-two second edition.7. French Patent 2,130,556 (VEB MonsatorHaushait grossgeratekombinat).8. French Patent 2,177,785 (VEB MonsatorHaushait grossgeratekombinat).9. French Patent 2,607,144 (Institute Francaise du Petrole).10. " chloro-fluorocarbon and surrogate thereof ", author: M.F.Bouzianis (ArthurD.Little, 1988).The frigorific mixture 11. of used for automobile air conditioning " after market ", author: D.J.Bateman etc., SAE series technique paper 900216 (SAE international conference and exhibition one Detroit, Michigan, 26 days～March 2 February nineteen ninety." 12. ASHRAE heat supply, ventilation, air-conditioning and refrigeration glossary ", second edition (U.S.'s heat supply, refrigeration and air-conditioning man SCTE, 1991).
Under basic identical circulation external conditions, compare with a pure working medium or an azeotropic working medium, zeotrope (if outstanding) is a kind of so advantageous working medium, its advantage is, in isobaric evaporative process, inhale more heat, in isobaric condensation process, put more heat, in expansion process, do more merit or in compression process, do still less merit, that is to say, in contrary circulation device, higher coefficient of performance COP is arranged, in the normal circulation device, higher mechanical efficiency is arranged.
But each refrigeration agent all has certain limitation, for different vaporization temperature zone and condensing temperature zones, can not there be a kind of mix refrigerant to be suitable for simultaneously, therefore must seek more kinds of refrigeration agents, in addition, be used in refrigeration and the conditioning unit at these refrigeration agents of formerly being introduced in the patent, energy-saving effect is all not very big, is generally 5%-10%.In addition, these refrigeration agents formerly often require former refrigeration and conditioning unit are done transformation than many places, and this will bring difficulty to practical application and popularization.
The invention provides a series of non-azeotropic operating mediums that contain the circulation system of two or more component, its feature is, the energy-saving effect that larger proportion can be arranged, be applicable to refrigeration, air-conditioning, heat pump, four kinds of working temperature zones of hot fluid generator simultaneously, and need only carry out less change or not do the mixed non-azeotropic refrigerant of change refrigeration, air-conditioning, heat pump, thermal fluid power device in actual applications.This refrigeration agent can save energy 15-25% in air-conditioning plant, can save energy 15-30% in refrigeration plant, can save energy 15-30% in thermal-pump unit, can improve capacity usage ratio more than 20% in thermal fluid power device.
Fig. 1 has represented a kind of refrigeration unit that uses non-azeotropic operating medium of the present invention.
Fig. 2 has represented the description of device of the main assembly of air-conditioning plant of the sort of refrigeration unit manufacturing of a kind of Fig. 1 of use.
Referring to the shown refrigeration unit of Fig. 1, working medium among the present invention circulates in a following recycle system, the direction of the arrow indication at 15 places among round-robin direction such as the figure, fluid flows to condenser 30 by compressor 20 by the sensing at 15 places, is throttling valve 40 then, is vaporizer 50 then, flow back to compressor 20 then, condenser 30 links to each other with an interchanger, and passes through this interchanger heat transferred another one device, such as cooling column 60.Vaporizer 50 is to a specified control space cooling, with remove this spatial heat or it by a heat exchanger to a cryogen 70 supply colds.
Referring to Fig. 2, an air-conditioning system according to present invention manufacturing, comprise a refrigeration unit 140 (being presented among Fig. 1) and a fluid flow line 100, this streamline representative provides fresh air, the control loop 105 that comprises a recirculation, the air that air that is provided by 105 loops and 110 lines provide mixes in mixing tank 120, through fan in 130 and strainer, then to being similar to a refrigeration plant 140 shown in Figure 1, and then, lead to a part flow arrangement 170,180 then to humidifier 150.170,180 splitting systems are all supplied freezing air user 190 respectively respectively.
Working medium of the present invention can be used in compression, condensation, expansion and the evaporation circulating system on the thermal engineering, as the power generation assembly of thermal-pump unit, refrigeration plant, air-conditioning plant and hot-fluid, and does not need these systems to do expensive modification.
The impurity of being mentioned is meant any material except that the specified ingredients material and composition thereof in the present invention.
Can be used for specifically being constructed as follows of non-azeotropic operating medium two or more component, that be used for therrmodynamic system of containing of the present invention: 1. non-azeotropic working medium, its component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.40～0.999
CH 2＝CH-CH 3(R1270) 0.001～0.60
And allow to contain peak concentration and be no more than 20% impurity.2. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.30
CH 2F 2(R32) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.3. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
C 2HF 5(R125) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.4. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
CH 3CF 3(R143a) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.5. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
C 2HF 5(R125) 0.001～0.95
CH 2F 2(R32) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.6. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
CH 3CF 3(R143a) 0.001～0.95
CH 2F 2(R32) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.7. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
CH 3CF 3(R143a) 0.001～0.95
C 2F 5H(R125) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.8. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 3CFCL 2(R141b) 0.001～0.95
CH 2＝CH-CH 3(R1270) 0.001～0.3
And allow to contain peak concentration and be no more than 20% impurity.9. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
CHF 2Br(R22B1) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.10. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
C 3F 6(R1216) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.11. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
C 3HF 5(R1225) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.12. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
C 3H 3F 3(R1243) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.13. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
CHF 2CHF 2(R134) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.14. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
CF 3CFH 2(R134a) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.15. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
C 2H 3F(R1141) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.16. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.3
C 2H 2F 2(R1132a) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.17. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.15～0.99
CH 3CHF 2(R152a) 0.001～0.50
C 2F 4CLH(R124a) 0.001～0.70
CH 3CCLF 2(R142b) 0.001～0.80
And allow to contain peak concentration and be no more than 20% impurity.18. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.3～0.99
CH 3CHF 2(R152a) 0.001～0.5
CF 3CFH 2(R134a) 0.001～0.5
C 2F 4CLH(R124a) 0.001～0.6
And allow to contain peak concentration and be no more than 20% impurity.19. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.15～0.99
CH 3CHF 2(R152a) 0.001～0.5
CH 3CCLF 2(R142b) 0.001～0.7
C 2H 3FCL 2(R141b) 0.001～0.8
And allow to contain peak concentration and be no more than 20% impurity.20. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.2～0.99
CH 3CHF 2(R152a) 0.001～0.6
C 3F 5H(R1225) 0.001～0.7
And allow to contain peak concentration and be no more than 20% impurity.21. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.15～0.99
CH 3CHF 2(R152a) 0.001～0.6
C 3F 5H(R1225) 0.001～0.7
C 2F 4CLH(R124a) 0.001～0.8
And allow to contain peak concentration and be no more than 20% impurity.22. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.19～0.99
CH 3CHF 2(R152a) 0.001～0.6
C 3H 3F 3(R1243) 0.001～0.8
And allow to contain peak concentration and be no more than 20% impurity.23. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.27～0.99
CH 3CHF 2(R152a) 0.001～0.6
C 3H 3F 3(R1243) 0.001～0.7
C 2F 4CLH(R124a) 0.001～0.7
And allow to contain peak concentration and be no more than 20% impurity.24. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.17～0.99
CH 3CHF 2(R152a) 0.001～0.7
CF 2BrH(R22B1) 0.001～0.7
CH 3CCLF 2(R142b) 0.001～0.8
And allow to contain peak concentration and be no more than 20% impurity.25. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.15～0.99
CH 3CHF 2(R152a) 0.001～0.7
CF 2BrH(R22B1) 0.001～0.7
C 2F 4CLH(R124a) 0.001～0.8
And allow to contain peak concentration and be no more than 20% impurity.26. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.09～0.99
CH 3CHF 2(R152a) 0.001～0.7
CH 3CCLF 2(R142b) 0.001～0.2
C 2F 3CLH 2(R133a) 0.001～0.9
And allow to contain peak concentration and be no more than 20% impurity.27. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
C 2F 5H(R125) 0.01～0.7
CF 3CH 3(R143a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.28. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CHCLF 2(R22) 0.01～0.95
And allow to contain peak concentration and be no more than 20% impurity.29. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.7
And allow to contain peak concentration and be no more than 20% impurity.30. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.6
And allow to contain peak concentration and be no more than 20% impurity.31. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.7
And allow to contain peak concentration and be no more than 20% impurity.32. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.7
CF 3CFH 2(R134a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.33. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 3CFH 2(R134a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.34. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 3CFH 2(R134a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.35. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
CF 3CH 8(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 2HCF 2H(R134) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.36. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 2HCF 2H(R134) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.37. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 2HCF 2H(R134) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.38. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.7
CF 3CFH 2(R134a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.39. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.7
CF 2HCF 2H(R134) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.40. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.7
CF 3CFH 2(R134a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.41. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.7
CF 2HCF 2H(R134) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.42. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 2BrH(R22B1) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.43. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
C 3H 3F 3(R1243) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.44. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
C 3F 5H(R1225) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.45. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 2BrH(R22B1) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.46. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
C 3F 5H(R1225) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.47. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
C 3H 3F 3(R1243) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.48. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
C 3H 8(R290) 0.01～0.6
CF 2BrH(R22B1) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.49. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
C 3H 8(R290) 0.01～0.6
C 3F 5H(R1225) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.50. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
C 3H 8(R290) 0.01～0.6
C 3H 3F 3(R1243) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.51. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
C 3H 8(R290) 0.01～0.6
C 3F 5H(R1225) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.52. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
C 3H 8(R290) 0.01～0.6
CF 2BrH(R22B1) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.53. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
C 3H 8(R290) 0.01～0.6
C 3F 3H 3(R1243) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.54. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
C 3H 8(R290) 0.01～0.6
CF 2BrH(R22B1) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.55. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.90
C 3H 8(R290) 0.01～0.6
C 3F 5H(R1225) 0.01～0.90
And allow to contain peak concentration and be no more than 20% impurity.56. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
C 3H 8(R290) 0.01～0.6
C 3H 3F 3(R1243) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.57. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.27～0.99
CH 3CHF 2(R152a) 0.001～0.5
CH 3CCLF 2(R142b)?0.001～0.6
Figure A9511707400571
0.001～0.7
And allow to contain peak concentration and be no more than 20% impurity.58. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.3～0.95
CH 3CHF 2(R152a) 0.01～0.5
CH(CH 3) 3(R600a) 0.01～0.5
Figure A9511707400581
0.01～0.6
And allow to contain peak concentration and be no more than 20% impurity.59. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.3～0.9
CH 3CHF 2(R152a) 0.01～0.5
CH 3(CH 2) 2CH 3(R600)0.01～0.5
0.01～0.6
And allow to contain peak concentration and be no more than 20% impurity.60. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.3～0.95
CH(CH 3) 3(R600a) 0.01～0.5
CH 8CCLF 2(R142b) 0.01～0.5
0.01～0.6
And allow to contain peak concentration and be no more than 20% impurity.61. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.3～0.95
CH 3(CH 2) 2CH 3(R600)?0.01～0.5
CH 3CCLF 2(R142b) 0.01～0.5
0.01～0.6
And allow to contain peak concentration and be no more than 20% impurity.62. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.63. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 3CHF 2(R152a) 0.01～0.6
Figure A9511707400602
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.64. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 3(CH 2) 2CH 3(R600)0.01～0.6
Figure A9511707400603
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.65. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH(CH 3) 3(R600a) 0.01～0.6
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.66. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CFH 2(R134a) 0.01～0.9
CH 3(CH 2) 2CH 3(R600)0.01～0.6
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.67. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CFH 2(R134a) 0.01～0.9
CH(CH 3) 3(R600a) 0.01～0.6
Figure A9511707400613
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.68. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2HCF 2(R134) 0.01～0.9
CH 3(CH 2) 2CH 3(R600)?0.01～0.6
Figure A9511707400621
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.69. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2HCF 2H(R134) 0.01～0.9
CH(CH 3) 3(R600a) 0.01～0.6
Figure A9511707400622
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.70. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CFH 2(R134a) 0.01～0.9
C 2F 4CLH(R124a) 0.01～0.6
Figure A9511707400631
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.71. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2HCF 2H(R134) 0.01～0.9
C 2F 4CLH(R124a) 0.01～0.6
Figure A9511707400632
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.72. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
C 2H 2＝CH-CH 3(R1270)0.01～0.6
CH 3CHF 2(R152a) 0.01～0.7
0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.73. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.6
CH 3CHF 2(R152a) 0.01～0.7
Figure A9511707400641
0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.74. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.6
CH 3(CH 3) 3(R600a)?0.01～0.7
0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.75. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.6
CH 3(CH 2) 2CH 3(R600)0.01～0.7
0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.76. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 3CHF 2(R152a) 0.01～0.6
CF 3CFH 2(R134a) 0.01～0.7
0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.77. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 3CHF 2(R152a) 0.01～0.6
CF 2HCF 2H(R134) 0.01～0.7
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.78. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
CH 3CHF 2(R152a) 0.01～0.6
CH 3CCLF 2(R142b) 0.01～0.7
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.79. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
CH 3CHF 2(R152a) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.80. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
CH 3CCLF 2(R142b) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.81. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
CF 3CFH 2(R134a) 0.01～0.9
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And permitted to contain peak concentration and be no more than 20% impurity.82. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
CF 2HCF 2H(R134) 0.01～0.9
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.83. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.84. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.7
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.85. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
C 3H 8(R290) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.86. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH(CH 3) 3(R600a) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.87. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 3(CH 2) 2CH 3(R600)?0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.88. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH(CH 3) 3(R600a) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.89. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 3(CH 2) 2CH 3(R600)?0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.90. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
C 3H 8(R290) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
Theme of the present invention also comprises:
A kind of thermal apparatus of circulation system is characterized in that, this device uses 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90, the non-azeotropic operating medium that is constituted.
A kind of air-conditioning system of circulation system work is characterized in that, this device uses 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90 non-azeotropic operating mediums that constituted.
A kind of refrigeration system of circulation system work is characterized in that, this device uses 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90 non-azeotropic operating mediums that constituted.
A kind of heating system of circulation system work is characterized in that, this device uses 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90 non-azeotropic operating mediums that constituted.
A kind of thermal fluid power device of circulation system work is characterized in that, this device uses 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90 non-azeotropic operating mediums that constituted.

Claims (96)

1. a series of non-azeotropic operating mediums that are used for circulation system that contain two or more component, under basic identical circulation external conditions, compare with a pure working medium or a non-azeotropic working medium, its advantage is, in isobaric evaporative process, inhale more heat, in isobaric condensation process, put more heat, in expansion process, do more merit, perhaps in compression process, do merit still less.That is to say, in contrary circulation device, there is higher coefficient of performance COP[COP to be defined as or exports the ratio of specific energy (with regard to heating) and total input energy only from clean exhaust energy rate (with regard to regard to the refrigeration) the surrounding environment, be expressed as a constant unit and Ratio Conditions], in the normal circulation device, higher mechanical efficiency is arranged.
2. non-azeotropic working medium, its component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.40～0.999
CH 2＝CH-CH 3(R1270) 0.001～0.60
And allow to contain peak concentration and be no more than 20% impurity.
3. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270) 0.001～0.30
CH 2F 2(R32) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
4. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)0.001～0.3
C 2HF 5(R125) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
5. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)0.001～0.3
CH 3CF 3(R143a) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
6. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)0.001～0.3
C 2HF 5(R125) 0.001～0.95
CH 2F 2(R32) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
7. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)0.001～0.3
CH 3CF 3(R143a) 0.001～0.95
CH 2F 2(R32) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
8. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)0.001～0.3
CH 3CF 3(R143a) 0.001～0.95
C 2F 5H(R125) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
9. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 3CFCL 2(R141b) 0.001～0.95
CH 2＝CH-CH 3(R1270)0.001～0.3
And allow to contain peak concentration and be no more than 20% impurity.
10. non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)?0.001～0.3
CHF 2Br(R22B1) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
11. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)?0.001～0.3
C 3F 6(R1216) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
12. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)?0.001～0.3
C 3HF 5(R1225) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
13. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)0.001～0.3
C 3H 3F 3(R1243) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
14. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)0.001～0.3
CHF 2CHF 2(R134) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
15. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)0.001～0.3
CF 3CFH 2(R134a) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
16. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)0.001～0.3
C 2H 3F(R1141) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
17. a non-azeotropic working medium, its component fully and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.04～0.99
CH 2＝CH-CH 3(R1270)0.001～0.3
C 2H 2F 2(R1132a) 0.001～0.95
And allow to contain peak concentration and be no more than 20% impurity.
18. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.15～0.99
CH 3CHF 2(R152a) 0.001～0.50
C 2F 4CLH(R124a) 0.001～0.70
CH 3CCLF 2(R142b) 0.001～0.80
And allow to contain peak concentration and be no more than 20% impurity.
19. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.3～0.99
CH 3CHF 2(R152a) 0.001～0.5
CF 3CFH 2(R134a) 0.001～0.5
C 2F 4CLH(R124a) 0.001～0.6
And allow to contain peak concentration and be no more than 20% impurity.
20. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.15～0.99
CH 3CHF 2(R152a) 0.001～0.5
CH 3CCLF 2(R142b)?0.001～0.7
C 2H 3FCL 2(R141b)0.001～0.8
And allow to contain peak concentration and be no more than 20% impurity.
21. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.2～0.99
CH 3CHF 2(R152a) 0.001～0.6
C 3F 5H(R1225) 0.001～0.7
And allow to contain peak concentration and be no more than 20% impurity.
22. a non-azeotropic working medium, its component fully and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.15～0.99
CH 3CHF 2(R152a)0.001～0.6
C 3F 5H(R1225) 0.001～0.7
C 2F 4CLH(R124a)0.001～0.8
And allow to contain peak concentration and be no more than 20% impurity.
23. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.19～0.99
CH 3CHF 2(R152a)0.001～0.6
C 3H 3F 3(R1243)0.001～0.8
And allow to contain peak concentration and be no more than 20% impurity.
24. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.27～0.99
CH 3CHF 2(R152a)0.001～0.6
C 3H 3F 3(R1243)0.001～0.7
C 2F 4CLH(R124a)0.001～0.7
And allow to contain peak concentration and be no more than 20% impurity.
25. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.17～0.99
CH 3CHF 2(R152a)?0.001～0.7
CF 2BrH(R22B1) 0.001～0.7
CH 3CCLF 2(R142b)0.001～0.8
And allow to contain peak concentration and be no more than 20% impurity.
26. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.15～0.99
CH 3CHF 2(R152a)?0.001～0.7
CF 2BrH(R22B1) 0.001～0.7
C 2F 4CLH(R124a)?0.001～0.8
And allow to contain peak concentration and be no more than 20% impurity.
27. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.09～0.99
CH 3CHF 2(R152a) 0.001～0.7
CH 3CCLF 2(R142b) 0.001～0.2
C 2F 3CLH 2(R133a)?0.001～0.9
And allow to contain peak concentration and be no more than 20% impurity.
28. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
C 2F 5H(R125) 0.01～0.7
CF 3CH 3(R143a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
29. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CHCLF 2(R22) 0.01～0.95
And allow to contain peak concentration and be no more than 20% impurity.
30. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.7
And allow to contain peak concentration and be no more than 20% impurity.
31. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.6
And allow to contain peak concentration and be no more than 20% impurity.
32. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.7
And allow to contain peak concentration and be no more than 20% impurity.
33. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.7
CF 3CFH 2(R134a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
34. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.6
CF 3CFH 2(R134a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
35. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.6
CF 3CFH 2(R134a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
36. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.6
CF 2HCF 2H(R134) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
37. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2H 2(R32) 0.01～0.9
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.6
CF 2HCF 2H(R134) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
38. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270)?0.01～0.6
CF 2HCF 2H(R134) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
39. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.7
CF 3CFH 2(R134a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
40. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.7
CF 2HCF 2H(R134) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
41. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.7
CF 3CFH 2(R134a) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
42. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.7
CF 2HCF 2H(R134) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
43. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 2BrH(R22B1) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
44. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 3H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
C 3H 3F 3(R1243) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
45. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
C 3F 5H(R1225) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
46. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 2BrH(R22B1) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
47. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
C 3F 5H(R1225) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
48. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
C 3H 3F 3(R1243) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
49. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
C 3H 8(R290) 0.01～0.6
CF 2BrH(R22B1) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
50. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
C 3H 8(R290) 0.01～0.6
C 3F 5H(R1225) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
51. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
C 3H 8(R290) 0.01～0.6
C 3H 3F 3(R1243) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
52. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
C 3H 8(R290) 0.01～0.6
C 3F 5H(R1225) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
53. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
C 3H 8(R290) 0.01～0.6
CF 2BrH(R22B1) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
54. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
C 3H 8(R290) 0.01～0.6
C 3F 3H 3(R1243) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
55. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
C 3H 8(R290) 0.01～0.6
CF 2BrH(R22B1) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
56. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.90
C 3H 8(R290) 0.01～0.6
C 3F 5H(R1225) 0.01～0.90
And allow to contain peak concentration and be no more than 20% impurity.
57. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
C 3H 8(R290) 0.01～0.6
C 3H 3F 3(R1243)?0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
58. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.27～0.99
CH 3CHF 2(R152a)?0.001～0.5
CH 3CCLF 2(R142b)0.001～0.6
Figure A9511707400211
0.001～0.7
And allow to contain peak concentration and be no more than 20% impurity.
59. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.3～0.95
CH 3CHF 2(R152a)?0.01～0.5
CH(CH 3) 3(R600a)0.01～0.5
0.01～0.6 and allow to contain peak concentration and be no more than 20% impurity.
60. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.3～0.9
CH 3CHF 2(R152a) 0.01～0.5
CH 3(CH 2) 2CH 3(R600)0.01～0.5
Figure A9511707400221
0.01～0.6
And allow to contain peak concentration and be no more than 20% impurity.
61. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.3～0.95
CH(CH 3) 3(R600a) 0.01～0.5
CH 3CCLF 2(R142b) 0.01～0.5
Figure A9511707400222
0.01～0.6
And allow to contain peak concentration and be no more than 20% impurity.
62. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.3～0.95
CH 3(CH 2) 2CH 3(R600)0.01～0.5
CH 3CCLF 2(R142b) 0.01～0.5
0.01～0.6
And allow to contain peak concentration and be no more than 20% impurity.
63. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.
64. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 3CHF 2(R152a) 0.01～0.6
0.01～0.8 and allow to contain peak concentration and be no more than 20% impurity.
65. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 3(CH 2) 2CH 3(R600)?0.01～0.6
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.
66. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH(CH 3) 3(R600a) 0.01～0.6
Figure A9511707400242
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.
67. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CFH 2(R134a) 0.01～0.9
CH 3(CH 2) 2CH 3(R600) 0.01～0.6
Figure A9511707400251
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.
68. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CFH 2(R134a) 0.01～0.9
CH(CH 3) 3(R600a) 0.01～0.6
Figure A9511707400252
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.
69. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2HCF 2(R134) 0.01～0.9
CH 3(CH 2) 2CH 3(R600) 0.01～0.6
Figure A9511707400261
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.
70. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2HCF 2H(R134) 0.01～0.9
CH(CH 3) 3(R600a) 0.01～0.6
Figure A9511707400262
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.
71. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CFH 2(R134a) 0.01～0.9
C 2F 4CLH(R124a) 0.01～0.6
0.01～0.8 and allow to contain peak concentration and be no more than 20% impurity.
72. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 2HCF 2H(R134) 0.01～0.9
C 2F 4CLH(R124a) 0.01～0.6
Figure A9511707400271
0.01～0.8
And allow to contain peak concentration and be no more than 20% impurity.
73. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
C 2H 2＝CH-CH 3(R1270)?0.01～0.6
CH 3CHF 2(R152a) 0.01～0.7
Figure A9511707400272
0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
74. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.6
CH 3CHF 2(R152a) 0.01～0.7
Figure A9511707400281
0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
75. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.6
CH 3(CH 3) 3(R600a) 0.01～0.7
Figure A9511707400282
0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
76. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CF 3CH 3(R143a) 0.01～0.6
CH 3(CH 2) 2CH 3(R600)?0.01～0.7
Figure A9511707400283
0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
77. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 3CHF 2(R152a) 0.01～0.6
CF 3CFH 2(R134a) 0.01～0.7
Figure A9511707400291
0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
78. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 3CHF 2(R152a) 0.01～0.6
CF 2HCF 2H(R134) 0.01～0.7
0.01～0.8 and allow to contain peak concentration and be no more than 20% impurity.
79. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
CH 3CHF 2(R152a) 0.01～0.6
CH 3CCLF 2(R142b) 0.01～0.7
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
80. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
CH 3CHF 2(R152a) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
81. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
CH 3CCLF 2(R142b) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
82. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
CF 3CFH 2(R134a) 0.01～0.9
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And permitted to contain peak concentration and be no more than 20% impurity.
83. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CHCLF 2(R22) 0.01～0.9
CF 2HCF 2H(R134) 0.01～0.9
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
84. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
85. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.7
CH 2＝CH-CH 3(R1270) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110) 0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
86. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
C 3H 8(R290) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
87. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH(CH 3) 3(R600a) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
88. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
C 2F 5H(R125) 0.01～0.9
CH 3(CH 2) 2CH 3(R600)?0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
89. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH(CH 3) 3(R600a) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
90. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
CH 3(CH 2) 2CH 3(R600) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)?0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
91. a non-azeotropic working medium, its each component and weight concentration are as follows:
Composition weight concentration
CF 3CH 3(R143a) 0.01～0.9
C 3H 3(R290) 0.01～0.6
CF 3CF 2CF 2CF 3(R3110)0.01～0.9
And allow to contain peak concentration and be no more than 20% impurity.
92. the thermal apparatus of a circulation system is characterized in that, this device uses by claim 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90,91 non-azeotropic operating mediums that constituted.
93. the air-conditioning system of a circulation system job is characterized in that, this device uses by claim 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90,91 non-azeotropic operating mediums that constituted.
94. the refrigeration system of a circulation system job is characterized in that, this device uses by claim 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90,91 non-azeotropic operating mediums that constituted.
95. the heating system of a circulation system job is characterized in that, this device uses by claim 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90,91 non-azeotropic operating mediums that constituted.
96. the thermal fluid power device of a circulation system job is characterized in that, this device uses by claim 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24,25,26,27,28,29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,81,82,83,84,85,86,87,88,89,90,91 non-azeotropic operating mediums that constituted.
CN95117074A 1995-10-24 1995-10-24 Improved non-azeotropic operating medium using in thermal circulation Expired - Fee Related CN1083474C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN95117074A CN1083474C (en) 1995-10-24 1995-10-24 Improved non-azeotropic operating medium using in thermal circulation

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN95117074A CN1083474C (en) 1995-10-24 1995-10-24 Improved non-azeotropic operating medium using in thermal circulation

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CNB011314710A Division CN1162503C (en) 1995-10-24 1995-10-24 Improved zeotropic working medium used in thermal circulation
CNB011314702A Division CN1162502C (en) 1995-10-24 1995-10-24 Improved zeotropic working medium used in thermal circulation
CNB011314737A Division CN1137236C (en) 2001-09-11 2001-09-11 Improved zeotropic working medium used in thermal circulation
CNB011314729A Division CN1137235C (en) 2001-09-11 2001-09-11 Improved zeotropic working medium used in thermal circulation
CN 01131475 Division CN1124326C (en) 2001-09-11 2001-09-11 Improved zeotropic working medium used in thermal circulation
CNB011314761A Division CN1176177C (en) 2001-09-11 2001-09-11 Improved zeotropic working medium used in thermal circulation
CNB011314699A Division CN1165593C (en) 2001-09-11 2001-09-11 Improved zeotropic working medium used in thermal circulation
CNB011314745A Division CN1176176C (en) 2001-09-11 2001-09-11 Improved zeotropic working medium used in thermal circulation

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US7229567B2 (en) 1997-07-15 2007-06-12 E.I. Dupont De Nemours And Company Refrigerant compositions
US7258813B2 (en) 1999-07-12 2007-08-21 E.I. Du Pont De Nemours And Company Refrigerant composition
US7276176B2 (en) 2002-10-11 2007-10-02 E. I. Du Pont De Nemours And Company Refrigerant compositions
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US7641810B2 (en) 2002-11-29 2010-01-05 Neil Andre Roberts Refrigerant compositions
CN102066852A (en) * 2008-06-16 2011-05-18 三菱电机株式会社 Non-azeotropic refrigerant mixture and refrigeration cycle device
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US8808570B2 (en) 2010-05-20 2014-08-19 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
US8926856B2 (en) 2010-02-16 2015-01-06 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
US8961812B2 (en) 2010-04-15 2015-02-24 E I Du Pont De Nemours And Company Compositions comprising Z-1,2-difluoroethylene and uses thereof
US8961811B2 (en) 2010-04-15 2015-02-24 E I Du Pont De Nemours And Company Compositions comprising E-1,2-difluoroethylene and uses thereof
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US7258813B2 (en) 1999-07-12 2007-08-21 E.I. Du Pont De Nemours And Company Refrigerant composition
US7799240B1 (en) 2002-10-11 2010-09-21 E.I. Du Pont De Nemours And Company Refrigerant compositions
US7276176B2 (en) 2002-10-11 2007-10-02 E. I. Du Pont De Nemours And Company Refrigerant compositions
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US7648642B2 (en) 2002-10-11 2010-01-19 E.I. Du Pont De Nemours And Company Refrigerant compositions
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US8333901B2 (en) 2007-10-12 2012-12-18 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
CN102066852A (en) * 2008-06-16 2011-05-18 三菱电机株式会社 Non-azeotropic refrigerant mixture and refrigeration cycle device
CN102181269A (en) * 2008-06-23 2011-09-14 王高元 Mixed working medium for heat pump system
CN102181269B (en) * 2008-06-23 2013-08-28 王高元 Mixed working medium for heat pump system
US9175202B2 (en) 2010-02-16 2015-11-03 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
US8926856B2 (en) 2010-02-16 2015-01-06 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
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US8961811B2 (en) 2010-04-15 2015-02-24 E I Du Pont De Nemours And Company Compositions comprising E-1,2-difluoroethylene and uses thereof
US8961812B2 (en) 2010-04-15 2015-02-24 E I Du Pont De Nemours And Company Compositions comprising Z-1,2-difluoroethylene and uses thereof
US8808571B2 (en) 2010-05-20 2014-08-19 Mexichem Amanco Holding S.A. De C.V. Heat transfer compositions
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US9835365B2 (en) 2013-07-30 2017-12-05 Mexichem Fluor S.A. De C.V. Compositions comprising 1,1-difluoroethene (R-1132A)
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CN103820082A (en) * 2014-03-02 2014-05-28 上海海洋大学 Environmental protection refrigerant for ultralow-temperature refrigeration system
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