CN105567069A - Environment-friendly bicomponent waterborne polyurethane camouflage paint preparation method - Google Patents

Environment-friendly bicomponent waterborne polyurethane camouflage paint preparation method Download PDF

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CN105567069A
CN105567069A CN201510824935.6A CN201510824935A CN105567069A CN 105567069 A CN105567069 A CN 105567069A CN 201510824935 A CN201510824935 A CN 201510824935A CN 105567069 A CN105567069 A CN 105567069A
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inorganic
environment
preparation
mixtures
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CN105567069B (en
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肖圣荣
张桐
刘鹏瑞
王智勇
许亚楠
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BEIJING INSTITUTE OF AERONAUTICAL MATERIALS CHINA AVIATION INDUSTRY GROUP Corp
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BEIJING INSTITUTE OF AERONAUTICAL MATERIALS CHINA AVIATION INDUSTRY GROUP Corp
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Abstract

The invention belongs to the technical field of pain coating and particularly relates to an environment-friendly bicomponent waterborne polyurethane camouflage paint preparation method. Green waterborne camouflage paint is prepared from 25-32wt% of waterborne emulsion, 10-15wt% of fillers, 15-20wt% of pigments, 20-30wt% of distilled water, 0.3-0.5wt% of an antifoaming agent, 0.3-0.5wt% of a dispersing agent, 0.3-0.5wt% of a flatting agent, 0.3-0.5wt% of a wetting agent, 0.3-0.5wt% of a thickening agent, 10-13wt% of a curing agent, wherein the pigments include 8-10% of an inorganic green pigment, 3-4% of an inorganic yellow pigment, 2-3% of an inorganic black pigment and 2-3% of inorganic blue pigment. The waterborne emulsion refers to hydroxyl acrylic emulsion; the curing agent refers to waterborne isocyanate; the fillers and the pigments include talcum powder, light calcium carbonate, fumed silica, the inorganic green pigment, the inorganic yellow pigment, the inorganic black pigment and the inorganic blue pigment; auxiliaries include the antifoaming agent, the flatting agent, the dispersing agent, the wetting agent and the thickening agent. The waterborne camouflage paint is effective in camouflage and excellent in salt spray resistance, water resistance, corrosion resistance and physical and mechanical properties and can be used for camouflage of military equipment.

Description

The preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting
Technical field
The invention belongs to paint spraying technical field, be specifically related to the preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting.
Background technology
Along with the development of military new and high technology, the progress of Intelligence Technology, domestic and international reconnaissance equipment makes rapid progress.There is uv photography equipment in ultraviolet band work, have visual telescope, optical rangefinder etc. in visible light wave range work, have infrared viewing device and CCD optical imaging system in near-infrared band work.Multi light spectrum hands infrared photography equipment and infrared imaging system etc. are had at the reconnaissance equipment of infrared band work, greatly strengthen the resolving power to camouflaged target, therefore, application Camouflage painting is by the combination of different colours, reducing and be found probability, is the requisite measure of effectively preserving effective strength.
At present, published camouflage painting has the kinds such as polyacrylic resin coating, phthalic resin coating, perchlorvinyl resin coating.Coating system used is solvent-based system, containing a large amount of organic solvents, can cause environmental pollution in coating application process, and very easily endanger the healthy of workmen.Further, along with the increase of people's environmental consciousness, every country carries out strict restriction to volatile organic matter (VOC) quantity discharged.
Summary of the invention
The object of the invention is, for above-mentioned solvent based coating system Problems existing, the invention provides a kind of preparation method of environmental protection double-component waterborne polyurethane Camouflage painting.Technical solution of the present invention is, is made up of the component of following massfraction meter:
Water-based emulsion: 25-32wt%;
Filler: 10-15wt%;
Pigment: 15-20wt%, wherein, inorganic green 8-10%, inorganic yellow 3-4%, inorganic black 2-3%, inorganic blue 2-3%;
Distilled water: 20-30wt%;
Defoamer: 0.3-0.5wt%;
Dispersion agent: 0.3-0.5wt%;
Flow agent: 0.3-0.5wt%;
Wetting agent: 0.3-0.5wt%;
Thickening material: 0.3-0.5wt%;
Solidifying agent: 10-13wt%;
Wherein, water-based emulsion is one or more in hydroxyl acrylic emulsion, and solidifying agent is one or more of Water-borne modification isocyanic ester, filler comprise talcum powder, light calcium carbonate, aerosil one or more,
During preparation, first water-based emulsion, filler, pigment, distilled water, defoamer, dispersion agent, flow agent, wetting agent and thickening material be mixed in proportion and stir, then, then solidifying agent being added mixing.
Aqueous acrylic emulsion is one or more mixtures of ten thousand China 2042, Bayhydrolxp2470, Bayhydrolxp2695.
Inorganic veridian is one or more mixtures of HEUCODURGreen5G, HEUCODURGreen654.
Inorganic yellow pigment is one or more mixtures of HEUCODURYellow255, HEUCODURYellow256, HEUCODURYellow259.
Inorganic black pigments is one or more mixtures of HEUCODURBlack9-100, HEUCODURBlack940, HEUCODURBlack955.
Inorganic blue pigments is one or more mixtures of HEUCODURBlue545, HEUCODURBlue5-100.
Defoamer is one or more mixtures of BYK-011, BYK-021, TEGO-825, Tego-901.
Flow agent is one or more mixtures of BYK-381, BYK-333, TEGOGlide450, TEGOGlide410.
Dispersion agent is one or more mixtures of BYK-190, BYK-180, TEGODispers715w, TEGODispers755w.
Wetting agent is one or more mixtures of TEGOWet280, TEGOWet260, TEGOTwin4100.
Thickening material is one or more mixtures of TEGOViscoPlus3010, TEGOViscoPlus3030, BYK-420.
Solidifying agent is one or more mixtures of Bayhydurxp2547, Bayhydurxp304, ten thousand China 161.
The thickness of this double-component aqueous Camouflage painting is 40-60 micron.
The advantage that the present invention has and beneficial effect, the resin system that the present invention adopts is double-component waterborne polyurethane system, rigid segment is rolled into a ball containing alkane soft segment and urethano in molecular chain, and can hydrogen bond be formed between molecular chain, there is excellent physical and mechanical properties (Ying Du≤3H, Rou Ren≤1mm and Fu as coating Li≤20MPa) and barrier propterty (salt spray resistance≤1000h, Xing of Nai Shui≤20d and artificial accelerated aging≤1000h).Resin used and solidifying agent are Water-borne modification process, and containing the high organic solvent of toxicity, solvent is distilled water, and the low VOC quantity discharged of system, meets environmental requirement, have the advantages such as environmentally friendly, nontoxic, construction safety.
Embodiment
Be made up of the component of following massfraction meter:
Water-based emulsion: 25-32wt%;
Filler: 10-15wt%;
Pigment: 15-20wt%, wherein, inorganic green 8-10%, inorganic yellow 3-4%, inorganic black 2-3%, inorganic blue 2-3%;
Distilled water: 20-30wt%;
Defoamer: 0.3-0.5wt%;
Dispersion agent: 0.3-0.5wt%;
Flow agent: 0.3-0.5wt%;
Wetting agent: 0.3-0.5wt%;
Thickening material: 0.3-0.5wt%;
Solidifying agent: 10-13wt%;
Wherein, water-based emulsion is one or more in hydroxyl acrylic emulsion, solidifying agent is one or more of Water-borne modification isocyanic ester, filler comprise talcum powder, light calcium carbonate, aerosil one or more, during preparation, first water-based emulsion, filler, pigment, distilled water, defoamer, dispersion agent, flow agent, wetting agent and thickening material be mixed in proportion and stir, then, then solidifying agent being added mixing.
Described water-based Camouflage painting, aqueous acrylic emulsion is one or more mixtures of ten thousand China 2042, Bayhydrolxp2470, Bayhydrolxp2695;
Described water-based Camouflage painting, filler is one or more mixtures of talcum powder, light calcium carbonate, aerosil, process white;
Described water-based Camouflage painting, inorganic veridian is one or more mixtures of HEUCODURGreen5G, HEUCODURGreen654;
Described water-based Camouflage painting, Inorganic yellow pigment is one or more mixtures of HEUCODURYellow255, HEUCODURYellow256, HEUCODURYellow259;
Described water-based Camouflage painting, inorganic black pigments is one or more mixtures of HEUCODURBlack9-100, HEUCODURBlack940, HEUCODURBlack955;
Described water-based Camouflage painting, inorganic blue pigments is one or more mixtures of HEUCODURBlue545, HEUCODURBlue5-100;
Described water-based Camouflage painting, defoamer is one or more mixtures of BYK-011, BYK-021, TEGO-825, Tego-901;
Described water-based Camouflage painting, flow agent is one or more mixtures of BYK-381, BYK-333, TEGOGlide450, TEGOGlide410;
Described water-based Camouflage painting, dispersion agent is one or more mixtures of BYK-190, BYK-180, TEGODispers715w, TEGODispers755w;
Described water-based Camouflage painting, wetting agent is one or more mixtures of TEGOWet280, TEGOWet260, TEGOTwin4100;
Described water-based Camouflage painting, thickening material is one or more mixtures of TEGOViscoPlus3010, TEGOViscoPlus3030, BYK-420;
Described water-based Camouflage painting, solidifying agent is one or more mixtures of Bayhydurxp2547, Bayhydurxp304, ten thousand China 161;
Described water-based Camouflage painting, the thickness of this double-component aqueous Camouflage painting is 40-60 micron;
Double-component waterborne polyurethane coating of the present invention, under the technical requirements that can meet camouflage paint, also has low VOC quantity discharged, environmental protection, the advantage such as nontoxic.
Embodiment one
By the Bayhydrolxp2470 emulsion of 25 parts, defoamer BYK-011, flow agent BYK-381, wetting agent TEGOWet280, thickening material TEGOViscoPlus3010, each 0.3 part of dispersant B YK-190 is uniformly mixed, add the inorganic veridian HEUCODURGreen5G of 8 parts again, the Inorganic yellow pigment HEUCODURYellow255 of 3 parts, the inorganic black pigments HEUCODURBlack9-100 of 2 parts, the inorganic blue pigments HEUCODURBlue545 of 2 parts, the talcum powder of 3 parts, the light calcium carbonate of 3 parts, the aerosil of the process white of 3 parts and 1 part, add the distilled water of 20 parts, after abundant stirring, adopt the abundant grinding distribution of conoidal mill, add the solidifying agent Bayhydurxp2547 of 10 parts, namely environment-friendly double-component aqueous polyurethane camouflage painting is obtained.Its coating salient features is in table 1.
Embodiment two
By 32 parts ten thousand magnificent 2042 emulsions, defoamer BYK-011, flow agent TEGOGlide450, wetting agent TEGOTwin4100, thickening material TEGOViscoPlus3030, each 0.5 part of dispersion agent TEGODispers715w is uniformly mixed, add the inorganic veridian HEUCODURGreen654 of 10 parts again, the Inorganic yellow pigment HEUCODURYellow255 of 4 parts, the inorganic black pigments HEUCODURBlack9-100 of 3 parts, the inorganic blue pigments HEUCODURBlue5-100 of 3 parts, the talcum powder of 4 parts, the light calcium carbonate of 4 parts, the aerosil of the process white of 4 parts and 3 parts, add the distilled water of 30 parts, after abundant stirring, adopt the abundant grinding distribution of conoidal mill, add the solidifying agent Bayhydurxp2547 of 13 parts, namely environment-friendly double-component aqueous polyurethane camouflage painting is obtained.
Embodiment three
By 28 parts ten thousand magnificent 2042 emulsions, defoamer BYK-021, flow agent TEGOGlide450, wetting agent TEGOTwin4100, thickening material TEGOViscoPlus3030, each 0.4 part of dispersion agent TEGODispers755w is uniformly mixed, add the inorganic veridian HEUCODURGreen654 of 9 parts again, the Inorganic yellow pigment HEUCODURYellow255 of 2 parts, the inorganic black pigments HEUCODURBlack9-100 of 1.5 parts, the inorganic blue pigments HEUCODURBlue5-100 of 1.5 parts, the talcum powder of 5 parts, the light calcium carbonate of 5 parts, the aerosil of the process white of 2 parts and 1 part, add the distilled water of 28 parts, after abundant stirring, adopt the abundant grinding distribution of conoidal mill, add solidifying agent ten thousand China 161 of 12 parts, namely environment-friendly double-component aqueous polyurethane camouflage painting is obtained.
The double-component aqueous camouflage paint salient features of table 1
Prepared coating is deep green camouflage coating, its color and standard DG-0810 deep green dazzle paint basically identical, aberration Δ E value is 2.56, and camouflage effectiveness is better.

Claims (13)

1. a preparation method for environment-friendly double-component aqueous polyurethane Camouflage painting, is characterized in that, is made up of the component of following massfraction meter:
Water-based emulsion: 25-32wt%;
Fill out: 10-15wt%;
Pigment: 15-20wt%, wherein, inorganic green 8-10%, inorganic yellow 3-4%, inorganic black 2-3%, inorganic blue 2-3%;
Distilled water: 20-30wt%;
Defoamer: 0.3-0.5wt%;
Dispersion agent: 0.3-0.5wt%;
Flow agent: 0.3-0.5wt%;
Wetting agent: 0.3-0.5wt%;
Thickening material: 0.3-0.5wt%;
Solidifying agent: 10-13wt%;
Wherein, water-based emulsion is one or more in hydroxyl acrylic emulsion, and solidifying agent is one or more of Water-borne modification isocyanic ester, filler comprise talcum powder, light calcium carbonate, aerosil one or more,
During preparation, first water-based emulsion, filler, pigment, distilled water, defoamer, dispersion agent, flow agent, wetting agent and thickening material be mixed in proportion and stir, then, then solidifying agent being added mixing.
2. the preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting according to claim 1, is characterized in that, aqueous acrylic emulsion is one or more mixtures of ten thousand China 2042, Bayhydrolxp2470, Bayhydrolxp2695.
3. the preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting according to claim 1, is characterized in that, inorganic veridian is one or more mixtures of HEUCODURGreen5G, HEUCODURGreen654.
4. the preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting according to claim 1, it is characterized in that, Inorganic yellow pigment is one or more mixtures of HEUCODURYellow255, HEUCODURYellow256, HEUCODURYellow259.
5. the preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting according to claim 1, it is characterized in that, inorganic black pigments is one or more mixtures of HEUCODURBlack9-100, HEUCODURBlack940, HEUCODURBlack955.
6. the preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting according to claim 1, is characterized in that, inorganic blue pigments is one or more mixtures of HEUCODURBlue545, HEUCODURBlue5-100.
7. the preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting according to claim 1, is characterized in that, defoamer is one or more mixtures of BYK-011, BYK-021, TEGO-825, Tego-901.
8. the preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting according to claim 1, is characterized in that, flow agent is one or more mixtures of BYK-381, BYK-333, TEGOGlide450, TEGOGlide410.
9. the preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting according to claim 1, is characterized in that, dispersion agent is one or more mixtures of BYK-190, BYK-180, TEGODispers715w, TEGODispers755w.
10. the preparation method of environment-friendly double-component aqueous polyurethane Camouflage painting according to claim 1, is characterized in that, wetting agent is one or more mixtures of TEGOWet280, TEGOWet260, TEGOTwin4100.
The preparation method of 11. environment-friendly double-component aqueous polyurethane Camouflage paintings according to claim 1, is characterized in that, thickening material is one or more mixtures of TEGOViscoPlus3010, TEGOViscoPlus3030, BYK-420.
The preparation method of 12. environment-friendly double-component aqueous polyurethane Camouflage paintings according to claim 1, is characterized in that, solidifying agent is one or more mixtures of Bayhydurxp2547, Bayhydurxp304, ten thousand China 161.
The preparation method of 13. environment-friendly double-component aqueous polyurethane Camouflage paintings according to claim 1, is characterized in that, the thickness of this double-component aqueous Camouflage painting is 40-60 micron.
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Cited By (8)

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Publication number Priority date Publication date Assignee Title
CN107459899A (en) * 2017-09-13 2017-12-12 四川航龙航空工业有限公司 Infrared ray invisible coating and the camouflage color preparation method using the coating and stealthy dustcoat
CN108311356A (en) * 2018-01-05 2018-07-24 河北晨阳工贸集团有限公司 A kind of camouflage painting water paint coating process
CN111978846A (en) * 2020-09-08 2020-11-24 安徽省金盾涂料有限责任公司 Bionic visible light and near infrared detection-resistant camouflage coating composition and preparation method thereof
CN112011239A (en) * 2020-09-04 2020-12-01 陈广洪 Non-toxic environment-friendly water-based paint and preparation method thereof
CN112143362A (en) * 2020-10-15 2020-12-29 安徽省金盾涂料有限责任公司 Water-based chemical-medium-resistant and weather-resistant visible light near-infrared camouflage coating and preparation method thereof
CN112812640A (en) * 2021-01-14 2021-05-18 浙江枫翎环保科技有限公司 Photocatalytic antibacterial antiviral formaldehyde-removing peculiar smell-removing varnish
CN113756114A (en) * 2021-09-30 2021-12-07 山东非金属材料研究所 Northern forest land type digital camouflage tarpaulin and preparation method thereof
CN115806768A (en) * 2022-12-15 2023-03-17 江苏新创天利新材料发展有限公司 Water-based two-component typical green optical camouflage paint, preparation and coating method thereof

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CN101108951A (en) * 2007-08-30 2008-01-23 桂林工学院 Aquosity bi-component polyurethane coloured paint and method of manufacturing the same
CN102585631A (en) * 2011-12-28 2012-07-18 江苏大中制漆有限公司 Waterborne camouflage paint and preparation method thereof
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107459899A (en) * 2017-09-13 2017-12-12 四川航龙航空工业有限公司 Infrared ray invisible coating and the camouflage color preparation method using the coating and stealthy dustcoat
CN108311356A (en) * 2018-01-05 2018-07-24 河北晨阳工贸集团有限公司 A kind of camouflage painting water paint coating process
CN112011239A (en) * 2020-09-04 2020-12-01 陈广洪 Non-toxic environment-friendly water-based paint and preparation method thereof
CN111978846A (en) * 2020-09-08 2020-11-24 安徽省金盾涂料有限责任公司 Bionic visible light and near infrared detection-resistant camouflage coating composition and preparation method thereof
CN112143362A (en) * 2020-10-15 2020-12-29 安徽省金盾涂料有限责任公司 Water-based chemical-medium-resistant and weather-resistant visible light near-infrared camouflage coating and preparation method thereof
CN112812640A (en) * 2021-01-14 2021-05-18 浙江枫翎环保科技有限公司 Photocatalytic antibacterial antiviral formaldehyde-removing peculiar smell-removing varnish
CN113756114A (en) * 2021-09-30 2021-12-07 山东非金属材料研究所 Northern forest land type digital camouflage tarpaulin and preparation method thereof
CN113756114B (en) * 2021-09-30 2023-08-15 山东非金属材料研究所 North woodland type digital camouflage tarpaulin and preparation method thereof
CN115806768A (en) * 2022-12-15 2023-03-17 江苏新创天利新材料发展有限公司 Water-based two-component typical green optical camouflage paint, preparation and coating method thereof
CN115806768B (en) * 2022-12-15 2023-12-15 江苏新创天利新材料发展有限公司 Aqueous two-component typical green optical camouflage paint, preparation and coating method thereof

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