CN105297291A - Water-absorbing melt-blow non-woven fabric and preparation method for same - Google Patents
Water-absorbing melt-blow non-woven fabric and preparation method for same Download PDFInfo
- Publication number
- CN105297291A CN105297291A CN201510596953.3A CN201510596953A CN105297291A CN 105297291 A CN105297291 A CN 105297291A CN 201510596953 A CN201510596953 A CN 201510596953A CN 105297291 A CN105297291 A CN 105297291A
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- Prior art keywords
- woven fabrics
- resin
- melt spraying
- spraying non
- water suction
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Classifications
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- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/005—Synthetic yarns or filaments
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H3/00—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length
- D04H3/08—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating
- D04H3/16—Non-woven fabrics formed wholly or mainly of yarns or like filamentary material of substantial length characterised by the method of strengthening or consolidating with bonds between thermoplastic filaments produced in association with filament formation, e.g. immediately following extrusion
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Nonwoven Fabrics (AREA)
Abstract
The invention provides a water-absorbing melt-blow non-woven fabric and a preparation method for the same. The water-absorbing melt-blow non-woven fabric is in a skin-covering-core type side-by-side composite structure. A first skin-covering part is formed by 30% to 70% of resin composite; the resin composite is formed by sulphone hydrophilic resin and other resin; other resin is formed by either polyolefin resin, polyester resin or polybutylene terephthalate or more than one; a second core part is formed by 70% to 30% of other resin or polyamide resin. The non-woven fabric is in the skin-covering-core type side-by-side composite structure; the skin-covering material is made from hydrophilic material, thereby improving non-woven fabric water-absorbing quality and maintaining ventilating property; and the non-woven fabric can be repeatedly used.
Description
Technical field
The invention belongs to nonwoven cloth material field, particularly one water suction melt spraying non-woven fabrics and preparation method thereof.
Background technology
Existing high-hydroscopicity melt spraying non-woven fabrics the fiber after spinning sprays or absorptive substance that the mode of impregnation is adsorbed and possess water imbibition.Be used for disposable products.Concrete mode is: use polyolefin-based resins, be supplied to the nozzle of several rows of row by multiple hole after melting, in nozzle bore, during molten polymer continuous spinning, in the slit of nozzle bore both sides, high velocity jet contains the solution of hydroaropic substance, obtained fibre diameter is 3-10 micron.
In Korea S, the liquid that molten polymer is formed as polymer is assigned to the fiber spinning apparatus transformed to carry.Liquid finishing agent is used in the surface of the molten polymer liquid in device for spinning.The absorptive material that possesses made may be used for infant article (as diaper), or feminine care products.
Comprise exterior layer and the interior layer of more than one deck at the nonwoven fabric of Korea S's multi-ply construction, wherein the acrylic resin of 40-90% defines interior layer, and the polyvinyl resin of 10-60% defined outside once, and the weight of spray fusing nonwoven fabric is 0.3-2gsm.This nonwoven fabric not only has cut-out effect, and soft-touch, is suitable for amenities.
But the outstanding nonwoven fabric initial stage absorption speed of water imbibition is higher, also gas permeability is to a certain degree possessed, but owing to being the mode process such as the surface injection of fiber process or impregnation, so can only disposable products be used for, and the problem that under there will be hot conditions, performance reduces and surperficial xanthochromia and the larger problem of viscosity.So nonwoven fabric technology still needs to improve.
Summary of the invention
The object of this invention is to provide a kind of there is remarkable water absorbing properties while washing after water imbibition constant class recycling water suction spray fusing nonwoven fabric.
For realizing above object, technical scheme of the present invention is:
A kind of water suction melt spraying non-woven fabrics, for suitcase core pattern shape composite construction side by side, first foreskin part is the resin compound of 30-70%, resin compound comprises sulfone system hydrophilic resin and other resins, other resins be vistanex, mylar, polybutylene terephthalate (PBT) any one and more than; Second core is other resins or the polyamide of 70%-30%.
Described sulfone system hydrophilic resin accounts for the 3-15% of Part I and Part II gross weight.
Described polyamide is intrinsic viscosity IV0.455, and melting density is 1.11g/cm
3resin.
Described vistanex is acrylic resin.
The preparation method of composite spinning melt spraying non-woven fabrics is: 1) process raw material, make its moisture at below 150ppm, 2) then heating and melting, 3) by two squeezers, the polymer of melting is sprayed through nozzle, 4) cooling.
The cooling-air of 5-20 DEG C is adopted to force cooling in cooling step.
Described nozzle is core-skin type nozzle, and density is 20-100hole/inch.
Obtained non-woven weight is 10-200g/m2.
Manufactured water suction melt spraying non-woven fabrics, for water treatment film, amenities and industrial goods.
Water imbibition melt spraying non-woven fabrics of the present invention uses 2 kinds of different different raw materials to mix in feedway, wherein drop into sulfone system hydroaropic substance in raw material feed device on one side, polymer melting compressed by two squeezers is after by gear pump, each distributes, the resin spued from the distribution plate of nozzle is with the extension of the air molten polymer of High Temperature High Pressure, cooling limit, superfineization back allows the fiber pad of superfineization roll on a moving belt, the melt spraying non-woven fabrics of water absorbing properties is now had to be subject to melt temperature, air themperature, air pressure, chilling temperature and from nozzle to the impact of conveyer belt distance.But what have the greatest impact is the constituent ratio of polymer.The identical lower air pressure increase of other conditions can cause fibre crystallinity to increase and intensity increases, thus improves the intensity of fiber.And the higher injection index of water absorbing component content can increase.
The nozzle of melt-blown use is 25-100hole/inch, and polymer each polymer before weaving silk of melting flows at each distribution plate, defines the fusion spray cloth of core-skin type or type side by side before nozzle spinning.The fibre diameter of fusion spray cloth of the present invention is 1-10 micron, and fibre diameter is less, and the fiber of unit are is more, and intensity is higher.
Beneficial effect:
Nonwoven fabric of the present invention adopts core-skin type or side-by-side-type structure, wherein employs hydroaropic substance in skin material, can also improve the water imbibition of nonwoven fabric and keep its gas permeability, and can reuse.
Specific embodiment
The present invention is illustrated below by exemplary embodiment.Should be appreciated that scope of the present invention should not be limited to the scope of embodiment.Any do not depart from purport of the present invention change or change and can be understood by those skilled in the art.Protection scope of the present invention is determined by the scope of claims.
Embodiment 1:
The first is as mixing and hydrophilizing agent in the acrylic resin of crust, absorptive spray fusing nonwoven fabric is made by nozzle, the melt index of acrylic resin is M1 (1100), the weight of hydrophilic resin accounted for 0.5% of hybrid resin, hybrid resin under the condition of baking temperature 50 DEG C dry 4-10 hour; Do not use hydrophilizing agent in the acrylic resin of the second as to be melt index be M1 (1100) of core, processing method is with the first.Melt temperature is set to 250 DEG C, and air pressure is 6.0PSI, and air themperature is 250 DEG C, DCD17cm, obtained weight is the melt spraying non-woven fabrics of 50gsm.Nozzle is the core-skin type nozzle of 35hole/inch.The part by weight of the first composition and the second composition is 30:70.
Embodiment 2:
Identical with embodiment 1, the first crust composition same resin and hydrophilizing agent have done pre-treatment, the second nucleus employs the polyamide of IV0.45, moisture rate is at below 150ppm, melt temperature is 280 DEG C, and air pressure is 7.5PSI, and air themperature is 280 DEG C, DCD20cm, obtained weight is the melt spraying non-woven fabrics of 50gsm.The part by weight of the first crust composition and the second nucleus is 30:70.
Embodiment 3:
Identical with embodiment 2, the first crust composition same resin and hydrophilizing agent have done pre-treatment, and the melt index of thermoplastic polyurethane resin is M1 (1100), and the weight of hydrophilic resin accounts for 1% of hybrid resin; The second nucleus employs the polyamide of IV0.45, and moisture rate is at below 150ppm, and melt temperature is 280 DEG C, and air pressure is 7.5PSI, and air themperature is 280 DEG C, DCD20cm, and obtained weight is the melt spraying non-woven fabrics of 50gsm.The part by weight of the first crust composition and the second nucleus is 30:70.
Comparative example 1:
The method identical with embodiment, have employed the acrylic resin of 100%, and moisture rate is below 150ppm, has manufactured the nonwoven fabric of 50gsm under the same terms.
Comparative example 2:
Identical with comparative example 1, have employed the acrylic resin of 100%, during fibre spinning, the solution containing 20 hydrophilic resins is injected in surface, then dry, obtained weight is the melt spraying non-woven fabrics of 50gsm.
Comparative example 3:
Identical with comparative example 2, employ the polyamide of 100% of intrinsic viscosity IV0.45, moisture rate is below 150ppm, and manufacturing technique is as comparative example 2, and obtained weight is the melt spraying non-woven fabrics of 50gsm.
The assay method of embodiment and comparative example is:
1) basis weight uses ASTMD3778 method to measure;
2) nonwoven fabric intensity and retractility measure according to JISL1018;
3) absorption speed of nonwoven fabric measures according to ASTMD1044;
4) water absorption of nonwoven fabric measures according to JISL1018.
Measurement result is as following table:
Above-described embodiment is only and technological thought of the present invention and feature is described, it describes comparatively concrete and detailed, its object is to enable those of ordinary skill in the art understand content of the present invention and implement according to this, and be not limited in signle crystal alumina fiber, other inorganic staple fibre or whisker all can make prefabricated component by this kind of method.Therefore only the scope of the claims of the present invention can not be limited with this, it should be noted that, for the person of ordinary skill of the art, without departing from the inventive concept of the premise, some distortion and improvement can also be made, namely all do according to the embodiment of the present invention any amendment, equivalent variations and modification, all still belong in the scope of technical scheme of the present invention.
Claims (9)
1. a water suction melt spraying non-woven fabrics, for suitcase core pattern shape composite construction side by side, first foreskin part is the resin compound of 30-70%, resin compound comprises sulfone system hydrophilic resin and other resins, other resins be vistanex, mylar, polybutylene terephthalate (PBT) any one and more than; Second core is other resins or the polyamide of 70%-30%.
2. water suction melt spraying non-woven fabrics according to claim 1, described sulfone system hydrophilic resin accounts for the 3-15% of Part I and Part II gross weight.
3. water suction melt spraying non-woven fabrics according to claim 1, described polyamide is intrinsic viscosity IV0.455, and melting density is 1.11g/cm
3resin.
4. water suction melt spraying non-woven fabrics according to claim 1, described vistanex is acrylic resin.
5. the preparation method of composite spinning melt spraying non-woven fabrics is: 1) process raw material, make its moisture at below 150ppm, 2) then heating and melting, 3) by two squeezers, the polymer of melting is sprayed through nozzle, 4) cooling.
6. the preparation method of water suction melt spraying non-woven fabrics according to claim 5, adopts the cooling-air of 5-20 DEG C to force cooling in cooling step.
7. the preparation method of water suction melt spraying non-woven fabrics according to claim 5, described nozzle is core-skin type nozzle, and density is 20-100hole/inch.
8. the preparation method of water suction melt spraying non-woven fabrics according to claim 5, obtained non-woven weight is 10-200g/m
2.
9. the water suction melt spraying non-woven fabrics manufactured by any one of claim 5-8, for water treatment film, amenities and industrial goods.
Priority Applications (1)
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CN201510596953.3A CN105297291A (en) | 2015-09-18 | 2015-09-18 | Water-absorbing melt-blow non-woven fabric and preparation method for same |
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CN201510596953.3A CN105297291A (en) | 2015-09-18 | 2015-09-18 | Water-absorbing melt-blow non-woven fabric and preparation method for same |
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CN201510596953.3A Pending CN105297291A (en) | 2015-09-18 | 2015-09-18 | Water-absorbing melt-blow non-woven fabric and preparation method for same |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107938172A (en) * | 2017-12-25 | 2018-04-20 | 安徽省临泉县万隆塑料包装有限公司 | A kind of hydrophily melt spraying non-woven fabrics |
CN110699857A (en) * | 2019-10-18 | 2020-01-17 | 江苏亿茂滤材有限公司 | Water-absorbing melt-blown nonwoven fabric and preparation method thereof |
Citations (4)
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---|---|---|---|---|
CN1085972A (en) * | 1992-08-26 | 1994-04-27 | 金伯利-克拉克公司 | The non-weaving cloth of making by the multicomponent polymeric strands of the blend that comprises a kind of polyene and ethylene alkyl acrylate copolymer |
US5534339A (en) * | 1994-02-25 | 1996-07-09 | Kimberly-Clark Corporation | Polyolefin-polyamide conjugate fiber web |
CN102675730A (en) * | 2011-03-10 | 2012-09-19 | 北京伊士通新材料发展有限公司 | Hydrophilic polypropylene mixture and preparing method and application thereof |
CN103668791A (en) * | 2013-11-30 | 2014-03-26 | 江苏奥森新材料有限公司 | Production method for non-woven fabric wet curtain |
-
2015
- 2015-09-18 CN CN201510596953.3A patent/CN105297291A/en active Pending
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1085972A (en) * | 1992-08-26 | 1994-04-27 | 金伯利-克拉克公司 | The non-weaving cloth of making by the multicomponent polymeric strands of the blend that comprises a kind of polyene and ethylene alkyl acrylate copolymer |
US5336552A (en) * | 1992-08-26 | 1994-08-09 | Kimberly-Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer |
US5534339A (en) * | 1994-02-25 | 1996-07-09 | Kimberly-Clark Corporation | Polyolefin-polyamide conjugate fiber web |
CN1179184A (en) * | 1995-01-27 | 1998-04-15 | 金伯利-克拉克环球有限公司 | Polyolefin-polyamide conjugate fiber web |
CN102675730A (en) * | 2011-03-10 | 2012-09-19 | 北京伊士通新材料发展有限公司 | Hydrophilic polypropylene mixture and preparing method and application thereof |
CN103668791A (en) * | 2013-11-30 | 2014-03-26 | 江苏奥森新材料有限公司 | Production method for non-woven fabric wet curtain |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107938172A (en) * | 2017-12-25 | 2018-04-20 | 安徽省临泉县万隆塑料包装有限公司 | A kind of hydrophily melt spraying non-woven fabrics |
CN107938172B (en) * | 2017-12-25 | 2020-06-23 | 安川科技(东阳)有限公司 | Hydrophilic melt-blown non-woven fabric |
CN110699857A (en) * | 2019-10-18 | 2020-01-17 | 江苏亿茂滤材有限公司 | Water-absorbing melt-blown nonwoven fabric and preparation method thereof |
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