CN1051671A - 改进的面部清洁组合物 - Google Patents
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Abstract
本发明公开了一种水包油型乳剂形式的面部清
洁组合物,它含有HLB值大于约10的特定表面活
性剂,并配合有特定的聚-α-烯烃以及特定的羧酸共
聚物,该组合物可以增加清洁效果和增强漂洗能力以
及改善皮肤感觉(如无油腻感)。
Description
本发明涉及改进的用于去除化装及类似物的水包油型乳剂形式的面部清洁组合物。
用于去除化装及类似物的美容清洁组合物在当今广为使用,并且以各种剂型如乳膏、洗液、收敛剂等在市场上出售。这种清洁组合物可用于清洁面部和身体,尤其是用于去除化装、油垢、污物、灰尘以及人面部或身体上其它不需要的物质。
有两种“传统”的清洁乳膏。第一种是以蜂蜡/硼砂配方为基础的冷霜。第二种是用烃油和蜡的混合物配制成的半透明液化剂。
冷霜配方已有几百年的历史。最早的配方基本上是动植物脂肪和油:典型的是蜂蜡和橄榄油。后来则向熔化的蜂蜡和橄榄油中加水。这样在使用过程中通过皮肤上水分的蒸发而产生一种“凉爽”的感觉。这些最原始的产品不稳定并且易于酸败。不久,甜杏仁油取代了较重的橄榄油,并使用硼砂作为一种稳定剂,后来则加入鲸蜡(鲸油)以软化该产品。之后又进行了改进,把杏仁油换成了矿物油,加入玫瑰香水和玫瑰油以增加香味。
较为现代的清洁乳膏则使用其它的脂肪酸酯作为乳化剂,而不是使用硼砂,并且用脂肪酸和脂肪醇取代了蜂蜡。例如,流行的清洁剂含有合成乳化剂,而不是硼砂,以及传统的蜂蜡/硼砂系统。
在使用许多皮肤清洁组合物如冷霜之后,使用者通常会接着使用肥皂以去掉留下的任何残余物质,来获得一种“清洁感”。
已经发现,本发明的水包油型乳剂形式的面部清洁组合物,含有HLB值高于约10的特定表面活性剂和特定的聚α-烯烃以及特定的羧酸共聚物,该组合物可以增加清洁效果、增强漂洗能力以及改善皮肤感觉(如无油腻感)。
因此,本发明的一个目的就是提供一种改进的面部清洁组合物,它可以通过去除如灰尘和油垢以及难于去除的化装、防水睫毛油等而使皮肤彻底清洁。
本发明的另一个目的是提供一种具有良好清洗作用的改进的面部清洁组合物。
本发明的再一个目的是提供一种改进的面部清洁组合物,在使用它清洁之后会改善皮肤的感觉。
从下面的详细描述中可以容易地阐明这些和其他的发明目的。
本发明涉及用于去除化装及类似物的水包油型乳剂形式的清洁组合物,它含有:
a.约0.5%至约10%的HLB值大于约10的表面活性剂,该表面活性剂选自阴离子的、非离子的、两性离子的(zwitte-rionic)和两性的(amphoteric和ampholytic)表面活性剂及其混合物。
b.约2%至约30%的具有下列分子式的聚α-烯烃:
R1-C=C-R2
其中R1和R2分别是从约C20至约C30的烷基,其中所述的聚α-烯烃在100℃下的粘度为约2至约4厘沲;和
c.约0.025%至约0.75%的一种由单体混合物的聚合体组成的羧酸共聚物,该单体混合物包含有95.9%至98.8%(重量)的一种选自丙烯酸、甲基丙烯酸和乙基丙烯酸的烯属不饱和羧酸单体,约1%至约3.5%(重量)的一种具有下列分子式的丙烯酸酯:
其中R是一个含有10到30个碳原子的烷基,R1是氢、甲基或乙基,和0.1%至0.6%(重量)的一种多元醇的可聚交联聚链烯基聚醚,该聚醚的每个分子中含有一个以上的链烯基醚基,其中母体多元醇含有至少3个碳原子和至少3个羟基。
除非另外说明,本文所用的所有百分数和比率都是以组合物的总重量计算,并且所有测量都是在25℃下进行。
表面活性剂
本发明的表面活性剂成分选自阴离子的、非离子的、两性离子的和两性的表面活性剂,以及这些表面活性剂的混合物。这些表面活性剂对于那些去垢技术领域中的熟练人员来说是熟知的。用于本发明的表面活性剂的HLB值大于约10,并且优选的是从约10至约14,更好的是约11至约14,最好是约12至约14。
在出版物HLB系统,乳化剂选择效率手册(The HLB System.A Time-Saving Guide to Emulsifier Selection)(ICI Americas有限公司出版,Wilmington,Delaware;1984)中详细描述了HLB(“亲水-亲脂平衡”的简称)值系统,并给出了各种物质的HLB值。本申请引入该书的全部内容作参考。
最普通的阴离子表面活性剂可以概括地描述为有机硫反应产物的水溶性盐,尤其是碱金属盐,其分子结构中具有一个约8至约22个碳原子的烷基和一个选自磺酸和硫酸酯基的基团。这些表面活性剂的重要例子是烷基硫酸钠、钾或铵,尤其是那些通过将脂或椰子油的甘油酯还原产生的高级醇进行硫酸化得到的;其中烷基含有约9至约15个碳原子的烷基苯磺酸钠或钾,尤其是在美国专利2,220,099和2,477,383中所描述的那些类型,该专利引入本文作为参考;烷基甘油醚磺酸钠,尤其是那些从脂和椰子油得到的高级醇的醚;椰油脂肪酸单酸甘油酯硫酸和磺酸钠;1摩尔高级脂肪醇(如脂或椰子油醇)与大约3摩尔环氧乙烷的反应产物的硫酸酯的钠盐或钾盐;含有大约3至约20摩尔环氧乙烷的烷基酚环氧乙烷醚的硫酸钠或钾;烷基酚环氧乙烷醚硫酸的钠盐或钾盐;每分子含有大约4至约20单位环氧乙烷并且其中的烷基含有约9个碳原子的烷基酚环氧乙烷醚的硫酸钠或钾;用羟乙磺酸对来自如椰子油的脂肪酸进行酯化并用氢氧化钠中和而得到的反应产物,一种甲基牛磺酸的脂肪酸酰胺钠或钾盐,其中的脂肪酸可以是如来自椰子油;以及现有技术中已知的其他表面活性剂,特别是美国专利2,486,921、2,486,922和2,396,278中所列举的那些,该专利引入本文作为参考。
一种重要的有用的阴离子表面活性剂是肥皂。可以用于本发明组合物作为表面活性剂的肥皂包括含有约8至约24、最好是约10至约20个碳原子的脂肪酸的碱金属(如钠或钾)皂。用于制备肥皂的脂肪酸可以来源于自然界,例如从植物或动物中得到的甘油酯(如,棕榈油,椰子油,巴巴苏油,豆油,蓖麻油,牛脂,鲸油,鱼油,润滑脂,猪油及其混合物)。也可以人工合成制备脂肪酸(如通过石油氧化或通过费-托沄)。α-甲硫酯(由Stepan Chemical出售,商品名为Alpha-Step)也可以用于本发明。
可以通过脂肪和油的直接皂化反应或通过中和在分离生产步骤中制备的游离脂肪酸来制备碱金属皂。尤其有用的是从椰子油和脂中得到的脂肪酸混合物的钠和钾盐,即钠和钾脂与椰油皂。
本文涉及到脂肪酸混合物所用术语“脂”是指典型的碳链长度分布约为2.5%C14,29%C16,23%C18,2%棕榈酸,41.5%油酸和3%亚油酸的酸(前三种脂肪酸是饱和的)。其他具有类似分布的混合物,如从各种动物脂和猪脂得到的脂肪酸,也包括在术语“脂”中。还可以使脂硬化(即氢化)将部分或全部的不饱和脂肪酸部分转化成饱和脂肪酸部分。
本文所用术语“椰子油”是指典型的碳链长度分布大约为8%C8,7%C10,48%C12,17%C14,9%C16,2%C18,4%油酸和2%亚油酸的脂肪酸混合物(前六种脂肪酸是饱和脂肪酸)。具有类似碳链长度分布的其他来源脂肪酸,如棕榈仁油和巴巴苏油,也包括在术语椰子油的范围之内。
非离子表面活性剂可以概括定义为通过烯化氧基团(亲水性)与一种有机疏水性化合物进行缩合制备的化合物;它可以是脂族的或烷基芳香族的化合物。可以容易地控制与任何特定疏水基进行缩合的亲水或聚氧化烯基的长度,以产生一种在亲水与疏水单体之间具有所需平衡度的水溶性化合物。
例如,一类已知的非离子表面活性剂由BASF Wyandotte公司以商品名“Pluronic”出售。可以通过环氧乙烷与一种由氧化丙烯与丙二醇缩合形成的疏水基进行缩合形成这些化合物。显然这种分子的疏水部分是水不溶性的,其分子量是约1500至约1800。向这个疏水部位加上聚氧乙烯基团可以增加整个分子的水溶性,并且可使这种产物的液体特性保持达到聚氧乙烯含量约为缩合产物总重量50%的水平。
其他合适的非离子表面活性剂包括,例如:
(ⅰ)烷基酚聚环氧乙烷缩合物,如,具有一个在直链或支链构型上含有约6至约12个碳原子的烷基的烷基酚与环氧乙烷的缩合产物,所说的环氧乙烷的含量为每摩尔烷基酚约5至约25摩尔的环氧乙烷。例如,这种化合物中的烷基取代基可以来源于聚合的丙烯、二异丁烯、正辛烷和壬烷。这种类型化合物的例子包括每摩尔酚与大约12摩尔环氧乙烷进行缩合的壬基酚;每摩尔酚与大约15摩尔环氧乙烷进行缩合的二壬基酚;每摩尔酚与大约15摩尔环氧乙烷进行缩合的二异辛酚。这种类型的市售非离子表面活性剂包括由GAF公司出售的Igepal CO-630;以及由Rohm和Haas公司出售的Triton X-45,X-114,X-100和X-102。
(ⅱ)那些由氧化丙烯与乙二胺产物反应所得产物和环氧乙烷缩合得到的物质,这些物质的组成根据所需疏水和亲水单体的平衡情况而有所不同。这些化合物的例子是那些含有大约40%至约80%(重量)的聚氧乙烯,分子量大约为5000至约11,000的化合物,它是由环氧乙烷基与一种由乙二胺和过量环氧丙烷反应产物组成的疏水基进行反应而得到的化合物,所说的这种疏水基的分子量应为2500至3000。这类非离子表面活性剂的例子包括某些由Wyandotte化学公司出售的Tetronic化合物。
(ⅲ)在直链或支链构型中具有8至36个碳原子的脂肪醇与环氧乙烷进行缩合的产物,例如,一种每摩尔椰子醇含有7至40摩尔环氧乙烷的椰子醇环氧乙烷缩合物。市售的这种类型的非离子表面活性剂的例子包括Tergitol 15-S-9(C11-C15仲醇与9摩尔环氧乙烷的缩合产物),由联合碳化物公司出售;Neodol 45-9(C14-C15线性醇与9摩尔环氧乙烷的缩合产物),Neodol 45-7(C14-C15线性醇与7摩尔环氧乙烷的缩合产物),Neodol 45-4(C14-C15线性醇与4摩尔环氧乙烷的缩合产物),这些产品由壳牌化学公司(Shell Chemical Company)出售;和Kyro EOB(C13-C15线性醇与9摩尔环氧乙烷的缩合产物),由P&G公司(Procter & Gamble Company)出售。
(ⅳ)三烷基氧化胺和三烷基氧化膦,其中一个烷基有10至18个碳原子,而另两个烷基有1至3个碳原子;这些烷基可以含有羟基取代基。特定的例子包括十二烷基(二-2-羟乙基)一氧化胺和十四烷基二甲基氧化膦。
两性离子表面活性剂包括三甲铵乙内酯及类三甲铵乙内酯化合物,该分子中含有碱性和酸性两种基团,形成一种内盐,使该分子在很宽的pH值范围内具有阳离子和阴离子亲水基团。
在美国专利2,082,275、2,702,279,和2,555,082中描述了一些常见的这种表面活性剂,这些专利引入本文作为参考。合适的两性离子表面活性剂具有下面的分子式:
其中R1是一个含有约8至约22个碳原子的烷基,R2和R3含有约1至约3个碳原子,R4是一种含有约1至约4个碳原子的亚烷基链,X选自氢和羟基,Y选自羧基和磺酰基,并且其中R1、R2和R3的总和是大约14至约26个碳原子。
其他有用的非离子表面活性剂包括C12至C36乙氧基化脂肪酸,C12至C38单-和二甘油酯,C12至C36单-和二脱水山梨醇酯,每分子中各自含有约4至约20摩尔环氧乙烷的C12至C36丙二醇或乙二醇酯;含有约8至20个重复甘油单位的C8至C36聚甘油单酯;具有约1-10个重复糖单位的C8至C36烷基聚葡糖苷;C8至C14蔗糖单酯;每分子中含有约1-20摩尔环氧乙烷的C12至C36羧化乙氧基化脂肪醇。
根据系统的pH值不同可以是阳离子或者阴离子表面活性剂的两性表面活性剂以清洁剂为代表,如十二烷基-β-氨基丙酸,N-烷基牛磺酸如按照美国专利2,658,072所述的十二烷胺与羟乙磺酸钠反应所制备的一种N-烷基牛磺酸,N-高级烷基天冬氨酸如按照美国专利2,438,091所述方法制备的那些物质,和以商品名“Miranol”出售并在美国专利2,528,378中描述的产物,所述专利引入本文作为参考。
本发明优选的是使用阴离子表面活性剂,非离子表面活性剂及其混合物。
在Mc Cutcheon的著作清洁剂和乳化剂(Detergents and Emulsi-fiers)(North American Ed.1986)第317-324页中可以发现可用于本发明的其他表面活性剂,此文献引入本文作为参考。
表面活性剂成分的含量约是0.5%至约10%,优选的是约0.5%至约5%,最优选的是约0.5%至约2%。
聚-α-烯烃。本发明组合物基本上也包含一种或多种具有下述分子式的聚-α-烯烃:
其中R1和R2分别是约C20至约C30的烷基。
有用的聚-α-烯烃的平均分子量为约250至约350道尔顿,而在100℃的粘度为约2至约4厘沲。可以按照ASTM方法D-88用毛细管粘度计来测量其粘度。
聚-α-烯烃可以购买到,如从金刚砂化学专业集团(Emery Chemical Specialties Group)以E-3002的名称购买到。
聚-α-烯烃一般占全部组合物的约2%至约30%,优选的是约5%至约15%,最优选的是约8%至约11%。
羧酸共聚物
用于本发明的羧酸共聚物是一种单体混合物的聚合物,这种单体混合物含有95.9-98.8%(重量)的选自丙烯酸、甲基丙烯酸和乙基丙烯酸的烯属不饱和羧酸单体,约1%至约3.5%(重量)的具有下述分子式的丙烯酸酯:
其中R是一个含有10至30个碳原子的烷基,R1是氢、甲基或乙基,以及0.1-0.6%(重量)的一种多元醇的可聚合交联聚链烯基聚醚,每个分子中含有一个以上的链烯基醚基,其中母体多元醇含有至少3个碳原子和至少3个羟基。
优选的是,这些聚合物含有约96%至约97.9%(重量)的丙烯酸和约2.5%至约3.5%(重量)的丙烯酸酯,其中烷基含有12至22个碳原子,R1是甲基,最优选的是,丙烯酸酯是甲基丙烯酸硬脂醇酯。交联单体的含量最好是约0.2%至约0.4%(重量)。优选的交联单体是烯丙基季戊四醇,三羟甲基丙烷二烯丙基醚或烯丙基蔗糖。这些聚合物全部都在1985年4月5日出版的Huang等人的美国专利4,509,949中进行了描述。
在生产用于本发明的聚合物中,有用的羟酸单体是含有至少一个活化的碳-碳烯双键和至少一个羧基的烯属不饱和羧酸。
优选的羧酸单体是具有下列通式的丙烯酸:
其中R2是一种选自氢、卤素和氰(---C=N)基团,一价烷基,一价烷芳基和一价环脂族基的取代基。在这类物质中,最优选的是丙烯酸、甲基丙烯酸和乙基丙烯酸。另一种有用的羧酸单体是马来酸酐或马来酸。所用酸的含量是所用单体总量的约95.5%至98.9%(重量)。更优选的范围是约96%至约97.9%(重量)。
将该聚合物与一种含有至少2个末端 基团的多官能亚乙烯基单体,包括如丁二烯、异戊二烯、二乙烯基苯、二乙烯基萘、丙烯酸烯丙酯等进行交联。用于制备该共聚体的特别有用的交联单体是每分子中含有一个以上链烯基醚基的聚链烯基聚醚。最有用的交联单体具有链烯基,其中一个烯双键被连接到末端亚甲基 上。最优选的是Carbomer 1342(可以从B.F.Goodrich以Carbopol 1342的商品名购买到)。
这些聚合物的含量为约0.025至约0.75,优选的是约0.05至约0.25,最优选的是约0.075至约0.175。
可任选的成分
乳化剂。本发明的组合物中最好含有乳化剂,优选的是占组合物重量的约0.05%至约10%,最优选的是约2%至约8%。尽管也可以使用其他类型的乳化剂,但是优选的乳化剂是阴离子或非离子乳化剂,最优选的是阴离子乳化剂。在例如,1973年8月28日出版的Dickert等人的美国专利3,755,560;1983年12月20日出版的Dixon等人的美国专利4,421,769和Mc Cutcheon的著作清洁剂和乳化剂(North American Edition,1983)中,公开了合适的乳化剂;这些文献引入本文作为参考。
可用于本发明组合物的其他类型的乳化剂包括乙氧基化脂肪酸,乙氧基化脂肪醇酯,乙氧基化醇,磷酸酯,聚氧乙烯脂肪族醚磷酸酯,脂肪酸酯,脂肪酸酰胺,酰基乳酸酯(acyl lactylates),肥皂及其混合物。脂肪醇如鲸蜡醇和十八烷醇以及cetearyl alcohol也可看作是用于本发明目的的乳化剂。这种乳化剂的例子包括聚氧乙烯(8)硬脂酸酯,十四烷基乙氧基(3)肉豆蔻酸酯,聚氧乙烯(100)单硬脂酸酯,月桂酰二乙醇胺,硬脂酰单乙醇胺,硬脂酰-2-乳酸钠。
润滑剂。本发明组合物最好还包含至少一种润滑剂。优选的润滑剂是挥发性硅油,非挥发性润滑剂及其混合物。本发明组合物更优选的是包含至少一种作为液体润滑剂的挥发性硅油,或者尤其是挥发性硅油和非挥发性润滑剂的混合物。本文所用术语“挥发性”是指在室温下具有可测蒸气压的那些物质。
用于本发明组合物的挥发性硅油最好是含有约3至约9个,尤其是约4至约5个硅原子的环状或线性聚二甲基硅氧烷。下面的分子式表示用于本发明组合物的环状挥发性聚二甲基硅氧烷:
其中n等于约3至约7,每分子线性聚二甲基硅氧烷含有约3至约9个硅原子,并且具有下面的通式:
(CH3)3Si-O-[Si(CH3)2-O]n-Si(CH3)3
其中n等于约1至约7。在25℃线性挥发性硅氧烷物质的粘度一般为约0.5厘沲,而环状硅氧烷物质的粘度一般低于10厘沲。对于各种挥发性硅油的描述见Todd等人的“化妆品用挥发性硅氧烷液体”(Cosmetic & Toiletries,91,1976)第27-32页,在本文中全部引入作为参考。
适用于本发明的优选挥发性硅油的例子包括:Dow Corning 344,Dow Corning 345和Dow Corning 200(由Dow Corning公司生产);硅氧烷7207和硅氧烷7158(由联合碳化物公司生产);SF1202(由普通电器公司(General Electric)生产);和SWS-03314(由SWS硅氧烷有限公司生产)。
本发明组合物最好还含有一种或多种非挥发性润滑剂。这类物质包括脂肪酸和脂肪醇酯,碳氢化合物,非挥发性硅油及其混合物。在化妆品科学与技术(Cosmetics.Science and Technology)27-104(M.Balsam和E.Sagarin,Ed.;1972),以及1980年5月13日出版的Shelton的美国专利4,202,879中对那些适用于本发明的润滑剂进行了描述,这两篇文献都引入本文作为参考。
可用于作为一种润滑剂材料的非挥发性硅油包括聚烷基硅氧烷,聚烷芳基硅氧烷和聚醚硅氧烷共聚物。适用于本发明的基本上非挥发性的聚烷基硅氧烷包括,例如,在25℃粘度约为5-100,000厘沲的聚二甲基硅氧烷。适用于本发明组合物的优选的非挥发性润滑剂是在25℃下粘度约为10-400厘沲的聚二甲基硅氧烷。这种聚烷基硅氧烷包括Vicasil系列(由General Electric公司出售)。和Dow Corning 200系列(由Dow Corning公司出售)。多烷芳基硅氧烷包括在25℃下粘度约为15-65厘沲的聚甲基苯基硅氧烷。这些润滑剂是市售的,例如以SF1075甲基苯基液(General Electric公司出售)和556化妆品级液(Dow Corning公司出售)的商品名购买到。有用的聚醚硅氧烷共聚物包括,例如,一种在25℃下粘度约为1200-1500厘沲的聚氧化烯醚共聚物。这种液体可以以SF-1066有机硅氧烷表面活性剂的商品名购买到(General Electric公司出售)。聚硅氧烷乙二醇醚共聚物是用于本发明组合物的优选共聚物。
适用于本发明作为一种润滑剂材料的非极性脂肪酸和脂肪醇酯包括,例如,己二酸二异丙酯,肉豆蔻酸异丙酯,棕榈酸异丙酯,棕榈酸乙基己酯,新戊烷酸异癸酯,苯甲酸C12-C15醇酯,油酸异癸酯,马来酸二乙基己酯,PPG-14丁基醚和PPG-2十四烷基醚丙酸酯。矿脂和USP轻(如Klearol )或重(如Kaydol )矿物油也可以用作润滑剂。
润滑剂总量一般占本发明组合物重量的约2%至约10%,最好是约2%至约6%。
尤其适用于本发明清洁组合物的是一种具有下面分子式的多支链烃化合物:
其中n是1-225的整数,优选的是1-214,较好是1-16,更好是1-4,最好是2-4的整数。这种多支链烃化合物的分子量约为170-12,000,而且可以从Presperse有限公司(South Plainfield,New Jersey)以Permethyl 99A-108A系列的商品名购买到。这些permethyl化合物的含量约为1%-30%,优选的是约1%-10%,最优选的是约1%-5%。
本发明的清洁组合物还可以任意含有在皮肤清洁组合物中惯用的现有技术用量的其他物质。
本发明组合物中也可以含有各种水溶性物质。这些物质包括湿润剂,如甘油、山梨醇、己二醇、丙二醇、聚乙二醇、烷氧基化葡萄糖和己烷三醇、乙基纤维素、聚乙烯醇、羧甲基纤维素、植物胶和粘土如Veegum (硅酸镁铝,R.T.Vanderbilt,Inc.);蛋白质和多肽;防腐剂如羟基苯甲酸的甲基、乙基、丙基和丁基酯(Parabens-Mallinckrodt化学公司),EDTA,甲基异噻唑啉酮和咪唑烷基脲(Germall 115-Sutton Laboratories);和碱性剂如三羟乙基胺,以在需要时中和组合物中存在的部分脂肪酸或增稠剂。另外,本发明典型的组合物可以含有常规的化妆品辅剂如,染料、遮光剂(如二氧化钛)、色素和香料。
本发明组合物也可以含有各种维生素。例如,可以使用维生素A及其衍生物,维生素B,生物素,泛酸,维生素D及其混合物。也可以使用维生素E,生育酚乙酸酯及其衍生物。
该皮肤清洁组合物中可以含有约0.5%至约4%的常规抗菌剂和卫生清洁剂(sanitizers)。适用于本发明的典型抗菌卫生清洁剂包括3,4-二-和3,4′,5′-三-溴-N-水杨酰苯胺;4,4′-二氯-3-(三氟甲基)-N-碳酰苯胺;3,4,4′-三氯-N-碳酰苯胺及这些物质的混合物。在1966年6月14日出版的Reller等人的美国专利3,256,200中更详细地描述了这些物质及相关物质在皮肤清洁组合物中的应用,该专利引入本文作为参考。
可以向本发明组合物中加入多达10%含量的游离脂肪酸,如椰子油脂肪酸,以致改善该组合物所产生泡沫的体积和质量(乳化性)。
除了前面所述的成分外,本发明的局部组合物可以含有各种其他的现有技术用量的局部组合物中惯用的油溶性物质和/或水溶性物质。
一种特别优选的可任意选择成分是阳离子或非离子聚合皮肤感觉助剂。在“护肤用聚合物JR”公报(Union Carbide,1977)引列出了两种类型聚合物在减少皮肤刺激性方面的优点。阳离子助剂比非离子助剂更适用于本发明,因为它能提供更好的皮肤感觉。下面列出了一些可用于此目的的阳离子聚合物和非离子聚合物的例子。
适用于本发明的聚合皮肤感觉助剂的含量约为该组合物的0.5%-5%,优选的是约0.1%至约2%,更优选的是约0.1%至约1%。
一种特别优选的皮肤感觉助剂是阳离子(季铵化的)瓜耳树胶,如,Celanese公司提供的Jaguar C-14-S。
用于本发明的其他类型高分子量聚合皮肤感觉助剂包括非离子瓜耳树胶,由Merck & Co.,Inc.制造的Merquats 100和550;联合碳化物公司制造的UCARE聚合物JR-400;Miranol化学有限公司制造的Mirapol A 15;和Henkel有限公司制造的Galactasol 811。
可以用来作为皮肤感觉助剂的非离子聚合物包括非离子多糖,例如,由Celanese公司的分公司Celanese水溶性聚合物公司出售的非离子羟丙基瓜耳树胶。一种优选的非离子羟丙基瓜耳树胶物质是Jaguar HP-60,其羟丙基摩尔取代数约为0.6。另一类有用的非离子皮肤感觉助剂包括纤维素非离子聚合物,例如,羟乙基纤维素和羧甲基纤维素。
该皮肤清洁组合物的物理状态不是很严格的。可以运用公知的技术将该组合物制备成,例如,乳剂和洗剂等。
下面的非限定性实施例对本发明目的的具体实现作出了说明,其中的必要成分和可任选成分配合使用。应该理解这些实施例只是用于说明本发明,而不是对本发明范围的限制。
实施例Ⅰ
按下述方法制备一种本发明的面部清洁组合物:
成分 %W/W
A相
水 适量
Carbomer 1342 0.20
甘油 6.00
己二醇 2.00
B相
矿物油 13.00
聚-α-烯烃2cst.19.00
异十二烷25.00
聚乙二醇-8月桂酸酯31.60
C12-C16苷43.50
脱水山梨醇硬脂酸酯52.15
十八烷醇 1.60
Ceteareth-20 1.00
鲸蜡醇 0.70
C相
水 1.00
三羟乙基胺 0.20
D相
水 1.00
甲基氯异噻唑啉酮
(Methychloroisothiazolonone)
(和)甲基异噻唑啉酮60.06
1可以从Quantum-Emery Division以Emerest 3002的商品名购买到
2可以从Presperse有限公司以Permethyl 99A的商品名购买到
3可以从Lonza有限公司以Pegosperse 400 ML的商品名购买到
4可以从Henkel公司以APG 625的商品名购买到
5可以从ICI Americas以Arlacel 60的商品名购买到
6可以从Rohm和Haas以Kathon CG的商品名购买到
使Carbomer A相进行水合,并加热至70℃。分别使B相的成分结合,并加热至75℃。然后将B相加至A相中,同时以中等速度搅拌。将C相加入到这种混合物中,并将得到的混合物冷却至40℃。将D相加入到这种混合物中,然后将该混合物冷却至30℃。
对于局部应用可以使用2克所得到的乳剂作为清洁剂,以去除灰尘和油腻以及难于去除的化装和防水睫毛油等。
实施例Ⅱ
按下述方法制备一种本发明的面部清洁组合物:
成分 %W/W
A相
水 适量
Carbomer 1342 0.20
甘油 6.00
丙二醇 2.00
对羟基苯甲酸甲酯 0.30
B相
聚-α-烯烃2cst 15.00
矿物油 7.00
棕榈酸异丙酯13.00
二甲基聚硅氧烷21.00
Steareth-21 2.30
Steareth-2 2.15
对羟基苯甲酸丙酯 0.20
对羟基苯甲酸乙酯 0.20
C相
水 1.00
三羟乙基胺 0.20
D相
水 1.00
DMDM乙内酰脲30.50
混合醚硫酸酯43.50
1可以从Wicken Chemicals以Wickenol 111的商品名购买到
2可以从Dow Corning公司以Dow Corning 225液的商品名购买到
3可以从Glyco以Glydant的商品名购买到
4可以从Henkel公司以Texapon ASV的商品名购买到
使Carbomer A相水合,并加热至70℃。分别使B相的成分结合并加热至75℃。然后将B相加入到A相中,同时以中等速度进行搅拌。将C相加入到这种混合物中,然后将所得混合物冷却至40℃。将D相加入到这种混合物中,然后将所得混合物冷却至30℃。
对于局部应用可以使用2克所得到的乳剂作为清洁剂,以去除灰尘和油腻以及难于去除的化装和防水睫毛油等。
实施例Ⅲ
按下述方法制备本发明的一种面部清洁组合物:
成分 %W/W
A相
水 适量
Carbomer 1342 0.15
甘油 5.50
丙二醇 1.50
对羟基苯甲酸甲酯 0.30
B相
聚-α-烯烃2cst 14.00
棕榈酸异丙酯 8.00
油酸异癸酯 4.00
二甲基聚硅氧烷 1.00
聚乙二醇-8月桂酸酯 3.25
单硬脂酸甘油酯SE13.00
十八烷醇 1.80
鲸蜡醇 1.80
Ceteareth-20 1.20
对羟基苯甲酸丙酯 0.20
对羟基苯甲酸乙酯 0.20
C相
水 1.00
三羟乙基胺 0.15
D相
水 1.00
咪唑烷基脲 0.50
E相
香料 0.25
1可以从Van Dyke以Cerasynt WM的商品名购买到
使Carbomer A相水合,并加热至70℃。分别使B相的成分结合,并加热至75℃。然后将B相加入到A相中,同时以中等速度搅拌。将C相加入到这种混合物中并将所得混合物冷却至40℃。将D相和E相加入到这种混合物中,然后将此混合物冷却至30℃。
对于局部应用可以使用2克所得到的乳剂作为清洁剂,以去除灰尘和油腻以及难于去除的化装和防水睫毛油等。
实施例Ⅳ
按下述方法制备本发明的一种面部清洁组合物。
成分 %W/W
A相
水 适量
Carbomer 1342 0.30
甘油 5.50
丙二醇 2.00
对羟基苯甲酸甲酯 0.30
混合醚硫酸酯 2.50
B相
聚-α-烯烃2cst 11.50
马来酸二辛酯19.00
异十六烷24.75
环甲基聚硅氧烷31.00
辛酰基/癸酰基(capryl)糖苷43.25
十八烷醇 2.00
鲸蜡醇 1.80
Ceteareth-20 1.50
对羟基苯甲酸丙酯 0.20
对羟基苯甲酸乙酯 0.20
C相
水 1.00
三羟乙基胺 0.30
D相
水 1.00
咪唑烷基脲 0.50
FD & C Blue #1(0.10%溶液) 0.10
E相
香料 0.15
1可以从Bernel以Bernel Ester DOM的商品名购买到
2可以从Presperse有限公司以Permethyl 101 A的商品名购买到
3可以从Dow Corning公司以Dow Corning 345液的商品名购买到
4可以从Rohm和Haas以Triton CG 110的商品名购买到
使Carbomer A相进行水合,并加热至70℃。使B相的成分分别结合,并加热至75℃。将B相加入到A相中,同时以中等速度搅拌。将C相加入到这种混合物中,然后将所得混合物冷却至40℃。再将D相和E相加入到这种混合物中,使所得混合物冷却至30℃。
对于局部应用可以使用2克所得到的乳剂作为清洁剂,以去除灰尘和油腻以及难于去除的化装和防水睫毛油等。
Claims (10)
1、一种用于去除化装及类似物的水包油型乳剂形式的的清洁组合物,含有:
a.约0.5%至约10%的HLB值大于约10的表面活性剂,该表面活性剂选自阴离子的、非离子的、两性离子的和两性的表面活性剂及其混合物。
b.约2%至约30%的具有下面分子式的聚-α-烯烃:R1-C=C-R2其中R1和R2分别是从约C20至约C30的烷基,所说的聚α-烯烃在100℃下的粘度为约2至约4厘沲;和
c.约0.025%至约0.75%的一种由单体混合物的聚合体组成的羧酸共聚物,该单体混合物包含有95.9%至98.8%(重量)的一种选自丙烯酸、甲基丙烯酸和乙基丙烯酸的烯属不饱和羧酸单体,约1%至约3.5%(重量)的一种具有下列分子式的丙烯酸酯:
其中R是一个含有10到30个碳原子的烷基,R1是氢、甲基或乙基,和0.1%至0.6%(重量)的一种多元醇的可聚交联聚链烯基聚醚,该聚醚的每个分子中含有一个以上的链烯基醚基,其中母体多元醇含有至少3个碳原子和至少3个羟基。
2、一种如权利要求1的清洁组合物,含有约0.5%至约5%的表面活性剂成分,其中所说的表面活性剂选自阴离子表面活性剂、非离子表面活性剂及其混合物,并且还含有约5%至约15%的聚-α-烯烃。
3、一种如权利要求2的清洁组合物,还含有约1%至约30%的分子式如下的多支链烃化合物:
其中n是一个1-225的整数。
4、一种如权利要求3的清洁组合物,含有约1%至约10%的多支链烃化合物成分,并且其中n是1-16的整数。
5、一种如权利要求4的清洁组合物,含有约0.5%至约2%的表面活性剂成分和约1%至约5%的多支链烃化合物成分,并且其中的n是1-4的整数。
6、一种如权利要求5的清洁组合物,含有约8%至约11%的聚-α-烯烃成分。
7、一种如权利要求6的清洁组合物,还含有约0.05%至约10%的一种乳化剂。
8、一种如权利要求7的清洁组合物,含有约2%至约8%的乳化剂成分。
9、一种如权利要求8的清洁组合物,还含有约2%至约10%的一种润滑剂。
10、一种如权利要求9的清洁组合物,其中所说的润滑剂选自挥发性硅油和非挥发性润滑剂及其混合物。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US07/419,895 US5011681A (en) | 1989-10-11 | 1989-10-11 | Facial cleansing compositions |
US419,895 | 1989-10-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
CN1051671A true CN1051671A (zh) | 1991-05-29 |
Family
ID=23664196
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN90109130A Pending CN1051671A (zh) | 1989-10-11 | 1990-10-11 | 改进的面部清洁组合物 |
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US (1) | US5011681A (zh) |
EP (1) | EP0422862A3 (zh) |
JP (1) | JPH03169804A (zh) |
KR (1) | KR910007507A (zh) |
CN (1) | CN1051671A (zh) |
AU (1) | AU626466B2 (zh) |
CA (1) | CA2026963C (zh) |
FI (1) | FI904982A0 (zh) |
IE (1) | IE903624A1 (zh) |
MX (1) | MX171356B (zh) |
MY (1) | MY107415A (zh) |
NZ (1) | NZ235607A (zh) |
PT (1) | PT95562A (zh) |
TR (1) | TR25525A (zh) |
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-
1989
- 1989-10-11 US US07/419,895 patent/US5011681A/en not_active Expired - Fee Related
-
1990
- 1990-10-04 CA CA002026963A patent/CA2026963C/en not_active Expired - Fee Related
- 1990-10-08 EP EP19900310986 patent/EP0422862A3/en not_active Ceased
- 1990-10-09 TR TR90/0997A patent/TR25525A/xx unknown
- 1990-10-09 NZ NZ235607A patent/NZ235607A/xx unknown
- 1990-10-10 MY MYPI90001765A patent/MY107415A/en unknown
- 1990-10-10 AU AU63973/90A patent/AU626466B2/en not_active Ceased
- 1990-10-10 FI FI904982A patent/FI904982A0/fi not_active IP Right Cessation
- 1990-10-10 IE IE362490A patent/IE903624A1/en unknown
- 1990-10-11 CN CN90109130A patent/CN1051671A/zh active Pending
- 1990-10-11 KR KR1019900016075A patent/KR910007507A/ko not_active Application Discontinuation
- 1990-10-11 JP JP2273106A patent/JPH03169804A/ja active Pending
- 1990-10-11 MX MX022817A patent/MX171356B/es unknown
- 1990-10-11 PT PT95562A patent/PT95562A/pt not_active Application Discontinuation
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN100475178C (zh) * | 2000-04-11 | 2009-04-08 | 路博润高级材料公司 | 稳定的含水表面活性剂组合物 |
CN107427445A (zh) * | 2015-02-19 | 2017-12-01 | 荷兰联合利华有限公司 | 快速冲洗的清洁组合物 |
US10751271B2 (en) | 2015-02-19 | 2020-08-25 | Conopco, Inc. | Fast rinsing cleansing composition |
CN106749376A (zh) * | 2016-12-28 | 2017-05-31 | 江苏美思德化学股份有限公司 | 不同挥发速率的线性聚硅氧烷组合物及制备方法 |
Also Published As
Publication number | Publication date |
---|---|
TR25525A (tr) | 1993-05-01 |
IE903624A1 (en) | 1991-04-24 |
FI904982A0 (fi) | 1990-10-10 |
JPH03169804A (ja) | 1991-07-23 |
CA2026963A1 (en) | 1991-04-12 |
AU626466B2 (en) | 1992-07-30 |
KR910007507A (ko) | 1991-05-30 |
US5011681A (en) | 1991-04-30 |
CA2026963C (en) | 1995-02-21 |
AU6397390A (en) | 1991-04-18 |
EP0422862A2 (en) | 1991-04-17 |
MY107415A (en) | 1995-12-30 |
PT95562A (pt) | 1991-08-14 |
NZ235607A (en) | 1993-04-28 |
EP0422862A3 (en) | 1992-11-25 |
MX171356B (es) | 1993-10-20 |
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