CN104987767A - Package printing ink and preparation method therefor - Google Patents

Package printing ink and preparation method therefor Download PDF

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Publication number
CN104987767A
CN104987767A CN201510427779.XA CN201510427779A CN104987767A CN 104987767 A CN104987767 A CN 104987767A CN 201510427779 A CN201510427779 A CN 201510427779A CN 104987767 A CN104987767 A CN 104987767A
Authority
CN
China
Prior art keywords
resin
printing ink
minute
solvent
butyl acrylate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510427779.XA
Other languages
Chinese (zh)
Inventor
徐中豪
徐数数
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hefei Zhonghao New Material Co Ltd
Original Assignee
Hefei Zhonghao New Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Zhonghao New Material Co Ltd filed Critical Hefei Zhonghao New Material Co Ltd
Priority to CN201510427779.XA priority Critical patent/CN104987767A/en
Publication of CN104987767A publication Critical patent/CN104987767A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/03Printing inks characterised by features other than the chemical nature of the binder
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/106Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D11/107Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof

Abstract

The invention provides package printing ink which is prepared from the following raw materials in percentage by weight: 15-25% of LX-2 resin, 10-15% of acrylic acid, 15-20% of deionized water, 1-5% of paraffin, 5-10% of butyl acrylate, 10-15% of ammonia water, 2-5% of urea, 1-5% of a gelatin solution, 1-5% of glycerinum, 2-5% of a defoamer, 1-5% of titanium dioxide, 10-15% of D3 resin and 10-20% of a solvent. The invention provides the package printing ink which has the characteristic of environment protection, and toxic and harmful substances which are harmful to health and pollute the environment are prevented from being volatilized.

Description

A kind of packages printing ink and preparation method thereof
Technical field
The present invention relates to a kind of packages printing ink and preparation method thereof, belong to printing technology.
Background technology
Ink is the material for the formation of graph text information in printing process, and ink occupies important effect in print field, and the quality of ink property directly determines the contrast, color, sharpness etc. of printed matter epigraph.Ink should except possessing bright colour, and excellent printing adaptability, outside suitable rate of drying, also has the application indexes such as certain solvent resistant, acid, alkali, water, light, heat.
During printing, operator are when selecting ink, generally color regarded as first requirement, and the color of ink is one of index the most intuitively, and it is a leading indicator of reflection printing standard.So the quality of pigment directly has influence on the quality of ink, pigment determines the quality of ink to a great extent, as: color, rare thick, on viscosity, physicochemical property and printing performance etc. by very large impact.But all prepare chemical substance in general pigment, easily volatilize hazardous and noxious substances, unhealthful, contaminate environment.
Summary of the invention
In order to overcome problems of the prior art, the invention provides a kind of packages printing ink with environmental protection characteristic, avoiding the volatilization of hazardous and noxious substances, health risk, contaminate environment.
Technical problem to be solved by this invention realizes by the following technical solutions:
A kind of packages printing ink, is made up of the raw material of following weight percent: LX-2 resin 15-25%, vinylformic acid 10-15%, deionized water 15-20%, paraffin 1-5%, butyl acrylate 5-10%, ammoniacal liquor 10-15%, urea 2-5%, gelatin solution 1-5%, glycerine 1-5%, defoamer 2-5%, titanium dioxide 1-5%, D3 resin 10-15%, solvent 10-20%.
As optimal technical scheme, described solvent is alcohol, ester solvent.
A preparation method for packages printing ink,
Comprise the following steps:
1) vinylformic acid and ammoniacal liquor are put in reactor, then start stir and slowly add LX-2 resin (in this process, section adds a small amount of pure water), test ph to 8-8.5, and after reaching standard, discharging is filtered stand-by;
2) butyl acrylate and D3 resin are joined in reactor mix, be warming up to 45-120 DEG C, start to stir lasting 15-25 minute, liquid to be mixed leave standstill transparent after, more slowly add deionized water, modulation makes ph be 6.8-7.5, after reaching mark, discharging is filtered stand-by;
3) by step 1), step 2) and remaining raw material be mixed together in rear placements baking incubator, the temperature that incubator is dried in modulation continues after 7-13 minute between 27-33 DEG C, put into agitator and carry out rapid stirring 15-20 minute, get product after leaving standstill.
The invention has the beneficial effects as follows: being added with of (1) titanium dioxide, paraffin, glycerine helps strengthen the gorgeous degree of light and the solid sense of ink; (2) defoamer be added with the fixation and antiseptic property that are beneficial to ink; (3) gelatin solution contributes to the assurance of transparency in preparation process, shortens settling time; (4) composition of colorant greatly reduces pollutent and the volatile contaminant of chemical, and environmental protection and economy degree is high.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearly understand, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
Embodiment 1
A kind of packages printing ink, is made up of the raw material of following weight percent: LX-2 resin 15%, vinylformic acid 15%, deionized water 15%, paraffin 5%, butyl acrylate 5%, ammoniacal liquor 15%, urea 2%, gelatin solution 1%, glycerine 4%, defoamer 2%, titanium dioxide 1%, D3 resin 10%, solvent 10%.
Solvent is alcohol, ester solvent.
A preparation method for packages printing ink,
Comprise the following steps:
1) vinylformic acid and ammoniacal liquor are put in reactor, then start stir and slowly add LX-2 resin (in this process, section adds a small amount of pure water), test ph to 8-8.5, and after reaching standard, discharging is filtered stand-by;
2) butyl acrylate and D3 resin are joined in reactor mix, be warming up to 45-120 DEG C, start to stir lasting 15-25 minute, liquid to be mixed leave standstill transparent after, more slowly add deionized water, modulation makes ph be 6.8-7.5, after reaching mark, discharging is filtered stand-by;
3) by step 1), step 2) and remaining raw material be mixed together in rear placements baking incubator, the temperature that incubator is dried in modulation continues after 7-13 minute between 27-33 DEG C, put into agitator and carry out rapid stirring 15-20 minute, get product after leaving standstill.
Wherein, titanium dioxide (on a small quantity), paraffin, being added with of glycerine help strengthen the gorgeous degree of light of ink and solid sense; Defoamer be added with the fixation and antiseptic property that are beneficial to ink; Gelatin solution contributes to the assurance of transparency in preparation process, shortens settling time; The composition of colorant greatly reduces pollutent and the volatile contaminant of chemical, and environmental protection and economy degree is high.
According to concrete demand, the mass percent of above-mentioned raw materials can do suitable adjustment allotment, and ph value also can modulate difference, thus the obtained coating possessing different performance, obtain different results of use.
Embodiment 2
A kind of packages printing ink, is made up of the raw material of following weight percent: LX-2 resin 20%, vinylformic acid 10%, deionized water 20%, paraffin 1%, butyl acrylate 5%, ammoniacal liquor 10%, urea 2%, gelatin solution 2%, glycerine 2%, defoamer 3%, titanium dioxide 3%, D3 resin 12%, solvent 10%.
Solvent is alcohol, ester solvent.
A preparation method for packages printing ink,
Comprise the following steps:
1) vinylformic acid and ammoniacal liquor are put in reactor, then start stir and slowly add LX-2 resin (in this process, section adds a small amount of pure water), test ph to 8-8.5, and after reaching standard, discharging is filtered stand-by;
2) butyl acrylate and D3 resin are joined in reactor mix, be warming up to 45-120 DEG C, start to stir lasting 15-25 minute, liquid to be mixed leave standstill transparent after, more slowly add deionized water, modulation makes ph be 6.8-7.5, after reaching mark, discharging is filtered stand-by;
3) by step 1), step 2) and remaining raw material be mixed together in rear placements baking incubator, the temperature that incubator is dried in modulation continues after 7-13 minute between 27-33 DEG C, put into agitator and carry out rapid stirring 15-20 minute, get product after leaving standstill.
Wherein, titanium dioxide (on a small quantity), paraffin, being added with of glycerine help strengthen the gorgeous degree of light of ink and solid sense; Defoamer be added with the fixation and antiseptic property that are beneficial to ink; Gelatin solution contributes to the assurance of transparency in preparation process, shortens settling time; The composition of colorant greatly reduces pollutent and the volatile contaminant of chemical, and environmental protection and economy degree is high.
According to concrete demand, the mass percent of above-mentioned raw materials can do suitable adjustment allotment, and ph value also can modulate difference, thus the obtained coating possessing different performance, obtain different results of use.
Embodiment 3
A kind of packages printing ink, is made up of the raw material of following weight percent: LX-2 resin 18%, vinylformic acid 12%, deionized water 18%, paraffin 2%, butyl acrylate 6%, ammoniacal liquor 12%, urea 2%, gelatin solution 2%, glycerine 2%, defoamer 2%, titanium dioxide 1%, D3 resin 11%, solvent 12%.
Solvent is alcohol, ester solvent.
A preparation method for packages printing ink,
Comprise the following steps:
1) vinylformic acid and ammoniacal liquor are put in reactor, then start stir and slowly add LX-2 resin (in this process, section adds a small amount of pure water), test ph to 8-8.5, and after reaching standard, discharging is filtered stand-by;
2) butyl acrylate and D3 resin are joined in reactor mix, be warming up to 45-120 DEG C, start to stir lasting 15-25 minute, liquid to be mixed leave standstill transparent after, more slowly add deionized water, modulation makes ph be 6.8-7.5, after reaching mark, discharging is filtered stand-by;
3) by step 1), step 2) and remaining raw material be mixed together in rear placements baking incubator, the temperature that incubator is dried in modulation continues after 7-13 minute between 27-33 DEG C, put into agitator and carry out rapid stirring 15-20 minute, get product after leaving standstill.
Wherein, titanium dioxide (on a small quantity), paraffin, being added with of glycerine help strengthen the gorgeous degree of light of ink and solid sense; Defoamer be added with the fixation and antiseptic property that are beneficial to ink; Gelatin solution contributes to the assurance of transparency in preparation process, shortens settling time; The composition of colorant greatly reduces pollutent and the volatile contaminant of chemical, and environmental protection and economy degree is high.
According to concrete demand, the mass percent of above-mentioned raw materials can do suitable adjustment allotment, and ph value also can modulate difference, thus the obtained coating possessing different performance, obtain different results of use.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.

Claims (3)

1. a packages printing ink, it is characterized in that, be made up of the raw material of following weight percent: LX-2 resin 15-25%, vinylformic acid 10-15%, deionized water 15-20%, paraffin 1-5%, butyl acrylate 5-10%, ammoniacal liquor 10-15%, urea 2-5%, gelatin solution 1-5%, glycerine 1-5%, defoamer 2-5%, titanium dioxide 1-5%, D3 resin 10-15%, solvent 10-20%.
2. a kind of packages printing ink according to claim 1, it is characterized in that, described solvent is alcohol, ester solvent.
3. the preparation method of a kind of packages printing ink according to claim 1, is characterized in that, comprise the following steps:
1) vinylformic acid and ammoniacal liquor are put in reactor, then start stir and slowly add LX-2 resin (in this process, section adds a small amount of pure water), test ph to 8-8.5, and after reaching standard, discharging is filtered stand-by;
2) butyl acrylate and D3 resin are joined in reactor mix, be warming up to 45-120 DEG C, start to stir lasting 15-25 minute, liquid to be mixed leave standstill transparent after, more slowly add deionized water, modulation makes ph be 6.8-7.5, after reaching mark, discharging is filtered stand-by;
3) by step 1), step 2) and remaining raw material be mixed together in rear placements baking incubator, the temperature that incubator is dried in modulation continues after 7-13 minute between 27-33 DEG C, put into agitator and carry out rapid stirring 15-20 minute, get product after leaving standstill.
CN201510427779.XA 2015-07-17 2015-07-17 Package printing ink and preparation method therefor Pending CN104987767A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510427779.XA CN104987767A (en) 2015-07-17 2015-07-17 Package printing ink and preparation method therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510427779.XA CN104987767A (en) 2015-07-17 2015-07-17 Package printing ink and preparation method therefor

Publications (1)

Publication Number Publication Date
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107502039A (en) * 2017-10-12 2017-12-22 安徽同利塑胶彩印有限公司 One kind is used for packaging for foodstuff and prints water-based type ink
CN107603331A (en) * 2017-09-30 2018-01-19 安徽嘉美包装有限公司 A kind of ultraviolet light solidifies packaging ink
CN108034299A (en) * 2017-12-19 2018-05-15 费晨 A kind of aqueous composite ink and preparation method thereof
CN111645387A (en) * 2020-05-19 2020-09-11 席志竹 Printing ink laminate

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4620876A (en) * 1982-08-23 1986-11-04 Ricoh Company, Ltd. Aqueous ink for ink-jet printing
CN101328232A (en) * 2007-06-22 2008-12-24 东莞市佳景印刷材料有限公司 Semi-filming emulsion and preparation thereof
CN104046123A (en) * 2014-07-09 2014-09-17 繁昌县朱氏印务有限责任公司 Environment-friendly package printing ink formula
CN104672987A (en) * 2015-02-14 2015-06-03 力嘉包装(深圳)有限公司 Water-based environment-friendly multi-purpose ink

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4620876A (en) * 1982-08-23 1986-11-04 Ricoh Company, Ltd. Aqueous ink for ink-jet printing
CN101328232A (en) * 2007-06-22 2008-12-24 东莞市佳景印刷材料有限公司 Semi-filming emulsion and preparation thereof
CN104046123A (en) * 2014-07-09 2014-09-17 繁昌县朱氏印务有限责任公司 Environment-friendly package printing ink formula
CN104672987A (en) * 2015-02-14 2015-06-03 力嘉包装(深圳)有限公司 Water-based environment-friendly multi-purpose ink

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107603331A (en) * 2017-09-30 2018-01-19 安徽嘉美包装有限公司 A kind of ultraviolet light solidifies packaging ink
CN107502039A (en) * 2017-10-12 2017-12-22 安徽同利塑胶彩印有限公司 One kind is used for packaging for foodstuff and prints water-based type ink
CN108034299A (en) * 2017-12-19 2018-05-15 费晨 A kind of aqueous composite ink and preparation method thereof
CN111645387A (en) * 2020-05-19 2020-09-11 席志竹 Printing ink laminate

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Application publication date: 20151021

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