CN104556011A - Method for preparing porous graphene microspheres through high-speed mixing technology - Google Patents
Method for preparing porous graphene microspheres through high-speed mixing technology Download PDFInfo
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- CN104556011A CN104556011A CN201510001514.3A CN201510001514A CN104556011A CN 104556011 A CN104556011 A CN 104556011A CN 201510001514 A CN201510001514 A CN 201510001514A CN 104556011 A CN104556011 A CN 104556011A
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Abstract
The invention relates to a preparation method of porous graphene microspheres, discloses a method for preparing the porous graphene microspheres through a high-speed mixing technology and aims to solve the problem in the prior art that porous graphene with a spherical structure cannot be prepared. The method comprises the following steps: mixing polyvinylpyrrolidone powder, dried graphene oxide powder and dried silicon dioxide microsphere powder with deionized water to obtain composite suspension liquid, adding the composite suspension liquid into simethicone, performing high-speed mixing at a certain temperature, curing, forming, standing, precipitating, heating, curing, calcining, soaking in a hydrofluoric acid solution, and drying to obtain the porous graphene microspheres. The method is used for preparing the porous graphene microspheres through the high-speed mixing technology.
Description
Technical field
The present invention relates to the preparation method of porous graphene microballon.
Background technology
Carbon material specific surface area is high, conductive capability good, stable chemical nature, easily shaping, simultaneously cheap, raw material sources extensively, mature production technology, be the most widely used electrode materials in ultracapacitor field.Graphene is as a kind of novel nanometer two-dimensional material, show a lot of excellent physical property, as specific surface area is large, electroconductibility is good, thermostability and physical strength high, since finding one of most popular domain just becoming people's research, and very large effect is played in the performance boost of the discovery of new carbon Graphene to electrode material for super capacitor.M.D.Stouer etc. using the rare ultracapacitor as electrode of graphite, and test its ratio capacitance in water system and organic electrolyte respectively, can reach 135F/g and 99F/g respectively; Quadrol and the Resorcino such as Chen modify graphene oxide, greatly increase the ratio capacitance value of graphene oxide; The people such as Wang adopt in-situ polymerization, reduction/doping and dedoping three processes to prepare polyaniline/Graphene hybrid supercapacitor electrode materials, and ratio capacitance value is up to 1126F/g.Therefore, Graphene is applied in electrode material for super capacitor field as carbon material very large development prospect.The invention provides a kind of globosity of porous graphene, former porous graphene does not almost have globosity.
Summary of the invention
The present invention will solve the problem that prior art cannot prepare the porous graphene of globosity, and provides a kind of method utilizing high-speed stirring technology to prepare porous graphene microballon.
Utilize high-speed stirring technology to prepare a method for porous graphene microballon, specifically carry out according to following steps:
One, polyvinylpyrrolidonepowder powder, graphene oxide dry powder and silicon dioxide microsphere dry powder are mixed, obtain powder mix, then powder mix is mixed with deionized water, obtain composite suspension liquid;
The mass ratio of described polyvinylpyrrolidonepowder powder and graphene oxide dry powder is 1:(0.2 ~ 0.3); The mass ratio of described polyvinylpyrrolidonepowder powder and silicon dioxide microsphere dry powder is 1:(0.5 ~ 1); Described powder mix and the mass ratio of deionized water are 1:(25 ~ 30);
Two, composite suspension liquid is joined fill in the polypropylene microwave oven box of dimethyl silicone oil, under temperature is 80 DEG C ~ 90 DEG C and stirring velocity is the condition of 400rpm ~ 600rpm, magnetic agitation 2h ~ 3h, then curing molding, last at room temperature standing precipitating 12h ~ 24h, obtains polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads;
Three, substep intensification heating method is adopted by polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads to be cured; Described substep intensification heating method is specifically carried out according to the following steps: polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads is heated 2h ~ 3h at temperature is 80 DEG C ~ 100 DEG C, 10h ~ 12h is heated again at temperature is 150 DEG C, finally at temperature is 280 DEG C, heat 1.5h ~ 2h, obtain the compounded microbeads of completion of cure;
Four, under condition of nitrogen gas, be under the condition of 750 DEG C ~ 850 DEG C by the compounded microbeads of completion of cure in temperature, calcining 1.5h ~ 2h, obtains graphene/silicon dioxide compounded microbeads;
Five, 1., by graphene/silicon dioxide compounded microbeads impregnated in the hydrofluoric acid solution that mass percent is 8%, dipping 2h ~ 3h; 2., again change mass percent be the hydrofluoric acid solution of 8%, repeating step five 1. 4 times ~ 5 times; 3., dry, namely obtain porous graphene microballon.
The invention has the beneficial effects as follows: 1. the present invention obtains having the Graphene microballon of vesicular structure, and the graphene layer pattern of inside and outside all has obvious fold sense.
2. adopt direct-fired mode to be cured mixed solution small droplets, solidification rate obtains great lifting.
3. polyvinylpyrrolidone is a kind of water miscible polymkeric substance, and along with water is from drop internal diffusive evaporation gradually, water miscible polyvinylpyrrolidone is also thereupon to the diffusion of drop skin, and in whole solidification process, polyvinylpyrrolidone plays the effect of firm pattern.
4. the pyrroles's nitrogen be rich in polyvinylpyrrolidone and carbonyl can produce fake capacitance, and it has a great impact the capacitive property of porous graphene microballon.
5. the Graphene of two dimension is transformed into the Graphene microballon of the three-dimensional packed structures of porous by the present invention, and Graphene has high-ratio surface sum highly conc, has broad application prospects in electrode material for super capacitor field.
The present invention is used for a kind of method utilizing high-speed stirring technology to prepare porous graphene microballon.
Accompanying drawing explanation
Fig. 1 is the scanning electron microscopic picture of the porous graphene microballon of preparation in embodiment 1, and magnification is 100;
Fig. 2 is the scanning electron microscopic picture of the porous graphene microballon of preparation in embodiment 1, and magnification is 10000;
Fig. 3 is the porous graphene microballon of preparation and the X-ray diffractogram of graphene oxide in embodiment 1, and 1 is graphene oxide, and 2 is porous graphene microballon;
Fig. 4 is cyclic voltammetry curve, and 1 represents the cyclic voltammetry curve sweeping the porous graphene microballon prepared in embodiment 1 when speed is 5mV/s; 2 represent the cyclic voltammetry curve sweeping the porous graphene microballon prepared in embodiment 1 when speed is 10mV/s; 3 represent the cyclic voltammetry curve sweeping the porous graphene microballon prepared in embodiment 1 when speed is 20mV/s; 4 represent the cyclic voltammetry curve sweeping the porous graphene microballon prepared in embodiment 1 when speed is 50mV/s; 5 represent the cyclic voltammetry curve sweeping the porous graphene microballon prepared in embodiment 1 when speed is 100mV/s.
Embodiment
Technical solution of the present invention is not limited to following cited embodiment, also comprises the arbitrary combination between each embodiment.
Embodiment one: a kind of method utilizing high-speed stirring technology to prepare porous graphene microballon described in present embodiment, specifically carry out according to following steps:
One, polyvinylpyrrolidonepowder powder, graphene oxide dry powder and silicon dioxide microsphere dry powder are mixed, obtain powder mix, then powder mix is mixed with deionized water, obtain composite suspension liquid;
The mass ratio of described polyvinylpyrrolidonepowder powder and graphene oxide dry powder is 1:(0.2 ~ 0.3); The mass ratio of described polyvinylpyrrolidonepowder powder and silicon dioxide microsphere dry powder is 1:(0.5 ~ 1); Described powder mix and the mass ratio of deionized water are 1:(25 ~ 30);
Two, composite suspension liquid is joined fill in the polypropylene microwave oven box of dimethyl silicone oil, under temperature is 80 DEG C ~ 90 DEG C and stirring velocity is the condition of 400rpm ~ 600rpm, magnetic agitation 2h ~ 3h, then curing molding, last at room temperature standing precipitating 12h ~ 24h, obtains polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads;
Three, substep intensification heating method is adopted by polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads to be cured; Described substep intensification heating method is specifically carried out according to the following steps: polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads is heated 2h ~ 3h at temperature is 80 DEG C ~ 100 DEG C, 10h ~ 12h is heated again at temperature is 150 DEG C, finally at temperature is 280 DEG C, heat 1.5h ~ 2h, obtain the compounded microbeads of completion of cure;
Four, under condition of nitrogen gas, be under the condition of 750 DEG C ~ 850 DEG C by the compounded microbeads of completion of cure in temperature, calcining 1.5h ~ 2h, obtains graphene/silicon dioxide compounded microbeads;
Five, 1., by graphene/silicon dioxide compounded microbeads impregnated in the hydrofluoric acid solution that mass percent is 8%, dipping 2h ~ 3h; 2., again change mass percent be the hydrofluoric acid solution of 8%, repeating step five 1. 4 times ~ 5 times; 3., dry, namely obtain porous graphene microballon.
Curing molding in present embodiment step 2 evaporates by the moisture in liquid.
The beneficial effect of present embodiment is: 1. present embodiment obtains having microballon, and the Graphene pattern of inside and outside all has obvious fold sense.
2. adopt direct-fired mode to be cured mixed solution small droplets, solidification rate obtains great lifting.
3. polyvinylpyrrolidone is a kind of water miscible polymkeric substance, and along with water is from drop internal diffusive evaporation gradually, water miscible polyvinylpyrrolidone is also thereupon to the diffusion of drop skin, and in whole solidification process, polyvinylpyrrolidone plays the effect of firm pattern.
4. the pyrroles's nitrogen be rich in polyvinylpyrrolidone and carbonyl can produce fake capacitance, and it has a great impact the capacitive property of porous graphene microballon.
5. the Graphene of two dimension is transformed into the Graphene microballon of the three-dimensional packed structures of porous by present embodiment, and Graphene has high-ratio surface sum highly conc, has broad application prospects in electrode material for super capacitor field.
Embodiment two: present embodiment and embodiment one unlike: the mass ratio of the polyvinylpyrrolidonepowder powder described in step one and graphene oxide dry powder is 1:(0.2 ~ 0.28).Other is identical with embodiment one.
Embodiment three: one of present embodiment and embodiment one or two unlike: the mass ratio of the polyvinylpyrrolidonepowder powder described in step one and silicon dioxide microsphere dry powder is 1:(0.5 ~ 0.9).Other is identical with embodiment one or two.
Embodiment four: one of present embodiment and embodiment one to three unlike: the mass ratio of the powder mix described in step one and deionized water is 1:(25 ~ 28).Other is identical with embodiment one to three.
Embodiment five: one of present embodiment and embodiment one to four unlike: the substep intensification heating method described in step 3 is specifically carried out according to the following steps: polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads is heated 2h ~ 2.8h at temperature is 80 DEG C ~ 100 DEG C, 10h ~ 11h is heated again at temperature is 150 DEG C, finally at temperature is 280 DEG C, heat 1.6h ~ 2h, obtain the compounded microbeads of completion of cure.Other is identical with embodiment one to four.
Embodiment six: one of present embodiment and embodiment one to five unlike: in step 4 under condition of nitrogen gas, be under the condition of 750 DEG C ~ 800 DEG C in temperature by the compounded microbeads of completion of cure, calcining 1.6h ~ 2h, obtains graphene/silicon dioxide compounded microbeads.Other is identical with embodiment one to five.
Following examples are adopted to verify beneficial effect of the present invention:
Embodiment 1:
A kind of method utilizing high-speed stirring technology to prepare porous graphene microballon described in the present embodiment, specifically carry out according to following steps:
One, polyvinylpyrrolidonepowder powder, graphene oxide dry powder and silicon dioxide microsphere dry powder are mixed, obtain powder mix, then powder mix is mixed with deionized water, obtain composite suspension liquid;
The mass ratio of described polyvinylpyrrolidonepowder powder and graphene oxide dry powder is 1:0.2; The mass ratio of described polyvinylpyrrolidonepowder powder and silicon dioxide microsphere dry powder is 1:0.5; Described powder mix and the mass ratio of deionized water are 1:25;
Two, composite suspension liquid is joined fill in the polypropylene microwave oven box of dimethyl silicone oil, under temperature is 80 DEG C and stirring velocity is the condition of 500rpm, magnetic agitation 2h, curing molding, last at room temperature standing precipitating 12h, obtains polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads;
Three, substep intensification heating method is adopted by polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads to be cured;
Described substep intensification heating method is specifically carried out according to the following steps: polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads is heated 2h at temperature is 100 DEG C, 10h is heated again at temperature is 150 DEG C, finally at temperature is 280 DEG C, heat 1.5h, obtain the compounded microbeads of completion of cure;
Four, under condition of nitrogen gas, by the compounded microbeads of completion of cure at temperature is 750 DEG C, calcining 1.5h, obtains graphene/silicon dioxide compounded microbeads;
Five, 1., by graphene/silicon dioxide compounded microbeads impregnated in the hydrofluoric acid solution that mass percentage is 8%, dipping 2h; 2., again change mass percentage be the hydrofluoric acid solution of 8%, repeating step five 1. 4 times; 3., dry, namely obtain porous graphene microballon.
Fig. 1 is the scanning electron microscopic picture of the porous graphene microballon of preparation in embodiment 1, and magnification is 100; Fig. 2 is the scanning electron microscopic picture of the porous graphene microballon of preparation in embodiment 1, and magnification is 10000; The diameter of porous graphene microballon is between 15 ~ 50 microns as seen from the figure, and the sense of graphene layer fold is obvious, and pore size on graphene layer is homogeneous.
Fig. 3 is the porous graphene microballon of preparation and the X-ray diffractogram of graphene oxide in embodiment 1, and 1 is graphene oxide, and 2 is porous graphene microballon; As seen from the figure, disappear after calcining in figure in the sharp-pointed diffraction peak at 11 ° of places, represent that graphene oxide successfully reduces, in figure, the diffraction peak at 26 ° of places is more weak, and after reduction is described, the degree of crystallinity of Graphene declines, in agraphitic carbon state.
Fig. 4 is cyclic voltammetry curve, and 1 represents the cyclic voltammetry curve sweeping the porous graphene microballon prepared in embodiment 1 when speed is 5mV/s; 2 represent the cyclic voltammetry curve sweeping the porous graphene microballon prepared in embodiment 1 when speed is 10mV/s; 3 represent the cyclic voltammetry curve sweeping the porous graphene microballon prepared in embodiment 1 when speed is 20mV/s; 4 represent the cyclic voltammetry curve sweeping the porous graphene microballon prepared in embodiment 1 when speed is 50mV/s; 5 represent the cyclic voltammetry curve sweeping the porous graphene microballon prepared in embodiment 1 when speed is 100mV/s; As seen from the figure, along with the shape of the increase cyclic voltammetry curve of scanning speed does not change, having good stability of illustrative material; Porous graphene microballon presents electric double layer capacitance and fake capacitance performance, illustrates that pyrroles's nitrogen in polyvinylpyrrolidine and carbonyl have very large effect to capacitive property.
Claims (6)
1. utilize high-speed stirring technology to prepare a method for porous graphene microballon, it is characterized in that a kind of method utilizing high-speed stirring technology to prepare porous graphene microballon is carried out according to following steps:
One, polyvinylpyrrolidonepowder powder, graphene oxide dry powder and silicon dioxide microsphere dry powder are mixed, obtain powder mix, then powder mix is mixed with deionized water, obtain composite suspension liquid;
The mass ratio of described polyvinylpyrrolidonepowder powder and graphene oxide dry powder is 1:(0.2 ~ 0.3); The mass ratio of described polyvinylpyrrolidonepowder powder and silicon dioxide microsphere dry powder is 1:(0.5 ~ 1); Described powder mix and the mass ratio of deionized water are 1:(25 ~ 30);
Two, composite suspension liquid is joined fill in the polypropylene microwave oven box of dimethyl silicone oil, under temperature is 80 DEG C ~ 90 DEG C and stirring velocity is the condition of 400rpm ~ 600rpm, magnetic agitation 2h ~ 3h, then curing molding, last at room temperature standing precipitating 12h ~ 24h, obtains polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads;
Three, substep intensification heating method is adopted by polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads to be cured; Described substep intensification heating method is specifically carried out according to the following steps: polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads is heated 2h ~ 3h at temperature is 80 DEG C ~ 100 DEG C, 10h ~ 12h is heated again at temperature is 150 DEG C, finally at temperature is 280 DEG C, heat 1.5h ~ 2h, obtain the compounded microbeads of completion of cure;
Four, under condition of nitrogen gas, be under the condition of 750 DEG C ~ 850 DEG C by the compounded microbeads of completion of cure in temperature, calcining 1.5h ~ 2h, obtains graphene/silicon dioxide compounded microbeads;
Five, 1., by graphene/silicon dioxide compounded microbeads impregnated in the hydrofluoric acid solution that mass percent is 8%, dipping 2h ~ 3h; 2., again change mass percent be the hydrofluoric acid solution of 8%, repeating step five 1. 4 times ~ 5 times; 3., dry, namely obtain porous graphene microballon.
2. a kind of method utilizing high-speed stirring technology to prepare porous graphene microballon according to claim 1, is characterized in that the mass ratio of the polyvinylpyrrolidonepowder powder described in step one and graphene oxide dry powder is 1:(0.2 ~ 0.28).
3. a kind of method utilizing high-speed stirring technology to prepare porous graphene microballon according to claim 1, is characterized in that the mass ratio of the polyvinylpyrrolidonepowder powder described in step one and silicon dioxide microsphere dry powder is 1:(0.5 ~ 0.9).
4. a kind of method utilizing high-speed stirring technology to prepare porous graphene microballon according to claim 1, is characterized in that the mass ratio of the powder mix described in step one and deionized water is 1:(25 ~ 28).
5. a kind of method utilizing high-speed stirring technology to prepare porous graphene microballon according to claim 1, it is characterized in that the substep intensification heating method described in step 3 is specifically carried out according to the following steps: polyvinylpyrrolidone/graphene oxide/silicon-dioxide compounded microbeads is heated 2h ~ 2.8h at temperature is 80 DEG C ~ 100 DEG C, 10h ~ 11h is heated again at temperature is 150 DEG C, finally at temperature is 280 DEG C, heat 1.6h ~ 2h, obtain the compounded microbeads of completion of cure.
6. a kind of method utilizing high-speed stirring technology to prepare porous graphene microballon according to claim 1, to it is characterized in that in step 4 under condition of nitrogen gas, be under the condition of 750 DEG C ~ 800 DEG C in temperature by the compounded microbeads of completion of cure, calcining 1.6h ~ 2h, obtains graphene/silicon dioxide compounded microbeads.
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US20200039828A1 (en) * | 2018-08-02 | 2020-02-06 | Nanotek Instruments, Inc. | Environmentally benign production of graphene suspensions |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090068470A1 (en) * | 2007-09-12 | 2009-03-12 | Samsung Electronics Co., Ltd. | Graphene shell and process of preparing the same |
| CN102502609A (en) * | 2011-11-10 | 2012-06-20 | 东华大学 | Method for preparing graphene hollow microspheres for anisotropic conductive materials |
| CN102544459A (en) * | 2012-01-09 | 2012-07-04 | 上海交通大学 | Method for preparing graphene-coated carbon microsphere material by coating graphene oxide on carbon microsphere |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090068470A1 (en) * | 2007-09-12 | 2009-03-12 | Samsung Electronics Co., Ltd. | Graphene shell and process of preparing the same |
| CN102502609A (en) * | 2011-11-10 | 2012-06-20 | 东华大学 | Method for preparing graphene hollow microspheres for anisotropic conductive materials |
| CN102544459A (en) * | 2012-01-09 | 2012-07-04 | 上海交通大学 | Method for preparing graphene-coated carbon microsphere material by coating graphene oxide on carbon microsphere |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20200039828A1 (en) * | 2018-08-02 | 2020-02-06 | Nanotek Instruments, Inc. | Environmentally benign production of graphene suspensions |
| US11572280B2 (en) * | 2018-08-02 | 2023-02-07 | Global Graphene Group, Inc. | Environmentally benign production of graphene suspensions |
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