CN104016759A - Cane molasses fermentation waste liquid recycling method - Google Patents
Cane molasses fermentation waste liquid recycling method Download PDFInfo
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- CN104016759A CN104016759A CN201410189534.3A CN201410189534A CN104016759A CN 104016759 A CN104016759 A CN 104016759A CN 201410189534 A CN201410189534 A CN 201410189534A CN 104016759 A CN104016759 A CN 104016759A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/20—Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
Abstract
The invention discloses a cane molasses fermentation waste liquid recycling method. The cane molasses fermentation waste liquid recycling method comprises the following steps: (1) waste liquid pretreatment, to be specific, concentrating fermentation waste liquid, then using an alkaline hydrolysis agent or an acid hydrolysis agent for adjusting the pH value, adding a probiotics seed solution, feeding air, fermenting, heating and drying; (2) primary biological fermentation, to be specific, mixing and stirring sugarcane ash, filter mud, waste slurry and a basic culture medium so as to carry out primary biological fermentation; (3) secondary biological fermentation, to be specific, adding trace elements and the probiotics seed solution, uniformly stirring and then carrying out aeration fermentation; and (4) adjustment of the pH value and inorganic fertilizer dressing, to be specific, adding an alkaline hydrolysis agent or an acid hydrolysis agent, uniformly stirring, then adjusting the pH value, adding calcium-magnesium fertilizer and potash fertilizer, uniformly stirring and drying, thus obtaining active chemical combined organic fertilizer. The cane molasses fermentation waste liquid recycling method has the advantages that a modern biological high technology is used for inoculating biological bacteria, the high-efficiency compound microorganism leavening agent is produced through multistage fermentation culture, secondary pollution is avoided in a treatment process, and the fertilizer obtained by treating the ash, the filter mud and the waste slurry is close to natural organic fertilizer.
Description
Technical field
The invention belongs to trade waste and recycle field, relate to a kind of cane molasses fermented waste fluid recoverying and utilizing method.
Background technology
In cane sugar manufacture process, sugarcane juice is by clarification, and the residue after being filtered by pressure filter or vacuum suction filter is filter mud.Filter mud contains Caulis Sacchari sinensis fiber, sucrose, and with the colloid that condenses of cerosin, protein, calcium phosphate, also carry the sand mud bringing with raw material sugarcane stem secretly, and these compositions are many from sugarcane itself, and calcareous thing majority adds while being cane juice clarification processing; Filter mud also contains the trace elements such as a small amount of iron, the heart.Filter mud generally accounts for the 3%-4% of pressing quantity thereof, sugar refinery of day processing 2000t, and a squeezing just can produce filter mud 10,000 t left and right season.What China sugar enterprise generally adopted is sulfurous method, and the filter mud of sulfurous method sugaring, has higher utility value, and organic abundant, fertilizer efficiency is high, by the processing of becoming thoroughly decomposed, is good organic fertilizer resource.The independent as fertilizer sources of filter mud, should carry out after stack retting becomes thoroughly decomposed just using, and adds a cover film or covers with earth, to reduce nutrient loss in stack retting process.Filter mud is generally made base manure, also can topdress, and amount of application 15t/hm
2left and right, discharge filter mud sugarcane answer compounding application lime 750kg/hm2 to neutralize its acidity.
Alcohol waste mash (fermented waste fluid) is by product after the alcohol produced from molasses after the utilization sugaring of sugar refinery, is generally 15% left and right of raw material sugarcane amount.Alcohol waste mash has the required nutrient of a lot of sugarcane productions, comprising the nutrient adding in the nitrogen in molasses, phosphorus, potassium and fermenting process, all be dissolved in alcohol waste mash, according to one's analysis, alcohol waste mash is approximately containing full nitrogen 0.05%, full phosphorus 0.01%, full potassium 0.1%, research shows, use alcohol waste mash, more than average volume increase sugarcane can reach 15t/hm2, alcohol waste mash nutrient density is low, in liquid mode, irrigates and uses, while therefore using, should note irrigating amount of application, generally with soil moisture content, approach saturated being advisable, general amount of application is at 450-600t/hm
2left and right.But long-term application alcohol waste mash can cause Sucrose to decline, according to the experience of the advanced countries such as Brazil, when using alcohol waste mash, should be at the supporting sugarcane sugar enriching agent that sprays of sugarcane ripening stage.
Although the treatment process of molasses alcohol waste mash has evaporation concentration method, settling process etc. at present, and " rushing buck " technology of carrying out in recent years, also be a kind of practical approach of processing alcohol mash, useless mash after processing also rests on traditional retting method at present for the preparation of the research of solid fertilizer, with low content of technology, the fertilizer effect of increasing production, the environmental protection degree that prepare are not high.The present invention is directed to the deficiencies in the prior art, by treated dense useless mash, combine with modern biological high-technology, inoculation biological bacteria, through multistage fermentation culture, just can produce efficient compound microbial culture starter; Add the lime-ash that produces in sugaring, filter mud etc. as matrix, just can go out fixedly high-performance bio bacterial manure by production development.
Summary of the invention
Of the present inventionly provide a kind of cane molasses fermented waste fluid recoverying and utilizing method; by in conjunction with modern biofermentation technique; the starting material such as pretreated useless mash; and sugarcane lime-ash, filter mud; under the effect of additive, pass through the technology such as multi-stage biological fermentation culture, wet heap retting; recycle waste and prepare high-performance solid fertilizer, solve the recycling and the effect that realizes environment protection of waste.
To achieve these goals, the present invention has adopted following technical scheme:
A cane molasses fermented waste fluid recoverying and utilizing method, the method comprises the following steps:
1) waste liquid pre-treatment: utilize heating evaporation that fermented waste fluid is concentrated into organic content for 40-75%, obtaining concentrated solution carries out cooling, in concentrated solution inflow equalizing tank, utilize alkaline hydrolysis agent or acidolysis agent adjusting pH to 5-6.5, access 10～20% probiotic bacterium seed liquor, after aerobic fermentation 20～48h, stop fermentation, fermented liquid heating, drying, to water content≤30%, obtains pretreated waste liquid slurry.
2) one-level biological fermentation: get 15～30 parts of sugarcane lime-ash, 50～70 parts of filter muds, 10～30 parts of steps 1) waste pulp preparing, 2～5 parts of basic mediums, mix and blend is placed in one-level biological fermentation pond aerated fermentation 10～15 days, between yeast phase, stir 1～2 time, obtain one grade fermemtation fertilizer;
3) one grade fermemtation fertilizer two stage biological fermentation: get step 2) obtaining, adds 2～5 parts of trace elements, 5～15 parts of probiotic bacterium seed liquor, and after stirring, aerated fermentation is 7～10 days, obtains active organic fertilizer;
4) pH adjusts and inorganic fertilizer condiment: in step 3) active organic fertilizer in add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling dissolve to be measured pH and is stopped adding alkaline hydrolysis agent or acidolysis agent between 5.5～7 time, add again 5～15% ca and mg fertilizers, 5～15% potash fertilizer, dry under 40`60 ℃ of ventilation condition after stirring, obtain the active ingredient fertilizer that water content is≤10%;
As further restriction of the present invention, described alkaline hydrolysis medicament is any or their composition in lime, liquefied ammonia, volatile salt, and lime is pulvis, and CaCO in lime
3content>=92%; Described acidolysis medicament is any or their composition in 60-85% sulfuric acid, 60～95% hydrochloric acid, 70～95% phosphoric acid.
As further restriction of the present invention, described heating evaporation is 50-85 ℃ of heating.
As further restriction of the present invention, described basic medium composition comprises 0.5-1% peptone, 0.5-2% sodium-chlor, 0.5-2% sodium phosphate.
As further restriction of the present invention, described probiotic bacterium comprises any or their arbitrary combination in root nodule bacterium, vinelandii, phosphorus bacteria and potassium bacterium; Described probiotic bacterium seed liquor is the fermented liquid that probiotic bacterium is fermented and obtains after 16～24h in basic medium.A large amount of interventions of highly active profitable strain, using flora in the soil after this fertilizer can be up to 500,000,000/gram, formed rapidly and enduringly beneficial microorganism population advantage, the Growth and reproduction that has suppressed harmful germ, fundamentally change the micro-ecological environment of soil, and formed the natural cover for defense of the harmful germ of a blockage.
As further restriction of the present invention, described trace element comprises any or their composition in iron, boron, arsenic, manganese, zinc, copper, cobalt, molybdenum, selenium, magnesium.Adding of the number Ten microelements such as boron, zinc, copper, provide crop growth required various trace elements, fertilizer is balanced, and short root strong sprout, activating soil, increasing of quality and production are had to vital role, and use the crop of this composite organic-inorganic fertilizer, crop product special flavour is good.
Know-why of the present invention is: owing to making it contain large amount of organic (composition such as sugar, crude protein, colloid) in cane molasses alcoholic fermentation waste liquor, can not directly by farm crop, be absorbed, need to make by chemistry or biological respinse the reactions such as the degraded of organism generation soda acid, charing, condensation, dehydration, owing to adopting in chemical reaction handling, need to digest a large amount of acid-base reagents, and chemical treating process produces the bad smells such as SO2, foul smell, environment is caused to secondary pollution, have many weak points.The present invention, by treated dense useless mash, combines with modern biological high-technology, inoculation biological bacteria, through multistage fermentation culture, just can produce efficient compound microbial culture starter, in treating processes, there is no secondary pollution, fertilizer after processing approaches natural organic fertilizer, and fertility is strong and friendly to soil; Add the lime-ash that produces in sugaring, filter mud etc. as matrix, just can go out fixedly high-performance bio bacterial manure by production development.
For making the present invention further fully open, the active ingredient fertilizer that drying treatment of the present invention obtains, utilize existing conventional urea spray granulation, prepare organic-inorganic composite bio-fertilizers such as can be used for rice field, sugarcane, corn, gourd, fruit and vegetable, use the molasses fermented waste liquid after this treatment technology.
Advantage of the present invention:
1. the present invention is by treated dense useless mash, combine with modern biological high-technology, inoculation biological bacteria, through multistage fermentation culture, just can produce efficient compound microbial culture starter, in treating processes, there is no secondary pollution, the fertilizer after processing approaches natural organic fertilizer, and fertility is strong and friendly to soil; Add the lime-ash that produces in sugaring, filter mud etc. as matrix, just can go out fixedly high-performance bio bacterial manure by production development.
2. the sugar in the molasses concentrated solution after the technology of the present invention processing, crude protein, colloid etc. can not be reduced to for the organic content that plant directly absorbs below 5%, after multistage fermentation, the charing of organic process, degraded, condensation change into small molecules fertilizer, can be farm crop and directly absorb.
3. the active ingredient fertilizer that drying treatment of the present invention obtains, utilize urea spray granulation, prepare organic-inorganic composite bio-fertilizer particles such as can be used for rice field, sugarcane, corn, gourd, fruit and vegetable, use the particle that the molasses concentrated solution after this treatment technology is made, sugarcane can be increased production 10-20%, and paddy rice can be increased production 5-15%, gourd, fruit and vegetable can increase production 5-20%, especially the crop such as sugarcane, Ipomoea batatas local flavor is splendid, and sugar degree is also improved, and Sugar Content in Sugarcane improves 3～7%.
Accompanying drawing explanation
Fig. 1. recoverying and utilizing method schematic flow sheet of the present invention.
Embodiment
Below in conjunction with drawings and Examples, the present invention is further described, but protection scope of the present invention is not limited to these embodiment.
Embodiment 1:
The fermented waste fluid that the present embodiment is used, lime-ash, filter mud etc. come from the large-scale sugar enterprise in Guangxi, Alcohol Production enterprise, and the basic medium formula of using in embodiment is: 0.5% peptone, 1.5% sodium-chlor, 1.0% sodium phosphate; Probiotic bacterium comprises that root nodule bacterium, the two concentration of vinelandii approximate 1:1 combination; Described probiotic bacterium seed liquor is the fermented liquid that probiotic bacterium is fermented and obtains after 18h in basic medium; Trace element comprises that four kinds of quality in boron, arsenic, zinc, molybdenum, selenium is than the composition that approximates 1:1:1:1, before trace element adds, is dissolved in the 1L aqueous solution, and each micro-content is probably between 0.5～1g/L.
1) waste liquid pre-treatment: utilizing heating evaporation that fermented waste fluid is concentrated into organic content is 60%, obtaining concentrated solution carries out cooling, concentrated solution flows in equalizing tank and utilizes lime powder to regulate pH to 6.0, access 10% probiotic bacterium seed liquor, after aerobic fermentation 44h, stop fermentation, fermented liquid heating, drying, to water content 25-30%, obtains pretreated waste liquid slurry.
2) one-level biological fermentation: get 25 parts of sugarcane lime-ash, 60 parts of filter muds, 10 parts of steps 1) waste pulp preparing, 5 parts of basic mediums, mix and blend is placed in one-level biological fermentation pond aerated fermentation 15 days, between yeast phase, stir 2 times, obtain one grade fermemtation fertilizer.
3) one grade fermemtation fertilizer two stage biological fermentation: get step 2) obtaining, adds 3 parts of trace elements, 15 parts of probiotic bacterium seed liquor, and after stirring, aerated fermentation is 7 days, obtains active organic fertilizer.
4) pH adjusts and inorganic fertilizer condiment: in step 3) active organic fertilizer in add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling dissolve to be measured pH and is stopped adding sulfuric acid between 5.5 time, add again 5% ca and mg fertilizer, 10% potash fertilizer, dry under 40 ℃ of ventilation conditions after stirring, obtaining water content is the active ingredient fertilizer of 8-9%.
Embodiment 2:
The fermented waste fluid that the present embodiment is used, lime-ash, filter mud etc. come from the large-scale sugar enterprise in Guangxi, Alcohol Production enterprise, and the basic medium formula of using in embodiment is: 1% peptone, 0.5% sodium-chlor, 2% sodium phosphate; Probiotic bacterium comprises that root nodule bacterium, vinelandii, phosphorus bacteria, four kinds of bacterial concentrations of potassium bacterium approximate 1:1:1:1 combination; Described probiotic bacterium seed liquor is the fermented liquid that probiotic bacterium is fermented and obtains after 16h in basic medium; Trace element comprises that six kinds of mass ratioes in iron, manganese, zinc, molybdenum, selenium, magnesium approximate 1:1:1:1:1 composition, before trace element adds, is dissolved in the 1L aqueous solution, and each micro-content is probably between 2～3g/L.
1) waste liquid pre-treatment: utilizing heating evaporation that fermented waste fluid is concentrated into organic content is 65%, obtaining concentrated solution carries out cooling, concentrated solution flows in equalizing tank and utilizes volatile salt to regulate pH to 5, access 15% probiotic bacterium seed liquor, after aerobic fermentation 48h, stop fermentation, fermented liquid heating, drying, to water content 25-30%, obtains pretreated waste liquid slurry.
2) one-level biological fermentation: get 20 parts of sugarcane lime-ash, 50 parts of filter muds, 25 parts of steps 1) waste pulp preparing, 5 parts of basic mediums, mix and blend is placed in one-level biological fermentation pond aerated fermentation 10 days, between yeast phase, stir 1～2 time, obtain one grade fermemtation fertilizer.
3) one grade fermemtation fertilizer two stage biological fermentation: get step 2) obtaining, adds 5 parts of trace elements, 10 parts of probiotic bacterium seed liquor, and after stirring, aerated fermentation is 9 days, obtains active organic fertilizer.
4) pH adjusts and inorganic fertilizer condiment: in step 3) active organic fertilizer in add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling dissolve to be measured pH and is stopped adding hydrochloric acid between 6 time, add again 15% ca and mg fertilizer, 10% potash fertilizer, dry under 50 ℃ of ventilation conditions after stirring, obtaining water content is the active ingredient fertilizer of 7-8%.
Embodiment 3:
The fermented waste fluid that the present embodiment is used, lime-ash, filter mud etc. come from the large-scale sugar enterprise in Guangxi, Alcohol Production enterprise, and the basic medium formula of using in embodiment is: 1% peptone, 2% sodium-chlor, 0.5% sodium phosphate; Probiotic bacterium comprises vinelandii; Described probiotic bacterium seed liquor is the fermented liquid that probiotic bacterium is fermented and obtains after 24h in basic medium; Trace element comprises that ten kinds, iron, boron, arsenic, manganese, zinc, copper, cobalt, molybdenum, selenium, magnesium etc. are according to 1:1:1:1:1:1:1:1:1:1 composition, before trace element adds, is dissolved in the 1L aqueous solution, and each micro-content is probably between 0.5～1g/L.
1) waste liquid pre-treatment: utilizing heating evaporation that fermented waste fluid is concentrated into organic content is 70%, obtaining concentrated solution carries out cooling, concentrated solution flows in equalizing tank and utilizes liquefied ammonia to regulate pH to 6.5, access 10% probiotic bacterium seed liquor, after aerobic fermentation 30h, stop fermentation, fermented liquid heating, drying, to water content 15-20%, obtains pretreated waste liquid slurry.
2) one-level biological fermentation: get 30 parts of sugarcane lime-ash, 58 parts of filter muds, 10 parts of steps 1) waste pulp preparing, 2 parts of basic mediums, mix and blend is placed in one-level biological fermentation pond aerated fermentation 12 days, between yeast phase, stir 1～2 time, obtain one grade fermemtation fertilizer.
3) one grade fermemtation fertilizer two stage biological fermentation: get step 2) obtaining, adds 2 parts of trace elements, 15 parts of probiotic bacterium seed liquor, and after stirring, aerated fermentation is 10 days, obtains active organic fertilizer.
4) pH adjusts and inorganic fertilizer condiment: in step 3) active organic fertilizer in add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling dissolve to be measured pH and is stopped adding phosphoric acid between 5.5 time, add again 7% ca and mg fertilizer, 8% potash fertilizer, dry under 60 ℃ of ventilation conditions after stirring, obtaining water content is the active ingredient fertilizer of 8-10%.
Embodiment 4:
The fermented waste fluid that the present embodiment is used, lime-ash, filter mud etc. come from the large-scale sugar enterprise in Guangxi, Alcohol Production enterprise, and the basic medium formula of using in embodiment is: 0.5% peptone, 1% sodium-chlor, 1% sodium phosphate; Probiotic bacterium comprises root nodule bacterium; Described probiotic bacterium seed liquor is the fermented liquid that probiotic bacterium is fermented and obtains after 20h in basic medium; Trace element comprises that ten kinds, arsenic, manganese, zinc, copper, cobalt, molybdenum, selenium, magnesium etc. are according to 1:1:1:1:1:1:1:1 composition, before trace element adds, is dissolved in the 1L aqueous solution, and each micro-content is probably between 1.5～2g/L.
1) waste liquid pre-treatment: utilizing heating evaporation that fermented waste fluid is concentrated into organic content is 40%, obtaining concentrated solution carries out cooling, concentrated solution flows in equalizing tank and utilizes liquefied ammonia and volatile salt pH to 5.5, access 20% probiotic bacterium seed liquor, after aerobic fermentation 48h, stop fermentation, fermented liquid heating, drying, to water content 15-20%, obtains pretreated waste liquid slurry.
2) one-level biological fermentation: get 20 parts of sugarcane lime-ash, 65 parts of filter muds, 13 parts of steps 1) waste pulp preparing, 2 parts of basic mediums, mix and blend is placed in one-level biological fermentation pond aerated fermentation 15 days, between yeast phase, stir 2 times, obtain one grade fermemtation fertilizer.
3) one grade fermemtation fertilizer two stage biological fermentation: get step 2) obtaining, adds 4 parts of trace elements, 10 parts of probiotic bacterium seed liquor, and after stirring, aerated fermentation is 8 days, obtains active organic fertilizer.
4) pH adjusts and inorganic fertilizer condiment: in step 3) active organic fertilizer in add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling dissolve to be measured pH and is stopped adding phosphoric acid between 7 time, add again 10% ca and mg fertilizer, 15% potash fertilizer, dry under 45 ℃ of ventilation conditions after stirring, obtaining water content is the active ingredient fertilizer of 9-10%.
Embodiment 5:
The fermented waste fluid that the present embodiment is used, lime-ash, filter mud etc. come from the large-scale sugar enterprise in Guangxi, Alcohol Production enterprise, and the basic medium formula of using in embodiment is: 1% peptone, 2% sodium-chlor, 0.5% sodium phosphate; Probiotic bacterium comprises that phosphorus bacteria, two kinds of concentration ratio of potassium bacterium approximate 1:1 combination; Described probiotic bacterium seed liquor is the fermented liquid that probiotic bacterium is fermented and obtains after 18h in basic medium; Trace element comprises that six kinds, iron, zinc, copper, molybdenum, selenium, magnesium etc. are according to 1:1:1:1:1:1 composition, before trace element adds, is dissolved in the 1L aqueous solution, and each micro-content is probably between 2.0～2.5g/L.
1) waste liquid pre-treatment: utilizing heating evaporation that fermented waste fluid is concentrated into organic content is 50%, obtaining concentrated solution carries out cooling, concentrated solution flows in equalizing tank and utilizes lime powder to regulate pH to 6.0, access 15% probiotic bacterium seed liquor, after aerobic fermentation 24h, stop fermentation, fermented liquid heating, drying, to water content 18-20%, obtains pretreated waste liquid slurry.
2) one-level biological fermentation: get 15 parts of sugarcane lime-ash, 70 parts of filter muds, 13 parts of steps 1) waste pulp preparing, 2 parts of basic mediums, mix and blend is placed in one-level biological fermentation pond aerated fermentation 10～15 days, between yeast phase, stir 1～2 time, obtain one grade fermemtation fertilizer.
3) one grade fermemtation fertilizer two stage biological fermentation: get step 2) obtaining, adds 3 parts of trace elements, 12 parts of probiotic bacterium seed liquor, and after stirring, aerated fermentation is 7 days, obtains active organic fertilizer.
4) pH adjusts and inorganic fertilizer condiment: in step 3) active organic fertilizer in add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling dissolve to be measured pH and is stopped adding hydrochloric acid between 6.5 time, add again 5% ca and mg fertilizer, 12% potash fertilizer, dry under 55 ℃ of ventilation conditions after stirring, obtaining water content is the active ingredient fertilizer of 9-10%.
Embodiment 6:
The fermented waste fluid that the present embodiment is used, lime-ash, filter mud etc. come from the large-scale sugar enterprise in Guangxi, Alcohol Production enterprise, and the basic medium formula of using in embodiment is: 0.5% peptone, 2% sodium-chlor, 0.5% sodium phosphate; Probiotic bacterium comprises that root nodule bacterium, phosphorus bacteria, three kinds of concentration ratio of potassium bacterium approximate 1:1:1 combination; Described probiotic bacterium seed liquor is the fermented liquid that probiotic bacterium is fermented and obtains after 20h in basic medium; Trace element comprises that two kinds of boron, cobalts etc. are according to 1:1 composition, before trace element adds, is dissolved in the 1L aqueous solution, and each micro-content is probably between 0.5～1.0g/L.
1) waste liquid pre-treatment: utilizing heating evaporation that fermented waste fluid is concentrated into organic content is 75%, obtaining concentrated solution carries out cooling, concentrated solution flows in equalizing tank and utilizes liquefied ammonia to regulate pH to 6.5, access 20% probiotic bacterium seed liquor, after aerobic fermentation 20h, stop fermentation, fermented liquid heating, drying, to water content 15-18%, obtains pretreated waste liquid slurry.
2) one-level biological fermentation: get 15 parts of sugarcane lime-ash, 50 parts of filter muds, 30 parts of steps 1) waste pulp preparing, 5 parts of basic mediums, mix and blend is placed in one-level biological fermentation pond aerated fermentation 12 days, between yeast phase, stir 2 times, obtain one grade fermemtation fertilizer.
3) one grade fermemtation fertilizer two stage biological fermentation: get step 2) obtaining, adds 5 parts of trace elements, 15 parts of probiotic bacterium seed liquor, and after stirring, aerated fermentation is 9 days, obtains active organic fertilizer.
4) pH adjusts and inorganic fertilizer condiment: in step 3) active organic fertilizer in add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling dissolve to be measured pH and is stopped adding sulfuric acid between 6.0 time, add again 15% ca and mg fertilizer, 5% potash fertilizer, dry under 60 ℃ of ventilation conditions after stirring, obtaining water content is the active ingredient fertilizer of 5-6%.
Embodiment 7 application examples:
Embodiment 1-6 is processed to the active ingredient fertilizer obtaining, utilize existing conventional urea spray granulation, prepare organic-inorganic composite bio-fertilizers such as can be used for rice field, sugarcane, corn, gourd, fruit and vegetable, use the particle that the molasses concentrated solution after this treatment technology is made, sugarcane can be increased production 10-20%, and paddy rice can be increased production 5-15%, gourd, fruit and vegetable can increase production 5-20%, especially the crop such as sugarcane, Ipomoea batatas local flavor is splendid, and sugar degree is also improved, and Sugar Content in Sugarcane improves 3～7%.
Claims (6)
1. a cane molasses fermented waste fluid recoverying and utilizing method, is characterized in that, the method comprises the following steps:
1) waste liquid pre-treatment: utilize heating evaporation that fermented waste fluid is concentrated into organic content for 40-75%, obtaining concentrated solution carries out cooling, in concentrated solution inflow equalizing tank, utilize alkaline hydrolysis agent or acidolysis agent adjusting pH to 5-6.5, access 10～20% probiotic bacterium seed liquor, after aerobic fermentation 20～48h, stop fermentation, fermented liquid heating, drying, to water content≤30%, obtains pretreated waste liquid slurry;
2) one-level biological fermentation: get 15～30 parts of sugarcane lime-ash, 50～70 parts of filter muds, 10～30 parts of steps 1) waste pulp preparing, 2～5 parts of basic mediums, mix and blend is placed in one-level biological fermentation pond aerated fermentation 10～15 days, between yeast phase, stir 1～2 time, obtain one grade fermemtation fertilizer;
3) one grade fermemtation fertilizer two stage biological fermentation: get step 2) obtaining, adds 2～5 parts of trace elements, 5～15 parts of probiotic bacterium seed liquor, and after stirring, aerated fermentation is 7～10 days, obtains active organic fertilizer;
4) pH adjusts and inorganic fertilizer condiment: in step 3) active organic fertilizer in add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling dissolve to be measured pH and is stopped adding alkaline hydrolysis agent or acidolysis agent between 5.5～7 time, add again 5～15% ca and mg fertilizers, 5～15% potash fertilizer, dry under 40`60 ℃ of ventilation condition after stirring, obtain the active ingredient fertilizer that water content is≤10%.
2. a kind of cane molasses fermented waste fluid recoverying and utilizing method according to claim 1, is characterized in that: described alkaline hydrolysis medicament is any or their composition in lime, liquefied ammonia, volatile salt, and lime is pulvis, and CaCO in lime
3content>=92%; Described acidolysis medicament is any or their composition in 60-85% sulfuric acid, 60～95% hydrochloric acid, 70～95% phosphoric acid.
3. a kind of cane molasses fermented waste fluid recoverying and utilizing method according to claim 1, is characterized in that: described heating evaporation is 50-85 ℃ of heating.
4. a kind of cane molasses fermented waste fluid recoverying and utilizing method according to claim 1, is characterized in that: described basic medium composition comprises 0.5-1% peptone, 0.5-2% sodium-chlor, 0.5-2% sodium phosphate.
5. a kind of cane molasses fermented waste fluid recoverying and utilizing method according to claim 1, is characterized in that: described probiotic bacterium comprises any or their arbitrary combination in root nodule bacterium, vinelandii, phosphorus bacteria and potassium bacterium; Described probiotic bacterium seed liquor is the fermented liquid that probiotic bacterium is fermented and obtains after 16～24h in basic medium.
6. a kind of cane molasses fermented waste fluid recoverying and utilizing method according to claim 1, is characterized in that: described trace element comprises any or their composition in iron, boron, arsenic, manganese, zinc, copper, cobalt, molybdenum, selenium, magnesium.
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| CN108863457A (en) * | 2018-08-09 | 2018-11-23 | 芜湖市三山区绿色食品产业协会 | Natural feather Organic sludge manure and preparation method thereof |
| CN109553475A (en) * | 2018-12-28 | 2019-04-02 | 云南云叶化肥股份有限公司 | It is a kind of to give up mash as the preparation method and application of the fertilizer of raw material using cane molasses |
| CN109678614A (en) * | 2019-02-28 | 2019-04-26 | 广西地源之本生物科技有限公司 | A kind of biology-Organic-inorganic composite nutrient solution and preparation method thereof |
| CN110115219A (en) * | 2019-05-23 | 2019-08-13 | 广西南亚热带农业科学研究所 | A kind of sugarcane water-fertilizer integral fertilizing method |
| CN111393207A (en) * | 2020-04-20 | 2020-07-10 | 云南省农业科学院甘蔗研究所 | Application method of cane molasses alcohol waste liquid used as sugarcane area fertilizer |
| CN113135568A (en) * | 2021-05-27 | 2021-07-20 | 吉林大学 | Nitrogen-doped porous carbon material and preparation method and application thereof |
| CN113475333A (en) * | 2021-07-30 | 2021-10-08 | 广西壮族自治区农业科学院 | Method for planting rice by using sugarcane ash and organic fertilizer |
| CN115707677A (en) * | 2022-08-12 | 2023-02-21 | 新疆大滋然生物科技有限公司 | Method for producing liquid water-soluble fertilizer by using sugar-making waste honey |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1062892A (en) * | 1990-12-30 | 1992-07-22 | 顺德县食品公司均安有机肥料厂 | The method of producing organic composition fertilizer from fermented waste liquid of sugar |
| CN1171384A (en) * | 1997-05-20 | 1998-01-28 | 陈立平 | Process for producing active organic compound fertilizer with waste liquid of molasses alcohol |
| CN101108779A (en) * | 2007-06-20 | 2008-01-23 | 福建省诏安县绿洲生化有限公司 | Method of manufacturing organic, inorganic compound fertilizer with molasses zymolysis waste liquor and lime sludge |
| US7662206B2 (en) * | 2005-09-15 | 2010-02-16 | Vitag Corporation | Organic containing sludge to fertilizer alkaline conversion process |
-
2014
- 2014-05-07 CN CN201410189534.3A patent/CN104016759A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1062892A (en) * | 1990-12-30 | 1992-07-22 | 顺德县食品公司均安有机肥料厂 | The method of producing organic composition fertilizer from fermented waste liquid of sugar |
| CN1171384A (en) * | 1997-05-20 | 1998-01-28 | 陈立平 | Process for producing active organic compound fertilizer with waste liquid of molasses alcohol |
| US7662206B2 (en) * | 2005-09-15 | 2010-02-16 | Vitag Corporation | Organic containing sludge to fertilizer alkaline conversion process |
| CN101108779A (en) * | 2007-06-20 | 2008-01-23 | 福建省诏安县绿洲生化有限公司 | Method of manufacturing organic, inorganic compound fertilizer with molasses zymolysis waste liquor and lime sludge |
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| CN106518397A (en) * | 2016-11-14 | 2017-03-22 | 广西新天德能源有限公司 | Method for preparing organic/inorganic mixed activated compound fertilizer from ethyl alcohol filter mud |
| CN108863457A (en) * | 2018-08-09 | 2018-11-23 | 芜湖市三山区绿色食品产业协会 | Natural feather Organic sludge manure and preparation method thereof |
| CN109553475A (en) * | 2018-12-28 | 2019-04-02 | 云南云叶化肥股份有限公司 | It is a kind of to give up mash as the preparation method and application of the fertilizer of raw material using cane molasses |
| CN109678614A (en) * | 2019-02-28 | 2019-04-26 | 广西地源之本生物科技有限公司 | A kind of biology-Organic-inorganic composite nutrient solution and preparation method thereof |
| CN109678614B (en) * | 2019-02-28 | 2021-04-27 | 广西地源之本生物科技有限公司 | Biological-organic-inorganic composite nutrient solution and preparation method thereof |
| CN110115219A (en) * | 2019-05-23 | 2019-08-13 | 广西南亚热带农业科学研究所 | A kind of sugarcane water-fertilizer integral fertilizing method |
| CN111393207A (en) * | 2020-04-20 | 2020-07-10 | 云南省农业科学院甘蔗研究所 | Application method of cane molasses alcohol waste liquid used as sugarcane area fertilizer |
| CN113135568A (en) * | 2021-05-27 | 2021-07-20 | 吉林大学 | Nitrogen-doped porous carbon material and preparation method and application thereof |
| CN113475333A (en) * | 2021-07-30 | 2021-10-08 | 广西壮族自治区农业科学院 | Method for planting rice by using sugarcane ash and organic fertilizer |
| CN113475333B (en) * | 2021-07-30 | 2022-05-31 | 广西壮族自治区农业科学院 | Method for planting rice by using sugarcane ash and organic fertilizer |
| CN115707677A (en) * | 2022-08-12 | 2023-02-21 | 新疆大滋然生物科技有限公司 | Method for producing liquid water-soluble fertilizer by using sugar-making waste honey |
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