CN103980025A - Comprehensive recycling method for high-permeability fermentation waste liquid and sludge - Google Patents
Comprehensive recycling method for high-permeability fermentation waste liquid and sludge Download PDFInfo
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- CN103980025A CN103980025A CN201410115700.5A CN201410115700A CN103980025A CN 103980025 A CN103980025 A CN 103980025A CN 201410115700 A CN201410115700 A CN 201410115700A CN 103980025 A CN103980025 A CN 103980025A
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Abstract
The invention discloses a comprehensive recycling method for high-permeability fermentation waste liquid and sludge. The method comprises the following steps: 1) concentrating, specifically concentrating a molasses fermentation waste liquid, and using part of the concentrate to perform alkaline hydrolysis dehydration, and using part of the concentrate to perform acidolysis hydration; 2) performing alkaline hydrolysis hydration, specifically adding an alkaline hydrolysis reagent into the concentrate, stirring with a low speed, and then adding calcium magnesium phosphate and potash fertilizer and stirring uniformly, so as to obtain an alkaline hydrolysis mixing material; 3) performing acidolysis hydration, specifically adding an acidolysis reagent into the concentrate, and stirring with a low speed, so as to obtain an acidolysis mixing material; and 4) preparing a neutralization mixing material, specifically mixing the acidolysis mixing material with the alkaline hydrolysis mixing material to perform acid-alkali neutralization, and then performing drying, multi-stage biological fermentation retting and pH adjusting, so as to obtain an active combined organic fertilizer. According to the method, acidification and alkalization are combined, modern fermentation biological technology is merged, parts of the molasses fermentation waste liquid concentrate are respectively subjected to acid humification and alkali humification, and an additionally added neutralization reagent for acid humification or for alkali humification is omitted, so that the molasses fermentation waste liquid is utilized in two ways and gives play to dual effect.
Description
Technical field
The invention belongs to trade waste and recycle field, relate to a kind of high comprehensive reutilization method that oozes fermented waste fluid and mud.
Background technology
Molasses are syrup remaining in sugar refining technology process, and molasses fermented processing reality is also the further biochemical degradation of organism, conversion process.Domestic during taking molasses as raw material production alcohol, about every production 1t alcohol consumption 4t molasses, approximately discharge the waste liquid of 14t, and the pH value of waste liquid is generally 3.0-3.5, mainly contains carbohydrate (polyose) and alcohols.The pH value of molasses yeast wastewater is generally 4.0-5.0, mainly containing biodegradable larger molecular organicses such as remaining sugar, nutritive salt, part yeast cell and pectin substances.In molasses msg mother liquor, except containing a small amount of L-glutamic acid, also there is thalline, residual sugar, high ammonium state nitrogen, pigment, colloidalmaterial and other fermentation byproduct.Current molasses fermented liquid organic waste water adopts agricultural resource technology route, solves waste water pollution problem, and promotes the Sustainable development of waste ecological circulation and industrial or agricultural.Papermaking and molasses fermented industrial effluent contain a large amount of organic matters and various nutrient elements, evaluate from Plant Nutrition angle, and these two kinds of waste liquids all belong to Organic Fertilizer Resources, but can not directly use in a large number as organic fertilizer.If amount of application is too much, may cause plant-growth be suppressed, injure, even dead.Its major cause is that molasses fermented waste liquid is high concentrated organic wastewater, and water-soluble C content is high, and biological activity is strong, contain more low molecule organic matter, as residual sugar, organic acid etc., the particularly sugar crop of easily fermenting in soil, generate heat, burn, and make the further acidifying of soil.Therefore molasses fermented trade waste (waste liquid and mud) agricultural before, generally all need to carry out desugar and further humify, stabilization, the i.e. harmless treatment of molasses fermented waste liquid.
The waste that fermentation produces also comprises lime-ash and mud, and especially cassava grain stillage mud is containing the moisture of 30% left and right of having an appointment after fermentation, and such material can not be pulverized and can not carry out granulation, needs further processing treatment.And in cassava alcohol production process, produce a large amount of high concentrated organic wastewaters, these waste water produce biogas through anaerobically fermenting, are settled out a large amount of mud, and the efficient economy recovery and utilization technology of mud has become a problem in the urgent need to address.
Due to not fully degraded of most of organism in high concentrated organic waste liquid, be spray dried to after dry powder easily the moisture absorption, rotten and viscosity is large, limited recycling.For the stabilization treatment of sugary organic liquid, except conventional anaerobe digestion degraded, over the past two years, sugar and yeast separation recovery technology, carrier adsorption solid aerobic compost new technology, basic material (lime) dehydration stabilization technology etc. have also been developed and have been particularly suitable for quick humify and the batch production utilization of organic liquid waste.
Utilize sulfuric acid stabilization waste liquid, its principle is that sulfuric acid and gas chromatography react, and comprises that degraded and Transglycosylation occur starch, generate oligose; The hydrolysis of Hemicellulose Polysaccharide class; Proteolysis becomes polypeptide, amino acid; The dehydration of two pools and monose generates aldehyde material, and under concentrated acid and heating condition, polysaccharide stabilizes processing is the dynamic process that organism is progressively degraded, transformed, and degree of humification and acid concentration, temperature, pressure, time are relevant., mainly there is organic alkaline hydrolysis, dehydration and part condensation reaction in basic material stabilization treatment organic liquid waste, though cost is low, denitrogenation phenomenon easily occurs, and causes nutrient loss and stink large, and the acid treatment of liquid phase charing strength ratio want a little less than.
Although at present acidity or alkalescence all can play humification, all there is meta-acid or meta-alkali after humify in the two, all will separately add alkali or another acid adding neutralizes, and just can make the product that conforms with composite fertilizer's quality standard.So the present invention proposes to adopt the method for the two combination, molasses fermented waste liquid concentrated solution is carried out respectively to acid, alkali humify, then the two relaxes neutralization and makes fermented waste fluid after humify can be used for preparing multiple organic/inorganic to mix composite fertilizer, this organic/inorganic mixes composite fertilizer and utilizes modern microbial technique, inoculation biological bacteria, through multistage fermentation culture, just can produce efficient compound microbial culture starter; Add the lime-ash, the mud etc. that in alcohol slops production, produce as matrix, develop fixing high-performance bio bacterial manure.
Summary of the invention
The object of the invention is to for molasses fermented waste in prior art innoxious not exclusively for fertiliser production, humify acidifying or alkalization process are single, cause humify poor effect, humify is incomplete, contain in molasses fermented waste liquid Fertilizer application process soil is caused to secondary pollution, fertilizer for growth of crop etc. without effect, provide one to utilize fermented waste fluid to prepare organic/inorganic mixed active composite fertilizer method, the method proposes to adopt the method for acidifying or the two treating processes combination of alkalizing, molasses fermented waste liquid concentrated solution is carried out respectively to acid, alkali humify, then the two relaxes neutralization and makes fermented waste fluid after humify can be used for preparing multiple organic/inorganic to mix composite fertilizer, this organic/inorganic mixes composite fertilizer and utilizes modern microbial technique, inoculation biological bacteria, through multistage fermentation culture, just can produce efficient compound microbial culture starter, add the lime-ash, the mud etc. that in alcohol slops production, produce as matrix, develop fixing high-performance bio bacterial manure.
To achieve these goals, the present invention has adopted following technical scheme:
A high comprehensive reutilization method that oozes fermented waste fluid and mud, the method comprises the following steps:
1) concentrated: utilize heating evaporation that molasses fermented waste liquid is concentrated into organic content for 40-75%, obtain concentrated solution and carry out coolingly, cooling rear concentrated solution is divided into two portions and uses, and a part is for alkaline hydrolysis dehydration, and a part is for acidolysis dehydration.
2) alkaline hydrolysis dehydration: get the partial concentration liquid that step 1) obtains, add the alkaline hydrolysis medicament of 10%-35%, alkaline hydrolysis dehydration 20-40min under stirring at low speed condition, then add 5-15% fused(calcium magnesium)phosphate, 10-15% potash fertilizer to stir, obtain alkaline hydrolysis condiment.
3) acidolysis dehydration: get the partial concentration liquid that step 1) obtains, add the acidolysis medicament of 10%-35%, under stirring at low speed condition, acidolysis dehydration 20-40min, obtains acidolysis condiment.
4) preparation in and condiment: the acidolysis condiment of step 3) is joined to step 2) alkaline hydrolysis condiment in mix, make the two occur acid-base neutralisation, in obtaining after mixing and condiment pH between 5 ~ 7.PH, between 5 ~ 7, runs into alkali and can decompose to prevent from adding urea, lowers the nutritive value of fertilizer.
5) dry: during step 4) is obtained and condiment dry under 35-50 DEG C, ventilation condition, obtain water content and be≤10% dry condiment;
6) one-level biological fermentation: get 15 ~ 30 parts of lime-ash, 50 ~ 70 parts of mud, 10 ~ 30 parts of dry condiment, 2 ~ 5 parts of basic mediums that step 5) prepares, mix and blend is placed in one-level biological fermentation pond aerated fermentation 10 ~ 15 days, between yeast phase, stir 1 ~ 2 time, obtain one grade fermemtation fertilizer;
7) two stage biological fermentation: get the one grade fermemtation fertilizer that step 6) obtains, add 2 ~ 5 parts of trace elements, 5 ~ 15 parts of probiotic bacterium seed liquor, after stirring, aerated fermentation 7 ~ 10 days, obtains active organic fertilizer;
8) pH adjusts: in the active organic fertilizer of step 3), add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling is dissolved and is measured pH and stop adding alkaline hydrolysis agent or acidolysis agent between 5.5 ~ 7 time, dry under 40`60 DEG C of ventilation condition, obtain water content and be≤10% active ingredient fertilizer.
As further restriction of the present invention, described alkaline hydrolysis medicament is any or their composition in lime, liquefied ammonia, volatile salt, and lime is pulvis, and CaCO in lime
3content>=92%; Described acidolysis medicament is any or their composition in 60-85% sulfuric acid, 60 ~ 95% hydrochloric acid, 70 ~ 95% phosphoric acid.
As further restriction of the present invention, described heating evaporation is 50-85 DEG C of heating.
As further restriction of the present invention, described stirring at low speed is 100 ~ 200 r/min.
As further restriction of the present invention, described basic medium composition comprises 0.5-1% peptone, 0.5-2% sodium-chlor, 0.5-2% sodium phosphate.
As further restriction of the present invention, described probiotic bacterium comprises any or their arbitrary combination in root nodule bacterium, vinelandii, phosphorus bacteria and potassium bacterium; Described probiotic bacterium seed liquor is the probiotic bacterium fermented liquid obtaining after 16 ~ 24h that ferments in basic medium.
As further restriction of the present invention, described trace element comprises any or their composition in iron, boron, arsenic, manganese, zinc, copper, cobalt, molybdenum, selenium, magnesium.
Know-why of the present invention is: can not directly be absorbed by farm crop owing to making it contain large amount of organic (composition such as sugar, crude protein, colloid) in molasses fermented waste liquid, need to make by chemistry or biological respinse the reactions such as the degraded of organism generation soda acid, charing, condensation, dehydration, owing to adopting acid or alkali can play humification, but all there is meta-acid or meta-alkali after humify in the two, after alkaline hydrolysis or acidolysis, need to neutralize with acid or alkali again, just can make the quality standard product that conforms with composite fertilizer.The present invention adopts acidifying or alkalizes the method for the two treating processes combination, and chemical treating process produces the bad smells such as SO2, foul smell, environment is caused to secondary pollution, there are many weak points, molasses fermented waste liquid concentrated solution is carried out respectively acid, alkali humify by the present invention, and then the two relaxes neutralization and makes fermented waste fluid after humify can be used for preparing multiple organic/inorganic to mix composite fertilizer.Combine with modern biological high-technology, inoculation biological bacteria, through multistage fermentation culture, just can produce efficient compound microbial culture starter, there is no secondary pollution in treating processes again, and fertilizer after treatment approaches natural organic fertilizer, and fertility is by force and to soil close friend; Add the lime-ash, the mud etc. that in sugaring, produce as matrix, just can go out to fix high-performance bio bacterial manure by production development.The neutralizing agent that the technology of the present invention has separately added while having saved independent use acid or alkali humify, plays the double effects of dual-use material.
For making the present invention openly abundant, the fixing high-performance bio bacterial manure that the molasses fermented waste liquid harmless treatment of the present invention obtains, utilize existing conventional urea spray granulation, prepare organic-inorganic composite bio-fertilizers such as can be used for rice field, sugarcane, corn, gourd, fruit and vegetable, use the molasses concentrated solution after this treatment technology, the particle that mud is made, sugarcane can be increased production 10-20%, paddy rice can be increased production 5-15%, gourd, fruit and vegetable can increase production 5-20%, especially the crop such as Ipomoea batatas, sugarcane local flavor is splendid, and sugar degree is also improved.
Advantage of the present invention:
1. the present invention adopts acidifying or the method for the two treating processes combination of alkalizing, molasses fermented waste liquid concentrated solution is carried out respectively to acid, alkali humify, then the two relaxes and neutralizes the harmless treatment that realizes molasses fermented liquid making after humify, the neutralizing agent that this technological method has separately added while having saved independent use acid or alkali humify, plays the double effects of dual-use material.
2. the present invention is by treated dense useless mash, combine with modern biological high-technology, inoculation biological bacteria, through multistage fermentation culture, just can produce efficient compound microbial culture starter, in treating processes, there is no secondary pollution, fertilizer after treatment approaches natural organic fertilizer, and fertility is strong and to soil close friend; Add the lime-ash, the mud etc. that in sugaring, produce as matrix, just can go out to fix high-performance bio bacterial manure by production development.
3. the sugar in the technology of the present invention molasses concentrated solution after treatment, crude protein, colloid etc. can not be reduced to below 5% for the organic content that plant directly absorbs, after acidolysis and alkaline hydrolysis, the charing of organic process, degraded, condensation change into small molecules fertilizer, can be farm crop and directly absorb.
4. the dry condiment that the molasses fermented waste liquid harmless treatment of the present invention obtains, utilize urea spray granulation, prepare organic-inorganic composite bio-fertilizer particles such as can be used for rice field, sugarcane, corn, gourd, fruit and vegetable, use the particle that the molasses concentrated solution after this treatment technology is made, sugarcane can be increased production 10-20%, and paddy rice can be increased production 5-15%, and gourd, fruit and vegetable can increase production 5-20%, especially the crop such as Ipomoea batatas, sugarcane local flavor is splendid, and sugar degree is also improved.
Embodiment
Below in conjunction with embodiment, the present invention is further described, but protection scope of the present invention is not limited to these embodiment.
Embodiment 1:
The molasses fermented waste liquid of the present embodiment is from Guangxi large-scale Cassava alcohol fermentation manufacturing enterprise.The basic medium formula of using in embodiment is: 0.5% peptone, 1.5% sodium-chlor, 1.0% sodium phosphate; Described probiotic bacterium seed liquor is the probiotic bacterium fermented liquid obtaining after 18h that ferments in basic medium; Probiotic bacterium comprises that root nodule bacterium, the two concentration of vinelandii approximate 1:1 combination.Trace element comprises that four kinds of quality in boron, arsenic, zinc, molybdenum, selenium is than the composition that approximates 1:1:1:1, before trace element adds, is dissolved in the 1L aqueous solution, and the content of each trace element is probably between 0.5 ~ 1g/L.Active fertilizer treating and preparing process step is as follows:
1) concentrated: at 65 DEG C, molasses fermented waste liquid is concentrated into organic content is 55% to heating evaporation, obtain concentrated solution and carry out coolingly, cooling rear concentrated solution is divided into two portions and uses, and a part is for alkaline hydrolysis dehydration, and a part is for acidolysis dehydration.
2) alkaline hydrolysis dehydration: get the partial concentration liquid that step 1) obtains, add 30% alkaline hydrolysis medicament (lime, content >=92% of CaCO3 in lime), alkaline hydrolysis dehydration 30min under 150 r/min stirring at low speed conditions, add again 10% fused(calcium magnesium)phosphate, 10% potash fertilizer to stir, obtain alkaline hydrolysis condiment.
3) acidolysis dehydration: get the partial concentration liquid that step 1) obtains, add 15% acidolysis medicament (75% sulfuric acid), under 150 r/min stirring at low speed conditions, acidolysis dehydration 30min, obtains acidolysis condiment.
4) preparation in and condiment: the acidolysis condiment of step 3) is joined to step 2) alkaline hydrolysis condiment in mix, make the two occur acid-base neutralisation, in obtaining after mixing and condiment pH between 6.PH, between 6, runs into alkali and can decompose to prevent from adding urea, lowers the nutritive value of fertilizer.
5) dry: during step 4) is obtained and condiment dry under 40 DEG C, ventilation condition, obtaining water content is 7-8%, obtains dry condiment.
6) one-level biological fermentation: get 25 parts of lime-ash, 60 parts of mud, 10 parts of dry condiment, 5 parts of basic mediums that step 5) prepares, mix and blend is placed in one-level biological fermentation pond aerated fermentation 15 days, stirs 2 times between yeast phase, obtains one grade fermemtation fertilizer.
7) two stage biological fermentation: get the one grade fermemtation fertilizer that step 6) obtains, add 3 parts of trace elements, 15 parts of probiotic bacterium seed liquor, after stirring, aerated fermentation 7 days, obtains active organic fertilizer.
8) pH adjusts and inorganic fertilizer condiment: in the active organic fertilizer of step 7), add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling is dissolved and is measured pH and stop adding sulfuric acid between 5.5 time, dry under 40 DEG C of ventilation conditions, obtaining water content is the active ingredient fertilizer of 8-9%.
Embodiment 2:
The molasses fermented waste liquid of the present embodiment is from Guangxi large-scale Cassava alcohol fermentation manufacturing enterprise.The basic medium formula of using in embodiment is: 1% peptone, 0.5% sodium-chlor, 2% sodium phosphate; Probiotic bacterium comprises that root nodule bacterium, vinelandii, phosphorus bacteria, four kinds of bacterial concentrations of potassium bacterium approximate 1:1:1:1 combination; Described probiotic bacterium seed liquor is the probiotic bacterium fermented liquid obtaining after 16h that ferments in basic medium; Trace element comprises that six kinds of mass ratioes in iron, manganese, zinc, molybdenum, selenium, magnesium approximate 1:1:1:1:1 composition, before trace element adds, is dissolved in the 1L aqueous solution, and the content of each trace element is probably between 2 ~ 3g/L.Processing preparation process is as follows:
1) concentrated: at 85 DEG C, molasses fermented waste liquid is concentrated into organic content is 75% to heating evaporation, obtain concentrated solution and carry out coolingly, cooling rear concentrated solution is divided into two portions and uses, and a part is for alkaline hydrolysis dehydration, and a part is for acidolysis dehydration.
2) alkaline hydrolysis dehydration: get the partial concentration liquid that step 1) obtains, add 35% alkaline hydrolysis medicament (liquefied ammonia), alkaline hydrolysis dehydration 25min under 200 r/min stirring at low speed conditions, then add 13% fused(calcium magnesium)phosphate, 15% potash fertilizer to stir, obtain alkaline hydrolysis condiment.
3) acidolysis dehydration: get the partial concentration liquid that step 1) obtains, add 20% acidolysis medicament (70% hydrochloric acid), under 200 r/min stirring at low speed conditions, acidolysis dehydration 35min, obtains acidolysis condiment.
4) preparation in and condiment: the acidolysis condiment of step 3) is joined to step 2) alkaline hydrolysis condiment in mix, make the two occur acid-base neutralisation, in obtaining after mixing and condiment pH between 7.PH, between 7, runs into alkali and can decompose to prevent from adding urea, lowers the nutritive value of fertilizer.
5) dry: during step 4) is obtained and condiment dry under 35 DEG C, ventilation condition, obtaining water content is 5-6%, obtains dry condiment.
6) one-level biological fermentation: get 20 parts of lime-ash, 50 parts of mud, 25 parts of dry condiment, 5 parts of basic mediums that step 5) prepares, mix and blend is placed in one-level biological fermentation pond aerated fermentation 10 days, between yeast phase, stir 1 ~ 2 time, obtain one grade fermemtation fertilizer.
7) two stage biological fermentation: get the one grade fermemtation fertilizer that step 5) obtains, add 5 parts of trace elements, 10 parts of probiotic bacterium seed liquor, after stirring, aerated fermentation 9 days, obtains active organic fertilizer.
8) pH adjusts and inorganic fertilizer condiment: in the active organic fertilizer of step 7), add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling is dissolved and is measured pH and stop adding hydrochloric acid between 6 time, dry under 50 DEG C of ventilation conditions, obtaining water content is the active ingredient fertilizer of 7-8%.
Embodiment 3:
The molasses fermented waste liquid of the present embodiment is from Guangxi large-scale Cassava alcohol fermentation manufacturing enterprise.The basic medium formula of using in embodiment is: 1% peptone, 2% sodium-chlor, 0.5% sodium phosphate; Probiotic bacterium comprises vinelandii; Described probiotic bacterium seed liquor is the probiotic bacterium fermented liquid obtaining after 24h that ferments in basic medium; Trace element comprises that ten kinds, iron, boron, arsenic, manganese, zinc, copper, cobalt, molybdenum, selenium, magnesium etc. are according to 1:1:1:1:1:1:1:1:1:1 composition, before trace element adds, is dissolved in the 1L aqueous solution, and the content of each trace element is probably between 0.5 ~ 1g/L.Treatment step is as follows:
1) concentrated: at 50 DEG C, molasses fermented waste liquid is concentrated into organic content is 60% to heating evaporation, obtain concentrated solution and carry out coolingly, cooling rear concentrated solution is divided into two portions and uses, and a part is for alkaline hydrolysis dehydration, and a part is for acidolysis dehydration.
2) alkaline hydrolysis dehydration: get the partial concentration liquid that step 1) obtains, add 25% alkaline hydrolysis medicament (volatile salt pulvis), alkaline hydrolysis dehydration 40min under 150 r/min stirring at low speed conditions, then add 8% fused(calcium magnesium)phosphate, 15% potash fertilizer to stir, obtain alkaline hydrolysis condiment.
3) acidolysis dehydration: get the partial concentration liquid that step 1) obtains, add 30% acidolysis medicament (90% phosphoric acid), under 150 r/min stirring at low speed conditions, acidolysis dehydration 25min, obtains acidolysis condiment.
4) preparation in and condiment: the acidolysis condiment of step 3) is joined to step 2) alkaline hydrolysis condiment in mix, make the two occur acid-base neutralisation, in obtaining after mixing and condiment pH between 5.PH, between 5, runs into alkali and can decompose to prevent from adding urea, lowers the nutritive value of fertilizer.
5) dry: during step 4) is obtained and condiment dry under 45 DEG C, ventilation condition, obtaining water content is 8-9%, obtains dry condiment.
6) one-level biological fermentation: get 30 parts of lime-ash, 58 parts of mud, 10 parts of dry condiment, 2 parts of basic mediums that step 5) prepares, mix and blend is placed in one-level biological fermentation pond aerated fermentation 12 days, between yeast phase, stir 1 ~ 2 time, obtain one grade fermemtation fertilizer.
7) two stage biological fermentation: get the one grade fermemtation fertilizer that step 6) obtains, add 2 parts of trace elements, 15 parts of probiotic bacterium seed liquor, after stirring, aerated fermentation 10 days, obtains active organic fertilizer.
8) pH adjusts and inorganic fertilizer condiment: in the active organic fertilizer of step 7), add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling is dissolved and is measured pH and stop adding phosphoric acid between 5.5 time, after dry under 60 DEG C of ventilation conditions, obtaining water content is the active ingredient fertilizer of 8-10%.
Embodiment 4:
The molasses fermented waste liquid of the present embodiment is from Guangxi large-scale Cassava alcohol fermentation manufacturing enterprise.The basic medium formula of using in embodiment is: 0.5% peptone, 1% sodium-chlor, 1% sodium phosphate; Probiotic bacterium comprises root nodule bacterium; Described probiotic bacterium seed liquor is the probiotic bacterium fermented liquid obtaining after 20h that ferments in basic medium; Trace element comprises that ten kinds, arsenic, manganese, zinc, copper, cobalt, molybdenum, selenium, magnesium etc. are according to 1:1:1:1:1:1:1:1 composition, before trace element adds, is dissolved in the 1L aqueous solution, and the content of each trace element is probably between 1.5 ~ 2g/L.Prepare treatment step as follows:
1) concentrated: at 75 DEG C, molasses fermented waste liquid is concentrated into organic content is 50% to heating evaporation, obtain concentrated solution and carry out coolingly, cooling rear concentrated solution is divided into two portions and uses, and a part is for alkaline hydrolysis dehydration, and a part is for acidolysis dehydration.
2) alkaline hydrolysis dehydration: get the partial concentration liquid that step 1) obtains, add 10% alkaline hydrolysis medicament (liquefied ammonia and volatile salt are according to the mixture of mass ratio 1:1), alkaline hydrolysis dehydration 35min under 200 r/min stirring at low speed conditions, then add 5% fused(calcium magnesium)phosphate, 12% potash fertilizer to stir, obtain alkaline hydrolysis condiment.
3) acidolysis dehydration: get the partial concentration liquid that step 1) obtains, add 25% acidolysis medicament (60% sulfuric acid mixes according to the ratio of volume ratio 1:1 with 75% hydrochloric acid), under 200 r/min stirring at low speed conditions, acidolysis dehydration 40min, obtains acidolysis condiment.
4) preparation in and condiment: the acidolysis condiment of step 3) is joined to step 2) alkaline hydrolysis condiment in mix, make the two occur acid-base neutralisation, in obtaining after mixing and condiment pH between 7.PH, between 7, runs into alkali and can decompose to prevent from adding urea, lowers the nutritive value of fertilizer.
5) dry: during step 4) is obtained and condiment dry under 50 DEG C, ventilation condition, obtaining water content is 10%, obtains dry condiment.
6) one-level biological fermentation: get 20 parts of lime-ash, 65 parts of mud, 13 parts of dry condiment, 2 parts of basic mediums that step 5) prepares, mix and blend is placed in one-level biological fermentation pond aerated fermentation 15 days, stirs 2 times between yeast phase, obtains one grade fermemtation fertilizer.
7) two stage biological fermentation: get the one grade fermemtation fertilizer that step 6) obtains, add 4 parts of trace elements, 10 parts of probiotic bacterium seed liquor, after stirring, aerated fermentation 8 days, obtains active organic fertilizer.
8) pH adjusts and inorganic fertilizer condiment: in the active organic fertilizer of step 7), add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling is dissolved and is measured pH and stop adding phosphoric acid between 7 time, dry under 45 DEG C of ventilation conditions, obtaining water content is the active ingredient fertilizer of 9-10%.
Embodiment 5:
The molasses fermented waste liquid of the present embodiment is from Guangxi large-scale Cassava alcohol fermentation manufacturing enterprise.The basic medium formula of using in embodiment is: 1% peptone, 2% sodium-chlor, 0.5% sodium phosphate; Probiotic bacterium comprises that phosphorus bacteria, two kinds of concentration ratio of potassium bacterium approximate 1:1 combination; Described probiotic bacterium seed liquor is the probiotic bacterium fermented liquid obtaining after 18h that ferments in basic medium; Trace element comprises that six kinds, iron, zinc, copper, molybdenum, selenium, magnesium etc. are according to 1:1:1:1:1:1 composition, before trace element adds, is dissolved in the 1L aqueous solution, and the content of each trace element is probably between 2.0 ~ 2.5g/L.Prepare treatment step as follows:
1) concentrated: at 75 DEG C, molasses fermented waste liquid is concentrated into organic content is 40% to heating evaporation, obtain concentrated solution and carry out coolingly, cooling rear concentrated solution is divided into two portions and uses, and a part is for alkaline hydrolysis dehydration, and a part is for acidolysis dehydration.
2) alkaline hydrolysis dehydration: get the partial concentration liquid that step 1) obtains, add 35% alkaline hydrolysis medicament (lime powder and volatile salt are according to the ratio mixture of mass ratio 1:2), alkaline hydrolysis dehydration 25min under 200 r/min stirring at low speed conditions, add again 15% fused(calcium magnesium)phosphate, 13% potash fertilizer to stir, obtain alkaline hydrolysis condiment.
3) acidolysis dehydration: get the partial concentration liquid that step 1) obtains, add 20% acidolysis medicament (80% phosphoric acid), under 200 r/min stirring at low speed conditions, acidolysis dehydration 20min, obtains acidolysis condiment.
4) preparation in and condiment: the acidolysis condiment of step 3) is joined to step 2) alkaline hydrolysis condiment in mix, make the two occur acid-base neutralisation, in obtaining after mixing and condiment pH between 6.PH, between 6, runs into alkali and can decompose to prevent from adding urea, lowers the nutritive value of fertilizer.
5) dry: during step 4) is obtained and condiment dry under 40 DEG C, ventilation condition, obtaining water content is 5-6%, obtains dry condiment.
6) one-level biological fermentation: get 15 parts of lime-ash, 70 parts of mud, 13 parts of dry condiment, 2 parts of basic mediums that step 5) prepares, mix and blend is placed in one-level biological fermentation pond aerated fermentation 10 ~ 15 days, between yeast phase, stir 1 ~ 2 time, obtain one grade fermemtation fertilizer.
7) two stage biological fermentation: get the one grade fermemtation fertilizer that step 6) obtains, add 3 parts of trace elements, 12 parts of probiotic bacterium seed liquor, after stirring, aerated fermentation 7 days, obtains active organic fertilizer.
8) pH adjusts and inorganic fertilizer condiment: in the active organic fertilizer of step 7), add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling is dissolved and is measured pH and stop adding hydrochloric acid between 6.5 time, dry under 55 DEG C of ventilation conditions, obtaining water content is the active ingredient fertilizer of 9-10%.
Embodiment 6:
The molasses fermented waste liquid of the present embodiment is from Guangxi large-scale Cassava alcohol fermentation manufacturing enterprise.The basic medium formula of using in embodiment is: 0.5% peptone, 2% sodium-chlor, 0.5% sodium phosphate; Probiotic bacterium comprises that root nodule bacterium, phosphorus bacteria, three kinds of concentration ratio of potassium bacterium approximate 1:1:1 combination; Described probiotic bacterium seed liquor is the probiotic bacterium fermented liquid obtaining after 20h that ferments in basic medium; Trace element comprises that two kinds of boron, cobalts etc. are according to 1:1 composition, before trace element adds, is dissolved in the 1L aqueous solution, and the content of each trace element is probably between 0.5 ~ 1.0g/L.Preparation method's treatment step is as follows:
1) concentrated: at 80 DEG C, molasses fermented waste liquid is concentrated into organic content is 65% to heating evaporation, obtain concentrated solution and carry out coolingly, cooling rear concentrated solution is divided into two portions and uses, and a part is for alkaline hydrolysis dehydration, and a part is for acidolysis dehydration.
2) alkaline hydrolysis dehydration: get the partial concentration liquid that step 1) obtains, add 20% alkaline hydrolysis medicament (liquefied ammonia), alkaline hydrolysis dehydration 20min under 200 r/min stirring at low speed conditions, then add 12% fused(calcium magnesium)phosphate, 10% potash fertilizer to stir, obtain alkaline hydrolysis condiment.
3) acidolysis dehydration: get the partial concentration liquid that step 1) obtains, add 35% acidolysis medicament (80% hydrochloric acid), under 200 r/min stirring at low speed conditions, acidolysis dehydration 35min, obtains acidolysis condiment.
4) preparation in and condiment: the acidolysis condiment of step 3) is joined to step 2) alkaline hydrolysis condiment in mix, make the two occur acid-base neutralisation, in obtaining after mixing and condiment pH between 5.PH, between 5, runs into alkali and can decompose to prevent from adding urea, lowers the nutritive value of fertilizer.
5) dry: during step 4) is obtained and condiment dry under 35 DEG C, ventilation condition, obtaining water content is 5-6%, obtains dry condiment.
6) one-level biological fermentation: get 15 parts of lime-ash, 50 parts of mud, 30 parts of dry condiment, 5 parts of basic mediums that step 5) prepares, mix and blend is placed in one-level biological fermentation pond aerated fermentation 12 days, stirs 2 times between yeast phase, obtains one grade fermemtation fertilizer.
7) two stage biological fermentation: get the one grade fermemtation fertilizer that step 6) obtains, add 5 parts of trace elements, 15 parts of probiotic bacterium seed liquor, after stirring, aerated fermentation 9 days, obtains active organic fertilizer.
8) pH adjusts and inorganic fertilizer condiment: in the active organic fertilizer of step 7), add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling is dissolved and is measured pH and stop adding sulfuric acid between 6.0 time, dry under 60 DEG C of ventilation conditions, obtaining water content is the active ingredient fertilizer of 5-6%.
Embodiment 7 application examples:
Embodiment 1-6 is processed to the active ingredient fertilizer obtaining, utilize existing conventional urea spray granulation, prepare organic-inorganic composite bio-fertilizers such as can be used for rice field, sugarcane, corn, gourd, fruit and vegetable, use the particle that the molasses concentrated solution after this treatment technology is made, sugarcane can be increased production 10-20%, and paddy rice can be increased production 5-15%, gourd, fruit and vegetable can increase production 5-20%, especially the crop such as sugarcane, Ipomoea batatas local flavor is splendid, and sugar degree is also improved, and Sugar Content in Sugarcane improves 3 ~ 7%.
Claims (7)
1. a high comprehensive reutilization method that oozes fermented waste fluid and mud, is characterized in that, the method comprises the following steps:
1) concentrated: utilize heating evaporation that molasses fermented waste liquid is concentrated into organic content for 40-75%, obtain concentrated solution and carry out coolingly, cooling rear concentrated solution is divided into two portions and uses, and a part is for alkaline hydrolysis dehydration, and a part is for acidolysis dehydration;
2) alkaline hydrolysis dehydration: get the partial concentration liquid that step 1) obtains, add the alkaline hydrolysis medicament of 10%-35%, alkaline hydrolysis dehydration 20-40min under stirring at low speed condition, then add 5-15% fused(calcium magnesium)phosphate, 10-15% potash fertilizer to stir, obtain alkaline hydrolysis condiment;
3) acidolysis dehydration: get the partial concentration liquid that step 1) obtains, add the acidolysis medicament of 10%-35%, under stirring at low speed condition, acidolysis dehydration 20-40min, obtains acidolysis condiment;
4) preparation in and condiment: the acidolysis condiment of step 3) is joined to step 2) alkaline hydrolysis condiment in mix, make the two occur acid-base neutralisation, in obtaining after mixing and condiment pH between 5 ~ 7;
5) dry: during step 4) is obtained and condiment dry under 35-50 DEG C, ventilation condition, obtain water content and be≤10% dry condiment;
6) one-level biological fermentation: get 15 ~ 30 parts of lime-ash, 50 ~ 70 parts of mud, 10 ~ 30 parts of dry condiment, 2 ~ 5 parts of basic mediums that step 5) prepares, mix and blend is placed in one-level biological fermentation pond aerated fermentation 10 ~ 15 days, between yeast phase, stir 1 ~ 2 time, obtain one grade fermemtation fertilizer;
7) two stage biological fermentation: get the one grade fermemtation fertilizer that step 6) obtains, add 2 ~ 5 parts of trace elements, 5 ~ 15 parts of probiotic bacterium seed liquor, after stirring, aerated fermentation 7 ~ 10 days, obtains active organic fertilizer;
8) pH adjusts: in the active organic fertilizer of step 3), add alkaline hydrolysis agent or acidolysis agent, after stirring, sampling is dissolved and is measured pH and stop adding alkaline hydrolysis agent or acidolysis agent between 5.5 ~ 7 time, dry under 40`60 DEG C of ventilation condition, obtain water content and be≤10% active ingredient fertilizer.
2. height according to claim 1 oozes the comprehensive reutilization method of fermented waste fluid and mud, it is characterized in that: described alkaline hydrolysis medicament is any or their composition in lime, liquefied ammonia, volatile salt, and lime is pulvis, and CaCO in lime
3content>=92%; Described acidolysis medicament is any or their composition in 60-85% sulfuric acid, 60 ~ 95% hydrochloric acid, 70 ~ 95% phosphoric acid.
3. height according to claim 1 oozes the comprehensive reutilization method of fermented waste fluid and mud, it is characterized in that: described heating evaporation is 50-85 DEG C of heating.
4. height according to claim 1 oozes the comprehensive reutilization method of fermented waste fluid and mud, it is characterized in that: described stirring at low speed is 100 ~ 200 r/min.
5. height according to claim 1 oozes the comprehensive reutilization method of fermented waste fluid and mud, it is characterized in that: described basic medium composition comprises 0.5-1% peptone, 0.5-2% sodium-chlor, 0.5-2% sodium phosphate.
6. height according to claim 1 oozes the comprehensive reutilization method of fermented waste fluid and mud, it is characterized in that: described probiotic bacterium comprises any or their arbitrary combination in root nodule bacterium, vinelandii, phosphorus bacteria and potassium bacterium; Described probiotic bacterium seed liquor is the probiotic bacterium fermented liquid obtaining after 16 ~ 24h that ferments in basic medium.
7. height according to claim 1 oozes the comprehensive reutilization method of fermented waste fluid and mud, it is characterized in that: described trace element comprises any or their composition in iron, boron, arsenic, manganese, zinc, copper, cobalt, molybdenum, selenium, magnesium.
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CN106915876A (en) * | 2017-02-24 | 2017-07-04 | 中山大学 | A kind of utilization bipolar membrane electrodialysis device electrolytic salt produces the method that alkali carries sludge digestibility high is produced in acid |
CN107555746A (en) * | 2017-10-30 | 2018-01-09 | 刘胜军 | Earthworm enzymatic sludge high-drying cryogenic dewatering carbonization treatment system and technique |
CN109553475A (en) * | 2018-12-28 | 2019-04-02 | 云南云叶化肥股份有限公司 | It is a kind of to give up mash as the preparation method and application of the fertilizer of raw material using cane molasses |
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