CN103554860A - Decoration wall brick and making method thereof - Google Patents
Decoration wall brick and making method thereof Download PDFInfo
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- CN103554860A CN103554860A CN201310382092.XA CN201310382092A CN103554860A CN 103554860 A CN103554860 A CN 103554860A CN 201310382092 A CN201310382092 A CN 201310382092A CN 103554860 A CN103554860 A CN 103554860A
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Abstract
The invention discloses a decoration wall brick and a making method thereof to solve the problems of frangibility, single shape and color, inconvenient installation and the like of present wall bricks. The decoration wall brick is composed of an unsaturated polyester resin, a filler, an initiator, an accelerant, a polymerization inhibitor and an enhancement material, has the characteristics of light weight, difficult fragmentation, high strength, convenient production and installation, long service life and the like, is suitable for the inside, and is also suitable for the outside.
Description
Technical field
The invention belongs to building decoration field, be specifically related to a kind of decorative wall brick and preparation method thereof.
Background technology
Wall tile is widely used in the places such as external wall, interior wall, washroom, is that modern architecture is decorated an indispensable part.Along with the development of building trade and people improve building decoration demand, about wall tile product and technology, in succession emerge in large numbers.
To be 201120105471.0 Granted publications number disclose a kind of wall brick for the Chinese utility model patent of CN 202248475 U to application number, wall brick body forms corresponding two end faces, the He Liangge bottom surface, two sides arranging, on wall brick body, be provided with the wall brick of realizing wall brick splicing and tile structure, wall brick tiles structure and is arranged at face of wall brick body or more than one, and wall brick tiles amalgamation groove or the amalgamation edge that structure forms mutual coupling.
To be 201120456036.2 Granted publications number disclose a kind of metal wall brick for the Chinese utility model patent of CN 202324493 U to application number, comprise that profile is the metal shell of thin lid-like, metal wall brick also comprises the weighting material for reinforcement metal casing rigidity, and weighting material is built in the vallecular cavity of metal shell.
To be 99236033.1 Granted publications number disclose a kind of Wall brick for the Chinese utility model patent of CN 2371186 Y to application number, it assembles a monoblock by the little Wall brick of some emulation sizes and fires and form, and between adjacent two little Wall bricks, is provided with the groove that can distinguish them; On adjacent two square edges of monoblock Wall brick, be respectively equipped with plural positioning boss.
Application number be 201220271055.2 Granted publications number for the Chinese utility model patent of CN 202644814 U discloses a kind of Wall brick of exempting from, comprised brick body, wherein, at brick body, be at least provided with at least one semicircle orifice in one end.
The decorative wall brick using is in the market mostly the stone brick that integrated ceramic wall tile or stone material are cut into, and ceramic wall tile and stone brick exist following problem:
One, more or less have aberration, shape and color are single;
Even if pattern or decorative pattern have been fired with colored glaze in two part ceramic wall tiles or stone brick surface, not only complex process but also pattern or decorative pattern are single, and decorative effect is poor;
Three, Heavy Weight transportation cost is high, frangible in transportation;
Four, in installation process, not only to consume a large amount of material (cement), and install slowly, higher to operator's technical requirements;
Five, form not tractable building waste in a large number after short, discarded work-ing life;
Six, ceramic wall tile and stone material heat-proof quality are poor.
On market, have part human consumer to adopt emulsion paint as decoration, however use emulsion paint as decoration exist that color is single, the problem such as production and use procedure produce a large amount of pollutents, easily pollute simultaneously not easy cleaning, work-ing life is short, not heat insulation.
Summary of the invention
The present invention is for solving the above-mentioned technical problem of existing wall brick, emulsion paint, and a kind of decorative wall brick and preparation method thereof is provided, and has light weight, is difficult for the features such as broken, intensity is high, production and easy for installation, long service life.
For solving the problems of the technologies described above, the technical solution adopted in the present invention is:
, it is characterized in that, the material component of described decorative wall brick and the parts by weight of each component are:
20-30 parts of unsaturated polyester resins;
30-60 parts of fillers;
0.5-10 parts of initiators;
2-3 parts of promotor;
0.1-4 parts of stoppers;
10-30 parts of strongtheners.
Further, described unsaturated polyester resin is one or more the combination in adjacent benzene type unsaturated polyester resin, metaphenylene unsaturated polyester resin, terephthalic unsaturated polyester resin, Bisphenol a unsaturated polyester resin or vinyl ester type unsaturated polyester resin;
Further, described filler is one or more the combination in calcium carbonate, Aluminum calcium silicate, barium sulfate, miemite, china clay, glass microballon, silicate microballon, aluminium hydroxide, aluminum oxide, magnesium oxide, magnesium hydroxide, zirconium white, weisspiessglanz or talcum powder.
Further, described initiator is one or more the combination in benzoyl peroxide, methylethyl ketone peroxide, cyclohexanone peroxide, peroxidized t-butyl perbenzoate or 1,1-bis-(t-butyl peroxy) hexanaphthene.
Further, described promotor is one or more the combination in cobalt naphthenate, cobalt octoate, xylidine, Diethyl Aniline or dimethyl-p-toluidine.
Further, described stopper is Resorcinol, para benzoquinone, tertiarybutylhydroquinone, 2, the combination of one or more in 5-ditert-butylhydro quinone or methyl hydroquinone.
Further, described strongthener is one or more the combination in glass fibre/felt, carbon fiber, aramid fiber, trevira or cyclization.
The preparation method of decorative wall brick, is characterized in that: its preparation method comprises the following steps:
(1) batching: unsaturated polyester resin, filler and auxiliary agent are prepared burden according to above-mentioned parts by weight;
(2) stir: the batching in (1) is stirred in stirring mechanism, make resin slip;
(3) infiltrate: at plate material forming machine, utilize resin slip to infiltrate strongthener, obtain the laminboard layer of resin slip-strongthener-resin slip, make resin slip soak into strongthener and mix; Plate material forming unit has upper and lower two cover slip coating devices, polyethylene film is emitted through scraper gluing table by releasing device, resin slip pours on film, in gluing edge of table, there is scraper, regulate the clearance height of scraper and table top to be frictioning thickness, the gap of scraper and table top is by micron setter minute adjustment.Two films are respectively by being transported on travelling belt after machine upper and lower coated with resin slip, strongthener is layered on above the resin slip of lower film, then double-layer films closes up, form the laminboard layer of resin slip-strongthener (glass fibre)-resin slip, in plate material forming unit, a series of extrusion rolls are pinched and are rubbed work laminboard layer, make resin slip soak into strongthener and mix.
(4) rolling: rolling in sheet stock unit;
(5) maturation process: carry out maturation process in sheet stock unit, the temperature of described maturation process is 25 °-30 °, and the time of maturation process is 10-48 hours;
(6) compression moulding: pass through mould compression moulding in thermocompressor or vacuum hotpressing machine.
Further, described stirring mechanism is high speed dispersor, and the temperature stirring in high speed dispersor is 25 ℃-35 ℃, and the time of stirring is 30-40 minute.
Compared with prior art, the present invention has following beneficial effect:
Decorative wall brick of the present invention, has that no color differnece, light weight, intensity are high, good toughness, resistance to chemical attack are strong, it is broken to be difficult for, manufacture conveniently, and blowdown is few in process of production, uses pollution-freely, also has long service life, easy cleaned feature simultaneously.
Decorative wall brick of the present invention, prepares by above-mentioned preparation method, has the simple feature of process for producing, can produce different shapes as required simultaneously, different color, and the wall brick of different pattern, meets people for the demand of Modern Decorative.
Wall brick of the present invention can be used for outdoor, indoor, fixed orifices can be set on the body of wall brick to be arranged on body of wall through bolt or screw, or be arranged on body of wall by fixed strip, no longer need to consume unclassified stores, installation personnel is not needed to technical requirements, there is easy for installation, feature efficiently.
Accompanying drawing explanation
Fig. 1 is the structural representation of wall brick embodiment mono-of the present invention;
Fig. 2 is the structural representation of wall brick embodiment bis-of the present invention;
Fig. 3 is the structural representation of wall brick embodiment tri-of the present invention;
Fig. 4 is the structural representation of wall brick one embodiment of the present invention, and the surrounding of wall brick is equipped with fixed strip;
Fig. 5 is the structural representation of wall brick one embodiment of the present invention, and the back side of wall brick is provided with cavity;
Mark in figure: 1, wall brick, 2, fixed strip, 3, through hole, 4, cavity.
Embodiment
Below in conjunction with embodiment, the invention will be further described, and described embodiment is only the present invention's part embodiment, is not whole embodiment.Embodiment based in the present invention, those of ordinary skill in the art, not making other embodiment used that obtain under creative work prerequisite, belongs to protection scope of the present invention.
, the material component of described decorative wall brick and the parts by weight of each component are:
20-30 parts of unsaturated polyester resins;
30-60 parts of fillers;
0.5-10 parts of initiators;
2-3 parts of promotor;
0.1-4 parts of stoppers;
10-30 parts of strongtheners.
Further, described unsaturated polyester resin is one or more the combination in adjacent benzene type unsaturated polyester resin, metaphenylene unsaturated polyester resin, terephthalic unsaturated polyester resin, Bisphenol a unsaturated polyester resin or vinyl ester type unsaturated polyester resin;
Further, described filler is one or more the combination in calcium carbonate, Aluminum calcium silicate, barium sulfate, miemite, china clay, glass microballon and silicate microballon, aluminium hydroxide, aluminum oxide, magnesium oxide, magnesium hydroxide, zirconium white, weisspiessglanz or talcum powder.
Further, described initiator is one or more the combination in benzoyl peroxide, methylethyl ketone peroxide, cyclohexanone peroxide, peroxidized t-butyl perbenzoate or 1,1-bis-(t-butyl peroxy) hexanaphthene.
Further, described promotor is one or more the combination in cobalt naphthenate, cobalt octoate, xylidine, Diethyl Aniline or dimethyl-p-toluidine.
Further, described stopper is Resorcinol, para benzoquinone, tertiarybutylhydroquinone, 2, the combination of one or more in 5-ditert-butylhydro quinone or methyl hydroquinone.
Further, described strongthener is one or more the combination in glass fibre/felt, carbon fiber, aramid fiber, trevira or cyclization.
The preparation method of decorative wall brick, is characterized in that: its preparation method comprises the following steps:
(1) batching: unsaturated polyester resin, filler and auxiliary agent are prepared burden according to above-mentioned parts by weight;
(2) stir: the batching in (1) is stirred in stirring mechanism, make resin slip;
(3) infiltrate: at plate material forming machine, utilize resin slip to infiltrate strongthener, obtain the laminboard layer of resin slip-strongthener-resin slip, make resin slip soak into strongthener and mix; Plate material forming unit has upper and lower two cover slip coating devices, polyethylene film is emitted through scraper gluing table by releasing device, resin slip pours on film, in gluing edge of table, there is scraper, regulate the clearance height of scraper and table top to be frictioning thickness, the gap of scraper and table top is by micron setter minute adjustment.Two films are respectively by being transported on travelling belt after machine upper and lower coated with resin slip, strongthener is layered on above the resin slip of lower film, then double-layer films closes up, form the laminboard layer of resin slip-strongthener (glass fibre)-resin slip, in plate material forming unit, a series of extrusion rolls are pinched and are rubbed work laminboard layer, make resin slip soak into strongthener and mix.
(4) rolling: rolling in sheet stock unit;
(5) maturation process: carry out maturation process in sheet stock unit, the temperature of described maturation process is 25 °-30 °, and the time of maturation process is 10-48 hours;
(6) compression moulding: pass through mould compression moulding in thermocompressor or vacuum hotpressing machine.
Further, described stirring mechanism is high speed dispersor, and the temperature stirring in high speed dispersor is 25 ℃-35 ℃, and the time of stirring is 30-40 minute.
Compared with prior art, the present invention has following beneficial effect:
Decorative wall brick of the present invention, has that no color differnece, light weight, intensity are high, good toughness, resistance to chemical attack are strong, it is broken to be difficult for, manufacture conveniently, and blowdown is few in process of production, uses pollution-freely, also has long service life, easy cleaned feature simultaneously.
Decorative wall brick of the present invention, prepares by above-mentioned preparation method, has the simple feature of process for producing, can produce different shapes as required simultaneously, different color, and the wall brick of different pattern, meets people for the demand of Modern Decorative.
Wall brick of the present invention can be used for outdoor, indoor, fixed orifices can be set on the body of wall brick to be arranged on body of wall through bolt or screw, or be arranged on body of wall by fixed strip, no longer need to consume unclassified stores, installation personnel is not needed to technical requirements, there is easy for installation, feature efficiently.
Embodiment mono-
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 22 parts, 23 parts of adjacent benzene type unsaturated polyester resins, 40 parts, calcium carbonate, 2 parts of benzoyl peroxides, 2.5 parts of cobalt naphthenates, 3.5 parts of Resorcinol and glass fibre.First adjacent benzene type unsaturated polyester resin, calcium carbonate, benzoyl peroxide, cobalt naphthenate and Resorcinol are prepared burden according to above-mentioned weight part; In stirring mechanism, stir and make resin slip, the stirring mechanism of the use of the present embodiment is high speed dispersor, and stirring work is carried out at normal temperatures, and the time of stirring, whipping temp was 30 degree until stir, and churning time is 30 minutes; At plate material forming machine, utilize resin slip sized glass fibres, obtain the laminboard layer of resin slip-glass fibre-resin slip, make resin slip soak into glass fibre and mix.Plate material forming unit has upper and lower two cover slip coating devices, polyethylene film is emitted through scraper gluing table by releasing device, resin slip pours on film, in gluing edge of table, there is scraper, regulate the clearance height of scraper and table top to be frictioning thickness, the gap of scraper and table top is by micron setter minute adjustment.Two films are respectively by being transported on travelling belt after machine upper and lower coated with resin slip, glass fibre is layered on above the resin slip of lower film, then double-layer films closes up, form the laminboard layer of resin slip-glass fibre-resin slip, in plate material forming unit, a series of extrusion rolls are pinched and are rubbed work laminboard layer, make resin slip soak into glass fibre and mix.
In sheet stock unit, carry out rolling and maturation process, the temperature of maturation process is 26 °, and the time of maturation process is 36 hours.
In thermocompressor, by mould compression moulding, the decorative wall brick that the present embodiment makes is cuboid, and wall brick is provided with through hole, and through hole is used for installing wall brick.As shown in Figure 1, the wall brick of the present embodiment is used for decorating indoor and outdoors to the structure iron of the present embodiment.
Embodiment bis-
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 20 parts of metaphenylene unsaturated polyester resins, 30 parts of Aluminum calcium silicates, 0.5 part of methylethyl ketone peroxide, 2 parts of cobalt octoates, 0.1 part of para benzoquinone, 10 parts, carbon fiber.
First metaphenylene unsaturated polyester resin, Aluminum calcium silicate, methylethyl ketone peroxide, cobalt octoate and para benzoquinone are prepared burden according to above-mentioned parts by weight; In stirring mechanism, stir and make resin slip, the stirring mechanism of the use of the present embodiment is high speed dispersor, and stirring work is carried out at normal temperatures, and the time of stirring is until stir, in the time of the present embodiment test, whipping temp is 25 °, and the time stirring is 35 minutes; At plate material forming machine, utilize resin slip to infiltrate carbon fiber, obtain the laminboard layer of resin slip-carbon fiber-resin slip, make resin slip soak into carbon fiber and mix.Plate material forming unit has upper and lower two cover slip coating devices, polyethylene film is emitted through scraper gluing table by releasing device, resin slip pours on film, in gluing edge of table, there is scraper, regulate the clearance height of scraper and table top to be frictioning thickness, the gap of scraper and table top is by micron setter minute adjustment.Two films are respectively by being transported on travelling belt after machine upper and lower coated with resin slip, carbon fiber is layered on above the resin slip of lower film, then double-layer films closes up, form the laminboard layer of resin slip-carbon fiber-resin slip, in plate material forming unit, a series of extrusion rolls are pinched and are rubbed work laminboard layer, make resin slip soak into carbon fiber and mix.
In sheet stock unit, carry out rolling and maturation process, the temperature of maturation process is 25 °, and the time of maturation process is 48 hours.
In vacuum hotpressing machine, by mould compression moulding, the decorative wall brick integral body of the present embodiment is cuboid, and the surrounding of wall brick is provided with fixed strip, offers for the through hole of wall brick is installed on fixed strip; Fixed strip and wall brick main body are through mould one pressing structure, and the structural representation of the present embodiment as shown in Figure 2.
Embodiment tri-
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 30 parts of terephthalic unsaturated polyester resins, 60 parts, barium sulfate, 10 parts of cyclohexanone peroxides, 3 parts of xylidines, 4 parts of tertiarybutylhydroquinones, 30 parts of aramid fibers.
First by terephthalic unsaturated polyester resin, barium sulfate, cyclohexanone peroxide, xylidine, tertiarybutylhydroquinone is prepared burden according to above-mentioned parts by weight; In stirring mechanism, stir and make resin slip, the stirring mechanism of the use of the present embodiment is high speed dispersor, and stirring work is carried out at normal temperatures, and the time of stirring is until stir, in the time of the present embodiment test, whipping temp is 26 °, and the time stirring is 36 minutes; At plate material forming machine, utilize resin slip to infiltrate aramid fiber, obtain the laminboard layer of resin slip-aramid fiber-resin slip, make resin slip soak into aramid fiber and mix.Plate material forming unit has upper and lower two cover slip coating devices, polyethylene film is emitted through scraper gluing table by releasing device, resin slip pours on film, in gluing edge of table, there is scraper, regulate the clearance height of scraper and table top to be frictioning thickness, the gap of scraper and table top is by micron setter minute adjustment.Two films are respectively by being transported on travelling belt after machine upper and lower coated with resin slip, aramid fiber is layered on above the resin slip of lower film, then double-layer films closes up, form the laminboard layer of resin slip-aramid fiber-resin slip, in plate material forming unit, a series of extrusion rolls are pinched and are rubbed work laminboard layer, make resin slip soak into aramid fiber and mix.
In sheet stock unit, carry out rolling and maturation process, the temperature of maturation process is 26 °, and the time of maturation process is 42 hours.In conjunction with Fig. 3, the decorative wall brick main body of the present embodiment is provided with installation through hole, and the back side of wall brick main body is provided with cavity, and for heat insulation, the present embodiment is specially adapted to exterior decoration.
Embodiment tetra-
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 25 parts of Bisphenol a unsaturated polyester resins, 50 parts of miemites, 2.1 parts of 0.8 part of peroxidized t-butyl perbenzoates, Diethyl Aniline, 2,0.5 part of 5-ditert-butylhydro quinone, 29 parts, trevira.
First by p-phenyl's Bisphenol a unsaturated polyester resin, miemite, peroxidized t-butyl perbenzoate, Diethyl Aniline, 2,5-ditert-butylhydro quinone stirs and makes resin slip in stirring mechanism, and the stirring mechanism of the use of the present embodiment is high speed dispersor, stirring work is carried out at normal temperatures, the time of stirring, in the time of the present embodiment test, whipping temp was 35 ° until stir, and the time stirring is 30 minutes; At plate material forming machine, utilize resin slip to infiltrate trevira, obtain the laminboard layer of resin slip-trevira-resin slip, make resin slip soak into trevira and mix.Plate material forming unit has upper and lower two cover slip coating devices, polyethylene film is emitted through scraper gluing table by releasing device, resin slip pours on film, in gluing edge of table, there is scraper, regulate the clearance height of scraper and table top to be frictioning thickness, the gap of scraper and table top is by micron setter minute adjustment.Two films are respectively by being transported on travelling belt after machine upper and lower coated with resin slip, trevira is layered on above the resin slip of lower film, then double-layer films closes up, form the laminboard layer of resin slip-trevira-resin slip, in plate material forming unit, a series of extrusion rolls are pinched and are rubbed work laminboard layer, make resin slip soak into trevira and mix.
In sheet stock unit, carry out rolling and maturation process, the temperature of maturation process is 30 °, and the time of maturation process is 10 hours.
Embodiment five
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 40 parts of totally 27 parts of adjacent benzene type unsaturated polyester resin and metaphenylene unsaturated polyester resins, china clay, 1,1 part of 1-bis-(t-butyl peroxy) hexanaphthene, 2.3 parts of dimethyl-p-toluidines, Resorcinol and totally 2 parts of para benzoquinone, 10 parts of cyclizations.
First by adjacent benzene type unsaturated polyester resin and metaphenylene unsaturated polyester resin, china clay, 1,1-bis-(t-butyl peroxy) hexanaphthene, dimethyl-p-toluidine, Resorcinol and para benzoquinone stir and make resin slip in stirring mechanism, the stirring mechanism of the use of the present embodiment is high speed dispersor, stirring work is carried out at normal temperatures, the time of stirring is until stir, in the time of the present embodiment test, whipping temp is 25 °, and the time stirring is 40 minutes; At plate material forming machine, utilize resin slip to infiltrate cyclization, obtain the laminboard layer of resin slip-increasing cyclization-resin slip, make resin slip soak into cyclization and mix.Plate material forming unit has upper and lower two cover slip coating devices, polyethylene film is emitted through scraper gluing table by releasing device, resin slip pours on film, in gluing edge of table, there is scraper, regulate the clearance height of scraper and table top to be frictioning thickness, the gap of scraper and table top is by micron setter minute adjustment.Two films are respectively by being transported on travelling belt after machine upper and lower coated with resin slip, strongthener is layered on above the resin slip of lower film, then double-layer films closes up, form the laminboard layer of resin slip-cyclization-resin slip, in plate material forming unit, a series of extrusion rolls are pinched and are rubbed work laminboard layer, make resin slip soak into cyclization and mix.
In sheet stock unit, carry out rolling and maturation process, the temperature of maturation process is 25 °, and the time of maturation process is 48 hours.
Embodiment six
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: terephthalic unsaturated polyester resin, Bisphenol a unsaturated polyester resin and totally 24 parts of vinyl ester type unsaturated polyester resins, 55 parts of glass microballons, peroxidized t-butyl perbenzoate and totally 8 parts of 1,1-bis-(t-butyl peroxy) hexanaphthenes, cobalt naphthenate and totally 3 parts of cobalt octoates, 3.5 parts of tertiarybutylhydroquinones, 18 parts of glassmats.
First by terephthalic unsaturated polyester resin, Bisphenol a unsaturated polyester resin and vinyl ester type unsaturated polyester resin are altogether, glass microballon, peroxidized t-butyl perbenzoate and 1, 1-bis-(t-butyl peroxy) hexanaphthene, cobalt naphthenate and cobalt octoate, tertiarybutylhydroquinone stirs and makes resin slip in stirring mechanism, the stirring mechanism of the use of the present embodiment is high speed dispersor, stirring work is carried out at normal temperatures, the time of stirring is until stir, in the time of the present embodiment test, whipping temp is 25 °, the time stirring is 40 minutes, at plate material forming machine, utilize resin slip to infiltrate glassmat, obtain the laminboard layer of resin slip-glassmat-resin slip, make resin slip soak into glassmat and mix.Plate material forming unit has upper and lower two cover slip coating devices, polyethylene film is emitted through scraper gluing table by releasing device, resin slip pours on film, in gluing edge of table, there is scraper, regulate the clearance height of scraper and table top to be frictioning thickness, the gap of scraper and table top is by micron setter minute adjustment.Two films are respectively by being transported on travelling belt after machine upper and lower coated with resin slip, glassmat is layered on above the resin slip of lower film, then double-layer films closes up, form the laminboard layer of resin slip-glassmat-resin slip, in plate material forming unit, a series of extrusion rolls are pinched and are rubbed work laminboard layer, make resin slip soak into glassmat and mix.
In sheet stock unit, carry out rolling and maturation process, the temperature of maturation process is 25 °, and the time of maturation process is 48 hours.
Embodiment seven
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: adjacent benzene type unsaturated polyester resin, metaphenylene unsaturated polyester resin and totally 23 parts of terephthalic unsaturated polyester resins, 40 parts of silicate microballons, 17 parts of totally 7 parts of methylethyl ketone peroxide and cyclohexanone peroxides, cobalt naphthenate and totally 2 parts of cobalt octoates, methyl hydroquinone, Resorcinol and totally 2.8 parts of para benzoquinone, trevira and cyclizations.
Embodiment eight
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 2.6 parts of 26.5 parts of vinyl ester type unsaturated polyester resins, 44 parts, aluminium hydroxide, BP and 0.5 part of peroxidized t-butyl perbenzoate, cobalt octoates, 2, totally 19 parts of 3.4 parts of 5-ditert-butylhydro quinones, carbon fiber and aramid fibers.
Embodiment nine
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: totally 25 parts, 21 parts of terephthalic unsaturated polyester resins, 54 parts, aluminum oxide, 7.8 parts of peroxidized t-butyl perbenzoates, 2.6 parts of Diethyl Anilines, 3.6 parts of Resorcinol, carbon fiber and aramid fiber, trevira.
Embodiment ten
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 22 parts of vinyl ester type unsaturated polyester resins, 35 parts, magnesium oxide, 6 parts of peroxidized t-butyl perbenzoates, 2.3 parts of dimethyl-p-toluidines, 2.5 parts of para benzoquinone, 17 parts of aramid fibers.
Embodiment 11
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 40 parts of 20 parts of Bisphenol a unsaturated polyester resins, magnesium hydroxide, 1,2.8 parts of 1.5 parts of 1-bis-(t-butyl peroxy) hexanaphthenes, cobalt naphthenate, 2,1.3 parts of 5-ditert-butylhydro quinones, 21 parts, carbon fiber.
Embodiment 12
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 30 parts of terephthalic unsaturated polyester resins, 37 parts of zirconium whites, 5.6 parts of peroxidized t-butyl perbenzoates, 2.2 parts of xylidines, 3 parts of Resorcinol, 14 parts of aramid fibers.
Embodiment 13
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 29 parts of metaphenylene unsaturated polyester resins, 55 parts of weisspiessglanzs, 7 parts of cyclohexanone peroxides, 2 parts of xylidines, 0.8 part of tertiarybutylhydroquinone, 13 parts, glass fibre.
Embodiment 14
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 23 parts of unsaturated polyester resins, 50 parts of talcum powder, 5 parts of methylethyl ketone peroxides, 2.4 parts of cobalt octoates, 0.5 part of para benzoquinone, 20 parts of glassmats.
Embodiment 15
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: 24 parts of Bisphenol a unsaturated polyester resins, calcium carbonate and 40 parts of Aluminum calcium silicates, 3 parts of benzoyl peroxides, 3 parts of cobalt octoates, 0.8 part of methyl hydroquinone, 15 parts, trevira.
Embodiment 16
The material component of the decorative wall brick of the present embodiment and the parts by weight of each component are: totally 26 parts of totally 25 parts of metaphenylene unsaturated polyester resin and terephthalic unsaturated polyester resins, glass microballon and silicate microballon, totally 45 parts of china clay, peroxidized t-butyl perbenzoate and totally 1 part of 1,1-bis-(t-butyl peroxy) hexanaphthene, cobalt octoate and totally 3 parts of xylidines, Resorcinol and totally 2.7 parts of para benzoquinone, glass fibre and glassmats.
Below by the contrast table of decorative wall brick of the present invention and existing decorative block, emulsion paint:
From upper table, can significantly find out, the contrast of wall brick of the present invention and prior art products, have that no color differnece, light weight, intensity are high, good toughness, resistance to chemical attack are strong, it is broken to be difficult for, manufacture conveniently, blowdown is few in process of production, use pollution-freely, also there is long service life, easy cleaned feature simultaneously; Can meet modern people to the demand of decorating, there is very large economic benefit simultaneously.
Claims (9)
1. a decorative wall brick, is characterized in that, the material component of described decorative wall brick and the parts by weight of each component are:
20-30 parts of unsaturated polyester resins;
30-60 parts of fillers;
0.5-10 parts of initiators;
2-3 parts of promotor;
0.1-4 parts of stoppers;
10-30 parts of strongtheners.
2. decorative wall brick according to claim 1, is characterized in that: described unsaturated polyester resin is one or more the combination in adjacent benzene type unsaturated polyester resin, metaphenylene unsaturated polyester resin, terephthalic unsaturated polyester resin, Bisphenol a unsaturated polyester resin or vinyl ester type unsaturated polyester resin.
3. decorative wall brick according to claim 1, is characterized in that: described filler is one or more the combination in calcium carbonate, Aluminum calcium silicate, barium sulfate, miemite, china clay, glass microballon, silicate microballon, aluminium hydroxide, aluminum oxide, magnesium oxide, magnesium hydroxide, zirconium white, weisspiessglanz or talcum powder.
4. decorative wall brick according to claim 1, it is characterized in that: described initiator is one or more the combination in benzoyl peroxide, methylethyl ketone peroxide, cyclohexanone peroxide, peroxidized t-butyl perbenzoate or 1,1-bis-(t-butyl peroxy) hexanaphthene.
5. decorative wall brick according to claim 1, is characterized in that: described promotor is one or more the combination in cobalt naphthenate, cobalt octoate, xylidine, Diethyl Aniline or dimethyl-p-toluidine.
6. decorative wall brick according to claim 1, is characterized in that: described stopper is Resorcinol, para benzoquinone, tertiarybutylhydroquinone, 2, the combination of one or more in 5-ditert-butylhydro quinone or methyl hydroquinone.
7. decorative wall brick according to claim 1, is characterized in that: described strongthener is one or more the combination in glass fibre/felt, carbon fiber, aramid fiber, trevira or cyclization.
8. according to the preparation method of the arbitrary described decorative wall brick of claim 1-7, it is characterized in that, comprise the following steps:
(1) batching: unsaturated polyester resin, filler and auxiliary agent are prepared burden according to above-mentioned parts by weight;
(2) stir: the batching in (1) is stirred in stirring mechanism, make resin slip;
(3) infiltrate: at plate material forming machine, utilize resin slip to infiltrate strongthener, obtain the laminboard layer of resin slip-strongthener-resin slip, make resin slip soak into strongthener and mix;
(4) rolling: rolling in sheet stock unit;
(5) maturation process: carry out maturation process in sheet stock unit, the temperature of described maturation process is 25 °-30 °, and the time of maturation process is 10-48 hours;
(6) compression moulding: pass through mould compression moulding in thermocompressor or vacuum hotpressing machine.
9. the preparation method of decorative wall brick according to claim 8, is characterized in that: described stirring mechanism is high speed dispersor, and the temperature stirring in high speed dispersor is 25 ℃-35 ℃, and the time of stirring is 30-40 minute.
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