CN103478894A - Camellia extract composition with spicy fragrance and application of same to cigarettes - Google Patents
Camellia extract composition with spicy fragrance and application of same to cigarettes Download PDFInfo
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- CN103478894A CN103478894A CN201310446696.6A CN201310446696A CN103478894A CN 103478894 A CN103478894 A CN 103478894A CN 201310446696 A CN201310446696 A CN 201310446696A CN 103478894 A CN103478894 A CN 103478894A
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Abstract
The invention relates to a camellia extract composition with spicy fragrance and application of the composition serving as a cigarette additive to cigarettes. The camellia extract composition is prepared from camellia extract and spice. After the camellia extract composition with the spicy fragrance is added into the cigarettes, fragrance of the cigarettes is harmonious, unique fragrance of the cigarettes is enhanced, the spicy fragrance is enhanced, cigarette flavor is enabled to be richer and more natural, richness, sense of thickness and mellowness of the cigarette fragrance are improved, smokers smoking the cigarettes can feel nature and relaxed, offensive odor and stimulation are reduced, and overall smoking quality is improved.
Description
Technical field
The invention belongs to the tobacco spice technical field, relate to a kind of have the Tea Flower extractive composition of hot note and the application in cigarette thereof.
Background technology
Essence and flavoring agent is widely used in the fields such as tobacco, food, daily use chemicals, and natural perfume material forms complexity due to it, and fragrance is abundant, fragrance remaining time is the indispensable raw material of preparing essence lastingly.
International tobacco business is paid much attention to the development and application of essence spice for cigarette, and the technology of the high-quality essence and flavoring agent of production application is used as to the core technology of oneself.Along with the technological progress of tobacco business with greatly develop the proposition of Chinese-style cigarette target, the essence spice for cigarette technology is as the important core technology of tobacco business, as forming the Chinese-style cigarette quality characteristic, making one of key of Chinese-style cigarette core technology.Essence and flavoring agent can be given the style and features of cigarette product uniqueness, improves the suction quality of cigarette product, is one of important connotation of constructing the Chinese-style cigarette core competitiveness.Still there is certain deficiency in current domestic cigarette product at aspects such as style and features and suction qualities, and the Application and Development of novel essence spice for cigarette is an important solution route.
There is abundant natural perfume material resource in China, approximately has more than 500 kind fragrant plants to be distributed widely in 20 provinces and cities, yet only has minority to be exploited, and exist the problems such as level of processing is low, application technology is single.
Tea tree (Camellia sinensis) is the Theaceae Camellia Plants, and its cultivation has had history in thousand, and in China, distributed pole is wide.Tea Flower is very abundant as the accessory substance resource in the Tea Production process.Tea Flower has the advantages that the florescence is long, the amount of blooming is large and fragrance is fresh and sweet, has high value of exploiting and utilizing.In recent years, the comprehensive utilization of Tea Flower is more and more paid attention to.
Tea Flower is rich in multiple beneficial composition and the active materials such as protein, Tea Polyphenols, tea polysaccharide, Tea Saponin, flavonoids, amino acid, vitamin, trace element and superoxide dismutase (SOD), theobromine, has hypoglycemic, reducing blood lipid, anticoagulant, antithrombotic, nourishing, beauty treatment and the effect such as anticancer.Tea Flower contains number of chemical material and fragrance component.The fragrance component of Tea Flower is mainly alcohols, ester class, aldehydes and lower alkyl hydro carbons material, and wherein the relative amount of acetophenone, 2-enanthol, phthalic acid two (2-ethylhexyl) ester, linalool is higher.The Tea Flower essence fragrance prepared by the Tea Flower extract is fresh and clean, and sweet spiciness is strongly fragrant, has higher potential using value.
Hot spices is with the fresh and sweet rhythm of the fragrance of a flower, the hot sweet and clear dense warm fragrance of a flower, head is fragrant have the banksia rose and the Xin Xiang that gentleness is fresh, end rhythm have sweet and in the fragrance of a flower and cream perfume (or spice), dense and lasting.Hot spices has makes a perfumed ribbon that feeling of freshness be arranged, natural sense, and in mediation essence, fragrance rushes thick raw material fragrance, can make whole fragrance flavouring, and make its many rhythms.
Have no at present by the flavor compositions of Tea Flower extract and Xin Xiang flavor confect and the application in cigarette thereof.
Goal of the invention of the present invention is to provide a kind of Tea Flower extractive composition with hot note, and said composition application in cigarette as cigarette additive, for sucking quality and the sense organ comfort level of improving cigarette.
Summary of the invention
It is primary raw material that the inventor adopts the Tea Flower extract, adds and has the fragrant spices of suffering (as clove bud oil, ginger oil, extract of cinnamomum cassia bark, eugenol, coriander extract, fennel seeds wet goods) of natural equivalent composition of stronger hamony formulated to Tea Flower.The graceful nature of said composition fragrance, fresh many rhythms, with the graceful breath of hot note.
A first aspect of the present invention provides a kind of Tea Flower extractive composition, by Tea Flower extract and hot fragrant flavor confect, formed, wherein said suffering spices be selected from that carrot seed oil, clove bud oil, aniseed oil, ennel oil, ginger oil, coriander extract, cumal, β-China pink are rare, one or more in eugenol, sage clary oil, radix valerianae extract, extract of cinnamomum cassia bark, radix tarxaci extract.
According to the described composition of first aspect present invention, wherein said Tea Flower extract is selected from Tea Flower medicinal extract, essential oil of the flower of Camellia sinensis, Tea Flower absolute oil, Tea Flower tincture or its combination.
According to the described composition of first aspect present invention, in a specific embodiment, wherein said suffering spices is that clove bud oil, ennel oil, coriander extract, β-China pink are rare, eugenol and extract of cinnamomum cassia bark.
According to the described composition of first aspect present invention, the preparation method of wherein said Tea Flower medicinal extract, Tea Flower absolute oil and/or Tea Flower tincture comprises the step of the raw material Tea Flower being carried out to the super-pressure extraction.
According to the described composition of first aspect present invention, in a specific embodiment, the preparation method of described Tea Flower tincture, Tea Flower medicinal extract and/or Tea Flower absolute oil comprises following step (1), step (1)-(2) or step (1)-(3):
(1) super-pressure extracts: take a certain amount of Tea Flower and put into the super-pressure extractor, the edible alcohol that adds at least 2 times of (w/w) Tea Flower weight, carry out the super-pressure extraction, obtain Tea Flower tincture 1, the concentration of wherein said edible alcohol is the 20-70%(mass concentration); Preferably, the 1/5-1/10 that Tea Flower tincture 1 is concentrated into to original volume obtains Tea Flower tincture 2;
(2) prepare Tea Flower medicinal extract: the Tea Flower tincture 1 or the Tea Flower tincture 2 that obtain in step (1) are further concentrated, obtain Tea Flower medicinal extract;
(3) prepare the Tea Flower absolute oil: the Tea Flower medicinal extract obtained by a certain amount of 95% ethanol back dissolving step (2), then carry out freezing processing (for example-10 ℃ to-20 ℃), cooling time is that 16-48h(is preferably 20-36h) then filter, concentrated, obtain the Tea Flower absolute oil.
In the present invention, freezing temperature can be-10 ℃ to-20 ℃.
In a specific embodiment, in the preparation method of above-mentioned Tea Flower medicinal extract, Tea Flower absolute oil and/or Tea Flower tincture, in step (1), described is that adopted Tea Flower is Tea Flower fresh flower, dried flower, spray Ethanol Treatment Tea Flower, saline sook Tea Flower or alcohol immersion Tea Flower.
In a specific embodiment, in the preparation method of above-mentioned Tea Flower medicinal extract, Tea Flower absolute oil and/or Tea Flower tincture, in step (1), add at least edible alcohol of 2-15 times of (w/w) Tea Flower weight, be preferably 2-10 doubly, 2-8 doubly, 3-8 doubly (w/w), 4-7 doubly (w/w) more preferably, for example 4 times, 5 times, 6 times or 7 times (w/w).
In a specific embodiment, in the preparation method of above-mentioned Tea Flower tincture, Tea Flower medicinal extract and/or Tea Flower absolute oil, in step (1), particularly, the concentration of described edible alcohol is the 20-70%(mass concentration), 20-40%, 20-50%, 40-50%, 50-70%, 20%, 30%, 40%, 50%, 60%, 70%.
In a specific embodiment, in the preparation method of above-mentioned Tea Flower medicinal extract, Tea Flower absolute oil and/or Tea Flower tincture, in step (1), release immediately after super-pressure extracts.
In a specific embodiment, in the preparation method of above-mentioned Tea Flower tincture, Tea Flower medicinal extract and/or Tea Flower absolute oil, in step (1), the pressure of described super-pressure is 150-500Mpa; Particularly, be 150-250Mpa, 150-300Mpa, 250-300Mpa, 250-350Mpa, 250-500Mpa, 300-350Mpa, 300-500Mpa, 350-500Mpa, 150Mpa, 200Mpa, 250Mpa, 300Mpa, 350Mpa, 400Mpa, 450Mpa, 500Mpa etc.
In a specific embodiment, in the preparation method of above-mentioned Tea Flower tincture, Tea Flower medicinal extract and/or Tea Flower absolute oil, in step (1), dwell time is 5-120min, be preferably 5-60min, 10-30min more preferably, such as 10-15min, 10-20min, 10-25min, 15-20min, 15-25min, 15-30min, 20-25min, 20-30min, 25-30min, 10min, 15min, 20min, 25min, 30min etc.
In a specific embodiment, in the preparation method of above-mentioned Tea Flower medicinal extract, Tea Flower absolute oil and/or Tea Flower tincture, concentrating in step (1) or (2) can be the method that those skilled in the art know, for example suction filtration is concentrated.
According to the described composition of first aspect present invention, in a specific embodiment, the preparation method of wherein said essential oil of the flower of Camellia sinensis is the reduced steam way of distillation.
According to the described composition of first aspect present invention, in a specific embodiment, the preparation method of described essential oil of the flower of Camellia sinensis, comprise the steps:
(1) take a certain amount of Tea Flower pack into be furnished with the trapping cold-trap the decompression extraction element in;
(2) add the water of at least 5 times of Tea Flower weight, and the temperature of the water added is more than 80 ℃, at least 5min is soaked in sealing, is cooled to 30-70 ℃;
(3-1) carry out the reduced steam distillation, temperature used is identical with cooled temperature in step (2), and vacuum is 1-17kpa, collects distillate;
Preferably, also comprise step (3-2): repeating step (2) and (3-1) in operation 1 time or repeatedly, and merge distillate;
(4) in the use, low polar organic solvent carries out 1 time the distillate obtained in step (3-1) or step (3-2) or repeatedly back extraction (for example 2,3,4 or 5 times, preferably 3 times), obtains stripping workshop; Stripping workshop is concentrated, obtained concentrate;
(5) use concentrate weight 2-4 absolute ethyl alcohol doubly to carry out backwash to the concentrate obtained in step (4), reduced pressure concentration remove wherein residual in after low polar organic solvent essential oil of the flower of Camellia sinensis.
In a specific embodiment, in the preparation method of above-mentioned essential oil of the flower of Camellia sinensis, described in step (1), be that adopted Tea Flower is Tea Flower fresh flower, dried flower, spray Ethanol Treatment Tea Flower, saline sook Tea Flower or alcohol immersion Tea Flower.
In a specific embodiment, in the preparation method of above-mentioned essential oil of the flower of Camellia sinensis, the 5-50 that the amount of the water added in step (2) is Tea Flower weight doubly, be preferably 5-40 times or 8-40 times, more preferably 10-30 doubly, for example 10-15 doubly, 10-20 doubly, 10-25 doubly, 15-20 doubly, 15-25 doubly, 15-30 doubly, 20-25 doubly, 20-30 doubly, 10 times, 11 times, 12 times, 13 times, 14 times, 15 times, 16 times, 17 times, 18 times, 19 times, 20 times, 21 times, 22 times, 23 times, 24 times, 25 times, 26 times, 27 times, 28 times, 29 times or 30 times.
In a specific embodiment, in the preparation method of above-mentioned essential oil of the flower of Camellia sinensis, the temperature of the water added in step (2) is preferably more than 85 ℃, more preferably more than 90 ℃, more preferably more than 95 ℃, for example 95 ℃, 96 ℃, 97 ℃, 98 ℃, 99 ℃, preferably 100 ℃; Particularly preferably, the water added is boiling water.Be immersed under normal pressure and carry out, the temperature of the boiling water of immersion is generally 100 ℃, and those skilled in the art know, according to atmospheric difference, boiling point is different.
In a specific embodiment, in the preparation method of above-mentioned essential oil of the flower of Camellia sinensis, the time that in step (2), sealing is soaked is 5min-4h, be preferably 5min-4h, 5min-3h or 5min-2h, more preferably 5-60min, 5-50min or 5-40min, be particularly preferably 5-30min, for example 5-18min, 5-20min, 5-25min or 18-30min.
In a specific embodiment, in the preparation method of above-mentioned essential oil of the flower of Camellia sinensis, step is cooled to 30-70 ℃ in (2), for example 30-40 ℃, 30-50 ℃, 30-60 ℃, 40-50 ℃, 45-55 ℃, 40-60 ℃, 40-70 ℃, 50-60 ℃, 50-70 ℃ or 60-70 ℃.
Those skilled in the art know, and vacuum is corresponding to a certain extent with vapo(u)rizing temperature, need to guarantee to allow distilled water and aroma component in cucurbit steam under giving fixed temperature and vacuum.
Be not limited to theoretical restriction, temperature is lower, and required vacuum is less, and temperature is higher, and required vacuum is larger.Inventor's discovery, when temperature is 30 ℃, vacuum 2.5kpa; Can be faster than the little speed distilled of 2.5kpa; When temperature is 70 ℃, vacuum 17kpa; Can be faster than the little speed distilled of 17kpa.
Be not limited to theoretical restriction, on the other hand, under the prerequisite of Temperature Setting, if vacuum is too low, may cause bumping, make to extract pot liquid and go out; If vacuum is too high, may make to extract the pot liquid distillation not out, do not have the effect of decompression distillation.Therefore, the corresponding proper vacuum ranges of each temperature value.
Therefore, about step (3-1) or the vacuum of reduced steam (3-2) distillation, those skilled in the art can be set according to the theory above selected temperature reference or this area knowledge, also can be with reference to following vacuum ranges, or adjusted on this basis:
For example 1-12kPa, 1-10kPa, 1-9.5kPa, 1-9kPa, 1-8.5kPa, 1-8kPa, 1-7.5kPa or 1-7kPa, 2.5-7kPa for example, 1-2kPa, 1-3kPa, 1-4kPa, 1-5kPa, 1-6kPa, 2-3kPa, 2-4kPa, 2-5kPa, 2-6kPa, 2-7kPa, 3-4kPa, 3-5kPa, 3-6kPa, 3-7kPa, 4-5kPa, 4-6kPa, 4-7kPa, 5-6kPa, 5-7kPa, 6-7kPa, 6-12kPa, 8-12kPa, 10-12kPa, 1kPa, 2kPa, 3kPa, 4kPa, 5kPa, 6kPa, 7kPa, 8kPa, 9kPa, 10kPa, 11kPa or 12kPa.
In a specific embodiment, in the preparation method of above-mentioned essential oil of the flower of Camellia sinensis, in step (4), described in low polar organic solvent be to be selected from any one in absolute ether and ethyl acetate; Ethyl acetate.In described, the consumption of low polar organic solvent can be the 1/4-1/3 of distillate volume.
In a specific embodiment, in the preparation method of above-mentioned essential oil of the flower of Camellia sinensis, the decompression extraction element used can be to be commercially available, or preferably uses the decompression extraction element in the Chinese patent application that publication number is 101920127A (application number is 200910111996.2).
In a specific embodiment, the described composition of first aspect present invention, wherein said Tea Flower extract is Tea Flower medicinal extract.
In a specific embodiment, the described composition of first aspect present invention, wherein the content of each component, in weight portion, is respectively:
Tea Flower medicinal extract 10-30, be preferably 15-25 or 18-22, and more preferably 20;
Clove bud oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Ennel oil 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Coriander extract 0.02-0.08, be preferably 0.03-0.07 or 0.04-0.06, and more preferably 0.05;
The rare 0.05-0.15 of β-China pink, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Eugenol 0.1-0.3, be preferably 0.15-0.25 or 0.18-0.22, and more preferably 0.2;
Extract of cinnamomum cassia bark 0.2-0.3, be preferably 0.22-0.28 or 0.24-0.26, and more preferably 0.25.
In a specific embodiment, the described composition of first aspect present invention, wherein said suffering spices is carrot seed oil, aniseed oil, ginger oil, sage clary oil, radix valerianae extract, extract of cinnamomum cassia bark, radix tarxaci extract.
In a specific embodiment, the described composition of first aspect present invention, wherein said Tea Flower extract is essential oil of the flower of Camellia sinensis.
In a specific embodiment, the described composition of first aspect present invention, wherein the content of each component, in weight portion, is respectively:
Essential oil of the flower of Camellia sinensis 5-15, be preferably 8-12 or 9-11, and more preferably 10;
Carrot seed oil 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Aniseed oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Ginger oil 0.02-0.08, be preferably 0.03-0.07 or 0.04-0.06, and more preferably 0.05;
Sage clary oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Radix valerianae extract 0.2-0.8, be preferably 0.3-0.7 or 0.4-0.6, and more preferably 0.55;
Extract of cinnamomum cassia bark 0.2-0.3, be preferably 0.22-0.28 or 0.24-0.26, and more preferably 0.25;
Radix tarxaci extract 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15.
In a specific embodiment, the described composition of first aspect present invention, wherein said suffering spices is that carrot seed oil, aniseed oil, ginger oil, β-China pink are rare, radix valerianae extract, extract of cinnamomum cassia bark, radix tarxaci extract.
In a specific embodiment, the described composition of first aspect present invention, wherein said Tea Flower extract is the Tea Flower absolute oil.
In a specific embodiment, the described composition of first aspect present invention, wherein the content of each component, in weight portion, is respectively: Tea Flower absolute oil 15-35 is preferably 20-30 or 22-28, more preferably 25;
Carrot seed oil 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Aniseed oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Ginger oil 0.02-0.08, be preferably 0.03-0.07 or 0.04-0.06, and more preferably 0.05;
The rare 0.1-0.2 of β-China pink, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Radix valerianae extract 0.2-0.8, be preferably 0.3-0.7 or 0.4-0.6, and more preferably 0.55;
Extract of cinnamomum cassia bark 0.2-0.3, be preferably 0.22-0.28 or 0.24-0.26, and more preferably 0.25;
Radix tarxaci extract 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15.
In a specific embodiment, the described composition of first aspect present invention, wherein said suffering spices is that clove bud oil, aniseed oil, ennel oil, β-China pink are rare, sage clary oil, extract of cinnamomum cassia bark, radix tarxaci extract.
In a specific embodiment, the described composition of first aspect present invention, wherein said Tea Flower extract is the Tea Flower tincture.
In a specific embodiment, the described composition of first aspect present invention, wherein the content of each component, in weight portion, is respectively: Tea Flower tincture 20-40 is preferably 25-35 or 28-32, more preferably 30;
Clove bud oil 0.02-0.08, be preferably 0.03-0.07 or 0.04-0.06, and more preferably 0.05;
Aniseed oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Ennel oil 0.02-0.08, be preferably 0.03-0.07 or 0.04-0.06, and more preferably 0.05;
The rare 0.1-0.2 of β-China pink, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Sage clary oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Extract of cinnamomum cassia bark 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Radix tarxaci extract 0.2-0.3, be preferably 0.22-0.28 or 0.24-0.26, and more preferably 0.25.
According to the described composition of first aspect present invention any one, also comprise ethanol in said composition, preferred 50～95% ethanol water, further preferred 60～80% ethanol water, more preferably 65～75% ethanol water, be particularly preferably 70% ethanol water;
Preferably, the weight portion content of ethanol or ethanol water is 60-90, is preferably 75-80,85-90,70-75 or 65-70.
The described composition of first aspect present invention any one can be used as cigarette additive, particularly as the purposes of cigarette flavors.The addition manner of said composition is: use ethanol or ethanol water to dissolve described composition, being mixed with perfuming solution evenly is sprayed onto in pipe tobacco, perhaps will contain ethanol or ethanol water the composition Direct Uniform be sprayed onto in pipe tobacco, perfuming solution or contain ethanol or the concrete usage ratio of the composition of ethanol water is tobacco quality 0.005～0.05%.
A second aspect of the present invention provides the purposes of composition in cigarette of first aspect present invention any one, preferably as the purposes of cigarette additive, particularly preferably as the purposes of cigarette flavors;
Preferably, said composition can be for the internal lining paper of pipe tobacco, thin slice, cigarette, filter stick etc.
A third aspect of the present invention provides a kind of cigarette, and it comprises the described composition of first aspect present invention any one,
Preferably, described composition is the composition that contains ethanol water;
Preferably, the consumption of the described composition that contains ethanol water is 0.005～0.05% of pipe tobacco weight.
Detailed Description Of The Invention
The various terms and the phrase that in the present invention, use have the general sense of well known to a person skilled in the art, but special definition is arranged in this article, with implication as defined herein, is as the criterion.
In the present invention, " tea tree " in described " Tea Flower ", if not otherwise specified, refer to the plant of Theales (Theales), Theaceae (Theaceae) or Camellia (Camellis);
In one aspect of the invention, " flower " in described " Tea Flower " comprising: perianth, oecium, gynoecium.Perianth comprises: calyx (being comprised of sepal), corolla (being comprised of petal).The color of flower and fragrance are from corolla.Stamen comprises: filigree and flower pesticide.Gynoecium comprises: column cap, style and ovary.
In one aspect of the invention, term " Tea Flower ", can be fresh flower, can be also dry flower; If there is no specified otherwise, it refers to the part of complete Tea Flower or Tea Flower; It at least comprises petal; Alternatively, also comprise and be selected from one or more in sepal, stamen and gynoecium.
In the present invention, described Tea Flower extract includes but not limited to: essential oil of the flower of Camellia sinensis, Tea Flower tincture, Tea Flower medicinal extract and/or Tea Flower absolute oil; Alternatively, it also comprises auxiliary material (carrier, solvent, pigment, antioxidant, anticorrisive agent, humectant, fumet etc.).
Tea Flower described in the present invention extracts can pass through the normal temperature lixiviate, heating and refluxing extraction, Soxhlet is extracted, ultrasonic auxiliary extraction, microwave auxiliary extraction, the enzyme process auxiliary extraction, accelerated solvent extraction, supercritical fluid extraction, the while distillation extraction, steam distillation, the combination of any one or a few method of decompression distillation etc. is prepared from, also can (for example: Australia China reaches international fragrance (Guangzhou) Co., Ltd by commercially available, Huabao Edible Essence & Condiment (Shanghai), Hangzhou prompt quick essence and flavoring agent Co., Ltd, Shenzhen GuanLiDa BoDun spice Co., Ltd).
The separation method that described Tea Flower extracts can be the combination of any one or a few method of isolated by filtration, centrifugation, film separation, molecular clock, column chromatography, chromatographic isolation etc.
Term " tincture " or " tincture " refer to uses certain density ethanol, lixiviate spice berry organ or exudate and secrete fragrant animal containing fragrant organ or its containing the resulting aroma material preparation that contains some ethanol of fragrant secretion.Under normal temperature, be worth tincture to be called " cold process tincture "; The tincture made under the heating counterflow condition is called " hot method tincture "." Tea Flower tincture " used in the present invention can, by commercially available, also can prepare by various conventional methods.
In one embodiment of the invention, described " Tea Flower tincture " can prepare by the following method:
(1) described Tea Flower includes but not limited to fresh Tea Flower, dried flower, alcohol immersion processing Tea Flower, spray Ethanol Treatment Tea Flower etc.;
(2) super-pressure extracts: take the certain quantity of fresh Tea Flower and put into the super-pressure extractor, add the edible alcohol that 7 times of concentration to Tea Flower weight are 20%, carry out release immediately after the super-pressure extraction; The pressure of described super-pressure is: 150MPa, dwell time: 30min;
(3) the 1/5-1/10 that the extract in step (2) is carried out after suction filtration being concentrated into original volume obtains the Tea Flower tincture.
Term " essential oil ", in broad terms, essential oil refers to from spice berry and secretes the general name of the organ of fragrant animal, passing through the resulting volatility fragrant containing substance goods of processing extraction, in the narrow sense, essential oil only refers to the goods of water steam distillation method, milling process, cold grinding method or cracking process prepared fragrant containing substance from spice berry organ (as flower, leaf, branch, skin, scapus, root, fruit, seed etc.).In actual applications, often adopt its narrow sense." essential oil of the flower of Camellia sinensis " used in the present invention can, by commercially available, also can prepare by various conventional methods.
In one embodiment of the invention, described " essential oil of the flower of Camellia sinensis " can prepare by the following method:
(1) take the certain quantity of fresh Tea Flower and pack in the decompression extraction element, add the boiling water of 30 times of Tea Flower weight, sealing is cooled to 70 ℃ after soaking 30min;
(2) carry out the reduced steam distillation on the decompressor of being furnished with the trapping cold-trap, temperature is: 70 ℃, vacuum is: 12kpa, collect distillate;
(3) boiling water that 25 times of Tea Flower weight are added in decompression distillation after complete is collected liquid to repeating twice rear merging of decompression distillation according to step (3) in extraction element;
(4) add 0.3 times and collect the long-pending ethyl acetate back extraction of liquid three times, merge stripping workshop and be concentrated into 1/10 of fresh Tea Flower weight; ;
(5) essential oil of the flower of Camellia sinensis is refining: the absolute ethyl alcohol that adds 3 times of the middle concentrates of step (4) carries out backwash, and reduced pressure concentration is removed wherein and obtained essential oil of the flower of Camellia sinensis after residual ethyl acetate.
Term " medicinal extract ", in a broad sense, medicinal extract refers to organic solvent extraction spice berry organ or its exudate (as resin, natural gum, balm), removes solvent for use and the general designation of the aroma material preparation that obtains.From narrowly, medicinal extract only refers to organic solvent extraction spice berry organ resulting not containing the aroma material preparation of solvent for use and moisture." Tea Flower medicinal extract " used in the present invention can, by commercially available, also can prepare by various conventional methods.
In one embodiment of the invention, described " Tea Flower medicinal extract " can prepare by the following method:
(1) described Tea Flower includes but not limited to fresh Tea Flower, dried flower, alcohol immersion processing Tea Flower, spray Ethanol Treatment Tea Flower etc.;
(2) super-pressure extracts: take the certain quantity of fresh Tea Flower and put into the super-pressure extractor, 4 times of concentration to Tea Flower weight are 40% edible alcohol, carry out release immediately after the super-pressure extraction; The pressure of described super-pressure is: 500MPa, dwell time: 10min;
(3) the 1/5-1/10 that the extract in step (2) is carried out after suction filtration being concentrated into original volume obtains the Tea Flower tincture;
(4) prepare Tea Flower medicinal extract: the Tea Flower tincture continuation obtained in step (3) is concentrated and can obtain Tea Flower medicinal extract.
Term " absolute oil ", in a broad sense, refer to the solution that extracts the fragrant composition in medicinal extract, botany bar gum, balm or face cream with high concentration ethanol, through freezing processing, the elimination insoluble matter, then after pressure reducing and steaming ethanol the general designation of the aroma material preparation of gained." Tea Flower absolute oil " used in the present invention can, by commercially available, also can prepare by various conventional methods.
In one embodiment of the invention, described " Tea Flower absolute oil " can prepare by the following method:
(1) described Tea Flower includes but not limited to fresh Tea Flower, dried flower, alcohol immersion processing Tea Flower, spray Ethanol Treatment Tea Flower etc.;
(2) super-pressure extracts: take the certain quantity of fresh Tea Flower and put into the super-pressure extractor, 5 times of concentration to Tea Flower weight are 70% edible alcohol, carry out release immediately after the super-pressure extraction; The pressure of described super-pressure is: 300MPa, dwell time: 20min;
(3) the 1/5-1/10 that the extract in step (2) is carried out after suction filtration being concentrated into original volume obtains the Tea Flower tincture;
(4) prepare Tea Flower medicinal extract: the Tea Flower tincture continuation obtained in step (3) is concentrated and can obtain Tea Flower medicinal extract;
(5) prepare the Tea Flower absolute oil: with a certain amount of 95% ethanol back dissolving Tea Flower medicinal extract, for example, after freezing (-10 ℃ to-20 ℃) 24-48h, filter, concentrated, obtain the Tea Flower absolute oil.
In the present invention, various suffering spices (for example carrot seed oil, clove bud oil, aniseed oil, ennel oil, ginger oil, coriander extract, cumal, β-China pink are rare, eugenol, sage clary oil, radix valerianae extract, extract of cinnamomum cassia bark, radix tarxaci extract) all can be by commercially available, such as: Australia China, reaches the fragrant spices of various sufferings that prompt quick essence and flavoring agent Co., Ltd of international fragrance (Guangzhou) Co., Ltd, Huabao Edible Essence & Condiment (Shanghai), Hangzhou, Shenzhen GuanLiDa BoDun spice Co., Ltd etc. provide.
The beneficial effect of the invention
The graceful nature of Tea Flower extractive composition fragrance with hot note provided by the invention, fresh many rhythms, with the graceful breath of hot note, can be widely used in tobacco, food and household chemicals field etc.
Sensory evaluating smoking's result shows: add the Tea Flower extractive composition with hot note provided by the invention in cigarette after, make the cigarette flavor harmony, improve the distinctive fragrance of tobacco leaf, increase hot note, make the more lush nature of cigarette perfume (or spice), promote the rich of cigarette flavor, make the more lush nature of cigarette perfume (or spice), improved the solid sense of cigarette flavor, increase the mellow and full property of cigarette flavor, the person experiences naturally easily to bring the cigarette smoking, and assorted gas, stimulation reduce, and whole sucking quality is improved.
Tea Flower extractive composition with hot note provided by the invention is joined in cigarette, do not change cigarette original performance, do not change the original processing technology of cigarette, improved the flavouring essence quality of cigarette, and improved sucking quality and the sense organ comfort level of cigarette, therefore have more the meaning and value of actual production.
The specific embodiment
Below in conjunction with embodiment, embodiment of the present invention are described in detail, but it will be understood to those of skill in the art that the following example is only for the present invention is described, and should not be considered as limiting scope of the present invention.Unreceipted actual conditions person in embodiment, carry out according to the condition of normal condition or manufacturer's suggestion.The unreceipted person of production firm of component used, being can be by the conventional products of commercial acquisition.
The Tea Flower tincture of using in following embodiment prepares by the following method:
(1) raw material: fresh Tie Guanyin tea plant flower, clovershrub Tea Flower, Chinese cassia tree Tea Flower or narcissus Tea Flower;
(2) super-pressure extracts: take the certain quantity of fresh Tea Flower and put into the super-pressure extractor, add the edible alcohol that 7 times of concentration to Tea Flower weight are 20%, carry out release immediately after the super-pressure extraction; The pressure of described super-pressure is: 150MPa, dwell time: 30min;
(3) the 1/5-1/10 that the extract in step (2) is carried out after suction filtration being concentrated into original volume obtains kwan-yin Tea Flower tincture, clovershrub Tea Flower tincture, Chinese cassia tree Tea Flower tincture or narcissus Tea Flower tincture.
The essential oil of the flower of Camellia sinensis of using in following embodiment prepares by the following method:
(1) take certain quantity of fresh Tea Flower (fresh Tie Guanyin tea plant flower, clovershrub Tea Flower, Chinese cassia tree Tea Flower or narcissus Tea Flower) and pack in the decompression extraction element, add the boiling water of 30 times of Tea Flower weight, sealing is cooled to 70 ℃ after soaking 30min;
(2) carry out the reduced steam distillation on the decompressor of being furnished with the trapping cold-trap, temperature is: 70 ℃, vacuum is: 12kpa, collect distillate;
(3) boiling water that 25 times of Tea Flower weight are added in decompression distillation after complete is collected liquid to repeating twice rear merging of decompression distillation according to step (3) in extraction element;
(4) add 0.3 times and collect the long-pending ethyl acetate back extraction of liquid three times, merge stripping workshop and be concentrated into 1/10 of fresh Tea Flower weight; ;
(5) essential oil of the flower of Camellia sinensis is refining: the absolute ethyl alcohol that adds 3 times of the middle concentrates of step (4) carries out backwash, and reduced pressure concentration is removed wherein and obtained Tie Guanyin tea plant flower essential oil, clovershrub essential oil of the flower of Camellia sinensis, Chinese cassia tree essential oil of the flower of Camellia sinensis or narcissus essential oil of the flower of Camellia sinensis after residual ethyl acetate.
The Tea Flower medicinal extract of using in following embodiment prepares by the following method:
(1) raw material: fresh Tie Guanyin tea plant flower, clovershrub Tea Flower, Chinese cassia tree Tea Flower or narcissus Tea Flower;
(2) super-pressure extracts: take the certain quantity of fresh Tea Flower and put into the super-pressure extractor, 4 times of concentration to Tea Flower weight are 40% edible alcohol, carry out release immediately after the super-pressure extraction; The pressure of described super-pressure is: 500MPa, dwell time: 10min;
(3) the 1/5-1/10 that the extract in step (2) is carried out after suction filtration being concentrated into original volume obtains the Tea Flower tincture;
(4) prepare Tea Flower medicinal extract: the Tea Flower tincture continuation obtained in step (3) is concentrated and can obtain Tie Guanyin tea plant flower concrete, clovershrub Tea Flower medicinal extract, Chinese cassia tree Tea Flower medicinal extract or narcissus tea tree flower concrete.
The Tea Flower absolute oil of using in following embodiment prepares by the following method:
(1) raw material: fresh Tie Guanyin tea plant flower, clovershrub Tea Flower, Chinese cassia tree Tea Flower or narcissus Tea Flower;
(2) super-pressure extracts: take the certain quantity of fresh Tea Flower and put into the super-pressure extractor, 5 times of concentration to Tea Flower weight are 70% edible alcohol, carry out release immediately after the super-pressure extraction; The pressure of described super-pressure is: 300MPa, dwell time: 20min;
(3) the 1/5-1/10 that the extract in step (2) is carried out after suction filtration being concentrated into original volume obtains the Tea Flower tincture;
(4) prepare Tea Flower medicinal extract: the Tea Flower tincture continuation obtained in step (3) is concentrated and can obtain Tea Flower medicinal extract;
(5) prepare the Tea Flower absolute oil: with a certain amount of 95% ethanol back dissolving Tea Flower medicinal extract, for example, after freezing (-10 ℃ to-20 ℃) 24-48h, filter, concentrated, obtain Tie Guanyin tea plant extrait, clovershrub Tea Flower absolute oil, Chinese cassia tree Tea Flower absolute oil or narcissus tea tree extrait.
The ethanol of using in following embodiment reaches international fragrance (Guangzhou) Co., Ltd, SC3005 purchased from Australia China; Carrot seed oil, aniseed oil, ennel oil, extract of cinnamomum cassia bark reach international fragrance (Guangzhou) Co., Ltd purchased from Australia China; Clove bud oil, cumal, β-China pink are rare, the radix tarxaci extract is purchased from Huabao Edible Essence & Condiment (Shanghai); Coriander extract, eugenol are purchased from Hangzhou prompt quick essence and flavoring agent Co., Ltd; Ginger oil, sage clary oil, radix valerianae extract are purchased from Shenzhen GuanLiDa BoDun spice Co., Ltd.
Sensory evaluating smoking in following embodiment experiment by the sensory evaluating smoking committee of Fujian China Tobacco Industrial Co., Ltd. by GB5606.4-2005 to the cigarette sample comparison of being smoked panel test.The Sensory Quality of Cigarette judgment criteria is as shown in Table A.
Table A Sensory Quality of Cigarette judgment criteria
Sensory evaluating smoking's inspection rule:
1, participating in the number of smokeing panel test is 13 people.
2, aesthetic quality's employing hundred-mark system of scoring, highest score is 100 minutes.
3, projects all are divided into 0.5 the unit of scoring.
4, when gloss, fragrance, harmony, assorted gas, excitant, six projects of pleasant impression are smoked panel test and scored, each project quality reaches the requirement of respective item, corresponding scoring.
Embodiment 1:
According to the formula in table 1, each component except 70% ethanol in table 1 is mixed, prepare the Tea Flower extractive composition with hot note.Wherein the 1# composition in contrast, only contains a kind of component Tea Flower medicinal extract.
Table 1
The Tea Flower extractive composition with hot note that embodiment 1 preparation is obtained, according to the ratio in upper table 1, adds 70% ethanol water, obtains Tea Flower extractive composition ethanolic solution.The Tea Flower extractive composition ethanolic solution with hot note obtained evenly is sprayed onto on pipe tobacco by 0.035% of pipe tobacco weight, rolls into cigarette after baking.Wherein 0#, as blank, only sprays 70% ethanol water on pipe tobacco.Then carry out sensory evaluating smoking's experiment by GB5606.4-2005, the comparison score of smokeing panel test situation is in Table 2.
Table 2 Sensory Quality of Cigarette check original record
Smoking result shows: the score of 3# and 4# composition is with to contrast 1# composition score suitable, and 2# composition score is the highest, apparently higher than control group and other groups.With respect to 1#, 3# and 4# composition, the cigarette that adds the 2# composition, its cigarette flavor harmony, cigarette perfume (or spice) is soft, and the skillful bent wine taste of ageing cigarette is arranged, and increases soft suffering perfume (or spice) and delicate fragrance, modify and correct the fragrant natural flavor of cigarette, augment the breath of flue-cured tobacco fragrance, assorted gas, stimulation reduce, and whole sucking quality is improved.
Embodiment 2:
According to the formula in table 3, each component except 70% ethanol in table 3 is mixed, prepare the Tea Flower extractive composition with hot note.Wherein the 1# composition in contrast, only contains a kind of component Tea Flower medicinal extract.
Table 3
The Tea Flower extractive composition with hot note that embodiment 2 preparations are obtained, according to the ratio in upper table 3, adds 70% ethanol water, obtains Tea Flower extractive composition ethanolic solution.The Tea Flower extractive composition ethanolic solution with hot note obtained evenly is sprayed onto on pipe tobacco by 0.025% of pipe tobacco weight, rolls into cigarette after baking.Wherein 0#, as blank, only sprays 70% ethanol water on pipe tobacco.Then carry out sensory evaluating smoking's experiment by GB5606.4-2005, the comparison score of smokeing panel test situation is in Table 4.
Table 4 Sensory Quality of Cigarette check original record
Smoking result shows: the score of 3# and 4# composition is with to contrast 1# composition score suitable, and 2# composition score is the highest, apparently higher than control group and other groups.With respect to 1#, 3# and 4# composition, the cigarette that adds the 2# composition, its cigarette flavor harmony, the natural flavor of improvement and promoting or transferring cigarette perfume (or spice), increase hot note, make cigarette flavor abundanter, increase the solid sense of fragrance, promote the mellow and full property of cigarette flavor, the person experiences naturally easily to bring the cigarette smoking, assorted gas, stimulation reduce, and whole sucking quality is improved.
Embodiment 3:
According to the formula in table 5, each component except 70% ethanol in table 5 is mixed, prepare the Tea Flower extractive composition with hot note.Wherein the 1# composition in contrast, only contains a kind of component Tea Flower medicinal extract.
Table 5
The Tea Flower extractive composition with hot note that embodiment 3 preparations are obtained, according to the ratio in upper table 5, adds 70% ethanol water, obtains Tea Flower extractive composition ethanolic solution.The Tea Flower extractive composition ethanolic solution with hot note obtained evenly is sprayed onto on pipe tobacco by 0.025% of pipe tobacco weight, rolls into cigarette after baking.Wherein 0#, as blank, only sprays 70% ethanol water on pipe tobacco.Then carry out sensory evaluating smoking's experiment by GB5606.4-2005, the comparison score of smokeing panel test situation is in Table 6.
Table 6 Sensory Quality of Cigarette check original record
Smoking result shows: the score of 3# and 4# composition is with to contrast 1# composition score suitable, and 2# composition score is the highest, apparently higher than control group and other groups.With respect to 1#, 3# and 4# composition, the cigarette that adds the 2# composition, its cigarette flavor harmony, increase happy tobacco aroma, promote cigarette nature cigarette perfume (or spice), increase hot note, the rich of cigarette flavor is improved, increase the comfortableness of cigarette flavor, assorted gas, stimulation reduce, and whole sucking quality is improved.
Embodiment 4:
According to the formula in table 7, each component except 70% ethanol in table 7 is mixed, prepare the Tea Flower extractive composition with hot note.Wherein the 1# composition in contrast, only contains a kind of component Tea Flower medicinal extract.
Table 7
The Tea Flower extractive composition with hot note that embodiment 4 preparations are obtained, according to the ratio in upper table 7, adds 70% ethanol water, obtains Tea Flower extractive composition ethanolic solution.The Tea Flower extractive composition ethanolic solution with hot note obtained evenly is sprayed onto on pipe tobacco by 0.045% of pipe tobacco weight, rolls into cigarette after baking.Wherein 0#, as blank, only sprays 70% ethanol water on pipe tobacco.Then carry out sensory evaluating smoking's experiment by GB5606.4-2005, the comparison score of smokeing panel test situation is in Table 8.
Table 8 Sensory Quality of Cigarette check original record
Smoking result shows: the score of 3# and 4# composition is with to contrast 1# composition score suitable, and 2# composition score is the highest, apparently higher than control group and other groups.With respect to 1#, 3# and 4# composition, add the cigarette of 2# composition, its cigarette flavor is coordinated, and fragrance is gentle and fragrance remaining time is long, increase hot note, fragrance is mellow and full soft, improves alcohol and the degree of cigarette flavor, increases fragrance rich, set off nature cigarette perfume (or spice), abirritate, improve mouthfeel.
Claims (17)
1. a Tea Flower extractive composition, by Tea Flower extract and hot fragrant flavor confect, formed, wherein said suffering spices be selected from that carrot seed oil, clove bud oil, aniseed oil, ennel oil, ginger oil, coriander extract, cumal, β-China pink are rare, one or more in eugenol, sage clary oil, radix valerianae extract, extract of cinnamomum cassia bark, radix tarxaci extract.
2. the composition of claim 1, wherein said Tea Flower extract is selected from Tea Flower medicinal extract, essential oil of the flower of Camellia sinensis, Tea Flower absolute oil, Tea Flower tincture or its combination.
3. the composition of claim 1, wherein said suffering spices is that clove bud oil, ennel oil, coriander extract, β-China pink are rare, eugenol and extract of cinnamomum cassia bark.
4. the composition of claim 3, wherein said Tea Flower extract is Tea Flower medicinal extract.
5. the composition of claim 4, wherein the content of each component, in weight portion, is respectively:
Tea Flower medicinal extract 10-30, be preferably 15-25 or 18-22, and more preferably 20;
Clove bud oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Ennel oil 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Coriander extract 0.02-0.08, be preferably 0.03-0.07 or 0.04-0.06, and more preferably 0.05;
The rare 0.05-0.15 of β-China pink, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Eugenol 0.1-0.3, be preferably 0.15-0.25 or 0.18-0.22, and more preferably 0.2;
Extract of cinnamomum cassia bark 0.2-0.3, be preferably 0.22-0.28 or 0.24-0.26, and more preferably 0.25.
6. the composition of claim 1, wherein said suffering spices is carrot seed oil, aniseed oil, ginger oil, sage clary oil, radix valerianae extract, extract of cinnamomum cassia bark, radix tarxaci extract.
7. the composition of claim 6, wherein said Tea Flower extract is essential oil of the flower of Camellia sinensis.
8. the composition of claim 7, wherein the content of each component, in weight portion, is respectively:
Essential oil of the flower of Camellia sinensis 5-15, be preferably 8-12 or 9-11, and more preferably 10;
Carrot seed oil 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Aniseed oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Ginger oil 0.02-0.08, be preferably 0.03-0.07 or 0.04-0.06, and more preferably 0.05;
Sage clary oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Radix valerianae extract 0.2-0.8, be preferably 0.3-0.7 or 0.4-0.6, and more preferably 0.55;
Extract of cinnamomum cassia bark 0.2-0.3, be preferably 0.22-0.28 or 0.24-0.26, and more preferably 0.25;
Radix tarxaci extract 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15.
9. the composition of claim 1, wherein said suffering spices is that carrot seed oil, aniseed oil, ginger oil, β-China pink are rare, radix valerianae extract, extract of cinnamomum cassia bark, radix tarxaci extract.
10. the composition of claim 9, wherein said Tea Flower extract is the Tea Flower absolute oil.
11. the composition of claim 10, wherein the content of each component, in weight portion, is respectively: Tea Flower absolute oil 15-35 is preferably 20-30 or 22-28, more preferably 25;
Carrot seed oil 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Aniseed oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Ginger oil 0.02-0.08, be preferably 0.03-0.07 or 0.04-0.06, and more preferably 0.05;
The rare 0.1-0.2 of β-China pink, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Radix valerianae extract 0.2-0.8, be preferably 0.3-0.7 or 0.4-0.6, and more preferably 0.55;
Extract of cinnamomum cassia bark 0.2-0.3, be preferably 0.22-0.28 or 0.24-0.26, and more preferably 0.25;
Radix tarxaci extract 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15.
12. the composition of claim 1, wherein said suffering spices is that clove bud oil, aniseed oil, ennel oil, β-China pink are rare, sage clary oil, extract of cinnamomum cassia bark, radix tarxaci extract.
13. the composition of claim 12, wherein said Tea Flower extract is the Tea Flower tincture.
14. the composition of claim 13, wherein the content of each component, in weight portion, is respectively: Tea Flower tincture 20-40 is preferably 25-35 or 28-32, more preferably 30;
Clove bud oil 0.02-0.08, be preferably 0.03-0.07 or 0.04-0.06, and more preferably 0.05;
Aniseed oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Ennel oil 0.02-0.08, be preferably 0.03-0.07 or 0.04-0.06, and more preferably 0.05;
The rare 0.1-0.2 of β-China pink, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Sage clary oil 0.05-0.15, be preferably 0.08-0.12 or 0.09-0.11, and more preferably 0.1;
Extract of cinnamomum cassia bark 0.1-0.2, be preferably 0.12-0.18 or 0.13-0.16, and more preferably 0.15;
Radix tarxaci extract 0.2-0.3, be preferably 0.22-0.28 or 0.24-0.26, and more preferably 0.25.
15. the composition of claim 1 to 14 any one, also comprise ethanol in said composition, preferred 50～95% ethanol water, further preferred 60～80% ethanol water, more preferably 65～75% ethanol water, be particularly preferably 70% ethanol water;
Preferably, the weight portion content of ethanol or ethanol water is 60-90, is preferably 75-80,85-90,70-75 or 65-70.
16. the purposes of the composition of claim 1 to 15 any one in cigarette, preferably as the purposes of cigarette additive, particularly preferably as the purposes of cigarette flavors;
Preferably, said composition can be for the internal lining paper of pipe tobacco, thin slice, cigarette, filter stick etc.
17. a cigarette, the composition that it comprises claim 1 to 15 any one,
Preferably, described composition is the composition that contains ethanol water;
Preferably, the consumption of the described composition that contains ethanol water is 0.005～0.05% of pipe tobacco weight.
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