CN103360670B - A kind of general high light black masterbatch - Google Patents
A kind of general high light black masterbatch Download PDFInfo
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- CN103360670B CN103360670B CN201310217932.7A CN201310217932A CN103360670B CN 103360670 B CN103360670 B CN 103360670B CN 201310217932 A CN201310217932 A CN 201310217932A CN 103360670 B CN103360670 B CN 103360670B
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- black
- carbon black
- resin
- high light
- black masterbatch
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- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 30
- 239000006229 carbon black Substances 0.000 claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 16
- 229920005989 resin Polymers 0.000 claims abstract description 16
- 239000004698 Polyethylene Substances 0.000 claims abstract description 14
- 229920000573 polyethylene Polymers 0.000 claims abstract description 9
- -1 polyethylene Polymers 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 239000000654 additive Substances 0.000 claims abstract description 5
- 230000000996 additive effect Effects 0.000 claims abstract description 5
- 229920001577 copolymer Polymers 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims description 5
- 239000004926 polymethyl methacrylate Substances 0.000 claims description 5
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 4
- 239000003963 antioxidant agent Substances 0.000 claims description 4
- 230000003078 antioxidant effect Effects 0.000 claims description 4
- 239000002270 dispersing agent Substances 0.000 claims description 4
- 239000000945 filler Substances 0.000 claims description 4
- 239000006057 Non-nutritive feed additive Substances 0.000 claims description 3
- 229920001903 high density polyethylene Polymers 0.000 claims description 3
- 239000004700 high-density polyethylene Substances 0.000 claims description 3
- 239000011164 primary particle Substances 0.000 claims description 3
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- ONIHPYYWNBVMID-UHFFFAOYSA-N diethyl benzene-1,4-dicarboxylate Chemical compound CCOC(=O)C1=CC=C(C(=O)OCC)C=C1 ONIHPYYWNBVMID-UHFFFAOYSA-N 0.000 claims description 2
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 2
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 2
- 229920001684 low density polyethylene Polymers 0.000 claims description 2
- 239000004702 low-density polyethylene Substances 0.000 claims description 2
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 2
- 229920001909 styrene-acrylic polymer Polymers 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 abstract description 7
- 239000004033 plastic Substances 0.000 abstract description 7
- 239000006185 dispersion Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 229920000728 polyester Polymers 0.000 abstract description 3
- 229920000098 polyolefin Polymers 0.000 abstract description 3
- 239000004952 Polyamide Substances 0.000 abstract description 2
- 229920002647 polyamide Polymers 0.000 abstract description 2
- 238000005453 pelletization Methods 0.000 description 9
- 239000001993 wax Substances 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 2
- 101100028196 Arabidopsis thaliana OS9 gene Proteins 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 101000617738 Homo sapiens Survival motor neuron protein Proteins 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 102100021947 Survival motor neuron protein Human genes 0.000 description 2
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BLDFSDCBQJUWFG-UHFFFAOYSA-N 2-(methylamino)-1,2-diphenylethanol Chemical compound C=1C=CC=CC=1C(NC)C(O)C1=CC=CC=C1 BLDFSDCBQJUWFG-UHFFFAOYSA-N 0.000 description 1
- 101000614436 Homo sapiens Keratin, type I cytoskeletal 14 Proteins 0.000 description 1
- 102100040445 Keratin, type I cytoskeletal 14 Human genes 0.000 description 1
- 208000033522 Proximal spinal muscular atrophy type 2 Diseases 0.000 description 1
- 101100351804 Schizosaccharomyces pombe (strain 972 / ATCC 24843) pfl8 gene Proteins 0.000 description 1
- 239000004699 Ultra-high molecular weight polyethylene Substances 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 201000006913 intermediate spinal muscular atrophy Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 125000002496 methyl group Chemical class [H]C([H])([H])* 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 208000032521 type II spinal muscular atrophy Diseases 0.000 description 1
- 229920000785 ultra high molecular weight polyethylene Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Abstract
The invention discloses a kind of general high light black masterbatch. General high light black masterbatch of the present invention is made up of following component and percetage by weight: carbon black and/or solvent black 20～60%, polyethylene 10～75%, transparent resin 5～50%, additive 4～40%. The invention provides a kind of general high light black masterbatch, this look female polyolefin, most of plastics such as styrol copolymer, polyester, polyamide of being applicable to; This look female good dispersion simultaneously; Blackness glossiness is high; Little to being colored the Effect on Mechanical Properties of resin.
Description
Technical field
The present invention relates to field of plastic coloring, relate to specifically a kind of general high light black masterbatch.
Background technology
Look mother is attached to the pigment of super quantity or dyestuff among resin and the aggregation obtaining also claims pigment concentrated equablyThing. According to Chinese Masterbatch committee statistics: within 2011, national Masterbatch output exceedes 650,000 tons. Wherein 40% is black masterbatch.Black masterbatch is widely used in the fields such as agricultural, packing business, architecture and decoration industry, automobile, machinery, household electrical appliances, post and telecommunications.
At present, the special and look mother that black masterbatch is carrier mainly with the resin same or close with being colored resin-phase; Or taking polyethylene asThe general black masterbatch of carrier. Special black masterbatch discloses taking MDPE and HDPE as carrier as: patent CN200610030033.6Polyethylene pipe workpiece for water supply black masterbatch, patent CN201010550637.X discloses gathering taking ultra-high molecular weight polyethylene as carrierEthylene tube carbonarius master batch. Patent CN02135596.7 disclose taking styrenic as carrier in styrene resinUse black agglomerate. Patent CN200810029614.7 disclose taking AS as carrier for AS serial plastic black agglomerate. PatentCN201010611390.8 discloses the degradation plastic black agglomerate taking PLA as carrier. These black masterbatch all haveGood dispersive property, but be only that a certain or a certain resinoid is special.
General black masterbatch as: patent CN201010599302.7 discloses taking LLDPE6201 as carrier, carbon black (900L) content>=70% high concentration black masterbatch, this black masterbatch can be used for ABS and vistanex. But the only black masterbatch taking polyethylene as carrierBe applied to other plastics, during as ABS, easily cause that blackness reduces, goods layering, the shortcomings such as impact strength reduction.
Summary of the invention
The object of the invention is to solve the problem that above-mentioned existing black masterbatch exists when painted, a kind of the logical of production and processing that be easy to is providedUse type black masterbatch, this look mother can be applicable to polyolefin, most of plastics such as styrol copolymer, polyester, polyamide. This lookFemale little to the Effect on Mechanical Properties of material, goods dispersive property is good simultaneously, blackness glossiness is high.
General high light black masterbatch of the present invention by following component by weight percentage form: carbon black and/or solvent black 20～60%,Polyethylene 10～75%, transparent resin 5～50%, additive 4～40%.
Above-mentioned carbon black is the carbon black of the average primary particle diameter≤30nm of carbon black, and preferably average primary particle size range is 9～17nmHigh-carbon black pigment. 250 DEG C of above solvent black dyestuffs of the preferred heatproof of above-mentioned solvent black.
Above-mentioned polyethylene is one or more the mixture in LLDPE, LDPE, HDPE, and preferred molten index is 2～70The polyvinyl resin of g/10min. Taking polyethylene as carrier, can make black masterbatch there is good processing characteristics.
Above-mentioned transparent resin be polymethyl methacrylate (PMMA), Merlon (PC), polybutyl terapthalate (PBT),Poly terephthalic acid diethylester (PET), acrylonitrile-styrene-acrylic ester copolymer (ASA), transparent ABS, metering systemAcid methyl esters-BS (MBS), acrylonitritrile-styrene resin (SAN), styrene-maleic anhydride copolymerThe mixture of one or more in thing (SMA), saturating benzene (GPPS), preferably PC and PMMA resin. In black masterbatch, add thoroughlyMing tree fat can improve the blackness of black masterbatch, increases the glossiness of goods.
Above-mentioned additive is dispersant, antioxidant, filler and processing aid. Wherein the preferred PE wax of dispersant, EBS, ester type waxes,EVA wax, oxidation PE wax; Antioxidant preferably 168,1010; Filler, preferably calcium carbonate, barium sulfate, talcum powder etc.; ProcessingThe mixture of one or more in the preferred calcium stearate of auxiliary agent, odium stearate, zinc stearate, dolomol. In black masterbatch, addAdd dispersant and can improve carbon black at the dispersive property being colored in resin, reduce the generation of stain, flow liner. Add antioxidant energyThe enough raising service life that is colored resin, avoids process thermal oxide to decompose simultaneously and is colored resin. Add filler and promote charcoalBlack dispersion, improves the tinting strength, tinting power of carbon black and reduces costs. Add processing aid and can improve look mother's processing characteristics.
Described black masterbatch can be prepared by the following method: 1. each component joined in low-speed mixer, and in blend 5～10min,Add extruding pelletization in double screw extruder to prepare described look mother well-mixed material. 2. each component being joined to low speed stirsMix in machine, in blend 5～10min, well-mixed material is added in two-rotor continuous mixer mixing, then through single screw rodExtruder extruding pelletization is prepared described look mother. 3. each component is directly dropped in banbury to banburying 5～20 minutes, then squeeze through screw rodGo out machine extruding pelletization and prepare described look mother.
Of the present invention have compared with existing product: highly versatile, is applicable to polyolefin, styrol copolymer, polyester, polyamideEtc. most of plastics; Good dispersion; Blackness glossiness is high; To being colored the advantages such as the Effect on Mechanical Properties of resin is little.
Detailed description of the invention
Embodiment 1
Carbon black 20%, HDPE14%, transparent ABS 20%, PE wax 3%, EBS3%, barium sulfate 40%. Each component is addedEnter in low-speed mixer, in blend 10min, add extruding pelletization in double screw extruder to prepare look well-mixed materialFemale.
Embodiment 2
Carbon black 30%, LLDPE20%, LDPE10%, PC20%, EVA wax 6%, SMA3%, dolomol 2%,Antioxidant 1010 6%, irgasfos 168 3%. Each component is joined in low-speed mixer, in blend 5min, will be fully mixedThe material closing adds in two-rotor continuous mixer mixing, then prepares look mother through single screw extrusion machine extruding pelletization.
Embodiment 3
Carbon black 35%, nigrosine 5%, LLDPE10%, PMMA10%, SMA2%, ASA28%, ester type waxes 7%, oxygenChange PE wax 2%, antioxidant 1010 1%. Each component is directly dropped in banbury to banburying 15 minutes, then through screw extruderExtruding pelletization is prepared look mother.
Embodiment 4
Carbon black 50%, LLDPE40%, SMA5%, PE wax 4%, calcium stearate 1%. Each component is directly dropped into banburyMiddle banburying 10 minutes, then prepare look mother through screw extruder extruding pelletization.
Comparative example 1
Carbon black 20%, LLDPE74%, EBS6%. Each component is joined in low-speed mixer, in blend 10min, will be fullyThe material mixing adds extruding pelletization in double screw extruder to prepare look mother.
Comparative example 2
Carbon black 40%, SAN54%, EBS6%. Each component is directly dropped in banbury to banburying 15 minutes, then squeeze through single screw rodGo out machine extruding pelletization and prepare look mother.
Masterbatch prepared by embodiment and comparative example, even according to 2% ratio and mixed with resin, be injection molded into colour table and impact sampleBar. Investigate dispersive property, blackness, glossiness and impact retention rate. Wherein blackness adopts color difference meter test, gets its L value, LBe worth littlely, blackness is higher, impacts retention rate and be the percentage that adds look female batten impact strength and account for pure resin-like bar impact strength. Surface gloss adopts vancometer to measure. No matter can find out it is at PP or ABS is painted from test result, realExecute example and be all better than comparative example aspect dispersiveness, blackness, impact retention rate and glossiness.
Table 1: comparative example and embodiment test result
Claims (1)
- A general high light black masterbatch by following component by weight percentage form: carbon black and/or solvent black 20～60%; Polyethylene 10～75%; Transparent resin 5～50%; Additive 4～40%; Wherein, the consumption summation of above-mentioned each component is 100%; Described carbon black is the carbon black of the average primary particle diameter≤30nm of carbon black, and described solvent black is 250 DEG C of above solvent black dyestuffs of heatproof; Described polyethylene is the polyvinyl resin of melt index at 2～70g/10min; Described transparent resin is polymethyl methacrylate (PMMA), Merlon (PC), polybutyl terapthalate (PBT), poly terephthalic acid diethylester (PET), acrylonitrile-styrene-acrylic ester copolymer (ASA), transparent ABS, MBS (MBS), acrylonitritrile-styrene resin (SAN), styrene-maleic anhydride copolymer (SMA), the mixture of one or more in benzene (GPPS) thoroughly; Described polyethylene is one or more the mixture in LLDPE, LDPE, HDPE; Described additive is one or more the mixture in dispersant, antioxidant, filler, processing aid.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310217932.7A CN103360670B (en) | 2013-06-03 | 2013-06-03 | A kind of general high light black masterbatch |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310217932.7A CN103360670B (en) | 2013-06-03 | 2013-06-03 | A kind of general high light black masterbatch |
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| CN103360670A CN103360670A (en) | 2013-10-23 |
| CN103360670B true CN103360670B (en) | 2016-05-04 |
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| CN103756095B (en) * | 2014-01-15 | 2016-02-10 | 佛山市南方包装有限公司 | A kind of high-barrier color plastic products hindering dampness gas |
| CN104356574B (en) * | 2014-10-14 | 2016-08-24 | 惠州市昊鹰新型材料科技有限公司 | Highlighted black masterbatch of high light and preparation method thereof |
| CN104592619A (en) * | 2014-11-05 | 2015-05-06 | 新疆开瑞新环保材料有限责任公司 | Multifunctional composite film master batch |
| CN104725755A (en) * | 2015-03-04 | 2015-06-24 | 安徽科聚新材料有限公司 | PMMA (polymethyl methacrylate)/ABS (acrylonitrile-butadiene-styrene) alloy material with high blackness and brightness and preparation method of PMMA/ABS alloy material |
| WO2017066973A1 (en) * | 2015-10-23 | 2017-04-27 | 揭东巴黎万株纱华纺织有限公司 | Colour masterbatch formula |
| CN105273349B (en) * | 2015-11-10 | 2017-12-29 | 宁波色母粒有限公司 | Polymethyl methacrylate black agglomerate and preparation method thereof |
| CN106084716B (en) * | 2016-06-13 | 2019-01-25 | 上海锦湖日丽塑料有限公司 | Weather-proof bloom is exempted to spray PC/ASA alloy material and preparation method thereof |
| CN105924753A (en) * | 2016-07-07 | 2016-09-07 | 苏州虹吸塑胶制品有限公司 | Plastic alloy composition |
| CN106009358B (en) * | 2016-07-22 | 2018-10-16 | 佳易容相容剂江苏有限公司 | Has the black masterbatch and preparation method thereof of high coloring power, surface aesthetic application effect |
| IT201600109323A1 (en) | 2016-10-28 | 2018-04-28 | Giovanni Broggi | UNIVERSAL PIGMENTARY PREPARATIONS FOR COLORING AND REINFORCING PLASTIC MATERIALS |
| WO2018138256A1 (en) * | 2017-01-30 | 2018-08-02 | Basf Se | Polyamide composition which is dyed in black, production and use thereof |
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| CN108610555A (en) * | 2018-05-09 | 2018-10-02 | 台山市恒嘉五金塑料制品有限公司 | Air-leg inner tube and preparation method thereof |
| CN108864540A (en) * | 2018-07-18 | 2018-11-23 | 广西南宁荣威德新能源科技有限公司 | A kind of impact high density polyethylene (HDPE) feed pipe and preparation method thereof |
| CN111171424B (en) * | 2019-12-26 | 2022-12-02 | 浙江佳华精化股份有限公司 | High-fluidity black master batch for PA engineering plastic and preparation method thereof |
| CN112552571B (en) * | 2020-12-08 | 2021-07-09 | 南京工业大学 | Universal color master batch with high carbon black content and high melt flow rate and preparation method thereof |
| CN112812359A (en) * | 2021-01-07 | 2021-05-18 | 上海英耀塑胶材料有限公司 | Carrier-free high-gloss oil black master batch and preparation method and application thereof |
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